共查询到19条相似文献，搜索用时 171 毫秒
1.
新疆达拉布特蛇绿混杂岩中辉长岩岩石学、微量元素地球化学和锆石U-Pb年代学研究 总被引：6，自引：4，他引：2
新疆西准噶尔地区达拉布特蛇绿混杂岩带中的辉长岩、辉长玢岩、角闪辉长岩呈不规则块体分布于蛇纹石化的地幔岩(尖晶石蛇纹岩)中。锆石SHRIMP定年显示角闪辉长岩形成于426±6Ma (MSWD=0.87),表明达拉布特所代表的古洋盆在中志留世就已存在。岩相学和微量元素地球化学研究表明,辉长岩、辉长玢岩、角闪辉长岩均来源于富Cr的地幔源区,确认3类岩石为同源岩浆演化的产物。选取达拉布特尖晶石二辉橄榄岩为源区所做的模拟显示:尖晶石二辉橄榄岩发生15%的部分熔融后的残余体形成了方辉橄榄岩,熔体通过分离结晶形成辉长岩,剩余熔体结晶形成辉长玢岩和角闪辉长岩。 相似文献
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西南天山哈拉达拉岩体的锆石SHRIMP年代学及地球化学研究 总被引：15，自引：6，他引：9
西南天山哈拉达拉侵入体由橄长岩、橄榄辉长岩和辉长岩组成,橄长岩和橄榄辉长岩具有典型的堆晶结构,堆晶矿物以斜长石和橄榄石为主。辉石、角闪石和金云母主要为堆晶间隙矿物。辉长岩发育辉长—辉绿结构。结晶分异作用在岩浆演化过程中起重要作用。对从辉长岩中分选出来的锆石进行的SHRIMP年代学研究表明,辉长岩形成于308.3±1.8Ma （MSWD=0.86,n=15）。哈拉达拉岩体稀土元素配分模式与E-MORB相似,具有高Rb、Cs、Ba及Sr的特点,87Sr/86Sr初始比值0.7040~0.7050。这些特征表明,岩浆源区具有富集地幔的特征(古南天山洋俯冲流体交代形成了富集地幔)。根据平坦的稀土元素配分模式以及Gd、Sm、Nb、Zr等微量元素的地球化学行为判别,岩浆源区岩石为含角闪石的尖晶石二辉橄榄岩。批式熔融模拟计算显示,地幔岩10%~15%的部分熔融能够形成哈拉达拉岩体的母岩浆。母岩浆通过48%~50%的结晶分异作用则能够形成哈拉达拉岩体。早期结晶的橄榄石和斜长石通过堆晶作用形成橄长岩和橄榄辉长岩,剩余岩浆结晶形成辉长岩。 相似文献
3.
西藏班公湖—怒江缝合带中段蓬湖蛇绿岩中的洋脊型二辉橄榄岩 总被引：1，自引：0，他引：1
蓬湖蛇绿岩产于西藏藏北湖区的蓬湖西侧,属班公湖-怒江缝合带中段白拉拉弄-依拉山亚带。该蛇绿岩主要由地幔橄榄岩、堆晶岩和辉绿岩等组成。其中地幔橄榄岩由方辉橄榄岩和二辉橄榄岩组成。蓬湖二辉橄榄岩的橄榄石Fo值介于88.85～90.33之间、斜方辉石的Al2O3含量范围在4.26%～6.60%。与原始地幔相比,蓬湖二辉橄榄岩岩石有较高的MgO含量和较低的Al2O3、CaO和TiO2等易熔组分含量;稀土元素总量介于1.11×10-6～1.53×10-6之间,明显低于原始地幔值,配分模式为轻稀土轻微亏损。在原始地幔微量元素蛛网图中,蓬湖二辉橄榄岩显示Rb、Zr亏损,U、Ta、Sr强烈富集特征。蓬湖二辉橄榄岩的铂族元素总量介于22.9×10-9～27×10-9之间,PGEs球粒陨石标准化图解显示其为接近原始地幔的"平坦型"。以上特征与深海橄榄岩相似,指示它们可能形成于大洋中脊环境。定量模拟估算表明,蓬湖二辉橄榄岩可能来源于地幔中尖晶石相二辉橄榄岩源区,系经历了约5%～10%的部分熔融残余。蓬湖堆晶岩矿物结晶顺序为橄榄石-单斜辉石-斜长石,其中异剥橄榄岩中的单斜辉石Mg#值介于86.92～89.93之间、橄榄石Fo平均值为84.45,明显不同于MOR型蛇绿岩堆晶岩。蓬湖堆晶岩的矿物组成、岩浆结晶顺序和矿物成分均与俯冲带上SSZ型蛇绿岩形成的堆晶岩类似。以上结果表明,蓬湖二辉橄榄岩形成于大洋脊环境,为尖晶石二辉橄榄岩源区经历了不超过10%部分熔融的残余,后期由于洋内俯冲作用经历了岩石-熔体反应,形成了SSZ型堆晶岩和含较高Cr#值尖晶石的方辉橄榄岩。 相似文献
4.
