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1.
硫铁矿制取硫酸过程中产生大量烧渣,该渣现多大量堆存。烧渣中含铁量较高,有些含有一定量的铜等有色金属及其它有价金属,具有很大的回收利用价值。目前国内外采用重磁选、焙烧等法回收。通过对烧渣深加工的初步研究,已显示出其综合利用的前景。  相似文献   

2.
王琦 《化工矿产地质》2005,27(3):189-191
提要硫铁矿制酸后产生的大量硫酸烧渣,长期以来因种种原因未被有效利用,绝大部分被简单的排放和就地堆存,不仅占用大量土地,还常常造成周边环境的污染。如何变废为宝,使硫酸烧渣得到综合有效的循环利用,广东云浮硫铁矿企业集团公司对此进行了有益的尝试——从硫酸烧渣中回收不同级别的铁红产品及用回收的高级铁红生产铁氧体预烧料和高性能永磁铁氧体产品,取得了较好的经济效益和社会效益。  相似文献   

3.
论硫铁矿烧渣的再生与利用   总被引:8,自引:0,他引:8  
介绍硫铁矿烧渣的一般特征,再生利用现状和存在问题,提出合理利用和保护资源,维护生态环境。  相似文献   

4.
直接酸溶法浸取硫铁矿烧渣中铁的实验研究   总被引:4,自引:0,他引:4  
对常压下用盐酸直接酸溶提取硫铁矿烧渣中的铁进行了实验研究,探讨了影响硫铁矿烧渣酸溶的因素。结果表明,影响铁溶出率的主要因素为液固比、反应时间和温度;当液固比为4.0mL/g、反应温度100℃时,高速搅拌反应2h后,铁的溶出率可达72%,浸取液经进一步处理可生产氯化铁系列产品,有较好的应用前景。  相似文献   

5.
<正> 我省的硫铁矿并非现实优势矿种,但它成矿条件好,类型多,共生有多种有色金属,并伴生有贵金属、分散元素等。从长远看,综合利用、综合回收不仅能促进硫铁矿业的开发,而且可填补省内某些矿种的空白。本文就省内硫铁矿资源的一般概况、利用现状及经济评价要求谈谈其综合利用的迫切性.一、硫铁矿资源的概况及我省的利用现状(一)硫铁矿资源的一般情况硫铁矿是黄铁矿、白铁矿、磁黄铁矿的总称,是硫资源的传统来源。科学技术的发展、选冶工艺的改进为世界硫源开辟了多种途径。西方国家从含硫化氢大于0.1%的酸性天然气  相似文献   

6.
矿山固体废弃物包括废石和尾矿(渣),是重要的二次资源,特别是金矿山尾矿作为一种非常重要的二次矿产资源,更应受到重视。笔者以贵州省丹寨汞金矿的矿山固体废弃物为主要研究对象,对丹寨汞金矿区矿产资源开采及选冶过程中产生的尾矿资源潜力进行了现场调查,并对相关样品进行分析测试,初步掌握了尾矿(渣)资源基本情况及远景资源量,有两个尾矿(渣)堆金潜在资源量达800 kg;并根据丹寨汞和金多共(伴)生的特征,对丹寨排庭汞金矿老采空区矿硐壁围岩研究,发现其1~1. 5 m范围内,普遍含金或具有金矿化,具有找金的潜力,且初步分析了金资源潜力。简要地进行了尾矿(渣)"二次资源"、废弃矿硐的残留金资源综合利用可行性分析。  相似文献   

7.
硫铁矿焙烧灰渣中铊分布规律及环境效应的研究   总被引:6,自引:0,他引:6  
利用分光光度法测定了铊在硫铁矿焙烧灰、渣中的含量,探讨了含铊硫铁矿燃烧后铊在灰渣中的集散规律及其对环境影响。结果显示硫铁矿焙烧灰渣中铊含量远高于克拉克值和土壤背景值;与原矿石相比,铊在炉灰中富集,炉渣中含量减少。硫铁矿燃烧产生的含铊灰渣对环境危害增大。  相似文献   

