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1.
As an essential nutrient for diatoms, silica plays a key role in the estuarine and coastal food web. High concentrations of dissolved silica (DSi) were found in the seepage water of tidal freshwater marshes, which were therefore assumed to contribute to the silica supply to estuarine waters in times of silica limitation. A comprehensive budget calculation for European salt marshes is presented in this study. Earlier, salt marshes were considered to have even higher silica recycling rates than tidal freshwater marshes. Between 2009 and 2011, concentrations, pools and fluxes of silica in two salt marshes at the German Wadden Sea coast were determined (in soil, pore water, aboveground vegetation, freshly deposited sediments and seepage water). Subsequently, a budget was calculated. Special emphasis was placed on the influence of grazing management on silica cycling. Our results show that the two salt marshes were sinks for silica. The average import of biogenic silica (BSi) with freshly deposited sediments (1,334 kmol km?2 year?1) largely exceeded the DSi and BSi exports with seepage water (80 kmol km?2 year?1). Grazing management can affect silica cycling of salt marshes by influencing hydrology and vegetation structure. Abandoned sites had larger DSi export rates than grazed sites. One third of all BSi imports occurred in only one major flooding, underlining the relevance of rare events in the silica budget of tidal marshes. This aspect has been widely neglected in earlier studies, what might have led to an underestimation of silica import rates to tidal marshes hitherto. 相似文献
2.
Silicon and sediment transport of the Changjiang River (Yangtze River): could the Three Gorges Reservoir be a filter? 总被引：3，自引：0，他引：3
Ran Xiangbin Yu Zhigang Chen Hongtao Zhang Xinquan Guo Hongbo 《Environmental Earth Sciences》2013,70(4):1881-1893
Water samples were collected from the Changjiang River (Yangtze River) in May 2005, after the impoundment of the Three Gorges Reservoir (TGR), to examine the influence of the TGR and large lakes on material delivery to the estuary of the Changjiang River. The concentrations of suspended particle material (SPM), dissolved silica (DSi) and biogenic silica (BSi) in the main stream were analyzed. The concentrations of DSi and BSi in the main channel of the Changjiang varied between 73 and 100 and 1.1–15 μmol/l, with a distance weighted average of 81 and 8.0 μmol/l, respectively. A calculation shows that live diatom comprises only an average value of 5.2 % of the BSi in the Changjiang River, and most of BSi may come from drainage basin. The concentrations of BSi and the ratios of BSi/SPM were relatively low in the Changjiang River compared to other rivers throughout the world, but the BSi carried in suspension by the Changjiang River was an important component of the rivers silicon load (i.e. ~13 %). SPM, DSi and BSi concentrations as observed in the Changjiang River tend to decrease from the upper sections of the river to the Three Gorges Dam (TGD), reflecting sedimentation associated with BSi trapping and DSi retention in the TGR in the normal-water period. SPM and BSi retention are more strongly influenced by the TGD compared to DSi. About 98 % of SPM, 72 % of BSi and 16 % of DSi were retained within the TGR in May 2005. The fluxes variations of DSi, BSi and SPM suggested that the large lakes and dams had a coupled effect on the transportation of DSi, BSi and SPM in the normal-water period. Such a change in silicon (DSi and BSi) balances of the Changjiang River will affect the ecological environment of the Changjiang estuary and its adjacent sea to some extent. 相似文献
3.
