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1.
Fluid evolution during metamorphism of the Otago Schist, New Zealand: (II) Influence of detrital apatite on fluid salinity 总被引：1，自引：0，他引：1
Apatite occurs in the zeolite to greenschist facies metamorphic rocks of the Otago Schist, South Island, New Zealand, as both a groundmass constituent and as a hydrothermal phase hosted in metamorphic quartz veins. Groundmass apatite from low-grade rocks, ranging from the zeolite facies to the pumpellyite–actinolite zone, has chloride contents ranging from 0–1.4 wt%, and fluoride contents ranging from 2.2–4.2 wt%, whilst groundmass apatite from the greenschist facies (chlorite to biotite zone) is virtually pure fluorapatite. Vein apatite from all grades is also fluorapatite with little or no chloride. This difference in composition is interpreted as resulting from the preservation of the primary magmatic compositions of detrital Cl-apatite grains, out of equilibrium with the metamorphic fluid, at low grades, whilst higher-grade groundmass apatite and neoformed apatite in quartz veins have compositions in equilibrium with an aqueous metamorphic fluid. The presence of detrital Cl-bearing apatite during the early stages of metamorphism may constitute a significant reservoir of Cl, given the low porosities of compacted sediments undergoing prograde metamorphism. Calculations indicate that the release of Cl from detrital apatite in the Otago Schist, as a result of re-equilibration of apatite with the pore fluid, may have had a significant effect on the salinity of the metamorphic fluid. 相似文献
2.
长江三角洲东西部晚新生代地层中的 重矿物差异及其物源意义* 总被引：10，自引：7，他引：10
主要针对长江三角洲东西部两个晚新生代钻孔的重矿物分布特征,探讨了近河口区和内陆三角洲平原区物源演化差异。研究结果表明,近河口区自下而上地层中可以划分出5个不同的重矿物组合带,内陆平原区可划分出4个重矿物组合带,这些组合带分别对应着上新世、早、中、晚更新世和全新世。两区在上新世时期重矿物特征十分相似,以金红石、锆石、电气石等酸性-中酸性矿物为主,伴随着许多强氧化自生矿物,如赤铁矿、褐铁矿、白钛石等,表明了以基底和西部天目山为主的物源,指示了强烈风化的沉积环境。进入第四纪,两区沉积物来源发生了变化,内陆平原区继承了西部山地物源,但不稳定矿物增加,并伴随出现许多还原性自生矿物,如黄铁矿、重晶石、碳酸盐等,指示还原环境占主导。相比之下,近河口区物源明显发生变化,尤其是中更新世后矿物种类丰富,金红石、榍石等酸性-中酸性矿物,紫苏辉石、钛铁矿等基性矿物,透辉石、蓝晶石、符山石、十字石等典型变质岩矿物都稳定出现,意味着随着沉积盆地下沉,河口区逐渐接受了长江中下游和上游沉积物的物源。 相似文献
3.
The finite strain of clasts (maximum aspect ratio varying from 2 to 40) in a deformed conglomerate from Dry Hill, Plymouth, Vermont, correlates inversely with the average grain size (300-150 μm) in the clast, suggesting that the operative deformation mechanism was grain-size sensitive. In a general way, the average quartz grain size appeared to be smaller in those clasts with higher volume of minerals other than quartz. Dislocation densities varied by as much as a factor of 10 from grain to grain within a clast, but the average dislocation density was relatively constant from clast to clast. If grain-size sensitivity of strength is accepted as a working hypothesis, other elements of the microstructure, such as grain flattening, grain morphology, and dislocation structure can be reconciled as happening either through a late, low strain, high stress pulse—if the current palaeostress indicators are correct to within a factor of 10 or as happening concurrently with the grain-size sensitive mechanism if the current palaeostress estimates are in error. The evidence from this study agrees with several previously published suggestions that grain-size sensitive deformation occurs in the crust for quartzose rocks with grain size of 100 to 300 μm at temperatures of 350 to 420°C. 相似文献
4.