西昆仑库地蛇绿混杂岩由方辉橄榄岩和纯橄榄岩等地幔变质橄榄岩、豆荚状铬铁矿、堆晶橄榄岩、堆晶辉石岩和辉长岩、辉绿岩墙、块状和枕状玄武岩等组成。强亏损方辉橄榄岩为主的地幔岩组合,二辉石的低Al含量和铬尖晶石的高Cr#,以及岩石的富Mg、Ni和贫Al、Ca特征一致表明地幔橄榄岩类是经较高程度部分熔融后的地幔残余,与消减带之上蛇绿岩中的同类岩石相近。岩石富Rb、Ba、U、Th、LREE,说明地幔残余岩石受到了来自消减带的洋壳重熔组分的混染。堆晶岩以辉石岩和辉长岩为主,可能属PPG系列,指示岩浆是在消减带环境和含水条件下熔融的。辉长岩为低Ti蛇绿岩型,代表洋内弧后盆地早期环境或弧前环境。辉绿岩和玄武岩为洋中脊拉斑玄武岩和岛弧拉斑玄武岩的过渡类型;玄武岩和辉绿岩相比富Ba、Th、LREE,贫Ta,指示玄武岩较辉绿岩更多地受到来自消减带洋壳重熔组分的影响。库地蛇绿岩形成时的古构造环境是消减带之上的弧间或弧后盆地。 相似文献
5.
西藏蓬湖西蛇绿岩地球化学及构造背景研究 总被引：3，自引：0，他引：3
西藏蓬湖西蛇绿岩隶属于班公湖—怒江缝合带的中段,是藏北湖区较好的堆晶岩剖面之一。形成该堆晶岩时矿物分离结晶顺序为铬铁矿→橄榄石→单斜辉石→斜长石,分离结晶作用具有由富镁质、铁质向富铝质、钙质演化趋势。堆晶岩主量元素组成与世界典型蛇绿堆晶岩成分相似;各种堆晶岩石的微量元素和稀土元素配分曲线总体上基本一致,反映其同源性;岩石Nb和Ta亏损,稀土元素含量很低,分配模式呈LREE微弱亏损的平坦型。该蛇绿岩形成于弧后盆地扩张中心,属SSZ型蛇绿岩。 相似文献
6.
7.
新疆且末县几克里阔勒镁铁—超镁铁岩体位于塔里木板块南缘活动带之喀拉米兰晚古生代沟弧系中段北侧,侵入下石炭统满达拉恰普组第三段海相碎屑岩、碳酸盐岩及中酸性火山岩建造中。主要岩石类型有纯橄岩、二辉橄榄岩、单辉橄榄岩、含长橄榄二辉岩、二辉岩、橄榄辉长岩、淡色辉长岩。岩石地球化学及岩相学特征表明:岩浆作用早期,分离结晶作用主导了岩浆演化过程和岩体形成过程,橄榄石和斜方辉石呈分离/堆晶相;矿物结晶顺序是:尖晶石/橄榄石→斜方辉石→单斜辉石→单斜辉石+斜长石→褐色普通角闪石/黑云母。原生岩浆可能来自原始地幔或中等程度熔融的高镁玄武质岩浆,属拉斑玄武岩系列,形成过程中受到了一定程度同化混染作用的影响,但硫化物熔离程度较弱。岩浆源区位于尖晶石稳定域。 相似文献
8.