Natalia Borrelli M. Osterrieth A. Romanelli M. F. Alvarez J. L. Cionchi H. Massone 《Environmental Earth Sciences》2012,65(2):469-480
Although phytoliths constitute part of the wetland suspended load, there are few studies focused on the quantification of
them in the biogenic silica (BSi) pool. So, the aim of this paper is both to determine BSi content (diatoms and phytoliths)
and its relationship with dissolved silica in surface waters, and the influence of soil and groundwater Si biogeochemistry
in Los Padres wetland (Buenos Aires Province, Argentina). In the basin of the Los Padres wetland, dissolved silica (DSi) concentration
is near 840 ± 232 μmol/L and 211.83 ± 275.92 μmol/L in groundwaters and surface waters, respectively. BSi represents an 5.6–22.1%
of the total suspension material, and 8–34% of the total mineralogical components of the wetland bottom sediments. DSi and
BSi vary seasonally, with highest BSi content (diatoms specifically) during the spring–summer in correlation to the lowest
DSi concentration. DSi (660–917.5 μmol/L) and phytolith (3.35–5.84%) concentrations in the inflow stream are higher than in
the wetland and its outflow stream (19.1–113 μmol/L; 0.45–3.2%, respectively), probably due to the high phytolith content
in soils, the high silica concentration in the soil solution, and the groundwater inflow. Diatom content (5–16.8%) in the
wetland and its outflow stream is higher than in the inflow stream (0.45–1.97%), controlling DSi in this system. The understanding
of the groundwater–surface water interaction in an area is a significant element for determining the different components
and the role that they play on the local biogeochemical cycle of Si. 相似文献
4.
Marcelo F. L. Souza Viviane R. Gomes Simone S. Freitas Regina C. B. Andrade Bastiaan Knoppers 《Estuaries and Coasts》2009,32(1):111-122
Net ecosystem metabolism (NEM) was measured in the Piauí River estuary, NE Brazil. A mass balance of C, N, and P was used to infer its sources and sinks. Dissolved inorganic carbon (DIC) concentrations and fluxes were measured over a year along this mangrove dominated estuary. DIC concentrations were high in all estuarine sections, particularly at the fluvial end member at the beginning of the rainy season. Carbon dioxide concentrations in the entire estuary were supersaturated throughout the year and highest in the upper estuarine compartment and freshwater, particularly at the rainy season, due to washout effects of carbonaceous soils and different organic anthropogenic effluents. The estuary served as a source of DIC to the atmosphere with an estimated flux of 13 mol CO2 m?2 year?1. Input from the river was 46 mol CO2 m?2 year?1. The metabolism of the system was heterotrophic, but short periods of autotrophy occurred in the lower more marine portions of the estuary. The pelagic system was more or less balanced between auto- and heterotrophy, whereas the benthic and intertidal mangrove region was heterotrophic. Estimated annual NEM yielded a total DIC production in the order of 18 mol CO2 m?2 year?1. The anthropogenic inputs of particulate C, N, and P, dissolved inorganic P (DIP), and DIC were significant. The fluvial loading of particulate organic carbon and dissolved inorganic nitrogen (DIN) was largely retained in two flow regulation and hydroelectric reservoirs, promoting a reduction of C:N and C:P particulate ratios in the estuary. The net nonconservative fluxes obtained by a mass balance approach revealed that the estuary acts as a source of DIP, DIN, and DIC, the latter one being almost equivalent to the losses to the atmosphere. Mangrove forests and tidal mudflats were responsible for most of NEM rates and are the main sites of organic decomposition to sustain net heterotrophy. The main sources for this organic matter are the fluvial and anthropogenic inputs. The mangrove areas are the highest estuarine sources of DIP, DIC, and DIN. 相似文献
5.
