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1.
W. Linke 《Mineralogy and Petrology》1970,14(1):61-63
Zusammenfassung Der Pleochroismus der OH-Streckfrequenz (=3,16 ±0,02 ) zeigt sowohl für -Zoisit als auch für -Zoisit, daß die OH-Dipole paralel [001] orientiert sind.
Mit 1 Abbildung 相似文献
Measurement of the infrared-pleochroism in minerals. X. The pleochroism of the OH-stretching frequency in zoisite
Summary The pleochroism of the OH-stretching frequency (=3.16 ±0.02 ) proves for - and -zoisite that the OH-dipoles are oriented parallel [001].
Mit 1 Abbildung 相似文献
2.
Zusammenfassung Im antarktischen Sommer 1979/80 führte die Deutsche Antarktis-Expedition Nord-Victorialand (Ganovex 1979) geowissenschaftliche Untersuchungen im nördlichen Victorialand durch. Von einem Teilgebiet an der Nordostecke von Victorialand, westlich des Ross-Meeres, werden Bilder des SatellitenLandsat vorgestellt. Diese Aufnahmen sind die ersten Versuche einer digitalen Bildverarbeitung für dieses Gebiet. Sie lassen aber schon den Wert besonders für die Glaziologie, Geomorphologie und Geologie erkennen.
In the Antarctic summer of 1979/80 the German Antarctic North Victoria Land Expedition (Ganovex 1979) carried out geoscientific investigations in the northern part of Victoria Land.Landsat satellite images from a section of the northeastern corner of Victoria Land, west of the Ross Sea, are described. These photos represent the first digital image processing for this area. Their value can be discerned already, especially in terms of our knowledge on the glaciology, geomorphology, and geology of this region.
Résumé Au cours de l'été antarctique 1979/1980, l'Expédition Allemande Antarctique de la Terre Victoria (Ganovex 1979) a effectué des recherches géoscientifiques sur la partie nord de la Terre Victoria. Nous présentons ici des images du satelliteLandsat de la partie nord-est de la Terre Victoria à l'ouest de la Mer de Ross. Ces images représentent le premier essai d'un traitement digital par images sur cette région. La valeur de ces essais est déja evidente en glaciologie, géomorphologie et géologie.
(GANOVEX 1979) 1979/80 . - LANDSAT. , .相似文献
3.
The distribution of some trace metals (Cu, Zn, Ni, Co,Fe, Mn) and of DOC over a particulate (> 1 m),a colloidal (size < 0.45 m and molecular weight > 10 kD) and an ultrafiltered fraction (< 10 kD)was determined at several sites on the Thur River,Switzerland, at various times of the year. Thecomplexation of Cu by strong ligands in theultrafiltrate and in the conventional filtrate (<0.45 m) was compared using a ligand-exchange/CSV method.The <0.45 m concentrations of Cu (from anaverage of 7 nM to 24 nM), Zn (<5–23 nM), Ni (5–13 nM),Co (1.5–3 nM) and Mn (7–92 nM)increased downstream. The major part of Cu, Zn, Niand Co usually occurred in the ultrafiltratefraction at all sites, whereas Fe and Mn were mostlyin the particulate fraction, under conditions of lowsuspended matter content (< 10 mg L-1) in theriver. The percentage of metal in the colloidalfraction, with respect to the 0.45-m filtrate,decreased in the order: Cu (median 11%) > Zn Ni(median 5–6%) > Mn Co (median < 5%). DOCalso consisted mostly of molecules in the < 10 kDrange.Cu was strongly complexed by natural organic ligandsin all filtrate and ultrafiltrate samples. A largepart of the strong Cu binding ligands consisted ofcompounds in the < 10 kD range, but colloidalligands with similar properties also occurred. Cu wasdistributed among the dissolved and the colloidalligands, roughly in proportion to organic carbon.The colloidal fraction (as defined here) did notincrease in its proportional amount downstream and wasonly of limited significance in transporting traceelements in the Thur River under low discharge conditions. 相似文献
4.
Samples of MH-10, a K-feldspar thought to contain discrete diffusion domains for argon, have been examined by light and TEM microsopy to search for domain boudaries. We examined both unheated K-feldspar separates and samples heated in vacuum between 750 and 1150°C in order to characterize the initial microstructure as well as any changes resulting from laboratory heating. The MH-10 rock shows almost no evidence of plastic deformation, and the K-feldspar does not possess networks of dislocations which might define a subgrain structure derived from external stresses. Three classes of substructure are present in the K-feldspar, but only the third appears to have been affected by laboratory heating: (1) Cross-hatched extinction in light microscope is common but variably developed. TEM reveals almost no albite/pericline twinning but tweed microstructure is ubiquitous. (2) Turbid zones occur with about 5 volume % abundance. Micropores, <1 to 2m in diameter, characterize these regions, which often also contain bleds of albite, up to 40 m indiameter, TEM shows these turbid zones to be very complex with intricate twin and tweed structures at the sub-micron scale and numerous dislocation and strain features. (3) Albitic exsolution lamellae (<1 m thick, 20 m long and separated by 1 m) are rarely seen in the light microscope but TEM shows that 0.01 m thick by 0.2–1 m long lamellae, separated by 0.1 to 0.5 m, occur in about 20% of the sample. These lamellae are disk-shaped, have a semi-coherent or coherent relationship to the host K-feldspar, and seem to disappear upon heating to 750°C. Extensive diffusion studies have been conducted on HM-10, and the results analyzed in terms of distribution of sizes of diffusion domains. The preferred result of the analyses was a distribution consisting of three distinct sizes. The largest domain size identified in this way is approximately 50 to 100 m, and this corresponds to blocks of K-feldspar defined by the network of fractured/turbid zones. The smallest domain size inferred from diffusion analysis is 0.1 m which corresponds to the spacing between albite exsolution lamellae that may represent fast diffusion pathways. Alternatively, the modulated argon distribution accompanying the lamellar variation in feldspar composition may result in an overestimation of the initial diffusion coefficients. Even though a promising agreement exists between domain analyses based upon diffusional and microstructural analyses, at least two questions remain unanswered. Firstly, no clear candidate has been identified for a domain of intermediate size. Secondly, the diffusion analysis has been formulated with independent gas release from all domains, whereas the observed structures are likely to be nested (i.e., small domains exist inside bigger domains) with the network of semi-coherent lamellar boundaries having connectivity and permeability which can provide only a modest increase in argon diffusivity over bulk values. 相似文献
5.
