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1.
王敏  王居里  胡洋  王建其 《岩石学报》2018,34(3):618-636
谢米斯台地区位于新疆西准噶尔北部,该地区中酸性岩浆活动强烈。本文对谢米斯台地区乌兰萨拉岩体进行了地质、地球化学、年代学及全岩Sr-Nd和锆石Hf同位素研究。结果表明,乌兰萨拉岩体是一个由碱长花岗岩和花岗闪长岩组成的复式岩体。碱长花岗岩形成时代为晚志留世(422.7±2.0Ma),岩石高硅、富碱,属于准铝质-弱过铝质高钾钙碱性花岗岩;球粒陨石标准化配分模式图显示"V"字型配分样式,Eu负异常强烈,相对富集Ga、K、Rb、Th、U和Pb,亏损Ba、Sr、P、Ti、Cr和Ni等;岩石具有低(~(87)Sr/~(86)Sr)i值(0.7017~0.7038),正的ε_(Nd)(t)值(+4.49~+6.58)和锆石ε_(Hf)(t)值(+10.0~+14.2),Hf同位素模式年龄(t_(DM2))为500~771Ma。花岗闪长岩形成时代为早泥盆世(411.7±1.7Ma),属于准铝质,高钾钙碱性-钾玄岩系列花岗岩;球粒陨石标准化配分模式图显示右倾型配分样式,无明显Eu异常,相对富集LREE、LILE(Rb、Ba、K)、Th、U和Pb,亏损Nb、Ta、P和Ti等;岩石具有低的(~(87)Sr/~(86)Sr)i值(0.7041~0.7046),正的ε_(Nd)(t)值(+1.66~+3.87)和锆石ε_(Hf)(t)值(+4.4~+13.9),Hf同位素模式年龄(t_(DM2))为516~1120Ma,岩石Nd同位素和锆石Hf同位素出现一定程度的解耦。综合研究认为,乌兰萨拉岩体碱长花岗岩属A_2型花岗岩,花岗闪长岩属I型花岗岩,两者都是由新生下地壳发生部分熔融而形成,前者经历了一定程度的分离结晶作用,后者受到亏损玄武质岩浆(俯冲板片脱水交代地幔楔产生的上涌岩浆)的底侵,它们均形成于陆缘弧环境。  相似文献   

2.
北山柳园地区分布大量的花岗岩类岩石,岩石类型有花岗闪长岩、二长花岗岩、钾长花岗岩和斑状花岗岩。锆石SHRIMP U—Pb 定年分析结果为:花岗闪长岩的侵位年代为423±8Ma 辉铜山以东(HT-)钾长花岗岩和二长花岗岩的侵位分别为436±9Ma 和397±7Ma。该区花岗质岩石都具有大离子亲石元素和轻稀土元素相对富集,K、Ni、Ta、P 和 Ti 负异常的特征,属于准铝质到过铝质的高 K 花岗岩。花岗闪长岩无 Sr 和 Eu负异常的特征,ε_(Nd)(t)=-2.5~-0.8,其岩浆源于岩石圈地幔或是软流圈与岩石圈地幔相混合的岩浆熔融,并受到了含有火山弧组分的年轻地壳的混染。钾长花岗岩和二长花岗岩具有 Sr 和 Eu 负异常的特征,ε_(Nd)(t)值分别为 1.4、-4.0~-2.0和-2.7~-0.3。HT-钾长花岗岩岩浆主要源于由于岩石圈地幔岩浆作用而导致上覆年轻地壳物质的部分熔融;花牛山附近(HN-)钾长花岗岩岩浆主要源于软流圈地幔部分熔融,可能受到了部分年轻地壳物质的混染;二长花岗岩岩浆主要源于年轻地壳的部分熔融。柳园地区4类花岗岩类岩石都是后碰撞构造背景下的岩浆产物,岩浆形成可能与俯冲板片断离有关。  相似文献   

