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1.
Sequences of laminated limestones found within thin Carboniferous carbonate strata of northeastern Kentucky were studied to determine their origin and palaeo-environmental significance. These laminated zones are strikingly similar to Holocene and Pleistocene surficial calcareous crusts (caliche) profiles that occur in various parts of the world. Carboniferous laminated carbonates are associated with shallow marine carbonate units, palaeokarst, and overlying palaeosol zones. A typical laminated profile ranges in thickness from 1 to 2 m and contains brecciated, light olive-grey to brown micrite that lacks distinctive bedding. Structures and textures common in most profiles include: (1) calcareous and silicious laminae (laminae form diffuse, alternating light and dark bands that generally parallel bedding but often fill fractures and vugs within the rocks); (2) particles (allochems, and micrite and microspar fragments) coated by brown microcrystalline calcite; (3) brecciated texture; (4) circular to elliptical fossil moulds (occur in sinuous patterns and fill fractures within the rocks); (5) large and small scale fracture patterns. Subaerial weathering and vadose diagenesis of carbonate mud banks or islands is suggested as a mechanism for the formation of these Carboniferous calcareous crust profiles. These ‘crusts’ formed by a combination of solution (karsting), brecciation, and soil development that transformed an exposed marine biomicrite (‘host’ rock) into a porous subsoil rubble. Laminated ‘crusts’ and coated particles developed as the result of dissolution and reprecipitation of CaCO3 and SiO3 from the soil and carbonate bedrock. Carboniferous laminated carbonates in northeastern Kentucky are often referred to as ‘algal limestones’ because of their superficial similarity to some modern and ancient algal structures. This study, however, reveals numerous characteristics that can only be explained by diagenesis in a subaerial environment.  相似文献   

2.
Large pisoliths from the Laguna Pastos Grandes playa in the Bolivian Altiplano have a wide diversity of cortical fabrics and variable mineralogical composition. The cortical laminae are composed of radial calcite bundles, spar calcite, micrite, amorphous silica, mixed micrite-amorphous silica, quartz, gypsum and halite. Diatoms are common in the outer parts of some radial calcite laminae and amorphous silica laminae, but cyanobacterial filaments are rare. Although the organization of the cortical laminae is highly variable, some repetitive sequences of different laminae are present. Cavities in and between pisoliths contain micrite, detrital grains, calcite bundles and peloids morphologically similar to those found in marine reefs. The pisoliths grow in shallow ephemeral pools fed by hot springs. Radial bundles of calcite precipitate rapidly by degassing and photosynthetic removal of CO2 following spring snowmelt. Conditions for micrite precipitation are unclear, but there is evidence to suggest formation in partially stagnant waters, some of elevated salinity. Amorphous silica laminae precipitate mainly by evaporative concentration; quartz may precipitate from warm silica-rich spring waters that remain below amorphous silica saturation. The evaporite minerals form during desiccation of the pools or from spray. The peloids in cavities are probably primary precipitates. Different types of laminae may form simultaneously in different pools because of the highly variable conditions across the playa. Lateral migration of spring locations through time has created a complex carbonate-silica pavement. Large spherical pisoliths form in outflow channels near spring orifices and across discharge aprons where waters are several decimetres deep. With mineral precipitation, channels are filled and become shallow, producing discoid pisoliths and crusts. In shallow waters and on distal aprons only small pisolith gravels form. As spring pools fill with deposits, their locations shift laterally; new pisoliths form elsewhere or precipitation may recommence on older abandoned pisoliths.  相似文献   

3.
Despite extensive research, the environmental and temporal significance of microbial lamination is still ambiguous because of the complexity of the parameters that control its development. A 13 year monitored record of modern fast‐accreting calcite stromatolites (mean 14 mm year?1) from artificial substrates installed in rapid flow in the River Piedra (north‐east Spain) allows comparison of the sedimentological attributes of successive six‐month depositional packages with the known climatic, hydrophysical and hydrochemical parameters of the depositional system. The stromatolites are formed of dense, porous and macrocrystalline composite laminae. The dense and porous composite laminae, which are composed of two to eight laminae consisting largely of calcified cyanobacteria, are characterized by: (i) dense composite laminae, up to 15 mm thick, mostly with successive dense laminae and minor alternating dense and porous laminae; and (ii) porous composite laminae, up to 12 mm thick, consisting mainly of porous laminae alternating with thinner dense laminae. Most of the dense composite laminae formed during the warm periods (April to September), whereas most of the porous composite laminae developed in the cool periods (October to March). Each dense and porous composite lamina represents up to or slightly longer than six months. The alternation of these two types of composite laminae parallels seasonal changes in temperature. The dense and porous laminae result from shorter (for example, intraseasonal) variations in temperature, insolation and hydrological conditions. The macrocrystalline laminae, with crystals >100 μm long, occur isolated and grouped into composite laminae up to 1·7 mm thick. Their occurrence suggests the absence or poor development of microbial mats over periods of weeks to several months. Thus, stromatolite lamination can record different‐order, periodic and non‐periodic changes in the magnitude of environmental parameters over a single year. These results hold important implications for the temporal and environmental interpretation of lamination in microbial structures.  相似文献   

