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1.
The study presents the results of Cu, Pb, Zn, Mn and Fe determination in the samples of bottom sediments collected from the Oder and Warta rivers. The sequential extraction of metals in the samples of bottom sediments was performed after introducing the modification of the extraction scheme suggested by Tessier et al. (Anal Chem 51(7):844–851, 1979). The extraction times of particular stages were optimised. The fifth stage was altered by introducing the new methods of performing extraction. The samples of bottom sediments submitted the following granulometric analyses: dry, wet and wet with (HMP) dispersing reagent. Seven granulometric fractions with the following grain sizes were isolated: >2.0, 2.0–1.0, 1.0–0.5, 0.5–0.25, 0.25–0.1, 0.1–0.063 and <0.063 mm. The sequential extraction of particular granulometric fractions was performed. The concentration of metals variability was analysed depending on the method of sample preparation for the chemical analysis, granulometric fraction of sediments subjected to the analysis, extraction conditions and the site of samples collection. The lack of linearity between the metal concentration and the size of granulometric fraction was observed. The highest concentrations of metals were observed in fractions >2.0, 2.0–1.0 and 0.1–0.063 and <0.063 mm while the lowest concentrations occurred in fractions 1.0–0.5, 0.5–0.25, and 0.25–0.1 mm. The atomic absorption spectrometry with flame atomisation (F-AAS) was used for the determination of the investigated elements.  相似文献   

2.
Effects of saline water irrigation on soil properties in northwest China   总被引：2，自引：1，他引：1  
Due to the lack of freshwater, highly saline groundwater was the main irrigation source in the last few decades in the Minqin Basin, which is in northwest China. The study evaluates the effects of salt accumulation on the soil physical–chemicals properties. Undisturbed and disturbed soil samples were taken from the experiment site, which was irrigated with saline water at a concentration of 0.8, 2 and 5 g L−1 (coded later as C08, C2 and C5). Undisturbed soil samples, at depths of 0–45 and 45–60 cm were taken to determine the water retention curve (WRC). Moreover, in the same place, another set of undisturbed soil samples were taken to determine the porosity and pore-size distribution (PoSD). From the WRC, the water-holding capacity of the soil was estimated. Disturbed soil samples at depths of 0–20, 0–45, 45–60 and 80–100 cm were taken to determine the index of aggregates stability in water (IC). The electrical conductivity of the saturated paste (ECe) was determined at depths of 0–30, 30–60 and 60–90 cm, during the irrigation season on C08, C2 and C5 treatments. The results show that the total porosity and the index of aggregates stability in water decrease with the increasing salinity of irrigation water, and the ECe increases with the increasing salinity of irrigation water especially in the surface soil. The water-holding capacity (WHC) of soil also increases with the increasing salinity of irrigation water.  相似文献   

3.
The adsorption behaviour of uranyl onto seven different samples of quartz was studied in batch experiments. Sea-sand (0.1–0.3 mm), Fil-Pro 12/20 (1–2 mm) and five Min-U-Sil samples with smaller particle sizes (5, 10, 15, 30 and 40 μm) were used. The uptake curves show “pH adsorption edges” in the range of pH 4–5. A good agreement of the new data with literature data was found when plotting surface-normalised distribution coefficients versus pH. Differences in the adsorption behaviour for pre-treated and untreated sea-sand samples were detectable resulting in a shift of the pH edge to higher pH values after treatment. A literature surface complexation model was applied for blind predictions of the experimental results. The simulations described the experimental observations quite well for the Min-U-Sil samples. For the two coarser quartz samples, the calculated over-predictions were explained by the larger-than-expected measured specific surface area and measurable amounts of associated minerals, for Fil-Pro 12/20 and sea-sand, respectively. Dissolution of the samples was studied as a function of pH. After 5 days, the measured Si concentrations were all higher than equilibrium quartz solubilities, but lower than those of amorphous silica. With increasing pH, dissolved silica increased. This strongly suggests that formation of dissolved uranyl–silicato complexes have to be considered based on measured silica concentrations.  相似文献   

