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1.
As is well known, a high content of sulphur in coals is an effect of the post-depositional history of coal seams and one of the most important criteria of its use as a fuel. Sulphur in coals can cause a serious environmental and technological problem during their utilization. This problem is very actual for the Donetsk Basin because 734 mined seams out of the total of 1009 （73%） are comprised of coals with sulphur content -2%. The chemical pre-treatment as a first stage in their processing is widely used in order to effectively obtain the thermal destruction products of coals （such as semi-coke, coke, adsorbents, etc.） and to simultaneously utilize coal wastes. Development in pre-treatment methods for high-sulphur, low-rank coals is especially desirable for reducing the sulphur contents of the solid products. The aim of the present work is to investigate the influence of coal pre-treatment on the yield and composition of thermal destruction products, and the sulphur distribution among different components of the coals of different genetic types by reductivity （low-reduced LRC and reduced RC coals）. The thermal behavior of the coals was studied by means of the Fisher method （heated to 520℃, at a rate of 7℃/min）. The composition of the semi-coking gas was investigated by means of a VTI gas analyzer. The coal samples were chemically treated directly before thermal destruction by the introduction of 1-% solutions of radical polymerization initiator AAD （acrylic acid dinitrile C8H12N4） and products of coal-tar distillation （absorber oil）. Coal pre-treatment increases the semi-coke yield and its coking ability, and changes the liquid/gaseous product ratio.  相似文献   

2.
The volumes per oxygen of some silicate melts have been calculated and then compared with those of silicate glasses.It is suggested that the volume of a silicate melt can be divided into two parts.One is contri buted by the silicon-oxygen network and the other by the “oxides”.Variation patterns of VPOs suggest that the volume of the Si-O network generally remains unchanged and the expansion of the melt is caused mainly by the locat expansion of the “oxides”.It is further proposed that the radius of O^2- shows little variation,in striking contrast to the radius of cations.The mechanism governing the expansion is discussed in detail.  相似文献   

3.
The bacteria used in the experiment are Thiobacillus Ferrooxidans separated from acidic mine water in sulphide deposits. The chemoautotrophic bacteria can act directly on sulphides and accelerate the oxidation of sulphides. The experiment shows that the bacteria, as an important microbial factor of gold's supergenous enrichment within the oxidized zones of sulphide deposits, are helpful to dissolve gold and silver in ferric sulphate. In the bacterial oxidation process, the precipitation of goethite is concerned both with the lower activity of ferric ions and with the existence of carbonates in solution. Meanwhile, the acid-resisting and oxidizing ability of the bacteria will certainly lead up to a microbial way of treating the acidic mine water.  相似文献   

4.
Metallogenic Effect of Transition of Tectonic Dynamic System   总被引：13，自引：0，他引：13  
Tectonic dynmnic system transition, one of the main factors in metallngenesis, controls metallogenic fluid movement and ore body location in orefields and on an ore deposit scale (mainly in the continental tectonic setting), and even the formation and distribution of large-scale deposit clusters. Tectonic dynamic system transition can be classified as the spacious difference of the tectonic dynamic system in various geological units and the temporal alteration of different tectonic dynamic systems. The former results in outburst of mineralization, while the latter leads to the metallogenic diversity. Both of them are the main contents of metallogenic effect of tectonic dynamic system transition, that is, the alteration of dynamic system, the occurrence of mineralization, and the difference of regional tectonic dynamic system and metallogenic diversity. Generally speaking, the coupling of spatial difference of tectonic dynamic system and its successive alternation controlled the tempo-spatial evolution regularity of mineralization on a larger scale. In addition, the analysis of mineralization factors and processes of typical ore deposits proved that the changes of tectonic stress field, the direct appearance of tectonic dynamic system transition, way lead to the accident of mineralization physical-chemical field and the corresponding accidental interfaces were always located at ore bodies.  相似文献   

5.
Isotopic ages of synsedimentary clay minerals were directly determined with the ultrasonicscattering-settlement separation-K-Ar dilution technique. The apparent age of black mudstoneis 123 Ma for the Quantou Formation, 111.9-89.0 Ma for the Qingshankou Formation and77.6-76.8 Ma for the upper part of the Nenjiang Formation. The Rb-Sr isochrone age of themuddy limestone-mudstone sequence of the lower part of the Nenjiang Formation is 81 Ma andthat of the muddy evaporite of the middle part of the Quantou Formation is 122.2 Ma. On thebasis of the above isotopic ages, the authors propose a modified scheme of stratigraphic classifi-cation of the Cretaceous of the Songliao basin.  相似文献   