Prof. Dr. W. M. Bausch Prof. Dr. K. G. Poll 《International Journal of Earth Sciences》1984,73(1):351-369
Zusammenfassung Das Malmprofil Loser (Altaussee) wurde auf seine Mikrofazies, die nichtkarbonatischen Rückstände sowie auf die Strontium-Gehalte hin untersucht. Das Säure-Unlösliche wurde nach Auftrennung in Silt- und Tonfraktion röntgenographisch analysiert.Während sich die Mikrofazies mit Tressenstein-, Barmstein- und Oberalmer Fazies (vom Hangenden zum Liegenden) als normal kalkalpin erweist, gibt es in den Rückstandswie Strontiumkurven sehr deutliche Analogien zum außeralpinen, süddeutschen Malm. Obwohl die Sr-Gehalte mit zunehmenden Tongehalten der Kalke ansteigen, gelingt der Nachweis, daß sie in die Karbonatphase eingebaut sind. Ferner werden Möglichkeiten beschrieben, Bereiche diffuser Verkieselung allein aus den Kenndaten der unlöslichen Rückstände zu ermitteln. Drei verschiedene Arten von Verkieselungen können den drei HauptFaziestypen zugeordnet werden.
Summary The Malm profile of Loser (near Altaussee, Austria) was investigated for microfacies, insoluble residues and strontium contents. The insoluble residues were separated into silt and clay fractions, and analyzed by X-ray diffraction.Whereas the microfacies was found to be of quite normal alpine character with Tressenstein-, Barmstein- and Oberalmer facies, the residues and the strontium curves exhibit striking similarities to the epicontinental Malm of Southern Germany. Although the contents of Sr increase with the increasing clay fraction, there can be shown that they are bound to the carbonate phase. Additionally methods were described to determine areas of diffuse silifications, only by data of the insoluble residues. 3 different types of silification are distinguishable, bound to the 3 main facies.
Résumé Le profil du Malm de Loser (Altaussee) a fait l'objet d'une recherche quant à ses microfacies, son résidu non carbonaté et aussi sa teneur en Strontium. L'insoluble dans l'acide a été analysé, après séparation, en fractions silt et argileuse.Tandis que le microfacies se montre, avec les facies de Tressenstein, de Barmstein et d'Oberalm (de bas en haut) comme « normal » pour l'alpin calcaire, il y a, dans les courbes concernant le résidu et le strontium, des analogies évidentes avec le Malm extraalpin de l'Allemagne méridionale. Bien que la teneur en Sr monte avec l'augmentation du contenu argileux des calcaires, on a la preuve qu'elle est liée à la phase carbonatée. En outre sont décrites les possibilités de découvrir les espaces de silicification diffuse sur les seules données du résidu insoluble. Trois formes différentes de silicification peuvent être subordonnées aux trois types de facies principaux.
( ) , . , , . , . ( ) , , , . , , . . .相似文献
6.
Metasomatic columns hosted in dolomitic marbles in the thermal aureole of the Traversella monzodiorite (Ivrea, Italy) differ by their mineralogy and/or mineral composition. Three groups have been distinguished. In group A, the first zone always contains forsterite-calcite and the second zone contains clinopyroxene. The last zone is made of wollastonite (A1), andradite-rich garnet (A 2) or grossular-rich garnet (A 3). In group B, tremolite instead of forsterite occurs in the first two zones. In group C columns, there are only two zones and clinohumite or chondrodite characterize the first zone.Field, petrographic and chemical data demonstrate that the occurrence of contrasted mineral zonations in the same protolith has not been induced by local heterogeneities in the dolomitic marbles. The presence of tremolite in group B instead of forsterite is due to the lower temperature prevailing in the external part of the contact aureole. Chemical data as well as - diagrams suggest that the columns in groups A and C were formed through the interaction of the dolomitic marbles with fluids with different Fe
2O3, Al
2
O
3 and F. A fluid with low Al
2
O
3 and Fe
2O3 is assumed for the metasomatic column with wollastonite (A 1) and different Al2O3/Fe2O3 values in the fluid are responsible for the formation of columns A 2 and A 3. The stability of clinohumite or chondrodite in group C columns has been induced by a higher F of the fluid than in the other groups. The presence during the prograde metasomatic stage of distinct fluids differing by their Al
2
O
3/Fe
2O3 (columns A 2 and A 3) is likely to have been induced by variations in the source composition. Moreover, the low A1 and Fe content in column A 1 could be due to the reaction of the dolomitic marble with a fluid previously depleted in these components during percolation and reaction with the country rocks.As shown by isocon diagrams and Gresens's equation, skarn formation has locally induced both mass and volume change. The volume decreased in the wollastonite zone of A 1 (19%) and in the Fo-Cc zone of A2 (17%). Mass is always increased except in the wollastonite of A 1 where it is decreased. Mass balance of major elements has shown that Ca is likely to be a perfectly inert component and that Si is always strongly increased. Moreover, Fe is increased in A 2 and A 3 whereas Al is only increased in A 3. Mg is leached in the internal part of column Al.Quantification of chemical potential diagrams using different values of Al
2
O
3 Fe
2
O
3, X
F and T suggests that the successive zones observed in all types of columns can be obtained along an increase of SiO
2 towards the inner zones. A simultaneous decrease in MgO is inferred for group A columns. 相似文献
7.
