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1.
Rebecca E. Green Thomas S. Bianchi Michael J. Dagg Nan D. Walker Greg A. Breed 《Estuaries and Coasts》2006,29(4):579-597
We investigated seasonal variability in organic carbon (OC) budgets using a physical-biological model for the Mississippi
River turbidity plume. Plume volume was calculated from mixed layer depth and area in each of four salinity subregions based
on an extensive set of cruise data and satellite-derived suspended sediment distributions. These physical measurements were
coupled with an existing food web model to determine seasonally dependent budgets for labile (reactive on time scales of days
to weeks) OC in each salinity subregion. Autochthonous gross primary production (GPP) equaled 1.3×1012 g C yr−1 and dominated labile OC inputs (88% of the budget) because riverine OC was assumed mostly refractory (nonreactive). For perspective,
riverine OC inputs amounted to 3.9×1012 g C yr−1, such that physical inputs were 3 times greater than biological inputs to the plume. Annually, microbial respiration (R)
accounted for 65% of labile OC losses and net metabolism (GPP—R) for the entire plume was, autotrophic, equaling 5.1×1011 g C yr−1. Smaller losses of labile OC occurred via sedimentation (20%), advection (10%), and export to higher trophic levels (5%).
In our present model, annual losses of labile OC are 10% higher than inputs, indicating future improvements are required.
Application of our model to estimate air-sea carbon dioxide (CO2) fluxes indicated the plume was a net sink of 2.0×109 mol CO2 yr−1, of which 90% of the total drawdown was from biotic factors. In all seasons, low salinity waters were a source of CO2 (pCO2=560–890 μatm), and intermediate to high salinity waters were a sink of CO2 (pCO2=200–370 μatm). Our model was also used to calculate O2 demand for the development, of regional hypoxia, and our spring and early summer budgets indicated that sedimentation of
autochthonous OC from the immediate plume contributed 23% of the O2 demand necessary for establishment of hypoxia in the region. 相似文献
2.
Mangrove ecosystems play an important, but understudied, role in the cycling of carbon in tropical and subtropical coastal
ocean environments. In the present study, we examined the diel dynamics of seawater carbon dioxide (CO2) and dissolved oxygen (DO) for a mangrove-dominated marine ecosystem (Mangrove Bay) and an adjacent intracoastal waterway
(Ferry Reach) on the island of Bermuda. Spatial and temporal trends in seawater carbonate chemistry and associated variables
were assessed from direct measurements of dissolved inorganic carbon, total alkalinity, dissolved oxygen (DO), temperature,
and salinity. Diel pCO2 variability was interpolated across hourly wind speed measurements to determine variability in daily CO2 fluxes for the month of October 2007 in Bermuda. From these observations, we estimated rates of net sea to air CO2 exchange for these two coastal ecosystems at 59.8 ± 17.3 in Mangrove Bay and 5.5 ± 1.3 mmol m−2 d−1 in Ferry Reach. These results highlight the potential for large differences in carbonate system functioning and sea-air CO2 flux in adjacent coastal environments. In addition, observation of large diel variability in CO2 system parameters (e.g., mean pCO2: 390–2,841 μatm; mean pHT: 8.05–7.34) underscores the need for careful consideration of diel cycles in long-term sampling regimes and flux estimates. 相似文献
3.
