共查询到20条相似文献，搜索用时 78 毫秒
1.
紫木凼金矿床是黔西南卡林型金矿区一个重要的大型金矿床,其成矿物质来源尚不明确.对紫木凼金矿床不同类型矿石和赋矿围岩进行了S、C、O、Pb和Sr同位素组成对比研究.矿石中硫化物的δ34S值为-13.49‰~17.91‰（主要为-0.99‰~3.58‰）,赋矿围岩的δ34S值为-26.23‰~-19.63‰,矿床成矿期硫主要来源于岩浆,部分来源于赋矿地层中成矿前黄铁矿.热液期方解石的δ13C和δ18O分别为-9.10‰~0.59‰和15.65‰~23.82‰,与赋矿围岩、区域地层的碳、氧同位素组成差别较大,成矿流体的碳、氧部分来源于碳酸盐岩溶解,部分可能来源于岩浆.矿石中硫化物的206Pb/204Pb、207Pb/204Pb和208Pb/204Pb比值分别为18.064~18.973、15.585~15.670和38.219~39.054,赋矿围岩的206Pb/204Pb、207Pb/204Pb和208Pb/204Pb比值分别为18.136~18.650、15.574~15.656和38.423~38.812,矿石铅的来源较复杂,赋矿地层和岩浆可能都为其提供了部分铅.矿石中石英和方解石（87Sr/86Sr）i比值为0.707 26~0.708 11,赋矿围岩的（87Sr/86Sr）i比值为0.707 28~0.707 31,成矿流体中的锶主要来源于赋矿地层.紫木凼金矿床成矿物质具壳幔混合来源特征,成矿物质主要来自矿床深部隐伏岩浆岩,部分来自二叠系-三叠系赋矿地层. 相似文献
2.
云南会泽铅锌矿田成矿物质来源：Pb、S、C、H、O、Sr同位素制约 总被引：19，自引：6，他引：19
云南会泽铅锌矿田是我国著名的超大型特富铅锌矿田之一,由相距3公里的矿山厂和麒麟厂两个独立的矿床组成,Zn Pb 金属量超过五百万吨,矿石品位在25%至35%之间。为确定矿床成矿流体和成矿金属来源,本文系统研究了矿床的 Pb、S、C、O、H 和 Sr 同位素组成特征。矿石硫化物的铅同位素组成均一,~(206)Pb/~(204)Pb,~(207)Pb/~(204)Pb 和~(208)Pb/~(104)Pb 的变化范围分别为18.251～18.530,15.663～15.855和38.487～39.433,与围岩碳酸盐岩中浸染状黄铁矿一致,与碳酸盐地层相近,在~(208)Pb/~(204)Pb-~(206)Pb/~(204)Pb 图上显示明显的线性关系,表明铅同位素组成相近的碳酸盐围岩地层提供了成矿物质。矿石硫化物的δ~(34)S 变化范围为10.9‰～17.4‰,多数集中于13‰～17‰,表明还原硫主要来自地层中海相硫酸盐的还原,还原方式为热化学还原,下伏页岩、碎屑岩和泥质岩中的有机质在硫酸盐还原过程中发挥了重要作用。三种不同产状的脉石矿物方解石的碳氧同位素组成均一且没有明显差别,δ~(13)C 变化范围为-2.1‰～-3.5‰,δ~(18)O 为16.8‰～18.6‰。脉石矿物方解石中流体包裹体水的δD_(FI)为-50‰～-60‰,取温度为200℃计算包裹体水的δ~(18)O_(H_2O)值为7.0‰～8.8‰。碳、氧和氢、氧同位素研究结果表明,成矿流体为来自下部上升的变质流体,由于下伏页岩、碎屑岩和泥质岩中有机质的参与,成矿流体具有低的δ~(13)C和δD_(FI)值,在上升过程中与围岩发生了同位素交换。矿石中黄铁矿、闪锌矿和方解石的初始锶同位素组成(~(87)Sr/~(86)Sr)_i值的变化范围为0.714～0.717,赋矿围岩中未蚀变白云岩的初始锶同位素组成(~(87)Sr/~(86)Sr)_i值为0.7083～0.7093,明显低于蚀变白云岩(0.7106),表明成矿流体具有高的(~(87)Sr/~(86)Sr)_i比值。相对围岩碳酸盐岩而言,下伏地层中的页岩、碎屑岩和泥质岩往往具有高得多的~(87)Sr/~(86)Sr,因此,流经或者起源于这些地层的流体具有高的锶同位素比值。 相似文献
3.
