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1.
The 558-m-deep ZK703 drillhole located near Donghai in the southern part of the Sulu ultrahigh-pressure metamorphic belt, eastern China, penetrates alternating layers of eclogites, gneisses, jadeite quartzites, garnet peridotites, phengite–quartz schists, and kyanite quartzites. The preservation of ultrahigh-pressure metamorphic minerals and their relics, together with the contact relationship and protolith types of the various rocks indicates that these are metamorphic supracrustal rocks and mafic-ultramafic rock assemblages that have experienced in-situ ultrahigh-pressure metamorphism. The eclogites can be divided into five types based on accessory minerals: rutile eclogite, phengite eclogite, kyanite–phengite eclogite, quartz eclogite, and common eclogite with rare minor minerals. Rutile eclogite forms a thick layer in the drillhole that contains sufficient rutile for potential mining. Two retrograde assemblages are observed in the eclogites: the first stage is characterized by the formation of sodic plagioclase+amphibole symplectite or symplectitic coronas after omphacite and garnet, plagioclase+biotite after garnet or phengite, and plagioclase coronas after kyanite; the second stage involved total replacement of omphacite and garnet by amphibole+albite+epidote+quartz. Peak metamorphic P– T conditions of the eclogites were around 32 to 40 kbar and 720°C to 880°C. The retrograde P– T path of the eclogites is characterized by rapidly decreasing pressure with slightly decreasing temperature. Micro-textures and compositional variations in symplectitic minerals suggest that the decompression breakdown of ultrahigh-pressure minerals is a domainal equilibrium reaction or disequilibrium reaction. The composition of the original minerals and the diffusion rate of elements involved in these reactions controlled the symplectitic mineral compositions. 相似文献
2.
Coarse-grained whiteschist, containing the assemblage: garnet+kyanite+phengite+talc+quartz/coesite, is an abundant constituent of the ultrahigh-pressure metamorphic (UHPM) belt in the Kulet region of the Kokchetav massif of Kazakhstan. Garnet displays prograde compositional zonation, with decreasing spessartine and increasing pyrope components, from core to rim. Cores were recrystallized at T=380°C (inner) to 580°C (outer) at P<10 kbar (garnet–ilmenite geothermometry, margarite+quartz stability), and mantles at T=720–760°C and PH20=34–36 kbar (coesite+graphite stability, phengite geobarometer, KFMASH system reaction equilibria). Textural evidence indicates that rims grew during decompression and cooling, within the Qtz-stability field. Silica inclusions (quartz and/or coesite) of various textural types within garnets display a systematic zonal distribution. Cores contain abundant inclusions of euhedral quartz (type 1 inclusions). Inner mantle regions contain inclusions of polycrystalline quartz pseudomorphs after coesite (type 2), with minute dusty micro-inclusions of chlorite, and more rarely, talc and kyanite in their cores; intense radial and concentric fractures are well developed in the garnet. Intermediate mantle regions contain bimineralic inclusions with coesite cores and palisade quartz rims (type 3), which are also surrounded by radial fractures. Subhedral inclusions of pure coesite without quartz overgrowths or radial fractures (type 4) occur in the outer part of the mantle. Garnet rims are silica-inclusion-free. Type 1 inclusions in garnet cores represent the low-P, low-T precursor stage to UHPM recrystallization, and attest to the persistence of low-P assemblages in the coesite-stability field. Coesites in inclusion types 2, 3, and 4 are interpreted to have sequentially crystallized by net transfer reaction (kyanite+talc=garnet+coesite+H2O), and were sequestered within the garnet with progressively decreasing amounts of intragranular aqueous fluid. During the retrograde evolution of the rock, all three inclusion types diverged from the host garnet P–T path at the coesite–quartz equilibrium, and followed a trajectory parallel to the equilibrium boundary resulting in inclusion overpressure. Coesite in type 2 inclusions suffered rapid intragranular H2O-catalysed transformation to quartz, and ruptured the host garnet at about 600°C (when inclusion P27 kbar, garnet host P9 kbar). Instantaneous decompression to the host garnet P–T path, passed through the kyanite+talc=chlorite+quartz reaction equilibrium, resulting in the dusty micro-assemblage in inclusion cores. Type 3 inclusions suffered a lower volumetric proportion transformation to quartz at the coesite–quartz equilibrium, and finally underwent rupture and decompression when T<400°C, facilitating coesite preservation. Type 4 coesite inclusions are interpreted to have suffered minimal transformation to quartz and proceeded to surface temperature conditions along or near the coesite–quartz equilibrium boundary. 相似文献
3.