8.
将高岭石型硫铁矿烧渣经磁化焙烧-磁选,得到w(TFe)为57.5%的铁精矿和偏高岭石为主的尾矿。利用微量热仪、差热分析(DTA)、扫描电镜(SEM)等手段研究了掺加磨细后尾矿对普通硅酸盐水泥水化硬化的影响。结果表明:主要含偏高岭石的尾矿能够明显降低水泥的水化热,吸收氢氧化钙,在水化后期改善水泥浆体的微观结构,使得水泥石更加均一密实。同时,磨细尾矿的掺入使水泥净浆的标准稠度需水量增加,凝结时间延长。当取代水泥用量达15%时,尾矿能够提高水泥胶砂的28天抗压强度。  相似文献   

9.
广东陆丰硫铁矿首次发现碲铋及多种硫盐矿物广东陆丰硫铁矿自1958年建矿以来,一直作为单独硫铁矿开采。我们在对该矿床物质组分研究过程中,首次发现硫化物、银矿物及少见复杂硫盐矿物十多种。其中AU,*g,Cu,Te,Bi等伴生元素均达到综合利用品位。尤其是...  相似文献   

10.
江苏省句容市团山硫铁矿床是中低温热液矿床,矿床规模小,形态复杂,但矿石品位高,并有可综合利用的铜、铅锌矿。本文阐述了团山硫铁矿床的矿床地质特征,提出4个有望找到矿体的物探异常区为远景区,为进一步找矿提供了依据。  相似文献   

11.
A survey of hot, acid springs in Yellowstone Park has shown that high concentrations of ferrous and ferric iron are often present. Total ionic iron concentrations in different springs ranged from less than 1 ppm to greater than 200 ppm, and up to 50% of the ionic iron was in the ferrous form. Some of these springs also have high concentrations of reduced sulfur species (S2? and S0). Significant populations of the bacterium Sulfolobus, acidocaldarius, an autotrophic organism able to live and oxidize sulfur compounds at low pH and high temperature, were present in most of these springs. The role of this organism in the oxidation of ferrous iron was investigated by incubating natural samples of water and assaying for disappearance of ferrous iron. Controls in which bacterial activity was inhibited by addition of 10% NaCl were also run. Bacterial oxidation of ferrous iron occurred in most but not all of the spring waters. The temperature optimum for oxidation varied from spring to spring, but significant oxidation occurred at temperatures of 80–85°C, but not at 90°C. Thus, 85–90°C is the upper temperature at which bacterial iron oxidation occurs; a similar upper limit has previously been reported for sulfur oxidation in the same kinds of springs. The steady-state concentrations of ferrous and ferric iron are determined by the rate at which these ions move into the spring pools with the ground water (flow rate), by the rate at which ferric iron is reduced to the ferrous state by sulfide, and by the rate of bacterial oxidation. The bacterial oxidation rate is faster than the flow rate, so that the rate of reduction of ferric iron is probably the rate-controlling reaction. In several springs, no decrease in ferrous iron occurred, even though high bacterial populations were present. It was shown that in these springs, ferrous iron oxidation occurred but the ferric iron formed was reduced back to the ferrous state again. These springs were all high in suspended sediment and the reductant was shown to be present in the sediment. X-ray diffraction revealed that the sediment contained three major ingredients, elemental sulfur, natroalunite, and quartz. Chemical analyses showed a small amount of sulfide, too little to reduce the ferric iron. Elemental sulfur itself did not reduce ferric iron but when elemental sulfur was removed from the sediment by CS2 extraction, the activity of the sediment was abolished. It is hypothesized that the sulfide present in the sediment (possibly bound to natroalunite) reacts with elemental sulfur to form a reductant for ferric iron. The results show that bacteria can have a profound influence on the ferrous/ferric ratios of geothermal systems, but that temperature and mineral composition of the water may significantly influence the overall result.  相似文献   

