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1.
系统分析了滇西早第三纪晚期煌斑岩的主元素、微量元素和Sr-Nd同位素组成。绝大多数煌斑岩属超钾质系列岩石(K2O/Na2O=2.1-5.2),少数为钾玄质系列(K2O/Na2O=1.6-1.7)。这些超钾质煌斑岩富集大离子亲石元素、轻稀土元素和Pb,亏损高场强元素,具有高的初始^87Sr/^86Sr比值(O.70624-0.70924)和负的εNd(t)值(-1.7~-4.6),类似于与俯冲环境有关的高K/Ti-低Ti钾质系列岩石。这些超钾质煌斑岩母岩浆来源于含金云母的交代地幔,经历了不同程度的结晶分异和地壳物质的同化混染。与藏北钾玄质系列岩石相比,滇西超钾质煌斑岩的Th/U比较低、Rb/Sr比较高,而且Nd模式年龄系统偏低0.1-0.4Ga,表明青藏高原北部和东南部岩石圈地幔组成存在区域性的差异。  相似文献   

2.
姚安干沟金矿是三江铜金多金属成矿带上的一个重要矿床,处于金沙江-哀牢山-红河富碱斑岩带中段,大地构造隶属于扬子板块西缘内部。通过对干沟金矿深部煌斑岩开展锆石LA-ICP-MS U-Pb定年及Hf同位素分析,结果表明煌斑岩成岩时代为(31.12±0.88)Ma,样品锆石176Hf/177Hf值为0.282 217~0.282 476,对应的εHf(t)值范围变化在-7.70到-18.94之间。通过与区域同期岩体同位素综合对比分析,认为姚安干沟金矿床深部煌斑岩起源于交代富集岩石圈地幔的部分熔融与加厚下地壳部分熔融的混合岩浆,干沟煌斑岩以及区域上北衙、马厂箐等晚期煌斑岩均是对印度-欧亚大陆后碰撞时期岩石圈地幔发生拆沉的响应,产在应力场环境由压扭挤压向张扭伸展逐渐过渡的动力学背景下,为杂岩体晚期岩浆活动的产物。  相似文献   

3.
对桂北罗城垒洞煌斑岩进行了锆石LA-ICP-MS U-Pb定年,获得的岩浆侵位年龄为约100Ma。其高钾(K2O/Na2O=15.7~24.0),富碱[w(K2O+Na2O)=6.18%~8.25%],富集大离子亲石元素和轻稀土元素,亏损高场强元素、Sr及重稀土元素,高(87Sr/86Sr)i(0.718 832~0.719 730),低εNd(t)(-9.15~-8.97),富集放射性Pb的特征,显示源区可能为早期俯冲交代作用形成的EMⅡ型富集地幔,该富集地幔形成于新元古代扬子和华夏地块的俯冲作用。煌斑岩岩浆的形成与华南陆块在白垩纪(100Ma)伸展拉张的背景下软流圈上涌促使这些富集地幔部分熔融有关。区域上NNE向的深大断裂为岩浆侵位提供了良好的通道。  相似文献   

4.
黑龙江三矿沟Fe-Cu矿床是中亚造山带东段大兴安岭北部裸河-多宝山-三矿沟NW向成矿带中矽卡岩型矿床的典型代表。LA-ICP-MS锆石U-Pb年代学表明,与成矿密切相关的黑云母花岗闪长岩的锆石谐和年龄和238U/206Pb加权平均年岭分别为175.9±1.6Ma和175.9±1.1Ma,二者在误差范围内具有良好的一致性,表明多宝山成矿区在早侏罗世晚期存在一期重要的岩浆-热液成矿事件。三矿沟花岗闪长岩的元素地球化学特征具有岛弧岩浆岩的地球化学亲缘性:岩石富钠(Na2O/K2O=1.39~1.59),准铝质(A/CNK=0.87~0.91),富集轻稀土元素(LREE),(La/Yb)N=8.02~10.45,Eu显示弱负异常(δEu=0.82~0.98),富集大离子亲石元素(LILE,如Rb、Ba、K)和元素地球化学性质活泼的不相容元素(U、Th、Pb),相对亏损高场强元素(HFSE,如Nb、Ta、Zr、Hf、Ti)。Sr-Nd-Pb同位素分析结果表明:三矿沟花岗闪长岩具有低的Sr同位素初始比值((87Sr/86Sr)i=0.7041~0.7045)、高的Nd同位素初始比值((143Nd/144Nd)i=0.512556~0.512576)、正的εNd(t)值(2.8~3.9)、年轻的二阶段亏损地幔模式年龄(tDM2=647~733Ma)和幔源铅同位素组成特征((206Pb/204Pb)t=18.121~18.418;(207Pb/204Pb)t=15.480~15.511;(208Pb/204Pb)t=37.628~37.713),上述同位素地球化学特征均显示花岗闪长质岩浆主要源于亏损地幔源区。结合东北地区区域构造演化和岩体微量元素及同位素组成特征反映该矿床形成于岛弧的构造背景,其形成可能与侏罗纪古太平洋板块的俯冲作用密切相关。  相似文献   

