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1.
皖东蚌埠—五河地区位于华北克拉通东南缘,区内主要出露古老结晶基底五河杂岩。小红山重晶石石英脉呈近顺层状产出于五河杂岩地层内,脉中组成矿物以石英和重晶石为主,另有厘米级长柱状金红石以及少量的金属硫化物和黑云母,重晶石石英脉的上下围岩均发生不同程度的热液蚀变。显微镜下,金红石内部发育环带结构和核边结构,是脉体中早期晶出的矿物,可分为2种类型:黑色金红石和褐色金红石,其中前者为早阶段形成。金红石进行的EMPA和LA-ICP-MS分析测试结果显示,金红石W含量较低,且具有显著高的Nb/Ta、Zr/Hf比值,指示其变质流体成因。其高Nb低Cr、低Mg、Al、Si的特点,表现出壳源长英质(泥质)金红石的特点。金红石Zr温度t=(504.18±79.60)℃,位于角闪岩相变质区间,黑色金红石的形成温度较红褐色金红石更高。(Fe+Cr+V)含量与(Nb+Ta+W)含量的关系说明金红石中的V为V4+,元素置换方式在黑色金红石中为Fe2++2R5+→3Ti4+,而在红褐色金红石中为Fe3++R  相似文献   

2.
热液金红石U-Pb测年是确定金成矿时代的有效方法,然而金红石的多种成因限制了其在金成矿过程和年代学方面的应用。胶东夏甸金矿床中广泛发育多种类型的金红石,是鉴别金红石成因和厘定金成矿时代的理想选择。该矿床中的金红石呈簇状分布,与银金矿、黄铁矿、黄铜矿、闪锌矿和辉钼矿等热液矿物共生,且发育交代结构,呈不规则环带状,表明其为热液成因。通过BSE和EPMA分析,识别出两种热液金红石:高W金红石(W含量1.672%~6.125%,平均3.48%)和低W金红石(W含量0.002%~0.788%,平均0.204%)。在金成矿期的早阶段,富钛或含钛矿物的分解或重新平衡导致了低W金红石的沉淀,而成矿主阶段热液流体携带难熔元素及部分高场强元素多次脉动式上涌,流体中的V3+、W6+、Fe3+、Cr3+和Nb5+等离子以2M3++W■6+3Ti4+为主要机制置换早阶段低W金红石中的Ti4+形成高W金红石。夏甸金矿床...  相似文献   

3.
吕伟 《地质与勘探》2023,59(6):1260-1270
为研究黑河地区金红石微量元素特征及榴辉岩型金红石矿床的成矿地质条件,本文选取滇西澜沧黑河地区榴辉岩、石榴多硅白云母片岩中的金红石进行LA-ICP-MS微量元素分析。结果表明金红石微量元素呈现阶梯式三级分布特征,最富集Nb、Ta,其次是Zr、Hf,含量较少的元素有Ba、Rb、Sr、Th、REE;榴辉岩、榴闪岩类原岩属于变质基性岩类,含蓝晶石榴闪岩原岩属于玄武质凝灰岩类,石榴多硅白云母片岩类原岩属于泥质岩类;榴辉岩中金红石Nb/Ta比值均要高于其全岩Nb/Ta比值,金红石Nb、Ta含量与变质作用过程中元素在各矿物间的分配系数有关;采用金红石Zr含量温度计获得黑河地区榴辉岩的峰期变质阶段金红石形成温度为578~605℃,峰期变质作用后的退变质流体会造成金红石中Zr的再平衡。此外,黑河地区具备榴辉岩型金红石矿床形成的成矿物源、成矿作用的物理化学条件以及成矿的物质基础,有一定的找矿潜力。  相似文献   