12.
Pore water from a wetland receiving acid mine drainage was studied for its iron and natural organic matter (NOM) geochemistry on three different sampling dates during summer 1994. Samples were obtained using a new sampling technique that is based on screened pipes of varying length (several centimeters), into which dialysis vessels can be placed and that can be screwed together to allow for vertical pore-water sampling. The iron concentration increased with time (through the summer) and had distinct peaks in the subsurface. Iron was mainly in the ferrous form; however, close to the surface, significant amounts of ferric iron (up to 40% of 2 mmol L-1 total iron concentration) were observed. In all samples studied, iron was strongly associated with NOM. Results from laboratory experiments indicate that the NOM stabilizes the ferric iron as small iron oxide colloids (able to pass a 0.45μm dialysis membrane). We hypothesize that, in the pore water of the wetland, the high NOM concentrations (>100 mg C L-1) allow formation of such colloids at the redoxcline close to the surface and at the contact zone to the adjacent oxic aquifer. Therefore, particle transport along flow paths and resultant export of ferric iron from the wetland into ground water might be possible. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

13.
酸性矿山废水(acid mine drainage,AMD)是一类pH低并含有大量有毒金属元素的废水。AMD及受其影响的环境中次生高铁矿物类型主要包括羟基硫酸高铁矿物(如黄铁矾和施威特曼石等)和一些含水氧化铁矿物(如针铁矿和水铁矿等),而且这些矿物在不同条件下会发生相转变,如施氏矿物向针铁矿或黄铁矾矿物相转化。基于酸性环境中生物成因次生矿物的形成会"自然钝化"或"清除"废水中铁和有毒金属这一现象所获得的启示,提出利用这些矿物作为环境吸附材料去除地下水中砷,不但吸附量大(如施氏矿物对As的吸附可高达120mg/g),而且可直接吸附As(III),还几乎不受地下水中其他元素影响。利用AMD环境中羟基硫酸高铁矿物形成的原理,可将其应用于AMD石灰中和主动处理系统中,构成"强化微生物氧化诱导成矿-石灰中和"的联合主动处理系统,以提高AMD处理效果和降低石灰用量。利用微生物强化氧化与次生矿物晶体不断生长的原理构筑生物渗透性反应墙(PRB)并和石灰石渗透沟渠耦联,形成新型的AMD联合被动处理系统,这将有助于大幅度增加处理系统的寿命和处理效率。此外,文中还探讨了上述生物成因矿物形成在AMD和地下水处理方面应用的优点以及今后需要继续研究的问题。  相似文献   

14.
长江口外悬浮颗粒物中自生纤铁矿和胶黄铁矿   总被引:1,自引:0,他引:1       下载免费PDF全文
范德江  陈彬  王亮  孙晓霞  刘明  杨作升 《地球科学》2014,39(10):1364-1370
以2010年11月“长江口及东海海洋综合考察”的基金委公共航次期间采集的长江口外不同站位的水体悬浮体颗粒为对象,使用扫描电镜和能谱仪相结合的方法对其进行了系统观察和研究,发现了铁氧化物和铁硫化物两种自生矿物集合体.铁氧化物集合体由纤铁矿微晶构成,形态不规则;铁硫化物集合体由大小均一的胶黄铁矿微晶构成,呈莓球状.纤铁矿的形成与周围水体的物理化学条件相关,而胶黄铁矿的形成则与有机质包裹的局部微环境有关.水体中所形成的两类自生铁矿物沉降到海底后,会受到底质物理化学条件的制约.本研究表明陆架泥质沉积体中的一部分莓球状铁硫化物属于水体沉积成因,当利用沉积物中黄铁矿莓球体进行环境分析时,需要充分考虑该部分自生铁硫化物的影响.   相似文献   