4.
In Upper Jurassic carbonate turbidites of the Betic mountains (southern Spain), chert occurs in three morphologies: bedded chert, nodular chert and mottled chert. The last refers to a weak dispersed and selective silification which gives a speckled appearance to the rock. The three types of chert are formed by replacement of limestones and are associated with different calcareous facies. Turbidite packstones of Saccocoma and peloids, and turbidite lime mudstones of pelagic material contain bedded and nodular cherts. The silicification textures are mainly micro- and cryptocrystalline quartz, with local chalcedonic quartz (both length-fast and length-slow) which is more common in the packstones. Only mottled chert is produced where calcareous breccia beds are silicified. Mottled chert consists of micro- and cryptocrystalline quartz, length-slow chalcedonic quartz and mosaics or individual crystals of euhedral megaquartz. Beds and nodules are the result of early diagenetic silicification, with silica derived from the calcitization and dissolution of radiolarians and, subordinately, sponge spicules, whereas mottled chert is the consequence of later silicification in a probably Mg-rich environment. Early silicification is mainly confined to turbidite beds and only rarely occurs in the interbedded pelagic limestones. Turbidite sedimentation favours silicification because rapid burial of the transported siliceous tests prevents silica from the dissolution of tests passing into overlying sea water. A silica-rich interstitial fluid develops in the turbidite layer and this migrates to more permeable zones giving rise to bedded and nodular chert.  相似文献   

5.
It has been shown that abundant coccoliths occur in many fine-grained, clay-poor limestones, generated in lagoon-like basins in an environment neither purely open-sea nor purely continental. In the Jurassic (Bathonian to Tithonian), Valanginian and Danian lithographic or sublitho-graphic limestones the coccoliths are tiny, not very diverse, cuff-link-shaped, and highly affected by diagenesis. The Stampian laminated coccolithic limestones consist of coccolithophorids of a single-species or not-very-diverse assemblage, and differ from one lamina to another; they are mostly cuff-link-shaped placoliths. Argillaceous laminae between calcareous laminae preserved the coccoliths from diagenetic effects. A review of the very few data on Recent coccolithophorids living in a low-salinity  相似文献   

6.
一、引言自从Ginsburg(1955)及Logan等(1961,1964)研究了巴哈马、佛罗里达和西澳大利亚的现代藻叠层石以来,已经建立了用藻叠层石的形态和构造来解释现代或古代海洋沉积环境的基础。在我国,报道前寒武纪叠层石的文章较多,上古生代则不多见。作者自1980年以来对广东泥盆纪碳酸盐沉积中的藻叠层石做了一些研究,现根据所得资料进行报道。  相似文献   

7.
M. Pacton  N. Fiet  G. Gorin 《地学学报》2006,18(6):380-387
Kimmeridgian bituminous laminites from Orbagnoux (France) contain abundant amorphous organic matter (AOM). Previous studies have shown that the vulcanization pathway was the dominant preservation mechanism of AOM in these laminites, and led to its structureless aspect (a process called amorphization) at the nanoscale. In contrast, new observations in scanning electron microscopy and transmission electron microscopy demonstrate that this AOM exhibits typical cyanobacterial structures (exopolymeric substances, filamentous and coccoid bacteria) and ultralaminae. This identification is supported by a comparison with a recent cyanobacterial biofilm considered as an analogue. Moreover, this comparison demonstrates that ultralaminae in the Orbagnoux environment cannot solely be attributed to microalgal cell walls, but also to constituents of cyanobacteria. The microscopic identification of a ubiquitous cyanobacterial imprint demonstrates that the selective preservation pathway has been largely underestimated in Orbagnoux AOM and/or that the vulcanization process does not lead to the amorphization of organic matter automatically.  相似文献   

