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四川赤普铅、锌矿床生物标志化合物特征研究 总被引：3，自引：0，他引：3
赤普铅、锌矿床的矿体中发育大量沥青,铅、锌矿化形成与沥青密切相关。应用族组分分离和定量及饱和烃色—质分析等方法对铅、锌矿中的沥青族组分和生物标志物进行了研究,并对其地质意义进行了探讨。通过研究取得如下认识:（1）铅、锌矿床内有机质主要来自碳酸盐岩,其次来自页岩,没有陆源有机质的加入;这种混合来源特征受到不同来源成矿流体作用的影响。（2）矿区内有机质反映了热液流体经历了还原、高盐度的物理化学过程。（3）矿区内有机质成熟度高,主要为炭质沥青,反映有机质的演化程度较高;矿体内有机质与围岩内有机质成熟度类似,反映它们经历了类似的地质作用过程。（4）有机质还原碳酸盐岩中的硫酸盐岩,产生还原硫,为铅、锌等硫化物的沉淀创造条件。（5）成矿流体中烃类含量比较高,推断已经演化到高成熟阶段的有机质可能以古油气藏的形式参与了成矿作用;有机质在与含矿流体混合过程中扮演着还原剂的角色。 相似文献
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XU Huiyuan LIU Quanyou JIN Zhijun ZHU Dongy MENG Qingqiang LI Pengpeng ZHU Biqing 《《地质学报》英文版》2023,97(1):327-336
Continental epithermal ore deposits are commonly associated with sedimentary organic matter, oils or solid bitumen. These organics embedded in mineral deposits can convey valuable information of the ore genesis. However, the extent to which the formation of ore minerals was recorded by organic compounds remains largely unknown, as also is how metal-rich ores interfere with the molecular proxies in the temperature regime envisaged for hydrothermal activity. The molecular compositional changes of ... 相似文献
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Sabina Strmić Palinkaš Jorge E. Spangenberg Ladislav A. Palinkaš 《Mineralium Deposita》2009,44(8):893-913
The Ljubija siderite deposits, hosted by a Carboniferous sedimentary complex within the Inner Dinarides, occur as stratabound
replacement-type ore bodies in limestone blocks and as siderite–sulfides veins in shale. Three principal types of ore textures
have been recognized including massive dark siderite and ankerite, siderite with zebra texture, and siderite veins. The ore
and host rocks have been investigated by a combination of inorganic (major, trace, and rare earth element concentrations),
organic (characterization of hydrocarbons including biomarkers), and stable isotope geochemical methods (isotope ratios of
carbonates, sulfides, sulfates, kerogen, and individual hydrocarbons). New results indicate a marine origin of the host carbonates
and a hydrothermal–metasomatic origin of the Fe mineralization. The differences in ore textures (e.g., massive siderite, zebra
siderite) are attributed to physicochemical variations (e.g., changes in acidity, temperature, and/or salinity) of the mineralizing
fluids and to the succession and intensity of replacement of host limestone. Vein siderite was formed by precipitation from
hydrothermal fluids in the late stage of mineralization. The equilibrium fractionation of stable isotopes reveals higher formation
temperatures for zebra siderites (around 245°C) then for siderite vein (around 185°C). Sulfur isotope ratios suggest Permian
seawater or Permian evaporites as the main sulfur source. Fluid inclusion composition confirms a contribution of the Permian
seawater to the mineralizing fluids and accord with a Permian mineralization age. Organic geochemistry data reflect mixing
of hydrocarbons at the ore site and support the hydrothermal–metasomatic origin of the Ljubija iron deposits. 相似文献