15.
The distribution of iron in a 6-m core of post-glacial sediment from an oligotrophic lake (Connistonwater, England) was determined, principally by Mossbauer spectroscopy on dried samples. The immediate post-glacial deposits contain 4.8 wt. % of iron, with a Fe2+; Fe3+ ratio ~- 4. The iron there is predominantly in the form of chlorite, but there are small amounts in hematite and illite. The distribution of iron is different, and very variable in the recent sediments (~ < 13,000 BP), which contain 25–35 per cent organic matter and 5.2 wt. % of iron relative to the inorganic fraction. Typically half the iron is present there as chlorite, and the rest is ferric, mostly in the form of an amorphous gel which is also present in undried samples. To explain the observed ferrous:ferric profile, it is proposed that the latter includes iron which was once mobile, having been leached from the Fe2+-bearing clays under reducing conditions in the soils of the drainage basin, or in the sediment itself. It was subsequently precipitated as ferric hydroxide on contact with the oxic lake water. In contrast, the ferrous iron in the sediments is immobile iron, which remained locked in the chlorite phase of the clay particles as they were carried from soil to sediment intact.All the sediments are rather inhomogeneous. Chlorite, and especially hematite, are mechanically concentrated in pink varves in the immediate post-glacial deposits. In the partly inorganic sediments, the concentration of ferrous iron (chlorite) is approximately uniform, but the ferric content may differ by a factor of five between regions only a few millimeters apart.  相似文献   

16.
Many features of the magma-hydrothermal interface are directly observable in, near seafloor hydrothermal systems at mid-ocean ridges. A striking aspect observed at that interface is the spontaneous redox reaction that occurs during rapid crystallization of basaltic magma, which results in generation of highly reducing hydrothermal fluids. A consequence of the reaction is that the ferric/ferrous ratio observed in the resulting crystalline basalt is much higher than it was in the basaltic magma, the redox state of the magma inferred from the ferric/ferrous ratio in the crystalline rock is considerably higher than it was in the magma [Earth Planet. Sci. Lett. 79 (1986) 397]. Magnetite-ulvöspinel is the only ferric iron-containing phase observed in the crystalline portion of the basalt. This suggests that the driving force for that reaction is related to the stability of magnetite relative to the FeO component in the basaltic liquid (or glass), resulting in the oxidation of ferrous iron by H2O dissolved in the melt, yielding magnetite, releasing H2 from the system. This is an auto-oxidation reaction in which all reactants are present internally in the basalt magma prior to crystallization. H2O is the limiting reagent for magnetite formation in the case of MORB magma. If a similar auto-oxidation occurs in the more silicic magmas commonly associated with terrestrial hydrothermal ore deposits, it would have important consequences for the interpretation of the redox condition existing at terrestrial magma-hydrothermal interfaces. Glassy I-type dacites extruded on the seafloor in the Manus Basin have ferric/ferrous ratios that are significantly lower than in I-type plutons, terrestrial volcanics. The ferric/ferrous ratios in the Manus Basin dacites yield oxygen fugacities from about one to more than two log units below that of nickel–nickel oxide. Oxidation of ferrous iron in these silicic magmas is predicted to generate an amount of H2 that is proportional to the amount of ferrous iron present, rather than the amount of H2O (as in the case of MORB) due to the high ratio of H2O to ferrous iron in silicic magmas. These relatively reduced dacitic magmas would yield significant quantities of H2 on crystallization, which would make hydrothermal fluids at the interface strongly reducing, thus affect the speciation in fluids at the magma-hydrothermal interface.  相似文献   