4.
苏北榴辉岩中金红石的微量元素地球化学特征   总被引:5,自引:7,他引:5  
本文利用电子探针分析了苏北地区三类榴辉岩中金红石的Nb、Cr和Zr含量,在Zaek et al.(2002)的金红石Nb-Cr图解中,三类榴辉岩的原岩均为镁铁质岩,但它们具有不同的地球化学特征,即(1)小焦G类金红石榴辉岩中金红石的Nb含量最低,平均值为68ppm,而其它两类榴辉岩中金红石的Nb含量较高,平均值介于192~255ppm;(2)蓝晶石榴辉岩具有极高Cr含量,均值6106ppm,而许沟P类榴辉岩中金红石的Cr含量也较高,均值1233ppm,金红石榴辉岩中金红石Cr含量最低,均值为183ppm。利用Zaek et al.(2004)提出的金红石地质温度计,计算得出许沟P类榴辉岩的金红石形成温度介于600~751℃,平均温度689℃;演马厂M类榴辉岩的金红石温度介于507~641℃,平均温度557℃;小焦G类金红石榴辉岩金红石的形成温度介于541~673℃,平均温度613℃;新扬昌G类蓝晶石榴辉岩的金红石形成温度介于541~655℃,平均温度603℃。一种可能的解释是,榴辉岩在拆返过程中退变质作用明显,流体活动强烈,导致金红石中Zr扩散丢失,金红石中Zr含量不同程度地受到角闪岩相退变质过程中再平衡作用的影响,致使计算的温度偏低。  相似文献   

5.
陈菲  苏文  李晓光  胡鑫蒙  高静 《岩石学报》2021,37(12):3893-3902
本文通过金刚石对顶砧与拉曼光谱、红外光谱联用技术,原位模拟了金红石在高温高压下晶体结构及其OH的变化,从而了解俯冲带流体中金红石在地质过程中的行为及作用。实验证明,金红石在压力的作用下经历两次相变,分别为金红石型TiO2结构→斜锆石型TiO2结构(P=23.43GPa)→萤石型TiO2结构(P=34.98GPa),其结构在经历过超深俯冲后、折返过程中则以ɑ-PbO2型TiO2结构稳定存在。并且金红石晶体中的OH红外特征峰强度随着压力的增加而降低,从而显示在加压过程中金红石中OH含量降低,但直至地球深部超过600km(37.28GPa,约1200km),其晶体中的OH也并未完全脱去。在高温高压实验中,金红石样品从常温常压条件加压、加温至P=4.01~4.08GPa和T=700℃时,金红石晶体的有序度、OH含量随着温度增加而降低,但至实验最高温压,晶体内部仍保留OH,其结构也稳定存在,因此金红石可以将水携带至深部约120km处。在降至常温常压的过程中,金红石中OH含量虽然增加,但并未恢复至实验开始时的含量,因此经历过快速俯冲、折返后的金红石中的OH含量无法代表金红石形成时的OH含量。  相似文献   

6.
CCSD主孔超高压榴辉岩金红石中的矿物包裹体研究   总被引:6,自引:0,他引:6  
金红石是榴辉岩中的主要含钛副矿物。中国大陆科学钻探工程(CCSD)主孔100~2000m岩心样品中,金红石榴辉岩、多硅白云母榴辉岩和蓝晶石榴辉岩中都程度不等地含有金红石。金红石既可以与其他矿物一起被石榴石、绿辉石等主要变质矿物包裹,也可以包裹其他矿物。本文利用电子探针技术,对CCSD所揭示的超高压榴辉岩的金红石中的矿物包裹体进行了鉴定和分析。结果显示,绿辉石、富铪锆石、高铝榍石、韭闪石和红闪石、斜黝帘石等矿物包裹体形成于榴辉岩相进变质至峰期变质阶段;随着超高压变质带快速折返,榴辉岩经受强烈的退变质作用,包括金红石、绿辉石在内的多种矿物都经受了退变质作用,与金红石共生的钛铁矿完全或者部分退变成含铁金红石和钛铁晶石。在退变的金红石中,还发现了透辉石+斜长石后成合晶、低铝榍石、镁绿闪石等退变质矿物组合。  相似文献   

