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1.
邱添  朱永峰 《矿床地质》2014,33(3):541-557
新疆西准噶尔萨Ⅰ金矿床由含金糜棱岩化石英菱镁岩和含金石英脉组成,矿体围岩为石英菱镁岩、碳酸盐-滑石片岩和蛇纹岩。根据岩相学研究,将萨Ⅰ金矿床的形成过程划分为5个阶段:黄铁矿-石英-碳酸盐阶段(Ⅰ)、自然金-辉砷镍矿-铬云母阶段(Ⅱ)、黄铁矿-碳酸盐-石英阶段(Ⅲ)、自然金-硫化物-石英阶段(Ⅳ)和碳酸盐阶段(Ⅴ)。阶段Ⅰ和阶段Ⅱ对应于石英菱镁岩经历的韧-脆性变形时期,其他3个阶段形成于脆性变形期间,反映出构造性质由挤压向拉伸环境转换的过程。阶段Ⅱ和阶段Ⅳ分别对应于Au-As和Au-Cu成矿作用。金矿化与石英菱镁岩经历的剪切变形过程相关。含金糜棱岩化石英菱镁岩的微量元素含量明显高于未变形的石英菱镁岩,说明剪切带流体输送了相关微量元素和成矿元素。在韧性变形向脆性变形转换过程中,流体压力骤降,含金络合物分解形成金矿。萨Ⅰ金矿床是产在糜棱岩化石英菱镁岩中的严格受剪切带控制的热液脉型金矿床。  相似文献   

2.
石英(滑石)菱镁岩是基性岩、超基性岩与富CO2流体反应形成的一套硅化-碳酸盐化蚀变岩,常伴生金、汞、菱镁矿、碱金属矿化而在国外备受关注,但国内相关研究较薄弱。巴尔蛇绿岩位于西藏阿里地区,石英菱镁岩主要出露在蛇绿岩体东北边界,出露厚度约20 m,近北西西向延伸数千米。本文系统研究了雅鲁藏布缝合带西段巴尔蛇绿岩边部石英菱镁岩矿物学及地球化学特征。根据尖晶石镜下特征,划分为两个阶段:一阶段石英菱镁岩中尖晶石稳定存在,二阶段石英菱镁岩中尖晶石几乎全部蚀变(代表更强程度蚀变作用)。石英菱镁岩主要地球化学组成为Si O2、Mg O及CO2,8件样品主量元素含量变化较大,Si O2/Mg O比值波动较大,反映石英菱镁岩形成为非等化学过程。蛇纹石化橄榄岩与石英菱镁岩有着相似微量元素分布规律,表明同源性,但两者仍有较明显差异:两阶段石英菱镁岩LREE都较地幔橄榄岩略富集,从地幔橄榄岩到两阶段石英菱镁岩,HREE先亏损再略富集。微量元素标准化图解中,Sr在橄榄岩与石英菱镁岩中都为正异常,其含量随蚀变强度增强而增加。此外,两阶段石英菱镁岩均无Au、Hg矿化。  相似文献   

3.
邱添  朱永峰 《岩石学报》2012,28(7):2250-2256
萨尔托海金矿产在达拉布特蛇绿混杂岩带中。本文首次在该金矿区厘定出韧性剪切带,糜棱岩或者糜棱岩化石英菱镁岩中构成糜棱面理的矿物(铬云母、石英)形成于韧性剪切变形过程中,而切割糜棱面理的方解石-石英-黄铜矿-白云母脉代表脆性变形阶段的流体活动。根据矿物组合相互切割关系,识别出三期构造变形:早期NE向韧性变形(形成铬云母-石英组合)之后,发生了应力方向显著不同的破裂,形成NNW向分布的方解石-石英-黄铜矿-白云母脉;再晚期,应力方向又恢复到NE向,发育了浅层次的脆性构造破坏,形成了白云母-石英细脉。韧性剪切变形向脆性变形转换期间形成了石英-碳酸盐脉,其中往往含硫化物和自然金,此阶段是萨尔托海金矿的主要成矿时期。韧性剪切带控制着萨尔托海地区的金矿分布,成矿作用主要受沿剪切带迁移流体的控制,穿切糜棱面理的方解石-石英-黄铜矿-白云母脉是主要的找矿标志。韧性剪切带对金矿的显著控制表明,韧脆性转换期间形成的含硫化物石英碳酸盐脉以及相伴生的热液蚀变使金富集成矿,矿体一般赋存在断裂构造复杂的膨胀部位。萨尔托海金矿的成因与蛇绿岩的形成和演化没有关系。对韧性剪切带的系统研究是在该地区取得找矿勘探突破的关键。  相似文献   

