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1.
Lipids extracted from lacustrine deposits in the paleolake Qarhan of the Qaidam basin in the northeastern Tibetan Plateau were determined by conventional gas chromatography-mass spectrometry. Several series of biomarkers were identified, mainly including n-alkanes, n-alkan-2-ones, n-alkanoic acids, branched alkanes, triterpenoids and steroids, indicative of various biogenic contributions. On the basis of cluster analysis, the n-C15, n-C17, n-C19 alkanes were proposed to be derived from algae and/or photosynthetic bacteria, the n-C21, n-C23, n-C25 homologues from aquatic plants, and the n-C29, n-C31 homologues from vascular plants. In contrast, the n-C27 alkane is not categorized in the n-C29 and n-C31 group of alkanes, probably due to more complex origins including both aquatic and vascular plants, and/or differential biodegradation. Stratigraphically, layers-2, 4 and 5 were found to show a close relationship in n-alkane distribution, associated with a positive shift in carbon isotope composition of bulk organic matter (δ13Corg), inferring a cold/dry period. Layers-1 and 6 were clustered together in association with a negative δ13Corg, excursion, probably indicating a relatively warm/humid climate. The potential coupling between the n-alkane distributions and δ13Corg, suggests a consequence of vegetation change in response to climate change, with the late MIS3 being shown to be unstable, thought to be the climatic optimum in the Tibetan Plateau. Our results suggest that the cluster analysis used in this study probably provides an effective and authentic method to investigate the n-alkane distribution in paleolake sediments.  相似文献   

2.
Lipid biomarkers from a peat plateau profile from the Northeast European Russian Arctic were analyzed. The peat originated as a wet fen ca. 9 ka BP and developed into a peat bog after the onset of permafrost ca. 2.5 ka BP. The distributions and abundances of n-alkanols, n-alkanoic acids, n-alkanes, n-alkan-2-ones and sterols were determined to study the effect of degradation on their paleoclimate proxy information. Plant macrofossil analysis was also used in combination with the lipid distributions. The n-alkanol and n-alkanoic acid distributions in the upper part of the sequence generally correspond to compositions expected from plant macrofossil assemblages. Their carbon preference index (CPI) values increase with depth and age, whereas those of the n-alkanes decrease. The different CPI patterns suggest that n-alkanoic acids and n-alkanols deeper in the sequence may be produced during humification through alteration of other lipids. Excursions in the n-alkanoic acid content also suggest an important contribution of invasive roots to the lipid biomarker composition. The CPIs associated with these compounds show that under permafrost conditions organic material from Sphagnum is better preserved than material from vascular plants. Increasing stanol/stenol ratio values and decreasing n-alkane CPI values indicate progressive degradation of organic matter (OM) with depth. The n-alkan-2-one/n-alkane and n-alkan-2-one/n-alkanoic acid ratios were shown to be useful proxies that can reflect the degree of OM preservation and suggest that both microbial oxidation of n-alkanes and decarboxylation of n-alkanoic acids produce n-alkan-2-ones in this peat sequence.  相似文献   

3.
We characterized the compositions of organic compounds in a Cheremushka bog sediment core (deposited over the last 35 kyr), located at the eastern coast of Lake Baikal, to obtain basic information about the terrestrial organic matter (OM) which contributed to Lake Baikal sediments. The bog sediment was analyzed for the molecular composition of n-alkanes, lignin phenols and n-C24 to C30 alkanoic acids, as well as the carbon isotopic composition of plant wax derived n-C27 to C33 alkanes.Concentrations of lignin phenols [vanillyl (V) plus syringyl (S) phenols] normalized to total organic carbon (TOC) in the Holocene are twice those for the last glacial maximum (LGM), while concentrations of TOC-normalized n-C24 to C30 alkanoic acids do not change markedly in this period. Thus, the ratio of lignin phenols to n-C24 to C30 alkanoic acids increases from the LGM to the Holocene. This result is essentially consistent with pollen analysis indicating an expansion of woody plants in the Holocene and a prevailing herb-abundant environment for the LGM. The δ13C values of n-C27 to C33 alkanes (e.g. ?29‰ to ?33‰ for C31) indicate the presence of C3-dominant plants throughout the core.The contribution of terrestrial OM to Lake Baikal sediments was estimated using the biomarkers, on the assumption that the OM in the bog sediments is a representative of the terrestrial OM around the lake. Hence, the estimation using lignin phenol or n-C24 to C30 alkanoic acid parameters indicates that 11–24% of the TOC in the Academician Ridge sediments is land-derived for both the Holocene and the LGM, which is similar to the estimates from C/N values of bulk OM. However, the estimates for terrestrial OM using the n-C27 to C33 alkane parameter are generally higher than those using lignin phenol or n-C24 to C30 alkanoic acid parameters. The difference is thought to be associated with the difference in source and behavior of these biomarkers.  相似文献   

