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1.
A totally objective procedure involving sixteen statistical tests (a total of thirty four single or multiple outlier versions of these tests) for outlier detection and rejection in a univariate sample is applied to a data base of sixty four elements in a recently issued international geochemical reference material (RM), a microgabbro PM-S from Scotland. This example illustrates the relative importance and usefulness of these tests in processing modern geochemical data for possible outliers and obtaining mean concentration and other statistical parameters from a final normal sample of univariate data. The final mean values are more reliable (characterized by smaller standard deviations and narrower confidence limits) than those obtained earlier using an accommodation approach (robust techniques) applied to this data base. Very high quality (certified value equivalent, cve) mean data are now obtained for eleven elements as well as high quality recommended values (rv) for thirty three elements in PM-S. Earlier work using the accommodation approach failed to establish even one cve value for any of the sixty four elements compiled here. The present procedure of outlier detection and elimination is therefore recommended in the study of RMs  相似文献   

2.
All data reported by 200 analysts (106 laboratories) are presented for the four ANRT samples: Diorite DR-N, Serpentine UB-N, Bauxite BX-N and Disthène DT-N. Recommended values are given for the major and minor elements. As far as the as trace elements are concerned, DR-N has been characterized for 35 elements whereas the other three samples have been for only 20 elements. Wherever possible, brief comments have been inserted so as to explain our way of assigning recommended or proposed values.
After more than a decade of existence the total number of data reported for all the four samples reach only 3200 units which are not sufficient enough for a valid evaluation of compiled data. It is also pointed out that these samples are most likely to be available even during the next century as they have been prepared in large quantities of the order of one ton. A plea is therefore made for contribution of more data particularly for trace elements and for major elements which are present as trace elements in UB-N, BX-N and DT-N.  相似文献   

3.
Analytical data for minor and trace elements published or communicated to us, on seventeen GSJ (Geological Survey of Japan) reference samples, "Igneous rock series" received up to April 1994 are compiled. The data were evaluated statistically in consideration of analytical methods. Based on the selected available data, 1994 recommended and proposed values for 65 minor and trace elements are presented.  相似文献   

4.
Third in the series of collaborative studies launched by the International Working Group "Analytical Standards of Minerals, Ores and Rocks" (IWG), the study on Ailsa Craig Granite AC-E has attracted the participation of 128 laboratories from 29 countries. Tables of compiled data, 3212 results in all, are presented with working values, recommended or proposed, for seventy major, minor and trace elements. The success of this study which lasted for only one year from the distribution of sample to the release of the present report is to be attributed entirely to the record participation of the IWG-Member laboratories.  相似文献   

5.
Abundances of twenty four trace elements, including Y and fourteen rare earth elements (REE), are reported for eighty six geological reference materials and four proficiency testing samples. Analytical data were obtained by ICP-MS using solution nebulisation after mixed acid digestion (HF-HClO4) under pressure. Analysed samples cover a wide range of element concentrations and mineralogical compositions, including samples for which there are few previously published data. Precision for elemental determinations in nearly 90% of the samples analysed is better than 5%. Accuracy, estimated by comparison with data from compilations is better than 6% for well characterized reference materials. Results obtained for samples that are low in trace elements are often significantly lower than compiled reference values. A critical discussion of the compiled data sets, especially for Y and the REEs, indicates that some reference values seem to be erroneous.  相似文献   

6.
Trace element data compiled on, geoshemical reference samples present invariably skewed distributions. It is proposed to treat such data as lognormally distributed and to compute geometric means (Xgm) as probable values. As examples, the Xgm values derived for some trace elements in some rock reference samples are compared with the "recommended" values and with the "gamma" values of Christie.  相似文献   

7.
Analytical data for five GSJ (Geological Survey of Japan) reference samples, the "Instrumental analysis series" received by October 1998, are compiled. The data reported in publications and personal communications were evaluated statistically, taking into account the analytical method and sample preparation. Based on the selected available data, recommended and preferred values for fourteen major and fifty one minor and trace elements are proposed.  相似文献   

