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1.
A combined in situ SIMS and LA-(MC)-ICPMS study of U-Pb ages, trace elements, O and Lu-Hf isotopes was conducted for zircon from eclogite-facies metamorphic rocks in the Sulu orogen. The two microbeam techniques sampled various depths of zircon domains, revealing different element and isotope relationships between residual magmatic cores and new metamorphic rims and thus the geochemical architecture of metamorphic zircons which otherwise cannot be recognized by the single microbeam technique. This enables discrimination of metamorphic growth from different subtypes of metamorphic recrystallization. Magmatic cores with U-Pb ages of 769 ± 9 Ma have positive δ18O values of 0.1-10.1‰, high Th/U and 176Lu/177Hf ratios, high REE contents, and steep MREE-HREE patterns with negative Eu anomalies. They are interpreted as crystallizing from positive δ18O magmas during protolith emplacement. In contrast, newly grown domains have concordant U-Pb ages of 204 ± 4 to 252 ± 7 Ma and show negative δ18O values of −10.0‰ to −2.2‰, low Th/U and 176Lu/177Hf ratios, low REE contents, and flat HREE patterns with weak to no Eu anomalies. They are interpreted as growing from negative δ18O fluids that were produced by metamorphic dehydration of high-T glacial-hydrothermally altered rocks during continental subduction-zone metamorphism. Differences in δ18O between different domains within single grains vary from 0.8‰ to 12.5‰, suggesting different degrees of O isotope exchange between the positive δ18O magmatic core and the negative δ18O metamorphic fluid during the metamorphism. The magmatic zircons underwent three subtypes of metamorphic recrystallization, depending on their accessibility to negative δ18O fluids. The zircons recrystallized in solid-state maintained positive δ18O values, and REE and Lu-Hf isotopes of protolith zircon, but their U-Pb ages are lowered. The zircons recrystallized through dissolution exhibit negative δ18O values similar to the metamorphic growths, almost completely reset U-Pb ages, and partially reset REE systems. The zircons recrystallized through replacement show variably negative δ18O values, and partially reset REE, and U-Pb and Lu-Hf isotopic systems. Therefore, this study places robust constraints on the origin of metamorphic zircons in eclogite-facies rocks and provides a methodological framework for linking the different types of metamorphic zircons to petrological processes during continental collision. 相似文献
2.
Simultaneously in-situ analyses of U–Pb isotopes and trace elements were carried out for zircons, in combination with the in-situ analyses of trace elements in coexisting minerals, from low-T/UHP metagranite in the Dabie orogen. The results provide geochemical evidence for the existence of supercritical fluid during continental subduction-zone metamorphism. The zircons are categorized into three types based on their patterns of REE distribution. Type I zircons show increasing enrichment from La to Lu, with prominent positive Ce anomalies and negative Eu anomalies, which are typical of magmatic zircon. Some of them display regular or blurred oscillatory-zoned texture and apparent 206Pb/238U ages of 341 to 780 Ma, suggesting metamorphic modification by solid-state recrystallization with no significant involvement of metamorphic fluid. Type II zircons share similar Th, U and HFSE contents and REE patterns to Type I zircons. However, they exhibit blurred oscillatory-zoned texture or are unzoned, have apparent 206Pb/238U ages of 348 to 709 Ma, and are LREE-enriched relative to Type I zircons. This suggests that they underwent metamorphic reworking by replacement recrystallization in the presence of metamorphic fluid. The LREE enrichment is due to the presence of microscale LREE-bearing mineral inclusions (such as apatite, monazite or epidote) in the zircons. Type III zircons, representing the majority of the present analyses, are characterized by spongy texture and consistent enrichment of LREE, HREE, Th, U and HFSE relative to Type I zircons. They yield nearly concordant U–Pb ages close to the discordia lower-intercept. The consistent enrichment of trace elements relative to the magmatic zircon indicates involvement of a special UHP metamorphic fluid that has a strong capacity to extract significant amounts of LREE, HREE, Th, U and HFSE from such accessory minerals as allanite, garnet, rutile and zircon. Because these minerals are stable in the field of hydrous melt in granite–water systems, they are not able to be decomposed during the exhumation of deeply subducted continental crust. Thus, a supercritical fluid is suggested to transport the LREE, HREE, Th, U and HFSE in the accessory minerals to recrystallized zircons. The mechanism of dissolution recrystallization is responsible for the spongy texture and the very high concentration of trace elements in this type of metamorphic zircons. Therefore, the action of supercritical fluid is evident under the low-T/UHP metamorphic conditions. 相似文献
3.