胶东蓬莱金成矿区的S-Pb同位素地球化学和Rb-Sr同位素年代学研究 总被引：8，自引：8，他引：8
蓬莱金矿区位于胶东三大金矿带中的栖霞-蓬莱金矿带内。本文系统研究了该金矿化集中区内的黑岚沟、大柳行和河西金矿的 S、Pb、Rb-Sr 同位素地球化学特征,并与招远-掖县成矿带中的玲珑金矿化集中区内的大型-超大型金矿床进行了对比研究。蓬莱金矿区δ~(34)S 值总体变化为6.3‰～9.5‰,平均值为7.5‰。其中河西金矿δ~(34)S 值为7.4‰～8.5‰,黑岚沟金矿δ~(34)S 值为6.3‰～9.5‰,大柳行金矿δ~(34)S 值为6.4‰～8.2‰。不同矿床的硫同位素组成差异十分小,并与玲珑金矿区的硫同位素组成相近(δ~(34)S=6.4‰～8.6‰,平均值为7.6‰)。蓬莱金矿区的铅同位素组成变化小,其中河西金矿~(206)Pb/~(204)Pb 为17.3086～17.4799,~(207)Pb/~(204)Pb 为15.5264～15.5543,~(208)pb/~(204)Pb 为38.0642～38.3698;大柳行金矿~(206)Pb/~(204)Pb 为17.3653～ 17.5037.~(207)Pb/~(204)Pb 为15.5142～15.5355,~(208)Pb/~(204)Pb 为38.1249～38.31 36:黑岚沟金矿~(206)Pb/~(204)Pb 为17.3558～17.5958,~(207)Ph/~(204)Pb 为15.5105～15.5746,~(208)Pb/~(204)Pb为38.0749～38.4361。投影到 Zartman and Doe(1981)铅构造模式图上,成分点落在造山带演化线附近。蓬莱金矿区与玲珑金矿区的铅同位素组成基本一致,部分数据与矿区内煌斑岩的铅同位素组成相近,而与赋矿围岩郭家岭花岗岩相差甚远,表明矿体中的铅可能与煌癍岩有相同的源区。矿石铅呈线性趋势分布,它正好位于煌斑岩与一个极具放射成因铅的胶东群地层的铅同位素组成之间,很可能说明矿石铅是壳幔混合的产物。对蓬莱金矿区黄铁矿的 Rb-Sr 同位素分析结果表明,河西金矿的成矿年龄为122.3±3.1Ma(MSWD=1.7),初始~(87)Sr/~(86)Sr 比值为0.71208;黑岚沟和大柳行金矿的成矿年龄为117.8±6.5Ma(MSWD=17),初始~(87)Sr/~(86)Sr 比值为0.71085。说明蓬莱金矿区具有与玲珑金矿区相近的成矿时代,两者均为120Ma 左右。锶同位素初始比值也说明成矿物质具有壳慢混合的特征。从蓬莱金矿区具有与玲珑金矿区一致的地质、地球化学和年代学特征可知,蓬莱金矿区具有产出大型一超大型金矿的巨大远景。 相似文献
4.