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黔西南灰家堡金矿田有机岩相学和地球化学 总被引：1，自引：0，他引：1
灰家堡金矿田是黔西南卡林型金矿床的集中产地之一,对其中的水银洞、紫木凼、太平洞和簸箕田4个代表性金矿床进行了有机岩相学和地球化学研究。灰家堡金矿田的矿床中固体沥青主要产于矿石内,与矿化关系密切,产出形态受孔隙、构造裂隙控制;沥青与热液期矿物的共生组合关系表明其形成时间与成矿时间大致一致。矿石中普遍发育有机质包裹体。有机地球化学特征表明,金矿石和围岩中的有机质成熟度均较高,经历了类似的地质作用过程;有机质形成于强还原、中低盐度的沉积环境;有机质来源以海相菌藻类等低等生物为主,有少量陆源高等植物的输入。 相似文献
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Data from the super-deep wells(PS10,PS14 and YS1)led to the discovery of widespread met-al-bearing hydrothermal fluids (or hot brines) related to basic magmas in the Lower Tertiary clastic sequence in the Dongpu Depression .In terms of SEM and EDAX analyses, pore-casting thin section examination of sandstone ,the composition and forming temperature of fluid inclusions ,the trace ele-ment composition of mustone and kerogen and organic geochemical analyses, it is demonstrated that the hydrothermal fluids existing in the area studied are ejecting fluids, which have a close bearing on diagenesis and sedimentation, rather than intrusive veins along the tectonic fractures.The main indicators of hydrothermal activity are:(1)abnormal alteration of kerogen;(2) high-temperature altered mineral assemblage;(30abnormal distribution of hydrocarbons;(4) specific assemblages and abnormal contents of heavy metals in mudstone and kerogen;(5) specific composi-tion of complex compounds and assemblages of fluid inclusions in sandstone;(6) periodic basaltic magma activity.Results of geological observations and laboratory simulating experiments demonstrated that the hydrothermal fluids have a close bearing on hydrocarbon generation in the Dongpu Depression. Two aspects of the effect of hydrothermal fluids are noticed:hydrothermal hydrocarbon production and strong metal catalysis in oil and gas generation. 相似文献
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钻井现场有机地球化学录井与油气识别评价技术 总被引：1，自引：3，他引：1
在现场钻进过程中，尤其是在油基泥浆及各种添加剂烃类污染、地质录井难以确定真假油气显示的情况下，有机地球化学录井对确定油气显示有独特的作用。但由于其烃类污染对岩屑罐顶气、岩石冷溶烃、岩石热解等常规地球化学录井技术有不同程度的影响，其检测数据通过校正污染后才能用于含油气性评价。为此，在现场开展了钻井泥浆及各种添加剂中烃类有机地化检测试验，对泥浆中轻烃（C1－C12）、萃取烃（C1－C35）和岩石冷溶烃进行动态检测，研究其烃类组成及变化特征，对钻进中真假油气显示、油气层质量及产能大小、油气烃类母质类型、储油层确定等及时作出解释与评价，为油气勘探与开发快速提供地球化学依据。 相似文献
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吐哈盆地十红滩铀矿床有机地球化学特征浅析 总被引：2，自引：0，他引：2
吐哈盆地十红滩铀矿床属层间氧化带砂岩型铀矿床,赋存于中侏罗统西山窑组含煤碎屑岩中。容矿层岩石中富含有机质,有机碳、可溶有机物、酸解吸附烃在不同地球化学分带的岩石中含量大小不同,尤以矿石带含量最高。矿石有机质母质类型为腐殖型,处于未成熟演化阶段,酸解吸附烃为煤成气型。统计计算表明:容矿层中铀和可溶有机物、酸解吸附烃含量之间具明显的相关关系。分析了有机质在砂岩型铀矿床形成过程中的作用,认为容矿层中有机质在含氧环境下分解的产物利于铀在水中的溶解和迁移,而在缺氧条件下分解的产物,构成铀沉淀的还原和吸附地球化学障,在铀的成矿过程中发挥重要的作用。 相似文献
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Structural measurements and geochemical analyses, including bulk and in situ pyrite geochemistry, sulfur isotopes, and whole-rock geochemistry, are presented for the No. 3 orebody of the Jiaojia gold deposit (JJ3), located in the Jiaodong district of northeast China. The JJ3 orebody is distinct from the main orebody of the Jiaojia deposit (JJ1) because it is characterised by steeply dipping sub-metric quartz-pyrite veins with up to 300 ppm of gold, whereas the JJ1 orebody represents an archetypal example of the