锆石微区矿物包体的激光拉曼和阴极发光测试以及相应的SHRIMP U-Pb定年结果表明,苏鲁地体片麻岩锆石微区记录了十分复杂的年代学信息。其中副片麻岩锆石核部记录了345～743 Ma的继承性锆石年龄,标志着原岩碎屑锆石来源的复杂性;含柯石英的锆石微区记录了220～234 Ma的超高压变质年龄;而含石英包体的边部则记录了202～219 Ma的退变质年龄。正片麻岩继承性锆石核部所记录的年龄为574～680 Ma,表明原岩锆石曾经历了部分Pb丢失,原岩的形成年龄应大于680 Ma;含柯石英锆石微区所记录的超高压变质年龄为224～242 Ma;而锆石边部所记录的退变质年龄为209～219 Ma。两类片麻岩锆石微区所隐藏的超高压变质和退变质年龄信息十分相近,平均值分别为229±4Ma和211±4Ma,标志着苏鲁地体超高压变质时代应为印支期,相应的构造抬升速率约5.6 km/Ma。该项成果不仅确定了苏鲁地体超高压变质和退变质时代,而且对于深入探讨苏鲁地体快速折返过程中的动力学机制有着重要的科学意义。 相似文献
4.
苏鲁超高压变质带中非超高压花岗质片麻岩的准确识别:来自锆石微区矿物包体及SHRIMP U-Pb定年的证据 总被引：6，自引：0，他引：6
通过隐藏在锆石微区矿物包体激光拉曼的系统鉴定和阴极发光图像特征的详细研究,配合相应的锆石微区SHRIMP U-Pb定年测试,发现苏鲁地体超高压变质带中确实存在非超高压变质的花岗质片麻岩。该类岩石中的锆石晶体自核部到边部所保存的矿物包体以不含超高压矿物为特征,相应的阴极发光图像具有典型岩浆结晶锆石的核部和幔部,以及变质的再生边的特点。其中岩浆结晶锆石微区记录的~(238)U-~(206)Pb年龄为404～748Ma,表明原岩中部分锆石可能经历了Pb丢失,也不排除后期热事件因素的影响,原岩的形成年龄应大于748 Ma;而锆石的再生边所记录的~(238)U-~(206)Pb。年龄为204～214 Ma,与研究区经历超高压变质的副片麻岩和花岗质片麻岩锆石微区所记录的苏鲁地体快速折返过程中角闪岩相退变质年龄(~(238)U-~(206)Pb年龄的平均值为211±4 Ma,刘福来等,2003a)十分相似。上述特征表明,苏鲁地体超高压变质带中的部分花岗质片麻岩在超高压变质事件之前就已经形成,但并未“参与”深俯冲—超高压的变质演化过程,而是在苏鲁地体快速折返的角闪岩相退变质过程中与超高压岩片“拼贴”在一起。该项成果不仅为正确识别非超高压变质岩石提供了一个新的研究方法,而且对进一步深入探讨苏鲁地体超高压和非超高压岩片的“拼贴”机制有着重 相似文献
5.
Compared to the extensively documented ultrahigh-pressure metamorphism at North Qaidam, the pre-metamorphic history for both continental crust and oceanic crust is poorly constrained. Trace element compositions, U–Pb ages, O and Lu–Hf isotopes obtained for distinct zircon domains from eclogites metamorphosed from both continental and oceanic mafic rocks are linked to unravel the origin and multi-stage magmatic/metamorphic evolution of eclogites from the North Qaidam ultrahigh-pressure metamorphic (UHPM) belt, northern Tibet.For continental crust-derived eclogite, magmatic zircon cores from two samples with U–Pb ages of 875–856 Ma have both very high δ18O (10.6 ± 0.5‰) and mantle-like δ18O (averaging at 5.2 ± 0.7‰), high Th/U and 176Lu/177Hf ratios, and steep MREE-HREE distribution patterns (chondrite-normalized) with negative Eu anomalies. Combined with positive εHf (t) of 3.9–14.3 and TDM (1.2–0.8 Ga and 1.3–1.0 Ga, respectively), they are interpreted as being crystallized from either subduction-related mantle wedge or recycled material in the mantle. While the metamorphic rims from the eclogites have U–Pb ages of 436–431 Ma, varying (inherited, lower, and elevated) oxygen isotopes compared with cores, low Th/U and 176Lu/177Hf ratios, and flat HREE distribution patterns with no Eu anomalies. These reflect both solid-state recrystallization from the inherited zircon and precipitation from external fluids at metamorphic temperatures of 595–622 °C (TTi-in-zircon).For oceanic crust-derived eclogite, the magmatic cores (510 ± 19 Ma) and metamorphic rims (442.0 ± 3.7 Ma) also show distinction for Th/U and 176Lu/177Hf ratios, and the REE patterns and Eu anomalies. Combined with the mantle-like δ18O signature of 5.1 ± 0.3 ‰ and two groups of model age (younger TDM close to the apparent ages and older > 700 Ma), two possible pools, juvenile and inherited, were involved in mixing of mantle-derived magma with crustal components. The relatively high δ18O of 6.6 ± 0.3‰ for metamorphic zircon rims suggests either the protolith underwent hydrothermal alteration prior to the ~ 440 Ma oceanic crust subduction, or external higher δ18O fluid activities during UHP metamorphism at ~ 440 Ma.Therefore, the North Qaidam UHPM belt witnesses multiple tectonic evolution from Late Mesoproterozoic–Neoproterozoic assembly/breakup of the Rodinia supercontinent with related magmatic emplacement, then Paleozoic oceanic subduction, and finally transition of continental subduction/collision related to UHP metamorphism. 相似文献
6.