扬子陆块北缘马元铅锌矿床成矿物质来源探讨: 来自C、O、H、S、Pb、Sr同位素地球化学的证据 总被引：7，自引：3，他引：4
呈层状、似层状产于震旦系灯影组角砾状白云岩层间构造带中的马元铅锌矿床是近年来在扬子陆块北缘铅锌找矿的新突破。文章通过碳、氧、氢、硫、铅和锶同位素地球化学特征研究,探讨了成矿流体和成矿金属来源。研究结果表明:矿石中热液脉石矿物的δ13CPDB为-4.24‰~0.93‰,δ18OSMOW为15.92‰~23.24‰,表明成矿流体中的CO2为震旦系碳酸盐岩的溶解成因。矿石中硫化物的δ34S变化于12.94‰~19.4‰之间;硫酸盐矿物的δ34S为32.2‰~33.48‰,表明还原硫主要来自地层中海相硫酸盐的还原。矿石硫化物的铅同位素组成均一,206Pb/204Pb、207Pb/204Pb和208Pb/204Pb分别为17.62~18.02、15.49~15.63和37.57~38.35,成矿金属可能主要来源于震旦系—志留系。脉石矿物石英流体包裹体的δDFI为-92‰和-113‰,如果取成矿温度200℃,根据δ18O石英值计算的相应流体包裹体的δ18O水为6.03‰~12.73‰,推测成矿流体可能起源于大气降水为主的盆地卤水,或为其他来源的流体与有机质反应形成。成矿流体87Sr/86Sr为0.70967~0.71146,高于赋矿围岩震旦系灯影组白云岩锶同位素比值(0.70890~0.70945),表明成矿流体流经了古生代地层(及基底),并与其中具有高锶同位素比值的碎屑岩、页岩和泥岩等进行了水岩反应及同位素交换。 相似文献
5.
华南诸广山花岗岩体中段锶氧铅硫同位素研究 总被引：5，自引：1，他引：5
诸广山中段花岗岩体的Rb-Sr同位素等时线年龄为215.23Ma,属印支期。锶同位素初始比值为0.7229,Rb/Sr比值为1.09～15.6,初始~(206)Pb/~(204)Pb(18.216～19.042)和~(207)Pb/~(204)Pb(15.605～15.801)较高。全岩δ~(18)O为10.6‰～12.4‰,δ~(18)O-~(87)Sr/~(86)Sr相关趋势呈水平方向展布。硫同位素绝大部分在零值左右摆动,从早到晚变化范围逐渐变小。这些表明岩体是源于上地壳的改造型花岗岩,并经过了岩浆阶段,且在早期岩浆岩基础上又经过了多次重熔演化。 相似文献
6.
蓄集矿床是宗务隆构造带内发现的重要银铅矿床。蓄集银铅矿床赋存于石炭-二叠系宗务隆群果可山组灰岩夹千枚岩地层中,矿体呈脉状、透镜状、似层状,明显受近东西走向的断裂构造控制,矿体围岩蚀变主要为硅化和绢云母化,矿石矿物主要为方铅矿和银黝铜矿,脉石矿物主要为石英,矿石具有斑杂状和网脉状构造。对该矿床开展了S-Pb同位素组成分析。硫同位素分析结果表明矿石中硫化物矿物δ~(34)S值变化于5.0‰～8.4‰之间,显示硫主要为岩浆来源,有少量地层的贡献;铅同位素分析结果表明,矿石~(206)Pb/~(204) Pb=17.896～17.922,~(207)Pb/~(204) Pb=15.589～15.617,~(208) Pb/~(204) Pb=38.072～38.166,与围岩铅同位素组成(~(206) Pb/~(204) Pb=17.94～18.976,~(207)Pb/~(204) Pb=15.600～15.696,~(208) Pb/~(204) Pb=38.106～40.943)较为相似,而与蓄集峡口闪长岩铅同位素组成(~(206) Pb/~(204) Pb=18.144～18.589,~(207)Pb/~(204) Pb=15.623～15.636,~(208)Pb/~(204) Pb=38.790～39.033)相差较大,反映成矿物质主要来自围岩地层宗务隆群果可山组。综合分析认为,蓄集银铅矿床与宗务隆构造带晚二叠世岩浆活动关系密切,应属岩浆热液为主的热液充填-交代成因类型。 相似文献
7.
