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1.
黑铜矿氧同位素分馏的理论计算   总被引:1,自引:0,他引:1  
方涛 《地球化学》1996,25(3):221-227
黑铜矿为铜的氧化矿物,对其结构、力场、光谱前人做过较详细的工作。本文在黑铜矿内部力场计算的同位素位移基础上,通过光谱简约配分函数比的计算,得到黑铜矿-水氧同位素分馏方程:10^3lhα=2.51X^2-14.87X+6.31(X=10^3/T)同时,利用Zheng的加和增量模式法对黑铜矿的氧同位素分馏进行了计算,得到如下黑铜矿-水体系的分馏方程:10^3lnα=2.89X^2-13.10X+3.9  相似文献   

2.
白云鄂博矿床独居石氧同位素组成特征及其意义   总被引:1,自引:0,他引:1  
方涛  裘愉卓 《地球化学》1997,26(1):45-53
独居石和氟碳铈矿是超大型稀土矿床-白云鄂博矿床中最主要的稀土矿物。对独居石的氧同位素研究工作国内外开展得很少,本研究对独居石氧同位素制样方法进行了讨论。在计算的独居石-水氧同位素分馏方程:10^3lnα=-0.091-4.224×(10^3/T)+3.896(10^6/T^2)基础上,分析了矿床白云石型矿石和萤石型矿石中独居石的氧同位素组成。独居石δ^18O值的变化范围为3.5‰-11.4‰,其中  相似文献   

3.
研究了新合成的meso-四(2-磺酸萘基)卟啉(TNPS4)与Mn^2+的显色反应。在pH8.0的Na2B4O7-HCl缓冲溶液中,TNPS4与Mn^2+形成稳定的配合物,最大吸收波长470nm,配合物组成为TNPS4:Mn^2+=2:1,表观摩尔吸光系数ε=1.03×10^5L·mol^-1·cm^-1,线性范围0.0-5.0μgMn^2+/25ml。用于化探样品中Mn的测定,结果令人满意。  相似文献   

4.
热液体系中Si的络合作用   总被引:1,自引:0,他引:1  
在不同温度、PH和硅浓度条件下,实验标定了Au-SiO以及Sn-SiO2之间的络合反应:Au^++H3SiO4^-之间的络合反应:Au^++H4SiO=AuH3SiO4 lgK=-1.65436+9611.21/T;Sn^4++4H3SiO4^-=Sn(H3SiO4)4;lgK200c=42.73。通过与Au-Cl、Au-HS以及Sn-OH络合物迁移能力的比较,表明在具地质意义的P睡EH条件下,A  相似文献   

5.
我国首次发现的砷钙锌石和羟砷锌石产于内蒙古自治区额济纳旗老硐沟金矿脉氧化带矿石的空洞中。砷钙锌石多呈半自形或自形晶体,绿或淡绿色,透明,比重4.32(计算)。Ng=1.778,Nm=1.760,Np=1.756,二轴晶(+),2V=46°。化学分子式为Ca0.99(Zn0.94Cu0.07)1.01[(AsO4)0.97(CO3)0.03]1.00(OH),其中(CO3)2-取代部分(AsO4)3-为红外光谱分析所证实,这不同于国外报道的砷钙锌石。据X射线粉末衍射分析的主要谱线,计算得其晶胞参数:a=0.7473nm,b=0.9017nm,c=0.5916nm。羟砷锌石常呈集合体或单个晶体产出,淡黄绿色或无色,透明,比重4.44(计算)。Ng=1.761,Nm=1.738,Np=1.719,二轴晶(+),2V=87°。化学分子式为(Zn1.97Ca0.02)1.99(AsO4)(OH)。据X射线粉末衍射分析的主要谱线,计算得其晶胞参数:a=0.8304nm,b=0.8516nm,c=0.6054nm。氧化矿石的主要矿物组合为:臭葱石+褐铁矿+针铁矿+砷钙锌石+羟砷锌石+自然金+自然银+石英+方解石+蛋白  相似文献   

6.
一种新型高效复合消毒剂:二氧化氯消毒剂虞承伟(地质矿产部山西省中心实验室)1ClO_2为强氧化剂在酸性条件下,ClO_2有很强的氧化性:ClO_2+4H ̄++5e=Cl ̄-+H_2O在水处理条件下(pH=7),ClO_2+e=,E_0=0.95V+2...  相似文献   

