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1.
华南奥陶—志留纪之交的五峰组—龙马溪组及华北新元古界下马岭组发现的钾质斑脱岩,都产自类似的黑色硅质-碳质页岩/板岩岩系。这两套黑色岩系与上、下地层的接触关系、岩性组成以及垂向序列所揭示的地质过程,具有良好的可对比性,都符合Ettensohn总结的黑色页岩与板块构造运动之间的成因关系模式。岩石元素地球化学研究表明,这两组不同时代的钾质斑脱岩具有相似的源岩岩浆背景,为中酸性的粗安岩-英安岩-流纹岩系列,源于同碰撞岛弧(synCOL-VA)背景的火山喷发活动,与板块边缘的俯冲碰撞密切相关。由于华南五峰组—龙马溪组内斑脱岩及黑色页岩沉积的形成与此间华夏地块与扬子地块的汇聚相关,华北下马岭组的黑色岩系与钾质斑脱岩的形成可能也和华北地块与相邻地块的碰撞相关。推测后者很可能为Rodinia超大陆或Pangea850Ma汇聚时的沉积-地层学响应。  相似文献   

2.
奥陶-志留交替时期是地球历史时期中的关键时期,该时期华南地区沉积的五峰-龙马溪组黑色页岩是现阶段我国页岩气勘探重点层位,多套斑脱岩存在于黑色页岩内指示该时期经历过多期连续的火山活动。本文选取了四川盆地东部华地1井和武隆黄莺乡五峰-龙马溪组两条剖面点,以黑色页岩和斑脱岩为研究对象,通过野外考察、元素地球化学等分析方法,系统分析了有机质富集的主控因素(陆源输入、古生产力、古氧化还原条件),并在此基础上分析斑脱岩的发育与否与页岩有机质富集间的关系。两剖面点均表明五峰-龙马溪组黑色页岩TOC呈高-低-高模式,氧化还原指标(V/V+Ni、V/Cr、Ni/Co)指示水体经历了厌氧-富氧-厌氧的过程,生产力指标(Cu、Babio、Sibio)、陆源输入指标(Ti/Al、Zr/Al、Th/Al)表明五峰和龙马溪组具较高的生产力和陆源输入,观音桥组较两者均低,三者与有机碳的相关关系反映氧化还原条件对有机质富集作用最大,生产力次之,陆源输入最弱。从斑脱岩发育特征与有机碳、生产力和氧化还原条件的关系看,频繁的火山活动可能对五峰和龙马溪组有机质的保存产生双促作用,一、为海洋提供营养物质,提升其生物生产力;二、火山灰飘落至海水表面阻止了部分光照进入,海底缺氧环境加剧,造成生物大量死亡并落入海底作为有机质埋藏。  相似文献   

3.
安亚运  杨忠琴  向坤鹏  黄艺  陈厚国  贺永忠  刘伟  余谦 《地质论评》2021,67(4):67041105-67041118
奥陶纪—志留纪之交是华南被动大陆边缘盆地向前陆盆地演化的重要转折时期,形成广泛分布的五峰组—龙马溪组黑色页岩。为进一步探讨该套黑色页岩的形成背景,以黔北地区道页1井为例,开展沉积序列和地球化学研究。研究结果表明:五峰组及龙马溪组底部主要为硅质碳质页岩,夹多层斑脱岩,U/Th为0.2~2.90,V/Cr为1.18~14.34,Ni/Co为2.31~11.59,TOC为0.68%~5.91%,平均3.76%,稀土配分曲线为平坦型,δEu以弱正异常为主、个别为弱负异常;龙马溪上部及新滩组主要由泥岩及钙质泥岩组成,U/Th为0.16~0.23,V/Cr为0.88~1.79,Ni/Co为1.77~3.91,TOC为0.1%~0.84%,δEu以明显负异常为主,表现出低斜率右倾型稀土配分曲线。以上特征表明五峰组及龙马溪组底部形成于间歇性缺氧的还原环境,龙马溪组上部及新滩组为富氧环境。结合斑脱岩的分布特征综合分析认为,五峰组及龙马溪组底部页岩是汇聚背景下前陆盆地早期沉积的产物,强烈火山作用给大陆边缘海带来营养元素,刺激初级生产力的增加,造成水体迅速缺氧,可能是造成同期海底缺氧的主要诱因。  相似文献   