Origin of the 3500-3300 Ma calc-alkaline rocks in the Pilbara Archaean: isotopic and geochemical constraints from the Shaw Batholith 总被引：1，自引：0，他引：1
M.J. Bickle L.F. Bettenay H.J. Chapman D.I. Groves N.J. McNaughton I.H. Campbell J.R. de Laeter 《Precambrian Research》1993,60(1-4)
Calc-alkaline plutonic rocks, intruded at 3450Ma, comprise a major component of the Shaw Batholith in the Archaean east Pilbara Block, Western Australia. New whole-rock Pb isotopic geochronology confirms the extent of these rocks, but a minor plutonic phase is dated at 3338±52 Ma and represents a second plutonic event of the same age as much of the nearby Mt Edgar Batholith. The Sm----Nd isotopic systematics of the 3450Ma rocks imply their derivation from a heterogeneous source, which probably included a slightly older crustal component as well as a depleted mantle component. The 3338±52 Ma pluton includes components derived from crustal sources older than 3600 Ma. The geochemistry and Sm---Nd isotopic systematics of these rocks are consistent with crustal growth in the early Archaean from upper mantle sources as depleted as the modern upper mantle. The Shaw Batholith calc-alkaline suites exhibit very similar chemical trends on variation diagrams to modern calc-alkaline plutonic rocks which can be modelled by a combination of mixing and fractionation. A suite collected from outcrops displaying prominent igneous layering shows distinct geochemical trends which can be modelled by differentiation into a component enriched in ferromagnesian minerals, principally hornblende, and possibly sphene, magnetite and epidote, and into a leucocratic component containing quartz, plagioclase and K-feld-par. These Archaean calc-alkaline plutonic rocks, in common with rocks from many other Archaean calc-alkaline provinces, exhibit very fractionated REE patterns with depleted HREE contents, a feature considered to result from equilibrium with garnet at depth in lower crustal regions. The geochemistry of the Pilbara Archaean calc-alkaline rocks is identical to the subset of modern continental-margin calc-alkaline plutonic rocks with fractionated REE patterns, such as those from the central and eastern Peninsular Ranges Batholith, western USA. The tectonic setting in which the Archaean calc-alkaline rocks formed is still not known. This reflects both uncertainty associated with the petrogenesis and environments of modern calc-alkaline rocks, as well as the limited knowledge of the precise timing and relationships of plutonic, depositional and tectonic events in the Pilbara Archaean. 相似文献
5.
Stephanie Butcher 《Geoforum》2008,39(2):1079-1092
This paper is concerned with the experiences of young adults with intellectual disabilities as they transition from high school in search of paid employment. The experiences of people with intellectual disability remain under-researched within geography. We use qualitative techniques to examine the experiences of six young adults with intellectual disabilities. Data are drawn from interviews with the youth themselves, their parents, and employers, as well as from participant observation at an employment training program for the intellectually disabled. While the primary goal of the youth and their parents was to make a transition to competitive paid work, a lack of transition planning, a shortage of appropriate opportunities and other factors meant the youth spent considerable time in ‘transitional spaces’ such as the vocational training centre, sheltered workshop, and supported employment placements. While these spaces are organized around an explicitly economic goal of augmenting the youth’s employability, they can play a critical role as spaces for social interaction and meaningful activity outside the home. Study findings point to the importance of moving beyond paid employment as the core of a successful transition to consider a broader goal of ‘meaningful activity’. 相似文献
6.
《Geoforum》2017
Research on international student’s post migration plans treats migration as a binary stay-return category and focuses on push-pull factors as the cause of this migration. In this paper we expand the definition of migration and consider the role of life experiences and aspirations, particularly the concept of home. We ask, what are the different conceptualizations of home and how are these tied to differential migratory plans? We analyze data from 232 interviews with international students from more than 50 countries who attended a flagship public university in Canada from 2006–2013.We find that students have four ways of thinking about home: as host, as ancestral, as cosmopolitan, and as nebulous. These understandings of home correspond to particular post-migration plans. While students who view home as a host plan to stay, and those who view home as ancestral plan to return, those with cosmopolitan and nebulous conceptions of home have more open migration plans. 相似文献
7.