湖南花垣铅锌矿床位于扬子地台东南缘,是湘西—黔东地区最典型的超大型铅锌矿床,已探明铅锌储量超过500×10~4t,其预测资源量逾1800×104t。报道了该矿床主要矿石硫化物的S、)Pb同位素研究成果,结合前人的Sr同位素数据,分析了矿床的成矿物质来源,并探讨了成矿机制。硫化物的δ~(34)S值变化范围较小,为24.5‰~34.7‰,平均值为30.2‰,硫来源于各时代碳酸盐地层中硫酸盐热化学还原作用(TSR),有机质在还原反应过程中发挥了重要作用;硫化物的~(206))Pb/~(204))Pb、~(207)Pb/~(204)Pb、~(208)Pb/~(204)Pb值分别为18.139~18.678、15.691~15.832、38.300~39.255,变化范围较小,具有上地壳来源的特点,赋矿地层下部具有高)Pb-Zn含量的地层为成矿提供了大量的金属物质;闪锌矿的~(87)Sr/~(86)Sr值变化范围为0.70915~0.70996,高于赋矿地层清虚洞组灰岩的Sr同位素比值(0.70885~0.70909),表明成矿流体可能流经围岩及基底地层,从而引起Sr同位素比值因混染作用而升高;矿石矿物的沉淀机制为2种流体的混合,即含金属物质的成矿溶液与富含有机质、硫酸盐的热水溶液在合适的部位汇合,并发生反应。 相似文献
8.
《地球化学》2020,(1)
铧厂沟金矿床赋存于新元古界碧口群细碧岩和泥盆系踏坡群灰岩中。矿体受高角度逆冲断层和韧-脆性剪切带控制,呈似层状、透镜状产出,是南秦岭典型的造山型金矿床。根据赋矿围岩不同,该矿床划分为细碧岩矿带和灰岩矿带。细碧岩矿带矿石中黄铁矿的δ~(34)S值范围为-1.3‰～4.7‰,呈塔式分布,具岩浆硫特征;灰岩矿带矿石中黄铁矿的δ~(34)S值为-14.8‰～1.9‰,离散度强,具有生物成因硫和地层硫的特征。矿石黄铁矿的δ~(34)S值均落入碧口群细碧岩(2.1‰～4.7‰)和踏坡群(-22.5‰～6.6‰)的δ~(34)S值范围,指示硫源主要为碧口群和踏坡群。Pb同位素组成中,细碧岩矿带矿石中黄铁矿~(206)Pb/~(204)Pb、~(207)Pb/~(204)Pb和~(208)Pb/~(204)Pb范围分别为18.017～17.856、15.530～15.585和38.150～38.413,灰岩矿带矿石中黄铁矿~(206)Pb/~(204)Pb、~(207)Pb/~(204)Pb和~(208)Pb/~(204)Pb范围分别为18.202～18.491、15.624～15.659和38.690～39.401。细碧岩矿带矿石黄铁矿与围岩细碧岩全岩的~(206)Pb/~(204)Pb、~(207)Pb/~(204)Pb和~(208)Pb/~(204)Pb值相近,灰岩矿带矿石黄铁矿Pb同位素投影点全部落入踏坡群灰岩地层范围内。以上S和Pb同位素结果表明,铧厂沟金矿床金属物质来源于新元古代碧口群细碧岩及泥盆系踏坡群。 相似文献
9.
青海驼路沟钴(金)矿床成矿物质来源的黄铁矿氦氩硫铅同位素示踪 总被引：2，自引：0，他引：2
为查明青海驼路沟新型独立钴(金)矿床的成因和成矿物质来源,文章对矿区发育的块状、条带状和浸染状黄铁矿矿石进行了黄铁矿流体包裹体氦氩同位素和黄铁矿硫、铅同位素测试。结果表明,不同类型矿石的成矿流体氦、氩同位素组成基本一致,3He/4He介于0.10~0.31Ra(平均0.21Ra),40Ar/36Ar比值为302~569(平均373),反映钴矿化流体主要来源于在赋矿岩系中深循环的大气降水;矿石黄铁矿硫同位素值分布集中且接近于零,δ34S变化于-4.5‰~+1.5‰,集中在-1.8‰~-0.2‰,显示深部来源;矿石铅以高放射性成因为特征(206Pb/204Pb>19.279、207Pb/204Pb>15.691、208Pb/204Pb>39.627),且自地层围岩→区域早古生代火山岩→矿石依次明显增大,可能指示高放射性成因矿石铅主要是由以深循环大气降水来源为主的热液不断从围岩地层中淋取而来。 相似文献
10.