7.
唐元骏  谭大芳 《地球科学》1994,19(3):329-336
章介绍了热动力学方法的研究历史,研究原理以及在研究地球化学机制中的应用,如石膏的脱水反应机制可分二步进行,CaSo4.2H2O→CaSO4.1/2H2O→CSO4活化能E=118.7KJ/mol,脱水温度T=380.60,呱应速率K1=4.41×10^-4S^-1方解石的溶解反应机制,在0-5000S期间以溶解反应为主,嗣后,发生周期性的溶解反应,热谱图上表现为化学振荡。  相似文献   

8.
用氧同位素温度计测定了西阿尔卑斯DoraMaira地块含柯石英—镁铝榴石白片岩的峰期变质温度。石英(柯石英较变后)的δ ̄(18)O(8.1‰~8.6‰,n=6),多硅白云母的(6.2‰~6.4‰,n=3)、蓝晶石的(6.1‰,n=2)、石榴石的(5.5‰~5.8‰,n=9)、ellenbergerite的(6;3‰,n=1)和金红石的(3。3‰~3.6‰,n=3)δ ̄(18)O(SMOW)值反映了同位素平衡。以石英—石榴石—金红石分馏为基础测定的温度为700~750℃。以对压力敏感的反应:镁铝榴石+朽石英=蓝晶石十顽火辉石为依据确定的最小压力为3.1~3.2GPa。为了通过对温度敏感的脱水反应:滑石十蓝晶石=镁铝榴石十柯石英十水,来稳定镁铝榴石和柯石英,在700~750℃时,α(H_2O)必须减小到0.4~0。75。当镁铝榴石在x(CO_2)>0.02(T=750℃,P=3.0GPa)不稳定时,α(H_2O)的减少不会是由于CO_2的稀释所引起的。当缺乏较多的外来流体稀释剂(即CH_4或N_2时,就需要有熔体相)。在α(H_2O)=1.O时,花岗岩的固相线温度为680℃/3.0GPa,在α(H_2O)=0.  相似文献   

9.
锌与meso—四(2—磺酸萘基)卟啉显色反应研究   总被引:3,自引:0,他引:3  
研究了新合成的显色剂meso-四(2-磺酸萘基)卟啉与Zn^2+的显色反应。在pH9.40的Na2B4O7-NaOH缓冲体系中,以Hg62+及咪唑共同催化,在室温下8min即反应完全。配合物最大吸收波长为434nm,表观摩尔吸光系数为4.26×10^5L.mol^-1.cm^-1,Zn^2+浓度在0-0.14μg/ml范围内符合比尔定律。配合物组成为TNPS4:Zn^2+=2:1。利用MIBK萃取  相似文献   

10.
李悦 《地球化学》1994,23(4):350-356
从地球化学角度出发,对钱塘江流域的物质平衡关系及起控制作用的化学风化反应进行了探讨和计算。结果表明,降雨提供了河水中大部分的K~+、Na~+和SO~2-_4。另外,灰岩地区碳酸钙的溶解反应提供了河水中大部分的Ca~2+和HCO~-_3,硅酸盐岩地区钠长石和黑云母生成高岭石的风化反应提供了剩余的K~+、Na~+、H_4SiO_4和大部分的Mg~2+及少量的HCO~-_3。石膏和白云石的风化反应控制了SO~2-_4和Mg~2+的平衡,其中碳酸钙的溶解反应占主导地位。流域的化学侵蚀率和机械剥蚀率分别为0.022和0.071(kg·m-2·a-1),碳酸盐岩区的物质流出量是硅酸盐岩区的2倍。  相似文献   

11.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

12.
Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931.  相似文献   

13.
PALEONTOLOGY     
正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.)  相似文献   

14.
正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.)  相似文献   

15.
正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.)  相似文献   

16.
PETROLOGY     
正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus.,  相似文献   

17.
正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an  相似文献   

18.
正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of  相似文献   

19.
正20140582 Fang Xisheng(Key Lab.of Marine Sedimentology and Environmental Geology,First Institute of Oceanography,State Oceanic Administration,Qingdao 266061,China);Shi Xuefa Mineralogy of Surface Sediment in the Eastern Area off the Ryukyu Islands and Its Geological Significance(Marine Geology Quaternary Geology,ISSN0256-1492,CN37  相似文献   

20.
正20141810 Bian Yumei(Geological Environmental Monitoring Center of Liaoning Province,Shenyang 110032,China);Zhang Jing Zoning Haicheng,Liaoning Province,by GeoHazard Risk and Geo-Hazard Assessment(Journal of Geological Hazards and Environment Preservation,ISSN1006-4362,CN51-1467/P,24(3),2013,p.5-9,2 illus.,tables,refs.)  相似文献   

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