H. L. Yu L. F. Zhang C. J. Wei X. L. Li J. H. Guo 《Journal of Metamorphic Geology》2017,35(8):855-869
Although eclogites in the Belomorian Province have been regarded as Archean in age and among the oldest in the world, there are also multiple studies that have proposed a Paleoproterozoic age. Here, we present new data for the Gridino‐type eclogites, which occur as boudins and metamorphosed dykes within tonalite–trondhjemite–granodiorite gneisses. Zircon from these eclogites has core and rim structures. The cores display high Th/U ratios (0.18–0.45), negative Eu anomalies and strong enrichment in HREE, and have Neoarchean U–Pb ages of c. 2.70 Ga; they are interpreted to be magmatic in origin. Zircon cores have δ18O of 5.64–6.07‰ suggesting the possibility of crystallization from evolved mantle‐derived magmas. In contrast, the rims, which include the eclogite facies minerals omphacite and garnet, are characterized by low Th/U ratios (<0.035) and flat HREE patterns, and yield U–Pb ages of c. 1.90 Ga; they are interpreted to be metamorphic in origin. Zircon rims have elevated δ18O of 6.23–6.80‰, which was acquired during eclogite facies metamorphism. Based on petrography and phase equilibria modelling, we recognize a prograde epidote amphibolite facies mineral assemblage, the peak eclogite facies mineral assemblage and a retrograde high‐P amphibolite facies mineral assemblage. The peak metamorphic conditions of 695–755°C at >18 kbar for the Gridino‐type eclogites suggest an apparent thermal gradient of <39–42°C/kbar for the Lapland–Kola collisional orogeny. 相似文献
7.
8.
SHRIMP U-Pb zircon dating from Sulu-Dabie dolomitic marble, eastern China: constraints on prograde, ultrahigh-pressure and retrograde metamorphic ages 总被引：15，自引：0，他引：15
F. L. LIU A. GERDES J.G. LIOU H. M. XUE F. H. LIANG 《Journal of Metamorphic Geology》2006,24(7):569-589
Laser Raman spectroscopy and cathodoluminescence (CL) images show that zircon from Sulu‐Dabie dolomitic marbles is characterized by distinctive domains of inherited (detrital), prograde, ultrahigh‐pressure (UHP) and retrograde metamorphic growths. The inherited zircon domains are dark‐luminescent in CL images and contain mineral inclusions of Qtz + Cal + Ap. The prograde metamorphic domains are white‐luminescent in CL images and preserve a quartz eclogite facies assemblage of Qtz + Dol + Grt + Omp + Phe + Ap, formed at 542–693 °C and 1.8–2.1 GPa. In contrast, the UHP metamorphic domains are grey‐luminescent in CL images, retain the UHP assemblage of Coe + Grt + Omp + Arg + Mgs + Ap, and record UHP conditions of 739–866 °C and >5.5 GPa. The outermost retrograde rims have dark‐luminescent CL images, and contain low‐P minerals such as calcite, related to the regional amphibolite facies retrogression. Laser ablation ICP‐MS trace‐element data show striking difference between the inherited cores of mostly magmatic origin and zircon domains grown in response to prograde, UHP and retrograde metamorphism. SHRIMP U‐Pb dating on these zoned zircon identified four discrete 206Pb/238U age groups: 1823–503 Ma is recorded in the inherited (detrital) zircon derived from various Proterozoic protoliths, the prograde domains record the quartz eclogite facies metamorphism at 254–239 Ma, the UHP growth domains occurred at 238–230 Ma, and the late amphibolite facies retrogressive overprint in the outermost rims was restricted to 218–206 Ma. Thus, Proterozoic continental materials of the Yangtze craton were subducted to 55–60 km depth during the Early Triassic and recrystallized at quartz eclogite facies conditions. Then these metamorphic rocks were further subducted to depths of 165–175 km in the Middle Triassic and experienced UHP metamorphism, and finally these UHP metamorphic rocks were exhumed to mid‐crustal levels (about 30 km) in the Late Triassic and overprinted by regional amphibolite facies metamorphism. The subduction and exhumation rates deduced from the SHRIMP data and metamorphic P–T conditions are 9–10 km Myr?1 and 6.4 km Myr?1, respectively, and these rapid subduction–exhumation rates may explain the obtained P–T–t path. Such a fast exhumation suggests that Sulu‐Dabie UHP rocks that returned towards crustal depths were driven by buoyant forces, caused as a consequence of slab breakoff at mantle depth. 相似文献
9.