4.
Phosphorus (P) species concentrations in 0–2 cm surface sediment layer were investigated monthly from November 2001 to December 2002 at the bay, channel and open sea stations in the middle Adriatic. Modified SEDEX method was used for inorganic phosphorus species determination [P in biogenic (P-FD), authigenic (P-AUT), detrital apatite (P-DET) and P adsorbed on to iron oxides and hydroxides (P–Fe)], and organic phosphorus (P-ORG). P-FD, P-AUT and P-DET concentration ranges (1.5–5.4, 0–2.7 and 0.4–3.4 μmol g−1, respectively) were similar at all stations, and showed no obvious common trend of seasonal changes. P–Fe ranged from 1.9 to 11.9 μmol g−1 with the highest values at bay station and higher seasonal oscillations than other inorganic P forms. P-ORG ranged from 0.3 to 18.7 μmol g−1 with higher concentrations at stations of fine-sized sediments and showed increased concentrations in warm part of the year at all stations. Correlation between concentrations of P–Fe in the surface sediment layer and orthophosphate sediment-water interface concentration gradients at bay and channel stations indicated to P–Fe importance in the orthophosphate benthic flux. For the bay station, linkage between sediment P-ORG and chlorophyll a concentrations, primary production and microzooplankton abundance was established, indicating a 1 month delay of sediment response to production fluctuations in the water column.  相似文献   

5.
In order to characterize the post-Svecofennian tectonothermal evolution of the Fennoscandian Shield, 40Ar–39Ar biotite and some 40Ar–39Ar muscovite geochronological data are reported from a total of 30 surface outcrop and 1,000 m long borehole samples at Forsmark, central Sweden. The 13 surface samples were collected across 3 branches of a major WNW to NW trending system of deformation zones, whereas the boreholes were drilled within a tectonic lens, in between two of these zones. The 40Ar–39Ar biotite ages indicate that the present erosion surface, in central Sweden, cooled below c. 300°C at 1.73–1.66 Ga, and that the rocks could have accommodated strain in a brittle manner between 1.8 and 1.7 Ga. The variation in surface ages is suggested to be due to fault along the large WNW to NW trending deformation zones, following the establishment of a sub-Cambrian peneplain. The minor variation of ages within a single crustal block may be due to disturbance along ENE to NNE trending fracture zones. Possible cooling paths, derived from 40Ar–39Ar hornblende, muscovite and biotite ages, were calculated for the time interval from 1.80 to 1.67 Ga, when the area cooled from c. 500 to 300°C. Cooling rates of 1.9–4°C/m.y. have been attained. Between 1.68 and 1.64 Ga, uplift rates of c. 22 m/m.y. were calculated from borehole 40Ar–39Ar biotite data. Tectonothermal histories, inferred from the combined cooling and uplift rates, are related to simple cooling after the Svecofennian orogeny, to crustal movement in response to far-field effects of c. 1.7 Ga orogenic activities further to the west or to a combination of these possibilities.  相似文献   

6.
The compressibilities of two synthetic glaucophane samples were measured over the range of 0–10 GPa at ambient temperature in a diamond-anvil cell at the Cornell High-Energy Synchrotron Source (CHESS). The pressure–volume data were fitted to the Birch–Murnaghan equation of state taking care to include only data with a minimum of deviatoric stress. When using a second-order truncation, both samples yielded essentially identical values of the bulk modulus K 0, which had an average value of 91.8 ± 1.3 GPa. Maximum compression was observed approximately along the a* axis as shown by the strain ellipsoid and supported by the a axis showing the highest compressibility. These results agree closely with the earlier study of a natural glaucophane single-crystal by Comodi et al. (Eur J Mineral 3:485–499, 1991), suggesting that the substitution of about 20–30 mol.% of Fe for Mg and Al in the structure may not significantly change its compressibility.  相似文献   