V. Desplanques L. Cary J.-C. Mouret F. Trolard G. Bourri O. Grauby J.-D. Meunier 《Journal of Geochemical Exploration》2006,88(1-3):190
We conducted a study of the biogeochemical cycle of silicon in a rice field in Camargue (France) in order to evaluate the role of biogenic silicon particles (BSi) in the cycle. Opal-A biogenic particles (phytoliths, diatoms…), which dissolve more rapidly than other forms of silicate usually present in soils, are postulated to represent the easiest bioavailable Si for rice. We found 0.03–0.06 wt.% of BSi in soils (mainly phytoliths). This value is lower than other values from the literature. Each year, the exportation of BSi from rice cultivation is 270 ± 80 kg Si ha− 1. We show that BSi input by irrigation is mostly composed of diatoms and we estimate it at 100 kg Si ha− 1 year− 1. This value is more than a third of the annual Si need for rice. The budget of the dissolved silicon (DSi) fluxes gives the following results: the atmospheric and irrigation inputs represents 1% and roughly 10%, respectively, of the annual need for rice; the drainage and infiltration outputs represent 17 ± 14 and 12 ± 9 kg Si ha− 1 year− 1, respectively; the balance of our budget shows that at least 170 kg Si ha− 1 year− 1 are exported from the soil. If we consider the soil BSi as the only source of dissolved silicon, this stock could be exhausted in 5 years. 相似文献
6.
7.
We present a model of estuarine mixing, removal, and input for dissolved constituents, and apply the model to 39 nutrient (P, N, Si) profiles collected over a 14-month period in a pristine river/ estuary: Ochlockonee Bay, Florida. Each profile is deconvolved into three component functions: linear mixing (conservative) first-order removal (biological productivity), and parabolic input (regeneration). After correction for temporal variations in the fluvial end-members, the model provides quantitative estimates of total estuarine primary production, net regeneration, and subsequent fluxes to the ocean over a year-long period. The modeled data set is internally self-consistent: virtually perfect mass balances are obtained for P and Si. All biological P-uptake is regenerated within the estuary so that virtually 100% of the fluvial reactive-P enters the ocean. One-third of the fluvial reactive-P enters the estuary as particles whose phosphate is released after deposition in estuarine sediments. About 20% of the dissolved fluvial silica flux is removed biologically; all of this biogenic silica dissolves in the estuary and enters the ocean. N cannot be mass balanced, probably because it enters and escapes the bay in unmeasured forms (as NH4 or via denitrification to N2 and N2O). In the Ochlockonee, biological productivity removes nutrients in the ratios N:P ? 9:1 and Si:P ? 20:1. 相似文献
8.
May-Linn Paulsen Andreas J. Andersson Lihini Aluwihare Tyler Cyronak Sydney D’Angelo Charlie Davidson Hany Elwany Sarah N. Giddings Heather N. Page Magali Porrachia Stephen Schroeter 《Estuaries and Coasts》2018,41(4):1050-1068
Estuaries are important subcomponents of the coastal ocean, but knowledge about the temporal and spatial variability of their carbonate chemistry, as well as their contribution to coastal and global carbon fluxes, are limited. In the present study, we measured the temporal and spatial variability of biogeochemical parameters in a saltmarsh estuary in Southern California, the San Dieguito Lagoon (SDL). We also estimated the flux of dissolved inorganic carbon (DIC) and total organic carbon (TOC) to the adjacent coastal ocean over diel and seasonal timescales. The combined net flux of DIC and TOC (FDIC?+?TOC) to the ocean during outgoing tides ranged from ??1.8±0.5?×?103 to 9.5±0.7?×?103?mol C h?1 during baseline conditions. Based on these fluxes, a rough estimate of the net annual export of DIC and TOC totaled 10±4?×?106?mol C year?1. Following a major rain event (36 mm rain in 3 days), FDIC?+?TOC increased and reached values as high as 29.0 ±?0.7?×?103?mol C h?1. Assuming a hypothetical scenario of three similar storm events in a year, our annual net flux estimate more than doubled to 25 ±?4?×?106?mol C year?1. These findings highlight the importance of assessing coastal carbon fluxes on different timescales and incorporating event scale variations in these assessments. Furthermore, for most of the observations elevated levels of total alkalinity (TA) and pH were observed at the estuary mouth relative to the coastal ocean. This suggests that SDL partly buffers against acidification of adjacent coastal surface waters, although the spatial extent of this buffering is likely small. 相似文献
9.