7.
对中国大陆科学钻探(CCSD)主孔200~1005m范围内8件榴辉岩样品的金红石进行了LA-ICPMS原位微区微量元素分析,结合前人已发表的全岩和金红石分析数据,研究结果发现:在不同类型榴辉岩中,金红石的微量元素与其全岩成分具有不同的相关关系。金红石中的Nb和Ta元素含量不同程度地受控于全岩Nb和Ta含量。在高钛和低镁钛榴辉岩中,金红石的Cr与全岩Cr/TiO2正相关;在富镁榴辉岩中,金红石的Cr含量受全岩MgO含量的控制;在高钛和富镁榴辉岩中,全岩成分明显影响着金红石的Zr含量,金红石Zr温度计可能不适用。低镁钛榴辉岩的金红石的平衡温度普遍低于榴辉岩峰期变质温度,可能是变质流体参与下的扩散作用和退变质作用所致;多数情况下,单个样品中大部分金红石颗粒的Zr含量是均匀的,金红石Zr温度计所给出的温度可能代表着退变质再平衡的温度;CCSD榴辉岩的全岩Nb/Ta比值普遍低于其中金红石的Nb/Ta比值,不支持金红石榴辉岩可能是地球上超球粒陨石Nb/Ta比值储库的观点。  相似文献   

8.
苏鲁榴辉岩型金红石矿床研究进展   总被引:1,自引:0,他引:1  
文章对苏鲁榴辉岩型金红石矿床的研究进展进行了简单综述。苏鲁超高压变质带金红石矿床的勘探可追溯到20世纪50年代末,近年来找矿工作取得重要进展,已查明金红石矿床总储量达数千万吨。矿床属典型的榴辉岩型金红石矿床,与超高压变质作用关系密切。金红石在榴辉岩中最主要也最具工业价值的赋存方式是呈粒间颗粒充填于主矿物绿辉石和石榴石之间,金红石中的微量元素与其寄主榴辉岩的类型和产状有明显的相关性,并且可反映其形成温度,因此在苏鲁超高压变质榴辉岩和金红石矿床的研究中具有重要价值。富钛基性原岩是榴辉岩型金红石矿床形成的物质基础,高压区域变质作用是这类矿床形成的必要条件。  相似文献   

9.
山西省代县脉矿金红石重选试验,用了螺旋选矿机,经磨矿机处理的金红石矿石,-200目含量为43.20%细粒物料;不分级或宽级别入选,能抛弃产率为54%的尾矿,其粗精矿作为摇床的给矿。再将金红石精矿进行磁选。用此简单的重选工艺流程,能取得金红石精矿TiO_2品位为95.28%,回收率76.93%的理想技术指标。给粗粒嵌布的金红石脉矿和金红石砂矿。开辟一条新的选矿途径。  相似文献   

10.
碎屑金红石:沉积物源的一种指针   总被引:3,自引:2,他引:1  
简星  关平  张巍 《地球科学进展》2012,27(8):828-846
近年来,碎屑金红石的研究已成为沉积物源区分析的一个新前沿。金红石的地球化学组成,尤其是Cr,Nb,Zr等微量元素的含量,对其母岩的形成条件和所经历的地质过程都具有重要的指示意义,同时,碎屑金红石在沉积、成岩过程中表现出极高的稳定性,因而是物源分析的理想指针矿物。首先介绍金红石的矿物学和地球化学基本性质,分析不同来源的金红石典型特征,重点阐述碎屑金红石在物源分析中运用的5个方面:①金红石重矿物比值;②金红石矿物化学成分Cr-Nb判别图解;③金红石Zr含量温度计;④金红石的U-Pb和(U-Th)/He定年;⑤金红石Lu-Hf同位素。综合上述5个方面的物源分析研究,可以获取金红石的母岩类型、形成温度及后期所经历的热演化史等信息。碎屑金红石的物源研究处于起步和探索阶段,仍存在一些亟需解决的问题。  相似文献   