湘南铜山岭铜多金属矿床成矿物质来源的 S、Pb、C同位素约束 总被引：2，自引：0，他引：2
铜山岭铜多金属矿床是湘南W、Sn、Pb、Zn、Cu多金属矿集区的代表性矿床,本文对其不同类型岩石和矿石矿物进行了S、Pb、C同位素组成对比研究。矿石硫化物的δ34 S值变化范围为-1.9‰~5.7‰,平均值为2.6‰,硫主要来源于硫同位素组成均一化的岩浆。硫化物硫同位素平衡温度表明,矿床主要成矿温度为134~339℃。矿石铅的206 Pb/204 Pb、207 Pb/204 Pb、208 Pb/204 Pb比值分别为18.256~18.856、15.726~15.877、38.352~39.430;岩体岩石铅的206Pb/204Pb、207Pb/204Pb、208Pb/204Pb比值分别为18.617~18.805、15.721~15.786、38.923~39.073;两者铅同位素组成相同,都主要为上地壳铅,是由同一岩浆体系分异形成,可能来源于古老基底岩石。不同类型岩石、方解石矿物的δ13 CPDB值为-9.88‰~1.32‰,δ18 OSMOW值为11.67‰~17.68‰,从矽卡岩矿体到距岩体稍远的围岩地层,方解石矿物的δ13 CPDB、δ18 OSMOW值逐渐增大,成矿流体中的碳早期可能主要来源于岩浆,在成矿过程中有部分碳酸盐岩地层碳的加入。铜山岭矿床成矿物质主要来源于岩浆,赋矿地层对矿床成矿物质来源作用不显著,仅提供了少量成矿物质。 相似文献
11.
Adriane Machado Farid Chemale Jr. Rommulo V. Conceio Koji Kawaskita Diego Morata Orlando Oteíza William R. Van Schmus 《Lithos》2005,82(3-4):435-453
Isotope data and trace elements concentrations are presented for volcanic and plutonic rocks from the Livingston, Greenwich, Robert, King George and Ardley islands (South Shetland arc, Antarctica). These islands were formed during subduction of the Phoenix Plate under the Antarctica Plate from Cretaceous to Tertiary. Isotopically (87Sr/86Sr)o ratios vary from 0.7033 to 0.7046 and (143Nd/144Nd)o ratios from 0.5127 to 0.5129. εNd values vary from +2.71 to +7.30 that indicate asthenospheric mantle source for the analysed samples. 208Pb/204Pb ratios vary from 38.12 to 38.70, 207Pb/204Pb ratios are between 15.49 and 15.68, and 206Pb/204Pb from 18.28 to 18.81. The South Shetland rocks are thought to be derived from a depleted MORB mantle source (DMM) modified by mixtures of two enriched mantle components such as slab-derived melts and/or fluids and small fractions of oceanic sediment (EM I and EM II). The isotopic compositions of the subduction component can be explained by mixing between at least 4 wt.% of sediment and 96 wt.% of melts and/or fluids derived from altered MORB. 相似文献
12.
Climatic and hydrologic variability during the past millennium in the eastern Rocky Mountains and northern Great Plains of western Canada 总被引：1，自引：0，他引：1
Modelling of tree-ring δ13C and δ18O data from the Columbia Icefield area in the eastern Rocky Mountains of western Canada provides fuller understanding of climatic and hydrologic variability over the past 1000 yr in this region, based on reconstruction of changes in growth season atmospheric relative humidity (RHgrs), winter temperature (Twin) and the precipitation δ18O-Twin relation. The Little Ice Age (~ AD 1530s-1890s) is marked by low RHgrs and Twin and a δ18O-Twin relation offset from that of the present, reflecting enhanced meridional circulation and persistent influence of Arctic air masses. Independent proxy hydrologic evidence suggests that snowmelt sustained relatively abundant streamflow at this time in rivers draining the eastern Rockies. In contrast, the early millennium was marked by higher RHgrs and Twin and a δ18O-Twin relation like that of the 20th century, consistent with pervasive influence of Pacific air masses because of strong zonal circulation. Especially mild conditions prevailed during the “Medieval Climate Anomaly” ~ AD 1100-1250, corresponding with evidence for reduced discharge in rivers draining the eastern Rockies and extensive hydrological drought in neighbouring western USA. 相似文献
13.