6.
There is a NE-trending earthquake hazard anomalous zone in the western part of the area of the city ofBeijing proper. A comprehensive study of it has been made. In the study the two-dimensional finite element dy-namic analysis and supersonic seismic model experiments were conducted for the first time. and some prelimi-nary results have been achieved. The Beijing depression, a lower order tectonic unit in the Beijing downwarp, is just located below theearthquake hazard anomalous zone. Analysis of the experimental results shows that the topography of the bu-ried bedrock is the main factor responsible for the presence of the anomalous zone. Besides. thetwo-dimensional mathematical analysis has more marked advantages in reflecting the lateral inhomogeneity ofthe foundation as compared with the one-dimensional one. and the supersonic seismic model experiments mayreflect the integrated effects of the earthquake sources, path of wave propagation and site geological structurein an all-round way.  相似文献   

7.
The fluctuation of most of the hydrograph in the deep aqueous system records the fluid pulsation in lithosphere and variation of the earth's crust. Many observations have verified that groundwater is an ideal information carrier of the crust. In this paper, the series of input (precipitation, air pressure, Earth tide etc.) and output (water level, artesian flow) of the deep aqueous system are studied by using the spectrum analysis and system theory. The application concepts of transfer function and the spectral structure of the hydrograph enrich the knowledge of the deep aqueous system. Two typical spectral structures of the hydrograph of the deep aqueous system are obtained by comparing with many water-bearing systems of the Jizhong depression. One is from well Ma-17 and the other is from the well Xinze-5. Finally, the physical models of forming the spectrum of the hydrograph are constructed on the basis of the spectrum research on the deep aqueous system.  相似文献   

8.
The source of silica in the formation of the Precambrian laminated cherts has long remained a problem to be solved. Through experiments on cherts and living blue-green algae, the authors found that the collected chert samples probably come from primary deposits, and there is a great biomass of fossil algae in chert, among which the filamentous algae can be compared with the living blue-green algae Oscillatoria, that a higher Pco_2 of the gas would be favourable for the increase of the biomass of living blue-green algae and consequently raises the pH value of the water body; and that lack of free oxygen and a higher concentration of SiO_2 in the water have no apparent influence on the biomass of blue-green algae. Based on the evidence above, a biogeochemical model concerning the origin of Precambrian laminated chert has been set up, in which the. photosynthesis of algae under the presumed atmospheric conditions of the Precambrian might raise the pH value of the water body and promote the dissolution of silicate minerals, thus providing a source of colloid SiO_2 for the formation of Precambrian laminated chert.Furthermore, a simulation experiment device has been designed successfully, which can control the temperature(30 ± 0.5°), Pco_2(50662.5 Pa) and Po_2(about zero Pa) of the gas, the rate of photosynthesis of algae and the movement of the water carrying opal. In the simulation experiments, separate measurements have been made on the rate of photosynthesis of algae, pH value and concentration of SiO_2 of the water body, with the results indicating that under the conditions similar to the presumed Precambrian atmosphere, the photosynthesis of algae can make the pH value of the water body go up steadily to over 9.7, leading to the dissolution of the silicate minerals, with the concentration of SiO_2 measured reaching as high as 84 mg/l. Finally, through the vaporation of water, a phenomenon of colloid floccilation has been observed.The simulation experiment has verified the proposed biogeochemical model illustrating the origin of Precambrian laminated chert. Moreover, the device and method of its kind may also be applied to the research on the relationship of the Precambrian algae with the formation of some other mineral deposits such as of Fe, Mn, U and carbonates.  相似文献   

