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1.
Interaction between slab-derived melt and mantle peridotite and the role of slab melt as a metasomatizing agent in the sub-arc mantle is being increasingly recognized. Adakite, the slab melt erupted on the surface, usually exhibits anomalously high MgO, CaO, Cr and Ni contents that indicate interaction with mantle peridotitite. Here we note that Cenozoic adakites have Na2O contents below 5.8 wt.% with ∼95% samples lower than 5.0 wt.%, and are generally depleted in this component relative to experimental basalt partial melts (mostly beyond 5.0 wt.% and up to 9.0 wt.% Na2O) produced under 1.5-3.0 GPa conditions that are most relevant to adakite production. We interpret the adakite Na depletion to be also a consequence of the melt / rock reaction that takes place within the hot mantle wedge. During ascent and reaction with mantle peridotite, primary adakite melts gain mantle components MgO, CaO, Cr and Ni but lose Na2O, SiO2 and perhaps K2O to the mantle, leading to Na-rich mantle metasomatism. Selective assimilation of predominately mantle clinopyroxene, some spinel and minor olivine at high T/P has been considered to be an important process in producing high-Mg adakites from primary low-Mg slab melts [Killian, R., Stern, C. R., 2002. Constraints on the interaction between slab melts and the mantle wedge from adakitic glass in peridotite xenoliths. Eur. J. Mineral. 14, 25-36]. In such a process, Na depletion in the assimilated melt is the result of dilution due to the increase in melt mass. Phase relationships in the reaction system siliceous melt + peridotite and quantitative calculation suggest that assimilation of mantle clinopyroxene, olivine and spinel and fractional crystallization of sodic amphibole and orthopyroxene, under conditions of moderate T/P and increasing melt mass, is also an important process that modifies the composition of adakites and causes the Na depletion.  相似文献   

2.
埃达克岩的Na亏损及其对地幔Na交代的指示意义   总被引:1,自引:3,他引:1  
埃达克岩是玄武质洋壳部分熔融的产物。然而,与实验室玄武岩部分熔融产生的埃达克质熔体相比,天然埃达克岩明显地高Mg、Cr和Ni,这表明埃达克岩浆在上升过程中有地幔成分的加入。本文的观察结果表明,全球新生代埃达克岩的Na2O含量低于5.8%,大约95%的新生代埃达克岩样品Na2O含量小于5.0%。然而,在埃达克岩产生的压力范围(1.5~3.0GPa),实验的玄武岩部分熔体大多数Na2O含量超过5.0%,最高达到9.0%,显示埃达克岩具有明显的Na亏损现象。我们认为这是埃达克熔体在热的地幔楔中与地幔橄榄岩反应的结果。在俯冲带,大洋板片熔融产生的熔体(埃达克熔体)上升并与地幔橄榄岩发生反应,原始的埃达克熔体获得MgO、Cr及Ni等地幔组分,但其Na2O和SiO2等通过反应进入地幔,导致地幔交代作用。根据长英质熔体与橄榄岩反应体系的相关系,我们认为,地幔单斜辉石、橄榄石、尖晶石的混染作用以及钠质角闪石和斜方辉石的分离结晶作用,是改变埃达克熔体组成并导致其Na亏损的一个重要的过程。埃达克岩的Na亏损为地幔Na交代作用和一些富Na的弧岩浆成因提供了重要证据。  相似文献   

3.
Omphacite is a typomorphic mineral of eclogites, which is inappropriate to mineral assemblages of peridotites. Nevertheless, findings of this mineral in inclusions in peridotitic diamonds can be considered as indirect evidence for the existence of this paradoxical mineral assemblage.In this paper we present experimental results on the interaction between carbonate-bearing amphibolite and olivine that model processes operated at the crust–mantle boundary in subduction zones. The experiments demonstrate growth of omphacite at the interface between acid melt and peridotite media at 2.9 GPa and 850–900 °C; the omphacite coexists either with garnet and orthopyroxene or with phlogopite. The synthetic omphacite is exclusively of reactive-magmatic origin and does not form in metasomatic way. Findings of omphacite inclusions in peridotitic diamonds and in some pyroxenites from kimberlites are discussed in scope of the obtained experimental data.  相似文献   