Gaoyang Cui Xiaodong Li Qinkai Li Jun Huang Yuele Tao Siqi Li Jun Zhang 《中国地球化学学报》2017,36(4):581-597
To assess the effects of river damming on dissolved inorganic carbon in the Jialing River, a total of 40 water samples, including inflow, outflow, and stratified water in four cascade reservoirs (Tingzikou, Xinzheng, Dongxiguan, Caojie) were collected in January and July, 2016. The major cations, anions, and δ13CDIC values were analyzed. It was found that the dissolved compositions are dominated by carbonate weathering, while sulfuric acids may play a relatively important role during carbonate weathering and increasing DIC concentration. Different reservoirs had variable characteristics of water physiochemical stratification. The DIC concentrations of reservoir water were lower in summer than those in winter due to the dilute effects and intensive aquatic photosynthesis, as well as imported tributaries. The δ13CDIC values in Tingzikou Reservoir were higher during summer than those in winter, which indicated that intensive photosynthesis increased the δ13CDIC values in residual water, but a similar trend was not obvious in other reservoirs. Except for in Xinzheng Reservoir, the δ13CDIC values in inflow and outflow reservoir water were lower than those in the surface water of stratified sampling in summer. For stratified sampling, it could be found that, in summer, the Tingzikou Reservoir δ13CDIC values significantly decreased with water depth due to the anaerobic breakdown of organic matter. The significant correlation (p < 0.01 or 0.05) between the DIC concentrations, the δ13CDIC values and anthropogenic species (Na++K+, Cl–, \({\text{SO}}_{4}^{2 - }\)and \({\text{NO}}_{3}^{ - }\)) showed that the isotope composition of DIC can be a useful tracer of contaminants. In total, Tingzikou Reservoir showed lacustrine features, Xinzheng Reservoir and Dongxiguan Reservoir had “transitional” features, and Caojie Reservoir had a total of “fluvial” features. Generally, cascade reservoirs in the Jialing River exhibited natural river features rather than typical lake features due to characteristics of reservoir water in physiochemical stratification, spatiotemporal variations of DIC concentrations and isotopic compositions. It is evident that the dissolved inorganic carbon dynamics of natural rivers had been partly remolded by dam building. 相似文献
4.
Zongqiang Chang Qi Feng Jianhua Si Yonghong Su Haiyang Xi Jianlin Li 《Environmental Geology》2009,58(3):483-490
Field experiments on the CO2 flux of alpine meadow soil in the Qilian Mountain were conducted along the elevation gradient during the growing season of
2004 and 2005. The soil CO2 flux was measured using the Li-6400-09 soil respiration chamber attached to the Li-6400 portable photosynthesis system. The
effects of water and heat and roots on the soil CO2 flux were statistically analyzed. The results show that soil CO2 flux along the elevation gradient gradually decreases. The soil CO2 flux was low at night, with lowest value occurring between 0200 and 0600 hours, started to rise rapidly during 0700–0830
hours, and then descend during 1600–1830 hours. The peak CO2 efflux appears during 1100–1600 hours. The diurnal average of soil CO2 efflux was between 0.56 ± 0.32 and 2.53 ± 0.76 μmol m−2 s−1. Seasonally, soil CO2 fluxes are relatively high in summer and autumn and low in spring and winter. The soil CO2 efflux, from the highest to the lowest in the ranking order, occurred in July and August (4.736 μmol m−2 s−1), June and September, and May and October, respectively. The soil CO2 efflux during the growing season is positively correlated with soil temperature, root biomass and soil water content. 相似文献
5.
V. V. S. S. Sarma M. Dileep Kumar M. Gauns M. Madhupratap 《Journal of Earth System Science》2000,109(4):471-479
The variability in partial pressure of carbon dioxide (pCO2) and its control by biological and physical processes in the mixed layer (ML) of the central and eastern Arabian Sea during
inter-monsoon, northeast monsoon, and southwest monsoon seasons were studied. The ML varied from 80–120 m during NE monsoon,
60–80 m and 20–30 m during SW- and inter-monsoon seasons, respectively, and the variability resulted from different physical
processes. Significant seasonal variability was found in pCO2 levels. During SW monsoon, coastal waters contain two contrasting regimes; (a) pCO2 levels of 520–685 μatm were observed in the SW coast of India, the highest found so far from this region, driven by intense
upwelling and (b) low levels of pCO2 (266 μatm) were found associated with monsoonal fresh water influx. It varied in ranges of 416–527 μatm and 375–446 μatm
during inter- and NE monsoon, respectively, in coastal waters with higher values occurring in the north. The central Arabian
Sea pCO2 levels were 351–433, 379–475 and 385–432 μatm during NE-inter and SW monsoon seasons, respectively. The mixed layer pCO2 relations with temperature, oxygen, chlorophylla and primary production revealed that the former is largely regulated by physical processes during SW- and NE monsoon whereas
both physical and biological processes are important in inter-monsoon. Application of Louanchiet al (1996) model revealed that the mixing effect is the dominant during monsoons, however, the biological effect is equally significant
during SW monsoon whereas thermodynamics and fluxes influence during inter-monsoons. 相似文献
6.