3.
中国东南部南岭地区广泛出露以弱过铝质黑云母二长花岗岩和黑云母钾长花岗岩为主的燕山早期花岗质岩石,其成缮因有待进一步研究.大东山岩体岩性主要为黑云母二长花岗岩和黑云母钾长花岗岩,两个样品的SHRIMP锆石U-Pb年龄为165 4±2 Ma和159±2 Ma,与区域南岭系列的黑云母花岗岩的主要形成时代一致.花岗岩样品以高硅(SiO2>72%)、高钾(K2O/Na2O>1.6)、富碱(K2O Na2O=7.36%~9.31%)和弱过铝质(集中于ASI=1.00~1.11)为特征.微量和稀土元素组成上,岩体富Rh,Th和LREE,贫Ba,Nb,Sr,P和Ti,Eu负异常显著(δEu=0.06~0.34).多数样品的Zr,Ce,Nb和Y含量总和小于350×10-6,10000×Ga/Al值低于典型的A型花岗岩.同位素组成上,样品具有高Isr (0.7123~0.7193)和低εNd (t)(-9.3~-11.5)的特点,两阶段Nd模式年龄为1.70~1.89 Ga;与全岩εNd (t)不同,岩浆锆石的εHf (t)具有较大的变化范围(-3.5~-11.8).矿物学及地球化学结果表明大东山是一个高分异的Ⅰ型花岗岩岩体.岩体岩浆很可能是由元古代火成岩石部分熔融形成,并伴随有少量年轻或新生幔源物质的加入,岩浆上升侵位的过程中发生混合、结晶分异作用.  相似文献   

4.
王居里  胡洋  王敏  王建其 《岩石学报》2019,35(2):523-540
布拉特矿化次火山岩出露于谢米斯台中部,岩性主要为英安斑岩和流纹斑岩。本文通过锆石U-Pb年代学、岩石地球化学和Sr-Nd-Hf同位素等研究,探讨其形成的构造环境、成因及成矿意义。结果表明,英安斑岩形成年龄为434.9±2.3Ma,属高钾钙碱性-钾玄岩系列准铝质-强过铝质岩石;岩石稀土总量中等(∑REE=97.9×10~(-6)~107×10~(-6)),富集轻稀土且轻重稀土分异明显((La/Yb)_N=7.93~9.95),具较弱铕负异常(δEu=0.78~0.90),相对富集Rb、Th、U、K等元素,亏损Nb、Ta、P、Ti等元素;岩石具有低的(~(87)Sr/~(86)Sr)_i值(0.7036~0.7043)和正的ε_(Nd)(t)值(+2.64~+5.01),t_(DM1)(Nd)=750~930Ma。流纹斑岩形成年龄为423.2±0.9Ma,属高钾钙碱性-钾玄岩系列准铝质-强过铝质岩石;稀土总量中等(∑REE=65.3×10~(-6)~127×10~(-6)),富集轻稀土且轻重稀土分异明显((La/Yb)_N=6.82~8.24),具较强铕负异常(δEu=0.51~0.71),相对富集Rb、Th、U、K等元素,亏损Nb、Ta、P、Ti等元素;岩石具有低的(~(87)Sr/~(86)Sr)_i值(0.7022~0.7038)和正的ε_(Nd)(t)值(+2.86~+5.78),t_(DM1)(Nd)=680~940Ma;锆石ε_(Hf)(t)=+9.8~+14.9,t_(DM2)(Hf)=456~783Ma。综合研究表明,布拉特矿化英安斑岩和流纹斑岩是不同岩浆演化结晶的产物,二者都形成于活动大陆边缘弧环境,可能是新生下地壳部分熔融形成的花岗质岩浆与部分源自地幔楔的玄武质岩浆发生混合、向上运移、冷凝结晶的产物。较晚形成的流纹斑岩岩浆形成过程中新生下地壳部分熔融的比例有所降低,熔出的岩浆相对更偏酸性;谢米斯台地区以志留纪-早泥盆世火山岩、次火山岩和中酸性侵入体为代表的岩浆岩带为一个主体形成于早古生代的陆缘弧岩浆岩带,是形成和寻找斑岩型铜矿的有利地区。  相似文献   