地质科学的任务正从资源勘探扩展到环境预测,从面向过去变为也要面向未来。与此相应,除地球的固态圈层外,气圈和水圈的历史演变也成为其直接的研究对象。古海洋学、古湖泊学、古水文学、古大气化学和古气象学等新学科应运而生。新的研究领域要求改革研究方法,应用严格的数据采集和处理技术、经过模式的建立和检验过程的定量研究,其结果必将推动整个地质科学的现代化。最后对我国开展相应研究提出了若干建议。 相似文献
8.
Modern and post-modern cities and ethnic residential segregation: Is Los Angeles different? 总被引：1，自引：0，他引：1
Dear and others associated with the ‘Los Angeles School of Urbanism’ have presented a series of challenging ideas regarding changes in urban form as a consequence of the shift from modernism to post-modernism. Some of those challenges relate to a city’s ethnic diversity and residential segregation, with Los Angeles presented as a paradigm exemplar of an emerging new urban form. This paper evaluates the arguments that Los Angeles in particular, and Californian metropolitan areas more generally, differ from metropolitan areas elsewhere in the United States in the nature of ethnic residential segregation there. Regression analyses provide little support for the argument, but graphical analyses show that although Los Angeles does not differ from the general, US-wide trends, its almost unique nature in terms of its ethnic diversity means that it clearly stands out as a place with a different pattern shared by very few others. 相似文献
9.
Core samples were taken at two sites from a peat deposit buried by a sanitary landfill operated by the city of Vancouver since the 1960s and from a third site where the same peat bed is not covered by landfill. Twenty-nine subsamples from the three cores were analyzed by a variety of techniques to determine the concentration of as many as 34 constituents. The content of heavy metals, the principal object of this investigation, is highest in the lower part of the peat succession, in which there is a significant amount of interbedded inorganic sediment, rather than in the upper clean bog peat. Individual layers as little as 2.5 cm thick can hold concentrations of heavy metals ten times that of the nearby layers. The heavy metal contents show a high positive correlation with those of iron and manganese and a very low correlation with sulfur. Iron from the landfill has been transported by downward percolating groundwater in solution or colloidal suspension into the lower layers of peat deposit where the passing heavy metals were sorbed. A comparison of the amounts of heavy metals stored in the peat alone with the amount leaving the whole landfill annually suggests that some metals, notably lead and arsenic, might be retained in the peat for very long periods, whereas other metals such as zinc and mercury might be quickly lost. 相似文献
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11.
Ida M. Berstad Joyce Lundberg Stein-Erik Lauritzen Henriette C. Linge 《Quaternary Research》2002,58(3):361
A stalagmite from northern Norway is dated with 12 thermal ionization mass spectrometry U-Th dates, and at least four separate growth periods are identified that correspond with marine isotope stages 9, 11, 13, and probably 15. The calcite is tested for isotopic equilibrium with the Hendy test. Oxygen isotope measurements on 231 subsamples on a vertical transect are used as a paleotemperature proxy. The detailed isotopic record from MIS 9 show apparent similarities to a Holocene record from the same cave, both in the climatic evolution and the overall temperatures: both show temperature oscillations changing from high-frequency, low-amplitude cycles in the beginning of the interglacial period to lower frequency, higher amplitude cycles in the later part of the interglacial period. The isotope record from MIS 11 shows a distinct isotopic event toward heavier values. The isotopic record together with the porous, humus-rich calcite are interpreted as indicating a warmer than present interglacial period with several episodes of heavy rainfall. 相似文献
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Sang Woo Ji Young Wook Cheong Gil Jae Yim Jayanta Bhattacharya 《Environmental Geology》2007,52(6):1033-1043
Acid rock drainage (ARD) is a longstanding problem often associated with the resulting corrosion due to the acidity generated
from sulfidic oxidation. To evaluate characteristics of ARD and corrosion, samples from the road side rock mass of Boeun and
Mujoo were analysed using X-ray diffraction, acid/base accounting and Leaching tests. The results indicated that many samples
had a pyritic origin and can be regarded as acid-generating rocks. The Leaching test showed that the average pH of the leachates
of samples from both Boeun and Mujoo were moderately acidic, ranging from 3 to 4. Interestingly, as acidity increases from
pH 4, the SO4−, Fe, Al and Mg concentrations increase abnormally. Samples from roadside slope of Mujoo showed high corrosive potential.
