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1.
《Russian Geology and Geophysics》2014,55(11):1306-1315
We present new original data on the geochemistry of scandium in the coals of Asian Russia, Mongolia, and Kazakhstan. In general, the studied coals are enriched in Sc as compared with the average coals worldwide. Coal deposits with abnormally high, up to commercial, Sc contents were detected in different parts of the study area. The factors for the accumulation of Sc in coals have been identified. The Sc contents of the coals depend on the petrologic composition of coal basins (composition of rocks in their framing) and the facies conditions of coal accumulation. We have established the redistribution and partial removal of Sc from a coal seam during coal metamorphism. The distribution of Sc in deposits and coal seams indicates the predominantly hydrogenic mechanism of its anomalous concentration in coals and peats. The accumulation of Sc in the coals and peats is attributed to its leaching out of the coal-bearing rocks and redeposition in a coal (peat) layer with groundwater and underground water enriched in organic acids. The enrichment of coals with Sc requires conditions for the formation of Sc-enriched coal-bearing rocks and conditions for its leaching and transport to the coal seam. Such conditions can be found in the present-day peatland systems of West Siberia and, probably, in ancient basins of peat (coal) accumulation. 相似文献
2.
Previous investigations have not well defined the controls on the development of minable coals in fluvial environments. This study was undertaken to provide a clearer understanding of these controls, particularly in of the lower Tertiary coal-bearing deposits of the Raton and Powder River basins in the Rocky Mountain region of the United States. In this region, large amounts of coals accumulated in swamps formed in the flow-through fluvial systems that infilled these intermontane basins. Extrabasinal and intrabasinal tectonism partly controlled the stratigraphic and facies distributions of minable coal deposits. The regional accumulation of coals was favored by the rapid basin subsidence coupled with minimal uplift of the source area. During these events, coals developed in swamps associated with anastomosed and meandering fluvial systems and alluvial fans. The extensive and high rate of sediment input from these fluvial systems promoted the formation of ombrotrophic, raised swamps, which produced low ash and anomalously thick coals. The petrology and palynology of these coals, and the paleobotany of the associated sediments, suggest that ombrotrophic, raised swamps were common in the Powder River Basin, where the climate during the early Tertiary was paratropical. The paleoecology of these swamps is identical to that of the modern ombrotrophic, raised swamps of the Baram and Mahakam Rivers of Borneo. 相似文献
3.
A.B. Cadle B. Cairncross A.D.M. Christie D.L. Roberts 《International Journal of Coal Geology》1993,23(1-4)
The coal-bearing sediments and coal seams of the Karoo Basin, Southern Africa are described and discussed. The Karoo Basin is bounded on its southern margin by the Cape Fold Belt, onlaps onto the Kaapvaal Craton in the north and is classified as a foreland basin. Coal seams are present within the Early Permian Vryheid Formation and the Triassic Molteno Formation.The peats of the Vryheid Formation accumulated within swamps in a cool temperate climatic regime. Lower and upper delta plain, back-barrier and fluvial environments were associated with peat formation. Thick, laterally extensive coal seams have preferentially accumulated in fluvial environments. The coals are in general inertinite-rich and high in ash. However, increasing vitrinite and decreasing ash contents within seams occur from west to east across the coalfields. The Triassic Molteno coal seams accumulated with aerially restricted swamps in fluvial environments. These Molteno coals are thin, laterally impersistent, vitrinite-rich and shaly, and formed under a warm temperate climatic regime.Palaeoclimate, depositional systems, differential subsidence and basin tectonics influence to varying degrees, the maceral content, thickness and lateral extent of coal seams. However, the geographic position of peat-forming swamps within a foreland basin, coupled with basin tectonics and differential subsidence are envisaged as the primary controls on coal parameters. The Permian coals are situated in proximal positions on the passive margin of the foreland basin. Here, subsidence was limited which enhanced oxidation of organic matter and hence the formation of inertinitic coals. The coals in this tectonic setting are thick and laterally extensive. The Triassci coals are situated within the tectonically active foreland basin margin. Rapid subsidence and sedimentation rates occurred during peat formation which resulted in the preservation of thin, laterally impersistent, high ash, vitrinite-rich, shaly coals. 相似文献
4.