Petrologic data on the paragenesis of (I) kyanite-zoisite marbles and (II) garnet-chloritoid quartz-mica schists are presented with the goal of providing constraints on the pressure-temperature evolution of the Eclogite Zone, Tauern Window, Austria. The peak metamorphic assemblages in the two rock types are: (I) kyanite + zoisite + dolomite + quartz; zoisite + muscovite + dolomite + calcite + quartz; and (II) garnet + chloritoid + kyanite + muscovite + quartz + epidote ± dolomite ± Zn-staurolite. The estimated peak metamorphic conditions are 19 ± 2 kbar, 590 ± 20°C. Secondary alteration of the kyanite-zoisite marbles was accomplished in two stages. The early stage resulted in the production of margarite, paragonite, secondary muscovite and chlorite and the later stage resulted in the formation of sudoite (a di/trioctahedral Mg---Al layer silicate) and kaolinite. The early alteration is bracketed at conditions between 3 and 10 kbar, 450–550°C and the later alteration between 200 and 350°C, P 3 kbar. The P-T path is characterized by maximum burial to approximately 19 kbar (60–70 km) (at≈590°C), followed by nearly isothermal decompression to approximately 10 kbar (30 km), and then more gradual decompression with cooling to approximately 3 kbar (10 km). Alteration was apparently accomplished by the influx of H2O-rich fluids, with the composition of the fluid locally buffered by the mineral assemblage. 相似文献
4.
The process of shape-transformation of quartz inclusions from polyhedral to spherical grains in albite single crystals during metamorphism is mainly controlled by the grain boundary diffusion of oxygen along the quartz/albite interface to reduce the interfacial free energy. The rate of the process, which is represented by the growth rate of the curvature of the edge surface of the grain, depends significantly on temperature and on the grain size of the quartz inclusion. The relations between temperature, T, the time, tr, and the critical radius, Rc, which is equal to the radius of maximum spherical grains, are given by log Rc = −0.11 Eb/ RT + 0.25log tr + C, in which Eb is the activation energy of the grain boundary diffusion of oxygen along the quartz/albite interface and C is a material constant. The mean critical radius of spherical quartz inclusions in albite is 5 μm for the upper chlorite zone and garnet zone, 10 μm for the lower biotite zone, and 20 μm for the upper biotite zone in the Sambagawa metamorphic terrain. The mean values of the critical radii of spherical quartz inclusions in oligoclase of the Ryoke metamorphic rocks is about 5 μm for the chlorite zone and about 10–20 μm for the sillimanite zone. Assuming temperatures of about 350°C for the upper chlorite and garnet zones, 400°C for the lower biotite zone, 550°C for the upper biotite zone, and 700°C for the sillimanite zone, the activation energy for the grain boundary diffusion of oxygen along the quartz/plagioclase interfase is estimated to be about 30 kcal/mol. 相似文献
5.
As is typical of ultra-high pressure (UHP) terrains, the regional extent of the UHP terrain in the Dabieshan of central China is highly speculative, since the volume of eclogites and paragneisses preserving unequivocal evidence of coesite and/or diamond stability is very small. By contrast, the common garnet ( XMn=0.18–0.45)–phengite (Si=3.2–3.35)–zoned epidote (Ps 38–97)–biotite–titanite–two feldspars–quartz assemblages in the more extensive orthogneisses have been previously thought to have formed under low P– T conditions of ca. 400±50°C at 4 kbar. However, certain orthogneiss samples preserve garnets with XCa up to 0.50, rutile inclusions within titanite or epidote and relict phengite inclusions within epidote with Si contents p.f.u. of up to 3.49 — overlapping with the highest values (3.49–3.62) recorded for phengites in samples of undoubted UHP schists. These and other mineral composition features (such as A-site deficiencies in the highest Si phengites, Na in garnets linked to Y+Yb substitution and Al F Ti −1 O −1 substitution in titanites) are taken to be pointers towards the orthogneisses having experienced a similar metamorphic evolution to the associated UHP schists and eclogites. Re-evaluated garnet–phengite and garnet–biotite Fe/Mg exchange thermometry and calculated 5 rutile+3 grossular+2SiO 2+H 2O=5 titanite+2 zoisite equilibria indicate that the orthogneisses may indeed have followed a common subduction-related clockwise P– T path with the UHP paragneisses and eclogites through conditions of Pmax at ca. 690°C–715°C and 36 kbar to Tmax at ca. 710°C–755°C and 18 kbar, prior to extensive re-crystallisation and re-equilibration of these ductile orthogneisses at ca. 400°C–450°C and 6 kbar. The consequential conclusion, that it is no longer necessary to resort to models of tectonic juxtapositioning to explain the spatial association of these Dabieshan orthogneisses with undoubted UHP lithologies, has far-reaching implications for the interpretation of controversial gneiss–eclogite relationships in other UHP metamorphic terrains. 相似文献
6.
