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1.
Understanding the nature of parental melts for pyroxenite veins in supra-subduction zone(SSZ) ophiolites provides vibrant constraints on melt infiltration processes operating in subduction zones. The Zedang ophiolitic massif in the eastern Yarlung–Zangbo suture zone in Tibet consists of mantle peridotites and a crustal section of gabbro, diabase, and basalt. Veins of two pyroxenite varieties cut the southern part of the Zedang massif. These pyroxenite rocks have different geochemical characteris...  相似文献   

2.
The>2000 km Indus-Yarlung Tsangpo suture zone(IYSZ)is composed of the Neo-tethys oceanic remnants,flysch units and related continental rocks,which has been regarded as the boundary between the Eurasian and Indian terranes.Among the ophiolitic complexes,the Purang ophiolite is the biggest massif in the IYSZ,and many studies have been conducted on this ophiolite.However,previous studies have mainly focused on harzburgite,clinopyroxenite and dunite.Field observations show that mafic dykes were emplaced within the Purang ophiolite.However,petrogenetic evolutions of those mafic dykes are poorly understood.In this study,we present new LA-ICP-MS zircon U-Pb dating results,whole-rock geochemistry and Sr-Nd-Hf isotope analyses for microgabbro,gabbro and dolerite dykes from the Purang ophiolite of the southwestern IYSZ,respectively.Three samples yielded zircon U-Pb ages of144.2±2.1 Ma.127.9±2.3 Ma and 126.5±0.42 Ma,suggesting two different phases of magmatic activities distinctly.Whole-rock geochemical results suggest that the gabbro samples show alkaline features marked by enrichments of light rare earth elements(LREE)and large-ion lithophile elements(LILE),as well as Nb-Ta elements,suggesting an oceanic island basalt-like(OIB-like)geochemical affinity.However,the dolerite and microgabbro samples demonstrate sub-alkaline characteristics with normal mid-oceanic ridge basalt-like(N-MORB-like)geochemical features.Three distinct mafic dykes show significant Rb element depletion.The geochemical data and Sr-Nd-Hf isotopic features suggest that the microgabbro and gabbro rocks were derived from a depleted mantle that had been metasomatized by partial melts of sediments and enriched slab-derived fluids.The dolerite was also originated from a depleted mantle marked by significantly depleted Sr-Nd-Hf compositions,which was not influenced by enriched slab-derived fluids and sediments contamination during subsequent evolution.The isotope and geochemical data and tectonic diagrams suggest a tectonic transition from a within-plate to a midoceanic ridge basalt-like(MORB-like)setting during the period from ca.144 Ma to 127 Ma.Combined with regional background and this study,we propose that these mafic dykes were formed in an oceanic back-arc basin setting.Additionally,integrated with previous studies,we suggest that the geodynamic evolution of the southwestern and central parts of the Neo-Tethys oceanic basin is comparable in Early Cretaceous.  相似文献   

3.
The Jinghong mafic–ultramafic complex, exposed in the eastern margin of the Lancangjiang tectonic belt, is related to the subduction of the Paleo-Tethys Ocean. Its petrogenesis plays a key role in constraining the tectonic evolution of the eastern Paleo-Tethys Ocean in southwestern China. In this study, we present petrological, geochemical and geochronological results of the Jinghong complex rocks, in order to decipher their origin and tectonic significance. The Jinghong mafic–ultramafic complex was composed of peridotite, gabbro, basalt and minor plagiogranite. Whole-rock geochemical data of the mafic rocks indicate that they have both MORB and IAB affinities and plot in the back-arc basin basalt (BABB) field in the FeO*/MgO vs. TiO2 diagram. Combined with their trace element characteristics, it can be concluded that the Jinghong mafic–ultramafic complex represents an ophiolite suite that was formed in a back-arc ocean basin. Precise LA-ICP-MS zircon U-Pb dating yielded weighted mean 206Pb/238U ages of 298.4 ± 1.7 Ma, 294.3 ± 1.6 Ma, and 292.8 ± 2.0 Ma for gabbroic rocks from this complex, which indicates that the Jinghong ophiolites were formed during the early Permian (298–293 Ma). We propose that during subduction of the main Paleo-Tethys Ocean, a back-arc ocean basin was formed at the east of the Lancangjiang tectonic belt.  相似文献   