V. V. Krapiventseva 《Russian Journal of Pacific Geology》2013,7(6):441-454
The catagenesis of the Jurassic-Cretaceous deposits and coals has been comprehensively examined based on a complex of features including the reflectance (R o and R a), the qualitative properties, and the petrochemical characteristics (the density and saturation porosity) of the host rocks. The catagenesis of the Jurassic-Cretaceous deposits was studied based on the structural zones in which the coal-bearing deposits occur at different depths ranging from ～ 10 to 300 m, down to 700m, and from 5 to 3460 m in the Western, Central, and Kyndal zones, accordingly. The following regularities of the changing of the coal’s catagenesis have been established: from group 3B to 1G, 2G, and GFL; from gradation PC3 to MC1-MC2; and from MC2 to MC3-MC4 with the changing of the composition of the coals from long-flame coal to gas and gasfat-lean coal. In the intrusive bodies distribution areas breaking through the coal-bearing deposits, the coal seams are metamorphosed to the marks of lean caking and lean coals. The data obtained have made possible the assessment of the hydrocarbon generation in the Jurassic-Lower Cretaceous deposits of the basin. 相似文献
5.
The gravity of Ethiopian energy problem has initiated studies to explore various energy resources in Ethiopia, one among this is the exploration for coal resources. Studies confirmed the presence of coal deposits in the country. The coal-bearing sediments are distributed in the Inter-Trappean and Pre-Trap volcanic geological settings, and deposited in fluvio-lacustrine and paludal environments in grabens and half-grabens formed by a NNE–SSW and NNW–SSE fault systems. Most significant coal deposits are found in the Inter-Trappean geological setting. The coal and coal-bearing sediments reach a maximum thickness of 4 m and 300 m, respectively. The best coal deposits were hosted in sandstone–coal–shale and mudstone–coal–shale facies. The coal formations of Ethiopia are quite unique in that they are neither comparable to the coal measures of the Permo-Carboniferous Karroo Formation nor to the Late Devonian–Carboniferous of North America or Northwestern Europe. Proximate analysis and calorific value data indicated that the Ethiopian coals fall under lignite to high volatile bituminous coal, and genetically are classified under humic, sapropelic and mixed coal. Vitrinite reflectance studies confirmed 0.3–0.64% Ro values for the studied coals. Palynology studies confirmed that the Ethiopian coal-bearing sediments range in age from Eocene to Miocene. A total of about 297 Mt of coal reserve registered in the country. The coal reserve of the country can be considered as an important alternative source of energy. 相似文献
6.
宁夏煤炭资源丰富,煤类多,在区域和垂向上呈现出明显的规律性。晚古生代煤层以中、高变质的烟煤、无烟煤为主,中生代煤层以低变质的烟煤为主,从各含煤区分布看,贺兰山、香山含煤区多为高变质的烟煤和无烟煤,灵盐、固原含煤区以低变质烟煤为主,青铜峡-固原深断裂西部的煤变质程度明显高于东部。分析认为深成变质作用对各时代煤变质具有普遍意义,在此基础上,岩浆热力变质作用和动力变质作用也是导致局部地区煤变质增高的因素,如贺兰山含煤区的汝箕沟矿区,受隐伏岩浆热力影响,以岭大井田为中心,呈现北东向展布的半环带状煤级分带;香山含煤区各时代煤类分布方向与区域构造线方向一致,推测可能在深成变质作用下叠加了岩浆热力变质和动力变质作用。 相似文献
7.