7.
Surface soil and sediment samples were collected from the surroundings of the Ittehad Chemical Industries Kalashah Kaku industrial zone to assess residual level of 19 organochlorine pesticides (OCPs) and identify their sources. DDTs and HCHs were most prevalent OCPs and general pattern of contamination followed the order: ∑DDT > ∑HCH > dicofol > endrin > heptachlor > dieldrin > endosulfan II. Total measured concentrations of HCHs (6.38–121.71 ng/g) and DDTs (759.65–1811.98 ng/g) were greater in the soil samples collected from fodder/rice fields irrigated with the factory effluents and in the surrounding of waste disposal site. Ratios of β to γ-HCH highlighted an old mixed source of technical HCH and lindane in surface soils. Predominance of p,p′-DDT and p,p′-DDE among isomers and metabolites showed that large quantity of technical grade DDT is still present in the surrounding surface soils. Six soil samples were categorized as heavy polluted soils (class III category of DDT > 1,000 ng/g), two soil samples into less polluted soil between class I and II (50–500 ng/g) and 28 soil samples as non-polluted (<50 ng/g) according to environmental quality standards for surface soils. Six soil samples were categorized as less polluted between class I and II of HCHs (50–500 ng/g). Greater concentration of DDTs and HCHs above quality guideline poses potential exposure risk to biological organisms, safety of agricultural products and human health in the surrounding of the Ittehad Chemical Industries.  相似文献   

8.
There is a pressing need of finding innovative and beneficial ways of using scrap tires in the construction of various geotechnical structures because a large number of waste tires are generated and discarded every year throughout the world. One example of such geotechnical application is the use of tire shreds mixed with soil as a backfill material for mechanically stabilized earth (MSE) walls. In this paper, we report the results of laboratory pullout tests performed to study the interaction between ribbed-metal-strip reinforcement and tire shred–sand mixtures prepared with various tire shred sizes (9.5 mm in nominal size, 50–100 mm in length, and 100–200 mm in length) and tire shred-to-sand mixing ratios (tire shred contents of 0, 12, 25, 100% by weight). The pullout capacities of ribbed metal strips embedded in tire shred–sand mixtures were obtained for three confining pressures (40, 65, and 90 kPa). The test results showed that the pullout capacity of ribbed metal strips embedded in tire shred–sand mixtures is much higher than that of ribbed metal strips embedded in samples prepared with only tire shreds. Based on the laboratory pullout test results, an equation was developed that can be used to estimate the pullout capacity of ribbed metal strips embedded in tire shred–sand mixtures if the tire shred size, compacted unit weight of the mixture, mean particle size of sand, and vertical effective stress acting at the interface are known.  相似文献   

9.
Metal fluxes to the sediments of the Moulay Bousselham lagoon,Morocco   总被引：2，自引：0，他引：2  
The metal content in surface sediments (0–2 cm, 26 samples), in a sediment core (120, 1 cm slices), taken from Moulay Bousselham (Morocco) was investigated. Concentrations of Al, Fe, Mn, Pb, Zn, Cu, Ni, Cr, Cd, As, and Hg were evaluated in surface and cored sediments of Moulay Bousselham lagoon. Significantly high concentrations in μg g−1 dw of Pb (31.7–6.2), Zn (758.9–167), Cu (310.7–22), Ni (96–10.5), Cr (113–18.9), Cd (0.84–0.02), As (1–0.1), and Hg (0.61–0.02) were found in sediment samples from Moulay Bousselham lagoon. Calculated enrichment factors [EFMe = (Me/Al)sample/(Me/Al)background], using Al as a normalizer, and correlation matrices showed that metal pollution in Merja Zerga of Moulay Bousselham lagoon was the product of anthropogenic sources, while the metal content in Merja Kehla was of natural origins. The results suggest that a major change in the sedimentary regime of the lagoon, associated with internal trapping and re-distribution of heavy metal, has been occurring in the past few decades. The cause would appear to be the construction of a Nador Canal at the lagoon. Probable effects concentrations (PEC) were often exceeded for heavy metals in the lagoon sediments, especially for Zn, Cu, Ni, and Cr, and four stations, stations MZ-11, MZ-12, MZ-13, MZ-14, MZ-16, and MZ-17, had multiple metals at presumptively toxic levels. These comparisons suggest that sediment metal levels in the river are clearly high and probably pose an environmental risk at some stations. The levels of most of the metals were not greatly enriched, a consideration that is of the utmost importance when contamination issues are at stake. Metal concentrations found in Moulay Bousselham lagoon were comparable to aquatic systems classified as contaminated from other regions of the world.  相似文献   