The Archean Shawmere anorthosite lies within the granulite facies portion of the Kapuskasing Structural Zone (KSZ), Ontario,
and is crosscut by numerous linear alteration veins containing calcite + quartz ± dolomite ± zoisite ± clinozoisite ± margarite ±paragonite ± chlorite.
These veins roughly parallel the trend of the Ivanhoe Lake Cataclastic Zone. Equilibria involving clinozoisite + margarite + quartz ± calcite
± plagioclase show that the vein minerals were stable at T < 600 °C, XCO2 < 0.4 at P ≈ 6 kbar. The stabilities of margarite and paragonite in equilibrium with quartz are also consistent with T < 600 °C and XCO2 < 0.4 at 6 kbar. Additional assemblages consisting of calcite + clinochlore + quartz + talc + margarite indicate T < 500 °C with XCO2 > 0.9. Thus, vein formation, while clearly retrograde, spanned a range of temperatures, and fluid compositions evolved from
H2O-rich to CO2-rich. The calcite in the retrograde veins has δ18O values that range from 8.4 to 11.2‰ (average = +9.7 ± 0.9‰) and δ13C values that range from −3.9 to −1.6‰ (average = −3.1 ± 0.6‰). These values indicate that the fluids from which calcite precipitated
underwent extensive exchange with the anorthosite and other crustal lithologies. The fluids may have been initially derived
either from devolatilization of metamorphic rocks or crystallization of igneous rocks in the adjacent Abitibi subprovince.
Vein quartz contains CO2-rich fluid inclusions (final melting T = −57.0 to −58.7 °C) that range in size from 5 to 17 μm. Measured homogenization temperatures (T h) range from −44.0 to 14.5 °C, however for most inclusions (46 of S1), T h = −44.0 to −21.1 °C (ρCO2 ≈ 1.13 to 1.05 g/cm3). At 400 to 600 °C, these densities correspond to pressures of 3.5 to 7 kbar, which is the best estimate of pressures of
vein formation. It has been argued that some high density CO2-rich fluid inclusions found in the KSZ were formed during peak metamorphism and thus document the presence of a CO2-rich fluid during peak granulite facies metamorphism (Rudnick et al. 1984). The association of high density CO2-rich fluid inclusions with clearly retrograde veins documents the formation of similar composition and density inclusions
after the peak of metamorphism. Thus, the coincidence of entrapment pressures calculated from fluid inclusion density measurements
with peak metamorphic pressures alone should not be considered strong evidence for peak metamorphic inclusion entrapment.
All fluid inclusion results are consistent with an initially semi-isobaric retrograde P–T path.
Received: 2 April 1996 / Accepted: 15 November 1996 相似文献
7.
Diurnal Variations of Hydrochemistry in a Travertine-depositing Stream at Baishuitai, Yunnan, SW China 总被引:6,自引:0,他引:6
Zaihua Liu Qiang Li Hailong Sun Changjun Liao Huaju Li Jinliang Wang Kongyun Wu 《Aquatic Geochemistry》2006,12(2):103-121
Diurnal variations of hydrochemistry were monitored at a spring and two pools in a travertine-depositing stream at Baishuitai,
Yunnan, SW China. Water temperature, pH and specific conductivity were measured in intervals of 5 and 30 min for periods of
1 to 2 days. From these data the concentrations of Ca2+, HCO3−, calcite saturation index, and CO2 partial pressure were derived. The measurements in the spring of the stream did not show any diurnal variations in the chemical
composition of the water. Diurnal variations, however, were observed in the water of the two travertine pools downstream.
