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1.
为了探讨西藏墨竹工卡县洞中拉铅锌矿的成矿物质来源,研究矿床成矿机制,对该矿床的矿石样品进行了硫和铅同位素分析,并对其变化规律和成因意义进行讨论。研究结果表明,6件金属硫化物样品(闪锌矿、黄铜矿、方铅矿)的δ34S值变化于2.2‰~4.8‰之间,显示硫同位素组成比较稳定。根据共生硫化物对所确定的温度,该矿床属中低温热液矿床。6件金属硫化物样品206Pb/204Pb、207Pb/204Pb和208Pb/204Pb变化范围分别为18.628 0~18.629 6、15.698 0~15.699 9、39.077 5~39.082 4,平均值分别为18.628 70、15.699 02和39.079 37。硫和铅同位素研究结果表明,洞中拉铅锌矿床的硫主要来自沉积围岩,主要为无机还原成因,有少量硫来自本地区燕山晚期花岗岩;洞中拉铅锌矿床矿石铅主要来自上地壳物质。  相似文献   

2.
那更康切尔银矿是东昆仑造山带的大型热液脉型独立银矿床,有望达到超大型规模。以矿区地质特征为研究基础,开展硫化物硫-铅同位素、二长花岗岩和花岗闪长岩铅同位素研究,探讨成矿物质来源及两类岩体与成矿的关系。矿区硫化物样品(黄铁矿、方铅矿和闪锌矿)的δ34S值介于-6.1‰~3.9‰之间,主体δ34 S值介于-4‰~2.1‰之间,数值集中,指示成矿物质硫源具有深源岩浆硫的特征。矿石铅同位素组成中206 Pb/204 Pb、207 Pb/204 Pb、208 Pb/204 Pb的变化范围分别为18.28~18.62、15.6~15.73、38.38~39.1,矿石铅具有壳幔混合源的特点。矿区内二长花岗岩LA-ICP-MS锆石U-Pb年龄为239±1 Ma,(206Pb/204Pb)i、(207Pb/204Pb)i、(208Pb/204Pb)i值分别为18.389~18.585、15.638~15.648、38.288~38.558;花岗闪长岩LA-ICP-MS锆石U-Pb年龄为252±1 Ma,(206Pb/204Pb)i、(207Pb/204Pb)i、(208Pb/204Pb)i值分别为18.348~18.447、15.625~15.629、38.394~38.412,铅同位素组成投图显示成矿与2类岩浆岩关系较弱,与区域上鄂拉山组火山岩呈较明显的线性相关。那更康切尔银矿与邻区哈日扎铅锌银矿床具有相似的成矿物质来源,硫源具有同一性,且矿石铅同位素组成表现出很明显的线性关系,表明2个矿床的成矿物质具有相近或相似的源区或演化过程。成矿地质条件、成矿物质来源及成矿流体特征均表明两者属中-低温热液脉型矿床。综合本文及前人对那更康切尔银矿床的研究,构建了成矿模式和找矿模型,为区域内同类型银矿床的找矿工作提供了指导作用。  相似文献   

3.
宝山铅锌矿床是湘南地区代表性矿床之一。宝山铅锌矿床的成矿作用与156~158 Ma的宝山花岗闪长斑岩密切相关。花岗闪长斑岩主要由古老地壳部分熔融而成。为确定成矿物质来源,文章系统研究了宝山铅锌矿床的硫、铅、碳、氧同位素组成特征。矿床中硫化物黄铁矿、闪锌矿、方铅矿的δ34S值呈狭窄的塔式分布,变化在-2.17‰~6.46‰之间,平均值为3.13‰。δ34S值总体表现为δ34S黄铁矿δ34S闪锌矿δ34S方铅矿,表明硫同位素分馏基本达到了平衡。矿石、花岗闪长斑岩和赋矿地层硫同位素对比研究表明,矿石中的硫主要由岩浆分异演化而来,岩浆中的硫主要来自古老地壳。矿石206Pb/204Pb、207Pb/204Pb和208Pb/204Pb比值分别为18.188~18.844、15.661~15.843和38.562~39.912,赋矿地层206Pb/204Pb、207Pb/204Pb和208Pb/204Pb比值分别为18.268~19.166、15.620~5.721和38.364~39.952。矿石铅同位素组成比地层中的更富放射性成因铅,矿石中部分铅来自宝山花岗闪长质岩浆,在成矿流体运移过程中有部分地层铅参与了成矿,岩浆中的铅主要来自古老地壳。热液方解石的碳、氧同位素组成介于岩浆和赋矿碳酸盐岩的碳、氧同位素之间,主要是由于岩浆流体和碳酸盐岩不同比例的水岩反应所致,测水组有机碳的加入造成了部分热液方解石δ13CPDB值偏低。  相似文献   

