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1.
安徽石台大山地区岩石-土壤地球化学特征 总被引：1，自引：0，他引：1
通过对安徽石台大山地区内岩石、土壤地球化学特征的论述,阐述了岩石和土壤中元素地球化学背景值,对不同类型的岩石和不同时代的岩石中元素地球化学背景值、表层和深层土壤元素背景值特征进行了论述,并对岩石—土壤系统地球化学迁移性进行探讨,探讨了土壤元素背景值与基岩的关系、元素的富集与贫化特征和主要土壤元素类型特征。 相似文献
2.
以广东省揭阳市土壤为研究对象,采集了1 330个表层土壤(0~20 cm)样品和331个深层土壤(150~200 cm)样品,通过 GIS 空间分析技术、半变异函数拟合和方差分析等方法对研究区土壤镉含量的富集特征、空间分布、结构特征以及影响因素进行了系统分析。结果表明,研究区表层土壤镉含量的均值为0.09 mg/kg,高于该区土壤背景值,但低于GB 15618—2018《土壤环境质量农用地土壤污染风险管控标准(试行)》的标准值。通过富集因子法研究表明,研究区表层土壤镉主要为轻微污染和中度污染。从结构特征来看,研究区表层土壤镉含量呈中等空间相关性。揭阳市表层土壤镉含量高值区主要分布在人类活动密集的东部和南部地区。土地利用类型、成土母质和土壤类型是影响表层土壤镉含量的重要因素,在不同土地利用方式下,建筑用地土壤镉含量最高;不同成土母质中,第四纪沉积物土壤镉含量显著高于其他母质;不同土壤类型中,水稻土的镉含量相对较高。 相似文献
3.
镉（Cd）是严重危害人类健康的一种重金属元素,具有较强的生物毒性。为了保证矿区充填复垦土地种植农作物的生态安全,以淮南新庄孜矿煤矸石充填复垦治理区为对象,对其土壤和煤矸石中镉元素的含量进行了跟踪分析研究,结果表明,煤矸石充填复垦区土壤中垂直方向上各层镉元素含量均高于淮南市土壤背景值和中国土壤背景值,其中靠近填充物——煤矸石的土壤镉含量超标率最高,从土壤中镉元素的水平和垂直空间分布来看,复垦充填物——煤矸石因受淋溶作用造成的重金属元素的排放和迁移直接或间接污染了复垦土壤的生态环境,其中镉元素已经出现富集,甚至达到了污染水平。 相似文献
4.
确定岩性复杂区的地球化学背景与异常的方法 总被引：3，自引：0，他引：3
地球化学背景和异常的确定是化探找矿的关键。不论是水系沉积物还是土壤地球化学测量,岩性对许多元素背景值的影响都是十分显著的。在地质情况复杂的区域内,采用统一的异常下限值圈定异常是不合理的。根据样品的成矿元素与氧化物(SiO2)的相关关系,确定了岩性对成矿元素背景的影响。对受岩性影响显著的成矿元素,通过线性回归模型,以残差置信带确定元素异常的下限。实例研究证明,该方法在很大程度上消除了岩性变化对成矿元素背景的影响,能够有效地区分元素背景和异常。 相似文献
5.