滇西吉义独蛇绿混杂岩位于金沙江缝合带的南端,岩石组合出露较齐全,包括堆晶橄榄岩、堆晶辉石岩、堆晶辉长岩以及玄武岩等,它们呈构造岩片的形式产出并与外来岩块组成蛇绿混杂岩.堆晶橄榄岩和辉石岩具低Al_2O_3,低TiO_2,而高Mg~#值(Mg~#=0.88～0.92),富集Cr和Ni,稀土总量偏低(∑REE=14.82×10~(-6)～27.75×10~(-6)),倒"U"型的稀土元素分布特征.堆晶辉长岩和玄武岩的Mg~#值较低,分别为0.70～0.79和0.51～0.66,具拉斑系列的演化趋势.玄武岩可以细分为2组:第一组玄武岩以平坦型稀土配分模式,低Mg~#(Mg~#=0.44～0.46),低稀土总量(∑REE=52.29×10~(-6)～60.26×10~(-6))为特征;第二组玄武岩则为LREE弱富集型的稀土配分模式,其Mg~#较高(Mg~#=0.54～0.68),稀土总量也较高(∑REE=62.13×10~(-6)～101.87×10~(-6)).在原始地幔标准化的微量元素配分图解中,两组玄武岩均相对富集大离子亲石元素而亏损Nb、Ta和Ti,与岛弧岩浆岩类似,明显不同于N-MORB.岩石的Sr-Nd同位素组成较为均一和稳定,堆晶橄榄岩和辉石岩的(~(87)Sr/~(86)Sr)_i=0.7051～0.7056,5_(Nd)(t)=2.8～4.1,玄武岩的(~(87)Sr/~(86)Sr)_i=0.7050～0.7056,ε_(Nd)(t)=5.1～5.8,且显示出原始地幔的同位素组成特征,暗示这些岩石为同源岩浆分异演化而成的岩浆产物.岩浆演化的主要方式为分离结晶作用,受地壳混染不明显.岩浆结晶形成岩石的顺序为:堆晶橄榄岩→堆晶辉石岩→堆晶辉长岩→玄武岩2组→玄武岩1组.岩石地球化学特征表明,吉义独蛇绿岩的形成与俯冲作用有关,且形成于金沙江洋内俯冲的消减环境. 相似文献
9.
新疆克拉玛依地区出露的早古生代蛇绿混杂岩带规模巨大,岩石单元出露齐全。白碱滩地区的地幔橄榄岩相对比较新鲜,单斜辉石、斜方辉石、尖晶石和橄榄石保存完好。研究表明,白碱滩蛇绿岩就位前,地幔岩发生了大于50km的快速隆升,且没有发生部分熔融。百口泉地区发现的地幔岩普遍遭受了改造,辉石多发生了强烈蚀变(透闪石化),但尖晶石和橄榄石保存较好。百口泉地区出露的地幔岩和白碱滩地幔岩的矿物组成基本一致,表明它们属于同一蛇绿混杂岩带。百口泉蛇绿岩剖面的揭露,将该蛇绿混杂岩带的范围向NE方向延伸了35km。 相似文献
10.
乌兰敖包基性-超基性岩位于阿拉善北缘兴蒙造山带,由方辉橄榄岩、辉绿岩、辉长岩组成。地球化学分析表明:蛇纹石化橄榄岩为地幔橄榄岩,辉绿岩和辉长岩为拉斑玄武岩系列岩石,均具有与N-MORB相似的微量元素特征,但区别于N-MORB,3种岩石共同组成了蛇绿混杂岩。矿物学分析表明蛇纹石化橄榄岩中橄榄石为地幔橄榄岩中镁橄榄石(Fo=91.10~91.81),铬铁矿为铬尖晶石,具有高的Cr~#和Mg~#值分别为61.04~64.44、50.40~56.37)。单斜辉石出现在方辉橄榄岩、辉长岩及辉绿岩中,而斜方辉石只出现在方辉橄榄岩中,其中方辉橄榄岩中单斜辉石为顽透辉石,辉长岩中为普通辉石,而辉长岩中为次透辉石、贫钙普通辉石、普通辉石,斜方辉石均为斜顽辉石。辉长岩U-Pb年龄为344.5±1.5 Ma,表明该蛇绿混杂岩形成于早石炭世。地球化学及矿物学特征表明乌兰敖包蛇绿岩形成于俯冲早期的弧前环境中,属于SSZ型蛇绿岩。蛇绿混杂岩成因提供铬铁矿形成的有利条件,因此应围绕铬铁矿进行找矿工作。 相似文献
11.