5.
延边小西南岔金铜矿区早白垩世英云闪长岩的岩石成因   总被引:3,自引:0,他引:3  
李红霞  郭锋  李超文  赵亮 《地球化学》2012,41(6):497-514
锆石U-Pb测年结果表明小西南岔富金铜矿床矿区内的英云闪长岩形成于(112±1)Ma。该英云闪长岩富Na2O和Al2O3,高Sr、LREE(轻稀土元素),低Y、Yb和HREE(重稀土元素)(如Sr=369~774μg/g,(La/Yb)CN=7.5~17.5),具有类似于埃达克质岩石的元素地球化学特征。在同位素组成上具中等放射成因Sr((87Sr/86Sr)i=0.7044~0.7048)、Nd(εNd(t)=+0.5~+1.7)和Hf(εHf(t)=+5.4~+8.6,ΔεHf=2.3~4.2)同位素,高放射成因Pb((206Pb/204Pb)i=18.40~18.60;(207Pb/204Pb)i=15.56~18.60;(208Pb/204Pb)i=38.22~38.36)同位素的特点。结合区域构造背景以及古太平洋板块俯冲历史,笔者倾向认为该岩体可能是玄武质岩浆底侵下地壳部分熔融形成的,而非板片熔融形成的埃达克质岩浆,岩浆源区为石榴子石角闪岩相向角闪岩相过渡的岩石。该岩体侵位的晚古生代((257±3)Ma)镁铁质围岩的角闪石Ar-Ar坪年龄为(110.1±1.5)Ma,与英云闪长岩的侵位时间一致,暗示晚古生代镁铁质侵入岩经历的热液事件与英云闪长岩的侵位作用存在成因联系,区域金铜矿化可能为早白垩世岩浆热液作用下成矿物质富集而形成。  相似文献   

6.
蒙西斑岩铜钼矿含矿斑岩体主要为斜长花岗斑岩。通过对含矿斑岩体地球化学和Sr-Nd-Pb同位素特征的研究,确立斑岩体为过铝质钙碱性系列岩石,富集Rb,Ba,U,K,Pb,Sr等大离子亲石元素,亏损Th,Ta,Nb,Nd,Ti等高场强元素;具低的(87Sr/86Sr)ⅰ值(0.704 65~0.705 37)和相对较高的εNd(t)值(-2.2~6.6),且有较低的初始铅同位素比值(206Pb/204Pb)i=17.13~17.33,(207Pb/204Pb)i=15.47~15.54,(208Pb/204Pb)i=37.11~37.33。上述特征表明其形成于岛弧环境,岩浆物质来源以幔源为主,但也有少量壳源组分参与,岩浆的形成可能与洋壳的俯冲作用有关。东准噶尔琼河坝地区是形成和寻找斑岩型铜矿的有利地区。  相似文献   

7.
天山北部沙湾地区火山岩由火山碎屑岩和火山熔岩组成,主要包括安山质(岩屑)晶屑凝灰岩、英安质熔结凝灰岩、玄武安山岩和流纹岩,为钙碱性系列。玄武安山岩和流纹岩主量元素平均含量分别为:SiO2=51.03%、77.33%,TiO2=0.76%、0.16%,CaO=10.30%、0.43%,MgO=5.19%、0.89%,Na2O=2.10%、1.27%,K2O=1.28%、2.54%;稀土元素特征分别为:∑REE=369.1×10-6、729.0×10-6,(La/Yb)N=5.0、3.5,(La/Sm)N=2.7、2.4,δEu=0.82、0.54;Sr、Nd、Pb同位素特征分别为:(87Sr/86Sr)t=0.70680和0.70476,(143Nd/144Nd)t=0.52224和0.51225,εNd(t)=0.2和0.1,(206Pb/204Pb)t=17.775和17.720,(207Pb/204Pb)t=15.790和15.826,(208Pb/204Pb)t=38.240和38.876。火山熔岩亏损Nb、Ta、Ti和P,富集K、Rb、U、Th、Zr和Hf,玄武安山岩的Zr为117×10-6~121×...  相似文献   