4.
扬子板块北缘大巴山地区上奥陶统-下志留统地层中斑脱岩较发育。笔者对大巴山西段陕西紫阳麻柳和四川万源皮窝乡上奥陶统五峰组-下志留统龙马溪组剖面的斑脱岩进行采样,开展了高精度锆石U-Pb测年,首次在该地区获得了445.1±3.5Ma和446.1±7.2Ma的锆石U-Pb年龄,限定了五峰组-龙马溪组地层沉积年龄,为扬子板块北缘大巴山地区奥陶系-志留系界线附近火山喷发事件、地层年代学研究提供了依据。本文所获得的年龄数据与秦岭-大别山造山带奥陶纪岩浆弧形成时间同步,略晚于华北克拉通西南缘奥陶系斑脱岩(449.0~465.8Ma),其火山活动可能与古秦岭洋壳向北的俯冲有关,火山凝灰质可能源自沿古秦岭洋盆北缘的火山弧喷发。中奥陶世晚期至早志留世早期,多幕次的高频火山喷发事件影响了当时海洋化学条件、碳循环波动、气候变冷和生物辐射脉动,造成了晚奥陶世末期的冰川启动和生物集群绝灭。  相似文献   

5.
《地学前缘》2017,(6):300-311
下扬子宁镇地区上奥陶统五峰组—下志留统高家边组沉积了一套良好的黑色烃源岩。本文以江苏句容仑山5号井岩心为研究对象,进行系统的岩相学研究与地球化学分析。该套岩系以黑色页岩夹硅质岩为主,夹多层火山灰薄层,笔石化石丰富。其中,五峰组底部发育钙质、硅钙质页岩,顶部以黑色页岩为主,SiO_2含量最高值82.38%,黑色页岩中存在硅质岩夹层,硅质岩夹层的形成可能与上升流及火山喷发带来的热液有关。高家边组底部与五峰组界限附近主要为黑色页岩。底部非黑色页岩段以粉砂-砂质泥岩与灰白-灰黑色页岩为主。δ~(13)C_(org)在奥陶系—志留系界限附近呈明显负偏移,反映海平面的迅速回升。五峰组与高家边组界限处微量元素氧化还原指标U/Th,V/(V+Ni),V/Cr,Ni/Co,V/Sc指示贫氧-缺氧环境,为有机质的保存提供了有利条件。草莓状黄铁矿的发现也为缺氧环境提供了证据。研究区岩石稀土元素配分型式较平坦,在五峰组和高家边组界限处局部出现Ce负异常,指示还原环境,且在界限附近Eu正异常最为显著,反映热液作用的影响。上奥陶统五峰组黑色页岩段和下志留统高家边组黑色页岩段为深水陆棚沉积,是良好的烃源岩发育区,向上至高家边组非黑色页岩段变为浅水陆棚沉积。五峰组—高家边组黑色烃源岩的形成受到了上升流、热液以及海平面回升等因素的多重影响。  相似文献   

6.
安亚运  杨忠琴  向坤鹏  黄艺  陈厚国  贺永忠  刘伟  余谦 《地质论评》2021,67(2):67030008-67030008
奥陶纪—志留纪之交是华南被动大陆边缘盆地向前陆盆地演化的重要转折时期,形成广泛分布的五峰组—龙马溪组黑色页岩。为进一步探讨该套黑色页岩的形成背景,以黔北地区道页1井为例,开展沉积序列和地球化学研究。研究结果表明:五峰组及龙马溪组底部主要为硅质碳质页岩,夹多层斑脱岩,U/Th为0.2~2.90,V/Cr为1.18~14.34,Ni/Co为2.31~11.59,TOC为0.68%~5.91%,平均3.76%,稀土配分曲线为平坦型,δEu以弱正异常为主、个别为弱负异常;龙马溪上部及新滩组主要由泥岩及钙质泥岩组成,U/Th为0.16~0.23,V/Cr为0.88~1.79,Ni/Co为1.77~3.91,TOC为0.1%~0.84%,δEu以明显负异常为主,表现出低斜率右倾型稀土配分曲线。以上特征表明五峰组及龙马溪组底部形成于间歇性缺氧的还原环境,龙马溪组上部及新滩组为富氧环境。结合斑脱岩的分布特征综合分析认为,五峰组及龙马溪组底部页岩是汇聚背景下前陆盆地早期沉积的产物,强烈火山作用给大陆边缘海带来营养元素,刺激初级生产力的增加,造成水体迅速缺氧,可能是造成同期海底缺氧的主要诱因。  相似文献   

