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1.
Material behaviour that exhibits characteristics of creep induced by a spontaneous mineral dissolution enhanced by material damage is studied. It is believed that the characteristic rates of the chemical processes involved determine the time‐rate dependence of the resulting strain. A basic model of a combined chemo‐plastic softening and chemically enhanced deviatoric strain hardening for saturated geomaterials is presented. Chemical softening is postulated to occur as a consequence of the net mass removal resulting from dissolution and precipitation of specific minerals occurring at the damage‐generated inter‐phase interfaces. Closed and open systems are discussed. In the former case, deformation at constant stress results entirely from a local compensation mechanism between the chemical softening and strain hardening. The classical three stages of creep are interpreted in terms of mechanisms of dissolution and precipitation, as well as the variation in the reaction surface areas involved in the mass exchange. In an open system, the above local mechanism is enhanced by the removal of mass via diffusion of species affecting the mass balance. Such a system is addressed via a boundary value problem as shown in an example. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

2.
A hierarchical mathematical model for analyses of coupled chemo‐thermo‐hygro‐mechanical behaviour in concretes at high temperature is presented. The concretes are modelled as unsaturated deforming reactive porous media filled with two immiscible pore fluids, i.e. the gas mixture and the liquid mixture, in immiscible–miscible levels. The thermo‐induced desalination process is particularly integrated into the model. The chemical effects of both the desalination and the dehydration processes on the material damage and the degradation of the material strength are taken into account. The mathematical model consists of a set of coupled, partial differential equations governing the mass balance of the dry air, the mass balance of the water species, the mass balance of the matrix components dissolved in the liquid phases, the enthalpy (energy) balance and momentum balance of the whole medium mixture. The governing equations, the state equations for the model and the constitutive laws used in the model are given. A mixed weak form for the finite element solution procedure is formulated for the numerical simulation of chemo‐thermo‐hygro‐mechanical behaviours. Special considerations are given to spatial discretization of hyperbolic equation with non‐self‐adjoint operator nature. Numerical results demonstrate the performance and the effectiveness of the proposed model and its numerical procedure in reproducing coupled chemo‐thermo‐hygro‐mechanical behaviour in concretes subjected to fire and thermal radiation. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

3.
This paper studies the chemo‐mechanics of cemented granular solids in the context of continuum thermodynamics for fluid‐saturated porous media. For this purpose, an existing constitutive model formulated in the frame of the Breakage Mechanics theory is augmented to cope with reactive processes. Chemical state variables accounting for the reactions between the solid constituents and the solutes in the pore fluid are introduced to enrich the interactions among the microstructural units simulated by the model (i.e., grains and cement bonds). Two different reactive processes are studied (i.e., grain dissolution and cement precipitation), using the chemical variables to describe the progression of the reactions and track changes in the size of grains and bonds. Finally, a homogenization strategy is used to derive the energy potentials of the solid mixture, adopting probability density functions that depend on both mechanical and chemical indices. It is shown that the connection between the statistics of the micro‐scale attributes and the continuum properties of the solid enables the mathematical capture of numerous mechanical effects of lithification and chemical deterioration, such as changes in stiffness, expansion/contraction of the elastic domain, and development of inelastic strains during reaction. In particular, the model offers an interpretation of the plastic strains generated by aggressive environments, which are here interpreted as an outcome of chemically driven debonding and comminution. As a result, the model explains widely observed macroscopic signatures of geomaterial degradation by reconciling the energetics of the deformation/reaction processes with the evolving geometry of the microstructural attributes. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

4.
Safety assessment of geosequestration of CO2 into deep saline aquifers requires a precise understanding of the study of hydro‐chemo‐mechanical couplings occurring in the rocks and the cement well. To this aim, a coupled chemo‐poromechanical model has been developed and implemented into a research code well‐suited to the resolution of fully coupled problems. This code is based on the finite volume methods. In a 1D axisymmetrical configuration, this study aims to simulate the chemo‐poromechanical behaviour of a system composed by the cement well and the caprock during CO2 injection. Major chemical reactions of carbonation occurring into cement paste and rocks are considered in order to evaluate the consequences of the presence of CO2 on the amount of dissolved matrix and precipitated calcium carbonates. The dissolution of the solid matrix is taken into account through the use of a chemical porosity. Matrix leaching and carbonation lead, as expected, to important variations of porosity, permeability and to alterations of transport properties and mechanical stiffness. These results justify the importance of considering a coupled analysis accounting for the main chemical reactions. It is worth noting that the modelling framework proposed in the present study could be extended to model the chemo‐poromechanical behaviour of the reservoir rock and the caprock when subjected to the presence of an acidic pore fluid (CO2‐rich brine). Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