The North Qinling Block (NQB) is an important segment of the Qinling Orogen in Central China. Here we report the results from SIMS geochronology and oxygen isotopes, as well as LA-MC-ICPMS Hf isotopic analyses on zircon grains from a suite of metamorphic rocks (felsic gneisses, garnet plagioclase amphibolites, and retrograde eclogite dikes) in the Qinling Group of the NQB. The age data show that these rocks underwent at least two episodes of metamorphism with the peak at 483–501 Ma, followed by 454–470 Ma retrograde metamorphism. These results are generally coeval with the periods of 500–480 Ma for peak metamorphism and 460–420 Ma for retrograde metamorphism previously obtained from the HP/UHP metamorphic rocks of the NQB. During the prograde and retrograde metamorphism, widespread fluid and melt circulation within the block has been identified from the geochemical features of the metamorphic zircons. The fluids that circulated in the felsic gneisses and retrograde eclogite dikes originated from the dehydration of altered oceanic basalts as inferred from the exceedingly low Th/U ratios, positive εHf(t) (> 5) and extremely δ18O (10.01–13.91‰) values in metamorphic zircons. In contrast, the melt involved in the formation of garnet plagioclase amphibolites appears to have been derived from continental sediments interlayered with the oceanic basalts since zircons crystallized during the peak and retrograde metamorphism show typical magmatic features with high U and Th contents and Th/U ratios and enriched Hf (εHf(t) = − 5.42 to − 0.18) and oxygen isotope composition (δ18O around 8‰). Geochronological and geochemical features of the magmatic cores of the clear core-rim textured zircons demonstrate that the protoliths of the gneisses were intermediate-acid volcanic rocks erupted before Neoproterozoic (800 Ma), which is further supported by the intrusion of basaltic magma of asthenospheric origin as represented by protoliths of retrograde eclogite dikes, with the oldest magmatic zircon formed at 789 Ma. The protoliths of garnet plagioclase amphibolites appear to be altered oceanic basalts but had been significantly affected by the melt during the metamorphism. Combined with the previous studies, the Qinling Group experienced overall subduction in the Early Paleozoic. The NQB as represented by the Qinling Group was most likely a discrete micro-block in the Neoproterozoic, and underwent deep subduction in the Cambrian (483–501 Ma) and exhumation in Ordovician (454–470 Ma). We propose that the NQB preserves a complete cycle of tectonic evolution of an orogen from an oceanic basin spreading, and micro-continent formation to deep subduction and exhumation. 相似文献
10.
Distinct zircon U–Pb and O–Hf–Nd–Sr isotopic behaviour during fluid flow in UHP metamorphic rocks: evidence from metamorphic veins and their host eclogite in the Sulu Orogen,China 
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下载免费PDF全文 Y.‐J. Zhao Y.‐B. Wu X.‐C. Liu S. Gao H. Wang J.‐P. Zheng S.‐H. Yang 《Journal of Metamorphic Geology》2016,34(4):343-362
Fluid plays a key role in metamorphism and magmatism in subduction zones. Veins in high‐pressure (HP) to ultrahigh‐pressure (UHP) rocks are the products of fluid‐rock interaction, and can thus provide important constraints on fluid processes in subduction zones. This contribution is an integrated study of zircon U–Pb and O–Hf, as well as whole‐rock Nd–Sr isotopic compositions for a quartz vein, a complex vein, and their host eclogite in the Sulu UHP terrane to decipher the timing and source of fluid flow under HP‐UHP metamorphic conditions. The inherited magmatic zircon cores from the host eclogite constrain the protolith age at c. 750 Ma. Their variable εHf(t) values from ?1.11 to 2.54 and low δ18O values of 0.32–3.40‰ reflect a protolith that formed in a rift setting due to the breakup of the supercontinent Rodinia. The hydrothermal zircon from the quartz and the complex veins shows euhedral shapes, relatively flat HREE pattern, slight or no negative Eu anomaly, low 176Lu/177Hf ratios, and low formation temperatures of 660–690 °C, indicating they precipitated from fluids under HP eclogite facies conditions. This zircon yielded similar U–Pb ages of 217 ± 2 and 213 ± 3 Ma within analytical uncertainty, recording the timing of fluid flow during the exhumation of the UHP rock. It is inferred that the fluids might be of internal origin based on the homogeneity of δ18O values of the hydrothermal zircon from the quartz (?2.41 ± 0.13‰) and complex veins (?2.35 ± 0.12‰), and the metamorphic grown zircon of the host eclogite (?2.23 ± 0.16‰). The similar εNd(t) values of the whole rocks also support such a point. Zircon O and whole‐rock Nd isotopic compositions are therefore useful to identify the source of fluid, for they are major and trace components in minerals involved in metamorphic reactions during HP‐UHP conditions. On the other hand, the hydrothermal zircon from the veins and the metamorphic zircon from the host eclogite exhibit variable εHf(t) values. Model calculation suggests that the Hf was derived from the breakdown of major rock‐forming minerals and recycling of the inherited magmatic zircon. The variable whole‐rock initial 87Sr/86Sr ratios might be caused by subsequent retrograde metamorphism after the formation of the veins. 相似文献
11.