10.
Pore-throat size distributions (PSDs) from mercury injection capillary pressure (MICP) tests have been used to characterise 153 samples of Permo-Triassic sandstones from the United Kingdom. The PSDs have been parameterised using the Brooks-Corey and van Genuchten functions. Pore-throat sizes are in the range 0.01–427 μm, and dominant pore-throat sizes range from about 0.1–90 μm. Values of λ, the Brooks-Corey pore-size distribution index, range from 0.002–2.27, and values of m, the van Genuchten pore-size distribution index, range from 0.03–0.92. A number of classes of sandstone can be recognised on the basis of trends in the fitted parameters. The van Genuchten function provides the most effective method for classifying different sandstones. Additionally, a cross-plot of gas permeability against displacement pressure (derived from the van Genuchten function) shows that the data fall into two distinct sub-populations. The frequency distribution of a larger population of sandstone permeabilities can be modelled using the mean and standard deviation of the two sub-populations identified in the MICP study, assuming that the sub-populations are approximated by log-normal distributions. The distribution of sandstones with small pore-throat sizes is critical to the fate of pathogens and immiscible phase contaminants in the aquifer. Electronic Publication  相似文献   

11.
Batch experiments were performed to investigate cephapirin (a widely used veterinary antibiotic) adsorption on various size sands of low total organic carbon content (0.08–0.36 wt%). In the aqueous concentration range investigated (11–112 μmol/L cephapirin), adsorption to nearly pure quartz filter sands (0.50–3.35 mm diameter) is low. Isotherms are S-shaped and most display a region of minimum adsorption, where decreased adsorption occurs with increasing solution concentration, followed by increased adsorption at higher concentrations. Cephapirin adsorption to quartz-rich, feldspar-bearing dune sands (0.06–0.35 mm diameter), and the smallest quartz filter sand investigated (0.43–0.50 mm), can be described by linear sorption isotherms over the range of concentrations investigated. Distribution coefficients (K d) range from 0.94 to 3.45 L/kg. No systematic relationship exists between grain size and amount of adsorption for any of the sands investigated. Cephapirin adsorption is positively correlated to the feldspar ratio (K-feldspar/(albite + Ca-plagioclase). Feldspar-ratio normalization of distribution coefficients was more effective than organic carbon normalization at reducing variability of K d values in the dune sands investigated.  相似文献   

12.
Mg-Al-rich rocks from the Palghat-Cauvery Shear Zone System (PCSZ) within the Gondwana suture zone in southern India contain sodicgedrite as one of the prograde to peak phases, stable during T = 900–990°C ultrahigh-temperature metamorphism. Gedrite in these samples is Mg-rich (Mg/[Fe + Mg] = X Mg = 0.69–0.80) and shows wide variation in Na2O content (1.4–2.3 wt.%, NaA = 0.33–0.61 pfu). Gedrite adjacent to kyanite pseudomorph is in part mantled by garnet and cordierite. The gedrite proximal to garnet shows an increase in NaA and AlIV from the core (NaA = 0.40–0.51 pfu, AlIV = 1.6–1.9 pfu) to the rim (NaA = 0.49–0.61 pfu, AlIV = 2.0–2.2 pfu), suggesting the progress of the following dehydration reaction: Ged + Ky → Na-Ged + Grt + Crd + H2O. This reaction suggests that, as the reactants broke down during the prograde stage, the remaining gedrite became enriched in Na to form sodicgedrite, which is regarded as a unique feature of high-grade rocks with Mg-Al-rich and K–Si-poor bulk chemistry. We carried out high-P-T experimental studies on natural sodicgedrite and the results indicate that gedrite and melt are stable phases at 12 kbar and 1,000°C. However, the product gedrite is Na-poor with only <0.13 wt.% Na2O (NaA = 0.015–0.034 pfu). In contrast, the matrix glass contains up to 8.5 wt.% Na2O, suggesting that, with the progressive melting of the starting material, Na was partitioned into the melt rather than gedrite. The results therefore imply that the occurrence of sodicgedrite in the UHT rocks of the PCSZ is probably due to the low H2O activity during peak P-T conditions that restricted extensive partial melting in these rocks, leaving Na partitioned into the solid phase (gedrite). The occurrence of abundant primary CO2-rich fluid inclusions in this rock, which possibly infiltrated along the collisional suture during the final amalgamation of the Gondwana supercontinent, strengthens the inference of low water activity.  相似文献   

