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1.
新疆塔里木西南缘塔木铅锌矿硫同位素特征与成因   总被引:2,自引:1,他引:1  
杨向荣  彭建堂  胡瑞忠  戚华文  刘燊 《岩石学报》2010,26(10):3074-3084
塔木铅锌矿位于塔里木西南缘,为碳酸盐岩容矿型铅锌矿。矿床形成经历了沉积期、成岩期和后生期。沉积期以内碎屑角砾和纹层构造为标志。成岩期以成岩角砾、重结晶白云石为标志。后生期以崩塌角砾、后生角砾及管/脉构造为标志。成矿期介于成岩期和后生期并具有溶蚀-交代和充填两个阶段。细粒闪锌矿和方铅矿多为溶蚀-交代阶段产物。粗粒闪锌矿和方铅矿多为充填阶段产物。本次研究对来自14个标本的沉积期和成矿期51件闪锌矿、方铅矿、黄铁矿和黄铜矿样品进行了硫同位素测试。塔木铅锌矿硫化物硫同位素值具有较大的变化范围。沉积期形成的金属硫化物(δ34SCDT介于-17.6‰~-7.3‰)较成矿期金属硫化物(δ34SCDT介于-5.7‰~+10.2‰)多富集轻硫同位素。充填阶段形成的硫化物(δ34SCDT介于+5.1‰~+10.2‰)较溶蚀-交代阶段硫化物(δ34SCDT介于-5.7‰~+9.2‰)富重硫,并且硫同位素达到平衡。结合地质背景、矿物生成顺序、矿石结构、流体包裹研究资料和硫同位素特征可以得出热化学硫酸盐还原作用(TSR)是成矿期HS-形成的主要机制,含硫有机质热裂解硫也是成矿期硫源之一,溶蚀-交代阶段硫储库效应和硫化物溶度积(Ksp)制约硫同位素值的变化。通过本次研究厘定了塔木铅锌矿矿化形成机制、硫酸盐还原特征和硫的来源,并进一步指出其硫同位素特征支持矿床流体混合成因模型。  相似文献   

2.
胡帷元  单永纲 《贵州地质》1991,8(3):261-268
凯里—黄平地区的灯影组白云岩,是黔东主要找气目的层之一.灯影组碳酸盐灰泥沉积物主要经历了准同生白云化、成岩缝形成、溶蚀作用、新生变形、白云石充填、进油、金属硫化物交代等成岩作用.白云岩的主要储集空间是成岩缝、溶蚀缝、洞的充填后残余空间及各期构造裂缝的充填后残余空间.预计白云岩储集条件的改善主要靠裂缝及其伴生的溶蚀作用.  相似文献   

3.
黄典豪 《矿床地质》1999,18(3):244-252
通过对热液脉型的铅-锌-银矿床(3个)和银矿床(1个)和闪锌矿中硫化物包囊体的特征研究表明,石英-硫化物阶段富铁闪锌矿(主矿物)的硫化物包裹体十分发育:沿生长带产出的乳滴状黄铜矿与主矿物为共同沉淀成因;沿穿切主矿物的黄铜矿或石英细脉两侧,和受粗粒黄铜矿溶蚀的富铁闪锌矿近接触部位发育的乳滴状黄铜矿为渗透-交代产物;沿解理(裂隙)或粒间、粒内产出的各种形态磁黄铁矿是充填-交代的结果;沿解理分布的脉状毒  相似文献   

4.
顾连兴  杨洁 《地质论评》1989,35(4):307-313
华南型块状硫化物矿床层状矿体下盘往往存在着裂隙充填、热液交代和角砾岩矿化形成的不整合矿体,其矿石成分主要有铜-硫和铅-锌两种类型。它们是块状硫化物成矿溶液在海水-岩石界面以下的卸载产物。在找矿工作中应充分重视寻找这类矿体。  相似文献   

5.
郑学正  关鸿 《岩石学报》1996,12(3):424-433
大水清金矿带是华北克拉通中有代表性的改造型绿岩金矿之一。它产于前东武纪绿岩地体中安家营子石英二长岩体内外接触带附近的剪切带中。金矿化交代主要受后阶段张性脆裂控制,而剪切带早阶段韧性剪切作用无明显矿化交代,后者主要为成矿交代提供有益的江游交代构造环,境即成矿交代蚀变作用和剪切带同步的两阶段演化模式。大水清金矿带的交代作用有四个阶段:即用长石化阶段,绿泥石化阶段,黄铁绢英岩化和石英-硫化物阶段以及石英-碳酸盐化阶段。第三阶段由五个亚阶段组成:即黄铁绢英岩化和强硅化-强黄铁矿化,石英-多金属硫化物交代,石英-贫扶矿充填交代和细粒黄铁矿充填交代。其中前四个亚阶段是本区金的主要成矿期.当韧性剪切转化为张性脆裂时产生的骤然扩容和伴随发生的交代体系转变为富硅体系的钾交代和石英-硫化物交代是金矿成矿的关键。本文还研究和探讨了该金矿成矿交代流体的性质及交代的物理化学环境。  相似文献   