4.
High resolution records of long chain n-alkanol biomarkers were obtained from a peat-lacustrine core from the Dingnan profile in southern China. The n-alkanol distributions are characterized by the predominance of even-over-odd carbon number and maximize at C24 or C26. On the basis of the reported n-alkanol records in the literature and the n-alkane record in our samples, we concluded that the n-alkanol ratio of C26/C30 varying from 1.25 to 6.48, together with the n-alkanol ratio C22/C24 less than unity, is indicative of the presence of a dominant forest paleovegetation. A 2000-year cycling in the variation of the n-alkanol ratio C26/C30 is identifiable in our profile, and probably results from the change in the abundance of the grass relative to trees induced by a cyclic paleoclimate. The n-alkanol ratio C24/C26 appears to be more sensitive to change in precipitation than in temperature, and may be a potential indicator of precipitation/humidity, with increased values being associated with relatively dry conditions. The paleovegetation and the paleoclimate reconstructed on the basis of the n-alkanol records for the recent 18000 cal a BP in general accord with the pollen data and other lipid evidence recorded in the Dingnan region in southern China. In particular, both the n-alkanol records and the pollen data infer the different paleoclimate conditions for the two peat sequences, with a cool and wet climate dominating in the lower peat deposition formed during the latest Pleistocene and a change to a drier and cooler climate occurring in the upper peat sequence in mid-Holocene.  相似文献   

5.
Anhydrous non-isothermal heating experiments were conducted under controlled compressive stress on cylindrical plugs of six oil shales from Permian through Eocene age. The objective of this study was to compare the distribution of acyclic paraffins in initial, residual and expelled organic matter and to highlight causes of compositional differences resulting from expulsion. Pristane generation from kerogen is highest in the Eocene Messel shale and affects the pristane / phytane (pr / ph) ratio commonly used as a redox proxy. The isoprenoid to n-alkane ratios (pr / n-C17, ph / n-C18) decrease during generation and are lowest in the residual bitumen due to preferential generation and retention of n-alkanes. The n-alkane distribution shows that only lacustrine shales produce high wax oils. Evaporative fractionation leads to loss of n-alkanes up to n-C20 with boiling points below 350 °C. This demonstrates that lacustrine and marine shales may lead to accumulation of low wax oils due to evaporative fractionation after expulsion.  相似文献   

6.
Nine rock samples from three Jurassic stratigraphic units of a shallow core from NW Germany were analyzed by pyrolysis-gas chromatography. The units contain a mixed Type-II/III kerogen (Dogger-α), a hydrogen-rich Type-II kerogen (Lias-), and a hydrogen-poor Type-III kerogen (Lias-δ). All of the kerogen was immature (Ro = 0.5%). Two sets of kerogen concentrates (“AD”: HCl/HF followed by a density separation, and “A”: only acid treatment) prepared from the rock samples were also analyzed to make a detailed comparison of the pyrolysates of rock and corresponding kerogen-concentrates.Hydrogen-index (HI) values of the kerogen concentrates prepared from organic-carbon poor rock were nearly 200% higher than HI values of the rock samples. Changes in HI were minimal for the samples containing Type-II kerogen. The A and AD samples from the Corg-poor rock yielded pyrolysates with n-alkane series of very different molecular lengths. Pyrograms of the rock samples had n-alkane series extending to n-C14; the chromatograms of the A samples reached the n-C14-nC20 range. The AD samples from Corg-poor rock and all three sample types from the Corg-rich rock had n-alkane series up to n-C29. The benzene/hexane and toluene/heptane ratios for the Corg-poor rock and A samples were far higher than for the AD samples, which had ratios similar to those of all three sample types from the Corg-rich rocks. These results indicate that choice of kerogen preparation method is critical when Corg-poor samples are analyzed.  相似文献   