4.
海南二甲金矿是一个与戈枕韧性剪切带活动明显相关的金矿床。利用构造地球化学方法和构造地球化学模拟试验 ,研究了戈枕韧性剪切活动与金成矿的关系 ,结果显示 :动力变形作用不仅导致混合岩发生明显的糜棱岩化 ,而且使矿物成分、化学成分发生明显变化 ,同时伴随着一定的构造岩流体活动。动力变形中岩石的变形机制可发现有多种 ,其中以恢复作用比较有利于糜棱岩中金的富集 ;由动态重结晶石英颗粒统计的差异古应力显示变形强度与Au富集有显著的正相关性 ,相关系数达 +0 .5 92 8。动力变形不同阶段形成的石英矿物其微量元素含量明显不同 ,石英中流体包裹体的成分也有明显的差异 ,反映出不同动力变形阶段流体活动的差异性与金富集密切相关。构造地球化学模拟试验表明 ,变形作用不仅导致岩石组构的变化 ,形成微型剪切带、碎粒流带等流动构造 ,而且伴随有明显的流体活动。这些过程与压溶作用密切相关 ;另外 ,动力作用中伴随着金的沉淀、富集 ,这其中Si、Fe组分起了重要的作用。  相似文献   

5.
玉峰金矿位于中亚造山带东天山东缘,是近年来新发现的含银高品位金矿床。该矿床目前已探明6个金矿体,均赋存在石英斑岩中。矿区热液蚀变作用发育,与成矿关系最密切的为黄铁绢英岩化和硅化,显示明显的蚀变分带:以石英硫化物脉为中心,黄铁绢英岩化带在其两侧大致对称分布。本文选取矿体上盘和下盘的石英斑岩、黄铁绢英岩进行了全岩的主、微量元素及成矿元素测试,并对其中的长石和绢云母进行电子探针成分分析。测试结果表明,黄铁绢英岩中的Au含量较蚀变前呈指数级增长,Ag、Cu、As等成矿元素大量增加,CaO、Na_2O、P_2O_5、P_2O_5、Sr、Pb、Th、U、Sb等元素显著迁出,而SiO_2、Al_2O_3、TiO_2含量和稀土元素含量变化较小,表现稳定。热液蚀变过程中,石英斑岩中71%~76%的正长石发生绢云母化,导致K_2O大量迁出;而钠长石几乎全部蚀变为绢云母,造成Na_2O大量迁出。热液流体的贡献使得蚀变岩中MgO、Fe_2O_3~T含量成倍增加,并主要富集在绢云母和/或黄铁矿晶格中。综合分析认为,绢英岩化蚀变带,Au、Cu、As和Bi等元素的综合化探异常,低电阻率、高激化率的地球物理特征可以作为玉峰矿区深部和外围找矿的标志。研究区内的石炭纪石英斑岩带,尤其是在构造叠加部位,热液活动使其更有利于矿化富集,是找矿勘探的有利部位。  相似文献   

6.
魏俊浩  张德全 《地质科学》1999,34(4):473-484
以河南西峡石板沟金矿为例,选择了一条控矿剪切带,对其中成矿地段的近矿蚀变岩和非成矿地段糜棱岩进行了系统的采样,探讨了二者在流体-岩石反应及岩石质量平衡之间的差异性。研究表明,剪切带中矿化地段蚀变岩其岩石体积总是扩容的,非矿化地段糜棱岩在变形过程中体积是损失的。矿化地段蚀变岩活性元素(K、Na、Si)总体呈被带入趋势,非矿化地段糜棱岩活性元素总体呈迁出趋势,糜棱岩的流体岩石率(Nu为93.68—468.40)远大于蚀变岩的流体岩石率(Nc(Ⅳ)s为36.11-216.67),剪切带中常量元素与微量元素富集与损失是渗透性流体带入、带出,岩石的体积损失与扩容综合作用的结果。  相似文献   