9.
A comprehensive grasp of the research status of tensile strength of frozen soil is the basis for further research. Firstly,the typical methods that can be used to test the tensile strength of frozen soil are introduced,and the test conditions,sample forms and stress mechanism of different test methods are described in detail. The advantages and disadvantages of typical tensile strength test methods are compared and listed. Secondly,the research work and shortcomings based on different test methods are summarized. Then,the latest research progress of the influence of temperature,water content,loading（deformation）rate,soil quality and sample size on the change law of frozen soil tensile strength is comprehensively analyzed. Finally,it is proposed to develop and improve the research method and system of frozen soil tensile strength,and increase the testing research of warm frozen soil tensile strength,so as to obtain the prospect of more accurately simulating the tensile failure behavior of frozen soil. It is pointed out that the internal cause of the formation of the tensile strength and the tensile failure mechanism of frozen soil should be thoroughly revealed by combining the research methods of microstructure and digital image technology of frozen soil. Based on the multi-factor test,a more perfect prediction method of frozen soil tensile strength is explored. Meanwhile,expand the in-situ test research on the tensile strength of frozen soil,and strengthen the parallel research ideas of indoor and outdoor double tracks. Through the analysis of the research status and development trend at home and abroad,it provides reference and guidance for the experimental study of frozen soil tensile strength,the improvement of theoretical model of frost heave,geotechnical engineering design in cold regions and artificial freezing reinforcement engineering. © 2022 Science Press (China).  相似文献   

10.
Based on an analysis of the fractal structures and mass transport mechanism of typical shear-fluid-ore formation system, the fractal dispersion theory of the fluid system was used in the dynamic study of the ore formation system. The model of point-source diffusive illuviation of the shear-fluid-ore formation system was constructed, and the numerical simulation of dynamics of the ore formation system was finished. The result shows that: (1) The metallogenic system have nested fractal structure. Different fractal dimension values in different systems show unbalance and inhomogeneity of ore-forming processes in the geohistory. It is an important parameter to symbolize the process of remobilization and accumulation of ore-forming materials. Also it can indicate the dynamics of the metallogenic system quantitatively to some extent. (2) In essence, the fractal dispersive ore-forming dynamics is a combination of multi-processes dominated by fluid dynamics and supplemented by molecule dispersion in fluids and  相似文献   

11.
The Minerogenetic Series of Nonmetallic Mineral Deposits of China   总被引：1，自引：0，他引：1  
Owing to the internal relationship between material sources or mineralization ways and the difference ofmineralization micro-environments or the change of constraints. certain types of nonmetallic mineral depositsare regularly formed either simultaneously or in successive order under the control of certain association ofmineralization processes in a certain geotectonic environment, thus forming a minerogenetic series ofnonmetallic mineral deposits. The geological setting that controls the formation of minerogenetic series is mosttruly recorded in ore-bearing formations. while the mineralization processes which are associated or surely suc-cessive are the indispensable prerequisite for the formation of the various mineral deposits of a minerogeneticseries. Therefore, the minerogenetic series of nonmetallic mineral deposits can be classified according tomineral-bearing formations and mineralization processes. Based on available data. 13 minerogenetic series aredistinguished in China. The study of minerogenetic series may not only result in the enrichment of the theory ofmineral deposits but also help direct mineral prospecting and give guidance in the integrated development andutillization of mineral resources.  相似文献   

12.
Three-Dimensional P-Wave Velocity Structure of the Crust of North China   总被引：2，自引：0，他引：2  
Since the Xingtai (邢台) earthquake in 1966,China Earthquake Administration has carried out a survey campaign along more than thirty deep seismic sounding (DSS) profiles altogether about twenty thousand kilometers long in North China to study the velocity structure of the crust and the upper mantle in this region,and has obtained a great number of research findings. However,these researches have not provided a 3D velocity structure model of the crust of North China and cannot provide seismic evidence for the study of the deep tectonic characteristics of the crust of the whole region. Hence,based on the information from the published data of the DSS profiles,we have chosen 14 profiles to obtain a 3D velocity structure model of North China using the vectorization function of the GIS software (Arc/Info) and the Kriging data gridding method. With this velocity structure model,we have drawn the following conclusions: (1) The P-wave velocity of the uppermost crust of North China changes dramatically,exhibiting a complicated velocity structure in plane view. It can be divided into three velocity zones mainly trending towards north-west. In the research area,the lowest-velocity zones lie in the Haihe (海河) plain and Bohai (渤海) Bay. Although the geological structure of the sedimentary overburden in the study area is somewhat inherited by the upper crust,there are still several differences between them. (2) Generally,the P-wave velocity of the crust increases with depth in the study area,but there still exists local velocity reversion. In the east,low-velocity anomalies of the Haihe plain gradually disappear with increasing depth,and the Shanxi (山西) graben in the west is mainly characterized by relatively low velocity anomalies. Bounded by the Taihang (太行) Mountains,the eastern and western parts differ in structural trend of stratum above the crystalline basement. The structural trend of the Huanghuaihai (黄淮海) block in the east is mainly north-east,while that of the Shanxi block and the eastern edge of the Ordos block is mainly north-west. (3) According to the morphological features of Moho,the crust of the study area can be divided into six blocks. In the Shanxi block,Moho apppears like a nearly south-north trending depression belt with a large crustal thickness. In the southern edge of the Inner Mongolia block and the south of the Yanshan (燕山) block,the Moho exhibits a feature of fold belt,trending nearly towards east-west. In the eastern edge of the Ordos block,the structure of Moho is relatively complex,presenting a pattern of fold trending nearly towards north-west with alternating convexes and concaves. Beneath the Huanghuaihai block,the middle and northern parts of the North China rift zone,the Moho is the shallowest in the entire region,with alternating uplifts and depressions in its shape. For the anteclise zone in the west of Shandong (山东) Province,the Moho is discontinuous for the fault depression extending in the north-west direction along Zaozhuang (枣庄) -Qufu (曲阜).  相似文献   