7.
Samples of Sphagnum palustre and peat from the Erxianyan peatland, central China, were analyzed for lipids and their carbon isotopes to investigate how lipid distributions respond to hydrological change and to evaluate the importance of the contribution of microbial lipids to the peat moss. The lipids in samples collected from different hydrological settings in and around a pond and in the central part of the bog show clear variation along the hydrological gradient, with higher n-C23/n-C25 alkane ratio values and lower ACL (average chain length) values of long chain n-alkanes, n-fatty alcohols and n-fatty acids at the wetter sites. Although the relationship between the S. palustre lipids and the hydrological conditions can be partially overprinted in peat by an input from vascular plants, lipid ratios such as Paq and ACL can provide useful qualitative information about Sphagnum contributions. In addition, lipid composition and carbon isotope values provide information about microbial activity associated with S. palustre. The occurrence of a high abundance of 7-methylheptadecane in submerged S. palustre is an indication of cyanobacteria in the living peat moss. The relatively 13C-depleted carbon isotope values of the n-C23 alkane could result from the influence of symbiotic methanotrophs on the carbon available for assimilation by S. palustre.  相似文献   

8.
Precise indices based on n-alkane signatures were developed in order to determine the sources and composition of sedimentary organic matter (SOM) in coastal systems. The Arcachon Bay (France), a well-studied temperate lagoon, was used as an example of a complex coastal system sheltering a wide diversity of OM sources. Three main groups of sources were well discriminated from their n-alkane signatures: seagrass (Zostera sp.) produced mainly n-C17, n-C19, n-C21, n-C23 and n-C25 alkanes, algae (Rhodophyta, Chlorophyta) produced n-C15 and n-C17 and the terrigenous input [Quercus sp., Spartina sp. and river suspended particulate OM (SPOM)] was characterized by n-C25, n-C27, n-C29, n-C31 and n-C33. From the above and literature n-alkane fingerprints, we developed a set of indices (n-alkane ratios) to quantify the contribution of these three major sources of the SOM. At the Arcachon Bay scale, they indicated that SOM was composed mainly of seagrass (ca. 53 ± 19%) and terrestrial (ca. 41 ± 17%) material, followed by algae (ca. 6 ± 9%). Moreover, the new n-alkane indices exhibited more relevant spatial patterns than classical ones – the TAR (C27 + C29 + C31/C15 + C17 + C19; terrestrial to aquatic ratio) and the Paq (C23 + C25/C23 + C25 + C29 + C31; aquatic plant %) – with a greater contribution from marine sources in the central part of the lagoon where a high density of Zostera seagrass was observed. Therefore, the development of precise indices adapted to the local diversity of OM sources is needed when using n-alkanes for quantifying the source composition of SOM in complex coastal systems.  相似文献   

9.
Novel ecosystem development is occurring within the western boreal forest of Canada due to land reclamation following oil sand surface mining. Sphagnum peat is the primary organic amendment used to reconstruct soil in these novel ecosystems. We hypothesised that ecosystem recovery would be indicated by an increasing similarity in the biomolecular characteristics of novel soil organic matter (SOM) derived from peat to those of natural boreal ecosystems. We evaluated the use of the homologous series of long chain (⩾ C21) n-alkanes with odd/even predominance to monitor the re-establishment of boreal forest on these anthropogenic soils. The lipids were extracted from dominant vegetation inputs and SOM from a series of natural and novel ecosystem reference plots. Twice the concentration of n-alkanes was extracted from natural than from novel ecosystem SOM (p < 0.01). We observed unique n-alkane signatures for the source vegetation, e.g. peat material was dominated by C31, and aspen (Populus tremuloides Michx.) leaves by C25. The n-alkane distribution differed between the two systems (p < 0.001) and reflected the dominant vegetation input, i.e. peat or tree species. Our results indicate that further research is required to clarify the influence of vegetation or disturbance on the signature of n-alkanes in SOM; however, the use of n-alkanes as biomarkers of novel ecosystem development is a promising application.  相似文献   