disseminated and veinlet style mineralisation characteristic of regional faults in the Jiaodong district. Measurements on JJ3 veins and the host Jiaojia-Xincheng regional fault are consistent with development of mineralised, steeply dipping extension fractures during normal faulting, which produced the fault-hosted disseminated-style JJ1 orebody. Trace element geochemistry of pyrite in these veins shows that JJ3 pyrite is geochemically distinct from those of the main Jiaojia and Xincheng orebodies, being relatively enriched in Ag and Pb, as well as Ba, Bi, Te and Au, and relatively depleted in Cu and As. Enrichment in Ag and Pb is possibly related to infiltration of a saline hydrothermal fluid, as both are effectively transported as chloride complexes; however, depletion of Cu, which is also mobile as chloride complexes, requires a low temperature saline fluid where Cu is no longer soluble. The textural setting of the ore minerals suggests that these cooler fluids likely infiltrated during the waning stages of the hydrothermal system. The relative abundance of barite in the JJ3 orebody, which formed from late-stage oxidised magmatic–hydrothermal fluids, also supports the interpretation that the JJ3 orebody represents a late mineralisation event. The pervasive alteration surrounding the JJ3 orebody is K-feldspathic with a minor sericitic overprint, indicating an earlier higher temperature pervasive fluid flow event that was followed by low-temperature mineralising fluids. This interpretation implies that fracture dilation post-dated the earliest alteration, and that mineralisation and pervasive alteration in the JJ3 orebody are geochemically disconnected. Thus structural analysis is expected to be the most effective targeting method in future exploration for similar ore bodies. 相似文献
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沉积盆地中与油气密切相关的金属矿床主要包括密西西比河谷型(MVT)铅锌矿床、砂页岩型铜-铀矿床、黑色页岩中的金属硫化物矿床、沉积岩容矿的金-锑-砷-汞-铊矿床等。金属矿床与(古)油气藏在空间上的密切共生/伴生关系,暗示了二者成因上的有机联系。在许多MVT铅锌矿床和砂页岩型铜矿床中,与成矿关系密切的原油及其衍生物形成于矿化前,它们为随后的金属成矿直接提供还原硫或充当硫酸盐还原反应的还原剂。在另一些情况下,某些低温热液金属矿床,特别是Au、As、Hg、Sb、Tl矿床与油气表现出同源、同运、同聚的耦合关系,金属成矿与油气成藏同时或近同时进行。与油气具不同耦合关系的金属矿床常表现出不同的特点。与成藏和/或成矿有关的盆地流体大致可分为以碳氢化合物为主的有机流体、以含金属盐水溶液为主的无机流体以及同时富含烃类和金属组分的有机成矿流体3类,盆地中的成矿、成藏作用及其耦合关系受控于这三类流体的演化过程。沉积盆地中金属矿床与油气藏空间上密切的共生/伴生关系以及成矿、成藏过程和机理的相似性,使金属与油气矿产资源的协同勘探和综合预测成为可能。 相似文献
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准噶尔盆地玛湖凹陷风城组页岩油勘探取得巨大突破,但是按照普遍认可的页岩油烃源岩评价标准,本区的烃源岩品质并不理想。为了科学评价玛湖凹陷烃源岩品质特征,本文在系统的岩心观察和有机地球化学分析的基础上,揭示烃源岩的形成环境,并按照矿物组成对烃源岩分类评价。玛湖凹陷风城组细粒岩主要沉积于正常半深湖、咸化半深湖、半咸化半深湖、含热液半深湖和滨浅湖环境中,各环境中细粒岩的有机质特征存在一定区别,其中半咸化半深湖有机质较为富集,w (TOC)均值在1%左右。进一步结合有机质类型判别图解,表明咸化半深湖和含热液半深湖有机质来源以湖泊生物为主,而其他环境中存在湖泊和陆源混合有机质来源。基于有机质生烃潜力评价和成熟度（Vre=0.74%）估算,表明目前风城组烃源岩中有机质正处于大量排烃的成熟阶段,且确定了细粒岩中的烃类为原生烃。由于不同矿物组成的烃源岩吸附能力的差异,按照陆相泥质烃源岩和碳酸盐质烃源岩开展分类评价,结果表明风城组沉积了累计厚度近250 m的的有效烃源岩,且富含以藻类体为主的有机质。 相似文献
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磷灰石在矿床学研究中的应用 总被引：1，自引：1，他引：0
磷灰石是一种常见的岩浆岩副矿物和热液矿物,不易受风化和氧化等表生作用影响,能较好记录和保存岩浆和热液活动的原始信息,因而是研究岩浆和/或热液过程的一种常见示踪矿物.在矿床学领域,磷灰石常被用来为探究多种科学问题.文章回顾了近年来磷灰石在矿床学研究中的主要应用方向,总结了磷灰石在实际研究中的争议问题,并较系统地阐释了磷灰石的地球化学特征对矿床成因、热液矿床成矿流体来源与演化、指导矿床勘探以及甄别矿床类型等方面的具体指示意义.通过文章的综述,希望能够为深化磷灰石矿物学和地球化学研究、加强磷灰石助力找矿工作、广泛开展与磷灰石有关的地质问题的探讨等提供较全面的基础性认识. 相似文献