8.
谢米斯台中段地区发育的火山岩主要为安山岩、英安岩和流纹岩。岩石地球化学研究表明,岩石的K2O、Na2O含量高(K2O=3.42%~9.85%;Na2O=0.48%~5.30%),大离子亲石元素(LILE)相对富集,高场强元素(HFSE)相对亏损,其中Nb、P、Ti强烈亏损,轻稀土元素(LREE)和重稀土元素(HREE)分馏较强;Pb同位素比值为206Pb/204Pb=18.435~19.409、207Pb/204Pb=15.535~15.602、208Pb/204Pb=38.36~39.213;火山岩具有高的初始εNd(t)值(+4.43~+6.65)和低的初始87Sr/86Sr值(0.700953~0.704435)。该地区流纹岩SIMS锆石U-Pb测年结果为422.5±1.9Ma。综合研究认为,谢米斯台中段地区火山岩是晚志留世准噶尔洋壳俯冲,在地幔楔形区,经过洋壳与富集地幔的局部熔融,经历了一定程度的分离结晶作用形成的中酸性岩浆喷发而成,在岩浆上升过程中有少量地壳物质的混染。  相似文献   

9.
本文对新县花岗岩岩基进行了系统的锆石U-Pb定年,全岩元素地球化学、Sr-Nd-Pb-Hf同位素测试,研究探讨其成岩年龄、岩石成因、物质来源以及地球化学动力学背景。锆石U-Pb年龄为125.5±1.5Ma,属于早白垩世产物。全岩元素地球化学成分表现为高硅、富碱,贫镁、铁和钙,富集轻稀土元素、大离子亲石元素(Rb、K、Th、U)和Pb,亏损重稀土元素、高场强元素(Nb、Ta、Ti)和Sr、Ba。全岩同位素具有中等略偏高的Sr 初始比值(87Sr/86Sr)i=0.706949~0.707086;低的放射性Pb同位素组成[ (206Pb/204Pb)i=16.611~17.152,(207Pb/204Pb)i=15.304~15.432,(208Pb/204Pb)i=37.316~37.702]; 低的Nd初始比值(εNd(t)=-13.65~-13.51)和老的Nd模式年龄(TDM2=2.12~2.13Ga)。锆石原位Hf同位素具有较低的初始比值(εHf(t)=-22.92~-19.40)和老的Hf二阶段模式年龄(TDM2=2.39~2.61 Ga)。综合以上元素地球化学特征、锆石U-Pb定年结果及Sr-Nd-Pb-Hf同位素组成,新县花岗岩岩基应属于分异的高钾钙碱性I型花岗岩,是化学成分类似于扬子板块北缘新元古代TTG型岩浆岩的扬子下地壳在非加厚下地壳(深度小于35km)环境下部分熔融的产物。  相似文献   

10.
莒县早白垩世火山岩沿郯庐断裂带分布,由粗安岩、粗面岩和流纹岩组成,属高钾钙碱性-钾玄岩系列.岩石富集Rb、K、Ba等大离子亲石元素和轻稀土元素,相对亏损Nb、Ta、Ti等高场强元素和重稀土元素,Sr-Nd同位素组成((87Sr/86Sr)t=0.7082~0.7095,ENd(t)=-16.4~-19.8)与区内基性岩的相类似,而Pb同位素组成((206pb/204Pb)t=16.523~17.038,(207pb/204Pb)t=15.414~15.468,(208pb/204Pb)t=37.058~37.427)类似于EM1型富集地幔.(87Sr/86Sr)t和εNd(t)与SiO2没有明显的相关性,且较高的Th/U、Ce/Pb值和较低的Nb/La、Nb/U值均暗示岩浆在上升过程中未遭受明显的地壳混染.粗安岩具有高的Cr、Ni、MgO含量及Mg#值和古老Nd同位素模式年龄,暗示其起源于富集的岩石圈地幔.粗面岩与粗安岩的主要氧化物、微量元素与SiO2呈明显的相关性,这暗示可能为同源岩浆结晶分异而来.研究表明,莒县地区中酸性火山岩形成于岩石圈伸展减薄背景下,由曾遭受俯冲扬子陆壳熔体改造的华北岩石圈地幔部分熔融形成的岩浆分离结晶作用而成.郯庐断裂带的伸展活动控制着火山岩的分布,为岩浆的形成和运移提供了有利的场所,在华北克拉通破坏中可能起到了重要的作用.  相似文献   