17.
The Mars Global Surveyor, Mars Exploration Rover, and Mars Express missions have stimulated considerable thinking about the surficial geochemical evolution of Mars. Among the major recent mission findings are the presence of jarosite (a ferric sulfate salt), which requires formation from an acid-sulfate brine, and the occurrence of hematite and goethite on Mars. Recent ferric iron models have largely focused on 25 °C, which is a major limitation for models exploring the geochemical history of cold bodies such as Mars. Until recently, our work on low-temperature iron-bearing brines involved ferrous but not ferric iron, also obviously a limitation. The objectives of this work were to (1) add ferric iron chemistry to an existing ferrous iron model (FREZCHEM), (2) extend this ferrous/ferric iron geochemical model to lower temperatures (<0 °C), and (3) use the reformulated model to explore ferrous/ferric iron chemistries on Mars.The FREZCHEM model is an equilibrium chemical thermodynamic model parameterized for concentrated electrolyte solutions using the Pitzer approach for the temperature range from <−70 to 25 °C and the pressure range from 1 to 1000 bars. Ferric chloride and sulfate mineral parameterizations were based, in part, on experimental data. Ferric oxide/hydroxide mineral parameterizations were based exclusively on Gibbs free energy and enthalpy data. New iron parameterizations added 23 new ferrous/ferric minerals to the model for this Na-K-Mg-Ca-Fe(II)-Fe(III)-H-Cl-SO4-NO3-OH-HCO3-CO3-CO2-O2-CH4-H2O system.The model was used to develop paragenetic sequences for Rio Tinto waters on Earth and a hypothetical Martian brine derived from acid weathering of basaltic minerals. In general, model simulations were in agreement with field evidence on Earth and Mars in predicting precipitation of stable iron minerals such as jarosites, goethite, and hematite. In addition, paragenetic simulations for Mars suggest that other iron minerals such as lepidocrocite, schwertmannite, ferricopiapite, copiapite, and bilinite may also be present on the surface of Mars. Evaporation or freezing of the Martian brine led to similar mineral precipitates. However, in freezing, compared to evaporation, the following key differences were found: (1) magnesium sulfates had higher hydration states; (2) there was greater total aqueous sulfate (SO4T = SO4 + HSO4) removal; and (3) there was a significantly higher aqueous Cl/SO4T ratio in the residual Na-Mg-Cl brine. Given the similarities of model results to observations, alternating dry/wet and freeze/thaw cycles and brine migration could have played major roles in vug formation, Cl stratification, and hematite concretion formation on Mars.  相似文献   

18.
Recent iron sediments forming at present in a bay of the volcanic island Palaea Kameni within the caldera of Santorini, Aegean Sea, have been investigated for their mineralogy and geochemistry. For the first time siderite has been found in a marine environment to be major constituent of a recent sediment. Further main constituents are opal, ferric hydroxide, vivianite, ferrous hydroxide, and possibly ferrous silicate. The chemical composition both of the solid material of the sediment cores and of their pore solution indicate that the ore forming solutions have originated from the leaching of volcanic kalk-alcaline rocks by hot acid solutions. This is in agreement with experimental leaching of these rock types. No enrichment of lead, copper, zinc etc. was found in the sediments. Iron oxidizing bacteria in the reddish-brown ferric hydroxide sediments now forming in bays of the Kameni Islands have been studied by light and electron microscopic investigations. Samples from the uppermost parts of the sediment consist mainly of the ferric hydroxide stalks of the iron bacteriumGallionella ferruginea. The stalks showing their morphological characteristics occur in such masses that there is no doubt concerning the presence, activity and share of these bacteria in the process of iron sedimentation. Phases of sedimentation process and kinetics of ferric hydroxide stalk formation have been determined qualitatively and quantitatively by in-situ-experiments using artificial growing surfaces (underwater “Aufwuchs” on glass slides). The results obtained are compared to similar iron sedimentation in fresh water habitats and iron rich carbonate springs discussed in literature in connection with the problem of submarine exhalative sedimentary iron ore formation.  相似文献   

19.
含金黄铁矿在细菌氧化、化学氧化过程中,除生成高铁的硫酸盐和硫酸外,还生成了亚铁的硫酸盐及硫的低价氧化物,体系中的电位较低,距溶解自然金呈Au(SO_4)_2~-所需电位甚远,实验表明,金不溶于硫酸铁溶液中。当氧化程度加深,介质pH>4,黄铁矿氧化产生的硫代硫酸根可稳定存在时,自然金呈稳定的硫代硫酸盐配合物溶解。  相似文献   

20.
蓝藻聚铁作用的模拟实验   总被引:3,自引:0,他引:3       下载免费PDF全文
实验模拟前寒武纪大气的高二氧化碳分压(PCO2),低氧浓度条件下,加入较低浓度(6μg/g)铁的Zarronk培养液培养蓝藻Spirulina platensis,观察铁的沉淀与凝聚。藻在生长过程中不断改变环境的离子平衡系统以及pH,Eh等,造成铁的氧化、还原、络合和Fe3+沉淀。实验组与未加蓝藻的对照组有显著差别。实验证实藻在聚铁和铁矿形成中起重要作用。  相似文献   

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