In one of them, a rise in temperature (thus more CO2 degassing) during day time and consumption of CO2 due to photosynthesis of submerged aquatic plants accelerated deposition of calcite, whereas in the other pool, where aquatic
plants flourished and grew out of the water (so photosynthesis was taking place in the atmosphere), the authors suggest that
temperature-dependent root respiration underwater took place, which dominated until noon. Consequently, due to the release
of CO2 by the root respiration into water, which dominated CO2 production by degassing induced by temperature increase, the increased dissolution of calcite was observed. This is the first
time anywhere at least in China that the effect of root respiration on diurnal hydrochemical variations has been observed.
The finding has implications for sampling strategy within travertine-depositing streams and other similar environments with
stagnant water bodies such as estuaries, lakes, reservoirs, pools and wetlands, where aquatic plants may flourish and grow
out of water. 相似文献
8.
Carbon dioxide (CO2) emission from the river-type reservoir is an hotspot of carbon cycle within inland waters. However, related studies on the different types of reservoirs are still inadequate. Therefore, we sampled the Three Gorges Reservoir (TGR), a typical river-type reservoir having both river and lake characteristics, using an online system (HydroCTM/CO2) and YSI-6600v2 meter to determine the partial pressure of carbon dioxide (pCO2) and physical chemical parameters in 2013. The results showed that the CO2 flux from the mainstream ranged from 26.1 to 92.2 mg CO2/m2 h with average CO2 fluxes of 50.0 mg/m2 h. The CO2 fluxes from the tributary ranged from ?10.91 to 53.95 mg CO2/m2 h with area-weighted average CO2 fluxes of 11.4 mg/m2 h. The main stream emits CO2 to the atmosphere the whole year; however, the surface water of the tributary can sometimes act as a sink of CO2 for the atmosphere. As the operation of the TGR, the tributary became more favorable to photosynthetic uptake of CO2 especially in summer. The total CO2 flux was estimated to be 0.34 and 0.03 Tg CO2/year from the mainstream and the tributaries, respectively. Our emission rates are lower than previous estimates, but they are in agreement with the average CO2 flux from temperate reservoirs estimated by Barros et al. (Nat Geosci 4(9):593–596, 2011). 相似文献
9.
We made direct measurements of the partial pressure of CO2 (PCO 2) in the tidal-freshwater portion of the Hudson River Estuary over a 3.5-yr period. At all times the Hudson was supersaturated in CO2 with respect to the atmosphere. PCO 2 in surface water averaged 1125±403 (SD) μatm while the atmosphere averaged 416±68 μatm. Weekly samples at a single, mid-river station showed a pronounced and reproducible seasonal cycle with highest values (~2000 μatm) in mid-to-late summer, and lowest values (~500 μatm) generally in late winter. Samples taken along the length of the 190-km section of river showed a general decline in CO2 from north to south. This decline was most pronounced in summer and very slight in spring. Diel and vertical variation were small relative to the standing stock of CO2. Over six diel cycles, all taken during the algal growing season, the mean range was 300±114 μatm. CO2 tended to increase slightly with depth, but the gradient was small, about 0.5 μmol m?1, or an increase of 190 μatm from top to within 1 m of the bottom. For a large subset of the samples (n=452) we also calculated CO2 from measurements of pH and total DIC. Calculated and measured values of CO2 were in reasonably good agreement and a regression of calculated versus measured values had a slope of 0.85±0.04 and an r2 of 0.60. Combining our measurements with recent experimental studies of gas exchange in the Hudson, we estimate that the Hudson releases CO2 at a rate of 70–162 g C m?2 yr?1 from the river to the atmosphere. 相似文献
10.