11.
Eclogites of the Dabie Region: Retrograde Metamorphismand Fluid Evolution   总被引:4,自引:0,他引:4  
Based upon fluid effects, retrograde metamorphism of eclogites in the Dabie region can be divided into the fluid-poor, fluid-bearing and fluid-rich stages. The fluid-poor stage is marked by polymorphic inversion, recrystallization and exsolution of solid solutions, and is thought to represent eclogite-facies retrograde environments. The fluid-bearing stage is likely to have occurred at the late stage of ecologite-facies diaphthorosis and is represented by kyanite porphyroblasts, rutile, and sodic pyroxene in association with high-pressure hydrous minerals such as phengite and zoisite (clinozoisite) without significant amount of hydrous minerals such as amphibole, epidote and biotite. The fluid-rich stage might have commenced concomitantly with lower amphibolite-facies diaphthoresis and persisted all the way towards the near-surface environment. The product of this stage is characterized by plentiful hydrous and volatile-bearing phases.The dissemination-type rutile mineralizations in eclogites might have  相似文献   

12.
Redistribution of HFSE elements during rutile replacement by titanite   总被引:2,自引:0,他引:2  
Titanite growth at the expense of rutile during retrograde hydration of eclogite into amphibolite is a common phenomenon. We investigated an amphibolite sample from the Tromsø eclogite facies terrain in Northern Norway to gain insight into the trace element distribution between rutile and titanite during incomplete resorption of the rutile by titanite. Patchy compositional zoning of Al, Ti, and F in titanite relates to the presence of a fluid with variable Ti/Al and/or F during its growth. Laser ablation ICP–MS and electron microprobe data for high field strength elements (HFSE: Nb, Zr, Ta, and Hf) of rutile resorbed by titanite indicate a pronounced enrichment of these elements in the rim of a large single rutile crystal (~8 mm) and a systematic decrease towards uniform HFSE contents in the large core. HFSE contents of smaller rutile grains (~0.5 mm) and rutile inclusions (<100 μm) in the titanite overgrowth are similar or higher than in the rims of large rutile crystals. Element profiles from the rim inward demonstrate that HFSE enrichment in rutile is controlled by diffusion. HFSE ratios in diffusion-altered rutile show systematic variations compared with the uniform core composition of the large rutile. Modelling of Zr and Nb diffusion in rutile indicates that diffusion coefficients in rutile in fluid-dominated natural systems must be considerably higher than those determined experimentally at 1 bar in dry systems. Variations of HFSE contents in the newly formed titanite show no systematic spatial distribution. HFSE ratios in titanite and the rims of rutile are different, indicating different solid/fluid distribution coefficients in these minerals. Element fractionation by diffusion into the relict rutile and during fluid-mediated growth of new titanite could substantially change the HFSE budget of these minerals and could affect their use for geochemical tracing and other applications, such as Zr-based geothermobarometry.  相似文献   

13.
On the origin of oriented rutile needles in garnet from UHP eclogites   总被引:4,自引:0,他引:4  
Although oriented rutile needles in garnet have been reported from several ultrahigh‐pressure (UHP) rocks and considered to be important UHP indicators, their crystallographic features including growth habit and lattice correspondences with garnet host have never been properly characterized. This paper presents a detailed analytical electron microscopic (AEM) study on evenly distributed oriented rutile needles in garnet of two eclogitic rocks from Sulu. Some garnet in one UHP diamondiferous quartzofeldspathic rock from the Saxonian Erzgebirge, and in one high‐pressure (HP) felsic granulite from Bohemia also contain a few unevenly distributed oriented rutile needles. They have also been studied for the purpose of comparison. Despite different distribution patterns, AEM revealed that all rutile needles are oriented along the 〈111〉 directions of garnet with their lateral sides surrounded by the {110} planes of garnet, and that the growth directions of most needles are close to the normal of the {101} planes of rutile. No other specific crystallographic orientation relationships between rutile and garnet host were observed, and there is no pyroxene associated with rutile, as necessitated by the precipitation reaction of rutile in garnet as previously proposed. A simple solid‐state precipitation scenario for the formation of the rutile needles in garnet in these two eclogitic rocks is not justified. Three alternative mechanisms are considered for the formation of oriented rutile needles: (i) the rutile needles may be inherited from precursor minerals; (ii) the rutile needles may be formed by a dissolution–reprecipitation mechanism; and (iii) the rutile needles may be formed by cleaving and healing of garnet with rutile deposition. None of these mechanisms can fully explain the observations, although the first one is less likely and the third one is preferred. This study presents an example where the presence of oriented/aligned inclusions in minerals does not necessarily imply a precipitation origin.  相似文献   