8.
塔里木盆地柯坪地区奥陶系鹰山组台内滩沉积特征   总被引：2，自引：0，他引：2  
周明  罗平  董琳  周川闽  杨宗玉  刘策 《沉积学报》2016,34(5):951-962
通过对柯坪地区蓬莱坝剖面奥陶系鹰山组的野外实测可以将其划分为下、中、上三段,每段都具有不同的相序结构和沉积特征,下段主要以含陆源泥质的泥晶粗砂屑灰岩为主,中段为亮晶粉-细砂屑灰岩和层纹石灰岩互层出现,上段主要为中-厚层状似球粒泥晶灰岩,台内颗粒滩主要发育在中、下两段;柯坪水泥厂剖面也可以划分为三段,但界限没有蓬莱坝剖面明显,主体表现为中层状的亮晶砂屑灰岩和泥晶砂屑灰岩交互出现。通过对蓬莱坝剖面和柯坪水泥厂剖面的岩石进行野外露头、偏光显微镜、扫描电镜等不同尺度的观测及沉积微相分析,理清了柯坪地区鹰山组的岩石类型和相序结构,建立了柯坪地区颗粒滩沉积模式:由于水体深度和能量的差异,柯坪地区发育了四种相带类型--高能颗粒滩相带、滩间洼地沉积相带、低能颗粒滩相带、开阔浅海沉积相带。中-低能颗粒滩相带主要发育泥晶中-粗砂屑颗粒滩,高能颗粒滩相带主要发育亮晶细-中砂屑颗粒滩,并且两种颗粒滩都可以划分出3种亚相--滩主体、滩翼和滩内洼地;在微生物主导的碳酸盐建造向后生动物主导的碳酸盐岩建造转换的地质背景下,柯坪地区在奥陶系鹰山组沉积时期总体处于大面积发育微生物似球粒的浅水环境,沉积物的形成与改造受微生物活动的影响,微生物作用一方面为颗粒滩的发育提供了良好的物质基础,另一方面也控制了该时期颗粒滩的沉积特征。  相似文献   

9.
The significance of stromatolites as depositional environmental indicators and the underlying causes of lamination in the lacustrine realm are poorly understood. Stromatolites in a ca 600 m thick Miocene succession in the Ebro Basin are good candidates to shed light on these issues because they are intimately related to other lacustrine carbonate and sulphate facies, grew under variable environmental conditions and show distinct lamination patterns. These stromatolites are associated with wave‐related, clastic‐carbonate laminated limestones. Both facies consist of calcite and variable amounts of dolomite. Thin planar stromatolites (up to 10 cm thick and less than 6 m long) occurred in very shallow water. These stromatolites represented first biological colonization after: (i) subaerial exposure in the palustrine environment (i.e. at the beginning of deepening cycles); or (ii) erosion due to surge action, then coating very irregular surfaces on laminated limestones (i.e. through shallowing or deepening cycles). Sometimes they are associated with evaporative pumping. Stratiform stromatolites (10 to 30 cm high and tens of metres long) and domed stromatolites (10 to 30 cm high and long) developed in deeper settings, between the surge periods that produced hummocky cross‐stratification and horizontal lamination offshore. Changes in stromatolite lamina shape, and thus in the growth forms through time, can be attributed to changes in water depth, whereas variations in lamina continuity are linked to water energy and sediment supply. Growth of the stromatolites resulted from in situ calcite precipitation and capture of minor amounts of fine‐grained carbonate particles. Based on texture, four types of simple laminae are distinguished. The simple micrite and microsparite laminae can be grouped into light and dark composite laminae, which represent, respectively, high and low Precipitation/Evaporation ratio periods. Different lamination patterns provide new ideas for the interpretation of microbial laminations as a function of variations in climate‐dependent parameters (primarily the Precipitation/Evaporation ratio) over variable timescales.  相似文献   