陆地硅的生物地球化学循环研究进展 总被引：2，自引：0，他引：2
地球表层硅(Si)的生物地球化学循环与大气CO2浓度变化、大洋生物泵作用以及海岸带富营养化等过程密切相关,因此成为全球环境变化研究的核心问题之一。在地质时间尺度上,硅酸盐矿物的化学风化是地球表层所有次生Si的来源。陆地生态系统各次生Si库具有不同的形成机制和驱动因子,这导致各Si库的贮存量和循环周期存在明显差异。土壤Si库中的黏土矿物Si、溶解硅(DSi)和淀积在其他矿物表面的无定形Si都源自硅酸盐矿物的化学风化过程;植物生长过程中吸收土壤中的DSi形成生物Si,然后经微生物分解过程返还给土壤;地表径流将流域陆源Si以悬移质Si和DSi的形式输入河流、海洋。迄今,陆地不同形态Si库的大小及其对全球Si循环的贡献仍不确定。因此,在研究陆地Si的生物地球化学循环过程中,综合考虑各种地表过程及其耦合作用是非常必要的。 相似文献
10.
Douglas W. Bell Susan Denham Erik M. Smith Claudia R. Benitez-Nelson 《Estuaries and Coasts》2018,41(8):2223-2239
Across the coastal zone, rates of carbon and nutrient exchange are defined by the spatiotemporal heterogeneity of individual estuarine systems. Elemental stoichiometry provides a mechanism for simplifying overlapping physical, chemical, and biological drivers into proxies that can be used to compare and monitor estuarine biogeochemistry. To this end, the seasonal and tidal variability of estuarine stoichiometry was examined over an annual cycle in North Inlet (NI), South Carolina. Surface samples for dissolved and particulate carbon (C), nitrogen (N), and phosphorus (P) were collected every 20 days (August 2014 to August 2015) over a semi-diurnal tidal cycle. Dissolved nutrient flux estimates of an individual tidal creek were also made. Overall, the results demonstrated the dominance of seasonal versus tidal forcing on water column C:N:P stoichiometry. This seasonal behavior mediated the relative exchange of N and P into and out of the tidal creek and influenced the nutrient status index (NSI) of NI plankton communities. These communities were largely N deficient with the magnitude of this deficiency impacted by assumptions of inorganic versus organic plankton P demand and nutrient supply. Persistent N deficiency appeared to help drive the net import of N, while temporary P surplus likely drives its seasonal export. Combined, these results indicate that material delivery must be considered on seasonal time frames, as net annual fluxes do not reflect the short-term deliveries of C and nutrients into nearshore ecosystems. 相似文献
11.
A 3-D coastal ocean model with a tidal turbine module was used in this paper to study the effects of tidal energy extraction on temperature and salinity stratification and density-driven two-layer estuarine circulation. Numerical experiments with various turbine array configurations were carried out to investigate the changes in tidally averaged temperature, salinity, and velocity profiles in an idealized stratified estuary that connects to coastal water through a narrow tidal channel. The model was driven by tides, river inflow, and sea surface heat flux. To represent the realistic size of commercial tidal farms, model simulations were conducted based on a small percentage (less than 10 %) of the total number of turbines that would generate the maximum extractable energy in the system. Model results show that extraction of tidal in-stream energy will increase the vertical mixing and decrease the stratification in the estuary. Installation of in-stream tidal farm will cause a phase lag in tidal wave, which leads to large differences in tidal currents between baseline and tidal farm conditions. Extraction of tidal energy in an estuarine system has stronger impact on the tidally averaged salinity, temperature, and velocity in the surface layer than the bottom layer even though the turbine hub height is close to the bottom. Finally, model results also indicate that extraction of tidal energy weakens the two-layer estuarine circulation, especially during neap tides when tidal mixing is weakest and energy extraction is smallest. 相似文献
12.