8.
Shi  X. S.  Zeng  Yiwen  Shi  Congde  Ma  Zhanguo  Chen  Wenbo 《Acta Geotechnica》2022,17(9):3839-3854

Gap-graded granular soils are used as construction materials worldwide, and their hydraulic conductivity depends on their relative content of coarse and fine grains, initial conditions, and particle shape. In this study, a series of constant head hydraulic conductivity tests were performed on gap-graded granular soils with different initial relative densities, fine contents, and particle shapes. The test results show that the hydraulic conductivity decreases with an increase in fine fraction and then remains approximately constant beyond the “transitional fine content.” The role of the structural effect on the hydraulic conductivity is different from that on the mechanical properties (such as stiffness and shear strength). This can be attributed to the degree of filling within inter-aggregate voids, disturbance of soil structure, and densified fine bridges between coarse aggregates. The equivalent void ratio concept was introduced into the Kozeny–Carman formula to capture the effect of fines (aggregates) on the “coarse-dominated” (“fine-dominated”) structure, and a simple model is proposed to capture the change of hydraulic conductivity of gap-granular soils. The model incorporates a structural variable to capture the effect of fines on “coarse-dominated” structure and coarse aggregates on “fine-dominated” structure. The performance of the model was verified with experimental data from this study and previously reported data compiled from the literature. The results reveal that the proposed model is simple yet effective at capturing the hydraulic conductivity of gap-graded granular soils with a wide range of fine contents, initial conditions, and particle shapes.

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9.
The region under study is located in the active “transition zone” from the Eurasian continent to the Pacific Ocean. The zone occupies not only the continent-ocean border area (continental coastline, marginal seas, island arcs, and deep-sea trenches) but also the margins of intracontinental regions of the Eurasian continent with different structures and regimes of development. The transition zone is a natural buffering and damping regulator of the interaction between the Eurasian and Pacific plates and is characterized by intense orogenesis, contemporary volcanism, active seismicity, diverse geothermal regime, and highly nonuniform measured heat-flow values. Available geothermal data for the region are not sufficiently generalized. After the latest maps compiled in the 1990s, new data have been obtained and new geoinformation technologies have been developed. In the study presented in this paper, available geothermal information has been generalized and a detailed heat flow distribution map has been compiled and used to calculate Moho temperatures, to determine the thickness of the “geothermal” lithosphere, and to construct distribution maps of these parameters.  相似文献   

10.
随着国家"一带一路"倡议的推进,在中国地质调查局的资助下,开展了老挝境内21万km^2的国家尺度(1:100万)地球化学填图工作,本次工作填补了老挝国家尺度地球化学填图的空白,为老挝基础地质、矿产开发、环境保护、农业生产等多个方面提供了基础地球化学保障。本次共采集老挝境内地球化学样品1905件,使用多种测试手段分析了71种元素的含量,并据此制作了这些元素的地球化学图和地球化学异常图。通过对老挝Au、Cu、Ni、Co、Mn、Zn、Ag、As、Sb、Pb、Bi和Sn的地球化学参数及其相关性的研究发现:这些元素的中位值均小于我国热带雨林区水系沉积物元素含量,而且这些元素的中位值均小于其平均值,As、Au、Bi、Pb和Sb在老挝境内的分布十分不均,元素局部富集明显。通过R型聚类分析,我们将上述元素分为Au;Cu;Ni、Co;Mn、Zn;Ag、As、Sb、Pb、Bi、Sn等5个簇群,并根据元素的地球化学分布特征及综合异常特征,在老挝划分了7个地球化学成矿远景区。  相似文献   

11.
Microanalytical trace element techniques (such as ion probe or laser ablation ICP-MS) are hampered by a lack of well characterized, homogeneous standards. Two silicate glass reference materials produced by National Institute of Standards and Technology (NIST), NIST SRM 610 and NIST SRM 612, have been shown to be homogeneous and are spiked with up to sixty one trace elements at nominal concentrations of 500 μg g-1 and 50 μg g-1 respectively. These samples (supplied as 3 mm wafers) are equivalent to NIST SRM 611 and NIST SRM 613 respectively (which are supplied as 1 mm wafers) and are becoming more widely used as potential microanalytical reference materials. NIST however, only certifies up to eight elements in these glasses. Here we have compiled concentration data from approximately sixty published works for both glasses, and have produced new analyses from our laboratories. Compilations are presented for the matrix composition of these glasses and for fifty eight trace elements. The trace element data includes all available new and published data, and summaries present the overall average and standard deviation, the range, median, geometric mean and a preferred average (which excludes all data outside ± one standard deviation of the overall average). For the elements which have been certified, there is a good agreement between the compiled averages and the NIST data. This compilation is designed to provide useful new working values for these reference materials.  相似文献   

12.
Direct injection techniques to measure trace metal concentrations by flameless atomic absorption were applied to fresh water samples of low to moderate matrix content. Many samples exhibited high non-atomic absorption which was decreased considerably by HNO3 digestion within the furnace. The remaining background absorption could not be reduced by selective volatilization prior to atomization. It was taken into account where necessary by background measurements at nearby non-absorbable wavelengths.Other interference problems applying especially to Cd, Pb and Zn were eliminated by operating at higher than usual atomization temperatures. The method of standard additions to calibrate concentrations seemed to be adequate for these particular samples.Using the method recommended, precision tests to measure “within batch” and “between batch” variations were carried out for four elements in a typical sample.  相似文献   