7.
郭旭升 《地球科学》2017,42(7):1069-1082
学者们在页岩层序划分与构成等方面还存在较大分歧;其次,现有研究中针对页岩非均质性在层序格架内的变化特征及成因规律方面亦有不足.五峰组-龙马溪组页岩是上扬子地区重要的页岩气勘探层位之一,通过钻井岩心、露头剖面、常规测井、能谱测井和地球化学参数等资料,对上奥陶统五峰组-下志留统龙马溪组黑色页岩层序地层学进行了定量分析.在五峰组-龙马溪组识别出3个三级层序,其中五峰组为一个三级层序,进一步划分出海侵体系域(五峰组下部黑色页岩)和高位体系域(五峰组上部观音桥段);龙马溪组一段作为一个三级层序,进一步划分出海侵体系域、早期高位和晚期高位体系域;龙马溪组二段和三段为一个三级层序,进一步划分出低位体系域、海侵体系域和高位体系域.以不同体系域为单元分析了五峰组-龙马溪组层序发育与沉积环境特征,揭示了各体系域内古生产力与水体氧化还原条件对有机质富集的控制机理,总结并提出了系统的五峰组-龙马溪组黑色页岩层序地层垂向演化模式.   相似文献   

8.
习科1井是位于黔北习水县良村镇的一口科研勘探井,该钻井由志留系石牛栏组钻至奥陶系涧草沟组。通过对习科1井五峰组—龙马溪组黑色页岩中的笔石进行系统鉴定和生物地层划分,判断该井奥陶纪—志留纪之交地层序列完整连续。该钻井五峰组中可识别出Paraorthograptus pacificus带(WF3),之上见富含腕足类的观音桥层,再向上为龙马溪组黑色页岩,其中自下而上可识别出Metabolograptus?persculptus-Akidograptus ascensus带(LM1—LM2)、Parakidograptus acuminatus带(LM3)、Cystograptus vesiculosus带(LM4)、Coronograptus cyphus带(LM5)和Demirastrites triangulatus带(LM6)。习科1井奥陶纪—志留纪之交笔石生物地层序列基本完整,可与桐梓凉风垭、韩家店对比;而与桐梓红花园、戴家沟不同,后两者缺失了Metabolograptus?persculptus带至Parakidograptus acuminatus带。同时其龙马溪组顶界符合从桐梓向北经习水—綦江,至四川华蓉山依次升高的规律,进一步验证了黔渝地区龙马溪组黑色页岩的"阶段性渐进展布模式"。  相似文献   

9.
元素地球化学在沉积环境判别中发挥重要的作用,尤其是沉积物形成时的氧化-还原环境和底层水体状况。本文对南大巴山上奥陶统五峰组-下志留统龙马溪组泥岩开展了元素地球化学分析,结果表明:临湘组Al2O3含量高于五峰组,五峰组-龙马溪组向上逐渐增加,TiO2和Al2O3具有相似的特征,二者与TOC呈负相关;氧化-还原敏感元素U、V和Mo较为富集,表明沉积时处于缺氧环境,不同剖面不同层位存在两次强烈富集异常,指示其为硫化环境;稀土元素均表现为轻稀土富集、重稀土亏损,略微右倾的稀土元素配分模式,具有明显Eu负异常,其中五峰组-龙马溪组Ce负异常,缺氧环境,栗子坪少数Eu正异常,可能存在热液活动;氧化-还原敏感元素比值、Mo/TOC及MoEF-UEF的协变模式揭示了南大巴山奥陶纪-志留纪之交主体上处于弱滞留贫氧-中等滞留缺氧的开阔海环境,主要受控于海平面升降变化和沉积时古海底地形,局部受北侧秦岭洋盆内洋流影响。  相似文献   