5.
赵辉  李舢  王涛  王文志  焦永艳 《地质通报》2015,34(12):2203-2218
大兴安岭南段黄岗梁地区早白垩世碎斑熔岩和钾长花岗岩代表大兴安岭南段最广泛的一次岩浆活动产物,二者LA-ICPMS锆石U-Pb年龄都为137.7±1.2Ma。该地区岩石大都具有高硅、钾,贫钙、镁,低铝的特点,体现了高度演化的高钾钙碱性-碱性系列特点;铝饱和指数显示其为准铝质-弱过铝质花岗岩。岩石稀土元素总量为116.98×10-6~350.51×10-6,具有强烈的负Eu异常,富集大离子亲石元素(如Rb、Ba、Th、U等)及高场强元素(如Nd、Zr、Hf等),亏损Ba、Sr、P、Ti、Nb等强不相容元素,显示出高分异I型花岗岩的特征。研究区早白垩世岩浆岩具有较高的全岩εNd(t)值(-0.8~+0.9)和正的锆石εHf(t)值(+1.9~+18.3),以及年轻的Nd模式年龄(993~855Ma)和Hf模式年龄(888~561Ma),表明其来源于新生的陆壳,可能有少量古老陆壳物质的参与。综合区域地质资料及大兴安岭南段的岩浆演化特征,这些早白垩世岩浆作用应形成于区域性伸展的构造背景,主体可能与蒙古-鄂霍茨克洋构造体系下的后造山伸展垮塌有关。  相似文献   

6.
西秦岭赛什塘铜矿区内出露的三叠纪花岗质岩石有闪长玢岩、石英闪长岩、石英闪长玢岩、花岗斑岩和石英斑岩,其岩浆源区与形成构造环境可为古特提斯洋演化和区域成矿作用研究提供证据。岩石地球化学特征共同表明,这些花岗质岩石属于准铝质钙碱性-高钾钙碱性系列,为I型花岗岩;Mg#值变化较大(39~68),LREE富集,HREE亏损,(La/Yb)N比值介于8.50~22.9,具有Eu负异常,δEu介于0.28~0.78,同时富集大离子亲石元素Cs、Rb、K、Pb,亏损高场强元素Nb、Ta、Ti,呈现出与典型俯冲作用密切相关岛弧花岗岩相一致地球化学特征。石英闪长玢岩和石英斑岩SHRIMP锆石U-Pb年龄分别为219.0±2.3Ma和220.0±2.0Ma,锆石εHf(t)分别为-4.5~-2.1和-2.5~+1.0,对应二阶段模式年龄分别为1392~1544Ma和1190~1415Ma。结合前人对西秦岭三叠纪花岗岩以及其南侧阿尼玛卿蛇绿混杂带研究成果,本文认为赛什塘铜矿区花岗质岩石与西秦岭同时期花岗岩形成于与古特提斯洋向北俯冲密切相关的大陆边缘弧环境,其岩浆源区为中元古代下地壳变基性岩,且岩浆可能受到地幔物质混染。  相似文献   