Yusheng Wan Renwei Li Dunyi Liu Zhenyu Chen Tianrui Song 《Geochimica et cosmochimica acta》2005,69(17):4333-4348
A SHRIMP U-Pb study of zircons separated from an ultrahigh-pressure (UHP) granitic gneiss cobble (sample DS12) from the Upper Jurassic Fenghuangtai Formation of the Hefei Basin, north of the Dabie Orogen, has identified three different domains: (1) cores, some of which show straight boundaries and strong oscillatory zoning, with Th/U ratios of 0.12-0.70 and an imprecise upper intercept age of 777 ± 220 Ma (MSWD = 2.4); (2) mantles, variable in shape and cathodoluminescence (CL) intensity and containing many UHP mineral inclusions, including coesite and omphacite, and with Th/U ratios of 0.02-0.26 and a weighted mean 206Pb/238U age of 244 ± 5 Ma (MSWD = 4.7); and (3) rims, which are more homogeneous and luminescent in CL than the mantles and contain fewer UHP mineral inclusions, with Th/U ratios of 0.01-0.05 and a weighted mean 206Pb/238U age of 226 ± 2 Ma (MSWD = 0.65). Monazites from the same sample do not contain coesite and omphacite inclusions, but they do show sector zones and are composed of two contrasting domains. The light domains in backscattered electron (BSE) images have a Th/U ratio of 7.3-18.9 and a weighted mean 206Pb/238U age of 221 ± 2 Ma (MSWD = 0.94). The dark domains in BSE have a Th/U ratio of 2.8-7.2 and have a weighted mean 206Pb/238U age of 218 ± 2 Ma (MSWD = 0.96). Based on these data and a review of the literature, it can be concluded that (1) the protolith of gneiss sample DS12 is a granitoid of Neoproterozoic age; (2) the ages of 244 and 226 Ma for the mantle and rim domains of the zircons are time records of two discrete stages in the UHP evolution of Dabieshan; (3) the ages of 221 and 218 Ma for the light and dark gray domains, respectively, of the monazites record the times of two stages of retrogressive metamorphism during exhumation of the UHP granitic gneiss to a higher crustal level; (4) the exhumation rate of the gneiss is estimated to be >6 km/Ma; and (5) the UHP metamorphic blocks of the Dabie Orogen provided significant detritus to the Hefei Basin in the Jurassic. 相似文献
12.
S. G. Skublov P. Ya. Azimov X.-H. Li V. A. Glebovitskii A. E. Melnik 《Geochemistry International》2017,55(1):47-59
U-Pb age and isotope-geochemical features were determined for zircon from kyanite gneisses and amphibolites of the Chupa Sequence of the Belomorian mobile belt (BMB) of the Fennoscandian shield. The cores of the zircon from the gneisses marks the Neoarchean events within 2700–2800 Ma known in the BMB, while those of the amphibolites correspond to the age of magmatic crystallization (2775 ± 12 Ma). The inner rims of zircon from the amphibolites and gneisses likely record two different Neoarchean metamorphic events (2650 ± 8 and 2599 ± 10 Ma, respectively). The outer rims record Paleoproterozoic metamorphism with an age of 1890 Ma, which formed the modern appearance and mineral assemblages of the rock association. The value of δ18O in the zircon from the gneiss is 8.6‰ in cores, slightly decreases to 8.0‰ in inner rims, and sharply decreases to 3.9‰ in outer rims. The value of δ18O in the zircon from the amphibolite is around 6.2‰ in cores, increases up to 8.6 in inner rims, and decreases to 5.2‰ in outer rims. A significant decrease of δ18O is likely related to the anomalous composition of Svecofennian metamorphic fluid restricted to local shear zones. The geochemical features of the zircons in combination with their morphology and anatomy make it possible to distinguish zircon generations of different age and change in metamorphic environments. 相似文献
13.