选取兴蒙造山带—华北克拉通地球化学走廊带上沉积物的SiO_2、Al_2O_3、CaO、MgO、Na_2O、K_2O、TFe_2O_3、FeO、TiO_2、MnO、P_2O_5、CO_2、H_2O~+、pH十四个指标,研究其在不同二级构造单元、地理景观、土壤类型、降雨量等级下的含量与空间分布特征,并讨论该地球化学走廊带上化学蚀变指数。结果表明:在兴蒙造山带—华北克拉通地球化学走廊带上,作为沉积物主体的SiO_2、Al_2O_3两者含量为明显负相关而空间分布表现出此消彼长的特征;CaO、MgO、CO_2高含量分布区则与碳酸盐岩地层或含碳酸盐矿物的土壤有关,而MgO的高含量还与走廊带上镁铁质基性-超基性岩有一定关系,表明了这三个指标的高含量受特定岩性或矿物的影响较大;Na_2O、K_2O含量除了受继承的基岩影响外,还受到后期的风化作用和气候及自身地球化学性质等复杂因素综合影响,对Na_2O来说尤为如此;TFe_2O_3、MnO、TiO_2、P_2O_5相对于在地质背景复杂地段,经过冲积平原的沉积物混匀后,含量差异更小;相对干冷的内蒙古半干旱草原的气候条件有利于FeO存在,使得其相对燕山地区含量差异较TFe_2O_3要小,在章丘以南相对温暖湿润地区更易被氧化而导致其含量整体较低;北方干冷气候条件下,沉积物H_2O~+含量普遍较低,局部高含量位于碳酸盐岩地层或第四系分布区;走廊带上的pH值反映了沉积物偏碱性的特征,而在章丘以南的地区随着降雨量的增加,相对温暖湿润的气候条件,沉积物pH值表现为中性-偏弱酸性;兴蒙造山带—华北克拉通地球化学走廊带沉积物的CIA值反映出在寒冷、干燥气候条件下低等的化学风化程度,兴蒙造山带沉积物平均风化程度相对华北克拉通沉积物的平均风化程度差异变化相对要小,显示兴蒙造山带的降雨量与温度等风化影响因素变化较小。作为反映元素的地球化学亲和性的量化指标,离子电位可以更好地帮助理解沉积物元素的含量和空间分布差异。 相似文献
6.
地质背景对土壤微量元素的影响——以渝北地区为例 总被引：3，自引：0，他引：3
研究地质背景对土壤元素的控制特征,可为区域土壤元素地球化学研究、种植施肥和农业布局提供科学依据。本研究利用网格化定位与化学分析的方法,结合GIS技术和相关评价标准,探讨了地质背景对Cl、Mn、B、Zn、Cu和Mo元素含量及分布的影响。结果表明:渝北地区土壤Mn、Cu、Zn元素含量整体处于适中与丰富水平,Mo、B元素丰缺参半;B、Mo元素含量显著高于重庆主城区,Zn元素含量显著高于全国水平。受地质背景影响,B、Cl、Cu、Mn元素呈现高度空间相关性,结构性空间变异起主导作用;Mo、Zn元素表现中等空间相关性,由结构性因素和随机因素双重控制。地层的组对元素含量分布起主控作用,土壤元素含量分布形状在空间上与地层组相对应。成土母岩决定土壤元素含量,是土壤元素含量水平的重要控制因素之一,其影响因素主要为岩石类型,其次为岩石形成的地质时期。土壤类型显著影响元素含量,总体上,Mn、Cu、Zn、Mo、B在石灰岩土中含量最高;除B、Mo元素外,其他元素在黄壤中含量最低。 相似文献
7.
中国汞的地球化学空间分布特征 总被引：1，自引：0，他引：1
20世纪80年代以来中国积累了岩石、土壤和水系沉积物中的大量可靠的汞分析数据和图件,为分析汞的地球化学空间分布特征提供了依据.从空间分布上看,从中国北部到南部,从西部到东部,土壤和水系沉积物中汞的含量背景值逐渐增高,汞在以干旱荒漠区、半干旱荒漠区、黄土地区和高寒山区为主的西部和北部呈低背景,在东部的森林沼泽区和半湿润低山丘陵区为中等背景,在南部的湿润低山丘陵区、热带雨林区和高山峡谷区为高背景,尤其在以云南东南部、贵州、广西西部、湖南西部岩溶区为中心的低温成矿域内,无论岩石、土壤还是水系沉积物,汞含量背景值达到最高.一般情况下,岩石、土壤和水系沉积物之间的汞含量具有继承性,在地理空间分布上呈明显的对栽应关系,并且土壤和水系沉积物之间的汞含量具有相近性,土壤和水系沉积物较岩石更为富集汞. 相似文献
8.
《地质科技情报》2019,(6)
乍得Bongor盆地基底结晶岩富含油气资源,为明确基岩的储集性能,综合利用岩心、岩石薄片、铸体薄片、主量元素测试、压汞和常规物性等资料,研究了乍得Bongor盆地潜山基岩的岩石类型、化学成分、矿物组成、储集空间类型、孔隙结构和物性特征。结果表明,研究区基岩由变质岩和岩浆岩组成,各种岩性所含氧化物和矿物含量有明显的差异。浅色矿物含量高的岩性脆性高,抗压强度小,在构造应力作用下更容易形成破碎粒间孔和构造裂缝,且在溶蚀作用下,长石易于被溶解,而发育溶蚀孔,储集空间组合类型有裂缝-孔隙复合型、裂缝型和孔隙型,孔渗高,排驱压力低,孔喉连通性好,中大孔径所占比例高,储集性能好;而暗色矿物含量高的岩性如变粒岩类、片麻岩类和闪长岩类等,其构造成因的储集空间相对较差,但在溶蚀改造作用下暗色矿物更易被溶蚀,而形成溶蚀孔,储集空间类型主要是孔隙型,局部存在裂缝型,孔渗低,排驱压力高,孔喉连通性差,小孔径所占比例高,储集性能较差。 相似文献
9.
