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1.
Ferrimagnetic minerals in red paleosols of Pleistocene Epoch, eastern China   总被引:1,自引:1,他引:0  
The type,grain size and origin of ferimagnetic minerals separated from red paleosols of pleistocene Epoch(Q2)in eastern China ,were studied by using mineral magnetic measurement,X-ray powder diffraction and electron microscopy.Results showed that the iron oxider in red paleosols were composed of hematite(α-Fe2O3),maghemite(γ-Fe2O3) and goethite(α-FeOOH),Mineral magnetic parameters and X-ray diffraction patterns indicated that maghemite was the dominant remanence carrier in red paleosols,which is characterized by superparamagnetic(SP) and stable single domain(SSD) grains,The variations of magnetic susceptibility(χ) ,anhysteretic magnetic susceptibility(χRAM)and saturation isothermal remanent magnetization(SIRM) for red paleosols following heating to various temperatures showed two peak values at 700℃ and 900℃.The spherulitic magnetic particles measuring 250-1000μm in diameter in red paleosols were separated by the magnetic separation method,indicating that these magnetic particles were an assemblage of superparamagnetic and stable single domain ferrimagnetic grains,It is suggested that the ferrimagnetic minerals of red paleosols be a pedogenic ferrimagnetic component under high temperature and high humid conditions in the Pleistocene Fpoch(Q2).It is concluded that the magnetism characteristics of red paleosols can be used to evaluate the environmental changes of Quaternary in eastern China.  相似文献   

2.
A 1248 m long core (KBH 07, 17°18′07″ N; 73°47′28.2″E, 960m above msl) drilled up to basement in the Deccan traps from Koyna region was sampled at ~10m interval for magnetic mineralogical studies.Analysis of routine rock magnetic parameters (mass specific magnetic susceptibility: χlf, frequency dependence of susceptibility: χfd, susceptibility of anhysteretic remanance: χARM, saturation isothermal remanance: SIRM, remanance coercivty: B(0)CR, SoftIRM, HardIRM, S-Ratio, SIRM/χlf, χARMlf) and density (σ, gm/cc) depicted significant higher order temporal variation. The χlf varies between 13 and 309 x 10-8m3/kg and is independent of density variation. The χARM, B(0)CR and S-Ratios indicate majority of SD-PSD ferrimagnets with episodes of MD ferrimagnetic concentration and few hard coercivity components. The giant plagioclase lath bearing (GPB) horizons show highest variability of ferrimagnetic concentration marked by anomalous peaks. Overall the variability of rock magnetic parameters independent of lava flow units suggest that the changeover in magnetic mineral concentration, composition and domain size occur at major episodes in magma composition (e.g., primary source, crustal contamination and fractional crystallization). The studied parameters are therefore examined to mark intervals of (i) magma compositional changes, (ii) zones of oxidative conditions and (iii) rapid/slow cooling intervals demanding detailed petrologic studies. We identified one I order trend, four II order cycles and eight III order cycles for the purpose of correlation. Notable peak in χlf at 650–700m, the changeover in rock magnetic parameters at ~930 m and ~280 m can facilitate marker intervals while several higher order variations can be adopted for high resolution correlation to other boreholes in the region. The complex variation in rock magnetic parameters independent of flow units reflect temporal magnitudes of compositional variability, cooling and emplacement history that needs detailed petro-mineralogical attempts; and the present data is useful for high order inter-core correlations under the deep drilling program.  相似文献   

3.
A magnetic investigation of a loess/paleosol sequences record in Ili area   总被引:1,自引:0,他引:1  
The pedogenic ferrimagnetic minerals have been considered to be the cause of magnetic susceptibility enhancement in loess deposits distributing in the Chinese Loess Plateau and Central Europe, while “wind intensity” mechanism is proposed to be responsible for the magnetic susceptibility enhancement of loess in Alaska and Siberia. However, the magnetic enhancement mechanism is still open for loess in Ili valley, Xinjiang Uygur Autonomous Region, China. To understand this, we conducted a rock magnetic investigation on Axike section that is located in Ili valley. Results show that transitional stage from magnetic (χlf) trough to magnetic (χlf) peak corresponds to soil units. The PSD and MD-grained magnetite dominate the magnetic properties of AXK sequences, and the main factor affecting magnetic properties is the concentration of ferrimagnetic fraction. For the “pedogenesis enhancement” and “wind intensity” model, it seems hard to explain the magnetic susceptibility enhancement in this area. For the concentration of fine-grained magnetite in magnetic mineral shows positive relationship with the intensity of pedogenesis, the magnetic parameters of loess deposit in Ili valley can be used to recover paleoclimatic variations.  相似文献   