13.
This paper deals with a simulated test of biogenic mineralization made with a blue-green alga species,Spirulina platensix. The data in the experiment were recorded by a computerized surveying system. The influ-ence of algae on the accumulation of phosphorus by changing their microenvironment to promote the forma-tion and deposition of phosphate was studied. The results show that the pH value of cultural liquor rose up to 10 and the redox potential (Eh) may dropby 100-200 mV during the algal logarithmic growth stage, and the cultrual liquor was changed into a mediumwith a weakly reducing condition. At the end of the logarithmic growth stage white deposits of Na_2Ca(CO_3)_2·5H_2O and Ca_2Mg (PO_4)_2·2H_2O were formed on the floor of cultural containers. The test presented a wduableevidence for the theory of biogenic mineralization.  相似文献   

14.
The distribution of frozen soil in our country is very broad, and the area of permafrost alone accounts for 22. 4% of the total land area. As a special kind of soil, frozen soil has many properties that thawing soil does not have due to the influence of ice cement in the soil. Among the many properties of frozen soil, the deformation and strength of frozen soil are the basic problems affecting engineering construction in frozen soil areas. The spherical template indenter test is widely used in the test of the mechanical properties of frozen soil because of its simple test process and relatively accurate test results. Compared with the conventional triaxial test or direct shear test, the test process of the spherical template indenter test is simple and easy to implement, the test period is short, and the sample preparation requirements are low. The advantage of effective cohesion is more significant. Therefore, based on the spherical template indenter test of the frozen soil, this paper estimates the strength and mechanical index of the soil through the indentation depth of the spherical template indenter test, and establishes the relationship between the force of the sample and the indentation depth of the indenter test. The specific test method is as follows:take the water-saturated frozen sandy soil made of different particle size groups(the moisture content of the sample is affected by the particle size in the saturated state)as the research object, study the variation law of the depth of the frozen soil sample pressed into the soil by the spherical indenter with time under the conditions of different fixed loads. By comparing and referring to the frozen sands of each particle size group, the long-term equivalent cohesion of the frozen sands of different particle size groups is summarized. The change law of force(long-term shear strength)with time, and the research method of elastic mechanics to solve space problems, summed up the mutual conversion between the depth St of spherical template indenters pressed into frozen sand samples under different fixed load test conditions relation. The research results show that the long-term shear strength of frozen sand based on the spherical mold test is positively correlated with its particle size. At the same time, since the ice content of frozen soil samples is proportional to its particle size, the long-term shear strength of frozen sand is also proportional to the test. The ice content of the sample increases year-on-year;the long-term shear strength of the frozen sand is related to the maximum contact pressure on the contact surface between the frozen soil and the indenter during the test, which can be expressed as Ct = γq0. The size of the relationship coefficient γ is inversely proportional to the diameter of the spherical indenter. In this paper, the spherical indenter is selected as 22 mm, and γ=3. 82×10-3. By establishing the relationship between the maximum contact pressure q0 and the long-term shear strength Ct When the maximum contact pressure q0 is the same under different fixed loads, the long-term shear strength Ct is also the same. According to this, the depth curve and the freezing depth of the frozen sand pressed into the soil by the spherical indenter over time under different fixed loads can be converted. Long-term shear strength curve of frozen sandy soil with time. It has been verified by experiments that the conversion curve of the depth of the indenter pressed into the soil with time under a fixed load of 7. 0 kg is highly consistent with the measured curve of the depth of the indenter pressed into the soil with time under a fixed load of 5. 1 kg and 7. 0 kg. © 2022 Nanjing Forestry University. All rights reserved.  相似文献   