10.
上扬子地区五峰组-龙马溪组黑色岩系是我国南方重要的海相烃源岩,也是目前我国页岩气勘探开发的重要层位之一,前人对其有机质富集因素的综合分析和富集因素之间的关系研究较少.以渝东南武隆地区焦页143-5井为例,对五峰组-龙马溪组下段黑色岩系进行了地层学及古海洋环境的研究,探讨了古气候、火山活动、古海洋生产力和氧化还原特征及其在有机质富集中的作用.研究表明,TOC与强烈火山活动、缺氧古海洋环境、高古生产力和温暖古气候具有良好的正相关关系.这是由于强烈火山作用和陆源化学风化,大大提高了海洋中的营养盐含量,促使生物繁盛、生产力增高,并形成了缺氧硫化、富硅的海洋环境,从而为有机质富集提供了优良的条件.   相似文献   

11.
It is known that high-quality, black-shale source rocks occur in the uppermost Ordovician Wufeng Formation and in the lowermost Silurian Longmaxi Formation in South China. Hence, it is important to understand their lithostratigraphy and the controls on their deposition. A review of lithostratigraphic criteria for subdividing the two adjacent formations provides new regional correlations between the formations and related stratigraphic successions and facies. Both the black shales and the related, overlying flysch deposits at the Ordovician-Silurian transition in South China appear to have migrated northwestward in time and space, reflecting probable flexural control in a foreland basin that developed in response to subduction-type orogeny southeast of the Yangtze block. The black shales also contain K-bentonites from explosive, felsic-intermediate volcanism, the distribution of which also supports orogeny to the southeast. Finally, the analysis of sequence stratigraphy, which shows that the initiation of transgressive system tracts (TST) and condensed section (CS) in the related third-order sequences coincided with the two black-shale horizons respectively, indicates that the main controlling factors for the deposition of the Ordovician-Silurian black shales in South China are (1) northwestwardly migrating, foreland-basin subsidence caused by deformational loading related to episodic accretion of the Cathaysia block to the Yangtze block during this period, and (2) the anoxic, sediment-starved water column caused by rapid rise of the sea-level during the two successive phases of third-order global sea-level rise near the Ordovician-Silurian transition in South China. In future exploration for hydrocarbon source rocks in the area, it is important to consider likely flexural and eustatic causes for subsiding, deep, anoxic seas in recognizing other source rock intervals, and our understanding of the Wufeng and Longmaxi formations may serve as models for future source rock exploration. __________ Translated from Earth Science—Journal of China University of Geosciences, 2007, 32(6): 818–827 [译自: 地球科学—中国地质大学学报]  相似文献   

12.
The K-bentonite, black shale and flysch successions at the Ordovician–Silurian transition in South China have been the subject of comprehensive investigations relative to the probable accretion of the Yangtze Block and the questionable Cathaysia Block. First, the geochemical analyses of K-bentonites show that the parent magma originated in syn-collisional, volcanic-arc and within-plate tectonic settings, which produced mainly intermediate-to-felsic series magmas, associated with continuous collision and subduction of paleo-continental blocks/arcs. Further, the regional distribution of K-bentonite thickness indicates that voluminous explosive volcanism was located in the present southeastern shoreline provinces of China. Secondly, northwestwardly migrating, Ordovician–Silurian, transitional flysch successions, and the accompanying diachronous K-bentonite-bearing black-shale interval, as well as the related, overlying, shallowing-upward succession at the interior of the Yangtze Block, developed as an unconformity-bound sequence that mirrors foreland-basin tectophase cycles in the Appalachian basin. The above features suggest that the sequence accumulated in a similar foreland basin, which formed in response to adjacent deformational loading in a northwesterly migrating orogen located to the southeast. Geochemical and paleocurrent data from the turbiditic flyschoid sandstones also support these depositional settings. Accordingly, it seems that all criteria strongly support the presence of an Ordovician–Silurian, subduction-related orogen resulting from collision with a block to the southeast that must have been the original “Cathaysia Block” of Grabau and later workers. The K-bentonite, black-shale and flysch successions can be regarded as distal, foreland responses to the continuous northwestward collision and accretion of the Cathaysia Block to the Yangtze Block. Hence, we prefer to suggest that the suture zone with the sensu stricto Cathaysia Block probably developed along previously identified late Early Paleozoic suture relicts in the shoreline provinces of southeast China. On the other hand, although accretion of fragments with Cathaysian affinities to the Yangtze Block may have begun as early as Middle to Late Proterozoic time, the Ordovician–Silurian orogeny described above probably reflects the final phase of accretion between the two blocks. Moreover, when combined with similar peri-Iapetan orogenic events in other areas during the same period, this accretion event may have been part of a major stage of global tectonic reconstruction in the evolution of Gondwana.  相似文献   