4.
This paper presents field, petrographic–structural and geochemical data on spinel and plagioclase peridotites from the southern domain of the Lanzo ophiolitic peridotite massif (Western Alps). Spinel lherzolites, harzburgites and dunites crop out at Mt. Arpone and Mt. Musinè. Field evidence indicates that pristine porphyroclastic spinel lherzolites are transformed to coarse granular spinel harzburgites, which are in turn overprinted by plagioclase peridotites, while strongly depleted spinel harzburgite and dunite bands and bodies replace the plagioclase peridotites. On the northern flank of Mt. Arpone, deformed, porphyroclastic (lithospheric) lherzolites, with diffuse pyroxenite banding, represent the oldest spinel-facies rocks. They show microstructures of a composite subsolidus evolution, suggesting provenance from deeper (asthenospheric) mantle levels and accretion to the lithosphere. These protoliths are locally transformed to coarse granular (reactive) spinel harzburgites and dunites, which show textures reminiscent of melt/rock reaction and geochemical characteristics suggesting that they are products of peridotite interaction with reactively percolating melts. Geochemical data and modelling suggest that <1–5% fractional melting of spinel-facies DMM produced the injected melts. Plagioclase peridotites are hybrid rocks resulting from pre-existing spinel peridotites and variable enrichment of plagioclase and micro-gabbroic material by percolating melts. The impregnating melts attained silica-saturation, as testified by widespread orthopyroxene replacement of olivine, during open system migration in the lithosphere. At Mt. Musinè, coarse granular spinel harzburgite and dunite bodies replace the plagioclase peridotites. Most of these replacive, refractory peridotites have interstitial magmatic clinopyroxene with trace element compositions in equilibrium with MORB, while some Cpx have REE-depleted patterns suggesting transient geochemical features of the migrating MORB-type melts, acquired by interaction with the ambient plagioclase peridotite. These replacive spinel harzburgite and dunite bodies are interpreted as channels exploited for focused and reactive migration of silica-undersaturated melts with aggregate MORB compositions. Such melts were unrelated to the silica-saturated melts that refertilized the pre-existing plagioclase peridotites. Finally, MORB melt migration occurred along open fractures, now recorded as gabbroic dikes.

Our data document the complexity of rock-types and mantle processes in the South Lanzo peridotite massif and describe a composite tectonic and magmatic scenario that is not consistent with the “asthenospheric scenario” proposed by previous authors. We envisage a “transitional scenario” in which extending subcontinental lithospheric mantle was strongly modified (both depleted and refertilized) by early melts with MORB-affinity formed by decompression partial melting of the upwelling asthenosphere, during pre-oceanic rifting and lithospheric thinning in the Ligurian Tethys realm.  相似文献   


5.
Melting relations of primitive peridotite were studied up to 25 GPa. The change of the liquidus phase from olivine to majorite occurs at 16 GPa. We confirmed the density crossover of the FeO-rich peridotite melt and the equilibrium olivine (Fo90) at 7 GPa. Sinking of equilibrium olivine (Fo95) in the primitive peridotite melt was observed up to 10 GPa. The compression curves of FeO-rich peridotitic and komatiite melts reported in this and earlier work suggest that the density crossover in the Earth's mantle will be located at 11–12 GPa at 2000°C, consistent with an previous estimation by C.B. Agee and D. Walker.

The density crossover can play a key role in the Moon and the terrestrial planets, such as the Earth, Venus and Mars. Majorite and some fraction of melt could have separated from the ascending diapir and sunk downwards at the depths below the density crossover. This process could have produced a garnet-rich transition zone in the Earth's mantle. The density crossover may exist in the FeO-rich lunar mantle at around the center of the Moon. The density crossover which exists at the depth of 600 km in the Martian mantle plays a key role in producing a fractionated mantle, which is the source the parent magmas of the SNC meteorites.  相似文献   


6.
宋衍茹  叶凯  续海金 《岩石学报》2009,25(1):147-158
苏鲁超高压变质地体中发现了大量包裹在超高压(UHP)变质片麻岩和混合岩中的造山带石榴橄榄岩。根据它们的野外产出特征和全岩地球化学成分,其中一部分石榴橄榄岩的原岩来自于亏损地幔,后来被卷入俯冲陆壳并经受过俯冲陆壳产生的熔/流体的交代。但是,对这些岩石早期的亏损过程尚缺乏清晰的认识。本文报道了东海芝麻坊石榴子石二辉橄榄岩早期变质演化的新证据。根据详细的变质反应结构观察和矿物成分研究,芝麻坊石榴子石二辉橄榄岩在经历高压低温俯冲带型超高压变质之前经历了至少两期变质演化。其原岩矿物组合由石榴子石变斑晶的高Ca-Cr核部及其中包裹的高Mg单斜辉石、高Al-Cr斜方辉石和高Mg-Ni橄榄石所记录;指示芝麻坊石榴子石二辉橄榄岩的原岩为高温-高压的富集石榴子石二辉橄榄岩。第二期矿物组合为包裹在低Cr变斑晶石榴子石幔部和细粒新生石榴子石核部的大量富Al铬铁矿和高Mg低Ni橄榄石以及少量高Mg斜方辉石。该期组合未发现单斜辉石,表明岩石随后被转变为高温低压的难熔尖晶石方辉橄榄岩或尖晶石纯橄岩。芝麻坊石榴子石二辉橄榄岩的早期变质演化记录了它们被卷入大陆板片俯冲带之前的地幔楔上升对流过程。笔者认为芝麻坊石榴子石二辉橄榄岩的原岩来源于早期俯冲大洋板片之上的深部高温富集地幔楔,洋壳俯冲过程中的地幔楔对流导致其上升到弧后或岛弧之下的地幔楔浅部,减压部分熔融使原本富集的石榴子石二辉橄榄岩转化为难熔的尖晶石方辉橄榄岩或尖晶石纯橄岩。  相似文献   