7.
太古宙末期钾质花岗岩的广泛发育是陆壳成熟和稳定化的重要标志,对了解早期陆壳的形成与演化具有重要的意义.发育于华北克拉通南缘中条山地区涑水杂岩中的烟庄正长花岗岩的形成年龄和成因还没有被很好地限定,构造背景还存在争议.对烟庄花岗岩进行了锆石U-Pb年代学和Hf同位素以及全岩地球化学和Nd同位素研究.烟庄花岗岩锆石SHRIMP U-Pb年龄为2 515±7 Ma.岩石具有高硅(SiO2=73.05%~74.85%)、高钾(K2O=4.46%~5.86%)、富碱(ALK=8.32%~9.36%)、贫钙(CaO=0.55%~0.98%)、低TFeO*(0.73%~1.28%)和MgO(0.31%~0.52%)的特征,A/CNK=1.01~1.04,为弱过铝质的钾玄系列.稀土总量变化较大(ΣREE=63.80×10-6~250.02×10-6)),轻重稀土元素分异明显((La/Yb)N=25.44~92.87),Eu异常变化较大(Eu/Eu*=0.47~0.79).岩石低Sr、Ba,富集Rb、Th、U等元素,亏损Nb、Zr、Y、Yb、Cr、Co、Ni等元素,具有较高的Rb/Sr、Rb/Ba和Sr/Yb比值以及较低Sm/Nd和Nd/Th比值,具有高分异I型花岗岩的特征.烟庄花岗岩具有0附近的全岩εNd(t)值,岩浆锆石具有正的εHf(t)值(2.85~3.66),两阶段Hf模式年龄为2 258~2 883 Ma,多数在2 600~2 883 Ma之间.结合其他方面研究,烟庄花岗岩具有同碰撞和后碰撞花岗岩的特征,推测为新生地壳在由挤压向伸展转换的构造背景下部分熔融所形成,可能有少量地幔物质添加.这期钾质花岗岩的形成,标志着华北克拉通太古宙末期强烈岩浆活动的结束以及稳定陆壳的形成.   相似文献   

8.
松潘造山带马尔康强过铝质花岗岩的成因及其构造意义   总被引:2,自引:0,他引:2  
松潘造山带广泛出露印支期后碰撞型花岗岩类,其中包括埃达克质花岗岩类、A型花岗岩和I型花岗岩,但目前人们对该区印支期强过铝质花岗岩尚未有深入的研究.松潘造山带马尔康花岗岩属于强过铝质花岗岩(A/CNK=1.10~1.20),其岩石类型主要为中粒二云母花岗岩和中细粒二云母花岗岩.利用LA-ICP-MS锆石U-Pb定年方法,获得中粒二云母花岗岩的岩浆结晶年龄为208±2Ma,中细粒二云母花岗岩的岩浆结晶年龄为200±2Ma.马尔康强过铝质花岗岩K2O/Na2O=1.13~1.75,富Rb、Th和U,贫Sr、Ba、Co和Ni等元素;稀土元素组成上显示存在强到中等的负Eu异常(Eu/Eu*=0.15~0.65);全岩初始87Sr/86Sr比值(ISr)为0.70712~0.71137,εNd(t)=-10.36~-8.43,锆石εHf(t)=-11.8~-1.1.地球化学和Sr-Nd-Hf同位素组成一致表明,它们的岩浆来自于地壳物质的部分熔融,其中中粒二云母花岗岩的源岩类型主要为地壳中的泥质岩类,而中细粒二云母花岗岩的源岩主要为地壳中的杂砂岩类.结合松潘带的地质背景、区域构造-岩浆事件及其岩浆岩的组合分析,印支期岩石圈...  相似文献   

9.
以赣西地区蒙山岩体为研究对象,通过对该岩体地球化学、锆石U-Pb年龄及Hf同位素的研究,探讨其岩浆物质来源及构造背景。该岩体经历了印支期、燕山期岩浆侵入活动,形成六种岩石类型,LA-ICP-MS锆石U-Pb年龄分别为224.0±2.10 Ma(n=19,MSWD=1.9)、223.0±2.20 Ma(n=21,MSWD=2.6)、222.0±2.80 Ma(n=21,MSWD=2.7)、220.0±1.90 Ma(n=16,MSWD=1.5)、217.0±3.70 Ma(n=8,MSWD=1.8)、142.0±0.98 Ma(n=21,MSWD=1.4),表明岩体经历了印支期、燕山期两期岩浆活动。印支期花岗质岩石地球化学具高硅富钾、准铝-过铝质特征;微量元素富集高场强元素Zr、Hf、Th、U和稀土元素La、Ce、Sm、Nd、Y,明显亏损Rb、Ba、Sr、Ti、P;稀土元素分馏程度不高,δEu介于0.03~0.15,具强Eu负异常,Ce异常不明显,稀土配分曲线呈“V”型;为同源岩浆演化的特点。CaO/Na_(2) O比值<0.3、Rb/Sr>5,岩石二阶段模式年龄T DM2主体介于868~1465 Ma,为中-新元古代,εHf(t)对应的T DM2值显示,岩体物源起源于成熟地壳,后期有大量新生地壳物质的加入,表明岩石来源于含水矿物(如白云母、绿帘石/黝帘石)的脱水反应导致成熟度高地壳物质的熔融而形成。在花岗岩构造环境判别图上,投于碰撞大地构造背景上的花岗岩和造山后花岗岩类(POG)区域,锆石U-Pb年龄表明成岩时段滞后于印支运动高峰期(258~243 Ma),为受印支运动造成华南地壳加厚滞后,地壳进入伸展阶段,减压熔融形成的花岗质岩浆。  相似文献   

