共查询到19条相似文献，搜索用时 109 毫秒
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投加粉末活性炭对MBR运行性能的影响 总被引：4，自引：0，他引：4
试验研究比较了在相同的进水和运行条件下,反应器1(投加粉末活性炭,投加量为12.3 g,使其质量浓度达到1 100 mg/L)和反应器2(未投加粉末活性炭)的膜透水性及对污染物的去除效果,并分析了粉末活性炭可以提高膜过滤性能的相关机理。试验结果表明：反应器1的膜通量衰减速率明显小于反应器2;投加粉末活性炭改变了混合液的性质,也大大降低了混合液中胞外聚合物和微细胶体的含量,从而减缓了膜通量的下降速度,可以使系统长时间地以相对高的膜通量运行。 相似文献
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采用天然碳酸钙中和烟气吸收酸性废水,研究中空纤维结晶膜蒸馏技术对中和后废水处理的效果。考察了料液温度、起始浓度、流速、pH值等因素对膜通量的影响。在选定的条件下对水样进行连续膜蒸馏处理。结果表明,在料液温度50℃,料液速度为18.5mL/min,pH值为7,运行18h后,浓缩溶液开始出现结晶,结晶效果较好。截留率均接近100%。 相似文献
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膜分离技术处理皂素酸性废水的试验研究 总被引：1，自引：0，他引：1
黄姜皂素酸性废水的Cl-、COD高、酸性强,治理难度大,采用纳滤NF(nanofiltration)、反渗透RO(reverse osmosis)过滤组合处理黄姜皂素酸性废水的试验表明:黄姜皂素酸性废水通过石灰中和、MF保安过滤预处理,再进行NF、RO组合处理,其COD可从25 000～50 000 mg/L降至200 mg/L以下,达到国家废水综合排放二级标准,并从废水中回收部分淀粉糖用作工业碳源.同时分析了NF、RO试验过程中膜通量变化的影响因素,为NF、RO组合处理皂素废水的膜运行参数确定提供了依据. 相似文献
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南海北部1987年9月～1988年10月沉积物捕获器中颗粒物质和硅藻通量的季节性变化受到季风气候的控制.颗粒物质与硅藻在东北和西南季风盛行期增加,在季风转变期减少.浅层和深层的颗粒总通量、蛋白石通量、碳酸钙通量、蛋白石/颗粒总通量比值、碳酸钙/颗粒总通量比值、有机碳/磷的比值以及浅层硅藻Thalassionema nitzschioides、Coscinodiscus excentricus、Coscinodiscus nodulifer、Nitzschia marina和Rhizosolenia bergonii的通量在东北季风期间明显地增加了,这些变化可能与1987年～1988年发生的EINino事件相关. 相似文献
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应对“双碳”目标,加强岩溶石漠化综合治理工作,地下水是关键。为探究重庆市酉阳县龙潭槽谷石漠化治理区岩溶泉的流量衰减及无机碳通量变化特征,采用流量衰减方程与水化学径流法对研究点老泉进行模拟与分析。结果表明：(1)老泉的流量衰减分为两个亚动态,衰减系数分别为0.089 2、0.019 6,其具有双重性含水介质特征。(2)暴雨期老泉的碳通量随流量变化的特征明显;而伏旱期(7月底-8月底)老泉的碳通量与土壤CO2、泉水CO2均具有明显的昼夜变化特征,表现为夜间低、日间高。(3)老泉夏季的碳通量与降水量呈正相关(R=0.78),与蒸发量呈负相关(R=-0.36),气候的不稳定性变化对碳通量影响显著。老泉的月HCO-3浓度与月土壤CO2浓度的相关系数为0.64,HCO-3敏感地响应土壤CO2的变化;而老泉年碳通量与年土壤CO2浓度的相关系数为0.90,且年均δ13CDIC... 相似文献
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研发了一种用于铀同位素比值α能谱分析的磷化膜制源新技术。试验发现,当镍镀片面积为3.14cm2,盐酸浓度为0.5mol/L,氯化钠浓度为2.5mol/L,磷酸二氢钾浓度为0.08mol/L,抗坏血酸浓度为20g/L,溶液体积为25 mL,恒温90℃,振荡速率为160次/min,振程20 mm时,磷化膜制源70min,200μg以下的铀可在镍箔上定量转化为磷化膜。与传统的电沉积制源技术相比较,应用磷化膜制源技术进行测量源制备时无需电沉积装置,制源过程简单快速,工效高,大量共存的232 Th、230 Th、226 Ra、231Pa等核素均不产生干扰,铀的全程回收率接近100%,α能谱峰分辨率较好。 相似文献
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为优化高负荷生物絮凝-膜反应器（HLB-MR）的工艺参数，提高其资源化城市污水的效能，采用平行对比实验，考察了不同固体停留时间（tSR）条件下反应器的有机物去除效率、生物絮凝效果、有机物回收效果和膜污染情况。结果表明：在tSR分别为0.2、0.6、1.0 d时，HLB-MR反应器有机物去除效率均在85%以上，其出水化学需氧量（COD）质量浓度均保持在30 mg/L左右；反应器内的生物絮凝效果随着tSR的延长而增强，其胶体COD絮凝效率从tSR为0.2 d时的66%增加到tSR为1.0 d时的95%，与此同时，有机物的矿化损失率也逐渐增加，从tSR为0.2 d时的6.9%增加到tSR为1.0 d时的10.5%，总COD的回收率逐渐降低；反应器内浓缩液的膜污染潜势随着tSR的延长逐渐缓解，这与较长tSR条件下反应器内胞外聚合物（EPS）产量较高、生物絮凝效果较好、微细颗粒（0~1 μm）的颗粒浓度较低有关。经过综合对比分析，0.6 d为反应器较优的tSR参数，在该条件下，胶体COD的絮凝效率高达90%，膜污染程度较轻；总COD的矿化损失率低至7.4%，总COD的回收率（忽略膜清洗时有机物损失）可高达80%以上。 相似文献
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大尺度水热通量观测系统的研制 总被引：1，自引：0，他引：1
基于闪烁理论、孔径平均效应及莫宁-奥布霍夫相似理论(MOST),成功研制了大尺度水热通量观测系统样机YZ01,该系统主要由发射器、接收器、云台、瞄准器、气象传感器、数据采集器、数据处理软件、远程无线数据传输模块、太阳能供电系统等部分组成.该系统发射器平均功耗3W,接收器功耗1.8 W,比德国的BLS450和荷兰的LAS都更省电;发射器光源功率为100 mW,比荷兰LAS的80 mW更强,在同样条件下,YZ01接收器接收到的闪烁光解调信号比荷兰LAS强14%左右,说明在相同的安装距离下,YZ01比荷兰LAS更适于在能见度低的条件下使用,或者说在同样的环境条件下,YZ01比荷兰LAS可以测量更远的距离.YZ01在北京密云站与荷兰Kipp＆Zonen公司的LAS、美国Campbell公司的涡度相关测定系统进行了短期的应用对比试验,结果为:空气折射指数的结构参数Cn2、感热通量H、潜热通量LE的日变化趋势都非常一致;YZ01与LAS之间Cn2的线性拟合系数为0.98,相关系数为0.7;H的线性拟合系数为0.90,相关系数为0.93;YZ01通过余项法算出的LE与涡度相关直接测得的LE的线性拟合系数为1.07,相关系数为0.78.YZ01在青海阿柔站与德国Scintec公司的BLS450进行对比结果为:空气折射指数的结构参数Cn2、感热通量H、潜热通量LE的日变化变化趋势也都非常一致,YZ01与BLS450之间Cn2的线性拟合系数为1.25,相关系数为0.93;H的线性拟合系数为1.17,相关系数为0.99;YZ01通过余项法算出的LE与涡度相关测定系统测得的LE的线性拟合系数为1.03,相关系数为0.84.表明该研究所研制的大尺度水热通量观测系统不仅可以达到国外同类仪器同样的应用水平,而且比国外同类产品更省电、比荷兰LAS更适应在低能见度条件下使用. 相似文献