15.
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16.
Analysis of the variations in the three-dimensional structural forms of the tungsten veins in the Xihuashantungsten district has proved that echelon structures of the veins were formed by the changes in stress directionthat caused the breakdown of the individual single veins. and are different from the echelon faults formed inshear zones. Echelon structures of the veins were produced near the lithologic boundary as a result of the rota-tion of stress direction in their neighbourhood and their control of vein distribution. The change in the echelonpattern caused by the varlation in the attitude of lithologic boundary surface in the district is an interestingstructural phenomenon, The echelon structures also reflect the variation characteristics of adjacent veins in theprocess of their propagation.  相似文献   

17.
Ultramafic rocks of Tibet and Xinjiang are the products of partial melting of the upper mantle. The evolution of their mineral composition is marked by two parallel evolutionary series: one is the progressive increase of the 100 Mg/(Mg+Fe~(2+) ratio of silicate minerals in order of lherzolite→harzburgite→dunite, i.e. the increase in magnesium; the other is the increase of the 100 Cr/(Cr+Al) ratio of accessory chrome spinel in the same order, i. e. the increase in Chromium. The above-mentioned evolutionary trends are contrary to that of magmatic differentiation. The evolution of fabrics of ultramafic rocks is characterized by progressive variation in order of protogranular texture→melted residual texture, symplectic texture and clastophyritic texture→equigranular mosaic texture and tabular mosaic texture. Experiments of partial melting of lherzolite have convincingly shown that the evolution of Alpine ultramafic rocks resulted from the partial melting of pyrolite. Various subtypes of them represent different degrees of partial melting. The vertical zoning marked by more basic rocks in the upper part and more acid rocks in the lower actually belongs to the fusion zoning of pyrolite.  相似文献   

18.
Model of Reflection Spectra of Rock Surface in 2π Space   总被引：5，自引：0，他引：5  
This paper deals with reflection spectra and polarized reflection spectra of 20 sorts of rock in 2π space, and then creates a model of reflection spectra of rock surface in 2π space. We measured the change of reflection and polarized reflection spectra as altering the incidence angle, vertex angle, azimuth angle, band and polarization. The results show that influence of the incidence angle on spectral curves is very strong. And when the vertex angle is constant, the horizontal azimuth polarizes rock spectra, and distorts the circular spectrum to become elliptic. The polarization influences the reflection intensity of rock spectra, but has no evident influence on the characteristics of wave forms of rock in 2π space. Therefore, we can describe the whole reflection spectral characteristics, including polarization, of rock surface in 2π space by measuring and calculating the e and p values in several key directions.  相似文献   

19.
As viewed from space remote-sensing images (e.g. Google Earth images) of South Guizhou and North Guangxi, the authors found that macroscopic karst landscape on the Earth’s surface is strongly controlled by the Conjugated shear joint of “X” type. Joints of this kind constitute a huge infiltration network and act as channel-ways for the permeation of meteoric waters from the surface, thus, leading to the dissolution of carbonate rocks nearby. As a result, the karst landscape is formed, which is dominated by linear karst valleys. An “X” karst valley network structure appears in the area where horizontal strata are distributed, and a feather-like network structure appears in the area where vertical strata are distributed, respectively. When the water permeates downwards to the underground-water level, it will flow horizontally along the strike of “X” joints toward the local base level of erosion to form an “X” network system of underground conduits in the area where horizontal strata are distributed, but it is relatively complex, because of the joining of other joints. This is the first time we have made use of Google Earth images to study the karst environment. Therefore, it has been successful in research on the Earth’s geomorphology, which could only rely on aerial photos and satellite photos in the past. Google Earth images provide low-cost and applicable imaging materials for the study of Earth’s geomorphology and karst rocky desertification and its control.  相似文献   

20.
Zonal distribution of seepage hydrocarbon-induced altereb carbonates over oil/gas reservoirs is a common phenomenon observed in the field.The authors considered that the continuous production of CO2 within the “alteration chimney ”gives rise to a significant difference in physical and chemical properties between its interior and the surrounding country rocks.And it is this difference that has promoted the erosion and precipitation of carbonates,thus leading to the zonal distribution of seepage hydrocarbon-induced altered carbonates over oil/gas reservoirs.This may be a reasonable interpretation of the phenomenon described above.  相似文献   

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