The Vandfaldsdalen macrodike, which lies in the Skaergaard region of East Greenland, is a remarkably zoned fossil magma chamber, with a granophyric cap overlying cumulate gabboros. The intrusion is distinctly bimodal, with a large compositional discontinuity at the contact between the gabbro and granophyre. Although the exposed part of the macrodike is in contact with Tertiary basalts and sediments, the granophyre originated by assimilation of xenoliths derived from the underlying Archean basement. Sr and Nd isotopic ratios throughout the cumulate sequence are remarkably similar, indicating insignificant contamination of the gabbro by the granophyre. Modelling of the compositional effects of cooling and crystallization indicate that the cumulate pile resulted from fractional crystallization, with the complicating effects of trapped liquid and post-cumulus fractionation. The uppermost rocks in the mafic part, of the chamber (SiO2=62%; FeO*=12.4%) resulted from about 85% fractional crystallization. A transgressive sill of strongly fractionated magma (SiO2=67%; FeO*=8.8%) formed from extracted intercumulus liquid that was the result of 90% fractional crystallization of the original magma. Mass-balance indicates that typical granophyre is made up of about 75% dissolved xenoliths, by weight, and 25% mantle-derived basaltic magma. The magmas were not measurably affected by material exchange across the interface between the gabbro and granophyre. This magma chamber evolved by both assimilation and fractional crystallization, but the residual liquids formed by fractional crystallization were unaffected by assimilation. Heat exchange between were unaffected by assimilation. Heat exchange between the two parts of the chamber was obviously important, but there was insignificant material exchange. The inability of fractional crystallization and assimilation to affect the same liquid is related to the dynamic behavior of this particular magma chamber, particularly the buoyancy of granophyre relative to evolving tholeiitic magma. 相似文献
12.
香桃湖变质堆晶辉长岩是由原"猫耳山岩组"解体出来的早古生代基性岩,其对于研究区域上龙木错—双湖—澜沧江缝合带的构造演化具有重要意义。岩相学研究表明,该堆晶辉长岩经历了高级角闪岩相变质,并遭受了绿片岩相退变质作用的改造;地球化学研究显示,其Si O2含量为44.7%~46.2%,Mg O为7.05%~8.48%,Mg#值为51.02~53.90,相容元素Cr含量为168×10-6~288×10-6、Ni为60×10-6~103×10-6,远低于原生玄武质岩浆,反映香桃湖变质堆晶辉长岩经历了一定程度镁铁质矿物的分离结晶作用;部分样品微量和稀土元素显示出OIB的特征,另一部分显示E-MORB的特征。因此,该变质堆晶辉长岩的原岩应形成于受洋中脊中轴型地幔热柱叠加的洋中脊,其可能为红脊山地区早古生代的大洋残片。 相似文献
13.
《Journal of African Earth Sciences》1999,28(3):721-741
Gabbroic intrusions of the El-Aradiya area are a part of the Neoproterozoic basement cropping out in the central Eastern Desert of Egypt. They are composed mainly of gabbroic cumulates (diopside-plagioclase cumulate and plagioclase-augite cumulate) and fine-grained noncumulate gabbro. Mineral chemistry data indicate that the plagioclase core compositions of the gabbroic cumulates range between An90 and An60, whereas fine-grained noncumulate gabbro plagioclase core compositions are An61−56 and rim compositions are An54−42. The clinopyroxenes are diopside and augite in the gabbroic cumulate, and augite in the fine-grained noncumulate gabbro. Chemical re-equilibration between pyroxenes of gabbroic cumulates vary from 1150-900°C and for fine-grained noncumulate gabbro range from 1200-1100°C. The amphiboles are calcic, varying from tschermakite and tschermakitic hornblende, and Mg-hornblende in the gabbroic cumulate and only Mg-hornblende in the fine-grained noncumulate gabbro. They indicate an island-arc tholeiitic setting for gabbroic intrusions of the El-Aradiya area. Major and trace element data suggest arc tholeiite characters, a comagmatic suite and subduction-related magma with enrichment of LILE and depletion in HFSE relative to MORB. The estimated parent magma is similar to tholeiitic Aleutian arc primary magma. The gabbroic intrusions are analogous to intrusions emplaced in an immature island-arc setting in which the oceanic crust was thin. 相似文献
14.