7.
蛇尾剪切带中糜棱岩的质量平衡分析表明:(1)以Al_2O_3守恒为限制条件,该剪切带损失了10%土的质量和体积,糜棱岩类有Na_2O,Zr,Sr的获得;SiO_2,TiO_2,FeO,Fe_2O_3,MgO,MnO,CaO,K_2O及Co,Ni,V,Cr,Cu,Y则损失了;(2)从初糜棱岩-糜棱岩,初糜棱岩-超糜棱岩和糜棱岩-超糜棱岩得出的质量等比线显示,糜棱岩类之间没有明显的质量和体积损失。糜棱岩组分的得失主要发生在初糜棱岩阶段,同初糜棱岩相比,糜棱岩、超糜棱岩有CaO的获得,FeO,MgO,TiO_2,Cr,Co,V,Y微弱的获得,Na_2O则有轻微的损失。  相似文献   

8.
中国金伯利岩地球化学   总被引:4,自引:0,他引:4  
董振信 《地球学报》1991,12(2):99-114
本文利用了100多个金伯利岩的主要元素及微量元素分析结果,用Si/Mg、C.l——(SiO_2+Al_2O_3+Na_2O)/(MgO+2K_2O)、Mg/(Mg+Fe)比值及SiO_2、Al_2O_3及Na_2O含量研究了金伯利岩的混染程度。结果表明,绝大部分金伯利岩受到了混染作用的影响,它们的成分实际上不能代表形成这些岩石的岩浆的成分。金伯利岩的Al_2O_3和Na_2O的含量比其他碱性超基性及基性岩石的Al_2O_3和Na_2O含量低得多。含金刚石的金伯利岩比不含金刚石的金伯利岩的MgO、(Cr_2O_3+NiO)高,而TiO_2+Al_2O_3+Na_2O+K_2O+P_2O_5低。 我国金伯利岩中Cr-Al,Ni-Co,Ni-Cr,Ni-V,Sc-Ti,Zn-Ti,Ba-Sr,Zr-Hf,Nb-Ta,U-Th,K-Rb呈正相关关系。  相似文献   

9.
与韧性剪切带有关的金矿化类型主要有蚀变糜棱岩型、构造蚀变岩型和石英脉型。不同金矿化类型具有不同的控矿构造类型,蚀变糜棱岩型金矿化受韧性变形带控制,构造蚀变岩型金矿化受脆性碎裂岩控制,石英脉型金矿化则受浅部裂 隙带控制;未矿化糜 棱岩变形越强,金元素含量就越低,超糜棱岩明显低于粗糜 棱岩,但强烈变形的糜 棱岩容易叠加后期的矿化蚀变;在时空关系上,同一厉矿期内石英脉型金矿化稍晚于构造蚀变岩型和蚀变糜棱  相似文献   