5.
Geomaterials respond to some environmental circumstances through generation of a series of feedback mechanisms of damage, deformation, erosion, and chemical processes or reactions: e.g. osmosis, dissolution and precipitation, mineral transformations. These mechanisms are coupled at different scales. Several natural geomechanical processes, as sediment compaction, rock weathering or landsliding appear to include such sequences of mechanisms. A multi-physics model of sediment compaction is examined from the point of view of feedbacks and feedforwards for the phenomena involved at micro- and meso-scale. Two types of feedback are identified: constitutive feedbacks and boundary condition feedbacks. A numerical sensitivity study points out which feedbacks and feedforwards are strong and which are weak.  相似文献   

6.
Coupled thermo‐hydro‐mechanical‐chemical modelling has attracted attention in past decades due to many contemporary geotechnical engineering applications (e.g., waste disposal, carbon capture and storage). However, molecular‐scale interactions within geomaterials (e.g., swelling and dissolution/precipitation) have a significant influence on the mechanical behaviour, yet are rarely incorporated into existing Thermal‐Hydro‐Mechanical‐Chemical (THMC) frameworks. This paper presents a new coupled hydro‐mechanical‐chemical constitutive model to bridge molecular‐scale interactions with macro‐physical deformation by combining the swelling and dissolution/precipitation through an extension of the new mixture‐coupling theory. Entropy analysis of the geomaterial system provides dissipation energy, and Helmholtz free energy gives the relationship between solids and fluids. Numerical simulation is used to compare with the selected recognized models, which demonstrates that the swelling and dissolution/precipitation processes may have a significant influence on the mechanical deformation of the geomaterials.  相似文献   

7.
Advanced material constitutive models are used to describe complex soil behaviour. These models are often used in the solution of boundary value problems under general loading conditions. Users and developers of constitutive models need to methodically investigate the represented soil response under a wide range of loading conditions. This paper presents a systematic procedure for probing constitutive models. A general incremental strain probe, 6D hyperspherical strain probe (HSP), is introduced to examine rate‐independent model response under all possible strain loading conditions. Two special cases of HSP, the true triaxial strain probe (TTSP) and the plane‐strain strain probe (PSSP), are used to generate 3‐D objects that represent model stress response to probing. The TTSP, PSSP and general HSP procedures are demonstrated using elasto‐plastic models. The objects resulting from the probing procedure readily highlight important model characteristics including anisotropy, yielding, hardening, softening and failure. The PSSP procedure is applied to a Neural Network (NN) based constitutive model. It shows that this probing is especially useful in understanding NN constitutive models, which do not contain explicit functions for yield surface, hardening, or anisotropy. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

8.
The paper presents detailed FE simulation results of concrete elements under mixed‐mode failure conditions according to the so‐called shear‐tension test by Nooru‐Mohamed, characterized by curved cracks. A continuous and discontinuous numerical two‐dimensional approach was used. In order to describe the concrete's behaviour within continuum mechanics, two different constitutive models were used. First, an elasto‐plastic model with isotropic hardening and softening was assumed. In a compression regime, a Drucker–Prager criterion with a non‐associated flow rule was used. In turn, in a tensile regime, a Rankine criterion with an associated flow rule was adopted. Second, an isotropic damage constitutive model was applied with a single scalar damage parameter and different definitions of the equivalent strain. Both constitutive laws were enriched by a characteristic length of micro‐structure to capture properly strain localization. As an alternative approach, the extended finite element method was used. Our results were compared with the experimental ones and with results of other FE simulations reported in the literature. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