11.
机械工业第六设计研究院原隶属于机械工业部,为事业单位,2000年10月转制后隶属于中国机械装备(集团)公司,为企业单位。该院现有在职员工459人,外聘人员300人,离退休人员356人,其中,中国工程院院士1人,中国工程设计大师2人,教授级高级工程师50人,高级工程师近260人,工程师300多人。该院是工业和民用建筑设计双甲级单位,并具有甲级工程总承包和工程监理资质。建院五十多年来,该院先后完成了5000余项大中型工业和民用建筑项目的设计和咨询,为我国国民经济建设和发展做出了卓越贡献。  相似文献   

12.
Summary Baotite occurs in the Garaoulére orebody, at Pierreftte, France, as an accessory mineral, included in alstonite and celsian, and associated with sphalerite, galena, pyrite, siderite and calcite in hydrothermal veins crosscutting calcareous, rutile-bearing, siltstones. Microprobe analyses revealed high W03 concentrations (up to 6 wt.%) in baotite. The empirical formula of W-rich baotite is Ba3.959Ti4(Ti3.169W0.393Fe0.116Al0.073 Cr0.048Nb0.024)3.823 Si4.05O28Cl1.166. The excess of charges due to the presence of W6+ and Nb5+ is compensated by the introduction of M3+ (Fe, Al, Cr) into Ti-octahedra, by the appearance of Al in Si-tetrahedra (for W-poor baotite) and by the appearance of vacancies in Ti-octahedra (3Ti4 -> 2W6+ + and in Ba-sites (Ti4+ Ba2+ W6+, ). The unit-cell parameters of W-rich baotite are: a = 19.92(2), c = 5.930(8) Å. Niobium-rich baotites (Baiyun-Obo,Semenov et al., 1961; Karlstein,Nmec, 1987) are characterized by substitutions: Ti4+(VI), Si4+(IV)Nb5+(VI), Al3+(IV) and 2Ti4+, Ba2+ 2Nb5+, .
Wolfram führender Baotit von Pierrefitte, Pyrenäen, Frankreich
Zusammenfassung Baotit kommt in dem Garaoulére Erzkórper in Pierrefitte, Frankreich als ein akzessorisches Mineral in Einschlÿussen in Alstonit und Celsian vor. Er ist mit Zinkblende, Bleiglanz, Pyrit, Siderit und Calcit assoziiert. Diese Paragenese ist an hydrothermale Gänge gebunden, die kalkige rutil-führende Siltsteine durchsetzen. Mikrosondenanalysen zeigen hohe W03 Gehalte (bis zu 6 Gew.%) in Baotit. Die empirische Formel von wolfram-reichem Baotit ist: Ba3.959Ti4(Ti3.169W0.393Fe0.116Al0.073Cr0.048Nb0.024)3.823 Si4.05O28Cl1.66. Der durch die Anwesenheit von W6+ und Nb5+ erforderliche Ladungsausgleich ergibt sich durch das Eintreten von M3+ (Fe, Al; Cr) in Ti-Oktaeder, und von Al in Si-Tetraeder (für W-armen Baotit) und schließlich durch das Erscheinen von Leerstellen in Ti-Oktaedern (3Ti4+ 2W6+ + und in Ba-Stellen (Ti4+, Ba` W6+, Die Zellparameter von ldW-reichem Baotit sind: a = 19.92(2), c = 5.930(8) Å. Niob-reiche Baotite (Baiyun-Obo, Semenov et al., 1961; Karlstein, Nmec, 1987) sind durch Substitutionen charakterisiert: Ti4+(VI), Si4+(IV)Nb5+(VI), Al3+(IV) und 2Ti4+, Ba2+ 2Nb5+, .
  相似文献   

13.
氯氧镁铝石(Koenenite)是一种少见矿物,最初发现于德国Gttingen。后来,F.里勒(F.Rinne)、R.库恩(R.Kühn)、H.-H.洛斯(H.-H.Lohse)、R.奥勒曼)R.Allmann)等人先后都作过报导,而在我国还是首次发现。氯氧镁铝石结构比较特殊,性质上是一个多变的矿物。  相似文献   

14.
CAAD(Computer Aided Architectural Design)在建筑设计专业工作中的应用技术称为计算机辅助建筑设计技术,它从上世纪60年代兴起80年代走红90年代席卷了整个建筑市场,并迅速成熟。设计师无疑已经离不开它们,代表作品有广为人知的AutoCAD、3DMAX,然而建筑师在享用它们的同时却不停的感慨它们的局限性:“它们把建筑设计引向机械的、单调的缺乏个性的死胡同……”,“建筑设计本身是一种模糊性设计,前期并不需要严格的定性定量,而且,美学问题是无法用定量的方法来描述的……”,它的呆板复杂与建筑师的灵性脱缰的思维无法合谐的同行,两者徘徊于等待与被等待之间隔岸对视。  相似文献   