6.
峨口铁矿石中的硫化物主要有四种类型,星点状散布于矿石中的硫化物,细脉状硫化物;后期石英脉型硫,包体态硫化物,其结构主要有粒状变晶结构,交代充填结构,港湾状结构,交代残余结构,构造主要为:星点状,脉状,条带状构造,硫化物的形成期分为四期,变质期,变质期后热液,后期热液,表生期。  相似文献   

7.
川西前陆盆地上三叠统须家河组成岩相研究   总被引:8,自引:1,他引:7  
通过成岩分析,将川西前陆盆地须家河组储层分为压实-压溶成岩相、碳酸岩胶结交代成岩相、粘土矿物(伊利石)胶结交代成岩相、绿泥石环边胶结成岩相、不稳定组分溶蚀成岩相和破碎裂缝成岩相、石英次生加大成岩相、有机质充填成岩相等8种单因素成岩相,并从构造、沉积和成岩作用三类储层要素入手分析其成因及展布,在此基础上划分出须家河组综合成岩相。冲断带发育的压实-破碎-硅质胶结成岩相、近前渊三角洲相砂体中发育强压实-溶蚀-绿泥石衬边胶结成岩相和前隆带三角洲相中发育的中压实-溶蚀-绿泥石衬边胶结相均可形成较好的储层。  相似文献   

8.
黄杰 《矿产与地质》1998,12(4):242-245
尖山银铅锌多金属矿床产出受NNE-NE向蚀变破碎带控制,主要矿体产出受钙质千枚岩、大理岩岩性控制,矿化具有明显分带性,矿石类型有含金石英脉型、含银铅锌硫化物型和含银铜硫化物型。矿床成因为岩浆-地层双源的中高温变质(岩浆)热液充填交代成矿。  相似文献   

9.
利用显微薄片、阴极发光、扫描电镜、X射线衍射、电子探针、碳氧同位素等资料,分析了川中东北部中侏罗统沙一段致密砂岩中自生浊沸石产出特征及形成机制。研究表明,沙一段砂岩中自生浊沸石呈连晶状、粒间孔隙充填状和交代产出;阴极发光呈暗棕色或不发光,具有富Si贫Al的特征。早期浊沸石主要呈连晶状,形成于同生期-早成岩A期,由斜长石水化及钠长石化形成;中-晚期浊沸石主要呈粒间孔隙充填和交代状,形成于早成岩B期-中成岩A2期,主要为斜长石的钠长石化、富Ca~(2+)溶液中钠长石的蚀变形成。浊沸石整体溶蚀极弱,对储集层物性改善意义不大,仅在局部裂缝较发育的区域溶蚀较强,对储集层物性有一定改善作用。  相似文献   

10.
阿舍勒块状铜-锌硫化物矿床产于中泥盆统阿舍勒组以英安质为主的钙碱性火山岩系中.矿化发生于中酸性火山喷发活动行将结束的阶段.矿床受岩性、火山穹丘和断裂控制.成矿物质主要来自火山岩浆热液、火山岩及海水.矿液主要由岩浆水和海水组成.矿床的形成经历了火山喷发沉积期、热液沉积充填期和矿床变质期.矿床是海底火山作用形成的热液沉积-交代充填成因的块状硫化物型矿床,可与黑矿型矿床对比.  相似文献   

11.
Fluorite mineralization at the La Nueva and Bubu mines yields Sm-Nd ages of 131 ± 22 and 117 ± 26 Ma, respectively. Thus, the mineralization most probably is related to a late Gondwanian (Lower Cretaceous) extensional and magmatic event that affected the Sierras Pampeanas basement during the opening of the Atlantic Ocean. Hydrothermal fluids involved in the formation of the fluorite probably were of meteoric origin, their isotopic composition (Sr and Nd) resulting largely from the incongruent dissolution of feldspars in the host porphyritic granites.  相似文献   