9.
A constitutive relation is derived for describing the mechanical response of chalk. The approach is based on a phenomenological framework which employs chemo‐plasticity. The properties of the material are assumed to be affected by the physico‐chemical processes that occur through the interaction between the skeleton and the pore fluid. The underlying mechanism is discussed by invoking a micromechanical analysis. The performance of the framework is illustrated by examining the evolution of mechanical characteristics in the presence of different pore fluids. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

10.
The paper presents a strainhardening constitutive model for unsaturated soil behaviour based on energy conjugated stress variables in the framework of superposed continua. The proposed constitutive law deals with hydro‐mechanical coupling phenomena. The main purpose is to develop within a consistent framework a model that can deal with possible mechanical instabilities occurring in partially saturated materials. The loss of capillary effects during wetting processes can, in fact, play a central role in unstable processes. Therefore, it will be shown that the bonding effects due to surface tensions can be described in a mathematical framework similar to that employed for bonded geomaterials to model weathering or diagenesis effects, either mechanically or chemically induced. The results of several simulations of common laboratory tests on partially saturated soil specimens are shown. The calculated behaviour appears to be in good qualitative agreement with that observed in the laboratory. In particular it is shown that volumetric collapse phenomena due to hydraulic debonding effects can be successfully described by the model. Finally, it will be highlighted the ability of the model to naturally capture the transition to a fully saturated condition and to deal with possible mechanical instabilities in the unsaturated regime. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

11.
Shale, as a kind of brittle rock, often exhibits different nonlinear stress-strain behavior, failure and time-dependent behavior under different strain rates. To capture these features, this work conducted triaxial compression tests under axial strain rates ranging from 5×10?6 s?1 to 1×10?3 s?1. The results show that both elastic modulus and peak strength have a positive correlation relationship with strain rates. These strain rate-dependent mechanical behaviors of shale are originated from damage growth, which is described by a damage parameter. When axial strain is the same, the damage parameter is positively correlated with strain rate. When strain rate is the same, with an increase of axial strain, the damage parameter decreases firstly from an initial value (about 0.1 to 0.2), soon reaches its minimum (about 0.1), and then increases to an asymptotic value of 0.8. Based on the experimental results, taking yield stress as the cut-off point and considering damage variable evolution, a new measure of micro-mechanical strength is proposed. Based on the Lemaitre’s equivalent strain assumption and the new measure of micro-mechanical strength, a statistical strain-rate dependent damage constitutive model for shale that couples physically meaningful model parameters was established. Numerical back-calculations of these triaxial compression tests results demonstrate the ability of the model to reproduce the primary features of the strain rate dependent mechanical behavior of shale.  相似文献   

12.
The mechanical behaviour of bonded geomaterials is described by means of an elastoplastic strain‐hardening model. The internal variables, taking into account the ‘history’ of the material, depend on the plastic strains experienced and on a conveniently defined scalar measure of damage induced by weathering and/or chemical degradation. For the sake of simplicity, it is assumed that only internal variables are affected by mechanical and chemical history of the material. Despite this simplifying assumption, it can be shown that many interesting phenomena exhibited by weathered bonded geomaterials can be successfully described. For instance, (i) the transition from brittle to ductile behaviour with increasing pressure of a calcarenite with collapsing internal structure, (ii) the complex behaviour of chalk and other calcareous materials in oedometric tests, (iii) the chemically induced variation of the stress and strain state of such kind of materials, are all phenomena that can be qualitatively reproduced. Several comparisons with experimental data show that the model can capture the observed behaviour also quantitatively. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