10.
Cretaceous phosphorites from the onshore of Tamil Nadu have been investigated for their origin and compared with those in the offshore. Cretaceous phosphorites occur as light brown to yellowish brown or white nodules in Karai Shale of the Uttatur Group in the onshore Cauvery basin. Nodules exhibit phosphatic nucleus encrusted by a chalky shell of carbonate. The nucleus of the nodules consists of light and dark coloured laminae, phosphate peloids/coated grains and detrital particles interspersed between the laminae. Scanning electron microscope (SEM) studies reveal trapping and binding activity of microbial filaments. A mat structure with linearly arranged microbial filaments and hollow, cell-based coccoid cyanobacterial mat are present. Nodules contain abundant carbonate fluorapatite, followed by minor calcite, quartz and feldspar. The P2O5 content of the phosphorites ranges from 18 to 26%. The CaO/P2O5, Sr and F contents are higher than that of pure carbonate fluorapatite. Concentrations of Si, Al, K, Fe, and Ti are low. We suggest that the nuclei of the nodules represent phosphate clasts related to phosphate stromatolites formed at intertidal conditions. At high energy levels the microbial mats were disintegrated into phosphate clasts, coated with carbonate and then reworked into Karai Shale. On the other hand, Quaternary phosphorites occur as irregular to rounded, grey coloured phosphate clasts at water depths between 180 and 320m on the continental shelf of Tamil Nadu. They exhibit grain-supported texture. Despite Quaternary in age, they also resemble phosphate stromatolites of intertidal origin and reworked as phosphate clasts onto the shelf margin depressions. Benthic microbial mats probably supplied high phosphorus to the sediments. Availability of excess phosphorus seems to be a pre-requisite for the formation of phosphate stromatolites.  相似文献   

11.
The Neoproterozoic Narji Formation of Cuddapah Basin, Southern India is mainly composed of limestones with minor amount of clastic rocks. Limestones are massive as well as laminated and occasionally chert bearing. Geochemistry (major, trace, and REE) of limestones is studied to strengthen the knowledge on depositional environment of Narji Formation in the direction to better figure out the development of Cuddapah Basin during Neoproterozoic era. Average SiO2 (25.97), Al2O3/TiO2 (16.67), and K2O/Al2O3 (0.21) ratios suggest clastic contamination in the Narji limestones. PAAS (Post Archean Australian Shale) normalized REE?+?Y pattern of Narji limestones are showing seawater like REE?+?Y pattern. The Er/Nd and Y/Ho ratios (average 0.17 and 35.68, respectively) of Narji limestones indicate the retention of normal seawater character with the signatures of terrigenous input and diagenesis process. Positive Ce anomaly, high U/Th (>?1.25), and V/(V?+?Ni) (>?0.5) ratios of Narji limestones clearly indicate their deposition in dyoxic to anoxic condition.  相似文献   

12.
The uppermost Permian Chuenmuping reef formed on the western side of a carbonate platform situated in the eastern Sichuan Basin, southern China. Contrasts exist between this western patch reef and the better known Jiantianba barrier reef complex on the eastern platform margin in western Hubei Province, 250 km to the east. Microbial micritic carbonates form significant components of the Chuenmuping reef limestones. Three types of fabric can be identified: irregular, clotted and scalloped-laminated. An additional, cuneiform fabric has been found only in fore-reef facies at Jiantianba. Irregular fabric is comparable with the surface of presently forming travertines at Rapolano Terme, central Italy, which are produced by calcification of cyanobacteria. Clotted fabric shows indistinct peloids which tend to lack rims, and are amalgamated into irregular masses, some of which exhibit bush-like arrangements where traces of filaments can be seen. Traces of filaments are observed in both dark and light layers in the scalloped-laminated fabric, again suggesting a microbial origin. Cuneiform fabric consists of peloids and filaments, and closely resembles deposits in Quaternary travertines which may have been caused by bacterial action. Chuenmuping reef shows a shallowing sequence in normal marine conditions. The micritic fabrics interpreted here as microbial occur more commonly in the upper part of the reef. This indicates that microbial micrites, with a cementing role, formed coevally with reef growth within the upper part of the photic zone.  相似文献   