14.
Nb,Ta的硅酸盐地球质量不平衡问题争论由来已久,备受关注。近年来研究发现,含金红石的榴辉岩Nb/Ta往往高于球粒陨石值(Nb/Ta=17.5),暗示其可能是平衡地球Nb亏损的独立储库。而洋壳玄武岩部分熔融实验表明Ta比Nb更倾向进入金红石晶格,这意味着作为俯冲洋壳部分熔融残留相的榴辉岩Nb/Ta不可能高于原岩。为了解释地质观察和实验结果之间的矛盾,系统分析了中国大陆科学钻探工程(CCSD)主孔、先导孔及附近地表榴辉岩的矿物微量元素。结果发现:榴辉岩中的Nb,Ta主要存在于金红石之中,其他矿物中含量极少;Nb,Ta之间存在着强烈分异(Nb/Ta=5.3~96.2),并总体上具有超球粒陨石的特征;韭闪石和多硅白云母的Nb/Ta平均分别为48.6,21.8,显示了很强的Nb,Ta分异能力;其他矿物如石榴石、绿辉石、绿帘石、磷灰石等的Nb、Ta含量及Nb/Ta都很低,对Nb-Ta分异不造成影响。认为导致Nb-Ta分异的不是金红石,而应出现在洋壳俯冲过程中金红石相出现之前的脱水和部分熔融阶段。富含Ti的角闪石(韭闪石)和白云母可能对Nb-Ta分异起到了决定性的作用。等金红石相出现之后,由于其对Nb,Ta的绝对控制作用,此前阶段的分异结果便被固定在金红石中而继承下来。因此,含金红石的榴辉岩常常表现出超球粒陨石Nb/Ta的特征,与金红石不能有效地分异Na,Ta的实验结果之间并不矛盾。在不均匀的上地幔中含金红石的榴辉岩是可能的超球粒陨石Nb/Ta储库之一。  相似文献   

15.
本文应用透射电子显微镜(TEM)详细研究了,中国苏鲁毛北地区金红石榴辉岩中金红石的超微构造特征。在该金红石榴辉岩中发育有两种不同类型的金红石晶体。第一种类型的金红石(Rt(A))与石榴石和绿辉石共生,其晶体内部发育有极密集的晶体缺陷,调制结构和变形双晶。变形双晶面分别为(100)和(010)。表明该类金红石晶体曾遭受过强烈的应力作用,推测它们可能是在大陆板块俯冲或折返过程中形成中发育的。而另一类金红石(Rt(B))存在于石榴石和绿辉石晶体中的包体,其晶格十分完整,没有变形痕迹。可能是由于该类金红石寄主于较大颗粒的石榴石或绿辉石晶体中,在大陆板块俯冲或折返过程中因受到寄住主晶的保护,没有发生晶格畸变。  相似文献   

16.

This work presents the results of studying srilankite, a rare zirconium titanate (ZrTi2O6), associated with ilmenite, rutile, zircon, uraninite, and other minerals discovered in high-pressure garnetites of the lherzolite Mindyak massif (Southern Urals). Srilankite occurs as inclusions in ilmenite and rutile of up to several tens of microns in size. It was established for the first time that srilankite contains a significant UO2 admixture (up to 20%). The negative correlation between Zr and U is evidence of isomorphism in the srilankite–brannerite system. The association of srilankite with high-Zr rutile indicates that formation of these minerals occurred at T > 850°С.