13.
Diffusion coefficients of Cr and Al in chromite spinel have been determined at pressures ranging from 3 to 7 GPa and temperatures ranging from 1,400 to 1,700°C by using the diffusion couple of natural single crystals of MgAl2O4 spinel and chromite. The interdiffusion coefficient of Cr–Al as a function of Cr# (=Cr/(Cr + Al)) was determined as D Cr–Al = D 0 exp {−(Q′ + PV*)/RT}, where D 0 = exp{(10.3 ± 0.08) × Cr#0.54±0.02} + (1170 ± 31.2) cm2/s, Q′ = 520 ± 81 kJ/mol at 3 GPa, and V* = 1.36 ± 0.25 cm3/mol at 1,600°C, which is applicable up to Cr# = 0.8. The estimation of the self-diffusion coefficients of Cr and Al from Cr–Al interdiffusion shows that the diffusivity of Cr is more than one order of magnitude smaller than that of Al. These results are in agreement with patterns of multipolar Cr–Al zoning observed in natural chromite spinel samples deformed by diffusion creep.  相似文献   

14.
Soil hydraulic properties such as soil infiltration rate and hydraulic conductivity are closely linked to runoff generation and infiltration processes but little is known about them on karst hillslopes. The objectives of this paper were to investigate the change in soil stable infiltration rate (q s) and near-saturated hydraulic conductivity (K ns) in different slope positions and to understand their relationship with rock fragment content and soil texture within the topsoil in subtropical karst regions of southwest China. Tension infiltrometers (20 cm in diameter) were used to measure q s and K ns at pressure head of −20 mm on hillslopes 1 (a disintegrated landslide failure) and 2 (an avalanche slope). The change of q s and K ns was great and they mostly had a moderate variability with coefficient of variations (CV) between 0.1 and 1.0 in the different slope positions. On average, q s ranged from 0.43 to 4.25 mm/min and K ns varied from 0.75 to 11.00 mm/min. These rates exceed those of most natural rainfall events, confirming that overland flow is rare on karst hillslopes. From bottom to top, q s and K ns had a decrease–increase–decrease trend due to the presence of large rock outcrops (>2 m in height) on hillslope 1 but had an increasing trend on hillslope 2 with less complex landform. They tended to increase with increase in total rock fragment content (5–250 mm) within the topsoil as well as slope gradient on both hillslopes. Pearson correlation analysis suggested that higher coarse pebble (20–75 mm), cobble (75–250 mm), and sand (2–0.05 mm) contents as well as total rock fragment content could significantly facilitate water infiltration into soils, but higher clay (<0.002 mm) content could restrict water movement. This result indicated that rock fragment, sand, and clay contents may remarkably affect water flow in the topsoil layers, and should be considered in hydrological modeling on karst hillslopes in subtropical regions.  相似文献   

15.
GPS-derived deformation rates in northwestern Himalaya and Ladakh   总被引：1，自引：0，他引：1  
Deformation rates derived from GPS measurements made at two continuously operating stations at Leh (34.1°N, 77.6°E) and Hanle (32.7°N, 78.9°E), and eight campaign sites in the trans-Himalayan Ladakh spanning 11 years (1997–2008), provide a clear picture of the kinematics of this region as well as the convergence rate across northwestern Himalaya. All the Ladakh sites move 32–34 mm/year NE in the ITRF2005 reference frame, and their relative velocities are 13–16 mm/year SW in the Indian reference frame and ~19 mm/year W with reference to the Lhasa IGS station in southeastern Tibet. The results indicate that there is no statistically significant deformation in the 200-km stretch between the continuous sites Leh and Hanle as well as between Leh and Nubra valley sites along the Karakoram fault, whereas the sites in and around the splayed Karakoram fault region indicate surface deformation of 2.5 mm/year. Campaign sites along the Karakoram fault zone indicate a fault parallel surface motion of 1.4–2.5 mm/year in the Tangste and western Panamik segment of the Karakoram fault, which quantifies the best possible GPS-derived dextral slip rate of 3 mm/year along this fault during this 11-year period. Baselines of Ladakh sites show convergence rates of 15–18 mm/year with respect to south India and 12–15 mm/year with respect to Delhi in north India and Almora in the Himalaya ~400 km north-northeast of Delhi. These constitute an arc normal convergence of 12–15 mm/year across the western Himalaya, which is consistent with arc normal convergence all along the Himalayan arc from west to east. Baseline extension rates of 14–16 mm/year between Lhasa and Ladakh sites are consistent with the east–west extension rate of Tibetan Plateau.  相似文献   