13.
Brian Jones 《Sedimentology》2020,67(4):1844-1878
Phosphatic limestones on the west end of Little Cayman, at an elevation of 3 to 4 m above sea level and ca 320 to 550 m inland of the coast, lie on top of a phytokarst surface that defines the upper boundary of the Pedro Castle Formation (Pliocene). These phosphatic limestones are formed of phosphatic lithoclasts, detrital phosphate grains, coated grains (glaebules), composite coated grains, biofragments and phosphate rafts that are held in a matrix that is formed of micrite, calcite cement, and non-crystalline masses formed of P, Al, Si and Fe. The phosphate in these limestones is primarily hydroxylapatite, whereas the overlying soils, found in some areas, are formed of hydroxylapatite, crandallite and minor amounts of boehemite, kaolinite and quartz. Textures in the lithoclasts and detrital phosphate grains indicate that they were derived from older insular phosphates that that were largely removed by mining in 1890 to 1895. The coated grains (glaebules) typically have nuclei formed of a detrital phosphate grains that are encased by non-crystalline cortical laminae that are composed primarily of Al with their variable red colour reflecting the variable Fe content. The phosphatic limestones developed in a low-lying coastal area where the guano produced by a large seabird colony that was close to or mixed with terra rossa and marine carbonates that were washed onshore during storms/hurricanes. The Al, Fe, Si and rare earth elements found in the phosphatic limestones came from the terra rossa. Critically, this study documents the complex depositional regimes and diagenetic processes that can exist at the interface of marine carbonates, coastal phosphates and terrestrial soils as sea-level fluctuations control phases of sediment accumulation that were periodically interrupted by periods of non-deposition.  相似文献   

14.
Major, trace and rare earth elements (REE) concentrations in limestone beds of the Asu River Group within the Middle Benue Trough were measured to understand the depositional conditions, characteristics and source of REE. The limestone has high content of CaO (Average of 46.55%), followed by SiO2 (Average of 7.90 %), Fe2O3(t), MgO and Al2O3. The limestones are depleted in most of the trace elements (Co, V, Rb, Ba, Zr, Y, Nb, Hf and Th) when compared with the Post-Archean Australian Shale (PAAS). The observed large variations in ΣREE contents among various limestones of the present study (12.22 to 142.53ppm) are mainly due to the amount of terrigenous matter present in them. The characteristics of non-seawater-like REE patterns, elevated REE concentrations, high LaN/YbN ratios and low Y/Ho ratios, suggest that the observed variations in ΣREE contents are mainly controlled by the amount of detrital sediments in the limestones of the Asu River Group in the middle Benue trough. The observed variations in Ce contents and Ce anomalies in the studied samples resulted from detrital input. The limestones show positive Mn* values (0.30 to 0.78) and low contents of U (～0.60–3.20 ppm) suggesting that they were deposited under oxygen-rich environment.  相似文献   

15.
Major, trace and rare earth elements (REE) concentration of the Eocene limestones, Jaisalmer Basin, Rajasthan, India are analysed to reconstruct the depositional conditions and to identify sources of REEs. Among the major oxides, CaO is the dominant oxide followed by SiO2 in the studied limestones. Trace element Ba dominates over the other trace elements and it shows negative correlation with CaO. The Sr, occurring in small concentration, shows positive correlation with CaO. Other trace elements such as V, Zr, Sc, Y, Rb, Ni, Pb Co, Cu, U occur in small concentrations. The studied limestones show a positive correlation of ΣREE with Fe2O3, Ni, Th, Sc, and Y. These limestones possess sea-water like shale-normalized REE + Y pattern with light REE depletion, slight Gd enrichment, slightly positive La anomaly, positive Y anomaly, positive Eu anomaly, negative Ce anomaly and superchondritic Y/Ho ratio from 23.12 to 28.57. The dominance of CaO and low percentage of MgO suggest that mineral phase is calcite and there is absence of dolomitization. The occurrence of SiO2 and Al2O3 in appreciable percentages may be because of the siliciclastic input during the limestone precipiatetion. The low concentration of Uranium (0.4-3.7) and authigenic Uranium (Average Total U-Th/3 value = 0.74) indicate that the studied limestones were precipitated in oxic condition from seawater. The depletion of LREE suggests that the limestones were precipitated from the seawater. The positive correlation of ΣREE with Al2O3 Fe2O3, Ni, Th, Sc, and Y and negative correlation with CaO suggest an input of siliciclastic sediments from the land during limestone precipitation. The negative Ce anomaly, slightly positive La anomaly, slight Gd enrichment, positive Y anomaly, and positive Eu anomaly also suggest that the limestone was precipitated from the seawater with some siliciclastic input from continent. The low values of the Y/Ho ratio (23.12 to 28.57) in the studied limestones suggest some modification of the seawater by the input of freshwater in a coastal environment. The REEs of the studied limestones are correlable with the shallow sea water REEs with exception of a few elements. We envisage a coastal/shallow marine depositional environment where mixing of the continental material in sea water appears feasible.  相似文献   