The chemical and microbiological characteristics of groundwater from two provinces of central Spain were studied. In some zones of this area, the concentrations of As in groundwater exceed the guideline concentrations, set internationally between 10 g/l and 50 g/l, reaching levels over 100 g/l. A narrow correlation between the contents of arsenic and HCO3– was observed. These data suggest a possible mechanism of the As mobilization from aquifer sediments to groundwater: the bicarbonate ions could displace HAsO42– adsorbed on aquifer oxyhydroxides. Sediments containing relatively high contents of adsorbed arsenic are deposited in surface water environments with low carbonate concentrations. Subsequently, the sediments become exposed to groundwater with highly dissolved carbonate content, and arsenic can be mobilized by displacement from mineral surfaces. In addition, the presence of Pseudomonas genera bacteria, which secrete siderophores (Fe chelating agents) could mobilize As adsorbed on Fe oxides through their dissolution. These combined microbiological and chemical processes might have increased the natural mobility of As. 相似文献
8.
A. Reuter 《Contributions to Mineralogy and Petrology》1987,97(1):105-115
White mica bearing fractions ranging in grain size from 0.4 m to 6.3–20 m were separated from metapelites and intercalated metatuffs of the eastern Rheinisches Schiefergebirge (FRG). The stratigraphic age of these rocks is Middle Devonian (Eifelian), and they contain detrital material of northwestern provenance (Old Red Continent, probably mainly derived from the Caledonian Orogen). Folding in the Carboniferous was associated with cleavage formation and an apparently synkinematic anchizonal metamorphism. Apparent K-Ar ages of metapelite fractions display a marked positive correlation with grain size illustrating the detrital influence which is diminished with decreasing grain size and increasing metamorphism (determined by illite crystallinity). Contrasting grain morphologies observed by SEM enable the interpretation of apparent age/ grain size relationship for coarse fractions. The anticipated lack of detrital mica in metatuffs is confirmed by the fairly consistent apparent K-Ar ages determined for the coarser than 0.63 m size fractions which date the anchizonal metamorphism at ca. 330 Ma. Comparison of metatuff and metapelite apparent ages suggests that the extent of rejuvenation in the latter was largely dependent on grain size. Rejuvenation was also somewhat controlled by the degree of anchizonal metamorphism as suggested by differences in K-Ar results of metapelites which were metamorphosed at variable anchizonal conditions. Fractions <0.63 m from upper anchizonal metapelites record ca. 330 Ma ages similar to those of the 0.63–20 m sizes in metatuffs. Together those results confirm the limited applicability of conventional K-Ar dating on bulk clay fractions (<2 m) of very-low grade (anchizonal) metamorphic rocks in dating metamorphic events and concomitant cleavage formation. 相似文献
9.
Twenty-eight samples of groundwater from bedrock boreholes in three distinct Norwegian geological provinces have been taken and analyzed for content of Rn, U, and Th, together with a wide variety of minor and major species. Median values of 290 Bq/1, 7.6 g/1, and 0.02 g/1 were obtained for Rn, U, and Th respectively, while maximum values were 8500 Bq/1, 170 g/1, and 2.2 g/1. Commonly suggested drinking water limits range from 8 to 1000 Bq/1 for radon and 14 to 160 g/1 for uranium. Radioelement content was closely related to lithology, the lowest concentrations being derived from the largely Caledonian rocks of the Trøndelag area, and the highest from the Precambrian Iddefjord Granite of southeast Norway (11 boreholes) where median values of 2500 Bq/1, 15 g/1 and 0.38 g/1, respectively, were obtained. The Iddefjord Granite is not believed to be unique in Norway in yielding high dissolved radionuclide contents in groundwaters, and several other granitic aquifers warrant further investigation in this respect. 相似文献
10.