Bat-Orshikh Erdenetsogt Insung Lee Delegiin Bat-Erdene Luvsanchultem Jargal 《International Journal of Coal Geology》2009,80(2):87-104
This paper presents geological settings, stratigraphy, coal quality, petrography, reserves and the tectonic history of the Mongolian coal-bearing basins. This is based on a synthesis of the data from nearly 50 coal deposits. The results of ultimate and proximate analyses, and calorific value, maceral composition and vitrinite reflectance data is given.The coal deposits of Mongolia tend to become younger from west to east and can be subdivided into two provinces, twelve basins, and three areas. Main controlling factor of coal rank is the age of the coal bearing sequences. Western Mongolian coal-bearing province contains mostly high rank bituminous coal in strata from Late Carboniferous. The basins in southern Mongolia and the western part of central Mongolia have low rank bituminous coal in strata from the Permian. The northern and central Mongolian basins contain mainly Jurassic subbituminous coal, whereas the Eastern Mongolian province has Lower Cretaceous lignite. The Carboniferous, Permian and Jurassic coal-bearing sequences were mainly deposited in foreland basins by compressional tectonic event, whereas Cretaceous coal measures were deposited in rift valleys caused by extensional tectonic event. Petrographically, Mongolian coals are classified as humic type. Vitrinite/huminite groups of Carboniferous, Permian, and Cretaceous coal range from 44.9% to 82.9%. Inertinite group varies between 15.0% and 53.3%, but liptinite group does not exceed more than 7%. Jurassic coals are characterized by high percentages of vitrinite (87.3% to 96.6%) and liptinite groups (up to 11.7%). This might be explained by paleoclimatic conditions. Mongolian coal reserves have been estimated to be 10.2 billion tons, of which a predominant portion is lignite in the Eastern Mongolian province and coking coal in the South Gobi basin. 相似文献
8.
9.
The coal deposits of southern Africa (Botswana, Malawi, Mozambique, Namibia, South Africa, Swaziland, Tanzania, Zambia and Zimbabwe) are reviewed. The coal seams formed during two periods, the Early Permian (Artinskian–Kungurian) and the Late Permian (Ufimian–Kazanian). The coals are associated with non-marine terrestrial clastic sedimentary sequences, most commonly mudrock and sandstones, assigned to the Karoo Supergroup. The Early Permian coals are most commonly sandstone-hosted while the younger coals typically occur interbedded with mudstones. The sediments were deposited in varying tectono-sedimentary basins such as foreland, intracratonic rifts and intercratonic grabens and half-grabens. The depositional environments that produced the coal-bearing successions were primarily deltaic and fluvial, with some minor shoreline and lacustrine settings. Coals vary in rank from high-volatile bituminous to anthracite and characteristically have a relatively high inertinite component, and medium- to high-ash content. In countries where coal is mined, it is used for power generation, coking coal, synfuel generation, gasification and for (local) domestic household consumption. 相似文献
10.