16.
The origin of fine‐grained dolomite in peritidal rocks has been the subject of much debate recently and evidence is presented here for a microbial origin of this dolomite type in the Norian Dolomia Principale of northern Calabria (southern Italy). Microbial carbonates there consist of stromatolites, thrombolites, and aphanitic dolomites. High‐relief thrombolites and stromatolites characterize sub‐tidal facies, and low‐relief and planar stromatolites, with local oncoids, typify the inter‐supratidal facies. Skeletal remains are very rare in the latter, whereas a relatively rich biota of skeletal cyanophycea, red algae and foraminifera is present in the sub‐tidal facies. Some 75% of the succession consists of fabric‐preserving dolomite, especially within the microbial facies, whereas the rest is composed of coarse dolomite with little fabric preservation. Three end‐members of dolomite replacement fabric are distinguished: type 1 and type 2, fabric retentive, with crystal size <5 and 5–60 μm, respectively; and type 3, fabric destructive, with larger crystals, from 60 to several hundred microns. In addition, there are dolomite cements, precipitated in the central parts of primary cavities during later diagenesis. Microbialite textures in stromatolites are generally composed of thin, dark micritic laminae of type 1 dolomite, alternating with thicker lighter‐coloured laminae of the coarser type 2 dolomite. Thrombolites are composed of dark, micritic clotted fabrics with peloids, composed of type 1 dolomite, surrounded by coarser type 2 dolomite. Marine fibrous cement crusts are also present, now composed of type 2 dolomite. Scanning electron microscope observations of the organic‐rich micritic laminae and clots of the inter‐supratidal microbialites reveal the presence of spherical structures which are interpreted as mineralized bacterial remains. These probably derived from the fossilization of micron‐sized coccoid bacteria and spheroidal–ovoidal nanometre‐scale dwarf‐type bacterial forms. Furthermore, there are traces of degraded organic matter, probably also of bacterial origin. The microbial dolomites were precipitated in a hypersaline environment, most likely through evaporative dolomitization, as suggested by the excess Ca in the dolomites, the small crystal size, and the positive δ18O values. The occurrence of fossilized bacteria and organic matter in the fabric‐preserving dolomite of the microbialites could indicate an involvement of bacteria and organic matter degradation in the precipitation of syn‐sedimentary dolomite.  相似文献   

17.
ABSTRACT A calcite mass more than 1·5 km long and 20 m wide crops outs along the faulted margin of the Albian carbonate platform of Jorrios in northern Spain. The mass contains abundant dissolution cavities up to 7 m long and 1 m high, filled with cross‐stratified quartz sandstone and alternating sandstone–calcite laminae. Similar cavities are also present in a 50‐m‐wide zone of platform limestones adjacent to the calcite mass that are filled with limestone breccias and sandstone. The calcite mass has mean δ18O values of 19·6‰ (SMOW), whereas platform limestones have mean δ18O values of 24·4‰ (SMOW). Synsedimentary faulting of the carbonate margin and circulation of heated fault‐related waters resulted in replacement of a band of limestone by calcite. Soon after this replacement, dissolution by undersaturated fluids affected both the calcite mass and the adjacent limestones. Percolating marine quartz sand filled all dissolution cavities, sometimes alternating with precipitating calcite. The resulting cavities and fills, which recall products of meteoric diagenesis, are attributed to a hydrothermal origin based on their geometry, occurrence along the profile and synsedimentary tectonic relationships. The early faulting and diagenesis are related to local extensional tectonism in a large‐scale strike‐slip setting. Movements occurred during the early dispar/appenninica zone of the Late Albian.  相似文献   