7.
This experimental study examines the mineral/melt partitioning of incompatible trace elements among high-Ca clinopyroxene, garnet, and hydrous silicate melt at upper mantle pressure and temperature conditions. Experiments were performed at pressures of 1.2 and 1.6 GPa and temperatures of 1,185 to 1,370 °C. Experimentally produced silicate melts contain up to 6.3 wt% dissolved H 2O, and are saturated with an upper mantle peridotite mineral assemblage of olivine+orthopyroxene+clinopyroxene+spinel or garnet. Clinopyroxene/melt and garnet/melt partition coefficients were measured for Li, B, K, Sr, Y, Zr, Nb, and select rare earth elements by secondary ion mass spectrometry. A comparison of our experimental results for trivalent cations (REEs and Y) with the results from calculations carried out using the Wood-Blundy partitioning model indicates that H 2O dissolved in the silicate melt has a discernible effect on trace element partitioning. Experiments carried out at 1.2 GPa, 1,315 °C and 1.6 GPa, 1,370 °C produced clinopyroxene containing 15.0 and 13.9 wt% CaO, respectively, coexisting with silicate melts containing ~1–2 wt% H 2O. Partition coefficients measured in these experiments are consistent with the Wood-Blundy model. However, partition coefficients determined in an experiment carried out at 1.2 GPa and 1,185 °C, which produced clinopyroxene containing 19.3 wt% CaO coexisting with a high-H 2O (6.26±0.10 wt%) silicate melt, are significantly smaller than predicted by the Wood-Blundy model. Accounting for the depolymerized structure of the H 2O-rich melt eliminates the mismatch between experimental result and model prediction. Therefore, the increased Ca 2+ content of clinopyroxene at low-temperature, hydrous conditions does not enhance compatibility to the extent indicated by results from anhydrous experiments, and models used to predict mineral/melt partition coefficients during hydrous peridotite partial melting in the sub-arc mantle must take into account the effects of H 2O on the structure of silicate melts.  相似文献   

8.
We performed partial melting experiments at 1 and 1.5 GPa, and 1180–1400 °C, to investigate the melting under mantle conditions of an olivine-websterite (GV10), which represents a natural proxy of secondary (or stage 2) pyroxenite. Its subsolidus mineralogy consists of clinopyroxene, orthopyroxene, olivine and spinel (+garnet at 1.5 GPa). Solidus temperature is located between 1180 and 1200 °C at 1 GPa, and between 1230 and 1250 °C at 1.5 GPa. Orthopyroxene (±garnet), spinel and clinopyroxene are progressively consumed by melting reactions to produce olivine and melt. High coefficient of orthopyroxene in the melting reaction results in relatively high SiO2 content of low melt fractions. After orthopyroxene exhaustion, melt composition is controlled by the composition of coexisting clinopyroxene. At increasing melt fraction, CaO content of melt increases, whereas Na2O, Al2O3 and TiO2 behave as incompatible elements. Low Na2O contents reflect high partition coefficient of Na between clinopyroxene and melt (\(D_{{{\text{Na}}_{ 2} {\text{O}}}}^{{{\text{cpx}}/{\text{liquid}}}}\)). Melting of GV10 produces Quartz- to Hyperstene-normative basaltic melts that differ from peridotitic melts only in terms of lower Na2O and higher CaO contents. We model the partial melting of mantle sources made of different mixing of secondary pyroxenite and fertile lherzolite in the context of adiabatic oceanic mantle upwelling. At low potential temperatures (T P < 1310 °C), low-degree melt fractions from secondary pyroxenite react with surrounding peridotite producing orthopyroxene-rich reaction zones (or refertilized peridotite) and refractory clinopyroxene-rich residues. At higher T P (1310–1430 °C), simultaneous melting of pyroxenite and peridotite produces mixed melts with major element compositions matching those of primitive MORBs. This reinforces the notion that secondary pyroxenite may be potential hidden components in MORB mantle source.  相似文献   