10.
在湘东北岳阳-平江-带分布有许多新元古代花岗岩体,对其中的张邦源岩体进行锆石sHRIMP U-Pb年龄测定,获得(816±4.6)Ma的年龄.花岗岩体岩石基性程度较高,SiO2平均为70.25%;低钾高钙,CaO平均为2_38%;全碱较低,Na2o+K2O平均为5.97%,且Na2O>K2O;ASI值平均1.16(0.97~1.29).总体属镁质过铝质钙碱性花岗岩系列.不相容元素RLb、Th含量较高,贫Ba和Nb.稀土元素总量较低,平均130μg/g;轻稀土相对富集,(La/Yb)N比值在6.76~8.50;铕亏损不明显,δEu值为0.54~0.78.εNd(t)值较高且变化范围较窄,为-1.5~1.6,T2DM1.35~1.60 Ga;δ18Ov-SMOW值为8.1‰~11.1‰.岩石具典型的Ⅰ型花岗岩或AcG型花岗岩特征,为壳-幔混合型成因,岩浆主要起源于亏损地幔源,并伴有地壳物质加入.地球化学特征显示为岛弧火山岩系,为会聚板块边缘(俯冲带)岩浆作用的产物,不具备地幔柱岩浆特性,不能作为Roinina超大陆裂解的标志.  相似文献   

11.
Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km2 and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.  相似文献   

12.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations.  相似文献   

13.
The contents of As, Cd, Cu, Cr, Mg, Mn, Ni, Pb and Zn have been determined in sediment and water samples from Valle de las Garzas estuary and Port Manzanillo (Colima, Mexico) using ICP-AES. The concentrations of these elements were used for a comparative study to determine the distribution of heavy metals and to evaluate which elements reflect natural or anthropogenic backgrounds. For this purpose, seven sampling points were selected: Four of them correspond to the lagoon, and three were situated in the port. Statistical analysis of the mineral content was assessed. Initially, data comparison was assessed by statistical tests for each variable. Principal component analysis was then applied considering the influence of all variables at the same time by obtaining the distribution of samples according to their scores in the principal component space. In this way, four studies were carried out: (1) study of sediments collected during the dry season; (2) study of sediments collected during the rainy season; (3) comparative study between sediments from rainy and dry season; and (4) study of water composition collected during rainy season. From the results of the performed analyses, it can be concluded that metals distribution pattern reflected natural and anthropogenic backgrounds (e.g., sediments from the lagoon, situated at the beginning of the rain channel, presented high contents of Zn and Cu, perhaps related to anthropogenic activities or the influence of igneous sediments).  相似文献   

14.
This article advances critical geographies of youth through examining the spatiality implicit in the imagined futures of young women in rural India. Geographers and other scholars of youth have begun to pay more attention to the interplay between young people’s past, present, and imagined futures. Within this emerging body of scholarship the role of the family and peer group in influencing young people’s orientations toward the future remain underexamined. Drawing on eleven months of ethnographic fieldwork, my research focuses on a first generation of college-going young women from socioeconomically marginalized backgrounds in India’s westernmost state of Gujarat. I draw on the “possible selves” theoretical construct in order to deploy a flexible conceptual framework that links imagined post-educational trajectories with motivation to act in the present. In tracing the physical movement of these young women as they navigate and complete college, my analysis highlights the ways in which particular kinds of spaces and spatial arrangements facilitate and limit intra- and inter-generational contact, and the extent to which this affects young women’s conceptions of the future. I conclude by considering the wider implications of my research for ongoing debates surrounding youth transitions, relational geographies of age, and education in the Global South.  相似文献   