10.
舒小超  刘琰  李德良  贾玉衡 《岩石学报》2019,35(5):1372-1388
霓长岩化作用是指碳酸岩(或碱性岩)流体对围岩的交代蚀变,它是碳酸岩型稀土(REE)矿床常见的蚀变类型,其所形成的岩石即为霓长岩。对霓长岩的深入研究可以鉴别碳酸岩体的存在,厘定碳酸岩岩浆(或流体)的地球化学性质及源区特征,这对于找寻碳酸岩相关的矿产资源(尤其是REE)以及剖析矿床成因机制有着重要的地质意义。川西冕宁-德昌稀土矿带是中国最重要的轻稀土矿带之一,包括牦牛坪超大型、大陆槽大型、木落寨和里庄中小型REE矿床以及一系列矿点。REE矿化与碳酸岩-碱性岩杂岩体密切相关,受一系列新生代走滑断裂的控制。该矿带广泛发育霓长岩化蚀变带,尤以大陆槽及里庄矿床为显著。岩相学分析表明,大陆槽和里庄霓长岩中的矿物多呈他形粒状结构,主要由长石、黑云母、霓辉石以及少量副矿物组成;主微量元素分析表明,霓长岩的碱质(K_2O+Na_2O)、MgO、Fe_2O_3T含量较高,且富集REE、Sr、Ba等微量元素;电子探针分析表明,霓长岩中的霓辉石Fe OT含量较高,长石Na_2O及K_2O含量较高,Ca O含量极低。An-Ab-Or三角图解显示长石主要为透长石和钠长石,属碱性长石系列;黑云母的地球化学成分图解表明云母的成因类型为交代型且具有相对富镁、贫铁等特征,属镁质黑云母。霓长岩化作用的交代流体含有较高的CO_2组分,且富含碱质、Mg、Fe及REE、Sr、Ba等元素。对比霓长岩与原岩的主微量元素发现:相比于正长岩原岩,在主量元素中,霓长岩的Fe、Mg、Ca等元素含量增加,Si、Al等元素含量降低;微量元素中,霓长岩的REE及Sr、Ba等元素显著增加。这意味着交代流体含有的Fe_2O_3T、MgO、CaO等组分在霓长岩化过程中被带进了围岩,而SiO_2和Al_2O_3等从围岩中被逐出。大陆槽及里庄矿区发育的角砾岩指示了矿区曾经历过频繁的角砾岩化事件,这提高了霓长岩作用的强度,并且为矿脉的穿插及REE矿物的沉淀提供了空间。在霓长岩化过程中,流体-围岩的组分交换反复发生,这削弱了REE络合物的稳定性,伴随多期次的热液活动及构造事件,最终完成REE活化→迁移→沉淀的过程。  相似文献   

11.
煎茶岭金镍矿田构造特征及控岩控矿作用探讨   总被引:1,自引:0,他引:1  
聂江涛 《地质与勘探》2012,48(1):119-131
[摘 要]煎茶岭含钴硫化镍矿床已进入开采阶段,金矿正进行外围找矿。因而,查明该金镍矿田构造特征并探讨控岩控矿作用尤为重要。笔者通过解析矿田构造、研究矿床特征及其构造地球化学等以后认为:煎茶岭矿田构造-热事件活动频繁,多期褶皱控制着地层展布,共轭区域韧性剪切带控制着岩体就位;构造地球化学特征表明韧性变形有利于元素的活化,韧脆性变形使元素迁移和富集;区域韧性剪切带和控矿韧脆性剪切带内有大量物质的带入带出,韧脆性控矿剪切带中糜棱岩化蛇纹岩型镍矿石中K2O、Cr 等元素含量相比区域韧性剪切带内蛇纹质糜棱岩明显减少,而Fe2O3 、FeO、P2O5 、LOI、MnO、SiO2 、CaO、Ni 和Co 为带入组分;韧脆性控矿剪切带对金镍矿体的形态、产状和矿石的结构构造有明显的控制作用。因此,煎茶岭金镍矿田岩(矿)石受多期褶皱、区域共轭韧性剪切带和控矿韧脆性剪切带共同控制,金镍矿体表现为韧性剪切带、超基性岩体和花岗斑岩体等酸性岩体(脉) 共同作用的“三位一体冶成矿模式。金矿在共轭韧性剪切带相互交叉部位,绕超基性岩呈“金项链冶分布。镍矿位于以花岗斑岩为核的“σ”型“旋转碎斑系”拖尾内韧脆性剪切带之中。脆性断裂生成较晚,并对地层、岩体和矿体有一定破坏作用。  相似文献   