Spatial gradients of silver concentrations in the surface waters of San Francisco Bay reveal substantial anthropogenic perturbations of the biogeochemical cycle of the element throughout the estuarine system. The most pronounced perturbations are in the south bay, where dissolved (<0.45 μm) silver concentrations are as high as 250 pM. This is more than one order-of-magnitude above baseline concentrations in the northern reach of the estuary (6 pM) and approximately two orders-of-magnitude above natural concentrations in adjacent coastal waters (3 pM). The excess silver is primarily attributed to wastewater discharges of industrial silver to the estuary on the order of 20 kg d?1. The contamination is most evident in the south bay, where wastewater discharges of silver are on the order of 10 kg d?1 and natural freshwater discharges are relatively insignificant. The limited amount of freshwater flushing in the south bay was exacerbated by persistent drought conditions during the study period. This extended the hydraulic residence time in the south bay (≥160 d), and revealed the apparent seasonal benthic fluxes of silver from anthropogenically contaminated sediments. These were conservatively estimated to average ≈16 nmol m?2 d?1 in the south bay, which is sufficient to replace all of the dissolved silver in the south bay within 22 d. Benthic fluxes of silver throughout the estuary were estimated to average ≈11 nmol m?2 d?1, with an annual input of approximately 540 kg yr?1 of silver to the system. This dwarfs the annual fluvial input of silver during the study period (12 kg yr?1) and is equivalent to approximately 10% of the annual anthropogenic input of silver to the estuary (3,700–7,200 kg yr?1). It is further speculated that benthic fluxes of silver may be greater than or equal to waste water fluxes of silver during periods of intense diagenic remobilization. However, all inputs of dissolved silver to the estuary are efficiently sorbed by suspended particulates, as evidenced by the relatively constant conditional distribution coefficient for silver throughout the estuary (Kd≈105). 相似文献
13.
Tidal pumping drives nutrient and dissolved organic matter dynamics in a Gulf of Mexico subterranean estuary 总被引：1，自引：0，他引：1
Isaac R. Santos William C. Burnett Thorsten Dittmar I G.N.A. Suryaputra Jeffrey Chanton 《Geochimica et cosmochimica acta》2009,73(5):1325-9900
We hypothesize that nutrient cycling in a Gulf of Mexico subterranean estuary (STE) is fueled by oxygen and labile organic matter supplied by tidal pumping of seawater into the coastal aquifer. We estimate nutrient production rates using the standard estuarine model and a non-steady-state box model, separate nutrient fluxes associated with fresh and saline submarine groundwater discharge (SGD), and estimate offshore fluxes from radium isotope distributions. The results indicate a large variability in nutrient concentrations over tidal and seasonal time scales. At high tide, nutrient concentrations in shallow beach groundwater were low as a result of dilution caused by seawater recirculation. During ebb tide, the concentrations increased until they reached a maximum just before the next high tide. The dominant form of nitrogen was dissolved organic nitrogen (DON) in freshwater, nitrate in brackish waters, and ammonium in saline waters. Dissolved organic carbon (DOC) production was two-fold higher in the summer than in the winter, while nitrate and DON production were one order of magnitude higher. Oxic remineralization and denitrification most likely explain these patterns. Even though fresh SGD accounted for only ∼5% of total volumetric additions, it was an important pathway of nutrients as a result of biogeochemical inputs in the mixing zone. Fresh SGD transported ∼25% of DOC and ∼50% of total dissolved nitrogen inputs into the coastal ocean, with the remainder associated with a one-dimensional vertical seawater exchange process. While SGD volumetric inputs are similar seasonally, changes in the biogeochemical conditions of this coastal plain STE led to higher summertime SGD nutrient fluxes (40% higher for DOC and 60% higher for nitrogen in the summer compared to the winter). We suggest that coastal primary production and nutrient dynamics in the STE are linked. 相似文献
14.