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H. S. Erkan G. O. Engin B. Kulil G. Gunalp 《International Journal of Environmental Science and Technology》2017,14(5):933-942
The properties of activated sludge are very important in a membrane bioreactor (MBR) in terms of membrane fouling. The most important parameters affecting the membrane fouling can be listed as mixed liquor suspended solid (MLSS) concentration, soluble microbial products (SMPs), extracellular polymeric substances (EPSs), floc size, aeration and viscosity of both supernatant and activated sludge. The COD/TKN ratio also affects the physical properties of sludge in MBR system. This study aimed to investigate the effect of chemical oxygen demand-to-total Kjeldahl nitrogen (COD/TKN) ratio of feed wastewater treated in an MBR on biological components of activated sludge. The activated sludge characteristics were determined by quantitative analyses such as MLSS, EPS, SMP, floc size distribution, zeta potential, relative hydrophobicity and capillary suction time in a submerged MBR treating simulated wastewater having different COD/TKN ratios (16, 56 and 107). The COD and TKN removal efficiencies were found to be almost equal in the sMBRs having different COD/TKN ratios. However, it was seen that the EPS content and SMP concentration in the supernatant increased with increasing COD/TKN ratio. The results indicated that the COD/TKN ratio of feed should be considered as an effective parameter on activated sludge properties in sMBR systems. 相似文献
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M. Sajjad K. S. Kim 《International Journal of Environmental Science and Technology》2016,13(7):1697-1706
In this study, sodium oxalate was employed to extract extracellular polymeric substances (EPS) from activated sludge samples. The optimum dose of sodium oxalate was 1.34 g/g VSS (volatile suspended solids), and the extraction time was 60 min at pH 7. The total EPS contents obtained under the optimized conditions were approximately 191 mg/g VSS, and they predominantly consisted of proteins, polysaccharides and humic substances. The extraction efficiencies of the chosen method for the major biopolymers were 39, 43 and 410 % higher compared with the ethylenediaminetetraacetic acid (EDTA), cation exchange resin and control methods. Cell lysis measured in terms of deoxyribonucleic acid, and unidentified EPS were approximately 50 % lower in the sodium oxalate method than in the NaOH and EDTA methods. The EPS composition and the ratio of proteins/polysaccharides (1.38–2.21) were extremely dependent on the operating conditions maintained during the extraction. The inductively coupled plasma spectroscopic results demonstrated that the release of divalent metals, such as Ca2+ and Mg2+, from the sludge matrix was directly correlated with higher EPS extraction efficiencies in the sodium oxalate protocol. Moreover, the precipitation of Ca2+ and Mg2+ as metallic oxalates disrupted the floc structure and subsequently enhanced the EPS recovery. Fourier transform infrared studies revealed the presence of functional groups due to EPS molecules in all extracted samples. 相似文献