12.
孔玉金矿区地处川滇构造带北缘,是大渡河金矿田的组成部分之一;矿体主要赋存于盖层泥盆系黑色岩系中,已有的年龄数据分别有13.2 Ma、9.55 Ma,代表喜马拉雅期成矿。川滇构造带历经中、新元古代和显生宙2个巨型构造旋回,矿床的形成叠加了被动大陆边缘、活动大陆边缘交替历史条件下岩石圈的伸展、裂陷和收缩、碰撞造山作用,发育大量韧性-脆韧性剪切带构造,成矿地球动力学环境极其复杂。矿床的动力变形样式与构造活动阶段并非同步发育,矿化就位时代滞后于赋矿围岩的剪切变形时代;构造运动控制了元素在地壳中的分布和分配,在含矿岩系中氧化物含量除SiO_2、Fe_2O_3显著偏高外,其他氧化物含量如K_2O、CaO、Al_2O_3、MgO、FeO等均明显偏低,构造地球化学特征表现为富Si、Fe,贫Na、K;依据元素在不同构造类型和单元中分配的规律性,区内成矿有用组分的分散和富集过程可分为矿源层、变质热液初步富集和成矿作用3个阶段。  相似文献   

13.
Serpentinites in the Eastern Desert of Egypt are the most distinctive lithological unit in the Arabian–Nubian Shield (ANS) ophiolite sequence which associated with major suture zones. Khor Um-Safi (KUS) serpentinites represent dismembered fragments of ophiolitic rocks located in the central Eastern Desert (CED) of Egypt.KUS serpentinites exhibit affinity to the typical metamorphic peridotites with harzburgitic protolith compositions. Their opaque mineral assemblage (pentlandite, heazlewoodite and magnetite) is similar to that observed in oceanic serpentinites and implies serpentinization under highly reducing conditions. They have refractory major element compositions with Al2O3 contents comparable to oceanic and active margin peridotites as well as Pan-African serpentinites. The Cr and TiO2 contents reflect evolution within a supra-subduction zone (SSZ) environment. This implication is confirmed by the Al2O3/SiO2 and MgO/SiO2 ratios which akin to ANS ophiolitic peridotites in fore-arc setting. Their enrichment in compatible trace elements (Cr, Ni and Co) reveals a depleted mantle peridotite protolith.Modelling trace elements indicates that they represent the mantle residues from 15 to 20 % melting of spinel peridotite at oxygen fugacity conditions of the QFM + 1 buffer. This range of melt extraction is consistent with the typical range of SSZ peridotite. Oxygen fugacity estimation suggests evolution under more oxidizing regime similar to modern fore-arc basin system. Moreover, this implication indicates that the KUS mantle represents arc lithosphere interacted with arc melt.  相似文献   

14.
The late Cretaceous-lower Tertiary hydrothermal alteration of serpentinized peridotite in the Semail ophiolite has formed two distinct types of listwaenite. Type I is characterized by the presence of calcite (Type IA) or dolomite (Type IB)+fuchsite±spinel. Type II is dominated by silicate minerals (quartz, chlorite, fuchsite)±calcite+dolomite±magnetite±apatite±plagioclase. Most listwaenites occur as veins along thrust fault zones within the ophiolite mélange. High Cr and Ni contents, abundant occurrence of Cr-spinel within a matrix of red-brown ferruginous carbonates within a micro-vein network of goethite, and the relics of mesh texture indicate an ultramafic protolith. Type I and II listwaenites represent different stages of hydrothermal alteration. The mineralogical and chemical distinctions of both types are the response to the extent of the reactions between the protoliths and the solutions leading to different stages of metasomatic replacement. The hydrothermal fluids involved in the formation of Type I listwaenite were enriched in Ca, Mg, and CO2, whereas Type II listwaenite bodies were formed from a hydrothermal fluid enriched in SiO2. REE and trace elements in both listwaenite types were extracted in part from adjoining peridotite. No Au anomaly in the study areas has been detected.  相似文献   