Ya-Chao Qin Huan-Xin Weng Haiyan Jin Jianyu Chen Rong-Xiang Tian 《Environmental Earth Sciences》2012,65(6):1855-1864
The extent of authigenic alteration of biogenic and reactive silica in Pearl River estuarine sediments has been estimated
using wet-chemical digestion methods. Results show relatively constant distributions of biogenic and reactive Si horizontally
and vertically. Based on three core measurements, the biogenic and total reactive Si average 77.91 and 264.77 μmol Si g−1, respectively. Their extents of authigenic alteration are correspondingly estimated as ~55.6 and ~70.6%. The average biogenic
Si accumulation rate is calculated as 1.91 × 109 mol Si year−1, which translates into storage of ~7.15% of the annual riverine dissolved silica input. By contrast, the total reactive Si
accumulation rate is as high as 6.49 × 109 mol Si year−1, improving annual riverine silicic acid storage to ~24.19%. Detailed investigation is required for a good understanding of
early diagenetic process of biogenic and reactive silica in this subtropical area. 相似文献
15.
J.-T. Cornelis B. Delvaux L. André S. Opfergelt 《Geochimica et cosmochimica acta》2010,74(14):3913-289
The terrestrial biogenic Si (BSi) pool in the soil-plant system is ubiquitous and substantial, likely impacting the land-ocean transfer of dissolved Si (DSi). Here, we consider the mechanisms controlling DSi in forest soil in a temperate granitic ecosystem that would differ from previous works mostly focused on tropical environments. This study aims at tracing the source of DSi in forest floor leachates and in soil solutions under various tree species at homogeneous soil and climate conditions, using stable Si isotopes and Ge/Si ratios. Relative to granitic bedrock, clays minerals were enriched in 28Si and had high Ge/Si ratios, while BSi from phytoliths was also enriched in 28Si, but had a low Ge/Si ratio. Such a contrast is useful to infer the relative contribution of silicate weathering and BSi dissolution in the shallow soil on the release of DSi in forest floor leachate solutions. The δ30Si values in forest floor leachates (−1.38‰ to −2.05‰) are the lightest ever found in natural waters, and Ge/Si ratios are higher in forest floor leachates relative to soil solution. These results suggest dissolution of 28Si and Ge-enriched secondary clay minerals incorporated by bioturbation in organic-rich horizons in combination with an isotopic fractionation releasing preferentially light Si isotopes during this dissolution process. Ge/Si ratios in soil solutions are governed by incongruent weathering of primary minerals and neoformation of secondary clays minerals. Tree species influence Si-isotopic compositions and Ge/Si ratios in forest floor leachates through differing incorporation of minerals in organic horizons by bioturbation and, to a lesser extent, through differing Si recycling. 相似文献
16.
Rafael Santana Guilherme C. Lessa John Haskins Kerstin Wasson 《Estuaries and Coasts》2018,41(1):99-113
Estuarine ecosystem diversity and function can be degraded by low oxygen concentrations. Understanding the spatial and temporal patterns of dissolved oxygen (DO) variation and the factors that predict decreases in DO is thus essential to inform estuarine management. We investigated DO variability and its drivers in Elkhorn Slough, a shallow, well-mixed estuary affected by high nutrient loading and with serious eutrophication problems. Long-term (2001–2012), high-resolution (15 min) time series of DO, water level, winds, and solar radiation from two fully tidal sites in the estuary showed that hypoxia events close to the bottom are common in the summer at the more upstream estuarine station. These events can occur in any lunar phase (spring to neap), at any time of the day, and both on sunny or cloudy days. They are, however, short-lived (lasting in average 40 min) and mainly driven by momentary low turbulent diffusion around slack tides (both at high and low water). Tidal advective transport explains up to 52.1% of the daily DO variability, and the water volume (or DO reservoir) contained in the estuary was not sufficient to avoid hypoxia in the estuary. Solar radiation was responsible for a positively correlated DO daily cycle but caused a decreased in the averaged DO in the summer at the inner station. Wind-driven upwelling reduced the average DO at the more oceanic station during spring. The approach we employed, using robust techniques to remove suspect data due to sensor drift combined with an array of statistical techniques, including spectral, harmonic, and coherence spectrum analysis, can serve as a model for analyses of long-term water quality datasets in other systems. Investigations such as ours can inform coastal management by identifying key drivers of hypoxia in estuaries. 相似文献
17.