4.
Located in the northern part of the Xinlin–Xiguitu suture zone,geochemistry and geochronology of the Xinlin ophiolite provide a unique opportunity to determine the the evolution of the eastern Xing’an–Mongolian Orogenic Belt.The Xinlin ophiolite was initially constrained roughly 21.5 km southeast of the Xinlin town by the First Regional Geological Survey Party of Heilongjiang Province.Subsequent work has shown that the mafic and ultramafic rocks in the adjacent Tayuan town was congenetic with the Xinlin ophiolite(Fig.1).Over the past three years we have conducted a series of studies to the Xinlin ophiolite with the aim to better understand its characteristic and tectonic implications.The present work is is to provide our preliminary geochemical data of the mafic rocks of the Xinlin ophiolite and possible"congenetic"mafic rocks in the Tayuan town.The mafic rocks of the Xinlin ophiolite including the gabbro,diabase and metabasalt show flat REE pattern[(La/Yb)N=0.68~1.58]and no Eu anomalies,which are transitional between normal and enriched mid-ocean ridge basalts(N-MORB and E-MORB).They also exhibit flat patterns from Ba to Yb in the trace elements spider diagram,which lie between those of typical E-MORB and N-MORB but closer to the former.The mafic rocks in the Tayuan town consist mainly of hornblende gabbro with alkaline affinity and are characterized by enriched in light rare earth elements and large ion lithophile elements,depleted in heavy rare earthelements and high field strength elements(Fig.2).The obvious differences in the geochemical characteristics indicate that the mafic rocks in the Tayuan town may not be cogenetic with those of the Xinlin ophiolite.This was further corroborated by their different formation time.Our zircon U–Pb dating indicates that the gabbro in the Tayuan town was emplaced during the late Carboniferous(~310 Ma;Fig.3),significantly younger than the recently reported U–Pb ages for the mafic rocks of the Xinlin ophiolite(~510 Ma;Feng,2015).Therefore,the two units appear as independent bodies and their origin and tectonic implication need to be further examined.  相似文献   

5.
The Zedong ophiolites in the eastern Yarlung–Zangbo suture zone of Tibet represent a mantle slice of more than 45 km~2. This massif consists mainly of mantle peridotites, with lesser gabbros, diabases and volcanic rocks. The mantle peridotites are mostly harzburgite, lherzolite; a few dike-like bodies of dunite are also present. Mineral structures show that the peridotites experienced plastic deformation and partial melting. Olivine(Fo89.7–91.2), orthopyroxene(En_(88–92)), clinopyroxene(En_(45–49) Wo_(47–51) Fs_(2–4)) and spinel [Mg~#=100×Mg/(Mg+Fe)]=49.1–70.7; Cr~#=(100×Cr/(Cr+Al)=18.8–76.5] are the major minerals. The degree of partial melting of mantle peridotites is 10%–40%, indicating that the Zedong mantle peridotites may experience a multi–stage process. The peridotites are characterized by depleted major element compositions and low REE content(0.08–0.62 ppm). Their "spoon–shaped" primitive–mantle normalized REE patterns with(La/Sm)_N being 0.50–6.00 indicate that the Zedong ultramafic rocks belong to depleted residual mantle rocks. The PGE content of Zedong peridotites(18.19–50.74 ppb) is similar with primary mantle with Pd/Ir being 0.54–0.60 and Pt/Pd being 1.09–1.66. The Zedong peridotites have variable, unradiogenic Os isotopic compositions with ~(187)Os/~(188)Os=0.1228 to 0.1282. A corollary to this interpretation is that the convecting upper mantle is heterogeneous in Os isotopes. All data of the Zedong peridotites suggest that they formed originally at a mid-ocean ridge(MOR) and were later modified in supra–subduction zone(SSZ) environment.  相似文献   