15.
Al_2O_3和Ti在风化和热液蚀变等地球化学过程中通常被认为是不活动元素,两者的比值Al_2O_3/Ti常被用来指示地球化学作用过程。通过对中国157件火成岩样品元素含量平均值的统计发现,火成岩样品中Al_2O_3/Ti与SiO_2含量值之间存在着较好的幂函数关系:ln(Al_2O_3/Ti)=0.073×SiO_2-0.89,式中Al_2O_3和SiO_2和Ti含量单位均为%。本文基于得到的经验方程和TAS图解构建了一个新的判别岩石类型的图解——Al_2O_3-Ti图解。该图解可以区分酸性岩、中酸性岩、中性岩、中基性岩-基性岩四类岩性。通过对三个火成岩风化剖面的研究发现,花岗岩风化剖面从新鲜基岩到风化形成的土壤在Al_2O_3-Ti图解中均落在酸性岩区,花岗闪长岩风化剖面从新鲜基岩到风化形成的土壤样品均落在中酸性岩区,玄武质安山岩风化剖面从新鲜基岩到风化形成的土壤样品均落在中基性岩-基性岩区。不同风化程度的风化产物与其母岩在Al_2O_3-Ti图解中所在的区域一致,即Al_2O_3-Ti图解可以用来追溯火成岩风化产物的母岩岩性。通过对胶东焦家金矿和豫西牛头沟金矿两个矿区岩石的研究发现,黑云母花岗岩从新鲜岩石到其蚀变岩及其形成矿石的样品在Al_2O_3-Ti图解中均落在酸性岩区。玄武质安山岩从新鲜岩石到其蚀变岩及其形成矿石的样品在Al_2O_3-Ti图解中均落在中基性岩-基性岩区。即不同蚀变程度的蚀变产物与其原岩在Al_2O_3-Ti图解中所在的区域一致,这表明新构建的Al_2O_3-Ti图解可以用来示踪蚀变岩的原岩性质。  相似文献   

16.
ABSTRACT

The Bir Umq ophiolite is one of the most important ophiolitic successions in the Arabian Shield, and represents an excellent case for the study of the tectonomagmatic evolution of the earliest Precambrian events in the juvenile part of the Arabian-Nubian Shield (ANS). It is a dismembered ophiolite, which includes a serpentinized peridotite with small amounts of gabbro and mélange, and is overlain by the Sumayir formation. The mantle section of the Bir Umq ophiolite has been pervasively sheared and folded during its emplacement and is extensively serpentinized, carbonated and silicified, resulting in the common development of magnesite and listwaenite along the shear zones. Listwaenite occurs in the form of upstanding ridges due to its resistance to erosion. Antigorite is the main serpentine mineral, which, however, has low amounts of lizardite and chrysotile, indicating that the present serpentinites formed by prograde metamorphism. The ophiolitic rocks of Bir Umq have undergone regional metamorphism up to the greenschist to amphibolite facies. The presence of mesh and bastite textures indicates harzburgite and dunite protoliths. The serpentinized peridotite preserves rare relicts of primary minerals such as olivine, pyroxene and Cr-spinel. The serpentinized ultramafics of Bir Umq have high Mg# [molar Mg/(Mg+Fe2+); 0.90–0.93), low CaO, and Al2O3 contents similar to that of the environment of the suprasubduction zone. Additionally, they are characterized by the depletion of some compatible trace elements (e.g., Nb, Sr, Ta, Zr, Hf and REE), but show a wide variation in the Rb and Ba. Moreover, they are enriched in some elements that have affinities for Mg-rich minerals such as Ni, Cr, V, and Co. Fresh relics of olivine have high Fo (av. 0.91) and NiO (av. 0.42) contents, similar to those in the mantle olivine. The fresh Cr-spinel has high Cr# (0.68) and low TiO2 content (av. 0.11), similar to those in modern fore-arc peridotites. The composition of both orth- and clinopyroxenes confirms the fore-arc affinity of the studied ultramafics. The present study indicates that the protoliths of the serpentinized ultramafics of Bir Umq have high partial melt degrees, which is consistent with the characteristics of ultramafic rocks formed in a subarc environment (fore-arc) within a suprasubduction zone system.  相似文献   