Maximum sulfide oxidation rate of a sample taken from Mujoo was as high as 5,166 mg/kg/week. 相似文献
14.
《Quaternary Science Reviews》2007,26(22-24):2694-2700
Data on fluvial sequences from around the world, collected as part of IGCP 449, has allowed comparison between such records with the purpose of searching for meaningful patterns. A key finding has been that fluvial incision rates, as measured by the vertical separations of well-dated terrace deposits one from another, and from the modern valley floor (which can be used as a proxy for uplift), are often very similar in different parts of the world but vary significantly between systems on different types of crust. The collection that this paper introduces, coupled with previous IGCP 449 publications cited, confirms that the aim of a worldwide compilation of fluvial archives has been achieved, with a number of syntheses already published. 相似文献
15.
岫岩玉的种类、矿床地质特征及成因 总被引：1，自引：0，他引：1
岫岩玉是我国四大名玉之一,开发历史悠久,在中华玉文化发展史上占有十分重要的地位,著名的兴隆洼文化、红山文化、龙山文化和河北满城的金缕玉衣皆为岫岩玉所制.在多年野外实地考察和室内测试研究的基础上,对岫岩玉的种类和宝玉石学特征进行了系统总结,对岫岩玉的矿床地质特征进行了全面阐述,最后从多方面论述了岫岩玉的成因,建立了岫岩玉的成矿模式. 相似文献
16.
LI Qiugen CHEN Xu LIU Shuwen WANG Zongqi ZHOU Yingkui ZHANG Jian WANG Tao 《《地质学报》英文版》2009,83(3):550-561
Abstract：In this study, whole-rock geochemical and Nd isotopic data, as well as detrital zircon Hf isotopes of Palaeoproterozoic metasedimentary rocks from the Jiangxian Group are presented to evaluate the characteristics of their provenance and the tectonic history. The major and trace element compositions are comparable to Post-Archean upper continental crust (PA-UCC), but have slight enrichment in the LILE, with the exception of Cs and Sr, and a slight depletion in ferromagnesian elements, HFS elements, such as Nb and Ta, and some major elements, such as CaO and Na2O. The geochemical data reveal that the collected metasedimentary rocks have experienced intermediate source weathering with chemical index of alteration values ranging from 72 to 78, varying degrees of K-metasomatism, and post-depositional loss of Na, as well as negligible sorting, and are derived from the weathering of mostly felsic and non-mafic rocks. The selected Lu–Hf isotopic analysis on detrital zircon points to both the Trans-North China Orogen and Eastern Block of the north China craton as the most likely sources for the metasedimentary rocks of the Jiangxian Group. However, a contribution of detritus from the Western Block of the north China craton can be ruled out. The sediments were probably deposited in a back-arc basin within an active continental margin setting. 相似文献
17.