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Halogen ratios (Br/Cl and I/Cl) and concentrations provide important information about how sedimentary formation waters acquire their salinity, but the possible influence of organic Br derived from sedimentary wall-rocks is rarely quantified. Here, it is demonstrated that Br/Cl versus I/Cl mixing diagrams can be used to deconvolve organic Br contributions; that organic matter has a limited range of Br/I ratios; and that organic Br is a more significant component in Zn–Pb deposit ore fluids than previously recognised. The significance of these findings is illustrated for the Lennard Shelf Zn–Pb deposits of Western Australia.Fluid inclusions related to Lennard Shelf Zn–Pb mineralisation have variable salinity and hydrocarbon contents. The halogen data from these fluid inclusions require mixing of three fluid end-members: (1) an evaporated seawater bittern brine (30 wt.% NaCl equiv.) with greater than seawater Br/Cl ratio; (2) a lower salinity pore fluid (?5 wt.% NaCl equiv.) with moderately elevated Br/Cl and I/Cl; and (3) fluids with Br/Cl ratios of ～5 times seawater and extremely elevated I/Cl ratios of ～11,500 times seawater. The first two fluids have 40Ar/36Ar of 300–400 and greater than air saturated water 36Ar concentrations that are typical of fluid inclusions related to Zn–Pb mineralisation. The third ‘organic-rich’ fluid has the highest 40Ar/36Ar ratio of up to 1500 and a depleted 36Ar concentration.Mineralisation is interpreted to have resulted from mixing of Zn-rich evaporitic brines and H2S present in hydrocarbons. It is suggested that aqueous fluids acquired organic Br and I from hydrocarbons, and that hydrocarbons exsolving from the aqueous fluid removed noble gases from solution. Interaction of variably saline brines and hydrocarbons could account for the variable Br/Cl and I/Cl composition, and 36Ar concentrations, recorded by Lennard Shelf fluid inclusions. The distinct 40Ar/36Ar signature of the fluid with the highest I/Cl ratio suggests the hydrocarbons and brines were sourced independently from different parts of the sedimentary basin. These data indicate the complementary nature of halogen and noble gas analysis and provide new constraints on important mixing processes during sediment-hosted Zn–Pb mineralisation. 相似文献
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关于成矿作用地球化学研究的几个问题 总被引：1，自引：0，他引：1
成矿作用地球化学是矿床地球化学的基础理论分支,属于应用基础类学科,以地球化学原理和方法研究造成元素沉淀富集形成矿床的地球化学作用的原因和机理。本文讨论了热液矿床成矿作用的几个问题。指出花岗岩与矿床类型之间是否存在相关性,即花岗岩是否具有成矿专属性仍然存在争论,需要继续探索。花岗岩类具有成矿潜力不等于这些花岗岩最终都能成矿。决定岩浆发生成矿作用的因素很多,其中岩浆分异作用过程和流体释放时间及其机制可能是决定成矿发生和矿床类型的关键,岩浆熔体中挥发组分及其行为可能是岩浆能否发生成矿作用的决定性要素,聚焦流体流动是成矿作用能否发生的关键环节,而自组织临界性和反馈作用决定了成矿效率和矿床的规模。 相似文献
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J. Jochum 《Mineralium Deposita》2000,35(5):451-464
A mechanical decrepitation device coupled with a gas chromatograph has been used to characterize the molecular composition