10.
The Namoi Formation in the Werrie Syncline, north and west of Tamworth, is part of the well-preserved Devonian–Carboniferous fore arc in the New England Fold Belt. The formation is between 640–914 m thick and consists of dominant olive-green mudstones with lenses of sandstone and oolitic limestone. To assess shale gas prospectivity, we analysed five outcrop samples from the Namoi Formation in the Keepit area. Well-preserved aliphatic and aromatic hydrocarbon fractions do not show evidence of weathering or biodegradation. n-Alkanes in all samples have a unimodal distribution maximising at C26 to C28. Little odd-to-even n-alkane carbon number predominance and relatively low Pr/n-C17 and Ph/n-C18 ratios are consistent with a high thermal maturity. Based on the distribution of alkylnaphthalenes and alkylphenanthrenes, the Namoi Formation is in the gas window. Calibration of the methylphenanthrene index and ratio with vitrinite reflectance suggests a calculated reflectance around 2.1%, which given a normal geothermal gradient is equivalent to a maximum temperature of 205°C for the deepest burial of the formation. There is a dominance of parent polycyclic aromatic hydrocarbons (PAH) over alkylated PAHs, supporting a high thermal maturity. Some samples contain biomarkers suggestive of a marine depositional environment, including the C30 sterane index and the C31/C30 hopane ratio. The Namoi Formation is a prospective shale-gas source, as it has been buried sufficiently to be well within the gas window. Where it is exposed at the surface gas will have been lost, but elsewhere it will be buried beneath other sediments and may still retain gas. Key exploration uncertainties include information on organic richness, lateral variation in thermal maturity, mineralogy, and porosity–permeability relationships.  相似文献   

11.
We present a systematic study of chain-length distributions and D/H ratios of n-alkyl lipids (both n-alkanes and n-alkanoic acids) in a wide range of terrestrial and aquatic plants around and in Blood Pond, Massachusetts, USA. The primary goal is to establish a model to quantitatively assess the aquatic plant inputs of the mid-chain length n-alkyl lipids to lake sediments and to determine the average hydrogen isotopic ratios of these lipids in different plants. Our results show that middle-chain n-alkyl lipids (C21-C23n-alkanes and C20-C24n-alkanoic acids) are exceptionally abundant in floating and submerged aquatic plants, in contrast to the dominance of long-chain n-alkyl lipids (C27-C31n-alkanes and C26-C32n-alkanoic acids) in other plant types, which are consistent with previously published data from Mountain Kenya and the Tibetan Plateau. Combining available data in different environmental settings allows us to establish statistically robust model distributions of n-alkyl lipids in floating/submerged macrophytes relative to other plant types. Based on the model distributions, we established a multi-source mixing model using a linear algebra approach, in order to quantify the aquatic inputs of mid-chain n-alkyl lipids in lake sediments. The results show that ∼97% of the mid-chain n-alkyl lipids (C23n-alkane and C22n-acid (behenic acid)) in Blood Pond sediments are derived from floating and submerged macrophytes. In addition, D/H ratios of C22n-acid and C23n-alkane in the floating and submerged plants from Blood Pond display relatively narrow ranges of variation (−161 ± 16‰ and −183 ± 18‰, respectively). Our study demonstrates that mid-chain n-alkyl lipids such as C23n-alkane and C22n-acid could be excellent recorders of past lake water isotopic ratios in lakes with abundant floating and submerged macrophyte inputs.  相似文献   

12.
Moss covered, high latitude wetlands hold large amounts of terrestrial organic matter (OM), which may be vulnerable to expected climate warming. Molecular analysis of fluvially transported material from these regions can distinguish between different sources of terrestrial OM. Sphagnum moss may represent one of the major sources. This study aimed to quantitatively establish a molecular proxy for identifying Sphagnum-derived OM from high latitude peatlands in the sub-Arctic coastal ocean. We collected and analyzed Sphagnum species throughout northern Sweden and Finland. Results show that the C25/(C25 + C29) n-alkane ratio is most suitable for terrestrial OM source apportionment in these coastal regions since, compared to other n-alkane Sphagnum proxies, it shows (i) the least variation between species, (ii) the most constant values for different latitudinal regimes and (iii) the largest dynamic range to the higher plant end member in two-source mixing models. Application of the proxy to surface sediments and suspended particulate matter in the sub-Arctic northern Baltic Sea shows that 68–103% of the terrestrial OM fraction is derived from Sphagnum-rich peatland. We recommend that future studies on terrestrial OM fluxes into (sub-)Arctic regions should apply the C25/(C25 + C29) proxy to improve insight into the contribution of Sphagnum-derived terrestrial OM from climate-vulnerable, high latitude wetlands.  相似文献   