Peter J. Crosdale Anatoly P. Sorokin Ken J. Woolfe David I. M. Macdonald 《International Journal of Coal Geology》2002,51(4)
Selected Tertiary coals from the Zeya–Buryea Basin, Far Eastern Russia, were investigated for aspects of their coal type, rank, depositional environment and post-depositional history. The coals have been examined in outcrop (lithotype logging), microscopically (maceral, reflectance and fluorescence), and geochemically (proximate analysis).Two laterally extensive coal-bearing horizons occur: one of Palaeocene age and the other of early Miocene age. The Palaeocene coals were investigated in active open-cut mines at Raichikhinsk and Yerkovtsi and the early Miocene deposit in an abandoned open-cut mine at Cergeyevka.Palaeocene coals at Raichikhinsk and Yerkovtsi were indistinguishable from each other macroscopically, microscopically, and geochemically. The deposits were sufficiently coalified that brightness logging could be undertaken. Dull coals, with numerous fusainous wisps, were dominant. Four dulling-up sequences, which represent stacked peat deposits, were observed at Raichikhinsk. At Yerkovtsi, only a small section of the middle of the seam, which was mostly dull and muddy coal, was investigated. Petrographically, these coals were dominated by inertinite group macerals, which is unusual in non-Gondwanan coals and rare in the Tertiary. Rank classification was problematic with volatile matter (VM) content of vitrain (daf), macroscopic appearance, and microscopic textures suggesting subbituminous B rank, but carbon content, moisture content and specific energy indicating a lignite rank.Notwithstanding complications of rank, estimates of the maximum-range burial depths were calculated. Taking the VM (daf) content of vitrain as 48%, burial depth estimates range from 900 m for a high geothermal gradient and long heating time to a maximum of 3300 m for a low geothermal gradient and short heating time. These estimates are maxima as the coal rank may be lower than implied by the VM.The Cergeyevka deposit is a soft brown coal. Limited sampling of the upper-most portion indicated a high moisture content (75% daf) and an unusual, hydrogen-rich geochemistry. Lack of identifiable liptinites using either reflected light or fluorescence microscopy suggested a significant bituminite component. Otherwise, the coals appear to be typical for the Tertiary. An estimate of 125 m maximum burial depth was obtained using the bed-moisture content of the coal, which is around the present burial depth.Comparison of present-day thicknesses with inferred burial depths suggests that at least 500 m of section is missing between the Palaeocene coals and the early Miocene coals.Palaeoenvironmental considerations suggest that fire played a significant role in the accumulation of the peats at Raichikhinsk and Yerkovtsi. At Cergeyevka, peat accumulation ended by drowning of the mire.Two tuff beds were recognised within the seam at Raichikhinsk and one in the seam at Yerkovtsi. Correlation of the tuff beds is uncertain but they should prove useful in regional coal seam correlation and interpreting coal depositional environments. Geochemical analysis by XRF was complicated by high loss-on-ignition (LOI) values. Despite extensive alteration, an acid igneous source is implied from the presence of free quartz and TiO2/Al2O3 ratios of 0.02 to 0.05. 相似文献
11.
Greta M. Eskenazy 《International Journal of Coal Geology》1982,2(2):99-111
This paper discusses the tungsten geochemistry in coal, based on the behavior of this element in 14 Bulgarian deposits. The W contents range from 0.5–4335 ppm in the ash and from 0.01–784 ppm in the coals. In four of the deposits the tungsten content proved to be 16 to 100 times higher than the Clarke value for sedimentary rocks. No correlation has been found between the W concentration and either the age of the coal-bearing strata or the coal rank. The deposits were divided in three groups on the basis of the relationship between tungsten and ash content. The role of sorption ash and terrigenous ash in tungsten binding was evaluated for each group. The correlation between tungsten and organic matter is demonstrated by the increased contents of tungsten in the ash of the low-ash coals, its concentration in the lighter coal fractions, its extraction from the coals by HF and NaOH only, and by model experiments. Sorption ash concentrates tungsten; terrigenous ash is a carrier of tungsten.Of the petrographic constituents of coal, vitrain was found to concentrate the largest amounts of tungsten.In two of the deposits richest in tungsten, there is a very distinct zonality in its vertical distribution — tungsten concentration decreases from the bottom to the top of the coal bed. This zonality might be explained by the diffusion (syngenetic or diagenetic with respect to the coal-forming process) through the coal bed of aqueous solutions enriched in tungsten.The wide range of variation of the tungsten concentrations, the considerable differences in the mean contents and the dispersions between the individual deposits show that tungsten is very sensitive to the differences of the source area.Coal deposits enriched in tungsten may be expected in the following favourable environments: (1) in areas with nitrogen-bearing thermal waters containing increased amounts of tungsten; (2) source areas with tungsten mineralizations; and (3) country rocks consisting of acid granitoids whose Clarke values of tungsten are the highest as compared to the other types of rocks. 相似文献
12.
13.