4.
长江中下游第四纪沉积物发育土壤磁性增强的环境磁学机制   总被引:25,自引:2,他引:23  
对长江中下游第四纪沉积物 (Q3 黄土,Q2 红土和Q3 红土 )发育土壤的磁性增强现象及其物理机制进行了讨论。结果表明 :(1)铁磁性矿物是土壤磁性的主要载体,它们是成土过程中形成的稳定单畴 (SSD)和超顺磁性 (SP)态的次生磁性矿物,没有显示重要的反铁磁性矿物的贡献;(2 )土壤磁化率 (χ)的高低与成土过程产生的稳定单畴和超顺磁性颗粒呈极显著正相关,指示了风化成土作用的强度,磁化率可作为反映成土环境变化的代用指标;(3)频率磁化率 (χfd) 5 %可作为土壤中的超顺磁性颗粒存在与否的临界值,土壤 χfd值的高低同样反映了风化成土作用的强度,可用作研究第四纪环境变化的有用工具之一。  相似文献   

5.
Four occurrences of highly magnetic soil in Brazil have been analysed with a view to identifying the magnetic minerals and quantifying the soil magnetization. Techniques used include X-ray diffraction, X-ray fluorescence and Mössbauer spectroscopy. This approach leads us to identify several ways that these soils, which have spontaneous magnetization in the range 1s<35 j/t/kg,="" can="" come="">One soil, which forms on dolerite (19.6 wt% Fe2O3), is found to contain fully-oxidized titanomaghemite inherited from the parent rock. This oxide has a canted ferrimagnetic spin structure with s=36 J/T/kg of sample. The three others, formed on very iron-rich rock (50–90 wt% Fe2O3), contain magnetite or maghemite as the magnetic species and in two cases the soil is more magnetic than the parent rock (largely composed of pure hematite).  相似文献   

6.
The rock magnetic properties of the Chinese loess and paleosols constitute a unique and sensitive record of East Asian paleoclimate through the Quaternary Period. Systematic variations in the concentration and grain size of the magnetic minerals in these sediments have produced systematic variations in the magnetic susceptibility signal, which can be easily and rapidly measured at many sites across the Loess Plateau. Variations in many other rock magnetic properties can be used to identify the key shifts in ferrimagnetic grain size, but magnetic susceptibility alone is sufficiently sensitive to record stadial and interstadial climate stages, as well as glaciations and interglaciations. Past changes in rainfall and monsoon activity for this region are reconstructed from the susceptibility variations. The susceptibility record is calibrated using the modern relationship between rainfall and pedogenic susceptibility on the Loess Plateau. Our rainfall reconstructions identify enhanced summer monsoonal activity in the Chinese Loess Plateau region in the early Holocene and the last interglaciation. In the presently semiarid western area of the plateau, annual precipitation in interglacial times was up to 80% higher than at present; in the more humid southern and eastern areas, values were up to 20% higher than today's levels. During the last glaciation, precipitation decreased across the entire plateau, typically by 25%. The relationship between pedogenic susceptibility, climate, and weathering age was examined over the Northern Hemisphere temperate zone and the observed positive correlation between rainfall and susceptibility indicates that climate, rather than soil age, is the predominant factor that controls pedogenic susceptibility enhancement in loess soils.  相似文献   