基岩裂隙水的富集规律 总被引：1，自引：0，他引：1
廖资生 《吉林大学学报(地球科学版)》1976,(2)
基岩裂隙水,是指那些储存于坚硬岩石构造或成岩裂隙中的地下水。我国北方碳酸岩地区溶蚀裂隙中的地下水亦属此种类型。它主要受着构造形迹的力学性质和空间形态特征所控制。迄今为止,主要是建立在松散沉积物孔隙地下水基础上的水文地质学,远不能解决基岩裂隙水所面临的复杂问题。因此,现在有必要加强基岩裂隙水的研究。 相似文献
10.
应用二组分成分变异曲线图判别岩浆作用的一套有效方法 总被引：3，自引：1，他引：3
本文以瑞利结晶、批式熔融、分离熔融和混合作用四种主要的微量元素模型为基础,建立了对应于这些岩浆作用的一套以元素比值-比值(或元素)、共分母元素比值-比值、共分子元素比值-比值和元素-元素作变量的数学方程及相应的成分变异曲线图。在分析一套有成因联系的岩石的形成机理时,只要将岩石成分投点成有关的变异图,并与本文的成分变异曲线图对比,就能快速确定岩石的成分变异主要受何种岩浆过程控制。若计算出元素的总分配系数,就可确定源岩、初始岩浆、端员岩浆或混染物的成分。 相似文献
11.
Sujatha Dantu 《Environmental Earth Sciences》2014,72(4):955-981
Regional-scale variations in soil geochemistry were investigated with special reference to differences among soil groups and lithology in an area of 9,699 km2 in Medak district, Andhra Pradesh, India. The concentrations of 29 elements (major: Si, Al, Fe, Mn, Mg, Ca, Na, K, Ti, P and trace: As, Ba, Cd, Co, Cr, Cu, F, Mo, Ni, Pb, Rb, Se, Sr, Th, U, V, Y, Zn, Zr) in 878 soil samples collected (557-topsoil, 321-subsoil) at a sampling density of 1 site/17 km2 from 557 sites representative of all the soil types present in studied area were determined, and their elemental composition are discussed. The baseline levels of these elements in soils are determined over different lithological units for the identification of anomalous values relative to these. For the first time, geochemical maps for Medak district are prepared on 1:50,000 scale and the lithogeochemical database generated provides information on the lateral and vertical distribution of elements in soil. The spatial variations in the distribution of elements reflect underlying geologic characteristics. Box-plots reveal that the concentration of most of the elements in soils were not strongly dependent on the soil group but the soil-geochemistry abruptly changes with the change in the soil parent materials indicating that the distribution of elements is mostly influenced by the bedrock lithology and other natural processes acting on them. For instance, the concentrations of Co, Cu, Fe, Mn, Ti, V and Zn are high in soils developed on basaltic terrain while the soils developed on granitic and gneissic terrain exhibit high elemental concentrations of K, Pb, Rb, Si, Th and Y. Alfisols had relatively high contents of elements while entisols had lower concentrations of most of the elements. The database can be used in the chemical characterisation of different geological units as well as applications in various environmental and agricultural fields. The results indicate that regional geology is an important determinant of soil geochemical baselines for soil pollution assessment and further emphasizes the importance of determining background levels locally. The defined baselines can be used to establish background values for future soil surveys. 相似文献
12.