of gaseous and liquid hydrocarbons contained in minerals. Application of this technique allows the identification of low-molecular-weight
n-alkanes and some aromatic hydrocarbons in sulfides and gangue minerals from epigenetic Variscan and post-Variscan lead–zinc
deposits in the Rhenish Massif, Germany. Based on the analysis of 200 samples, Variscan and post-Variscan mineralization can
be distinguished by the composition of associated hydrocarbons. Variscan sulfides and gangue minerals contain high abundancies
of methane. In contrast, n-alkanes in the C2–C9 range and aromatic hydrocarbons (benzene, toluene) are dominant in post-Variscan mineralization. The absence of high-molecular-weight
hydrocarbons in ore minerals suggests highly mature gas associated with hydrothermal activity, during which hydrothermal fluids
caused an increase in thermal maturation of organic matter and the generation of low-molecular-weight hydrocarbons in the
adjacent organic-rich rocks. The hydrocarbon compositions contained in fluid inclusions of Variscan and post-Variscan minerals
are probably governed by the maturation level of the potential source rocks. In Variscan time tectonic brines (T > 175 °C) generated predominantly methane, whereas basement brines (T < 175 °C) expelled higher-molecular-weight hydrocarbons (wet gases, condensates, aromatic hydrocarbons) from adjacent rocks
during the Mesozoic event. The specific role of hydrocarbons in sulfide precipitation via thermochemical sulfate reduction
is indicated by geochemical characteristics of organic matter associated with the Plombières Pb–Zn deposit, in eastern Belgium.
Intense alteration phenomena were observed in near-ore kerogens, compared with unaltered kerogens far from the ore body, as
well as by a very high maturity (5.40% Ro), a systematic depletion in 12C towards the vein-type mineralization, high atomic S/C ratios (0.49), and by low atomic H/C ratios (0.29). The data suggest
that hydrothermal solutions caused a drastic increase in the thermal maturation of organic matter within the adjacent wall
rock. Increased thermal maturation resulted in increased δ13C-values of organic carbon due to the preferential release of 12C. The change in the organic matter to a H-depleted and S-enriched bulk composition in association with sulfide ores strongly
suggests that thermochemical sulfate reduction was responsible for organic degradation. Thus, thermochemical sulfate reduction
probably triggered base metal sulfide precipitation in Variscan and post-Variscan ore deposits of the Rhenish Massif. Finally,
based on data from this study and previous investigations, new genetic models are presented for both Variscan and post-Variscan
mineralization in the Rhenish Massif.
Received: 15 September 1999 / Accepted: 2 December 1999 相似文献
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水热成矿流体中的短链羧酸 总被引：1，自引：1，他引：1
文中简述了天然水流体中的短链羧酸产出状况。短链羧酸地球化学的研究目前集中于沉积盆地和表生环境。根据C H O体系中某些C H O化合物的化学关系和热力学分析 ,推测深部水热流体中有可能存在短链羧酸。研究高温热液矿床矿物流体包裹体的水溶有机组分可能是检验这一推测的突破口。某些石英脉型热液矿床的矿物流体包裹体压碎浸取和离子色谱分析确定 ,成矿流体中存在少量短链羧酸 ,而且甲酸是优势物种。文章讨论了矿物包裹体浸取实验结果需要进一步探讨的问题 ,认为研究水热成矿流体短链羧酸地球化学具有重要的理论意义。 相似文献