13.
A numerical model is presented to describe the evolution of fracture aperture (and related permeability) mediated by the competing chemical processes of pressure solution and free‐face dissolution/precipitation; pressure (dis)solution and precipitation effect net‐reduction in aperture and free‐face dissolution effects net‐increase. These processes are incorporated to examine coupled thermo‐hydro‐mechano‐chemo responses during a flow‐through experiment, and applied to reckon the effect of forced fluid injection within rock fractures at geothermal and petroleum sites. The model accommodates advection‐dominant transport systems by employing the Lagrangian–Eulerian method. This enables changes in aperture and solute concentration within a fracture to be followed with time for arbitrary driving effective stresses, fluid and rock temperatures, and fluid flow rates. This allows a systematic evaluation of evolving linked mechanical and chemical processes. Changes in fracture aperture and solute concentration tracked within a well‐constrained flow‐through test completed on a natural fracture in novaculite (Earth Planet. Sci. Lett. 2006, in press) are compared with the distributed parameter model. These results show relatively good agreement, excepting an enigmatic abrupt reduction in fracture aperture in the early experimental period, suggesting that other mechanisms such as mechanical creep and clogging induced by unanticipated local precipitation need to be quantified and incorporated. The model is applied to examine the evolution in fracture permeability for different inlet conditions, including localized (rather than distributed) injection. Predictions show the evolution of preferential flow paths driven by dissolution, and also define the sense of permeability evolution at field scale. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

14.
冻融作用下岩石力-热-水耦合本构模型研究   总被引：1，自引：0，他引：1  
王震  朱珍德  陈会官  朱姝 《岩土力学》2019,40(7):2608-2616
在寒区隧道工程中,冻胀的水分迁移作用加剧了隧道围岩的冻融破坏。耦合水分迁移作用的岩石本构模型对防治冻融渗漏、崩塌等隧道围岩灾害有着重要意义。基于内状态变量理论,将冻胀过程中的水分迁移量作为本征变量引入Helmholtz自由能,在热力学框架下建立了一个岩石力-热-水耦合本构模型。模型描述了温度和水分迁移对冻融后岩石损伤阈值、等向强化饱和值、等向强化速率等力学参数的影响。模拟了岩石冻融后力学性质的劣化。区别于全量经验公式,本模型以增量形式给出,为复杂应力历史条件下的数值模拟提供了便利。通过将模型模拟曲线与冻融后岩石常规三轴压缩试验曲线进行对比,初步验证模型的可靠性,为实际寒区工程的冻胀破坏预测提供参考。  相似文献   

15.
Effective capabilities of combined chemo‐elasto‐plastic and unsaturated soil models to simulate chemo‐hydro‐mechanical (CHM) behaviour of clays are examined in numerical simulations through selected boundary value problems. The objective is to investigate the feasibility of approaching such complex material behaviour numerically by combining two existing models. The chemo‐mechanical effects are described using the concept of chemical softening consisting of reduction of the pre‐consolidation pressure proposed originally by Hueckel (Can. Geotech. J. 1992; 29 :1071–1086; Int. J. Numer. Anal. Methods Geomech. 1997; 21 :43–72). An additional chemical softening mechanism is considered, consisting in a decrease of cohesion with an increase in contaminant concentration. The influence of partial saturation on the constitutive behaviour is modelled following Barcelona basic model (BBM) formulation (Géotech. 1990; 40 (3):405–430; Can. Geotech. J. 1992; 29 :1013–1032). The equilibrium equations combined with the CHM constitutive relations, and the governing equations for flow of fluids and contaminant transport, are solved numerically using finite element. The emphasis is laid on understanding the role that the individual chemical effects such as chemo‐elastic swelling, or chemo‐plastic consolidation, or finally, chemical loss of cohesion have in the overall response of the soil mass. The numerical problems analysed concern the chemical effects in response to wetting of a clay specimen with an organic liquid in rigid wall consolidometer, during biaxial loading up to failure, and in response to fresh water influx during tunnel excavation in swelling clay. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

16.
Based on relevant experimental data of a petroleum cement paste under mechanical loading and chemical leaching, an elastic‐plastic model is first proposed by taking into account plastic shearing and pore collapse. The degradation of mechanical properties induced by the chemical leaching is characterized by a chemical damage variable which is defined as the increase of porosity. Both elastic and plastic properties of the cement paste are affected by the chemical damage. The proposed model is calibrated from and applied to describe mechanical responses in triaxial compression tests respectively on sound and fully leached samples. In the second part, a phenomenological chemical model is defined to establish the relationship between porosity change and calcium dissolution process. The dissolution kinetics is governed by a diffusion law taking into account the variation of diffusion coefficient with calcium concentration. The chemical model is coupled with the mechanical model, and both are applied to describe mechanical response of cement paste samples subjected to progressive chemical leaching and compressive stresses. Comparisons between experimental data and numerical results are presented.  相似文献   