Evaluation of heavy metal contamination and implication of multiple sources from Hunchun basin, northeastern China 总被引：1，自引：0，他引：1
J.-W. Moon H.-S. Moon N.-C. Woo J.-S. Hahn J.-S. Won Y. Song X. Lin Y. Zhao 《Environmental Geology》2000,39(9):1039-1052
Present concentrations and distributions of heavy metals through profiles, surface soil, and stream sediment samples in the
Hunchun area, north-eastern China, were investigated to determine the elemental background values. This study also aims to
characterize potentially toxic materials such as pulverized fly ash (PFA) from power stations or ash and slag from coal used
domestically in urban areas, agrochemicals applied inappropriately, and urban sewage sludges from Hunchun City, as well as
to ascertain the possibility of natural enrichment through site characterization by mineralogical and geochemical investigation.
The distribution of contaminants in the alluvial soils (fluvisol) of this area has been influenced by several interacting
factors. The parent alluvial materials from weathered products of amphiboles have made coatings such as ferrihydrite, goethite,
and hematite. This natural inheritance factor is supported by the fact that the concentrations of weak acid-extractable (plant-available)
heavy metals are very low, except for Fe and Mn. However, in agricultural soils and adjacent stream sediments, an anthropogenic
input of Cd, Pb, Ni and Cr by agrochemicals is strongly suggested. Also, F contamination by coal combustion and the dissolution
of F-bearing minerals could cause some future problems. Wide distribution and significantly high concentrations of Cd, Fe,
Mn, and F in soils throughout the combination of pollutants originating from lithogenic and the anthropogenic sources pose
potential problems in utilizing water resources.
Received: 14 June 1999 · Accepted: 27 December 1999 相似文献
13.
硫铁矿冶炼区不同土地利用方式及土壤类型对重金属迁移的影响 总被引：1，自引：1，他引：0
为探讨硫铁矿冶炼区不同土地利用方式和土壤类型对重金属元素迁移的影响,采集了毕节市林口废弃硫铁矿冶炼厂内耕地砂壤土及附近林地石灰土表层和深层样共40组。室内测试土壤理化指标Pb、Zn、Cd全量和有效态含量,并对重金属元素含量的水平和垂直分布特征及重金属元素含量的相关性进行了讨论。结果表明:土壤中Pb和Zn的含量均符合土壤环境质量二级标准值,耕地表层土壤Cd含量是贵州省农业土壤背景值的7倍。土壤Cd有效态含量占全量的比值最大,而Pb和Zn有效态含量占全量的比值差别较小。耕地砂壤土Zn和Cd的全量随剖面深度的增加表现为先增大后减小,Pb呈减少的趋势;Pb和Zn的有效态含量随剖面深度的增加而减少,Cd有效态含量呈波动变化。林地石灰土中Pb、Zn、Cd的全量和有效态含量均随剖面深度的增加而减少,且Pb、Zn、Cd全量之间及全量与有效态含量之间都具有显著的正相关关系,而在耕地中各元素的相关性不明显。土壤频繁的扰动和偏酸性的环境有利于重金属垂向迁移。 相似文献
14.
对于人为因素或自然因素造成的农田土壤重金属元素污染,需要进行大面积的土壤环境质量调查和分类管控,然而传统的采样测试方法存在工作量大、代价高等问题。可见—近红外（Vis-NIR）反射光谱是一种快速低成本获取土壤理化信息的手段。为研究Vis-NIR反射光谱预测模型划分土壤重金属污染风险类别的能力,文章以典型人为污染地区（浙江温岭）和典型地质高背景地区（广西横县）的390份农田土壤为样本,测定8种重金属元素（As、Cd、Cr、Cu、Hg、Ni、Pb和Zn）的含量和pH值,并测定土壤Vis-NIR光谱。使用偏最小二乘（PLS）和支持向量机（SVM）算法建立回归模型,对土壤重金属含量和pH值进行预测,并基于预测值进行土壤重金属污染风险分类。结果显示,温岭土壤主要污染元素Cd和Cu的光谱模型回归预测偏差（RPD）分别为1.23和1.19,预测机制与有机质有关。横县土壤主要污染元素As和Cd的RPD分别为1.98和1.93,预测机制与铁氧化物和粘土矿物有关。地质高背景土壤重金属与铁氧化物的正相关性普遍较强,使得光谱模型对重金属含量预测准确度较高。温岭和横县土壤pH值的光谱模型RPD分别为1.76和1.68。土壤重金属污染风险光谱分类的总体
准确度分别为75.0%~100%（温岭）和80.0%~100％（横县）。将Vis-NIR光谱与遥感技术相结合,对农田土壤重金属污染风险进行快速分类总体是可行的。 相似文献
15.