13.
A new computer programme was written in programming language TURBOC, which enables us to apply a procedure involving seventeen statistical tests (a total of sixty five single or multiple outlier versions of these tests) for outlier detection in univariate sample at a high confidence level of 99% (significance level α= 0.01). The outlying observations should be evaluated first for technical reasons and then rejected manually from the data base until no more outliers are detected and the final statistical parameters are computed from the remaining data. This programme has been used successfully to process two reference material data bases: WS-E from England and Soil-5 from Peru. The final mean values for WS-E are more reliable (characterized by smaller standard deviations and narrower confidence limits) than those obtained earlier using a different statistical approach. The application of a large number of statistical tests to Soil-5 also resulted in smaller standard deviation values for most elements than the method involving a limited number of such tests. For WS-E, some laboratories seem to have produced multiple data that were detected as statistical outliers. A close analysis of the distribution of outliers as a function of laboratory, country and analytical method leads to a technical justification for these outlying observations, probably in terms of inadequate QA/QC practices. Use of geochemical criteria indicates that the new mean values in WS-E might be closer to the "true" concentrations. This procedure of outlier detection and elimination is therefore recommended in the study of the existing RM.  相似文献   

14.
Coefficients of association have been widely employed in cluster analysis. However, their use has been, for the most part, restricted to binary data. This limitation can be overcome by redefining positive and negative matches and mismatches in terms of minimum and maximum values of paired elements of parallel vector arrays. Rewriting the algorithms of coefficients of association with these new components gives the new “quantified” coefficients general utility for binary, ordered multistate, and quantitative data, while retaining their original analytic properties. Quantified coefficients of association avoid several problems of shape and size that are associated with correlation coefficients and measures of Euclidean distance. However, when measuring similarity, quantified coefficients weight each attribute of an object by that attribute's magnitude. A related set of similarity indices termed “mean ratios” is introduced; these indices give each attribute equal weight in all situations. Both quantified coefficients of association and mean ratios are related to a number of measures of similarity introduced to various fields of scientific research during the past 50 years. A review of this literature is included in an attempt to consolidate methodology and simplify nomenclature.  相似文献   

15.
Cadmium, gadolinium and samarium concentrations were determined in seven geochemical reference materials by isotope dilution thermal ionisation mass spectrometry. The results for all three elements in BCR-1 are in excellent agreement with the compiled values as well as the literature values dete-mined by isotope dilution mass spectrometry. The agreement with compiled values on the other material is generally good except for Cd where the values for BHVO-1, BIR-1, DNC-1 and W-2 need to be revised.  相似文献   

16.
The complexity of modern geochemical data sets is increasing in several aspects (number of available samples, number of elements measured, number of matrices analysed, geological-environmental variability covered, etc), hence it is becoming increasingly necessary to apply statistical methods to elucidate their structure. This paper presents an exploratory analysis of one such complex data set, the Tellus geochemical soil survey of Northern Ireland (NI). This exploratory analysis is based on one of the most fundamental exploratory tools, principal component analysis (PCA) and its graphical representation as a biplot, albeit in several variations: the set of elements included (only major oxides vs. all observed elements), the prior transformation applied to the data (none, a standardization or a logratio transformation) and the way the covariance matrix between components is estimated (classical estimation vs. robust estimation). Results show that a log-ratio PCA (robust or classical) of all available elements is the most powerful exploratory setting, providing the following insights: the first two processes controlling the whole geochemical variation in NI soils are peat coverage and a contrast between “mafic” and “felsic” background lithologies; peat covered areas are detected as outliers by a robust analysis, and can be then filtered out if required for further modelling; and peat coverage intensity can be quantified with the %Br in the subcomposition (Br, Rb, Ni).  相似文献   