Modeling the effects of completion techniques and formation heterogeneity on CO2 sequestration in shallow and deep saline aquifers 总被引:1,自引:1,他引:0
This work studied the effect of completion techniques and reservoir heterogeneity on CO2 storage and injectivity in saline aquifers using a compositional reservoir simulator, CMG-GEM. Two reservoir models were
built based on the published data to represent a deep saline aquifer and a shallow aquifer. The effect of various completion
conditions on CO2 storage was then discussed, including partial perforation of the reservoir net pay (partial completion), well geometry, orientation,
location, and length. The heterogeneity effect was addressed by considering three parameters: mean permeability, the vertical
to horizontal permeability ratio, and permeability variation. Sensitivity analysis was carried out using iSIGHT software (design
of experiments) to determine the dominant factors affecting CO2 storage capacity and injectivity. Simulation results show that the most favorable option is the perforation of all layers
with horizontal wells 250–300 m long set in the upper layers. Mean permeability has the most effect on CO2 storage capacity and injectivity; k
v/k
h affects CO2 injectivity storage capacity more than permeability variation, V
k. More CO2 can be stored in the heterogeneous reservoirs with low mean permeability; however, high injectivity can be achieved in the
uniform reservoirs with high mean permeability. 相似文献
11.
ZHANG Jing JIANG Yanxing GAO Yang WU Yiying LUO Wenyun ZHOU Zhihua WANG Fushun 《中国地球化学学报》2013,32(4):430-435
Shallow fresh water bodies in peat areas could be an important contributor to greenhouse gases in the atmosphere.In this study,the partial pressure of CO2 in the surface water of the Dianshan Lake was investigated insitu in August 2011.The average pCO2 in the study area was 2300μatm and fluctuated within the range of 989–5000μatm.pCO2 showed a reverse trend to the variations of pH and DO in the surface water of the Dianshan Lake.The water to air diffusion flux of CO2 of the upstream,middle lake and downstream were respectively 63,33 and 14mmol/m2/d.On average,the diffusion flux of CO2 of the whole lake was 31 mmol/m2/d.Consequently,our results show that during the sampling season,the Dianshan Lake appears to be a great source of CO2.It is also demonstrated that respiration could be the dominant biochemical reaction in the Dianshan Lake in summer. 相似文献
12.
In investigating early karstification of one-dimensional conduits by computer models, so far one has assumed that the CO2 content of the calcite aggressive water stems entirely from the surface. Subterranean sources of CO2, however, can rejuvenate the solutional power of water already close to equilibrium with respect to calcite, and boost dissolution
rates. In a first scenario we have investigated the influence of a punctual source of CO2 as the most simple case of release of CO2 into a karstifiable fracture at some position KL from its entrance of the widening joint with length L, (K<1). The results
show that only a small increase of the p
CO2 in the solution to about 0.01 atm is sufficient to reduce the breakthrough times to about 0.3 with respect to the case, where
no CO2 is delivered. Other sources of CO2 are due to the metabolic activity of microorganisms. The existence of such diverse subterraneous microbial life in karst
systems is demonstrated. Whether situated on the fissure surfaces or free floating in the karst water, one basic product of
their metabolism is CO2. This contributes over the whole flow path to the p
CO2 of the karst water. Therefore in a second scenario we assumed a constant rate of CO2-input along parts of the fracture, as could be delivered by the activity of aerobic bacteria dwelling at its walls. Such
a scenario also applies to an extended diffuse CO2 migration from volcanic activity deep underground. In this case drastic reductions of the breakthrough time by about one
order of magnitude are observed. These reductions are enhanced when the fracture aperture width of the initial fracture decreases.
The physicochemical mechanisms of enhancement of karstification are discussed in detail by considering the evolution of the
fracture aperture width and of the dissolution rates in space and time.
Received: 17 December 1998 · Accepted 23 April 1999 相似文献
13.
Carbonate characteristics of the water mass of the deepwater part of the Arctic Ocean (AO) in the continental slope area were
determined, and the range and reasons of their variability during summer-fall season were revealed. The AO water area is a
meaningful sink for atmospheric carbon dioxide. The warm intermediate Atlantic waters (AW) are also undersaturated with carbon
dioxide relative to its content in the atmosphere. While these waters move along AO continental slope, the value pCO2 in the AW core decreases to 8–10 μatm (mainly, due to drop in the water temperature). The potential absorption capacity of
the AO deepwater basin is estimated at approximately 48 Tg of carbon (without sea ice taken into account). Joint analysis
of carbonate and hydrological parameters showed that near-bottom waters formed on the shallow shelf of the Laptev Sea, which
is rich in inorganic and organic carbon of terrestrial and marine genesis, take part in formation of halocline waters of the
AO. They are modified due to interaction with AW penetrating to the shelf and are transferred to the deepwater AO segment,
where they occur in the halocline according to their density. Transformed near-bottom waters of the Laptev Sea shelf, similar
to waters of the halocline of Pacific origin in the eastern sector of the AO, are traced above the continental slope in Amundsen
Basin on the basis of higher CO2 concentrations. 相似文献
14.