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Entrapment of clay particles enhances durability of bacterial biofilm-associated bioclogging in sand 总被引：1，自引：0，他引：1
Acta Geotechnica - Utilization of bacterial biofilms and extracellular polymeric substances (EPS) for engineered bioclogging has recently garnered increasing attention in various geotechnical... 相似文献
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铁细菌胞外多聚物对铁矿物的调控形成及其环境意义 总被引：1，自引：0，他引：1
环境介质溶液中铁的水解作用和稳定化作用主要受铁细菌及其代谢有机物质的影响。铁细菌普遍存在于自然环境中,可利用低价铁源为自身生长所需能量。铁细菌胞外有机物的主要组分如多糖和蛋白质等可与铁结合,并通过氧化或沉淀作用使铁稳定、沉积而形成铁矿物;此外铁细菌胞外多聚物可催化铁的氧化或促进铁的聚集。这些生物成因铁矿物因具有良好的表面吸附与氧化还原等化学活性,及有效固定环境中的重金属、放射性核素和催化降解有机污染物的良好环境属性,在环境生物矿物材料和环境治理研究领域被日益重视。故本文基于铁细菌及其胞外多聚物对铁矿物矿化形成的重要调控作用,介绍了环境中存在的铁细菌及其生物矿化特征,重点阐述了铁细菌胞外多聚物(组分、结构及特性)及其在铁矿物矿化过程中的作用,同时对铁细菌胞外多聚物及生物成因铁矿物的环境意义进行了概述。 相似文献
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白云岩有机成因模式:机制、进展与意义 总被引：4，自引：3，他引：1
白云岩是一种常见的碳酸盐岩,它广泛分布在古代碳酸盐岩台地中,却很少见于全新世沉积物中,这构成了一个未解之谜。近20多年的研究成果表明,早期成岩过程中微生物参与的硫酸盐还原反应、甲烷生成和厌氧氧化反应以及有氧呼吸作用能够促进白云石的沉淀:细菌细胞和胞外聚合物(EPS)带有负电荷,能够聚集溶液中Mg2+和Ca2+;同时上述氧化还原反应产生HCO3-,提高了孔隙水中反应物的浓度;这样在细菌细胞周围形成一个对白云石超饱和的微环境,有利于白云石的沉淀。这是一种新的白云石成因模式,微生物活动和有机质是影响白云石形成最重要的因素,特殊的球状形态和碳同位素特征是鉴别有机成因白云石的重要标志。白云岩有机成因模式为认识地质历史时期大套白云岩的成因、探索"白云岩之谜"提供了新的思路。 相似文献
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Environmentally friendly options for restoring limestone using microorganisms have attracted recent attention. The governing principle of this technique is to use the metabolism of microorganisms to precipitate carbonate in the gaps of mineral particles; this process is known as microbial carbonate precipitation (MCP). Here, an outcrop associated with MCP under natural conditions at the Giza cliff in Okinawa, Japan was investigated. Colonies of photoautotrophic microorganisms containing chlorophyll were found inhabiting a layer of limestone 2–4 mm below the surface of the outcrop. These microorganisms survived and photosynthesised within the limestone under favorable conditions that include an effective photon flux density of 15–75 µmol/m2/s, and some fresh calcium carbonates (i.e., calcite) were precipitated around the cell walls and extracellular polymeric substances (EPS) of the microorganisms. Furthermore, the results of powder X-ray diffraction (XRD) suggest that the synthetic calcite within the limestone may improve the mechanical strength of the outcrop. These in situ and laboratory findings indicate that these microbial functions may be applicable to some weathered rock surfaces as a self-organizing surface protection and conservation technology. 相似文献
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The effect of cell wall-associated extracellular polymeric substances (EPS) of the Gram-negative bacterium Shewanella oneidensis strain MR-1 on proton, Zn(II), and Pb(II) adsorption was investigated using a combination of titration/batch uptake studies, surface complexation modeling, attenuated total reflectance - Fourier transform infrared (ATR-FTIR) spectroscopy, and Zn K-edge extended X-ray absorption fine structure (EXAFS) spectroscopy. Both unmodified (wild-type (WT) strain) and genetically modified cells with inhibited production of EPS (ΔEPS strain) were used. Three major