K. R. Hari N. V. Chalapathi Rao Vikas Swarnkar 《Journal of the Geological Society of India》2011,78(6):501-509
We report the occurrence of orthopyroxene gabbro from the Phenai Mata Igneous Complex (containing thoeliitic and alkaline
rocks) that occur within Deccan Traps. The P-T calculations based on two pyroxene thermometry vary from 8.5±1.0 kbar and 963±39
°C. These gabbroic rocks exhibit high Mg# (0.67 to 0.71). But their primary magma signature can be negated due to their high
SiO2 (> 50 wt %), low Ni (32–35 ppm) and Cr (105–182 ppm) contents. Further, simple fractional crystallization was not responsible
for the modification of the magma. Modeling carried out using trace element concentrations revealed that concurrent assimilation
and fractional crystallization (AFC) was responsible for the genesis of these rocks. Small pods of magma could have accumulated
in the crustal portions and concurrent assimilation and fractional crystallization have taken place in the generation of gabbro
and orthopyroxene gabbro in the present study area. 相似文献
15.
黑龙江五星铜镍、铂钯矿床镁铁质杂岩的元素地球化学特征与岩石成因 总被引：3，自引：2，他引：1
五星超镁铁质- 镁铁质杂岩的元素地球化学特征研究表明, 其原始岩浆为低钛、高镁的拉斑玄武岩浆, 由以CO2 为主的流体交代亏损地幔所形成的弱亏损地幔部分熔融产生, 其残余矿物相主要为石榴石、尖晶石和金红石。岩浆形成与演化经历了3 个阶段: ① 上升的软流圈与岩石圈地幔接触, 热流体作用导致岩石圈地幔发生高度部分熔融, 形成初始硫饱和的次碱性玄武岩; ②初始岩浆上侵, 在下地壳形成岩浆房, 岩浆结晶作用形成以似层状橄榄石、紫苏辉石、普通辉石和磁铁矿等为主的堆晶岩, 在地壳物质的参与下形成残余辉长质岩浆; ③ 岩浆房破裂, 残余岩浆和含有熔体( < 30% ) 的堆晶岩相先后上侵形成五星原始镁铁质杂岩。就铜镍和铂钯矿化而言, 铜镍硫化物形成于岩浆房分离结晶晚期的熔离作用, 而铂钯矿化则主要在成岩期后流体作用阶段形成。 相似文献
16.
Petrology, geochemistry and paleogeographic reconstruction of the East Sulawesi Ophiolite, Indonesia
Ade Kadarusman Sumio Miyashita Shigenori Maruyama Christopher D. Parkinson Akira Ishikawa 《Tectonophysics》2004,392(1-4):55
The East Sulawesi Ophiolite (ESO) is tectonically dismembered and widely distributed in Central and East Sulawesi. It comprises, from base to top, residual mantle peridotite and mafic–ultramafic cumulate through layered to isotropic gabbro, to sheeted dolerites and basaltic volcanic rocks. Residual peridotite is dominantly spinel lherzolite intercalated with harzburgite and dunite. Ultramafic rocks from different locations display significant differences in rock composition and mineral. However, the clinopyroxene of peridotite displays REE pattern similarities with those of mid-ocean ridge (MOR) origin, rather than those of suprasubduction zone (SSZ) origin. The gabbroic unit consists of massive gabbro, layered gabbro, mafic and ultramafic cumulate and anorthosite. The observed crystallization sequence of gabbroic unit, which is olivine→(spinel)→plagioclase→clinopyroxene→(orthopyroxene)→(hornblende), and the mineral chemistry data indicate that the ESO gabbro has similarities with MOR setting.Major and trace element geochemistry of basalt and dolerite suggests MOR, oceanic plateau and minor SSZ origins. A possible oceanic plateau origin is supported by the following: (i) the 15-km thickness is comparable with the thickness of oceanic plateau rather than normal oceanic lithosphere; (ii) there are no or only minor olivine phenocrysts in the basalt; and (iii) predominance of aphyric texture in the basalts. The REE pattern of ESO basalt exhibits N-MORB-like signatures. However, a negative Nb anomaly in the trace element spider diagram may be attributed to mantle heterogeneity of an OPB source.The geochemical variations and disparities for both peridotite and basalt and the noncogenetic relationship between crust and mantle sections in several locations suggest that the ESO may have been formed at one tectonic setting and was later overprinted by magmatism in different environments through its birth to emplacement. A possible Cretaceous origin of an oceanic plateau component of the ESO is indicated on the basis of calculated paleopositions using plate trajectory analyses together with previously published paleolatitude data. The ESO can be traced back to the proximity of the presently active region of the SW Pacific Superplume. 相似文献
17.