13.
湖北恩施太阳河奥陶纪-志留纪之交沉积间断的研究   总被引:4,自引:0,他引:4  
依据湖北恩施太阳河灯草坪奥陶系—志留系剖面的生物地层学和岩石学的研究,该剖面的沉积间断发生在Paraorthograptus pacificus带至Coronograptus cyphus带之间,共缺失5个笔石带。奥陶系、志留系之间黏土岩矿物分析显示,在奥陶系、志留系之间出现有高岭土,推断在其间可能上升为陆地。具体演变...  相似文献   

14.
华南扬子地块是我国古热水沉积成矿作用最为发育的地区之一,其热水沉积特性最早引起我国学者的关注。华南下寒武统黑色岩系中赋存多个与热水沉积成矿作用相关的大型、超大型重晶石矿床与N i-Mo-U-V多金属富集层。进一步研究分布在华南扬子地块黑色岩系中的金属、非金属矿床成因及其地球化学特征,对认识华南乃至全球晚震旦—早寒武世生物与环境演化有着十分重要的意义。本文对华南下寒武统镍-钼富集层矿石进行电子探针研究,识别出黄铜矿、黝铜矿等铜的独立矿物;闪锌矿等锌的独立矿物;方铅矿、白铅矿等铅的独立矿物。研究表明,在镍-钼矿石中这些矿物的发现为镍-钼矿层是热水沉积作用产物提供了直接的矿物学证据。  相似文献   

15.
In the transitional period between the Middle and the Late Triassic, the Indochina orogeny caused two tectonic events in South China: (1) the formation and uplift of the Qinling-Dabie orogenic belt along the northern margin of the South China Plate, due to its collision with the North China Plate; and 2) the development of a 1300-km-wide intra-continental orogen in the southeastern part of the South China Plate, which led to a northwestward movement of the foreland thrust-fold zone. These tectonic events resulted in the ending of the Yangtze Platform, and were a stable paleogeographic factor from the Eidacaran to the end of the Middle Triassic. This platform was characterized by the widespread development of shallow-water carbonates. After the end of the Yangtze Platform, the upper Yangtze foreland basin (or Sichuan foreland basin) was formed during the Late Triassic and became a accumulation site of fluvial deposits that are composed of related strata of the Xujiahe Formation. In western Sichuan Province, the Xujiahe Formation overlies the Maantang Formation shallow-water carbonate rocks of the Xiaotangzi Formation siliciclastic rocks (from shelf shales to littoral facies). The sequence-stratigraphic framework of the Upper Triassic in the upper Yangtze foreland basin indicates a particular alluvial architecture, characterized by sequences composed of (1) successions of low-energy fluvial deposits of high-accommodation phases, including coal seams, and (2) high-energy fluvial deposits of low-accommodation phases, including amalgamated river-channel sandstones. The spatial distribution of these fluvial deposits belonging to the Xujiahe Formation and its relative strata is characterized by gradual thinning-out, overlapping, and pinching-out toward both the east and south. This sedimentary record therefore expresses a particular sequence-stratigraphic succession of fluvial deposits within the filling succession of the foreland basin. The sequence-stratigraphic framework for the Upper Triassic in the Upper Yangtze region provides a record of the end of the Yangtze Platform and the formation of the upper Yangtze foreland basin.  相似文献   