types of functional groups (carboxyl, phosphoryl, and amide groups) were identified in both strains using ATR-FITR spectroscopy. Potentiometric titration data were fit using a constant capacitance model (FITEQL) that included these three functional groups. The fit results indicate less interaction of Zn(II) and Pb(II) with carboxyl and amide groups and a greater interaction with phosphoryl groups in the ΔEPS strain than in the WT strain. Results from Zn(II) and Pb(II) batch adsorption studies and surface complexation modeling, assuming carboxyl and phosphoryl functional groups, also indicate significantly lower Zn(II) and Pb(II) uptake and binding affinities for the ΔEPS strain. Results from Zn K-edge EXAFS spectroscopy show that Zn(II) bonds to phosphoryl and carboxyl ligands in both strains. Based on batch uptake and modeling results and EXAFS spectral analysis, we conclude that the greater amount of EPS in the WT strain enhances Zn(II) and Pb(II) uptake and hinders diffusion of Zn(II) to the cell walls relative to the ΔEPS strain. 相似文献
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Cd adsorption onto Pseudomonas putida in the presence and absence of extracellular polymeric substances 总被引：1，自引：0，他引：1
Masato Ueshima 《Geochimica et cosmochimica acta》2008,72(24):5885-5895
The role of bacterial extracellular polymeric substances (EPS) in metal adsorption was determined by studying Cd adsorption onto the gram-negative bacterial species Pseudomonas putida with and without enzymatic removal of EPS from the biomass material. A range of experimental approaches were used to characterize the Cd adsorption reactions, including bulk proton and Cd adsorption measurements, FTIR spectroscopy, and fluorescence microscopy. The proton-reactivities of the biomass samples with EPS are not significantly different from those obtained for EPS-free biomass. Similarly, the presence of EPS does not significantly affect the extent of Cd removal from solution by the biomass on a mass-normalized basis, based on bulk Cd adsorption measurements conducted as a function of pH, nor does it appear to strongly affect the Cd-binding groups as observed by FTIR. However, fluorescence microscopy indicates that Cd, although concentrated on cell walls, is also bound to some extent to EPS. Together, the results from this study suggest that the P. putida EPS can bind significant concentrations of Cd from solution, and that the nature and mass-normalized extent of the binding is similar to that of the cell wall. Therefore, the EPS-bearing systems do not exhibit enhanced mass-normalized removal of Cd from solution relative to the EPS-free systems. The presence of the EPS effectively increases the viability of cells exposed to aqueous Cd, likely due to sequestration of the Cd away from the cells due to Cd-EPS binding. 相似文献
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矿物材料对废水厌氧处理及厌氧污泥改性具有十分重要的作用,而微生物代谢产物是生物处理系统的重要组分,在提高污染物去除率和甲烷产量等方面也起到非常重要的作用。本研究对矿物材料石墨和厌氧微生物共存体系内溶解性微生物产物(soluble microbial product,SMP)和胞外聚合物(extracellular polymeric substances,EPS)进行了分析表征。结果表明,石墨对EPS和SMP的组成和含量影响显著,主要是由于石墨的吸附作用及其对石墨颗粒的环境毒性所致。红外光谱分析表明,添加石墨体系内SMP与EPS的基团种类并未发生明显改变,但含量有所改变。三维荧光分析结果显示,SMP的主要荧光类物质为色氨酸类似物和腐殖质(辅酶NADH),而EPS的主要荧光类物质为色氨酸类似物和腐殖酸,石墨能明显降低色氨酸类似物及腐殖酸类物质的产生。石墨会减弱微生物的相对疏水性,提高表面自由能,有利于微生物团聚体的形成。 相似文献