14.
Carbon,sulfur, oxygen and strontium isotope records,organic geochemistry and biostratigraphy across the Permian/Triassic boundary in Abadeh,Iran 总被引：6，自引：0，他引：6
Pelagic deposits at Abadeh represent a complete biostratigraphic record across the Permian/Triassic boundary (PTB). The presumed water depth during deposition of these sediments was between 60 and 90 m. Similar to other Permian/Triassic boundary sections, the succession at Abadeh is characterised by a negative carbon isotope shift of approximately 4. The values start to decrease in the lower C. changxingensis - C. deflecta s.l. Zone, reach –0.12 (V-PDB) in the uppermost Permian just below the PTB, remain low to the early I. isarcica Zone (–0.32) and increase subsequently in the upper I. isarcica Zone. For the time interval of the PTB negative carbon isotope excursion, between the C. iranica and the I. isarcica Zones, no correlation exists between the 13Ccarb and the 18Ocarb. The above observations argue against the conclusion of Heydari et al. (2001) that the carbon isotope event at the P/T transition is an alteration artefact and not a global signal. The decrease in 13Ccarb is accompanied by a ~5 (and potentially up to 10) increase in 34SSSS. Together, these features are thought to reflect a complex global event, notably the development of widespread anoxic oceans with anoxic bottom layers rising onto the shelves. For the carbon isotope drop, other factors, such as the collapse of ocean primary productivity may also have played a role. The 87Sr/86Sr ratios of Dzhulfian seawater show only a minor increase from 0.70705 to 0.70710, reaching 0.70720 in the Dorashamian. The increase becomes steeper in the Early Triassic reaching 0.70754 in the N. dieneri Zone. The rise of the strontium isotope values is thought to be related to enhanced continental weathering under humid climatic conditions in the uppermost Permian (C. meishanensis - H. praeparvus Zone) and the lack of a dense land vegetation in the Early Triassic, prior to the Spathian (Upper Olenekian). 相似文献
15.
Movement of water through the thick unsaturated zone underlying Oro Grande and Sheep Creek Washes in the western Mojave Desert,USA 总被引：1，自引：0，他引：1
Previous studies indicate that a small quantity of recharge occurs from infiltration of streamflow in intermittent streams
in the upper Mojave River basin, in the western Mojave Desert, near Victorville, California. Chloride, tritium, and stable
isotope data collected in the unsaturated zone between 1994 and 1998 from boreholes drilled in Oro Grande and Sheep Creek
Washes indicate that infiltration of streamflow occurs to depths below the root zone, and presumably to the water table, along
much of Oro Grande Wash and near the mountain front along Sheep Creek Wash. Differences in infiltration at sites along each
wash are the result of hydrologic variables such as proximity to the mountain front, quantity of streamflow, and texture of
the subsurface deposits. Differences in infiltration between the washes are the result of large-scale geomorphic processes.
For example, Oro Grande wash is incised into the Victorville fan and infiltration has occurred at approximately the same location
over recent geologic time. In contrast, Sheep Creek Wash overlies an active alluvial fan and the stream channel can move across
the fan surface through time. Infiltration does not occur to depths below the root zone at control sites outside of the washes.
Electronic Publication 相似文献
16.
Li-Sr-Nd isotope signatures of the plume and cratonic lithospheric mantle beneath the margin of the rifted Tanzanian craton (Labait) 总被引：3，自引：2，他引：1
Sonja Aulbach Roberta L. Rudnick William F. McDonough 《Contributions to Mineralogy and Petrology》2008,155(1):79-92
Lithium concentrations and isotopic compositions of olivine and 87Sr/86Sr and 143Nd/144Nd of coexisting clinopyroxene from peridotite xenoliths from the Quaternary Labait volcano, Tanzania, document the influence
of rift-related metasomatism on the ancient cratonic mantle. Olivines show negative correlations between Fo content and both
δ7Li and Li concentrations. Olivines in iron-rich peridotites (Fo85–87) have high Li concentrations (3.2–4.8 ppm) and heavy δ7Li (+5.2 to +6.6). In contrast, olivines in ancient, refractory peridotites have lower Li concentrations (∼2 ppm) and relatively
light δ7Li (+2.6 to +3.5). This reflects mixing between ancient, refractory cratonic lithosphere and asthenosphere-derived rift magmas.