G. N. Baturin 《Lithology and Mineral Resources》2001,36(2):99-108
Uranium and thorium content, as well as their distribution patterns are studied in biogenic phosphates from the Atlantic and Indian oceans. The material studied is represented by differently lithified fish remains (bones, scales, teeth) and marine mammal bones (ribs, vertebras, earbones) collected from both reduced shelf sediments and oxidized pelagic ones. The U content in the material varies from 0.7 to 700 ppm, and the Th content ranges from less than 0.5 to 14 ppm. The U/Th ratio varies from 0.16 to 400. Contents of both elements increase with the lithification of biogenic phosphates. The U concentration is more intense on shelves, whereas the thorium concentration increases in pelagic areas. A partial positive correlation of U and Th with Fe but a negative correlation of U with organic carbon are noted. The latter corresponds to increasing lithification of biogenic phosphates. Calcium phosphate, which is transformed from hydroxyapatite to fluorcarbonate-apatite serves as the main carrier of U, while transformed organic matter is a minor agent. Thorium is mainly bound with Fe. 相似文献
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Fault blocks and inliers of uppermost Silurian to Middle Devonian strata in the Yarrol Province of central coastal Queensland have been interpreted either as island-arc deposits or as a continental-margin sequence. They can be grouped into four assemblages with different age ranges, stratigraphic successions, geophysical signatures, basalt geochemistry, and coral faunas. Basalt compositions from the Middle Devonian Capella Creek Group at Mt Morgan are remarkably similar to analyses from the modern Kermadec Arc, and are most consistent with an intra-oceanic arc associated with a backarc basin. They cannot be matched with basalts from any modern continental arc, including those with a thin crust (Southern Volcanic Zone of the Andes) or those built on recently accreted juvenile oceanic terranes (Eastern Volcanic Front of Kamchatka). Analyses from the other assemblages also suggest island-arc settings, although some backarc basin basalt compositions could be present. Arguments for a continental-margin setting based on structure, provenance, and palaeogeography are not conclusive, and none excludes an oceanic setting for the uppermost Silurian to Middle Devonian rocks. The Mt Morgan gold–copper orebody is associated with a felsic volcanic centre like those of the modern Izu–Bonin Arc, and may have formed within a submarine caldera. The data are most consistent with formation of the Capella Creek Group as an intra-oceanic arc related to an east-dipping subduction zone, with outboard assemblages to the east representing remnant arc or backarc basin sequences. Collision of these exotic terranes with the continent probably coincided with the Middle–Upper Devonian unconformity at Mt Morgan. An Upper Devonian overlap sequence indicates that all four assemblages had reached essentially their present relative positions early in Late Devonian time. Apart from a small number of samples with compositions typical of spreading backarc basins, Upper Devonian basalts and basaltic andesites of the Lochenbar and Mt Hoopbound Formations and the Three Moon Conglomerate are most like tholeiitic or transitional suites from evolved oceanic arcs such as the Lesser Antilles, Marianas, Vanuatu, and the Aleutians. However, they also match some samples from the Eastern Volcanic Front of Kamchatka. Their rare-earth and high field strength element patterns are also remarkably similar to Upper Devonian island arc tholeiites in the ophiolitic Marlborough terrane, supporting a subduction-related origin and a lack of involvement of continental crust in their genesis. Modern basalts from rifted backarc basins do not match the Yarrol Province rocks as well as those from evolved oceanic arcs, and commonly have consistently higher MgO contents at equivalent levels of rare-earth and high field strength elements. One of the most significant points for any tectonic model is that the Upper Devonian basalts become more arc-like from east to west, with all samples that can be matched most readily with backarc basin basalts located along the eastern edge of the outcrop belt. It is difficult to account for all geochemical variations in the Upper Devonian basalts of the Yarrol Province by any simplistic tectonic model using either a west-dipping or an east-dipping subduction zone. On a regional scale, the Upper Devonian rocks represent a transitional phase in the change from an intra-oceanic setting, epitomised by the Middle Devonian Capella Creek Group, to a continental margin setting in the northern New England Orogen in the Carboniferous, but the tectonic evolution must have been more complex than any of the models published to date. Certainly there are many similarities to the southern New England Orogen, where basalt geochemistry indicates rifting of an intra-oceanic arc in Middle to Late Devonian time. 相似文献
20.
The Lynx mine, currently inactive, has produced copper and zinc concentrates from massive sulfide deposits on a lease within the rainy, mountainous interior of Vancouver Island. Tailings, used to back-fill a mined-out stope, are being leached by percolating groundwater and the resulting acidic, metal-laden drainage is discharging from the portal of the 8-Level adit. Temporal variations in the flow rate, specific conductance and temperature of the discharge were monitored continuously over a 2-year period while effluent chemistry was sampled weekly. Conductivity was relatively constant throughout most of the year but peaked with the first autumn storm events as accumulated soluble sulfide oxidation products were flushed from the workings. Concentrations of sulfate and most metals were closely correlated with conductivity as were low pH values as stored acidity was released along with dissolved species. Variations in pH controlled the speciation and partitioning of metals between dissolved and particulate phases. 相似文献