6.
The Central Asian Orogenic Belt(CAOB) resulted from accretion during the Paleozoic subduction of the PaleoAsian Ocean. The Xilinhot area in Inner Mongolia is located in the northern subduction zone of the central-eastern CAOB and outcropped a large number of late Paleozoic mafic intrusions. The characteristics of magma source and tectonic setting of the mafic intrusions and their response to the closure process of the Paleo-Asian Ocean are still controversial. This study presents LA-ICPMS zircon U-Pb ages and geochemical features of mafic intrusions in the Xilinhot area to constrain the northward subduction of the Paleo-Asian Ocean. The mafic intrusions consist of gabbro, hornblende gabbro, and diabase. Their intrusion times can be divided into three stages of 326–321 Ma, 276 Ma and 254 Ma by zircon U-Pb ages. The first two stages of the 326–276 Ma intrusions mostly originated from subduction-modified continental lithospheric mantle sources that underwent a variable degree partial melting(5–30%), recording the subduction of oceanic crust. The third stage of the 254 Ma mafic rocks also show arc-related features. The primary magma compositions calculated by PRIMELT2 modeling on three samples of ～326 Ma and two samples of ～254 Ma show that these mafic samples are characterized by a variable range in SiO_2(47.51–51.47 wt%), Al_2O_3(11.46–15.55 wt%), ΣFeO(8.27–9.61 wt%), MgO(13.01–15.18 wt%) and CaO(9.13–11.67 wt%), consisting with the features between enriched mantle and lower continental crust. The source mantle melting of mafic intrusions occurred under temperatures of 1302–1351°C and pressures of 0.92–1.30 GPa. The magmatic processes occurred near the crust-mantle boundary at about 33–45 km underground. Combined with previous studies, it is concluded that Carboniferous to early Permian(～326–275 Ma) northward subduction of the Paleo-Asian oceanic crust led to the formation of the mafic magmatism in the Baolidao arc zone. The whole region had entered the collision environment at ～254 Ma, but with subduction-related environments locally. The final collision between the North China craton and the South Mongolian microcontinent may have lasted until ca. 230 Ma.  相似文献   

7.
The Yarlung Zangbo Suture Zone(YZSZ)in southern Tibet includes the remnants of Neotethyan oceanic lithosphere and marks a major suture between the Indian Plate to the south and the Lhasa Terrane of Tibet to the north(Dupuis et al.,2005;Yang et al.,2011).In the western part of the YZSZ,the Northern and the Southern sub-belts form two sub-parallel zones of mafic–ultramaficrockassemblageswithoverlapping crystallization ages(Xiong et al.,2011;Hebért et al.,2012;Liu et al.,2015).The upper mantle section of the Cuobuzha ophiolite in the northern sub-belt of the Yarlung–Zangbo Suture Zone(YZSZ)in SW Tibet comprises mainly clinopyroxene(cpx)–rich and depleted harzburgites.Spinels in the cpx-harzburgites show lower Cr#values(12.6–15.1)than the spinels in the harzburgites(26.1–34.5),and the cpx-harzburgites display higher heavy rare earth element concentrations than the depleted harzburgites.The harzburgites have subchondritic Os isotopic compositions(0.11624–0.11699),whereas the cpx-harzburgites have suprachondritic 187Os/188Os ratios(0.12831–0.13125)with higher Re concentrations(0.380-0.575 ppb).The cpx-harzburgites plot in a Re vs.Al2O3 diagram as a result of subsequent addition of Re following the last partial melting event that occurred during mid-ocean ridge melt evolution processes(Uysal et al.,2015).Although these geochemical and isotopic signatures suggest that both peridotite types in the ophiolite represent mid-ocean ridge type upper mantle units,their melt evolution trends reflect different mantle processes.The cpx-harzburgites formed from low-degree partial melting(~5%)of a primitive mantle source,and they weresubsequently modified by melt–rock interactions in a mid-ocean ridge environment.The depleted harzburgites,on the other hand,were produced by re-melting of the cpx-harzburgites,which later interacted with MORB-or island arc tholeiite(IAT)-like melts(Fig.1)possibly in a trench-distal backarc spreading center.Our new isotopic and geochemical data from the Cuobuzha peridotites confirm that the Neotethyan upper mantle had highly heterogeneous Os isotopic compositions as a result of multiple melt production and melt extraction events during its seafloor spreading evolution.  相似文献   

8.
The Spontang Ophiolite complex represents the most complete ophiolite sequence amongst the South Ladakh ophiolites and comprises mantle rocks(depleted harzburgites,dunites and minor lherzolites)as well as crustal rocks(basalt,isotropic gabbros,layered gabbros etc.).In the present study,detailed geochemistry(whole rock as well as mineral chemistry)and Sr-Nd isotopic analyses of thirty-six ultramaficmafic samples have been attempted to constraint the evolution and petrogenetic history of the Tethyan oceanic crust.Major,trace-element and REE patterns of the peridotites and their minerals indicate that the lherzolites experienced lower degrees of partial melting resembling abyssal peridotites(at higher temperatures,TREE=$1216℃)than the harzburgites(6%–8%versus 15%–17%).Elevated eNd(t)and variable87 Sr/86 Sr(t)ratios along with REE patterns suggest that the Spontang mafic rocks display N-MORB affinity with negligible participation of oceanic sediments in their genesis are originated from a depleted upper mantle with little contribution from subduction-related fluids.MORB-type Neotethyan oceanic crust is associated with the earliest phase of subduction(of older Jurassic age)through which a younger intra-oceanic island arc(Spong arc)subsequently developed.Harzburgites REE display typical U-shaped patterns,suggesting that these rocks have been metasomatized by LREE-enriched fluids.On the other side,mafic rocks are characterized by heterogeneous(Nb/La)PMand(Hf/Sm)PMand relatively homogeneous eNd(t),indicating interaction of subduction-related melts with the upper mantle during the initiation of subduction,in Early Cretaceous times.  相似文献   