Seasonal phosphate (Pi) uptake kinetics were determined using chambers encompassing the water column, sediment and the entire
system (water column + sediment + seagrass/epiphyte) in Florida Bay (FB) during 2003–2006 and on the Little Bahama Bank (LBB)
during a cruise June, 2004. Pi uptake was a linear function of concentration at low Pi levels (< 2 μmo11-1). Applying the Pi system rate constant (Sp) from western (177 ±50 x 10-6 m s-1) and eastern (272 ±66 x 10-6 m s-1) bay sites, and using Pi measured during the study (0.02 to 0.177 μmol Pi 1-1), we calculated a Pi uptake rate of 0.30 to 2.62 mmol Pi m-2 d-1 for western and 0.47 to 4.16 mmol Pi m-2 d-1 for eastern bay sites which includes phytoplankton uptake (0.455 m height). During non-bloom conditions, phytoplankton dominated
Pi uptake in the east (46%) and both phytoplankton and the seagrass-epiphyte consortium in the west (32 and 52%, respectively),
with a smaller contribution by the sediment (15–20%). On LBB interior sites, the water column always dominated (≽94%) Pi uptake
with a higher Sp (573-881 x 10-6 m s-1) than FB. During cyanobacterial blooms in FB (chla 17 μg 1-1), the water column dominated Pi uptake (100%) and Sp was the highest (>2,800 x 10-6 m s-1) measured. Phytoplankton accounted for 88% of this sequestered Pi with only 12% in the acid extractable fraction, likely
as calcium bound and/or adsorbed P, and only 1% attributable to small heterotrophs. When chl α levels declined (2 μg I-1) Pi uptake was still dominated by phytoplankton (77%), the acid extractable pool increased (18%) and the heterotrophic community
became more important (22%). In carbonate-dominated seagrass systems, Pi is primarily taken up by the water column biota and
is subsequently remineralized/hydrolyzed in the water column or settles to the benthos where it becomes available to benthic
primary producers. 相似文献
15.
Fushun Wang Cong-Qiang Liu Baoli Wang Yuanxiu Yu Xiaolong Liu 《Environmental Earth Sciences》2014,72(5):1465-1477
The Wujiang River is an important tributary to the Changjiang River that has been intensively impounded for hydropower exploitation. To understand the potential impact of reservoir construction on the riverine inorganic carbon transport, seasonal longitudinal sampling was conducted in four reservoirs Hongjiadu (HJD), Dongfeng (DF), Suofengying (SFY) and Wujiangdu (WJD) along the Wujiang River from April 2006 to January 2007. Results indicated that damming the river induced an obvious discontinuity of water chemistry in the warmer seasons. δ 13C of dissolved inorganic carbon (DIC) ranged from ?3 to ?11.4 ‰, likely as the results of photosynthesis, respiration and carbonate weathering. During periods of thermal stratification, the addition of CO2 from respiration to hypolimnion and the deep water release for hydropower generation led to higher pCO2 downstream, as well as 13C depletion in DIC and undersaturated to calcite. An estimate of DIC budget indicated that only DF reservoir was the sink for DIC while reservoirs HJD, SFY and WJD were the sources for DIC. However, when the retained water was taken into account, for the reason of water storage occurring mainly in HJD and DF, all reservoirs became the sources for DIC with exporting rates of 26.68, 7.97, 6.22 and 11.80 % for HJD, DF, SFY and WJD, respectively. 相似文献
16.