We report SHRIMP U–Pb age of zircons in four samples of eclogite and one sample of orthogneiss from Sulu ultrahigh-pressure (UHP) zone in Yangkou area, eastern China. UHP rocks are distributed along the Sulu orogenic belt suturing North China Block with South China Block. In Yangkou area, UHP unit is well exposed for about 200 m along Yangkou beach section and consists mainly of blocks or lenses of ultramafic rocks and eclogite together with para- and orthogneiss which are highly sheared partly. Zircon grains examined in this study from eclogite show oscillatory zoning and overgrowth texture in CL images, and most of the grains have high Th/U ratio ranging from 0.8 to 2.1 indicating an igneous origin. The weighted mean 206Pb/238U ages of zircons from the four samples range from 690 to 734 Ma. These ages can be correlated to the magmatic stage of the protoliths. In rare cases, zircon grains possess a narrow rim with very low Th/U ratio (< 0.02). EPMA U–Th-total Pb dating of such rim yields younger ages that range from 240 to 405 Ma marking the metamorphic stage. On the other hand, zircons from the orthogneiss show irregular shape and zoning with inclusion-rich core and inclusion-free rim. These grains of zircon yield U–Pb discordia intercept ages of 226 ± 63 Ma and 714 ± 110 Ma (MSWD 0.78). Bulk of the areas of the rims rim of the zircons demonstrate younger 206Pb/238U ages close to the upper intercept, with low Th/U ratio (< 0.20) indicating their metamorphic origin. In contrast, the cores show older 206Pb/238U ages close to lower intercept and high Th/U ratio of (0.14–5.25) indicating their igneous origin. The upper intercept age is also commonly noted in zircons from eclogite. Our results suggest a bimodal igneous activity along this zone during the Neoproterozoic, probably related to the rifting of the Rodinia supercontinent. 相似文献
14.
Based on new evidence the Sulu orogen is divided from south‐east to north‐west into high‐pressure (HP) crustal slice I and ultrahigh‐pressure (UHP) crustal slices II and III. A combined set of mineral inclusions, cathodoluminescence images, U‐Pb SHRIMP dating and in situ trace element and Lu‐Hf isotope analyses was obtained on zircon from orthogneisses of the different slices. Zircon grains typically have three distinct domains that formed during crystallization of the magmatic protolith, HP or UHP metamorphism and late‐amphibolite facies retrogression, respectively: (i) oscillatory zoned cores, with low‐pressure (LP) mineral inclusions and Th/U > 0.38; (ii) high‐luminescent mantles (Th/U < 0.10), with HP mineral inclusions of Qtz + Grt + Arg + Phe + Ap for slice I zircon and Coe + Grt + Phe + Kfs + Ap for both slices II and III zircon; (iii) low‐luminescent rims, with LP mineral inclusions and Th/U < 0.08. Zircon U‐Pb SHRIMP analyses of inherited cores point to protolith ages of 785–770 Ma in all seven orthogneisses. The ages recorded for UHP metamorphism and subsequent retrogression in slice II zircon (c. 228 and c. 215 Ma, respectively) are significantly older than those of slice III zircon (c. 218 and c. 202 Ma, respectively), while slice I zircon recorded even older ages for HP metamorphism and subsequent retrogression (c. 245 and c. 231 Ma, respectively). Moreover, Ar‐Ar biotite ages from six paragneisses, interpreted as dating amphibolite facies retrogression, gradually decrease from HP slice I (c. 232 Ma) to UHP slice II (c. 215 Ma) and UHP slice III (c. 203 Ma). The combined data set suggests decreasing ages for HP or UHP metamorphism and late retrogression in the Sulu orogen from south‐east to north‐west. Thus, the HP‐UHP units are interpreted to represent three crustal slices, which underwent different subduction and exhumation histories. Slice I was detached from the continental lithosphere at ～55–65 km depth and subsequently exhumed while subduction of the underlying slice II continued to ～100–120 km depth (UHP) before detachment and exhumation. Slice III experienced a similar geodynamic evolution as slice II, however, both UHP metamorphism and subsequent exhumation took place c. 10 Myr later. Magmatic zircon cores from two types of orthogneiss in UHP slices II and III show similar mid‐Neoproterozoic crystallization ages, but have contrasting Hf isotope compositions (εHf(～785) = ?2.7 to +2.2 and ?17.3 to ?11.1, respectively), suggesting their formation from distinct crustal units (Mesoproterozoic and Paleoproterozoic to Archean, respectively) during the breakup of Rodinia. The UHP and the retrograde zircon domains are characterized by lower Th/U and 176Lu/177Hf but higher 176Hf/177Hf(t) than the Neoproterozoic igneous cores. The similarity between UHP and retrograde domains indicates that late retrogression did not significantly modify chemical and isotopic composition of the UHP metamorphic system. 相似文献
15.