Experiments in the system K 2O---MgO---Al 2O 3---SiO 2---H 2O (KMASH) were undertaken with the piston-cylinder-apparatus to study the reactions: 1. (1) phengite±quartz+K,Mg-rich siliceous fluid=feldspar+phologopite+H2O 2. (2) phengite+talc+K,Mg-rich siliceous fluid=phlogopite+quartz/coesite+H2O
at temperatures between 400 and 700°C. The ultrapotassic fluid appearing at pressures above 15 kbar on the low-temperature sides of the corresponding reaction curves, which show positive dP/dT slopes, is probably supercritical. The P-T positions of the reactions are compatible with KMASH mineral reactions studied previously and with melting investigations in the KMASH system undertaken at temperatures higher than 700°C. It is possible that natural rocks, chiefly K-rich metasediments subducted as minor portions of the oceanic crust, could give rise to low-temperature ultrapotassic fluids, mainly at temperatures between 300° to 600°C and pressures between 15 and 30 kbar. The ascending K-rich fluids would penetrate the overlying mantle to metasomatize it. After termination of the subduction process, heating of this mantle material, previously cooled by the subducted lithosphere, could lead to the formation of high-temperature K-rich magmas. 相似文献
7.
The stability and phase relations of phengitic muscovite in a metapelitic bulk composition containing a mixed H 2O+CO 2 fluid were investigated at 6.5–11 GPa, 750–1050°C in synthesis experiments performed in a multianvil apparatus. Starting material consisted of a natural calcareous metapelite from the coesite zone of the Dabie Mountains, China, ultrahigh-pressure metamorphic complex that had experienced peak metamorphic pressures greater than 3 GPa. The sample contains a total of 2.1 wt.% H 2O and 6.3 wt.% CO 2 bound in hydrous and carbonate minerals. No additional fluid was added to the starting material. Phengite is stable in this bulk composition from 6.5 to 9 GPa at 900°C and coexists with an eclogitic phase assemblage consisting of garnet, omphacite, coesite, rutile, and fluid. Phengite dehydrates to produce K-hollandite between 8 and 11 GPa, 750–900°C. Phengite melting/dissolution occurs between 900°C and 975°C at 6.5–8 GPa and is associated with the appearance of kyanite in the phase assemblage. The formation of K-hollandite is accompanied by the appearance of magnesite and topaz-OH in the phase assemblage as well as by significant increases in the grossular content of garnet (average Xgrs=0.52, Xpy=0.19) and the jadeite content of omphacite ( Xjd=0.92). Mass balance indicates that the volatile content of the fluid phase changes markedly at the phengite/K-hollandite phase boundary. At P≤8 GPa, fluid coexisting with phengite appears to be relatively CO 2-rich (XCO 2/XH 2O=2.2), whereas fluid coexisting with K-hollandite and magnesite at 11 GPa is rich in H 2O (XCO 2/XH 2O=0.2). Analysis of quench material and mass balance calculations indicate that fluids at all pressures and temperatures examined contain an abundance of dissolved solutes (approximately 40 mol% at 8 GPa, 60 mol% at 11 GPa) that act to dilute the volatile content of the fluid phase. The average phengite content of muscovite is positively correlated with pressure and ranges from 3.62 Si per formula unit (pfu) at 6.5 GPa to 3.80 Si pfu at 9 GPa. The extent of the phengite substitution in muscovite in this bulk composition appears to be limited to a maximum of 3.80–3.85 Si pfu at P=9 GPa. These experiments show that phengite should be stable in metasediments in mature subduction zones to depths of up to 300 km even under conditions in which aH 2O1. Other high-pressure hydrous phases such as lawsonite, MgMgAl-pumpellyite, and topaz-OH that may form in subducted sediments do not occur within the phengite stability field in this system, and may require more H 2O-rich fluid compositions in order to form. The wide range of conditions under which phengite occurs and its participation in mixed volatile reactions that may buffer the composition of the fluid phase suggest that phengite may significantly influence the nature of metasomatic fluids released from deeply subducted sediments at depths of up to 300 km at convergent plate boundaries. 相似文献
8.