Types of Enclaves and Their Features and Origins in Intermediate-Acid Intrusive Rocks from the Tongling District, Anhui Province, China 总被引：9，自引：0，他引：9
WU Cailai WANG Zhihong QIAO Dewu LI Haibing HAO Meiying SHI Rendeng Institute of Geology Chinese Academy of Geological SciencesXi''an Engineering College Geological Mechanics Institute CAAGS 《《地质学报》英文版》2000,74(1):54-67
Enclaves in intermediate-acid plutons from Tongling can be divided into three types: xenoliths, relics and magmatogenic enclaves. The magmatogenic enclaves consist of cumulates, micrograined dioritite mixtite and dioritic chilled border enclaves. Petrologically, relics with eyed and meta-poikilitic texture are characterized by high content of biotite (>80%) and low content of cordierite and grossular. The cumulates with accumulate texture consist of a great amount of pyroxene, hornblende and minor spinel and phlogopite. The micrograined dioritic mixtite is composed of more hornblendes and feldspar and less needle apatites and an ellipsoid basic core included in plagio-clase. The chilled border enclaves have the same mineral association, but more dark minerals than the host rocks consisting of plagioclase, quartz, alkaline feldspar, hornblende and biotite. Geochemically, the relics exhibit high REE content (455.8×10-6) and high ratio of LREE/HREE, more obvious Eu negative anomaly and are rich in Cr and 相似文献
18.
新疆东天山黄山东岩体岩石地球化学特征与岩石成因 总被引：12，自引：7，他引：5
黄山东岩体位于东天山北部的土墩-黄山-图拉尔根镁铁-超镁铁质岩带中段,受康古尔塔格-黄山深大断裂控制,是由辉长闪长岩、角闪辉长岩、橄榄辉长岩、辉长苏长岩及二辉橄榄岩组成的复式岩体。主量元素化学组成部分属拉斑玄武岩系列,也有部分属钙碱性系列。大部分岩石相对富集LREE、适度亏损高场强元素(Nb、Ta、Ti)。元素地球化学和Nd、Sr、Pb同位素体系证明,岩浆遭受了5%～8%的中-上地壳物质的同化混染作用。岩浆源区由被消减板片交代的地幔楔物质和软流圈地幔物质组成。岩石圈根部拆沉和软流圈地幔上涌过程中生成了黄山东岩体。富铁硅酸盐的分离结晶作用对硫化物富集并分凝起到了关键性作用,成矿过程应该是岩浆自身演化过程的有机组成部分。 相似文献
19.
James Gerald Brophy 《Contributions to Mineralogy and Petrology》2009,158(1):99-111
Analytical expressions for the variation in D
La and D
Yb with increasing liquid SiO2 for olivine, plagioclase, augite, hornblende, orthopyroxene, magnetite and ilmenite (Brophy in Contrib Mineral Petrol 2008, online first) have been combined with numerical models of hydrous partial melting, of mid-ocean ridge (MOR) cumulate gabbro
melting, and fractional crystallization of slightly hydrous mid-ocean ridge basalt (MORB) magma to assess a melting versus
fractionation origin for oceanic plagiogranite. For felsic magmas (>63 wt.% SiO2) the modeling predicts the following. MOR cumulate gabbro melting should yield constant or decreasing La and constant Yb
abundances with increasing liquid SiO2. The overall abundances should be similar to those in associated mafic magmas. MORB fractional crystallization should yield
steadily increasing La and Yb abundances with increasing SiO2 with overall abundances significantly higher than those in associated mafic magmas. Application to natural occurrences of
oceanic plagiogranite indicate that both MOR cumulate gabbro melting and MORB fractionation are responsible. Application of
the model results to Icelandic rhyolites strongly support a fractional crystallization rather than a crustal melting origin. 相似文献