Nina Keul John W. Morse Rik Wanninkhof Dwight K. Gledhill Thomas S. Bianchi 《Aquatic Geochemistry》2010,16(3):337-351
This paper presents the results of two cruises in the Northern Gulf of Mexico in 2008 that investigated local and short-term
factors influencing the carbonate chemistry dynamics and saturation state with respect to aragonite (Ωaragonite) of surface seawater in this region. One cruise covered much of the northern half of the Gulf, and the other focused on
the coastal zone west of the Atchafalaya Bay outlet of the Mississippi River—the region where the hypoxic “dead zone” occurs
on the Louisiana shelf. Offshore waters (>100 m depth) exhibited only small variations in CO2 fugacity (fCO2), total alkalinity (TA) and Ωaragonite. Values were close to those typically observed in subtropical Atlantic Ocean and Caribbean Sea waters of similar salinity.
However, inner shelf waters (<50 m depth) exhibited large variations in fCO2, TA, and Ωaragonite that were not directly related to salinity or distance from the Mississippi River plume. Changes in TA values were not the
result of simple mixing of end-member freshwater and seawater TA concentrations but exhibited a minimum in values near salinity
of 25. This minimum could be the result of microbial recycling across salinity gradients, biological removal of alkalinity
by formation of calcium carbonate or mixing of a third end-member with a low alkalinity such as Terrebonne Bay. All waters
were supersaturated with respect to aragonite. Offshore waters had an average Ωaragonite of 3.86 with a standard deviation of only ±0.06 and inner shelf waters had a range in Ωaragonite values from 3.9 to 9.7 with a median of 4.3. Shelf water Ωaragonite values were elevated relative to the offshore as a consequence of both high TA input from Mississippi River and biological
drawdown of CO2. A dominant factor controlling Ωaragonite distribution in offshore waters with relatively constant temperatures was fCO2, with higher supersaturation occurring in areas with low fCO2. 相似文献
17.
Maurizio De Rosa Gianluca Gagliardi Alessandra Rocco Renato Somma Paolo De Natale Giuseppe De Natale 《Geochemical transactions》2007,8(1):5
We report on a continuous-measurement campaign carried out in Vulcano (Aeolian islands, Sicily), devoted to the simultaneous
monitoring of CO2 and H2O concentrations. The measurements were performed with an absorption spectrometer based on a semiconductor laser source emitting
around a 2-μm wavelength. The emitted radiation was selectively absorbed by two molecular ro-vibrational transitions specific of the investigated
species. Data for CO2 and H2O concentrations, and CO2 soil diffusive flux using an accumulation chamber configuration, were collected at several interesting sampling points on
the island (Porto Levante beach- PLB, Fossa Grande Crater – FOG- and Valley of Palizzi, PAL). CO2/H2O values, measured on the ground, are very similar (around 0.019 (± 0.006)) and comparable to the previous discrete detected
values of 0.213 (Fumarole F5-La Fossa crater rim) and 0.012 (Fumarole VFS – Baia Levante beach) obtaid during the 1977–1993
heating phase of the crater fumaroles. 相似文献
18.
M. Liu J. C. Peterson Richard A. Yund 《Contributions to Mineralogy and Petrology》1997,126(3):217-223
The growth rates of albite and pyroxene (enstatite + diopside + spinel) reaction rims were measured at 1000°C and ˜700 MPa
and found to be parabolic indicating diffusion-controlled growth. The parabolic rate constants for the pyroxene (+ spinel)
rims in samples with 0.5 wt% H2O added or initially vacuum dried at 25°C and 250°C are 1.68 ± 0.09, 0.54 ± 0.05 and 0.25 ± 0.06 μm2/h, respectively. The values for albite rim growth in samples initially dried at 60°C and with 0.1 wt% H2O added are 0.25 ± 0.04 and 0.33 ± 0.03 μm2/h, respectively. The latter values were used to derive the product of the grain boundary diffusion coefficient D′A, where A = SiO2, NaAlO2, or NaAlSi−1, and the grain boundary thickness δ in albite. The calculated D′SIO2δ in the albite aggregate for the situations of two different water contents are about 9.9 × 10−23 and 1.4 × 10−22 m3 s−1, respectively. Both the rate constants and the calculated D′Aδ demonstrate that the effect of water content on the grain boundary diffusion rate in monomineralic albite and polymineralic
pyroxene (+ spinel) aggregates is small, consistent with recent studies of monomineralic enstatite and forsterite rims.