18.
The Mascot–Jefferson City (M-JC) Mississippi Valley-type (MVT) deposits are in the Valley and Ridge province of the Appalachian orogen in East Tennessee. They have been a major source of zinc for the USA but their age is uncertain and thus their genesis controversial. About 10 specimens from each of 37 sites have been analysed paleomagnetically using alternating field and thermal step demagnetisation methods and saturation isothermal remanence methods. The sites sample limestones, dolostones, breccia clasts and sphalerite–dolomite MVT mineralisation from mines in the Lower Ordovician Kingsport and Mascot formations of the Knox Group. The characteristic remanent magnetisation (ChRM) is carried by magnetite in the limestones, by both magnetite and pyrrhotite in the dolostones and by pyrrhotite preferentially to magnetite in the mineralisation. Mineralized sites have a more intense ChRM than non-mineralised, indicating that the mineralising and magnetisation event are coeval. Paleomagnetic breccia tests on clasts at the three sites are negative, indicating that their ChRM is post-depositional remagnetisation, and a paleomagnetic fold test is negative, indicating that the ChRM is a remagnetisation, and a post-dates peak Alleghanian deformation. The unit mean ChRM direction for the: (a) limestones gives a paleopole at 129°E, 12°N (dp=18°, dm=26°, N=3), indicating diagenesis formed a secondary chemical remanent magnetisation during the Late Ordovician–Early Silurian; (b) dolomitic limestones and dolostone host rocks gives a paleopole at 125.3°E, 31.9°N (dp=5.3°, dm=9.4°, N=7), recording regional dolomitisation at 334±14 Ma (1σ); and (c) MVT mineralisation gives a paleopole at 128.7°E, 34.0°N (dp=2.4°, dm=4.4°, N=25), showing that it acquired its primary chemical remanence at 316±8 Ma (1σ). The mineralisation is interpreted to have formed from hydrothermal fluid flow, either gravity or tectonically driven, after peak Alleghanian deformation in eastern Tennessee with regional dolomitisation of the host rocks occurring as part of a continuum during the 20 Ma prior to and during peak deformation.  相似文献   

19.
Carbonates of Mississippian age (Viséan) in the Midale Beds, Charles Formation of southeastern Saskatchewan, Canada, produce significant amounts of hydrocarbons. The Midale Beds represent deposition in a shallow-water, periodically restricted, epeiric setting. The sedimentation is characterized by a variety of shallow-water carbonate lithologies ranging from wackestone, packstone, grainstone, to microbial boundstone. Algae, calcimicrobes, and related microbial fabrics are common features in these limestones. Cores and thin sections through the Midale Beds in the Glen Ewen and Midale pools of southeastern Saskatchewan were examined in order to study the contribution of calcimicrobes and microbial fabrics to the sedimentation of Mississippian carbonate rocks in southeastern Saskatchewan. Calcimicrobes and microbial fabrics are the important components in the grainstones and microbial boundstone. The calcimicrobes are commonly found as porostromate forms, including Garwoodia sp. and Ortonella sp., and other forms such as Archaeolithoporella-like, Girvanella-like, Wetheredella-like, and problematic microbes also occur but are not common. Microbial fabrics are characterized by microstromatolites, microbial laminations, thrombolite, clotted peloids, and fenestrate forms. Calcimicrobes stabilized grains and modified and created sediments, and the related syndepositional microbial fabrics affected the development of porosity/permeability of Midale carbonates. Calcimicrobes and microbial fabrics in Midale Beds highlighted a significant account of microbial facies associated with the Mississippian carbonates worldwide.  相似文献   

20.
The Trenton Group (Late Ordovician), the youngest carbonate unit in the Taconic foreland basin of southern Quebec, is a tripartite unit with a distinctive coarse-grained middle part, the Deschambault Formation. Lithofacies of the Deschambault Formation are dominated by coarse-grained bioclastic/intraclastic limestones; finer-grained lithofacies are ubiquitous but subordinate. The complete spectrum of lithofacies indicates sedimentation ranging from above fairweather- to below storm-wave base. Skeletal components are indicative of the modern temperate-water bryomol association. Non-skeletal elements are represented by peloids and intraclasts. Accretion rates from areas of continuous sedimentation were low (<14 cm/103 years). From sedimentological and faunal evidence, it is proposed that the Late Ordovician Deschambault ramp was bathed by temperate waters. The model compares favourably with modern cool-water shelves rimming the southern edge of the Australian continent. Palaeomagnetic data locate southern Quebec in a low latitudinal setting during the Late Ordovician. Upper Ordovician facies distribution in eastern Canada and progressive disappearance of some faunal provinces through Late Ordovician time are used to conclude that the initiation of the Late Ordovician glaciation that covered most of Gondwana was instrumental in easing northward movement of cold oceanic currents. This resulted in the rapid contraction of the southern hemisphere warm-water tropical belt from a 30° latitudinal-wide zone in the early Caradoc to a 15° zone in the late Caradoc.  相似文献   

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