15.
16.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2.  相似文献   

17.
Partition coefficients of Hf,Zr, and REE between zircon,apatite, and liquid   总被引:25,自引:2,他引:25  
Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite.  相似文献   

18.
Models have become so fashionable that many scientists and engineers cannot imagine working without them. The predominant use of computer codes to execute model calculations has blurred the distinction between code and model. The recent controversy regarding model validation has brought into question what we mean by a ‘model’ and by ‘validation.’ It has become apparent that the usual meaning of validation may be common in engineering practice and seems useful in legal practice but it is contrary to scientific practice and brings into question our understanding of science and how it can best be applied to such problems as hazardous waste characterization, remediation, and aqueous geochemistry in general. This review summarizes arguments against using the phrase model validation and examines efforts to validate models for high-level radioactive waste management and for permitting and monitoring open-pit mines. Part of the controversy comes from a misunderstanding of ‘prediction’ and the need to distinguish logical from temporal prediction. Another problem stems from the difference in the engineering approach contrasted with the scientific approach. The reductionist influence on the way we approach environmental investigations also limits our ability to model the interconnected nature of reality. Guidelines are proposed to improve our perceptions and proper utilization of models. Use of the word ‘validation’ is strongly discouraged when discussing model reliability.  相似文献   

19.
The shape of sedimentary particles may carry important information on their history. Current approaches to shape classification (e.g. the Zingg or the Sneed and Folk system) rely on shape indices derived from the measurement of the three principal axes of the approximating tri-axial ellipsoid. While these systems have undoubtedly proved to be useful tools, their application inevitably requires tedious and ambiguous measurements, also classification involves the introduction of arbitrarily chosen constants. Here we propose an alternative classification system based on the (integer) number of static equilibria. The latter are points of the surface where the pebble is at rest on a horizontal, frictionless support. As opposed to the Zingg system, our method relies on counting rather than measuring. We show that equilibria typically exist on two well-separated (micro and macro) scales. Equilibria can be readily counted by simple hand experiments, i.e. the new classification scheme is practically applicable. Based on statistical results from two different locations we demonstrate that pebbles are well mixed with respect to the new classes, i.e. the new classification is reliable and stable in that sense. We also show that the Zingg statistics can be extracted from the new statistics; however, substantial additional information is also available. From the practical point of view, E-classification is substantially faster than the Zingg method.  相似文献   

20.
Pools,riffles, and channelization   总被引:2,自引:0,他引:2  
The addition of regularly spaced deeps (pools) and shallows (riffles) that provide a variety of flow conditions, areal sorting of stream-bed material, cover for wildlife, and a positive aesthetic experience, may be desirable in many channel projects. Such designs will reduce adverse environmental impacts of stream channel modifications. Analysis of variance for pool-to-pool spacing data suggests that there is no significant difference with respect to channel width between pools that form in natural streams and those in streams affected by a variety of human uses. Short of channelization, which changes the channel width, pools and riffles, within limits, are not particularly sensitive to environmental stress. Experiments in Gum Branch near Charlotte, North Carolina, support the hypothesis that channel form and process evolve in harmony and that manipulation of cross-channel morphology can influence the development of desired channel processes. Planned manipulation of its channel form induced Gum Branch to develop as desired. Morphologic stability consisting of incipient point bars, pools, and riffles was maintained over a period of high magnitude flood events, only to be degraded later by a wave of sediment derived from upstream construction and stream-bank failures. Thus, environmentally desirable channel morphology in urban streams cannot remain stable if changes in the sediment load or storm-water runoff exceed the limits of the stream's ability to make internal adjustments while maintaining morphologic stability.  相似文献   

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