Cheng-Long Tu Teng-Bing He Xiao-Hui Lu Yun-Chao Lang Long-Bo Li 《Environmental Earth Sciences》2013,70(1):131-137
The properties of soils derived from carbonate rock, red residua, and sand-shale in Guizhou province, China are essentially different. However, the effects of parent material and anthropogenic activities on the concentration of trace elements when the soils are converted into paddy soils are unknown. A total of 319 paddy topsoil samples (0–20 cm) were collected in a typical region to determine their relative contribution to the concentrations of trace elements in the soil. The results indicated that the contents of trace elements were far beyond the uncultivated soil background and the input of organic fertilizers was presumably responsible for accumulation of trace elements. In addition, principal component analysis showed that the first component included Cd, Cr, and As, which strongly associated with anthropogenic activities. Pb and Hg formed the second component, which related to both parent materials and anthropogenic input. Furthermore, the Cr and Hg contents in paddy soil derived from carbonate rock have higher values than other types of soils partly because of the high background values as well as slightly alkaline condition. In the paddy soil derived from red residua, high physical clay content accounted for enrichment of Pb. 相似文献
16.
Selenium and heavy metals content in some Mediterranean soils 总被引：1，自引：0，他引：1
L. Roca-Perez C. Gil M.L. Cervera A. Gonzálvez J. Ramos-Miras V. Pons J. Bech R. Boluda 《Journal of Geochemical Exploration》2010
The study of metal contents in industrial, agricultural or/and polluted soils compared with natural or unpolluted soils is currently necessary to obtain reference values and to assess soil contamination. Nonetheless, very few works published appear in international journals on elements like Se, Li and Sr in Spanish soils. This study determines the total levels of Se, Li, Sr, As, Cd, Co, Cr, Cu, Ni, Pb, V, Zn, Fe, Mn and Ba in 14 natural (unpolluted) soils (Gypsisols, Leptosols, Arenosols and Acrisols), 14 agricultural soils (Anthrosols, Fluvisols and Luvisols), and 4 industrial–urban affected-surface soil horizons (Anthrosols and Fluvisols) of Eastern Spain. The geochemical baseline concentrations (GBC) and reference values (RV) have been established, and the relationships among elements and also between soil properties and elemental concentrations have been analysed. The RV obtained in this study were (mg kg−1): Se 2.68, Li 115, Sr 298, Cd 0.97, Co 35, Cr 217, Cu 46, Ni 50, Pb 137, V 120, Zn 246, Fe 124,472, Mn 2691, and Ba 743. The RV for Se and Li were used as a preliminary approach to assess soil contamination in Spanish soils. The results confirm human impact on Sr, As, Cd, Cr, Cu, Ni, Pb and Zn soil concentrations, but evidence no deviation from natural Se, Li, Co, V, Fe, Mn and Ba concentrations. The results obtained from the statistical analysis reveal significant correlations between some elements and clay and soil organic matter (SOM) contents, indicating that metal concentrations are controlled by soil composition. One particularly interesting finding is the high correlation coefficients obtained between SOM and Se, Cd, Cr, V, Fe, and Mn, and between clay and Cd, Zn, V, Fe and Mn. Once again, these facts confirm the role of SOM and clay minerals in soil functions and that soil is an ecosystem element responsible for maintaining environmental quality. 相似文献
17.
Emmanuel D&#x;lsch Herv Saint Macary Virginie Van de Kerchove 《Journal of Geochemical Exploration》2006,88(1-3):194
The objective of this study was to conduct an inventory of heavy metal concentrations (Cd, Cr, Cu, Hg, Ni, Pb and Zn) in the soils of La Réunion. 39 sampling sites were selected to cover the distribution of soils of the island. The results show that soils of La Réunion are rich in heavy metals: most of them exceed the French standard values beyond which sewage sludge spreading is not authorized. To identify the sources of heavy metals, we used: (i) the relationship between the heavy metal content in soils and the origin of the volcanic parent material; (ii) the comparison of heavy metal content between cultivated and uncultivated soils; and (iii) the heavy metal distribution in soil profiles. Cd and Pb evolution in soil profiles indicate an impact of human activities. High Hg concentrations in soils can be explained by the volcanic activity of the island. For Cr, Cu, Ni and Zn, we demonstrate that high concentrations in soils are mainly determined by the natural pedo-geochemical background. 相似文献
18.