Metagranites in the NKFMASH system require external hydration during prograde high-pressure metamorphism in order to equilibrate to ambient HP conditions by producing more siliceous muscovite. Any lack of external fluid or the disappearance of biotite stops re-equilibration and thus prevents recording of high-pressure conditions. The same hydration reactions cause dehydration during exhumation. Orthogneiss from shear zones or adjacent to metapelites and metabasites will take up external fluid during subduction and record the highest P– T conditions, but will also be the first to dehydrate upon exhumation, now hydrating other lithologies and probably refuelling shearzones. The (de)hydration behavior of Ca-bearing metagranitoids is similar to that in the Ca-free system. However, the anorthite component of plagioclase decomposes with increasing pressure to form either (clino)zoisite or a grossular-rich garnet. Both reactions are fluid-consuming. If H2O is supplied from an external source, the garnet-bearing assemblage can record P–T conditions up to very high pressures, but dehydrates again during heating and/or decompression to form a more Fe-rich garnet and Al-rich mica(s). The garnet compositions observed in natural HP-metagranites are mostly too Fe-rich to be formed in the presence of an H2O-rich fluid. N(C)KFMASH metapelites generally have a more complex mineralogy and succession of mineral assemblages along a P–T path. The H2O contained in hydrous silicates like chlorite and chloritoid is only partly released, but partly transferred to other minerals like paragonite, glaucophane or phengite during subduction and further dehydration during exhumation is common. The mineral assemblage preserved by the rock may then record P–T conditions way below those of the actual pressure and temperature peak of the path. Contouring of the P–T pseudosection of a specific metapelite composition with mode isopleths for H2O shows which P–T conditions along a given path are the ones most likely recorded by the rock. 相似文献
9.
High-grade exotic blocks in the Franciscan Complex at Jenner, California, show evidence for polydeformation/metamorphism, with eight distinct stages. Two parallel sets of mineral assemblages [(E) eclogite, and (BS) laminated blueschist] representing different bulk chemistry were identified. Stage 1, recorded by parallel aligned inclusions (S1) of crossite + omphacite + epidote + ilmenite + titanite + quartz (E), and glaucophane + actinolite + epidote + titanite (BS) in the central parts of zoned garnets, represents the epidote blueschist facies. The onset of a second stage (stage 2) is represented by a weak crenulation of S1 and growth of garnet. This stage develops a well-defined S2 foliation of orientated barroisite + epidote + titanite (E), or subcalcic actinolite + epidote + titanite (BS) at c. 90d? to S1, with syntectonic growth of garnet, defining the (albite-)epidote-amphibolite facies. A third stage, with aligned inclusions of glaucophane + (subcalcic) actinolite + phengite parallel to S2 in the outermost rims of large garnet grains, is assigned to the transitional (albite-)epidote-amphibolite/(garnet-bearing) epidote blueschist facies. The fourth stage represents the peak metamorphism, and was identified by unorientated matrix minerals in the least retrograded samples. In this stage the mineral assemblages garnet + omphacite + glaucophane + phengite (E) and garnet + winchite + phengite + epidote (BS) both represent the eclogite facies. Stage 5 is represented by the retrogression of eclogite facies assemblages to the epidote blueschist facies assemblages crossite/glaucophane + garnet + omphacite + epidote + phengite (E), and glaucophane + actinolite + epidote + phengite (BS), with the development of an S5 foliation subparallel to S2. Stage 6 represents a crenulation of S5, with the development of a well-defined S6 crenulation cleavage wrapping around relics of the eclogite facies assemblages. This crenulation cleavage is further weakly crenulated during a D7 event. Post-D7 (stage 8) is recorded by the growth of lawsonite + chlorite ± actinolite replacing garnet, and by veins of lawsonite + pumpellyite + aragonite and phengite + apatite. The different, yet coeval, mineral parageneses observed in rock types (E) and (BS) are probably due to differences in bulk chemistry. The metamorphic evolution from stage 1 to stage 8 seems to have been broadly continuous, following an anticlockwise P- Tpath: (1) epidote blueschist (garnet-free) to (2) (albite-)epidote-amphibolite to (3) transitional epidote blueschist (garnet-bearing)/(albite-)epidote-amphibolite to (4) eclogite to (5) epidote blueschist (garnet-bearing) to (6-7) epidote blueschist (garnet-free) facies to (8) lawsonite + pumpellyite + aragonite-bearing assemblages. This anticlockwise P- T path may have resulted from a decreasing geothermal gradient with time in the Mesozoic subduction zone of California at early or pre-Franciscan metamorphism. 相似文献
10.