Following deposition of widespread middle Oxfordian lacustrine carbonates and evaporites, the Lusitanian Basin was differentiated into a number of sub-basins. The Arruda sub-basin is a half graben basin situated some 30 km north of Lisbon. It accumulated over 2.5 km of Kimmeridgian siliciclastic sediments, and is bounded to the east by the Vila Franca de Xira fault zone. Carbonate deposition persisted over horsts along the fault zone from the Oxfordian to the early Kimmeridgian, and in places to the late Kimmeridgian, and shows a pronounced west-east facies zonation, with higher energy framestones and grainstones accumulating along the exposed western margins. Seismic data indicate a major gap between the horst blocks that acted as a conduit through which basement derived siliciclastics were fed westwards into the sub-basin to form a submarine fan system. The presence of large blocks of framestone carbonates encased in siliciclastics indicates that carbonate sedimentation occurred in abandoned parts of the fan system. The rapid changes of sediment thicknesses and facies types along the eastern margin of the Arruda sub-basin are indicative of contemporaneous strike-slip movements.
Zusammenfassung Nach der weitverbreiteten Ablagerung mitteloxfordischer Seenkarbonate und Evaporite differenzierte sich das Lusitanische Becken in verschiedene Sub-Becken. Das Arruda Sub-Becken befindet sich ca. 30 km nördlich Lissabon und entspricht einem Halbgraben, in dem über 2.5 km mächtige Siliziklastika des Kimmeridgium zur Ablagerung kamen. Das Sub-Becken wird durch die Störungszone von Vila Franca de Xira nach Osten begrenzt. Auf Horststrukturen entlang der Störungszone wurden im Oxfordium und Unterkimmeridgium, z. T. auch bis ins Oberkimmeridgium Karbonate sedimentiert. Diese Karbonatschelfe weisen eine ausgeprägte Fazieszonierung von West nach Ost auf. Die westlichen Schelfränder sind durch höherenergetische Riffkalke (framestones) und Karbonatsande (grainstones) charakterisiert. Seismische Profile lassen eine große Lücke zwischen den Horstblöcken erkennen, durch welche Siliziklastika aus dem Hinterland ins Sub-Becken gelangten, wo sie einen submarinen Fächer aufbauten. Große Riffkalkblöcke innerhalb der Siliziklastika weisen auf Karbonatsedimentation in verlassenen Fächerbereichen hin. Die schnellen Mächtigkeits- und Fazieswechsel entlang des Ostrandes des Arruda Sub-Beckens sind durch synsedimentäre tektonische Bewegungen zu erklären, welche oftmals eine Dominanz der Lateralkomponente aufweisen.
Resumo Depois da sedimentação dos calcários lacustres e depósitos evaporíticos da idade Oxfordiano médio, a Bacia Lusitánica diferenciou-se em várias sub-bacias. A sub-bacia de Arruda está situada ca. de 30 km ao norte de Lisboa e corresponde a uma estrutura «half-graben» em que mais do que 2.5 km de sedimentos foram acumulados. Para leste, a sub-bacia é limitada pela zona das falhas de Vila Franca de Xira. Entre o Oxfordiano e o Kimeridgiano, calcários desenvolveram-se em cima dos blocos elevados (horsts) ao longo da zona de falhas. Estes calcários de tipo plataforma exibem uma distincta zonação de facies de oeste a leste. As margens occidentals das plataformas pequenas são caracterisadas por sedimentos recifais e areníticos. Cortes sísmicos indicam uma abertura grande entre os blocos elevados, pelo quai sedimentos siliciclásticos passaram de hinterland à sub-bacia formando um fan submarino. Grandes blocos recifais situados dentro dos depósitos siliciclásticos são evidências para sedimentação carbonática em várias áreas abandonadas dentro do fan. Mudanças rápidas das espessuras e das fácies dos sedimentos ao longo da margem oriental da sub-bacia de Arruda podiam ser explicadas por uma tectónica sinsedimentária dominada por movimentos horizontais.
/ , / . , , 30 , 2,5 . Vila Franca de Xira . , - , . . / framestones / / grainstones /. , , . «». , .相似文献
11.
Concentration levels of the trace elements Al, As, B, Ba, Be, Cd, Co, Cr, Cu, Li, Mo, Ni, Pb, Sr, V, Y, and Zn in the shallow Dutch ground water were studied. Data were extracted from the data base of the Dutch National Ground Water Quality Monitoring Network, a network set up to monitor the diffuse contamination. The network contains over 350 sites at a low density of about 1 per 100 km2. The sites are sampled once a year at two depths (approx. 10 and 25 m below surface). A two-step multivariate statistical approach was used, in which the major element chemistry was used to define water types. Within each water type, trace element behavior could be coupled to distinct geochemical processes: dilution, acidification and weathering, carbonate dissolution, oxidation/reduction, and ion exchange. In recently infiltrated acid rain water in low buffering capacity sands, the anthropogenic influence indirectly caused mobilization of Al (median 430 g/l), Cd (0.6 g/l), Co (14 g/l), Cu (2.7 g/l), Ni (16 g/l), Y (11 g/l), and Zn (50 mg/l). In carbonate bearing sediments the acidification is neutralized, and the mentioned trace elements remain immobile. Arsenic and Cr have higher concentrations levels in ground waters with a slightly reducing character and are possibly governed by the dissolution of iron-manganese hydroxides. Boron, Li, and Sr have high concentrations (respectively 875, 80, 2700 g/l) in the water type related to a seawater source. Strontium is related to carbonate dissolution in all other water types (medians ranging from 100 to 1000 g/l). Barium shows a complex behaviour. It is concluded that the high Al, Cd, Co, Cr, Ni, and Zn concentrations are anthropogenically induced. High Ba and Cr concentrations are inferred to be due to natural processes. 相似文献
12.