13.
Leaf wax components of terrestrial plants are an important source of biomass in the geological records of soils, lakes and marine sediments. Relevant to the emerging use of plant wax derived biomarkers as proxies for past vegetation composition this study provides key data for C3 plants of tropical and subtropical Africa. We present analytical results for 45 savanna species and 24 rain forest plants sampled in their natural habitats. Contents and distribution patterns of long chain n-alkanes (n-C25 to n-C35) and n-alkan-1-ols (n-C24 to n-C34) as well as bulk and molecular carbon isotopic data are presented. The variations of the analysed parameters among different growth forms (herb, shrub, liana and tree) are small within the vegetation zones, whereas characteristic differences occur between the signatures of rain forest and savanna plants. Therefore, we provide averaged histogram representations for rain forest and savanna C3 plants.The findings were compared to previously published data of typical C4 grass waxes of tropical and subtropical Africa. Generally, trends to longer n-alkane chains and less negative carbon isotopic values are evident from rain forest over C3 savanna to C4 vegetation. For n-alkanols of rain forest plants the maximum of the averaged distribution pattern is between those of C3 savanna plants and C4 grasses. The averaged presentations for tropical and subtropical vegetation and their characteristics may constitute useful biomarker proxies for studies analysing the expansion and contraction of African vegetation zones.  相似文献   

14.
We measured molecular distributions and compound-specific hydrogen (δD) and stable carbon isotopic ratios (δ13C) of mid- and long-chain n-alkanes in forest soils, wetland peats and lake sediments within the Dorokawa watershed, Hokkaido, Japan, to better understand sources and processes associate with delivery of terrestrial organic matter into the lake sediments. δ13C values of odd carbon numbered C23-C33n-alkanes ranged from −37.2‰ to −31.5‰, while δD values of these alkanes showed a large degree of variability that ranged from −244‰ to −180‰. Molecular distributions in combination with stable carbon isotopic compositions indicate a large contribution of C3 trees as the main source of n-alkanes in forested soils whereas n-alkanes in wetland soil are exclusively derived from marsh grass and/or moss. We found that the n-alkane δD values are much higher in forest soils than wetland peat. The higher δD values in forest samples could be explained by the enrichment of deuterium in leaf and soil waters due to increased evapotranspiration in the forest or differences in physiology of source plants between wetland and forest. A δ13C vs. δD diagram of n-alkanes among forest, wetland and lake samples showed that C25-C31n-alkanes deposited in lake sediments are mainly derived from tree leaves due to the preferential transport of the forest soil organic matter over the wetland or an increased contribution of atmospheric input of tree leaf wax in the offshore sites. This study demonstrates that compound-specific δD analysis provides a useful approach for better understanding source and transport of terrestrial biomarkers in a C3 plant-dominated catchment.  相似文献   

15.
Transfer of organic carbon (OC) from the terrestrial to the oceanic carbon pool is largely driven by riverine and aeolian transport. Before transport, however, terrigenous organic matter can be retained in intermediate terrestrial reservoirs such as soils. Using compound-specific radiocarbon analysis of terrigenous biomarkers their average terrestrial residence time can be evaluated.Here we show compound-specific radiocarbon (14C) ages of terrigenous biomarkers and bulk 14C ages accompanied by geochemical proxy data from core top samples collected along transects in front of several river mouths in the Black Sea. 14C ages of long chain n-alkanes, long chain n-fatty acids and total organic carbon (TOC) are highest in front of the river mouths, correlating well with BIT (branched and isoprenoid tetraether) indices, which indicates contribution of pre-aged, soil-derived terrigenous organic matter. The radiocarbon ages decrease further offshore towards locations where organic matter is dominated by marine production and aeolian input potentially contributes terrigenous organic matter. Average terrestrial residence times of vascular plant biomarkers deduced from n-C29+31 alkanes and n-C28+30 fatty acids ages from stations directly in front of the river mouths range from 900 ± 70 years to 4400 ± 170 years. These average residence times correlate with size and topography in climatically similar catchments, whereas the climatic regime appears to control continental carbon turnover times in morphologically similar drainage areas of the Black Sea catchment. Along-transect data imply petrogenic contribution of n-C29+31 alkanes and input via different terrigenous biomarker transport modes, i.e., riverine and aeolian, resulting in aged biomarkers at offshore core locations. Because n-C29+31 alkanes show contributions from petrogenic sources, n-C28+30 fatty acids likely provide better estimates of average terrestrial residence times of vascular plant biomarkers. Moreover, sedimentary n-C28 and n-C30 fatty acids appear clearly much less influenced by autochthonous sources than n-C24 and n-C26 fatty acids as indicated by increasing radiocarbon ages with increasing chain-length and are, thus, more representative as vascular plant biomarkers.  相似文献   