16.
二叠纪海平面变化研究   总被引:2,自引:0,他引:2       下载免费PDF全文
在研究全球不同地区二叠纪沉积、层序及生物资料基础上,通过全球诸大陆典型剖面层序划分和对比表明,二叠纪至少有6次海平面升降事件具全球对比意义。二叠纪全球海平面旋回曲线,在不同板块不同成因盆地,其形态及结构不同,但总体可分为两种类型或分支:一是以海相→陆相沉积序列为主的反映主体海平面下降的经典型或欧美型;二是以海相碳酸盐岩→碳酸盐-硅质岩沉积序列为特征的揭示主体海平面上升的特拉斯型或华南型。这与二叠纪特定的全球构造-古地理密切相关。  相似文献   

17.
The Ediacaran and early Cambrian black shales are widespread across the South China Craton (Yangtze and Cathaysia blocks). However, the trace element distribution patterns of the Ediacaran and early Cambrian black shales in the Cathaysia Block are still unclear. In this study, thirty-four black shale samples in the Lechangxia Group (Ediacaran) and thirteen black shale samples in the lower Bacun Group (early Cambrian) from Guangning area, western Guangdong Province, South China, were analyzed for major and trace elements concentrations. Compared to the upper continental crust, the Ediacaran black shales exhibit strongly enriched Se, Ga, and As with enrichment factor values (EF) higher than 10, significantly enriched Bi and Rb (10>EF>5), weakly enriched Mo, Ba, Cs, V, In, Be, Tl, and Th (5>EF>2), normal U, Cr, Cd, Sc, Pb, Cu, and Li (2>EF>0.5), and depleted Ni, Zn, Sr, and Co. Early Cambrian black shales display strongly enriched Se, Ga, and As, significantly enriched Ba, Bi, and Rb, weakly enriched Mo, Cs, Cd, V, U, Be, In, and Tl, normal Sc, Th, Cr, Li, Cu, Ni, and Pb and depleted Co, Zn, and Sr. Moreover, Se is the most enriched trace element in the Ediacaran and early Cambrian black shales: concentrations vary from 0.25 to 30.09 ppm and 0.54 to 5.01 ppm, and averaging 4.84 and 1.72 ppm, with average EF values of 96.87 and 34.32, for the Ediacaran and early Cambrian shales respectively. The average concentration of Se in the Ediacaran black shales is 2.8 times higher than that of early Cambrian black shales. Se contents in the Ediacaran and early Cambrian black shales exhibit significant variation (P = 0.03). Provenance analysis showed that Se contents of both the Ediacaran and early Cambrian black shales were without detrital provenance and volcanoclastic sources, but of hydrothermal origin. The deep sources of Se and the presence of pyrite may explain the higher Se contents in the Ediacaran black shales. Similar with the Se-rich characteristics of the contemporaneous black shales in the south Qingling Mountain and Yangtze block, the Ediacaran and early Cambrian black shales in Guangning area, Cathaysia, are also enriched in Se, which may provide a clue for looking for the selenium-rich resources in western Guangdong Province.  相似文献   

18.
在扬子地块古生界发育了3套区域性的优质烃源岩,即:下寒武统、上奥陶统一下志留统、二叠系(中、上二叠统).下寒武统烃源岩主要由硅质岩(留茶坡组)和上部的硅质泥岩、碳质泥岩(或石煤)(牛蹄塘组)组成.早寒武世在台一盆转换带(或台地边缘)广泛发育的海底热液活动,喷流出大量的富硅流体,使大量硅岩得以在台缘外侧-盆地区沉淀;同时...  相似文献   

19.
Extensive organic-matter (OM) rich facies (black shales) occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections (Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province) straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon (TOC), pyrite sulphur, and different species of Fe, including dithionite-extractable Fe (FED), pyrite Fe (FeP), HCl-extractable Fe (FeH), and total Fe (FeT), in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe (FeHR = FeD + FeP) and FeT, and the FeP/(FeP + FeH) ratio, known as the degree of pyritization (DOP). In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios (0.20-0.77; avg. 0.45), high DOP values (0.21-0.72; avg. 0.54), and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios (0.10-0.35; avg. 0.21), low DOP values (0.11- 0.40; avg. 0.28), and SIC values are clustering on the normal marine value (SIC = 0.36). The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios (0.32-0.49; avg. 0.41), high DOP values (0.46-0.68; avg. 0.53) and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters  相似文献   

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