Soil samples collected from various places in and around Mysore were analyzed for the total trace elements such as Fe, Mn, Cu, Zn, Pb, and Cd. The results of the analysis indicate that the concentration of lead and cadmium in soils is below 2.5 g ml–1 and 0.2 g ml–1, respectively, which are the minimum detection levels, whereas the concentration of iron, manganese, copper, and zinc in most of the samples is within the global average ranges of 3%, 500–1000 g g–1, 15–40 g g–1, and 50–100 g g–1, respectively. The investigated area has the presence of gneisses and schists, in which partly there are igneous intrusions and pegmatitic intrusions. There are amphibolite enclaves in gneisses that account for the higher concentration of trace elements. The lower concentration may be attributed to the presence of silicic type of rock. 相似文献
13.
Metamictization and U-PB isotopic discordance in single zircons: a combined Raman microprobe and SHRIMP ion probe study 总被引：7，自引：0，他引：7
Summary We report results of a combined SHRIMP ion microprobe and Raman microprobe study of the correlation between metamictization and U-Pb isotopic discordance of zircon. The spatial resolution of the SHRIMP and Raman probe used are about 200 m3 and 80 m3, respectively. This allows a direct comparison of U-Pb isotopic discordance and metamictization of small areas within zircon crystals. We show that the impact of the oxygen ion beam on the zircon during the SHRIMP analysis does not cause significant amorphization or recrystallization in the remaining zircon on a scale of 1 m. Consequently, it is possible to determine the initial degree of metamictization of zircon within and adjacent to a SHRIMP analytical spot by Raman microprobe measurements after performing SHRIMP analyses. A combination of the two microprobe techniques gives information on the concentration and distribution of radionuclides as well as the degree of metamictization and its heterogeneity and the lateral age distribution within the grain. We found that the degree of U-Pb isotopic discordance correlates closely with the degree of metamictization within single zircon grains, on a scale of 15 m, which is consistent with previous results on the scale of single and multiple zircon grains showing that metamictization enhances the relative potential for secondary loss of radiogenic lead in zircon.
Metamiktisierung und U-Pb-Isotopendiskordanz in Einzelzirkonen: eine komplexe Untersuchung mittels Ramanmikrosonde und SHRIMP Ionensonde
Zusammenfassung Wir präsentieren die Ergebnisse einer Untersuchung des Zussammenhangs von Metamiktisierung und U-Pb Isotopendiskordanz in Zirkonen mittles kombinierter SHRIMP-Ionenmikrosonden- und Ramanmikrosondenanalysen. Die räumliche Auflösung der verwendeten Analysensysteme, experimentell mit 200 m3 (SHRIMP) und 80 m3 (Ramansonde) bestimmt, gestattet den direkten Vergleich der in Mikrobereichen innerhalb von Zirkon-Einkristallen gemessenen Isotopendiskordanzen und Metamiktisierungsgrade. Wir zeigen, daß der während der SHRIMP-Analyse auf den Zirkon einwirkende Sauerstoffionenstrahl weder signifikante Amorphisierung noch Rekristallisation des benachbarten Zirkonmaterials im 1 m-Bereich hervorruft. Es ist deshalb möglich, den Grad der Metamiktisierung eines Zirkon-Mikrobereiches auch in den SHRIMP-Analysengrübchen, d.h. erst nach dem Analysieren dieses Bereiches mit der Ionensonde, mittels hochauflösender Ramanmessungen unverfälscht zu bestimmen. Der Einsatz beider Mikromethoden liefert kombinierte Informationen zu den Gehalten und Verteilungen radioaktiver Elemente, zum Grad der Metamiktisierung und seiner Heterogenität und zur lateralen Altersverteilung innerhalb von Einzelkörnern. Wir weisen eine deutliche Korrelation des Grades der U-Pb-Isotopendiskordanz mit dem Grad der Metamiktisierung im Mikrobereich (15 m Auflösung) nach. Dies stimmt mit früheren, an Einzelzirkonen und Populationen getätigten Beobachtungen überein, daß die Metamiktisierung von Zirkon dessen Potential zu sekundären Bleiverlusten erhöht.相似文献
14.
Gerald L. Crow Marlin J. Atkinson Benny Ron Shannon Atkinson Arleene D. K. Skillman George T. F. Wong 《Aquatic Geochemistry》1998,4(3-4):469-480
Captive whitetip reef sharks, Triaenodon obesus,at Sea Life Park (SLP) Hawaii, Waimanalo, Hawaii develop goitre, whereas, T. obesus at the Waikiki Aquarium (WAQ), Honolulu,Hawaii do not develop goitre. To determine theeffects of natural concentrations of iodine on thereduction of goitre, two sharks from SLP with goitrewere placed in an enclosed coastal lagoon with naturalseawater. Using ultrasound measurements the twogoitres were initially 11.4 cm and 14.6 cm in depthand after 3 months decreased to 4.7 cm and 5.7 cm. Radioimmunoassay analysis of the thyroid hormoneT3 sera concentrations were initially 0.22 ng/mland 0.33 ng/ml and increased to 1.84 ng/ml after beingplaced in the lagoon. Sera T4 were initially0.93 ng/ml and 0.99 ng/ml and increased dramaticallyto 17 ng/ml and 56 ng/ml. Over the six month samplingperiod, two resident sharks in the lagoon with normalthyroids had sera T3 concentrations from 0.89ng/ml to 1.1 ng/ml, and sera T4 concentrationsfrom 3.1 ng/ml to 7.9 ng/ml. The hypothyroidcondition in the SLP goitred-sharks is likely linkedto the low environmental iodide (<0.005 M), andhigh nitrate (111 M) of SLP water. The WAQwell-water facility was characterized by anoxic waterwith high iodide (0.60 M), total iodine (1.90M), and typical nitrate (24.6 M)concentrations of interstitial groundwater. Thedifference of iodide concentration of SLP and WAQ tankwater (<0.005 M versus 0.60 M) wasdirectly related to the hydrogeology of the well-watersources. To avoid goitre in marine aquarium systems,we recommend maintaining iodide concentrations of atleast 0.15 M. 相似文献
15.