将该区内的高喜马拉雅结晶岩划分为南部的角闪岩相岩石和北部的中低压麻粒岩相岩石,后者沿那木拉逆冲断层向南推覆于前者之上。高压麻粒岩相岩石仅以残余产出于后者,主要包括石榴石蓝晶石片麻岩和石榴石透辉石岩。前者的峰期矿物组合为石榴石+蓝晶石+三元长石+石英+金红石;后者的峰期组合为石榴石(铁铝榴石10 ±钙铝榴石 >80)+透辉石+石英+方柱石+榍石(Al 2O 3为4%-4.5%).变质温压估计结果表明高压麻粒岩相岩石形成于大约1.7-1.8GPa,890℃,然后经历了近等温降压变质作用至0.5±0.1GPa,850±50℃。它们的原岩可能是大理岩及泥质岩。这表明在区内曾存在一高压麻粒岩带,那木拉冲断层可能是高喜马拉雅结晶岩内的一条重要的构造界线。 相似文献
11.
The peak metamorphic conditions of subducted continental crust in the Dora-Maira massif (Western Alps) have been revised by combining experimental results in the KCMASH system with petrologic information from whiteschists. Textural observations in whiteschists suggest that the peak metamorphic assemblage garnet+phengite+kyanite+coesite±talc originates from the reaction kyanite+talc↔garnet+coesite+liquid. In the experimentally determined petrogenetic grid, this reaction occurs above 45 kbar at 730 °C. At lower pressures, talc reacts either to orthopyroxene and coesite or, together with phengite, to biotite, coesite and kyanite. The liberated liquid contains probably similar amounts of H 2O and dissolved granitic components. The composition of the liquid in the whiteschists at peak metamorphic conditions, a major unknown in earlier studies, was probably very similar to the liquid composition produced in the experiments. Therefore, the experimentally determined petrogenetic grid represents a good model for the estimation of the peak metamorphic conditions in whiteschists. Experimentally determined Si-isopleths for phengite further constrain peak pressures to 43 kbar for the measured Si=3.60 of phengite in the natural whiteschists. All these data provide evidence that the whiteschists reached diamond-facies conditions. The fluid-absent equilibrium 4 kyanite+3 CELADONITE=4 coesite+3 muscovite+pyrope has been calibrated on the basis of garnet and phengite compositions in the experiments and serves as a geothermobarometer for ultra-high-pressure (UHP) metapelites. For graphite-bearing metapelites and kyanite–phengite eclogites, forming the country rocks of the whiteschists, peak metamorphic pressures of about 44±3 kbar were calculated from this barometer for temperatures of 750 °C estimated from garnet–phengite thermometry. Therefore, the whole ultra-high-pressure unit of the Dora-Maira massif most likely experienced peak metamorphic conditions in the diamond stability field. While graphite is common in the metapelites, diamond has not been found so far. The absence of metamorphic microdiamonds might be explained by the low temperature of metamorphism, the absence of a free fluid phase in the metapelites and a short residence time in diamond-facies conditions resulting in kinetic problems in the conversion of graphite to diamond. 相似文献
12.
浙西南遂昌-大柘地区八都岩群在印支期变质事件影响下发生变质变形,通过详细野外调查和岩相学研究,可将其划分为3期变质变形序列：S 1变形期,NW向片麻理记录的残留紧闭褶皱,共生矿物组合为石榴子石变斑晶及其内部定向分布的包裹体矿物,石榴子石+黑云母+石英（泥质）和石榴子石+角闪石+斜长石+石英（长英质）;S 2变形期,区域性宽缓褶皱及NE向缓倾透入性片麻理,共生矿物组合为石榴子石变斑晶及定向分布的基质矿物,矽线石+石榴子石+黑云母+石英+斜长石±钾长石（泥质）和石榴子石+钾长石+斜长石+黑云母+石英（长英质）;S 3变形期,NE向陡倾透入性片麻理及韧脆性断裂大部分被花岗斑岩脉填充,共生矿物组合为石榴子石变斑晶及其周围退变矿物,石榴子石+矽线石+堇青石+斜长石+黑云母+石英±钾长石（泥质）和角闪石+斜长石+黑云母+钛铁矿（长英质）。结合前人研究成果,八都岩群印支期变质事件峰期变质程度达到麻粒岩相,显示顺时针近等温降压（ITD）型的 p- T演化轨迹,S 1-S 3变质变形反映出从俯冲碰撞到快速折返冷却的演化过程,伴随S 3同期侵位的花岗斑岩锆石U-Pb定年结果,将该演化过程完成时间约束在229.7 Ma,可能是浙西南地区对印支期古特提斯洋域内印支-华南-华北板块之间俯冲-碰撞过程的响应。 相似文献
13.