17.
This paper presents new major and trace element data from 150 garnet xenocrysts from the V. Grib kimberlite pipe located in the central part of the Arkhangelsk diamondiferous province (ADP). Based on the concentrations of Cr2O3, CaO, TiO2 and rare earth elements (REE) the garnets were divided into seven groups: (1) lherzolitic “depleted” garnets (“Lz 1”), (2) lherzolitic garnets with normal REE patterns (“Lz 2”), (3) lherzolitic garnets with weakly sinusoidal REE patterns (“Lz 3”), (4) lherzolitic garnets with strongly sinusoidal REE patterns (“Lz 4”), (5) harzburgitic garnets with sinusoidal REE patterns (“Hz”), (6) wehrlitic garnets with weakly sinusoidal REE patterns (“W”), (7) garnets of megacryst paragenesis with normal REE patterns (“Meg”). Detailed mineralogical and geochemical garnet studies and modeling results suggest several stages of mantle metasomatism influenced by carbonatite and silicate melts. Carbonatitic metasomatism at the first stage resulted in refertilization of the lithospheric mantle, which is evidenced by a nearly vertical CaO-Cr2O3 trend from harzburgitic (“Hz”) to lherzolitic (“Lz 4”) garnet composition. Harzburgitic garnets (“Hz”) have probably been formed by interactions between carbonatite melts and exsolved garnets in high-degree melt extraction residues. At the second stage of metasomatism, garnets with weakly sinusoidal REE patterns (“Lz 3”, “W”) were affected by a silicate melt possessing a REE composition similar to that of ADP alkaline mica-poor picrites. At the last stage, the garnets interacted with basaltic melts, which resulted in the decrease CaO-Cr2O3 trend of “Lz 2” garnet composition. Cr-poor garnets of megacryst paragenesis (“Meg”) could crystallize directly from the silicate melt which has a REE composition close to that of ADP alkaline mica-poor picrites. P-T estimates of the garnet xenocrysts indicate that the interval of ～60–110 km of the lithospheric mantle beneath the V. Grib pipe was predominantly affected by the silicate melts, whereas the lithospheric mantle deeper than 150 km was influenced by the carbonatite melts.  相似文献   

18.
New data for 21 trace elements including eight rare-earths, determined by neutron activation analysis (NAA) in two rook reference samples (Granite G-2, Andesite AGV-1), are compared with the preferred values previously proposed. Using compiled data published in 1969 and in 1972, further comparisons are made with the preferred means calculated for different methods of trace analysis. NAA data compiled in 1969 and in 1972 and new results published since then are assembled in two tables for the 21 elements. These 1976 NAA data lead us to suggest slight revisions of the preferred values for five to ton elements in each sample.  相似文献   

19.
Assessment of strength anisotropy in transversely isotropic rocks has been one of the most challenging subjects in rock engineering. However, far too little attention has been paid to banded amphibolite rocks. This study aim to evaluate strength and deformation anisotropy behavior of banded amphibolite rocks. The dynamic mechanical tests including ultrasonic pulse test, uniaxial compressive strength, Brazilian test and deformability test were performed on drilled rock samples as a function of foliation plane angle (β = 0°, 30°, 60° and 90°). The results obtained have shown that the dynamic mechanical properties of amphibolite rocks have different values concerning banding plane. Compression and shear waves taken parallel to the foliation plane show highest values than those obtained in the other directions. Under uniaxial test, the banded amphibolite has a U-shaped anisotropy with maximum strength at β = 90° and minimum strength is obtained when β = 30°. Strength anisotropic index ranges between 0.96 and 1.47. It seems that the high range value of anisotropic index is mainly due to slight undulation of foliation planes, that being not perfectly straight. The results of elastic deformation test show that there is no clear dependence on microstructures characteristics of subtype-amphibolite rocks that controlling modulus “shape-anisotropy”. However, in this study, Young modulus values of amphibolite rocks with β follow both types of shape-anisotropy, “U-shape” and “decreased order-shaped”. Thus, this study recommended that further research be undertaken regarding the role of modulus “shape-anisotropy” within the same lithotype.  相似文献   

20.
D.H. Green 《Tectonophysics》1973,17(3):285-297
The pyrolite model composition provides a satisfactory source composition for mantle-derived magmas insofar as major elements and “compatible” trace elements are concerned but there is evidence for mantle inhomogeneity in the abundances of “incompatible” minor and trace elements (e.g., K, Ti, P, Rb, Sr, light rare earth elements etc.). The composition of a magma, assuming a constant source composition, varies according to the pressure, temperature and water pressure or water content of the source region. The latter two variables essentially determine the degree of partial melting of the source region and in considering the chemical composition of the melt and nature of the residual phases, this parameter is of prime importance.For high degrees (> 20% approx.) of partial melting of a pyrolite source region, magmas are of tholeiitic character but are of increasingly undersaturated and alkaline type for lower degrees of partial melting and high pressures. For any chosen degree of melting and fixed water content of the source region, magmas are more olivine-rich at higher pressures. For any chosen pressure and chosen degree of partial melting, magmas are less olivine-rich at high water contents (and thus lower temperatures). Quartz tholeiite magmas may be derived by ~ 30% melting of pyrolite under water-saturated conditions at pressures up to between 17 kbar and 20 kbar. These generalizations may be applied to understand the characteristic magmatism of mid-oceanic ridges, island chains, oceanic islands and orogenic regions.  相似文献   

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