John W. Morse Dwight K. Gledhill Karen S. Sell Rolf S. Arvidson 《Aquatic Geochemistry》2002,8(1):3-13
In sediments from the continental slope of the Northern Gulf of Mexico, generally,the degree of iron pyritization (DOP) is low (<0.1) and dissolved sulfide is belowdetection limits (5 M), whereas dissolved Fe is typically about 50 to100 M. Therefore, the dissolution of kinetically reactive iron minerals generallydominates over the rate of sulfide production in sediments throughout this region.However, in sediments where hydrocarbons have been added via seepage from thesubsurface, dissolved-Fe is undetectable, DOP can approach 1, and high concentrationsof dissolved sulfide (up to 11 mM) are commonly present. Even though thesesediments have high total reduced sulfide (TRS) concentrations (typically 150 to370 mol gdw-1), their average C/S ratio is about 4 times that of normal marine sediments reflecting the major input of hydrocarbons. DOP is significantly (20%) higher when calculated using reactive-Fe extracted by citrate dithionite than by cold 1N HCl. This difference is primarily due to the greater extraction efficiency of the cold HCl method for silicate-Fe. TRS tends to rise to a maximum, and remains close to constant even at high (mM) dissolved sulfide concentrations. These TRS concentrations, therefore, represent the size of the ``kinetically' reactive-Fe pool during early diagenesis. 相似文献
16.
Kevin H. Johannesson W. Berry Lyons Suey Huey Georgia a. Doyle Eric E. Swanson Ed Hackett 《Aquatic Geochemistry》1997,3(1):61-97
Water samples were collected from the Truckee River-Pyramid Lake system, the Walker River-Walker Lake system, and the Carson River, all located in eastern California and western Nevada, U.S.A., at three different times (i.e., summer 1991, spring 1992, and autumn 1992) over a two year period. The concentrations of As, Na, Cl, PO4, and pH were measured in these river samples and the associated terminal lakes. Arsenic values ranged from below 13 nmol/kg near Truckee, California to 160 nmol/kg at Nixon, Nevada in the Truckee River, from 40 nmol/kg in the headwaters of both West and East Walker Rivers to 270 nmol/kg below Weber Reservoir on the main branch of the Walker River, and from <27 nmol/kg to 234 nmol/kg for the lower Carson River system. Arsenic concentrations in Steamboat Creek (0.91 mol/kg–1.80 mol/kg) in the Truckee River catchment are above the U.S. EPA drinking water maximum contaminant level of 0.67 mol/kg, as are the As concentrations in both Pyramid Lake (1.33 mol/kg–1.57 mol/kg ) and Walker Lake (13.7 mol/kg–18.7 mol/kg). Sources of As for all three rivers include weathering of As-rich rocks and/or regolith and input of high-As geothermal spring waters, both processes primarily, although not exclusively, adding As to the headwater regions of these rivers. Steamboat Hot Springs (29 mol/kg As 54.5 mol/kg), for example, is identified as a source of As to the Truckee River via Steamboat Creek. The high As concentrations in Pyramid and Walker Lakes are likely due to (1) desorption of arsenate from aquatic particulate matter in these high pH waters (9.0 pH 9.5), (2) limited biologic uptake of arsenate, and (3) evaporative concentration of the lake waters. Evaluation of molar PO4}/As ratios of river waters and geothermal spring waters (e.g., Steamboat Hot Springs), indicates that phosphate is substantially enriched in Steamboat Creek as well as the mid to lower reaches of the Walker and Carson Rivers. These regions of each river are dominated by agricultural interests and, additionally, in the case of Steamboat Creek, residential areas and golf courses. Our data strongly imply that phosphate-rich agricultural return flow has likely added P to these streams and, consequently, increased their respective P:As ratios. 相似文献
17.
Dr. Hans-Peter Geis 《International Journal of Earth Sciences》1966,55(2):414-417
Zusammenfassung In Westnorwegen auftretende Magnetit-Ilmeniterze sind teilweise an intrusive, gabbroide Gesteine und teilweise an wahrscheinlich extrusive Amphibolite gebunden. Das TiO2Fe-Verhältnis der Amphiboliterze beträgt 0,14–0,15 und ist innerhalb der einzelnen Vorkommen konstant. In den Gabbroerzen liegt das Verhältnis zwischen 0,21 und 0,35 und schwankt auch innerhalb der Einzelvorkommen stark.