17.
In this paper, the onset of mechanical instability in time‐sensitive elasto‐viscoplastic solids is theoretically analyzed at the constitutive level and associated with the occurrence of ‘spontaneous accelerations’ under stationary external perturbations. For this purpose, a second‐order form of Perzyna's constitutive equations is first derived by time differentiation, and a sufficient stability condition is identified for general mixed loading programs. These loading conditions are in fact the most general in both laboratory tests and real boundary value problems, where a combination of certain stress and strain components is known/prescribed. The theoretical analysis leads to find precise stability limits in terms of material hardening modulus. In the case of constitutive relationships with isotropic strain‐hardening, no instabilities are possible while the hardening modulus is larger than the so‐called ‘controllability modulus’ defined for (inviscid) elasto‐plastic materials. It is also shown that the current stress/strain rate may also directly influence the occurrence of elasto‐viscoplastic instability, which is at variance with elasto‐plastic inviscid media. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

18.
On the basis of fundamental constitutive laws such as elasticity, perfect plasticity, and pure viscosity, many elasto‐viscoplastic constitutive relations have been developed since the 1970s through phenomenological approaches. In addition, a few more recent micro‐mechanical models based on multi‐scale approaches are now able to describe the main macroscopic features of the mechanical behaviour of granular media. The purpose of this paper is to compare a phenomenological constitutive relation and a micro‐mechanical model with respect to a basic issue regularly raised about granular assemblies: the incrementally non‐linear character of their behaviour. It is shown that both phenomenological and micro‐mechanical models exhibit an incremental non‐linearity. In addition, the multi‐scale approach reveals that the macroscopic incremental non‐linearity could stem from the change in the regime of local contacts between particles (from plastic regime to elastic regime) in terms of the incremental macroscopic loading direction. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

19.
An extended version of the classical Generalized Backward Euler (GBE) algorithm is proposed for the numerical integration of a three‐invariant isotropic‐hardening elastoplastic model for cemented soils or weak rocks undergoing mechanical and non‐mechanical degradation processes. The restriction to isotropy allows to formulate the return mapping algorithm in the space of principal elastic strains. In this way, an efficient and robust integration scheme is developed which can be applied to relatively complex yield surface and plastic potential functions. Moreover, the proposed algorithm can be linearized in closed form, thus allowing for quadratic convergence in the global Newton iteration. A series of numerical experiments are performed to illustrate the accuracy and convergence properties of the algorithm. Selected results from a finite element analysis of a circular footing on a soft rock layer undergoing chemical weathering are then presented to illustrate the algorithm performance at the boundary value problem level. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

20.
Unsaturated soils are highly heterogeneous 3‐phase porous media. Variations of temperature, the degree of saturation, and density have dramatic impacts on the hydro‐mechanical behavior of unsaturated soils. To model all these features, we present a thermo‐hydro‐plastic model in which the hydro‐mechanical hardening and thermal softening are incorporated in a hierarchical fashion for unsaturated soils. This novel constitutive model can capture heterogeneities in density, suction, the degree of saturation, and temperature. Specifically, this constitutive model has 2 ingredients: (1) it has a “mesoscale” mechanical state variable—porosity and 3 environmental state variables—suction, the degree of saturation, and temperature; (2) both temperature and mechanical effects on water retention properties are taken into account. The return mapping algorithm is applied to implement this model at Gauss point assuming an infinitesimal strain. At each time step, the return mapping is conducted only in principal elastic strain space, assuming no return mapping in suction and temperature. The numerical results obtained by this constitutive model are compared with the experimental results. It shows that the proposed model can simulate the thermo‐hydro‐mechanical behavior of unsaturated soils with satisfaction. We also conduct shear band analysis of an unsaturated soil specimen under plane strain condition to demonstrate the impact of temperature variation on shear banding triggered by initial material heterogeneities.  相似文献   

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