KS盆地磅士卑勘查区是位于柬埔寨西南部磅士卑省豆蔻山脉东麓。该盆地构造简单,断层较少,地层总体走向为一走向NNE倾向NWW的单斜构造,地层倾角平缓。勘查区煤炭资源较丰富,含煤地层为新近系中新统,聚煤期湖沼相沉积体系。主要可采煤层为S10、S20煤层,属中灰煤至高灰煤、低硫煤至中硫煤、低发热量煤至中发热量煤。 相似文献
14.
焉耆盆地侏罗纪煤系源岩显微组分组合与生油潜力 总被引：3，自引：1，他引：2
焉耆盆地为我国西部含煤、含油气盆地, 侏罗系含煤地层是最重要的潜在源岩.对侏罗纪煤系中的暗色泥岩、碳质泥岩和煤层分别进行了有机岩石学、Rock-Eval热解分析和核磁共振分析.泥岩、碳质泥岩和煤层具有不同的有机岩石学和有机地球化学特征, 其中煤层具有3种有机显微组分组合类型, 不同显微组分组合类型的煤层具有不同的生油、生气潜力或倾油、倾气性.基质镜质体、角质体、孢子体等显微组分是煤中的主要生烃组分.侏罗系泥岩、碳质泥岩和煤层具有不同的生物标志物分布特征, 生物标志物组合分析表明焉耆盆地已发现原油是泥岩、碳质泥岩和煤层生成原油的混合产物.含煤地层的地球化学生烃潜力分析和已发现原油的油源对比均表明, 含煤地层不仅是重要的气源岩, 而且可成为有效的油源岩. 相似文献
15.
我国含铀煤矿床的某些地球化学特征 总被引：1，自引：0，他引：1
我国含铀煤矿床主要产于中-新生代陆相沉积盆地中。盆地基底为华力西至燕山期花岗岩(黑云母花岗岩、二云母花岗岩等),或酸性火山岩(火山碎屑岩),或二者均有,其含铀丰度大于8ppm,高于酸性岩克拉克值的3-10倍。基底含铀丰度高为成矿提供了丰富的铀源。铀矿区内的地下水一般为弱酸至弱碱性,重碳酸钾-钠型,硫酸、重碳酸钙(钾)一钠型等，pH值6 -7.5，含铀丰度为n.10-7n.10-6克/升，干旱地区为n。10-6-n.10-5克/升。矿体一般为层状，似层状及透镜状与煤层整合产出。 相似文献
16.
Two coal-bearing units from the Lower Carboniferous succession in Central Spitsbergen, Svalbard, have been investigated using coal petrographic and geochemical techniques. The upper member consists mainly of algal cannels, dominated by Botryococcus-type algae. The coals from the lower member are a mixture of durite-type coals with sporinite and inertinite and coals containing prdominantly vitrinite. The Rock-Eval and pyrolysis-GC also show a clear distinction in the composition of the organic matter in the two coal-bearing units investigated. These results, together with detailed sedimentological analyses, are used to reconstruct the depositional environments for the two coal-bearing sequences. 相似文献
17.
V. V. Seredin Yu. A. Danilcheva L. O. Magazina I. G. Sharova 《Lithology and Mineral Resources》2006,41(3):280-301
Results of the study of a new Ge-bearing area of the Pavlovka brown coal deposit are presented. Ge is accumulated in bed III2 lying at the bottom of the Late Paleogene-Early Neogene coal-bearing sequence adjacent to the Middle Paleozoic granite basement. The Ge content in coals and coal-bearing rocks varies in different sections from 10 to 200–250 ppm, reaching up to 500–600 ppm in the highest-grade lower part of the bed. The metalliferous area reveals a geochemical zoning: complex Ge-Mo-W anomalies subsequently grades along the depth and strike into Mo-W and W anomalies. Orebodies, like those at many Ge-bearing coal deposits, are concentric in plan and dome-shaped in cross-section. Coals in their central parts, in addition to Ge, W, and Mo, are enriched in U, As, Be, Ag, and Au. Distribution of Ge and other trace elements in the metalliferous sequence and products of gravity separation of Ge-bearing coals is studied. These data indicate that most elements (W, Mo, U, As, Be) concentrated like Ge in the Ge-bearing bed relative to background values are restricted to the organic matter of coals. The electron microscopic study shows that Ge-bearing coals contain native metals and intermetallic compounds in association with carbonates, sulfides, and halogenides. Coal inclusions in the metalliferous and barren areas of the molasse section strongly differ in contents of Ge and associated trace elements. Ge was accumulated in the coals in the course of the interaction of ascending metalliferous solutions with organic matter of the buried peat bogs in Late Miocene. The solutions were presumably represented by N2-bearing thermal waters (contaminated by volcanogenic CO2) that are typical of granite terranes. 相似文献
18.