SHRIMP Dating and Recrystallization of Metamorphic Zircons from a Granitic Gneiss in the Sulu UHP Terrane 总被引：2，自引：2，他引：0
LI HongyanInstitute of Mineral Resources Chinese Academy of Geological Sciences Beijing Geosciences Rennes Universite de Rennes Rennes Cedex France 《《地质学报》英文版》2004,78(1):146-154
An unusual zircon SHRIMP dating result of a granitic gneiss from the Qinglongshan eclogite-gneiss roadcut section is presented in this paper. The very peculiar and complicated internal structures, as well as the very low Th/U ratios (0.01-0.08) of the zircons indicate that they were formed by metamorphic recrystallization. Strongly in contrast with previously published zircon U-Pb ages of the Dabie-Sulu UHP metamorphic rocks where protolith ages of 600-800 Ma are commonly recorded, only metamorphic age of 218±5 Ma, defined by 18 analytical spots either in rim or in core of zircons, are recorded in this granitic gneiss. This age represents the time of the complete metamorphic recrystallization overprint on primary magmatic zircons. The recrystallization was derived by the UHP metamorphism, and was strengthened by the early stage of retrograde metamorphic fluid activity. 相似文献
16.
Pegmatite dikes bearing andalusite crosscut foliation S2 in Alpujarride gneisses and schists. Post‐S2 andalusite is transposed by a foliation S3, defined by fibrolite, which affects the dikes. The dikes represent highly differentiated granitic magmas with low REE and Zr contents and a positive Eu anomaly. U‐Pb SHRIMP dating of magmatic zircons provided Pan‐African ages (cores) and late Variscan ages (rims). However, U‐rich rims also provided metamorphic Alpine ages, supporting a polyorogenic tectonometamorphic history for pre‐Mesozoic Alpujarride rocks. 相似文献
17.
LIU Fulai XU Zhiqin XUE Huaimin ZHOU Kaifu Institute of Geology Chinese Academy of Geological Sciences Bejing 《《地质学报》英文版》2006,80(3):336-348
Laser Raman spectroscopy and cathodoluminescence (CL) images show that most zircon crystals separated from paragneiss in the main drill hole of the Chinese Continental Scientific Drilling Project (CCSD-MH) at Maobei, southwestern Sulu terrane, contain low-pressure mineral-bearing detrital cores, coesite-bearing mantles and quartz-bearing or mineral inclusion-free rims. SHRIMP U Pb dating on these zoned zircons yield three discrete and meaningful age groups. The detrital cores yield a large age span from 659 to 313 Ma, indicating the protolith age for the analyzed paragneiss is Paleozoic rather than Proterozoic. The coesite-bearing mantles yield a weighted mean age of 228 ± 5 Ma for the UHP event. The quartz-bearing outmost rims yield a weighted mean age of 213 ± 6 Ma for the retrogressive event related to the regional amphibolite facies metamorphism in the Sulu UHP terrane. Combined with previous SHRIMP U-Pb dating results from orthogneiss in CCSD-MH, it is suggested that both Neoproterozoic granitic protolith and Paleozoic sedimentary rocks were subducted to mantle depths in the Late Triassic. About 15 million years later, the Sulu UHP metamorphic rocks were exhumed to mid-crustal levels and overprinted by an amphibolite-facies retrogressive metamorphism. The exhumation rate deduced from the SHRIMP data and metamorphic P-T conditions is about 6.7 km/Ma. Such a fast exhumation suggests that the Sulu UHP paragneiss and orthogneiss returned towards the surface as a dominant part of a buoyant sliver, caused as a consequence of slab breakoff. 相似文献
18.