4.
湘西地区铅锌矿成矿物质来源——来自S、Pb同位素的证据   总被引:2,自引:1,他引:1  
湘西地区铅锌矿床位于湘西-鄂西成矿带西南段,具有良好的成矿地质背景和控矿条件,有望成为中国最大的铅锌矿基地。S和Pb同位素组成分析结果表明,湘西地区矿床的δ~(34)S值变化范围为6.30‰~34.66‰,平均值为19.64‰,明显富重硫,具有双塔式分布特征,矿石硫主要来源于容矿地层中的海相硫酸盐类和海水。8个矿床矿石矿物的~(206)Pb/~(204)Pb值范围为17.689~18.295,~(207)Pb/~(204)Pb值变化于15.535~18.848之间,~(208)Pb/~(204)Pb值介于37.294~38.630之间。区内铅锌矿床Pb同位素成分具有造山带和上地壳Pb同位素特征,成矿物质来源于造山带和上地壳的混合作用,铅成因类型为上地壳和地幔因岩浆作用而混合的俯冲铅。提出了湘西地区铅锌矿成矿作用的两阶段演化模式,认为区内铅锌成矿作用经历了成矿流体形成和成矿流体迁移富集2个演化阶段。  相似文献   

5.
对新疆霍什布拉克铅锌矿床硫化物硫、铅同位素测定,获得成矿早期黄铁矿的δ34S值为-12.1‰~-8.5‰,闪锌矿的δ34S值为-17.6‰,方铅矿的δ34S值为-18.8‰;晚期黄铁矿的δ34S值为+12.8‰~+22.2‰,闪锌矿的δ34S值为+20.0‰~+24.2‰,方铅矿的δ34S值为+14.4‰+22.2‰.成矿从早到晚,硫同位素由大的负值变化到大的正值,方铅矿的206 Pb/204 Pb比值为17.900-18.086,207Pb/204Pb比值为15.586-15.732,208Pb/204Pb比值为37.997-38.381;黄铁矿的206Pb/204Pb比值为17.950,207 pb/204Pb比值为15.633,208 pb/204 Pb比值为38.144.灰岩的206pb/204 Pb比值为18.156-18.875,207Pb/204Pb比值为15.396-15.855,208Pb/204Pb比值为37.631-38.967.硫同位素指示硫来源于海水硫酸盐还原硫.铅同位素指示至少有两上以上来源.  相似文献   

6.
民稿铅锌矿床位于湘西北铅锌成矿带南西侧,处于花垣矿田与凤凰矿田之间,是近年来新发现的矿床。为探讨其成矿物质来源和矿床成因,本文在矿床地质特征研究的基础上,开展了硫、铅、碳、氧同位素研究。结果显示,3件方铅矿样品的δ~(34)S值为26.1‰~28.3‰;~(206)Pb/~(204)Pb值为18.05~18.29,~(207)Pb/~(204)Pb值为15.67~15.84,~(208)Pb/~(204)Pb值为38.23~38.24;3件成矿期方解石的δ~(13)C值为-4.78‰~-2.63‰,δ~(18)O值为21.4‰~21.8‰。结合区域研究成果认为,成矿硫源来自赋矿地层中海相硫酸盐TRS的产物;成矿铅源主要来自深部矿质,部分来自赋矿围岩;成矿流体中的碳来自赋矿围岩,成矿流体中含有地层水。综合分析认为,民稿铅锌矿床是扬子地台东南缘伸展拉张背景下,区域深大断裂活动引起的成矿作用的产物,矿床类型应为MVT型铅锌矿床,并建立了成矿模型。  相似文献   