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Leucitities of probable late Pleistocene age from the extinct volcano of Gaussberg on the coast of East Antarctica consist of microphenocrysts of olivine, diopside, and leucite in a largely glassy groundmass. Their extreme K contents and K/Na ratios, as well as high Rb, Ba, and possibly Ti, are compatible with an origin by small degrees of partial melting of phlogopite-rich mantle below the level of amphibole stability, whereas their enrichment in P, Sr, Zr, Nb, La, Ce, Pb, and Th indicates the presence of minor phases such as apatite in the source material. Although the Mg/(Mg+Fe) values (0.70) and relatively high Ni and Cr contents suggest that the Gaussberg lavas represent near-primary melts, some degree of fractionation involving an aluminous phase (probably garnet) may be necessary to produce liquids with atomic K>Al. Alternatively, an as yet poorly understood process such as wall-rock reaction, liquid immiscibility, or mantle metasomatism may have been a critical factor in the genesis of these unusual rocks.Gaussberg is situated on a passive continental margin and does not appear to be related to any other known area of Cainozoic volcanic activity.  相似文献   

18.
Mollusks were studied from six sites in Lake Algonquin deposits (12,000-10,000 yr B.P.), five transitional (Lake Stanley low stage; 10,000 – 6000 yr B.P.), and six Nipissing stage sites (6000-4000 yr B.P.) east of Lake Huron in southwestern Ontario. The sites represent a variety of near-shore, lagoonal, estuarine, and fluvial environments. Eighteen species were limited to occurrences in Algonquin stage deposits; 8 were found only in the transitional age sites; and 14 species were restricted to Nipissing stage localities. With the possible exception of Goniobasis livescens, which occurred at five of the six Nipissing stage sites, the remaining stratigraphically limited species were usually restricted to one or two localities and probably cannot be used as zone fossils. Some cold-tolerant species (e.g., Anodonta grandis simpsoniana) were very early migrants into the study area, while others arrived later, apparently from eastern, southern, and western sources. Mollusks proved useful in paleoenvironmental reconstructions and to a lesser extent in biostratigraphic zonation.  相似文献   

19.
During the past 8000 years, large volcanic debris flows from Mount Meager, a Quaternary volcano in southwest British Columbia, have reached several tens of kilometres downstream in Lillooet River valley, with flow velocities of many metres per second and flow depths of several metres. These debris flows inundated areas that have become settled in the past 100 years and are now experiencing rapid urban growth. Notably, Pemberton, 65 km from Mount Meager, has doubled in size in the past five years. Approval of subdivision and building permits in Pemberton and adjacent areas requires assessment and mitigation of flood hazards, but large, rare debris flows from Mount Meager are not considered in the permitting process. Unlike floods, some volcanic debris flows occur without warning. We quantify the risk to residents in Lillooet River valley from non-eruption triggered volcanic debris flows based on Holocene landslide activity at Mount Meager. The calculated risk exceeds, by orders of magnitude, risk tolerance thresholds developed in Hong Kong, Australia, England, and in one jurisdiction in Canada. This finding poses a challenge for local governments responsible for public safety.  相似文献   

20.
Metamorphism of the Gile Mountain Formation and Waits River Formation in the Strafford Dome and Townshend-Brownington Syncline in east-central Vermont records two nappe-style events, D1 and D2, followed by doming. D1 formed a muscovite + biotite ± ilmenite schistosity subparallel to compositional layering, SO, and was followed by heating to garnet grade. The temperature and pressure at the end of D1 are estimated to be c . 450 C and 6-8 kbar. D2 variably crenulated and folded S1 during a nearly isothermal pressure increase of 1-2 kbar, calculated from compositions of garnet, which have inclusions trails with progressive crenulation and rotation of the S1 fabric. Similar P-T paths are computed for most of the area, suggesting that the later schistosity developed during emplacement of a regional nappe 3-6 km thick. There is a general lack of D3 (dome-stage) microstructures.
Near the Strafford-Willoughby Arch, staurolite and kyanite overgrew S2 in pelites, and plagioclase with increasing X An overgrew S2 in calcic pelites, reflecting post-D2 heating to a maximum of 550-600 C. Metamorphic pressures at the end of D2 are fairly constant on the west side of the dome, indicating minor dome-stage uplift. In contrast, pressures at the thermal peak of metamorphism decrease by more than 4 kbar east of the dome. The observed pattern of isotherms and isobars is mainly the result of post-metamorphic, differential uplift and unroofing.
Finally, a minor, retrograde metamorphism produced the assemblage albite + epidote + K-feldspar + muscovite + chlorite, with grade increasing east toward the Connecticut River.  相似文献   

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