A uniquely fertile, deformed, high-temperature garnet lherzolite, interpreted to be from the base of the lithosphere, has
a 87Sr/86Sr of 0.7029 and 143Nd/144Nd of 0.51286, similar to HIMU oceanic basalts. It provides the best estimate of the Sr–Nd isotope composition of the upwelling
mantle (i.e., plume, sensu lato) underlying this portion of the East African Rift, and is slightly less radiogenic compared
to previous estimates of the plume that were based on rift basalts. Although elevated δ7Li are not exclusive to HIMU source regions, the data collectively indicate that the plume beneath Labait has HIMU characteristics
in Sr, Nd and Li isotope composition.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
17.
Lithological, chemical, and stable isotope data are used to characterize lacustrine tufas dating back to pre-late Miocene and later unknown times, capping different surfaces of a Tertiary carbonate (Sinn el-Kedab) plateau in Dungul region in the currently hyperarid south-western Egypt. These deposits are composed mostly of calcium carbonate, some magnesium carbonate and clastic particles plus minor amounts of organic matter. They have a wide range of (Mg/Ca)molar ratios, from 0.03 to 0.3. The bulk-tufa carbonate has characteristic isotope compositions: (δ13Cmean = −2.49 ± 0.99‰; δ18Omean = −9.43 ± 1.40‰). The δ13C values are consistent with a small input from C4 vegetation or thinner soils in the recharge area of the tufa-depositing systems. The δ18O values are typical of fresh water carbonates. Covariation between δ13C and δ18O values probably is a reflection of climatic conditions such as aridity. The tufas studied are isotopically similar to the underlying diagenetic marine chalks, marls and limestones (δ13Cmean = −2.06 ± 0.84‰; δ18Omean = −10.06 ± 1.39‰). The similarity has been attributed to common meteoric water signatures. This raises large uncertainties in using tufas (Mg/Ca)molar, δ13C and δ18O records as proxies of paleoclimatic change and suggests that intrinsic compositional differences in material sources within the plateau may mask climatic changes in the records. 相似文献
18.
19.
The classic hotspot hypothesis [Morgan, W. J., 1971. Convection plumes in the lower mantle. Nature 230, 42–43], which posits that linear volcanic chains are traces of fixed plumes in the mantle on moving lithospheric plates, was instrumental in elevating the plate tectonics paradigm in the 1960s into a modern Earth Science theory. The hypothesis itself, however, remains conjectural because many of its predictions, particularly the simple age-progressive type of volcanism, are not observed in many linear volcanic chains. As an alternative explanation, it is proposed that linear volcanic chains are formed through magmatism along pre-existing lines of weakness such as transform zones and old sutures, or along cracks created by stresses on lithospheric plates. The Marquesas linear volcanic chain in south-central Pacific has geologic features that are consistent with some of the predictions of both hypotheses. To better constrain the origin of this volcanic chain, we collected major and trace element and Sr, Nd, Pb, and He isotopic data from several Marquesan lavas. Our new analyses combined with literature data classify the samples into the well established tholeiitic to mildly alkalic, low 87Sr/86Sr, high 143Nd/144Nd, shield-building volcanic phase lava group and highly alkalic, high 87Sr/86Sr, low 143Nd/144Nd, post-shield phase group. Lead isotopes show generally higher 206Pb/204Pb ratios and suggest evidence of crustal assimilation for the shield-building phase lavas, consistent with the argument that the shield-building phase volcanism has a lithospheric source component. On the other hand, post-shield phase lavas that are predicted to represent the true composition of the mantle source by the hotspot hypothesis have higher 3He/4He ratios and these are coupled to other geochemical tracers. Thus our results show that the Marquesas volcanic chain, similar to many other linear volcanic chains, has a high 3He/4He component in its mantle source. The presence of such a distinct source component cannot be easily explained by dispersed upper mantle heterogeneities, but provides a powerful constraint for the hotspot origin of many linear volcanic chains. 相似文献