7.
西藏申扎县雄梅铜矿床的硫、铅同位素特征及其成矿意义   总被引:1,自引:1,他引:0  
西藏雄梅斑岩型铜矿床位于班公湖-怒江成矿带中段的申扎县雄梅乡。矿区岩石类型由含矿花岗闪长斑岩、孔雀石化次生石英岩及含矿角岩化砂板岩组成。该矿床自2012年发现以来尚未开展成因方面的深入研究,作者旨在通过对矿区硫化物硫、铅同位素的系统研究,查明矿区的成矿物质来源,并通过与成矿带西段多龙矿集区斑岩铜矿成因的对比研究,对本地区的成矿潜力做出评价。测试结果表明,雄梅铜矿矿石硫化物的δ34S值为-2.5‰~6.1‰,硫同位素呈塔式分布,显示岩浆硫特征;铅同位素组成~(206)Pb/~(204)Pb、~(207)Pb/~(204)Pb、~(208)Pb/~(204)Pb比值分别为18.220~19.005、15.626~15.770、38.510~39.856,显示正常铅的特征。对铅同位素的源区分析,显示样品大致分布于上地壳端员。铅μ值在9.51~9.78之间,也表明硫化物样品具壳源的特征。与多龙矿集区成矿条件的对比研究,发现两者都是形成于造山带的碰撞后伸展环境,成矿物质来源上两者存在一些差异。良好的构造成矿环境,表明了本地区优越的找矿前景。  相似文献   

8.
青海沱沱河地区多才玛铅锌矿床是西南三江特提斯北段新生代铅锌矿集区的典型矿床之一,本文首次应用飞秒激光剥蚀多接受器等离子体质谱法对多才玛铅锌矿床中金属硫化物的原位S和Pb同位素进行了测定。结果显示:黄铁矿、方铅矿和闪锌矿的原位S同位素的δ~(34)S_(V-CDT)值介于-26.34‰~4.24‰之间,均值-12.15‰(n=20),其中闪锌矿的δ~(34)S_(V-CDT)值介于-10.30‰~-3.52‰,均值-7.39‰(n=9);方铅矿的δ~(34)S_(V-CDT)值为-26.34‰~-11.74‰,均值-20.36‰(n=9);黄铁矿的δ~(34)S_(V-CDT)值分别为2.50‰,4.24‰。矿床δ~(34)S数据范围较宽,总体表现为富集负值硫的特征,说明有机质可能参与成矿。岩浆热液期发育的黄铁矿δ~(34)S值具有深源特征,沉积热液期发育的方铅矿和闪锌矿的δ~(34)S值表明成矿过程存在还原作用,指示盆地地层还原流体的混入,综上可认为多才玛铅锌矿床硫具有混合来源的特征。方铅矿原位Pb同位素结果为~(206)Pb/~(204)Pb=18.866~18.929,~(207)Pb/~(204)Pb=15.674~15.689,~(208)Pb/~(204)Pb=39.052~39.174。方铅矿与地层的Pb同位素组成一致,位于上地壳平均Pb演化线之上,具上地壳和地幔混合俯冲带铅的特征,表明其成矿物质的来源多样。结合矿床学、矿物学及同位素数据,本文认为多才玛铅锌矿床S元素主要来源于赋矿围岩,Pb金属元素主要来源于藏北钾质火山岩,侵入地层岩浆与盆地流体的混合是金属硫化物沉淀的重要机制。  相似文献   

9.
喇嘛萨依铜矿是新疆西天山赛里木微地块内的一处典型铜矿床,关于其成因类型尚存争议。总结了该铜矿床的地质特征,测试围岩、脉石碳酸盐的C、O同位素和硫化物的S、Pb同位素组成,探讨其成因类型。研究表明,喇嘛萨依铜矿床具有后生矿床特征,发育矽卡岩化蚀变,脉石方解石的δ13C值变化范围为-1.04‰~-0.87‰,低于围岩灰岩的δ13C值(变化范围为3.51‰~5.47‰),δ18O值变化范围为9.33‰~9.61‰,明显低于正常的海相碳酸盐岩的O同位素(δ18O=20‰~26‰),C、O同位素组成反映喇嘛萨依铜矿成矿晚阶段流体来自岩浆水和地下水的混合水;硫化物的δ34S值主要变化范围为3.75‰~8.64‰,与区域上海西期斑岩的硫同位素组成(如达巴特斑岩铜钼矿床硫化物的δ34S变化范围为4.9‰~7.9‰)接近,反映硫来源于斑岩;黄铜矿的铅同位素为206Pb/204Pb=18.264~19.544,207Pb/204Pb=15.575~15.656,208Pb/204Pb=38.103~38.705,具有富含放射成因铅、两阶段异常铅特征,与区域上海西期斑岩(达巴特流纹斑岩)的铅同位素组成特征相似,反映成矿金属物质部分来源于斑岩。通过综合分析认为,喇嘛萨依铜矿是与斑岩有关的矽卡岩型矿床。  相似文献   