In the Pulur complex, NE Turkey, a heterogeneous rock sequence ranging from quartz-rich mesocratic gneisses to silica- and alkali-deficient, Fe-, Mg- and Al-rich melanocratic rocks is characterized by granulite-facies assemblages involving garnet, cordierite, sillimanite, ilmenite, ±spinel, ±plagioclase, ±quartz, ±biotite, ±corundum, rutile and monazite. Textural evidence for partial melting in the aluminous granulites, particularly leucosomes, is largely absent or strongly obliterated by a late-stage hydrothermal overprint. However, inclusion relations, high peak P– T conditions, the refractory modes, bulk and biotite compositions of the melanocratic rocks strongly support a model of partial melting. The melt was almost completely removed from the melanocratic rocks and crystallised within the adjacent mesocratic gneisses which are silica-rich, bear evidence of former feldspar and show a large range in major element concentrations as well as a negative correlation of most elements with SiO 2. Peak conditions are estimated to be ≥800 °C and 0.7–0.8 GPa. Subsequent near-isothermal decompression to 0.4–0.5 GPa at 800–730 °C is suggested by the formation of cordierite coronas and cordierite–spinel symplectites around garnet and in the matrix. Sm–Nd, Rb–Sr and 40Ar/ 39Ar isotope data indicate peak conditions at 330 Ma and cooling below 300 °C at 310 Ma. 相似文献
14.
A 600 m thick, more than 40 km long slice of eclogite faciesrocks, called the Sug?z? Nappe, occurs in the Alanya area, southernTurkey, sandwiched between two other crystalline nappes whichdo not show H P/L T metamorphism. All three nappcs were affectedby a later Barrovian-type metamorphism and penetrative deformationwhich welded the nappes into a single tectonic unit. The SugOzuNappe consists predominantly of garnet-mica schists with lensesof eclogite and blueschist metabasites. The mineral assemblagein the eclogites, garnet+omphacite+glaucophane+paragonite+quartz+phengite+rutile, is estimated to have formed at 13?5?1?5 kb and510?25?C. The eclogite assemblage is variably overprinted bya later Barrovian metamorphism with the development of barroisite,chlorite, and albite. The extent of the Barrovian overprintwas controlled by the supply of fluid to the rocks. The Barrovian metamorphism increases in grade downwards in thestructural sequence; biotite and garnet isograds are mappedin the lowermost Mahmutlar Nappe, made up mostly of metapelitesand metapsammites. The metapelites in the garnet zone consistof garnet+biotite+chlorite+muscovite+albite+oligoclase+quartz+ilmenite;metamorphic conditions are estimated as 6?5?1?0 kb and 469?13?C. The H P/L T rocks of the Sug?z? Nappe underwent a cooling of about100?C during a dry uplift from a depth of about 48 km to 21km where they were intercalated with the other nappes, and affectedby a Barrovian metamorphism caused by the incoming fluids. Thecase of the Alanya Nappcs illustrates that the Barrovian overprintobserved in many eclogites and blueschists may not be due toincreasing temperature during uplift, but simply due to theintroduction of a fluid phase during part of the uplift P- Tpath. 相似文献
15.
Scapolite–wollastonite–grossular bearing calc-silicate rocks from the Vellanad area in the Kerala Khondalite Belt (KKB) of Southern India preserve a number of reaction textures which help to deduce their P– T–fluid history. Textures include calcite+plagioclase±quartz symplectites after scapolite, grossular+quartz coronas between wollastonite and plagioclase, grossular coronas between wollastonite and plagioclase+calcite that replace former scapolite, and grossular blebs replacing anorthite+calcite+quartz pseudomorphs of scapolite. Garnet coronas are also observed between clinopyroxene and wollastonite or scapolite or plagioclase. The reactions, apart from those involving clinopyroxene, can be modelled in the simple CaO–Al 2O 3–SiO 2–CO 2 system and interpreted using partial reaction grids constructed for the activities of end-members in the analysed phases. The reaction topologies produced are good approximations for the peak as well as retrograde mineral assemblages and reaction textures. For the compositions of the phases present in this study, the medium pressure calc-silicate assemblages are defined by the stable pseudo-invariant points [Qtz], [Mei] and [Grs]. The textural features interpreted using these activity-corrected grids indicate a phase of isobaric cooling from about 835°C to 750°C at 6 kbar in the Vellanad area. This is inconsistent with earlier studies on other lithologies from the KKB, most of which imply a post-peak P– T path involving near-isothermal decompression. However, as the temperatures obtained for the KKB from the calc-silicates are higher than those previously deduced from metapelites and garnet–orthopyroxene assemblages, the phase of near-isobaric cooling reported here is inferred to have proceeded prior to the onset of the decompression documented from studies of other rock types. 相似文献
16.