16.
The rate of static dislocation recovery in Fo90 olivine has been studied under conditions of high temperature and controlled atmosphere in compressively deformed polycrystals hot-pressed from synthetic (sol–gel) and natural (San Carlos) precursor powders. The sol–gel olivine, containing a small fraction of orthopyroxene, was deformed to a final strain of 19% with a maximum differential stress of 266 MPa whereas the San Carlos specimen was deformed to 15% strain and 260 MPa differential stress. Small samples cut from these deformed materials were annealed under high-temperature, controlled atmosphere conditions, for different durations to allow partial recovery of the dislocation sub-structures. Oxidative-decoration of the microstructural features, followed by backscattered electron imaging at 5 kV and image analysis, was used to determine dislocation density. The variation of dislocation density ρ with time t at absolute temperature T was fitted to a second-order rate equation, in integral form, 1/ρ(t) − 1/ρ(0) = kt with k = k 0 exp(−E a/RT). The activation energy E a of the recovery process is 240 ± 43 and 355 ± 81 kJ mol−1 for sol–gel and San Carlos olivine polycrystals, respectively. The measured rates are one to two orders of magnitude lower than those reported in previous studies on natural single crystal olivine. The difference may be explained by several factors such as high dislocation densities measurable from large areas at high magnification for the SEM and the technique used to estimate dislocation densities. Comparison between fine-grained sol–gel olivine and the coarser-grained San Carlos olivine aggregate did not indicate that grain boundaries play an important role in dislocation recovery, but the absence of grain boundaries might also have contributed to the high dislocation recovery rates previously measured for single crystals.  相似文献   

17.
A worldwide dataset of organic material from 553 samples belonging to coal and carbonaceous materials was used to analyze the evolution of hydrogen index (HI) and bitumen index (BI) with increasing thermal maturity. Basic statistical analyses were applied to detect the boundary lines of HImax and BImax in delineating the upper and lower limits of the HI and BI bands for the majority of samples. In addition, cross-plots of HI or BI versus maturity (Ro% and T max) also provide criteria for defining the HImax and BImax boundary lines. The constructed HI and BI bands are broad at low maturities and become narrower with increasing thermal maturities. The petroleum generation potential is completely exhausted at the vitrinite reflectance of 2.0–2.2% or T max of 510–520°C. An increase in HI implies extra petroleum generation which was related to changes in structure of organic materials. A declining BI means that the oil expulsion window starts to occur at the vitrinite reflectance range of 0.75–1.05%. The petroleum potential can be divided into four different areas based on the cross-plot of HI versus Ro%. The highest petroleum potential area is located in section II with Ro = 0.6–1.0% and HI > 100. The oil generation potential is rapidly exhausted at section III with Ro > 1.0%. This result is also in accordance with the result of curve regression of HI versus Ro% based on 80 samples with Ro = 1.02–3.43% (R 2 = 0.72). Overall, the total oil window can be extended up to Ro = ~1.25–1.95%. Finally, in the cross-plots of S1 versus S2, shale or C-shale exhibits a higher and slowly decreased slope, compared with a lower and then sharply increased slope of coal samples, which is attributable to their compositional difference in organic material.  相似文献   