10.
鱼库锌多金属矿床位于豫西栾川钼钨铅锌银矿集区内的鱼库—赤土店铅锌矿带的北西端。矿床赋存于新元古界栾川群三川组碳酸盐岩夹碎屑岩地层中,矿体呈似层状、透镜状产于透辉石-石榴石矽卡岩中,受矽卡岩带控制。硫化物的硫同位素组成比较稳定,δ~(34)S变化范围为2.3‰~3.9‰,平均3.2‰。硫同位素组成与区域内斑岩-矽卡岩型矿床的硫同位素组成一致,反映硫的主要来源为深部岩浆;金属硫化物样品的~(206)Pb/~(204)Pb变化范围为17.781~18.455,平均值18.043;~(207)Pb/~(204)Pb变化范围为15.502~15.590,平均值15.545;~(208)Pb/~(204)Pb变化范围为38.232~38.624,平均值38.438,矿石铅同位素组成稳定,矿石铅主要来源于地幔,成矿作用与构造岩浆作用相关的热液过程关系密切。综合分析认为矿床成因应属于岩浆热液接触交代矽卡岩型矿床。  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

13.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

14.
正The Kuqa depression deposited thick rock salt,which has a lower density than surrounding rocks.When salt bodies form a certain scale,obvious negative gravity anomalies can be detected in the surface.Therefore,gravitational method can quickly obtain the shape,plane distribution of deep-seated salt bodies and overall tectonic morphology of the basin.  相似文献   

15.
正1 Introduction The Pingluoba brine,which characterized as high concentration with sodium,potassium,boron,lithium,and rubidium,possess great development value.The main composition of the brine can be summarized to the  相似文献   

16.
正1 Introduction In the present paper,MgCl2·6H2O,FeCl3·6H2O,and CeCl3·6H2O were used as raw materials in the precipitationhydrothermal method to synthesize MgF eC e hydrotalcite.The effects of the Fe:Ce molar ratio on the composition,crystal structure,and thermal stability of hydrotalcite are examined.Energy-dispersive X-ray spectroscopy(EDS),X-  相似文献   

17.
正1 Introduction Crystallization is one of important unit operations in the chemical production process,which requires not only the crystal product with high purity and yield,but also the available particle size of the crystal products to ensure product quality.Crystallization process is affected by  相似文献   

18.
正Dear Authors and Readers:First of all,on behalf of the new Editorial Board,I would like to express our sincere appreciation for your continuing support of our journal.This journal,founded in 1922,is the oldest geological journal in China.As the flagship journal of the Geological Society of China,it has become more and more influential in earth sciences in China and beyond.The journal is now indexed by SCI,CA and more than 20 other databases,with an impact  相似文献   

19.
正20141283 Bai Daoyuan(Hunan Institute of Geological Survey,Changsha 410016,China);Zhong Xiang Nature,Origin and Tectonic Setting of Jinzhou Basin in the South Segment of Xuefeng Orogen(Geology in China,ISSN1000-3657,CN11-1167/P,40(4),2013,p.1079-1091,10 illus.,47 refs.)Key words:foreland basins,strike-slip faults,Hunan Province  相似文献   

20.
正20142093Chen Daohua(Guangzhou Marine Geological Survey,Guangzhou 510075,China);Diao Shaobo The Latest Progress of Geological Marine Testing Technology in China(Rock and Mineral Analysis,ISSN0254-5357,CN11-2131/TD,32(6),2013,p.850-859,105refs.)Key words:chemical analysis,China  相似文献   

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