The fate of zircon during UHT–UHP metamorphism: isotopic (U/Pb, δ18O,Hf) and trace element constraints 下载免费PDF全文
下载免费PDF全文 J. Kotková M. Whitehouse U. Schaltegger F.‐X. D'Abzac 《Journal of Metamorphic Geology》2016,34(7):719-739
Garnet–clinopyroxene ultra‐high‐pressure (UHP) rocks from the northern Bohemian Massif contain zircon with micro‐diamond inclusions. Trace element concentrations, oxygen and hafnium isotopic composition and U–Pb age of distinct textural domains in zircon characterize their growth conditions and temporal evolution. Diamond‐bearing zircon mantle domains with relicts of oscillatory zoning have uniform Th/U ratios (~0.1–0.2), high‐Ti contents (110–190 ppm, corresponding to temperatures of at least 1100 °C), and some (two of 17 mantle analyses) preserve steep heavy rare earth element (HREE) patterns with YbN/GdN = 10–11, with a weak negative Eu anomaly. These signatures are consistent with crystallization from a melt under UHP/ultra‐high‐temperature (UHT) conditions. Some of the bright‐cathodoluminscence (CL) rims preserve Th/U and Ti values characteristic of the zircon mantles, but others show elevated Th/U ratios of ~0.3–0.4 and lower Ti contents (20–40 ppm; only 13 ppm in a rare low‐CL outer rim). As they feature flat HREE patterns and negative Eu anomalies and commonly make embayments and truncate the mantle zoning, we suggest that they have formed through recrystallization in the solid state during exhumation of the rock, when both garnet and plagioclase were stable. The three zircon domains, that is, cores, mantles and rims, yield U–Pb concordia ages of 340.9 ± 1.5, 340.3 ± 1.5 and 341.2 ± 3.4 Ma respectively. When linked to the previously reconstructed P–T path of the rock, the error limits of the zircon mantle and rim ages constrain the exhumation of the rocks from depth of ~140 km (UHP) to ~80 km (HP) to a minimum rate of 1.5 cm yr?1. The zircon cores are heterogeneous in terms of Th/U ratio (below 0.1 but also above 0.2) and REE characteristics, and their εHf values scatter between ?15.7 and +4.8 with similar values for individual domains within a single zircon grain suggesting a very localized control on hafnium isotope composition on a grain scale. The non‐equilibrated εHf values as well as a large range of the Hf‐depleted mantle model ages possibly reflect the presence of a heterogeneous population of old zircon. Consequently, the uniform and young 238U/206Pb ages may represent (near‐)complete resetting of the U–Pb geochronometer during the UHP–UHT event at c. 340 Ma through dissolution–reprecipitation process. In contrast to Hf, the oxygen isotope composition of zircon is homogeneous, ranging between 7.8‰ and 9.6‰ VSMOW, reflecting a source containing upper crustal material and homogenization at UHP–UHT conditions. Our study documents that continental crust was subducted to mantle depths at c. 340 Ma during the Variscan orogeny and was subsequently very rapidly exhumed, implying that the sequence of events was faster than can be resolved by the secondary ion mass spectrometry technique. 相似文献
19.
Laser Raman spectroscopy and cathodoluminescence (CL) images reveal that most zircon separated from paragneiss and orthogneiss in drillhole CCSD‐PP2 at Donghai, south‐western Sulu terrane, retain low‐P mineral‐bearing inherited cores, ultrahigh‐pressure (UHP) mineral‐bearing mantles and low‐P mineral‐bearing (e.g. quartz) rims. SHRIMP U–Pb analyses of these zoned zircon identify three discrete and meaningful age groups: Proterozoic protolith ages (> 680 Ma) are recorded in the inherited cores, the UHP metamorphic event in the coesite‐bearing mantles occurred at 231 ± 4 Ma, and the late amphibolite facies retrogressive overprint in the quartz‐bearing rims was at 211 ± 4 Ma. Thus, Neoproterozoic supracrustal protoliths of the Sulu UHP rocks were subducted to mantle depths in the Middle Triassic, and exhumed to mid‐crustal levels in the Late Triassic. The exhumation rate deduced from the SHRIMP data and metamorphic P–T conditions is 5.0 km Ma?1. Exhumation of the Sulu UHP terrane may have resulted from buoyancy forces after slab break‐off at mantle depths. 相似文献
20.
北秦岭地区的早古生代超高压变质作用是整个秦岭-桐柏-红安-大别-苏鲁造山带内最古老的超高压变质记录, 代表华南与华北板块之间最早的一期增生碰撞事件, 然而目前对于该地区早古生代的构造演化过程仍存在较大争议.对北秦岭官坡超高压榴辉岩中的一个长英质脉体开展了详细的锆石形态学、微量元素和U-Pb年代学研究.结果表明, 脉体中的锆石呈自形的棱柱状晶形, 发育弱的振荡环带、面状分带或无明显分带特征, 具有高的HREE、Y、U含量, 低的Th含量和Th/U比值, 说明锆石生长自含水熔体.另外, 这些变质锆石具有LREE亏损、HREE相对富集的配分模式以及明显的Eu负异常, 表明含水熔体形成于角闪岩相退变质过程.锆石的206Pb/238U加权平均年龄为494±10 Ma (MSWD=2.2), 与北秦岭超高压变质作用的峰期年龄(490.4±5.8 Ma)在误差范围内基本一致.北秦岭地体经历深俯冲作用之后发生快速折返, 并在折返过程中发生角闪岩相退变质作用诱发俯冲板片部分熔融产生含水熔体. 相似文献