Urbanisation and industrial development lead to contamination of estuaries and streams with dispersed loadings of heavy metals and metalloids. Contributions of these elements also occur from natural sources. This study provides baseline geochemical data on the respective natural and anthropogenic inputs of Cu, Pb, Zn, Cd, As, Sb, Cr, Ni, Mn and S to estuarine, fluvial and wetland sediments, and adjacent soils, in the Kooloonbung Creek catchment that drains the Port Macquarie urban area in north coastal New South Wales. There have been anthropogenic additions of Cu, Pb, Zn and As from dispersed urban sources at Port Macquarie, but they are restricted to the local catchment and do not impact on the adjacent Hastings River estuary. The most contaminated sediments display enrichment factors up to 20 × for Cu and Pb, 9 × for Zn and 5 × for As relative to local background values. However, only one value (for Pb) exceeds National Water Quality Management Strategy interim sediment quality guideline (high) values. On the other hand, sediments and local soils are commonly strongly enriched in Cr, Ni and Mn, reflecting adjacent ultramafic and mafic rock substrate and lateritic regolith. Concentrations of Cr and Ni are commonly well above interim sediment quality guideline (high) values for sediments, but are in mineralogical forms that are not readily bioavailable. Sediment and soil quality guideline values consequently need to recognise natural enrichments and the mineralogical siting of heavy metals. Although dissolved concentrations of heavy metals in stream waters are commonly low, there is evidence for mobility of Cu, Zn, Fe and Al. Parts of the Kooloonbung Creek wetland area lie on sulfidic estuarine sediments (potential acid sulfate soils). Experimental oxidation of uncontaminated and contaminated sulfidic sediments leads to substantial dissolution of heavy metals under acid conditions, with subsequent aquatic mobility. The results warn about disturbance and oxidation of potential acid sulfate soils that have been contaminated by urban and natural heavy-metal sources. 相似文献
19.
Mohammad Tahsin Karimi Nezhad Manijeh Ghahroudi Tali Mohammad Hashemi Mahmoudi Ebrahim Pazira 《Environmental Earth Sciences》2011,64(5):1203-1213
The aim of this study was to investigate the influences of land use, parent materials (rock types) and soil properties on total arsenic and cadmium concentrations in the agricultural soils. A total of 87 surface (0–20 cm) soil samples were collected from four types of land use: irrigated farming, rangeland, dry farming and orchard. The average concentrations of the analyzed elements in topsoil were 84.426 mg As/kg and 3.289 mg Cd/kg. In addition, the pH, organic matter (OM), cation exchange capacity (CEC), soil grain sizes and CaCO3 were measured for each sample. The results indicated that land use had no significant effect on As and Cd concentrations. Our findings indicated that the Cd concentrations were influenced by bedrock composition, but for As there were no significant differences between various soil parent materials (bedrocks). Soil pollution was assessed on the basis of pollution index (PI), comprehensive pollution index (P n ) and geoaccumulation index (I geo). Calculated indices showed high-pollution levels for As and low- to moderate-pollution levels for Cd. 相似文献
20.
研究测定了百朗地下河大石围天坑段沉积柱芯中金属元素和沉积有机质(SOM)浓度,结合210Pb定年和历史事件记载,恢复了1932-2007年间百朗地下河流域的污染历史。研究结果表明,地下河沉积柱中主要有毒重金属Cd、Hg分别超过广西土壤背景值3.4和0.6倍,超过中国土壤背景值11.2和2.7倍;1932年至2007年间;总体上沉积柱中各重金属元素的垂直分布趋势相似,呈现不同程度的上升趋势;并推演了历史上农民运动、抗日战争、大跃进、改革开放初期和经济快速发展期等事件是造成百朗地下河流域金属元素变化的主要原因;尤其是沉积柱中钙与镁的垂直变化显示了1983年以来流域岩溶石山地区进入一个新的建设高潮。相关性分析和聚类分析表明,Cr、Pb主要来源于自然环境;Fe、Cu、Ni、Zn、As、MgO来源为自然和人为混合源;Cd、Hg、Mn、CaO和SOM主要来源于人为污染源;与多环芳烃相关性分析显示Zn、Cd和As部分来源为人为的燃煤污染。因此沉积柱较好地记录了百朗地下河流域重金属污染历史。 相似文献