恩洪矿区是云南省重要产煤基地，晚古生界的上二叠统宣威组是主要含煤岩系，其煤层镜质组含量较高，变质程度中等，蕴藏着丰富的煤层气资源。综合研究表明：该区煤层气富集的控制因素主要为煤层厚度、煤岩组分、煤级、吸附性能和良好的保存条件。 相似文献
19.
《Applied Geochemistry》2001,16(11-12):1353-1360
Southwest Guizhou Province is one of the most important areas of disseminated, sediment-hosted-type Au deposits in China and is an important area of coal production. The chemistry of most of the coals in SW Guizhou is similar to those in other parts of China. Their As content is near the Chinese coal average, but some local, small coal mines contain high As coals. The highest As content is up to 3.5 wt.% in the coal. The use of high As coals has caused in excess of 3000 cases of As poisoning in several villages. The high As coals are in the Longtan formation, which is an alternating marine facies and terrestrial facies. The coals are distributed on both sides of faults that parallel the regional anticlinal axis. The As content of coal is higher closer to the fault plane. The As content of coal changes greatly in different coal beds and different locations of the same bed. Geological structures such as anticlines, faults and sedimentary strata control the distribution of high As coals. Small Au deposits as well as Sb, Hg, and Th mineralization, are found near the high As coals. Although some As-bearing minerals such as pyrite, arsenopyrite, realgar (?), As-bearing sulfate, As-bearing clays, and phosphate are found in the high As coals, their contents cannot account for the abundance of As in some coals. Analysis of the coal indicates that As mainly exists in the form of As5+ and As3+, perhaps, combined with organic compounds. The occurrence of such exceptionally high As contents in coal and the fact that the As is dominantly organically associated are unique observations. 相似文献
20.
Canada's coal resources occur in 16 sedimentary basins or groups of basins and range in age from Devonian to Tertiary. The Western Canada Sedimentary Basin (WCSB), which contains the vast majority (about 90%) of the nation's coal resources of immediate interest, underlies a large area in the provinces of British Columbia, Alberta, Saskatchewan and Manitoba, extending northward to about the 62nd Parallel in Yukon and Northwest Territories. Coal deposits in the WCSB range in age from Early Carboniferous (Mississippian) to Paleocene. Rank ranges from lignite to semianthracite. About 36% of the total estimated 71,000 megatonnes of resources of immediate interest in the WCSB is bituminous coal, including a high proportion in the medium to low volatile range. Their low sulphur contents and acceptable ash levels make these medium and low volatile bituminous coals attractive 3s coking feedstocks and large quantities are mined for that purpose. The lower rank western Canadian coals are used mainly for electricity generation.Significant resources of bituminous coal occur in the coalfields of Atlantic Canada where they have been mined since 1720. Most of these coals are classed as high volatile A bituminous and most are used for power generation. Large resources of coal (lignite to anthracite) also occur in more remote regions of Canada, such as the Bowser Basin in northwestern British Columbia, and Sverdrup Basin/ Franklinian Geosyncline in the Arctic Islands. Information on distribution and compositional attributes of these frontier region coals is commonly scarce. 相似文献