16.
During the last decade, compound-specific hydrogen isotope analysis of plant leaf-wax and sedimentary n-alkyl lipids has become a promising tool for paleohydrological reconstructions. However, with the exception of several previous studies, there is a lack of knowledge regarding possible effects of early diagenesis on the δD values of n-alkanes. We therefore investigated the n-alkane patterns and δD values of long-chain n-alkanes from three different C3 higher plant species (Acer pseudoplatanus L., Fagus sylvatica L. and Sorbus aucuparia L.) that have been degraded in a field leaf litterbag experiment for 27 months.We found that after an initial increase of long-chain n-alkane masses (up to ∼50%), decomposition took place with mean turnover times of 11.7 months. Intermittently, the masses of mid-chain n-alkanes increased significantly during periods of highest total mass losses. Furthermore, initially high odd-over-even predominances (OEP) declined and long-chain n-alkane ratios like n-C31/C27 and n-C31/C29 started to converge to the value of 1. While bulk leaf litter became systematically D-enriched especially during summer seasons (by ∼8‰ on average over 27 months), the δD values of long-chain n-alkanes reveal no systematic overall shifts, but seasonal variations of up to 25‰ (Fagus, n-C27, average ∼13‰).Although a partly contribution by leaf-wax n-alkanes by throughfall cannot be excluded, these findings suggest that a microbial n-alkane pool sensitive to seasonal variations of soil water δD rapidly builds up. We propose a conceptual model based on an isotope mass balance calculation that accounts for the decomposition of plant-derived n-alkanes and the build-up of microbial n-alkanes. Model results are in good agreement with measured n-alkane δD results. Since microbial ‘contamination’ is not necessarily discernible from n-alkane concentration patterns alone, care may have to be taken not to over-interpret δD values of sedimentary n-alkanes. Furthermore, since leaf-water is generally D-enriched compared to soil and lake waters, soil and water microbial n-alkane pools may help explain why soil and sediment n-alkanes are D-depleted compared to leaves.  相似文献   

17.
We have developed a new approach to quantitatively reconstruct past changes in evaporation based on compound-specific hydrogen isotope ratios of vascular plant and Sphagnum biomarkers in ombrotrophic peatland sediments. We show that the contrast in H isotopic ratios of water available to living Sphagnum (top 20 cm) and in the rooting zone of peatland vascular plants can be used to estimate “?”—the fraction of water remaining after evaporation. Vascular plant leaf waxes record H isotopic ratios of acrotelm water, which carries the D/H ratio signature of precipitation and is little affected by evaporation, whereas the Sphagnum biomarker, C23n-alkane, records H isotopic ratios of the water inside its cells and between its leaves, which is strongly affected by evaporation at the bog surface. Evaporation changes can then be deduced by comparing H isotopic ratios of the two types of biomarkers. We calibrated D/H ratios of C23n-alkane to source water with lab-grown Sphagnum. We also tested our isotopic model using modern surface samples from 18 ombrotrophic peatlands in the Midwestern United States. Finally, we generated a 3000-year downcore reconstruction from Minden Bog, Michigan, USA. Our new record is consistent with records of other parameters from the same peatland derived from different proxies and allows us to differentiate precipitation supply and evaporative loss.  相似文献   