Magnetite-ilmenite ore in western Norway occurs partly in intrusive, gabbroic rocks, partly in amphibolites which seem to be extrusive. The relation TiO2: Fe in the amphibolite ores is 0.14–0.15 and is constant within every deposit. In the gabbro ores the relation TiO2Fe lies between 0.21 and 0.35 and varies also within every single deposit.
Résumé Dans l'Ouest de la Norvège des gisements de magnétite-ilménite se trouvent en partie dans des roches gabbroïques et intrusives, en partie dans des amphibolites qui sont probablement extrusives. Le rapport TiO2Fe dans les minerais amphibolitiques est de 0,14–0,15 et se montre très constant d'un gisement à l'autre. Dans les minerais gabbroïques, le rapport TiO2Fe varie entre 0,21 et 0,35 et diffère selon le gisement.
. TiO2: Fe .相似文献
18.
The role of tectonic grain size reduction in the rheological stratification of the lithosphere 总被引：3，自引：0，他引：3
With the aid of published constitutive flow laws for common crustal and upper mantle rock types, it is possible to construct curves showing variation of rock strength with depth in the continental lithosphere, assuming a particular crustal stratification of rock types and a particular geothermal gradient. Such exercises lead to the conclusion that marked changes in strength can occur at major petrological interfaces, such as the Moho discontinuity, which are therefore likely to be associated with a tendency for major, sub-horizontal detachments to form. Constitutive flow laws used for such purposes are usually assumed to represent steady-state flow, at constant rock microstructure.We argue that perhaps the most significant tectonic displacements of rock masses occur across major, localized shear zones, characterized by intense grain-size reduction, and illustrate this by reference to deformation in the metabasic and ultrabasic rocks of the lower part of the Ivrea Zone of northern Italy, which is believed to provide a section through what was once part of the deep continental crust. Calculations of the variation of the flow strength with depth of rocks should therefore use flow laws which include provision for strain dependent variations of strength, arising from strain dependent microstructural changes.We use the results of recent studies of grain-size dependent flow of olivine to estimate strain dependent variations in the flow strength of the sub-continental upper mantle, arising from dynamic recrystallization. From this we argue that after an initial period of flow at high stress, parts of the upper mantle can become very weak, if grain size is sufficiently reduced. Under favourable circumstances, flow can be concentrated immediately below the Moho, or in a band below the Moho. Such behaviour is consistent with our observations of the behaviour of dunites in the Ivrea Zone, and with some interpretations of upper mantle seismic reflectors.
Zusammenfassung Mit Hilfe von veröffentlichten wesentlichen Fließgesetzen für die meisten Krusten- und oberen Mantelgesteinstypen ist es möglich Kurven zu konstruieren, die Variationen in der Gesteinsfestigkeit in Abhängigkeit von der Tiefe innerhalb der kontinentalen Kruste zeigen. Dies unter der Annahme einer bestimmten krustalen Schichtung der Gesteinstypen sowie einem bestimmten geothermischen Gradienten. Derartige Untersuchungen führen zu dem Schluß, daß deutliche Unterschiede in der Gesteinsfestigkeit an markanten petrologischen Grenzflächen auftreten können, wie z. B an der Moho-Diskontinuität. Derartige Grenzflächen haben somit wahrscheinlich die Tendenz subhorizontale Ablösungsflächen auszubilden. Die allgemeinen Fließgesetze, die für diese Berechnungen angewandt wurden, repräsentieren gewöhnlich bei unverändertem Gesteinsmikrogefüge den »steady-state«Zustand. Es ist anzunehmen, daß die bedeutendsten tektonischen Verschiebungen in den Gesteinsmassen entlang großer, definierter Scherzonen stattfinden, die durch intensive Korngrößenreduktion charakterisiert werden. Belegt wird dies anhand der Deformation in den metabasischen und ultrabasischen Gesteinen des tieferen Teiles der Ivrea-Zone in Norditalien, von der angenommen wird, daß sie einen Schnitt durch denjenigen Teil darstellt, der ehemals dem tieferen Abschnitt der kontinentalen Kruste angehörte.Berechnungen der Variation der Fließfähigkeit von Gesteinen in Abhängigkeit von der Tiefe sollten daher Fließgesetze verwenden, die deformationsabhängige Variationen im Festigkeitsverhalten, das sich aus dem deformationsabhängigen Gefügewechsel ergibt, berücksichtigen.Wir benutzen die Ergebnisse neuerer Untersuchungen über korngrößenabhängiges Fließen von Olivin, um die Deformationsabhängigen Variationen im Fließverhalten des subkontinentalen oberen Mantels, das aus der dynamischen Rekristallisation entsteht, abzuschätzen. Hieraus läßt sich schließen, daß nach einer anfänglichen Periode des Fließens bei hohem Streß Teile des oberen Mantels sehr weich werden können, sofern nur die Korngröße genügend reduziert wird. Unter günstigen Bedingungen kann sich das Fließen direkt unter, zumindest aber in einem Bereich unter der Moho konzentrieren. Ein derartiges Verhalten steht in Übereinstimmung mit den Beobachtungen des Verhaltens der Dunite in der Ivrea-Zone sowie mit Interpretationen von seismischen Reflektoren des oberen Mantels.