9.
There is a general consensus that most ophiolites formed above subduction zones(Pearce,2003),particularly during forearc extension at subduction initiation(Shervais,2001;Stern,2004;Whattam and Stern,2011)."Supra-Subduction zone"(SSZ)ophiolites such as the well-studied Tethyan ophiolites,generally display a characteristic sequential evolution from mid-oceanic ridge basalts(MORBs)to island arc tholeiities(IATs)or bonites(BONs)(Pearce,2003;Dilek and Furnes,2009,2011),which were generated in sequence from the decompression melting of asthenospheric mantle and partial melting of subduction-metasomatized depleted mantle(Stern and Bloomer,1992;Dilek and Furnes,2009;Whattam and Stern,2011).However,ophiolites with MORB and/or oceanic-island basalt(OIB)affinities are rare,and their origin and tectonic nature are poorly understood(Boedo et al.,2013;Saccani et al.,2013).It is interesting that the composition of these ophiolites from the central Tibetan Plateau(CTP)is dominated by MORBs and minor OIBs and a distinct lack of IATs and BONs,which is inconsistent with most ophiolites worldwide(Robinson and Zhou,2008;Zhang et al.,2008).But the generation and tectonic nature of these ophiolites are still controversial.*In this study,we present new geochronological,mineralogical and Sr-Nd isotopic data for the Chayong and Xiewu mafic complexes in the western Garzê-Litang suture zone(GLS),a typical Paleo-Tethyan suture crossing the CTP(Fig.1).The Triassic ophiolite in the western GLS has been described by Li et al.(2009),who foundthat it mainly consists of gabbros,diabases,pillow basalts and a few metamorphic peridotites.The ophiolite has been tectonically dismembered and crops out in Triassic clastic rocks and limestones as tectonic blocks.The Chayong and Xiewu mafic complexes are generally regarded as important fragments of the Triassic ophiolites(e.g.,Jin,2006;Li et al.,2009).Zircon LA-ICP-MS U-Pb ages of234±3 Ma and 236±2 Ma can be interpreted as formation times of the Chayong and Xiewu mafic complexes,respectively.The basalts and gabbros of the Chayong complexexhibitenrichedMORB(E-MORB)compositional affinities except for a weak depletion of Nb,Ta and Ti relative to the primitive mantle,whereas the basalts and gabbros of the Xiewu complex display distinct E-MORB and OIB affinities.The geochemical features suggest a probable fractionation of olivine±clinopyroxene±plagioclase as well as insignificant crustal contamination.The geochemical and Sr-Nd isotopic data reveal that the Chayong mafic rocks may have been derived from depleted MORB-type mantle metasomatized by crustal components and Xiewu mafic rocks from enriched lithosphericmantlemetasomatizedbyOIB-like components.The ratios of Zn/Fet,La/Yb and Sm/Yb indicate that these mafic melts were produced by the partial melting of garnet+minor spinel-bearing peridotite or spinel±minor garnet-bearing peridotite.We propose thatback-arcbasinspreadingassociated with OIB/seamount recycling had occurred in the western GLS at least since the Middle Triassic times,and the decompression melting of the depleted MORB-type asthenospheremantleandpartialmeltingof sub-continental lithosphere were metasomatized by plume-related melts,such as OIBs,which led to the generation of the Chayong and Xiewu mafic melts.  相似文献   