  相似文献   

17.
The composition of accessory minerals from granites of the second phase, quartz-muscovite (+fluorite), and quartz-muscovite-topaz greisens from the Primorsky rapakivi granite complex, West Baikal region, were studied using backscattered scanning electron microscopy. Ilmenite from granites contains inclusions of cassiterite, titanocolumbite, fergusonite-(Y), polycrase-(Y), and betafite. Allanite-(Ce), bastnaesite-(Ce), xenotime-(Y), Y- and Zr-thorite, zircon, and cyrtolite have been identified in granites. Greisens contain cassiterite, ferrocolumbite (Ta/Nb = 0.02−0.06), pyrochlore-group minerals, ilmenorutile, rutile, wolframite, polycrase-(Y), monazite-(Ce), fluocerite-(Ce), bastnaesite-(Ce), cerphosphorhuttonite, thorite, and other minerals. The ferrocolumbite + ilmenorutile assemblage is typical of quartz-muscovite greisen, whereas the rutile + ilmenorutile + wolframite + W-columbite assemblage is contained in the quartzmuscovite-topaz greisen as a result of an increase in Eh and decrease in pH and potassium activity of solution in the back zone. The compositions of Th- and REE-bearing minerals indicate the important role of phosphate and fluorine complexes in the transport of these elements.  相似文献   

18.
山西省阳高县堡子湾金矿床矿物标型特征   总被引:2,自引:0,他引:2  
根据成因矿物学及找矿矿物学观点,系统研究堡子湾金矿床黄铁矿、金矿物、方铅矿、黄铜矿和闪锌矿等金属矿物,石英、碳酸盐、绢(白)云母和金红石等非金属矿物的产状、形态及化学成分标型,结果表明:①矿床中矿物组合复杂,硫化物种类多,有少量硫盐矿物出现;②矿物中微量元素成分复杂,富含As,Sb,Bi,Se,Te等Au活化、迁移有利的矿化搬运剂,Cu,Ph,Zn,Au,Ag等成矿元素和Cr,Ni,V等深源元素;元素矿物组合及其特征比值指示金矿化与深源(下地壳或上地慢)浅成岩浆热液活动(斑岩系统)有关,燕山期石英二长斑岩(角砾岩)是成矿的主导因素;③矿石中大量出现铁白云石、富铁闪锌矿,粒状、富Ti金红石的大量分布,反映矿床剥蚀深度较大,目前可能已揭露至中深部中温带,位于斑岩系统的中下部,深部金矿化不利;④矿石含丰富的铜矿物,其他硫化物矿物中含铜量大,指示深部可能存在斑岩型Cu(Au)矿化。  相似文献   

19.
贺义兴  马瑞等 《地质论评》2001,47(1):82-87,T005,T006
河北省平山县阜平群是一套高角闪岩相岩石。根据宏观现象,某些地段曾经历过深熔作用过程。深熔效应以小觉地区的夕线石钾长浅粒岩最为典型。通过电子显微镜观测确认,所研究的夕线石钾长浅粒岩经受了深熔作用的改造,具有丰富而显著的微区矿物学标志。主要表现为前存矿物,如钾长石、条纹长石、石英、钠长石、黑云母和磁铁矿等,不同程度地被熔蚀,主要组成元素发生迁移和重组,沿矿物的解理、裂隙及粒间形成夕线石、石英、云母、长石、金红石等再结晶相。在深熔过程中,元素的迁移有两种可能形式:①选择性地从前存矿物晶格中移出;②通过前存矿物的熔融。Fe、Ti等元素从黑云母中移出,形成再结晶磁铁矿和金红石;Si、AI等元素则从黑云母和长石中移出,形成夕线石和再结晶石英。  相似文献   

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