18.
Peatlands are widespread and important natural archives of environmental change. Here we explore the potential of the recently introduced MBT-CBT proxy (methylation index and cyclisation ratio of branched tetraethers) to estimate past annual mean air temperature (MAT) based on the distribution of bacterially-derived branched glycerol dialkyl glycerol tetraether (GDGT) membrane lipids in peat and coal. To this end, branched GDGTs in an ombrotrophic peat bog from Switzerland and three coal deposits of increasing maturity were analysed.For the surface of the bog, reconstructed annual MAT is higher than both measured annual MAT and measured in situ pore water temperature. Changes in the CBT ratio, considered a proxy for pH, with depth in the bog do not match with present day in situ pore water pH, but coincide with a peat stratigraphic boundary. This indicates that GDGTs down the bog profile are predominantly fossil and not derived from extant biomass. The MBT-CBT derived annual MAT record also shows a large drop at this stratigraphic boundary, which likely relates to past change in trophic status of the bog. Branched GDGTs are abundant in an immature lignite (vitrinite reflectance, Ro 0.25%), but occur in low amount in a slightly more mature coal (Ro 0.32%). Annual MAT could be reconstructed for the lignite alone and is higher than other proxy-based estimates from approximately the same time and location.Our results indicate potential for the application of the MBT-CBT proxy in peat and immature coals, but improved constraints on the effects of different types of peat on branched GDGT distributions as well as improved calibration of MAT estimates are needed before the method can be confidently applied.  相似文献   

19.
A 40 cm deep Sphagnum-dominated peat monolith from Bolton Fell Moss in Northern England was systematically investigated by lipid molecular stratigraphy and compound-specific δ13C and δD analysis using gas chromatography (GC), GC-mass spectrometry (GC-MS), GC-combustion-isotope ratio-MS (GC-C-IRMS) and GC-thermal conversion-IRMS (GC-TC-IRMS) techniques. 210Pb dating showed the monolith accumulated during the last ca. 220 yr, a period encompassing the second part of Little Ice Age. While the distributions of lipids, including n-alkan-1-ols, n-alkan-2-ones, wax esters, sterols, n-alkanoic acids, α,ω-alkandioic acids and ω-hydroxy acids, display relatively minor changes with depth, the cooler climate event was recorded in the concentrations of n-alkanes and organic carbon, CPI values of n-alkanes and n-alkanoic acids, and the ratio of 5-n-alkylresorcinols/sterols. Superimposed on the fossil fuel effect, the relatively cooler climate event was also recorded by δ13C values of individual hydrocarbons, especially the C23n-alkane, a major compound in certain Sphagnum spp. The δD values of the C29 and C33n-alkanes correlated mainly with plant composition and were relatively insensitive to climatic change. In contrast the C23n-alkane displayed variation that correlated strongly with recorded temperature for the period represented by the monolith, agreeing with previously reported deuterium records in tree ring cellulose spanning the same period in Scotland, Germany and the USA, with more negative values occurring during the second part of Little Ice Age. These biomarker characteristics, including the compound-specific δ13C and δD records, provide a new set of proxies of climatic change, potentially independent of preserved macrofossils which will be of value in deeper sections of the bog where the documentary records of climate are unavailable and humification is well advanced.  相似文献   

20.
Agricultural grasses cover a major part of the land surface in temperate agro-ecosystems and contribute significantly to the formation of soil organic matter. Crop-derived lipids are assumed to be responsible for fast carbon turnover in soils. Differences in lipid distribution patterns between crops following C3 and C4 photosynthesis pathways have rarely been described, but could be useful for source apportionment of crop-derived input into soils or sediments. The distribution of long chain n-carboxylic acids (C22, C24, C26) reveals significant differences between crop plants following either the C3 or the C4 photosynthetic carbon fixation pathway. The plant compartments leaves, stems and roots of C4 plants contain relatively large proportions (> 40%) of n-C24 carboxylic acid when compared to C3 plants. These reveal larger relative proportions of n-C22 and n-C26 acids, whose relative abundance is subject to change between different plant compartments and during the growing season. The carboxylic acid ratio [CAR = n-C24/(n-C22 + n-C26) carboxylic acids] provides distinct ratios for C4 (> 0.67) and C3 crops (< 0.67) and can thus be used as a molecular marker for the differentiation of crop plant biomass. In combination with the bulk stable carbon isotopic composition (δ13C) the CAR can be used as a tool for the estimation of the C4 derived carbon proportion in soils or sediments.  相似文献   

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