10.
The Dangqiong ophiolite, the largest in the western segment of the Yarlung-Zangbo Suture Zone(YZSZ)ophiolite belt in southern Tibet, consists of discontinuous mantle peridotite and intrusive mafic rocks. The former is composed dominantly of harzburgite, with minor dunite, locally lherzolite and some dunite containing lenses and veins of chromitite. The latter, mafic dykes(gabbro and diabase dykes), occur mainly in the southern part. This study carried out geochemical analysis on both rocks. The results show that the mantle peridotite has Fo values in olivine from 89.92 to 91.63 and is characterized by low aluminum contents(1.5–4.66 wt%) and high Mg# values(91.06–94.53) of clinopyroxene. Most spinels in the Dangqiong peridotites have typical Mg# values ranging from 61.07 to 72.52, with corresponding Cr# values ranging from 17.67 to 31.66, and have TiO2 contents from 0 to 0.09%, indicating only a low degree of partial melting(10–15%). The olivine-spinel equilibrium and spinel chemistry of the Dangqiong peridotites suggest that they originated deeper mantle(20 kbar). The gabbro dykes show N-MORB-type patterns of REE and trace elements. The presence of amphibole in the Dangqiong gabbro suggests the late-stage alteration of subduction-derived fluids. All the lherzolites and harzburgites in Dangqiong have similar distribution patterns of REE and trace elements, the mineral chemistry in the harzburgites and lherzolites indicates compositions similar to those of abyssal and forearc peridotites, suggesting that the ophiolite in Dangqiong formed in a MOR environment and then was modified by late-stage melts and fluids in a suprasubduction zone(SSZ) setting. This formation process is consistent with that of the Luobusa ophiolite in the eastern Yarlung-Zangbo Suture Zone and Purang ophiolite in the western Yarlung-Zangbo Suture Zone.  相似文献   

11.
Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N2 in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.  相似文献   

12.
在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明：玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。  相似文献   

13.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

14.
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15.
马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。  相似文献   

16.
岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...  相似文献   

17.
填海工程使滨海地区的地下水物理化学条件改变,导致该区域地下水中重金属浓度升高。本文以深港西部通道填海区为例,采用实验室模拟填海条件的办法,初步探讨了影响填海区地下水重金属迁移的关键因素。模拟实验结果表明,填海区地下水中钨元素含量升高与地下水淡化、淤泥氧化过程以及填料风化有关;铜元素含量升高则与淤泥氧化过程以及填料风化有关;钒元素含量升高与地下水淡化和淤泥氧化过程有关,而其他元素含量升高则主要与填料风化释放有关。  相似文献   

18.
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19.
This paper explores the hypothesis that chromite seams in theStillwater Complex formed in response to periodic increasesin total pressure in the chamber. Total pressure increased becauseof the positive V of nucleation of CO2 bubbles in the melt andtheir subsequent rise through the magma chamber, during whichthe bubbles increased in volume by a factor of 4–6. Byanalogy with the pressure changes in the summit chambers ofKilauea and Krafla volcanoes, the maximum variation was 0•2–0•25kbar, or 5–10% of the total pressure in the Stillwaterchamber. An evaluation of the likelihood of fountaining andmixing of a new, primitive liquid that entered the chamber withthe somewhat more evolved liquid already in the chamber is basedupon calculations using observed and inferred velocities andflow rates of basaltic magmas moving through volcanic fissures.The calculations indicate that hot, dense magma would have oozed,rather than fountained into the chamber, and early mixing ofthe new and residual magmas that could have resulted in chromitecrystallizing alone did not take place. Mixing was an important process in the Stillwater magma chamber,however. After the new magma in the chamber underwent {smalltilde}5% fractional crystallization, its composition, temperature,and density approached those of the overlying liquid in thechamber and the liquids then mixed. If this process occurredmany times over the course of the development of the Ultramaficseries, a thick column of magma with orthopyroxene on its liquiduswould have been the result. Thus, the sequence of multiple injections,fractionation, and mixing with previously fractionated magmacould have been the mechanism that produced the thick bronzitecumulate layer (the Bronzitite zone) above the cyclic units.  相似文献   

20.
The mineral composition of the Talatui gold deposit has been studied with modern methods. Previously unknown minerals (ilmenite, siegenite, glaucodot, wittichenite, matildite, hessite, pilsenite, zircon, tremolite, cummingtonite, hercynite, and goethite) have been identified in the ore. A high Re content has been detected in molybdenite. The spatiotemporal separation of Au and Ag is caused by different mineral species of these elements and their diachronous precipitation during the ore-forming process. Gold crystallized along with early mineral assemblages, beginning from virtually pure gold (the fineness is 996). Silver precipitated largely at the end of the process as hessite (Ag2Te) and matildite (AgBiS2). The temperature of ore deposition varied from 610 to 145°C, the pressure was 3370–110 bar, and the salt concentration ranged from 56.3 to 0.4 wt % NaCl equiv. The heterogeneous state (boiling) of fluid at the early stages has been documented. The chemical and isotopic compositions of the fluid testify to its magmatic nature and the participation of meteoric water at late stages in the ore-forming process. Thermodynamic modeling reproduces the main specific features of ore formation, including separation of Au and Ag. A physicochemical model of the gold mineralization in the Darasun ore district has been proposed. On the basis of several attributes, the Talatui deposit has been referred to the prophyry gold-copper economic type.  相似文献   

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