Received: 1 July 1995 / Accepted: 1 August 1996 相似文献
19.
Water from the Kombat mine was delivered to the Omatako dam via the 263-km-long Grootfontein-Omatako canal during test runs
in 1997. It is intended to supply water from Kombat and other underground mines in the Otavi Mountain Land to the capital
Windhoek. The Cu-Pb-Zn orebodies are hosted by carbonate rocks and the mine waters are supersaturated with respect to calcite
and CO2. Along the length of the canal, the CO2 partial pressure drops from 10−2.1 atm at the inlet of the Kombat mine to 10−3.5 atm at the end of the canal. This is accompanied by a drop in Ca concentration from about 60 to about 20 mg/l. The heavy
metal concentrations (Cd, Cu, Mn, Pb and Zn) drop along the course of the canal to values far below the national drinking-water
standard. Scavenging by calcium carbonate precipitation is the major depletion mechanism.
Received: 21 June 1999 · Accepted: 29 August 1999 相似文献
20.
At the Bufa del Diente contact-metamorphic aureole, brine infiltration through metachert layers embedded in limestones produced
thick wollastonite rims, according to Cc+Qz=Wo+CO2. Fluid inclusions trapped in recrystallized quartz hosts include: (1) high salinity four phase inclusions [Th(V-L)=460–573° C; Td(salts)=350–400° C; (Na+K)Cleq=64–73 wt%; X
CO
2≤0.02]; (2) low density vapour-rich CO2-bearing inclusions [Th(L-V)≈500±100° C; X
CO
2=0.22–0.44; X
NaCl≤0.01], corresponding to densities of 0.27± 0.05 gcm−3. Petrographical observations, phase compositions and densities show that the two fluids were simultaneously trapped in the
solvus of the H2O-CO2-salts system at 500–600° C and 700±200 bars. The low density fluid was generated during brine infiltration at the solvus
via the wollastonite producing reaction. Identical fluid types were also trapped as inclusion populations in wollastonite
hosts 3 cm adjacent to quartz crystals. At room temperature, both fluid types additionally contain one quartz and one calcite
crystal, generated by the back-reaction Wo+CO2=Cc+Qz of the host with the CO2-proportion of the fluid during retrogression. All of the CO2 was removed from the fluid. On heating in the microstage, the reaction progress of the prograde reaction was estimated via
volume loss of the calcites. In vapour-rich fluids, 50% progress is reached at 490–530° C; 80% at 520–560° C; and 100% at
540–590° C, the latter representing the trapping temperatures of the original fluid at the two fluid solvus. The progress
is volume controlled. With knowledge of compositions and densities from unmodified inclusions in quartz and using the equation
of state of Duan et al. (1995) for H2O-CO2-NaCl, along with f
CO
2-values extracted from it, the reaction progress curve was recalculated in the P-T-X-space. The calculated progress curve passes through the two fluid solvus up to 380° C/210 bars, continues in the one fluid
field and meets the solvus again at trapping conditions. The P-T slope is steep, most of the reaction occurs above 450° C and there is high correspondence between calculated and measured
reaction progress. We emphasize that with the exception of quartz, back-reactions between inclusion fluids and mineral hosts
is a common process. For almost any prograde metamorphic mineral that was formed by a devolatilization reaction and that trapped
the equilibrium fluid or any peak metamorphic fluid as an inclusion, a fluid-host back-reaction exists which must occur somewhere
along the retrograde path. Such retrograde reactions may cause drastic changes in density and composition of the fluid. In
most cases, however, evidence of the evolving mineral assemblages is not given for they might form submicroscopical layers
at the inclusion walls.
Received: 15 March 1995 / Accepted: 1 June 1995 相似文献