David J. DeMaster Gary B. Knapp Charles A. Nittrouer 《Geochimica et cosmochimica acta》1983,47(10):1713-1723
Water column and seabed samples were obtained from 92 stations on the Amazon continental shelf during October of 1979. Uptake of silica near and southeast of the river mouth began at a salinity of 8%. and accounted for 17% of the riverine silica flux to this region. Uptake northwest of the river mouth began at a salinity of 20%. and resulted in 33% removal of the riverine silica flux. Examination of filtered suspended solids revealed abundant diatoms in the surface waters, including Coscinodiscus. Skeletonema, Synedra. and Thalassiosira. The biological uptake of silica appears to be dependent on three factors: turbidity, turbulence, and nutrient availability. There was no evidence of abiological removal of silica in the Amazon estuary. 75 to 88% of the silica removed from surface waters by diatoms dissolves prior to accumulation in the seabed. Based on the mean biogenic silica content of shelf sediment (0.25%) and estimates of rates of sediment accumulation, the biogenic silica accumulation rate on the shelf is 2 × 1012 g/yr, which represents only 4% of the dissolved silica supplied by the Amazon River. Biological uptake of silica in estuarine surface waters may not accurately reflect permanent removal of biogenic silica to the seabed because of dissolution which occurs in bottom waters and near the sediment-water interface. 相似文献
18.
19.
Milena B. Fernandes Marie-Alexandrine Sicre Anne Boireau Jacek Tronczynski 《Estuaries and Coasts》1997,20(2):281-290
Dissolved and particulate hydrocarbons of biogenic origin were investigated for the first time in surface waters along the Seine River and its estuary. They comprise n-alkanes (n-ALKs) and diagenetic polycyclic aromatic hydrocarbons (PAHs). Samples were collected in three different sections of the estuary: the riverine zone, the mixing zone, and the marine zone. At the river mouth, two mooring stations were used for the collection of samples over tidal cycles. Total particulate n-ALK concentrations ranged from 31 ng 1?1 to 2,918 ng 1?1, or 5 μg g?1 dry ng 1?1, or 2 μg g?1 of SM. Concentrations varied with the SM load and could be related to sedimentation and estuarine mixing. The sources of the n-ALKs were different in each zone of the estuary. The dissolved n-ALKs displayed lower concentrations than the particulate phase, varying from 136 ng 1?1 to 344 ng 1?1, while biogenic dissolved PAHs were almost absent. 相似文献
20.
沉积物岩心记录着沉积环境的演变过程,其中生物硅(BSi)记录能反映硅质生物的生产力时间和空间变化,2012年5月在下辽河平原西南缘得到了ZK2钻孔柱状样,通过对其沉积物原位密度、生物硅、碳埋藏、粒度、AMS~(14)C和OSL测年、有孔虫鉴定、孢粉鉴定,将ZK2孔的沉积环境主要划分为上三角洲平原相沉积、海洋主导的沉积、湖相沉积、河道沉积4个沉积单元,其相应的生物硅(BSiO_2)浓度分布依次为(2.85±0.23)%、(1.55±0.10)%、(1.96±0.10)%、(0.92±0.05)%,并且生物硅的波动与颗粒有机碳浓度的波动同步。特别是在17~25 cal ka BP冰期形成的湖沼沉积出现较大的颗粒无机碳(PIC)浓度的波动,推测与当时干冷气候条件下CaCO_3过饱和从湖水中沉淀析出有关。钻孔沉积物生物硅浓度记录对格陵兰冰芯~(18)O同位素值的响应存在大约300 a的滞后现象。 相似文献