7.
Geochemistry of magnetite and maghemite in soils in European Russia   总被引:1,自引:0,他引:1  
A method is proposed for determining the proportions of soluble Fe oxides (magnetite, FeOFe2O3, and maghemite, γ-Fe2O3) based on the measured magnetic susceptibility before and after treatment of soil with the Tamm or Mehra-Jackson (DCB) reagents. The development of hydromorphism in steppe soils in Ciscausiaia is associated with an increase in the magnetite fraction and, consequently, the average magnetite: maghemite ratio increases from 0.8–0.9 to 1.1. In these soils, smectites facilitate magnetite oxidation to maghemite. Soddy-podzolic and dark humic soils in the Cis-Ural region are noted for low values of the magnetite: maghemite ratio (0.5 on average) due to maghemite predominance. Soils in the Cis-Ural region on cover red-earth clays inherit lithogenic Fe oxides: hematite and maghemite. Hydromorphism in humid environments in northern taiga is accompanied by a significant increase in the magnetite: maghemite ratio to 4–9. Some issues of Fe geochemistry in magnetite and maghemite are considered.  相似文献   

8.
Seasonal variation of ground water in Nayagarh district, Odisha is determined by analysing both pre and post monsoon water samples. The high fluoride content is an endemic problem in the area and special attention was attached to the point. The chemical compositions of the ground water of the area are dominated by CaCl, NaCl and mixed CaMgCl types in pre-monsoon and CaHCO3-mixed CaMgCl type in post-monsoon. This is largely due to chemical weathering of Eastern Ghats Mobile Belt rock types. Increasing alkalinity vis-a-vis F concentration in pre-monsoon is associated with sodium-bicarbonate water types having high pH (>7) and low calcium and magnesium contents. The percentage of total high fluoride containing water samples is nearly double in pre-monsoon than in post-monsoon. During both the seasons, pH values indicate mildly alkaline to weakly acidic nature of the water samples. Fluoride concentration has good correlation with pH in pre-monsoon whereas in post-monsoon it shows good correlation with Fe. Facies analysis indicates that water is becoming predominantly Ca-Na cation and Cl-SO4-HCO3 anion type in premonsoon than Ca-Mg type and HCO3-Cl-SO4 type in post-monsoon. The seasonal variations in concentrations of anthropogenic components demonstrate that the groundwater system is very less liable to pollution by human activities.  相似文献   

9.
Mineral magnetic analysis including thermo-magnetic studies and clay mineralogy on bed load and floodplain sediments from the Godavari river indicate distinct mineral assemblages. The floodplain sediments up to the delta region are characterised by unimodal ferrimagnetic mineralogy marked by the presence of maghemite and single domain magnetites derived from Deccan basalts. On the other hand the bed loads show varied magnetic mineral assemblages depicting greater local mixing from the non-basaltic bedrock province. The temperature dependent magnetic susceptibility and clay mineralogy of the floodplain samples show titanomagnetites (Fe3O4-Fe2TiO4), maghemite (χ LF-Fe2O3) and smectite that are characteristic of the Deccan Volcanic Province (DVP). Presence of this ferrimagnetically dominant unimodal assemblage up to the delta region and probably into the Bay of Bengal off the Godavari river is attributed to extensive chemical weathering of the basalt. The quantitative approach of mineral magnetism, therefore, can be used to study the paleomonsoon variability and its relation to Deccan basalt weathering from the Godavari-Bengal fan system.  相似文献   

10.
As the age of the soils in a chronosequence on the California coast increases, the difference between the magnetic susceptibility of eluvial and illuvial horizons increases, and the residual susceptibility after extraction with citrate-bicarbonate-dithionite (CBD) decreases. Enhanced susceptibility results from the conversion of nonferrimagnetic minerals to secondary ferrimagnetic forms (most likely maghemite) and the preferential accumulation of inherited and pedogenic magnetic minerals. Little enhancement occurs for pedons younger than 40,000 yr. By 124,000 yr, most of the magnetic susceptibility can be attributed to forms soluble in CBD. Magnetic susceptibility appears to vary systematically over time for three chronosequences from areas with mean annual precipitation ranging from 650 to 1500 mm yr−1. Magnetic susceptibility enhancement may be a useful parameter for estimating soil age in certain climates.  相似文献   

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