Résumé En utilisant les lois de fluage fournies par la littérature à propos des roches courantes de la croûte et du manteau supérieur, il est possible de construire des courbes montrant la variation de la rigidité des roches en fonction de la profondeur dans la lithosphére continentale, ceci pour un gradient géothermique déterminé et pour une superposition déterminée des divers types de roches dans la croûte. De telles recherches conduisent à la conclusion que des changements brusques de rigidité peuvent se produire aux interfaces pétrologiques majeures, telle la discontinuité Moho; ces interfaces apparaissent de la sorte comme des endroits favorables à la production de décollements subhorizontaux importants. Les lois de fluage utilisées sont généralement supposées s'appliquer à la déformation plastique d'une roche à microstructure constante.Les auteurs pensent que les déplacements tectoniques les plus significatifs des masses rocheuses s'opèrent le long de shear zones localisées, caractérisées par une forte réduction de la taille des grains. Cette conception est illustrée par la déformation des roches basiques et ultrabasiques de la partie inférieure de la zone d'Ivrée (Italie du Nord), considérée comme une coupe à travers une partie d'une ancienne croûte continentale profonde. Les calculs de la variation de la ductilité des roches en fonction de la profondeur devraient donc utiliser des lois de fluage qui tiennent compte des variations de rigidité résultant des modifications microstructurales induites par la déformation.Les auteurs ont utilisé les résultats d'études récentes relatives aux relations entre le fluage de l'olivine et sa granularité; ils ont appliqué ces données à l'estimation de la manière dont varie la ductilité en fonction de la déformation dans le manteau supérieur sub-continental, dont les roches résultent de la recristallisation dynamique. Il en concluent qu'après une période initiale de flux sous haute contrainte, certaines parties du manteau supérieur peuvent devenir très déformables si leur grain a été suffisamment réduit. Dans des circonstances favorables, le flux peut se concentrer immédiatement sous Moho, ou se répartir dans une zone située sous Moho. Un tel comportement est en accord avec celui des dunites de la zone d'Ivrée, ainsi qu'avec l'interprétation des réflecteurs sismiques du manteau supérieur.
, , , . , , , , .: . , . , , , , . , , . , ; , , . , , , , ; . , , , . , , . , , , . , .相似文献
19.
Alessandro Pavese 《Physics and Chemistry of Minerals》2005,32(4):269-276
The notion of scalar strain in minerals is crucial for the formulation of P-V equations of state (EoS). A scalar strain, , holding for any crystal symmetry has been derived by a rigorous and general approach, and then used to develop the related phenomenological P-V EoS. , which depends on V and the trace of the G* G0 matrix, can be split into two components, M and , where the former takes values close to those of the scalar strain according to Birch. M, providing the main contribution (often larger than 80%) to , is appropriate for the formulation of an EoS as M/V behaves regularly in the limit of an unstrained configuration. The phenomenological EoS based on M shows the same dependence on the elastic parameters (bulk modulus and derivatives versus pressure) of the usual Birch-Murnaghan EoS, and yields comparable results. Slight deviations occur for low symmetry minerals. This work is meant to contribute (1) to shed light on the relationships between scalar strain and related P-V EoSs, and (2) to provide a most general EoS which includes, as a particular case, the Birch-Murnaghan model and explains why this latter is reliable for crystal symmetry other than the cubic one, for which it was originally derived. 相似文献
20.
Joseph A. Shacat William J. Green Eric H. Decarlo Silvia Newell 《Aquatic Geochemistry》2004,10(3-4):325-352
Lake Joyce is one of the least studied lakes of the McMurdo Dry Valleys. Similar to other lakes in this region, Lake Joyce is a closed-basin, permanently ice-covered, meromictic lake. We present here a detailed investigation of major ions, nutrients, and dissolved trace elements for Lake Joyce. Specifically, we investigate the role of iron and manganese oxides and hydrous oxides in trace metal cycling.Lake Joyce is characterized by fresh, oxic waters overlying an anoxic brine, primarily Na–Cl. Surface waters have a maximum nitrate concentration of 26M with a molar dissolved inorganic nitrogen to phosphorus ratio of 477. The supply of nitrogen is attributed to atmospheric deposition, possibly from polar stratospheric clouds. Dissolved phosphorus is scavenged by hydrous iron oxides. The pH is highest (10.15) just beneath the 7-m thick ice cover and decreases to a minimum of 7.29 in the redox transition zone. Dissolved Al exceeds 8M in surface waters, and appears to be controlled by equilibrium with gibbsite. In contrast, concentrations of other trace elements in surface waters are quite low (e.g., 5.4nM Cu, 0.19nM Co, <20pM La). Dissolved Fe, Mn, Ni and Cd were below our detection limits of 13 nM, 1. 8 nM, 4.7 nM and 15pM (respectively) in surface waters. There was a 6-m vertical separation in the onset of Mn and Fe reduction, with dissolved Mn appearing higher in the water column than Fe. Based on thermodynamic calculations, dissolved Mn appears to be controlled by equilibrium with hausmannite (Mn3 O4 ). Co tracks the Mn profile closely, suggesting Co(III) is bound in the lattice of Mn oxides, whereas the Ce profile is similar, yet the Ce anomaly suggests oxidative scavenging of Ce. Release of Cu, Ni, Cd and trivalent REE appears to be controlled by pH-induced desorption from Fe and Mn oxides, although Cu (and perhaps Ni) may be scavenged by organic matter in surface waters. 相似文献