17.
刘贵  周永胜  宋娟  何昌荣 《岩石学报》2012,28(3):1005-1016
本文以高温高压条件下石英闪长岩流变实验样品为研究对象,利用偏光显微镜进行微观结构观察,研究了样品在实验温度压力条件下的变形机制与斜长石结构对流变强度的影响;通过透射电镜能谱与电子探针,分析了熔体分布和成分特征,讨论了角闪石脱水熔融的影响因素与脱水熔融对岩石流变的影响。结果表明,随着温度升高,岩石从脆塑性过渡域逐渐向高温位错攀移和动态重结晶为主的塑性域转化。在高温条件下,角闪石出现了脱水与部分熔融,脱水熔融的熔体分布和成分体现出非均匀与非平衡熔融的特点,空间分布上,熔体主要出现在角闪石和黑云母矿物颗粒的边缘以及角闪石和长石颗粒之间的区域内;成分分布上,熔体的成分与参与熔融的矿物成分密切相关。角闪石边缘的熔体和黑云母边缘的熔体具有低硅铝、高铁镁特征,斜长石边缘的熔体具有高硅铝、低铁镁的特征,处于角闪石和斜长石颗粒中间的熔体,其成分间于斜长石与角闪石成分之间。实验中出现的非平衡非均匀部分熔融可以解释混合岩中的浅色体与暗色体的成因,富硅熔体可以形成富硅铝的花岗质岩石,而贫硅富铁镁的熔体可以形成基性岩。角闪石的脱水熔融程度依赖于样品的封闭条件,处于封闭环境的样品,角闪石不易脱水熔融,而处于开放环境时,角闪石脱水熔融显著。拆离断层带及其附近具备这样的开放环境,有利于角闪石发生脱水熔融。实验力学数据和微观结构显示,随机分布的斜长石对岩石强度影响并不明显,但斜长石的长轴方向与最大主应力方向呈大角度相交(近90°)会显著强化岩石的强度,这意味着岩石组构与主应力方向大角度相交或呈垂直方向时,不利于岩石变形和拆离断层的形成,反之,均匀岩石或岩石组构与最大主应力方向小角度相交,有利于岩石的变形,容易发育拆离断层。  相似文献   

18.
The National Centre for Compositional Characterisation of Materials (NCCCM) / Bhabha Atomic Research Centre (BARC) and National Aluminium Company Limited (NALCO), India have produced an Indian origin bauxite certified reference material (CRM), referred to as BARC-B1201, certified for major (Al2O3, Fe2O3, SiO2, TiO2, loss on ignition - LOI) and trace contents (V2O5, MnO, Cr2O3, MgO). Characterisation was undertaken by strict adherence to ISO Guides. A method previously developed and validated in our laboratory, using single step bauxite dissolution and subsequent quantitation (of Al2O3, Fe2O3, SiO2, TiO2, V2O5, MnO, Cr2O3 and MgO) by ICP-AES (SSBD ICP-AES) was used for homogeneity studies and an inter-laboratory comparison exercise (ILCE) of the candidate CRM. LOI was determined by thermo-gravimetric analysis. Property values were assigned after an ILCE with participation from seventeen reputed government and private sector laboratories in India. The CRM was certified for nine property values: Al2O3, Fe2O3, SiO2, TiO2, V2O5, MnO, Cr2O3, MgO and LOI, which are traceable to SI units.  相似文献   

19.
The Songshugou mylonitized peridotites within the Qinling Group metamorphic rocks in Central China are distributed in the northern part of the Shang-Dan Suture Zone (SDSZ) and contain abundant dunites and harzburgites. The dunites were intensely deformed and mylonitized converting the coarse-grained type to medium- and fine-grained types which contain prominent lenticular structure and relict olivine (Ol) porphyroclasts. Mineralogical and geochemical compositions suggest that the protoliths of the mylonitized peridotites were coarse-grained peridotites of lithospheric mantle origin. The harzburgites occur as enclaves within mylonitic peridotites in the form of lenses or veins. The orthopyroxenes in harzburgites were formed at the expense of Ol and have similar compositions to those of metasomatized harzburgites, characterized by low Al2O3, CaO and Cr2O3 contents. The harzburgites exhibit the gently U-type REE patterns with enriched incompatible elements (Rb, Ba, Sr, Zr and Hf), suggesting the metasomatic origin. The obvious ductile deformation of the large porphyroclastic orthopyroxene (Opx) suggests that the metasomatism occurred before the deformation. Ductile shearing deformation is indicated by the small fold structures and net-style ductile shearing zones within the Songshugou peridotite massif. The process is also result in the alignment of elongated Ol grains from initially coarse-granular via porphyroclastic to fine-granular texture. The relatively low Fo olivine, together with high Al2O3, and CaO contents and the abnormally low total PGE abundance in the fine-grained dunites suggest the ingress of melt/fluid during the mylonitization. The presences of significant amount of amphibole in the peridotites indicate the ingress of hydrous fluids. In general, the Songshugou peridotites have similar compositional characteristics with peridotites of Oman and Troodos ophiolites which are fragments of oceanic lithosphere mantle. One coarse-grained dunite has a TRD age of 875 Ma. Additionally two stages Paleozoic TRD ages are obtained from medium-grained and fine-grained dunites (491 Ma and 550 Ma; 446 Ma and 476 Ma). The broadly coeval nature of mylonitization with progressive metamorphism of surrounding amphibolites suggested that the Songshugou peridotites were generated before the early Paleozoic deformation. Our data, combined with the previous work on the surrounding HP/UHP metamorphic rocks, demonstrate that the Songshugou mylonitized peridotites represent fragments of the Neoproterozoic fossil oceanic lithospheric mantle that experienced extensive deformation during the Early Paleozoic subduction processes.  相似文献   