12.
含矿流体混合反应与成矿作用的动力平衡模拟研究   总被引:7,自引:0,他引:7  
林舸  CBZHAO  王岳军  BEHOBBS  龚纪文 《岩石学报》2003,19(2):275-282
本文在约定热液体系中成矿元素成矿速率(成矿过程中单位时间内单位体积所合成矿元素重量的变化)的基础上。借助于物质-热-化学-成矿四重全耦合的研究思路,构建了均匀热液体系、层状热液体系、岩浆侵入热液体系下成矿元素的迁移、富集、溶解与沉淀作用数值模型。模拟结果表明;(1)硫化物(H2S)和硫酸盐(SO42-)流体的混合反应是成矿热液体系中铅、锌、铁成矿元素成矿的重要控制因素;(2)均匀介质、岩浆侵入或地质构造的存在,对成矿元素在成矿流体运移的速度、流线、温度分布和成矿元素的溶解与沉淀分布都有着各自的特征.不同的成矿环境或成矿背景制约了成矿元素的迁移与富集以及矿体的产出定位。暗示成矿环境及成矿速率对热液体系中成矿元素的沉淀与溶解具重要作用;成矿流体的混合反应是成矿作用发生的重要机制之一。在成矿理论研究中必须充分考虑不同地质构造因素的约束。  相似文献   

13.
The Cambrian Bonneterre Dolomite of south-eastern Missouri, USA, hosts the large Mississippi Valley type (MVT) lead-zinc-copper ore deposits of the region. The Bonneterre Dolomite consists of dolomitized algal bioherms, oolitic grainstone and associated lithologies that were deposited on a carbonate platform surrounding the Precambrian age St Francois Mountains. Porosity was determined by point counting thin sections from cores and mines in the Bonneterre Dolomite and by gas porosimetry. Volumes of epigenetic cements were estimated by point counting cement filling micro- and mesoporosity using cathodoluminescence. Cement volumes were added to present porosity to estimate porosities during various stages of mineralization. Prior to the onset of mineralization, micro- and mesoporosity in the Bonneterre Dolomite averaged approximately 19%. Precipitation of early dolomite cement (roughly concurrent with the main period of sulphide deposition) reduced average porosity to approximately 7% and closed off much of the intercrystalline pore space. Later cementation by dolomite (prior to late stage sulphides) reduced porosity to approximately 5%, and late cementation by quartz further reduced porosity to the present average value of <4%. Periods of carbonate dissolution during MVT mineralization enhanced large scale megaporosity associated with fractures and breccias but did not significantly increase smaller scale porosity. Dolomite cementation associated with MVT mineralization, porosity and permeability were facies controlled. Today, as a result of mineralization, large scale fractures and breccias control porosity and permeability. This study indicates that dolomite porosity may undergo significant change during basinal brine migrations associated with MVT mineralization.  相似文献   

14.
成矿流体动力学的原理、研究方法及应用   总被引:3,自引:0,他引:3       下载免费PDF全文
流体流动是热液成矿作用不可或缺的一部分,其研究是建立成矿模式的重要组成部分。成矿流体动力学主要研究流体流动的驱动力、压力状态、流速、流动方向以及它们与矿床定位的关系。文中总结了成矿流体动力学的基本原理和方法,并对其在成矿作用研究和矿产勘查上的重要性和局限性进行了讨论。流体流动的驱动力可以是流体的超压、地势差、构造变形以...  相似文献   

15.
The Pb-Zn-ores of Minas de Cartes, Sierra de Cartagena, Spain, occur in a zon along the lower boundary of a Miocene sequence and along post-Miocene faults. Pebbly mudstone beds in the Miocene are slump sediments, which by their lithological properties form preferred horizons for the spreading of the mineralization. Faulting and flexuring have caused cavernous fault breccias in the relatively competent pebbly mudstones, while dissolution of carbonate pebbles and carbonates in the matrix of these rocks has resulted in solution cavities. The brecciated cavernous pebbly mudstones form channelways for ore solutions and sites of deposition of ore streaks with marcasite, pyrite, galena, sphalerite and quartz. The mineralization is of typical cavity-filling nature and so-called “ore pebbles” are fillings of pebble-shaped voids resulting from selective dissolution of carbonate pebbles. The ores were formed by near-surface subvolcanic-hydrothermal processes in relation with Late Tertiary trachyandesitic volcanism in the region.  相似文献   

16.
构造成矿非线性动力学:2.湘西金矿研究实例   总被引:1,自引:0,他引:1  
应用递增应力流变学方法对湘西沃溪金矿成矿过程中构造变形、应力、流体流动、地球化学反应及成岩成矿作用等多过程间的耦合作用和非线性特征进行了模拟和分析。构造压溶作用对矿源层中成矿物质的溶解与迁移起了重要作用。断裂作用可以产生比原岩渗透率高近4个数量级的断裂渗透率,从而促进流体的流动、组分扩散和在断裂中的汇聚成矿。不同岩性对断裂作用和断裂渗透率的演化有重要影响,并且构造、流体、岩石之间存在强烈的非线性耦合作用,马底驿组中段是最有利的构造成矿层位。  相似文献   