遂昌-大柘泥质麻粒岩出露于华夏地块东北部的浙西南八都杂岩中,该岩石保留了典型的减压反应结构.但其变质演化特点、变质作用时代及构造意义目前尚不明确.通过系统的岩相学、矿物化学和同位素年代学分析,结果表明遂昌-大柘泥质麻粒岩记录了4个阶段的变质矿物组合,其中早期进变质阶段M 1的矿物组合为石榴石+黑云母+石英;压力峰期变质阶段M 2的矿物组合为石榴石+铝绿泥石+金红石+蓝晶石+刚玉+黑云母+石英±十字石,该矿物组合可能预示着岩石曾经历了超高压变质作用过程;峰期变质阶段M 3的矿物组合为石榴石+黑云母+夕线石+石英±钾长石±斜长石±钛铁矿;峰后近等温降压M 4-1阶段的矿物组合为石榴石+黑云母+夕线石+堇青石+石英+钛铁矿±尖晶石±斜长石±钾长石;M 4-2阶段的矿物组合为石榴石+堇青石+夕线石+斜长石+黑云母+石英±钾长石.相平衡模拟结合传统地质温压计限定其峰期变质阶段的温压条件为T=780~810 ℃、P=8.0~9.2 kbar;峰期后近等温降压的M 4-1阶段的温压条件为T=780~860 ℃和P=5.7~6.0 kbar,M 4-2阶段的温压条件为T=~700 ℃和P=~4.4 kbar,具有典型的顺时针近等温减压型P-T轨迹特征.LA-ICP-MS U-Pb定年结果表明其麻粒岩相变质作用时代为233.5~238.9 Ma.变质作用历史说明浙西南地体可能卷入了古特提斯洋域内印支-华南-华北板块之间的俯冲-碰撞过程,并经历了早中生代的麻粒岩相变质作用后快速折返至地表. 相似文献
17.
吉南新太古代泥质片麻岩出露于龙岗岩群四道砬子河岩组中,本文通过系统的岩相学、矿物化学、激光拉曼和锆石U Pb同位素年代学等分析,研究其变质演化特点、变质作用时代及构造意义.结果表明:龙岗岩群四道砬子河岩组泥质片麻岩记录了３个变质演化阶段,其中峰前期进变质阶段(M１)的矿物组合为石榴石＋黑云母＋斜长石＋石英＋白云母;峰期变质阶段(M２)的矿物组合为石榴石＋矽线石＋钾长石＋黑云母＋斜长石＋石英,达到麻粒岩相;峰后期退变质阶段(M３)以矽线石转变为蓝晶石为特征标
志,矿物组合为蓝晶石＋石榴石＋黑云母＋斜长石＋石英＋白云母.变质矿物地质温压计限定其变质作用,峰前期(M１)T 为４６８~５１５ ℃,p 为(３．８~４．３)×１０５ kPa;峰期(M２)T 为７０３~７６０ ℃,p 为(６．６~７．１)×１０５kPa;峰后期(M３)T 为５５２~５９１℃,p 为(５．５~６．０)×１０５kPa;具有典型的近等压冷却型逆时针变质作用p T 演化轨迹特征,可能是在地幔柱与岩石圈相互作用的环境中变质作用与大量的幔源岩浆底侵作用有关.LA ICP MS锆石U Pb定年结果显示麻粒岩相变质作用时代为２４９５~２４４２Ma,属于新太古代变质热事件产物. 相似文献
18.
The eclogite facies assemblage K-feldspar–jadeite–quartz in metagranites and metapelites from the Sesia-Lanzo Zone (Western Alps, Italy) records the equilibration pressure by dilution of the reaction jadeite+quartz=albite. The metapelites show partial transformation from a pre-Alpine assemblage of garnet (Alm 63Prp 26Grs 10)–K-feldspar–plagioclase–biotite±sillimanite to the Eo-Alpine high-pressure assemblage garnet (Alm 50Prp 14Grs 35)–jadeite (Jd 80–97Di 0–4Hd 0–8Acm 0–7)–zoisite–phengite. Plagioclase is replaced by jadeite–zoisite–kyanite–K-feldspar–quartz, and biotite is replaced by garnet–phengite or omphacite–kyanite–phengite. Equilibrium was attained only in local domains in the metapelites and therefore the K-feldspar–jadeite–quartz (KJQ) barometer was applied only to the plagioclase pseudomorphs and K-feldspar domains. The albite content of K-feldspar ranges from 4 to 11 mol% in less equilibrated assemblages from Val Savenca and from 4 to 7 mol% in the partially equilibrated samples from Monte Mucrone and the equilibrated samples from Montestrutto and Tavagnasco. Thermodynamic calculations on the stability of the assemblage K-feldspar–jadeite–quartz using available mixing data for K-feldspar and pyroxene indicate pressures of 15–21 kbar (±1.6–1.9 kbar) at 550±50 °C. This barometer yields direct pressure estimates in high-pressure rocks where pressures are seldom otherwise fixed, although it is sensitive to analytical precision and the choice of thermodynamic mixing model for K-feldspar. Moreover, the KJQ barometer is independent of the ratio PH2O/ PT. The inferred limiting a(H 2O) for the assemblage jadeite–kyanite in the metapelites from Val Savenca is low and varies from 0.2 to 0.6. 相似文献
19.