20.
The object of this study is to establish the nature of geochemical alteration in the wall rocks of the Selbaie Cu-Zn-Ag deposit, and to ascertain whether bedrock geochemistry could be applied in exploration for deposits of this type. The Selbaie Cu-Zn-Ag deposit, in northwestern Quebec, is atypical of base-metal deposits in the Canadian Shield, as mineralization occurs in epigenetic veins and as disseminations in volcanic wall rocks, rather than as syngenetic massive sulfide bodies which have been the focus of extensive comparable studies in the past. The deposit comprises three mineralized zones in felsic tuffs and quartz porphyry. Two of these, the A1 and A2 zones, which are the focus of the present study consist of quartz-carbonate veins containing chalcopyrite, sphalerite, and pyrite, and accessory sulfide minerals. The B zone is not considered in this study. Samples of drill core were collected from sections crossing the A1 and A2 zones and analyzed for total Si, Al, Fe, Mg, Ca, Na, K, Ti, Mn, P, and S by X-ray fluorescence, and for aqua-regia-extractable Cu, Zn, Ni, Pb, Fe, and Mn by atomic absorption. Although the distribution of individual element concentrations is clearly related to bedrock type, rocks proximal to mineralization have higher SiO2, Fe2O3, Cu, Zn, Fe, and S contents, and lower Al2O3 and K2O contents, than rocks more distal from mineralization. MgO content shows an irregular distribution and may also increase toward mineralization. CaO and Na2O contents are very low in all pyroclastic rocks.In order to take into account the effect of bedrock type, linear regression analysis was performed on the data to estimate the normal concentration of individual elements using SiO2 contents as the predicted variable. Spatial distributions of residual values of element concentrations indicate that rocks close to mineralization have higher residual Fe2O3, Cu, Zn, Pb, and Fe contents, and lower residual Al2O3 and K2O contents, compared to rocks more remote from mineralization. These distribution patterns are clearer than in the case of the single-element data but variations between element responses still exist in some instances. In an attempt to overcome the variation in patterns revealed by some element distributions, discriminant analysis was undertaken to see whether mineralized areas could be distinguished on the basis of an element association. Discriminant functions were calculated for data from areas adjacent to mineralization, and from areas remote from mineralization. Areal distribution of discriminant scores outlined an anomalous area extending up to 200 m beyond the mineralization. Petrographic studies of selected samples correlated high SiO2 and low Al2O3 content with silicification in the most altered rocks adjacent to mineralization. High Fe2O3, MgO, and extractable Fe concentrations were found to occur in chlorite- and carbonate-rich zones. Samples rich in S, Cu, Zn, and b, and to a lesser extent Fe, were characterized by the presence of sulfides. High concentrations of Al2O3 and K2O relative to that of SiO2 are typical of sericitization. On this basis, the results demonstrate that anomalously high or low concentrations of element associations, revealed by discriminant analysis, occur in large coherent zones exceeding the size of the deposit. The procedure is potentially useful as an exploration guide for epigenetic disseminated and vein-type base-metal styles of mineralization as well as the syngenetic massive sulfide type of deposits that have been extensively studied in the past.  相似文献   

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