18.
We report major and trace element composition, Sr–Nd isotopic and seismological data for a picrite–basalt–rhyolite suite from the northern Tarim uplift (NTU), northwest China. The samples were recovered from 13 boreholes at depths between 5,166 and 6,333 m. The picritic samples have high MgO (14.5–16.8 wt%, volatiles included) enriched in incompatible element and have high 87Sr/86Sr and low 143Nd/144Nd isotopic ratios (εNd (t) = −5.3; Sri = 0.707), resembling the Karoo high-Ti picrites. All the basaltic samples are enriched in TiO2 (2.1–3.2 wt%, volatiles free), have high FeOt abundances (11.27–15.75 wt%, volatiles free), are enriched in incompatible elements and have high Sr and low Nd isotopic ratios (Sri = 0.7049–0.7065; εNd (t) = −4.1 to −0.4). High Nb/La ratios (0.91–1.34) of basalts attest that they are mantle-derived magma with negligible crustal contamination. The rhyolite samples can be subdivided into two coeval groups with overlapping U–Pb zircon ages between 291 ± 4 and 272 ± 2 Ma. Group 1 rhyolites are enriched in Nb and Ta, have similar Nb/La, Nb/U, and Sr–Nd isotopic compositions to the associated basalts, implying that they are formed by fractional crystallization of the basalts. Group 2 rhyolites are depleted in Nb and Ta, have low Nb/La ratios, and have very high Sr and low Nd isotopic ratios, implying that crustal materials have been extensively, if not exclusively, involved in their source. The picrite–basalt–rhyolite suite from the NTU, together with Permian volcanic rocks from elsewhere Tarim basin, constitute a Large Igneous Province (LIP) that is characterized by large areal extent, rapid eruption, OIB-type chemical composition, and eruption of high temperature picritic magma. The Early Permian magmatism, which covered an area >300,000 km2, is therefore named the Tarim Flood Basalt.  相似文献   

19.
In coastal areas, abnormally high pressure may be caused by the tide-induced water table variation under extensive pavements, particularly during rainfall. To simulate the rainfall infiltration effects on the air permeability of asphalt pavements in coastal area, column-shaped asphalt sample was fixed in the upper part of a steel cylinder with its upper surface saturated with ponding water (depth < 5 mm) and open to the atmosphere. The cylinder’s lower part formed an air chamber. The chamber was pressurized and then the air therein was released naturally through the sample. The pressure variation with time in the chamber was recorded for analysis. Based on the Green–Ampt piston model for the surface water infiltration, an approximate analytical solution was derived to describe the pressure–time relationship in the chamber. A new parameter called the escape pressure was introduced to describe the air pressure needed for the chamber air to break through the capillary pressure induced by the ponding water. The analytical solution gave good estimations of both the escape pressures and the harmonic averages of the permeabilities of the wet and dry parts of 14 samples in the sense that excellent fittings were obtained between the observed and predicted air pressures in the air chamber. The estimated escape pressure ranges from 0.0 to 1.74 kPa. The harmonic average of the permeabilities of the wet and dry parts is 5–94% of the dry sample’s permeability.  相似文献   

20.
Copper contamination in soils and vegetables in the vicinity of an abandoned copper mine in China was investigated. The Cu concentrations of 93 soil samples ranged from 30.4 to 3,191 mg kg−1 soil for a mean of 816.8 mg kg−1 soil. Among 15 samples from a 0 to 20-cm soil layer used for the toxicity characteristic leaching procedure (TCLP) test, the highest value of Cu-TCLP was 133.8 mg kg−1 soil and the TCLP values were positively correlated with the total Cu content of the soils. The sequential extraction of soils in the 0–20-, 20–40-, and 40–60-cm soil layers showed that Cu existed mainly in the Fe–Mn oxide fraction, sulfide/organic fraction, and residual fraction. The copper contamination of 21 species of vegetables from in situ sampling was also examined. Cu concentrations in the edible portions of Brassica chinensis and Solanum melongena were higher than the FAO/WHO standard (40 mg kg−1 DW). The health risk of copper for local inhabitants from consuming these vegetables was assessed on the basis of the target hazard quotient. Enriched concentrations of copper were also found in situ in eight cultivars of B. chinensis planted in the fields, with two levels of Cu concentration. The results showed that there is severe copper contamination in this mine area, and the pollutant in soils show a high risk of leaching into the groundwater and diffusing through the food chain.  相似文献   

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