Calcic schists in the andalusite-type regional metamorphic terrainin the Panamint Mountains, California, contain the low-varianceassemblage quartz+epidote+muscovite+biotite+calcic amphibole+chlorite+plagioclase+spheneat low grade. Near the sillimanite isograd, chlorite in thisassemblage is replaced by garnet. The low variance in many calcicschists allows the determination of the nature of the reactionthat resulted in the coexistence of garnet+hornblende. A graphicalanalysis of the mineral assemblages shows that the reactioncan not be of the form biotite+epidote+chlorite+plagioclase+quartz=garnet+hornblende+muscovite+sphene+H 2Obecause garnet+chlorite never coexisted during metamorphismand the chlorite-bearing and garnet-bearing phase volumes donot overlap. The compositions of the minerals show that withincreasing grade amphibole changed from actinolite to pargasitichornblende with no apparent miscibility gap, the partitioningof Fe and Mg between chlorite and hornblende changed from KD(Mg/Fe, chl&) < 1 to KD > 1, the partitioning betweenbiotite and hornblende changed from KD (Mg/Fe, bio/amp) <1 in chlorite-zone samples to KD > 1 in garnet + hornblende-zonesamples, and the transition to the garnet-bearing assemblageoccurred when the composition of plagioclase was between An 55and An 80. Both the graphical analysis and an analytical analysisof the compositions of the minerals using simplified componentsderived from the natural mineral compositions indicate thatat the garnet+hornblende isograd the composition of hornblendewas colinear with that of plagioclase and biotite, as projectedfrom quartz, epidote, muscovite, and H 2O. During progressivemetamorphism, chlorite+biotite+epidote+quartz continuously brokedown to form hornblende+muscovite+sphene until the degeneracywas reached. At that point, tie lines from hornblende couldextend to garnet without allowing garnet to coexist with chlorite.Thus, the garnet+hornblende isograd was established throughcontinuous reactions within the chlorite-grade assemblage ratherthan through a discontinuous reaction. In this type of isograd,the low-grade diagnostic assemblage occurs only in Mg-rich rocks;whereas the high-grade assemblage occurs only in Fe-rich rocks.This relation accounts for the restricted occurrence of garnet+hornblendeassemblage in low-pressure terrains. In Barrovian terrains,garnet+chlorite commonly occurs, and the first appearana ofgarnet+hornblende can simply result from the continuous shiftof the garnet+chlorite tie line to Mg-rich compositions. 相似文献
20.
Migmatitic granulites from the Indian Head Range (IHR) are dominated by granoblastic, Opx-bearing (quartz) dioritic gneiss with subordinate garnet+orthopyroxene+biotite+albite (±quartz±microcline±cordierite±sillimanite) gneiss and comparatively biotite-rich, sapphirine+cordierite+orthopyroxene+albite (±microcline±sillimanite±corundum) gneiss. The latter contains at least two generations of sapphirine and cordierite, one apparently predating migmatization, the other associated with or following this event. Mineral thermobarometers yield temperatures up to 800 °C at 8 kbar. The IHR granulites have very high δ18O values (+10.8 to +14.5) which most likely indicate a sedimentary precursor. Their REE and HFSE contents resemble the trace element signature of post-Archean Australian shale (PAAS). Lithological analogues from other Grenvillian inliers in western Newfoundland have similar oxygen isotopic and immobile-element signatures. They too are interpreted as metasedimentary rocks. The IHR rocks, however, have unusually sodic compositions (e.g., Na 2O/CaO and Na 2O/K 2O=2.1–22.5 and 0.93–13.8, respectively) and contain albite or sodic oligoclase despite their high metamorphic grade. The geochemical data indicate that these rocks were albitized prior to high-grade metamorphism. No counterpart of this event is recorded in granulites from the other inliers, indicating that the IHR may be highly allochthonous with respect to these other Grenvillian terranes. 相似文献
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