17.
Shallowly plunging and branching pipe systems in Lease and Bobbejaankop Granite at the Zaaiplaats mine are host to major tin mineralization. Detailed textural study of Maggs Pipe indicates that dissolution of the granite was a major process in the formation of open space which provided permeability for the passage of hydrothermal fluids, and sites for the precipitation of ore and gangue minerals. The pipe formation process initiates with the dissolution of granite quartz and subsequently extends to feldspar dissolution, particularly in the central portion of Maggs Pipe. Spaces created by mineral dissolution are filled by hydrothermal phases and the relict feldspar matrix becomes progressively more altered toward the centre of the pipe. The distribution of alteration and infill minerals defines a zoning pattern which, from the outer margin to the central core, includes calcite-quartz, chlorite (± cassiterite, albite, fluorite) and synchisite-calcite zones. It is postulated that quartz and feldspar dissolution resulted from interaction between the granite and hydrothermal fluids containing alkali-chloride, -fluoride or -carbonate complexes which had separated from the granite magma during crystallization. Preliminary observations on several other pipes at Zaaiplaats indicate that quartz and feldspar dissolution was a major procress in forming the pipe systems.  相似文献   

18.
巴都希贾乌铜金矿是坐落在印度尼西亚松巴岛西南部的世界级的斑岩型铜金矿床,产于岛弧环境。从容矿岩石、矿化、蚀变、成矿流体等方面分析总结了该矿床的基本特征。矿床在岩浆组合、空间形态和矿化及围岩蚀变特征上均体现出了明确的斑岩型矿床的特征;矿区围岩蚀变可划分为四个阶段,与成矿关系最为密切的是第一阶段的黑云母化;成矿流体为相对低温高盐度的流体,且具有由深到浅石盐溶解温度升高的趋势。  相似文献   

19.
江西相山铀矿田西部地区实施的铀矿科学深钻3号孔在深部-700 m发现大量铅锌多金属矿化脉,垂向上呈"上铀下多金属"的分布特征。文章对深部多金属矿化进行了详细的矿物学和矿石组构学研究,并对其成因进行了探讨。研究表明,矿石结构主要有中细粒及微粒结构、自形晶粒状结构、他形晶粒状结构、填隙结构、包含结构、镶边结构、固溶体分离结构、碎裂结构、环带结构等;矿石构造主要有脉状构造、细脉状构造、条带状构造、角砾状构造、致密块状构造、稠密浸染状构造等。矿化类型主要有石英-毒砂-黄铁矿(锡石、黄铜矿)型、黄铁矿型、闪锌矿-方铅矿-黄铁矿型、闪锌矿-方铅矿-碳酸盐(菱铁矿-方解石)型,在空间上具有明显的分带性。根据矿物组合和穿插关系,矿化过程经历了成矿前期的碱性流体作用,形成矿前期绿泥石、锡石和金红石。铅锌成矿期经历了石英-毒砂阶段、黄铁矿化阶段、铅锌矿化阶段、铅锌银碳酸盐阶段等多期叠加。成矿后期以形成碳酸盐-石英脉为特征。综合分析认为,相山深部多金属矿化具有浅成、中低温特征,是与次火山岩有关的低硫化型浅成中低温热液多金属矿化。目前已经发现的铅锌多金属矿化很可能是深部矿化的一个端员,深部很有可能存在与成矿有关的次火山岩体,且具有寻找斑岩型多金属矿化的成矿潜力。  相似文献   

20.
Groundwater is the most important source of water supply in the Yeniceoba Plain in Central Anatolia,Turkey.An understanding of the geochemical evolution of groundwater is important for the sustainable development of water resources in this region.A hydrogeochemical investigation was conducted in the Plio-Quaternary aquifer system using stable isotopes(δ~(18)O andδD),tritium(~3H),major and minor elements(Ca,Na,K,Mg,Cl,SO_4,NO_3,HCO_3 and Br)in order to identify groundwater chemistry patterns and the processes affecting groundwater mineralization in this system.The chemical data reveal that the chemical composition of groundwater in this aquifer system is mainly controlled by rock/water interactions including dissolution of evaporitic minerals,weathering of silicates,precipitation/dissolution of carbonates,ion exchange,and evaporation.Based on the values of Cl/Br ratio(300 mg/l)in the Plio-Quaternary groundwater,dissolution of evaporitic minerals in aquifer contributes significantly to the high mineralization.The stable isotope analyses indicate that the groundwater in the system was influenced by evaporation of rainfall during infiltration.Low tritium values(generally1 tritium units)of groundwater reflect a minor contribution of recent recharge and groundwater residence times of more than three or four decades.  相似文献   

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