9.
We performed an experimental study, designed to reproduce the formation of an unusual merwinite?+?olivine-bearing mantle assemblage recently described as a part of a Ca-rich suite of inclusions in sublithospheric diamonds, through the interaction of peridotite with an alkali-rich Ca-carbonatite melt, derived from deeply subducted oceanic crust. In the first set of experiments, we studied the reaction between powdered Mg-silicates, olivine and orthopyroxene, and a model Ca-carbonate melt (molar Na:K:Ca?=?1:1:2), in a homogeneous mixture, at 3.1 and 6.5 GPa. In these equilibration experiments, we observed the formation of a merwinite?+?olivine-bearing assemblage at 3.1 GPa and 1200 °C and at 6.5 GPa and 1300–1400 °C. The melts coexisting with this assemblage have a low Si and high Ca content (Ca#?=?molar 100?×?Ca/(Ca?+?Mg)?>?0.57). In the second set of experiments, we investigated reaction rims produced by interaction of the same Ca-carbonate melt (molar Na:K:Ca?=?1:1:2) with Mg-silicate, olivine and orthopyroxene, single crystals at 3.1 GPa and 1300 °C and at 6.5 GPa and 1400 °C. The interaction of the Ca-carbonate melt with olivine leads to merwinite formation through the expected reaction: 2Mg2SiO4 (olivine)?+?6CaCO3 (liquid)?=?Ca3MgSi2O8 (merwinite)?+?3CaMg(CO3)2 (liquid). Thus, our experiments confirm the idea that merwinite in the upper mantle may originate via interaction of peridotite with Ca-rich carbonatite melt, and that diamonds hosting merwinite may have a metasomatic origin. It is remarkable that the interaction of the Ca-carbonate melt with orthopyroxene crystals does not produce merwinite both at 3.1 and 6.5 GPa. This indicates that olivine grain boundaries are preferable for merwinite formation in the upper mantle.  相似文献   

10.
Plagioclase-bearing peridotites are commonly associated with gabbroic rocks sampled around the Moho Transition Zone. Based on mineral chemistry, texture, and spatial relations, the formation of plagioclase-bearing peridotites has been attributed to impregnation of basalt into residual peridotites. We conducted reactive dissolution and crystallization experiments to test this hypothesis by reacting a primitive mid-ocean ridge basalt with a melt-impregnated lherzolite at 1,300 °C and 1 GPa and then cooling to 1,050 °C as pressure decreased to 0.7 GPa. Crystallization during cooling produced lithologic sequences of gabbro–wehrlite or gabbro–wehrlite–peridotite, depending on reaction time. Wehrlitic and peridotitic sections contain significant amounts of plagioclase interstitial to olivine and clinopyroxene and plagioclase compositions are spatially homogeneous. Clinopyroxene in the wehrlite–peridotite section is reprecipitated from the melt and exhibits poikilitic texture with small rounded olivine chadacrysts. Mineral composition in olivine and clinopyroxene varies spatially, both at the scale of the sample and within individual grains. Olivine grains that crystallized close to the melt–peridotite interface are enriched in iron due to their proximity to the basaltic melt reservoir. Consistent with many field studies, we observed gradual spatial variation in olivine and clinopyroxene composition across a lithologically sharp boundary between the gabbro and wehrlite–peridotite. Plagioclase compositions show no obvious dependence on distance from the melt–rock interface and were precipitated from late-stage trapped melts. Compositional trends of olivine, pyroxene, and plagioclase are consistent with previous experimental results and natural observations of the Moho Transition Zone. Different lithological sequences form based primarily on the melt–rock ratio, composition of the melt and host peridotite, and thermochemical conditions, but are expected to grade from gabbro to wehrlite or troctolite to peridotite. Plagioclase-bearing peridotite represents the low melt–rock ratio end member where pyroxene is only partially replaced by olivine and melt, whereas dunite is expected to form where melts overwhelm and consume all other phases. This study confirms that under nominally anhydrous conditions, the gabbro–wehrlite–plagioclase-peridotite sequence can be formed by reaction between basalt and lherzolite and subsequent crystallization at intermediate to low pressures. Melt–rock reaction is a fundamental process in the formation of new crust at the shallowest part of the melting column where pyroxene-undersaturated melts percolate through depleted peridotite.  相似文献   

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