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1.
Inductively coupled plasma mass spectrometry, inductively coupled plasma optical emission spectroscopy, hydride generation-atomic fluorescence spectrometry, emission spectrometry, X fluorescence spectrometry, and X-ray diffraction were employed to study the geochemistry and mineralogy of coal gangues from Nos. 2, 3, and 8 coal seams of the Du’erping coal mine, Xishan coalfield, Taiyuan, Shanxi Province. The study revealed that compared with the sedimentary cover, upper continent crust, Carboniferous-Permian coal from North China, as well as most coal in China, coal gangues from Nos. 2 and 3 coal seams are rich in Li, Be, Sc, Cr, Cu, Ga, Ba, Th, Nb, Cd, Pb, Ta and rare-earth elements, and coal gangues from No. 8 coal seam are rich in Li, Sc, V, Cr, Ga, U, and rare-earth elements. Compared with the Carboniferous-Permian coal from North China and most coal in China, coal gangues from Nos. 2, 3 and 8 seams are rich in Rb, V, Cs and Sr. Therefore, The Du’erping coal gangues in the Xishan coalfield are rich in most hazardous trace elements and rare-earth elements, wherein the contents of Ga and Li reach the industrial grade and have significance for industrial utilization. On the whole, coal gangues of the Shanxi Formation from the Permian are rich in more trace elements than those of the Carboniferous Taiyuan Formation. The distributions of REE show obviously dipping rightwards with negative Eu anomalies. The contents of rare-earth elements in the three seams are quite different. All of the above indicate that the source of the rare-earth elements is terrigenous debris. Minerals in No. 2 seam identified by X-ray diffraction mainly include quartz, kaolinite, in addition to calcite, pyrite, apatite, epidote, and epsomite. No. 3 seam mainly contains quartz, kaolinite, in addition to a small amount of sodium feldspar, calcium nitrate, iron ore, gypsum, and vivianite. No. 8 seam mainly contains kaolinite, dickite, quartz, illite, and a small amount of hematite and U. The correlations between major elements and trace elements in coal gangues of the Du’erping coal mine analyzed by using SPSS (Statistical Product and Service Solutions) indicate that the trace alkali elements and rare-earth elements occur mainly in such clay minerals as kaolinite. 相似文献
2.
V. Z. Khilimonyuk G. P. Pustovoit M. V. Filatova 《Moscow University Geology Bulletin》2011,66(3):207-212
A quantitative estimate of the influence on the temperature mode of perennially frozen rocks in the Pechorsk coal basin caused
by pollution of the surface by coal dust was undertaken. 相似文献
3.
Zhong Jianhua 《沉积学报》1997,15(1):128-134
Little is known about the geochemistry of peat and soft-brown coal The analytical chemical dataof forty eight samples have been obtained for the peat and soft-brow n coal in the 7henan basin, western Yunnan. njection of continental detritus into theswamp is favourable for the degradation of plant remains and thefor-oration of humic acid. The oxide compositions of the ash of the peat and soft一)rown coal and their distribution-typeshave indicated that the continental detritusome from two kinds of parent rocks.The Al2O3 and SiO2have a positive correlation with humic acid(Hmz)，showing that the organic matter is ad-vantageous to the formation of aluminosilic;ate mineral(mainly kaolinite, authigenic organic clay minerals). The TiO2 enrichment is mainly related to mineral materials. The Ge content in the peat and soft-brown coalranges from 0. 2- 2.6×10-6, and it is mainly bound to those minerals with Al2O3and organic matters. The GaContent is from 2. 3- 19.1×10-6，and it is associated with minerals that are MgO一Baring aluminosilicate minerals.The uranium (0.3- 4.9×10-6) is mainly bound in the Ca-and Mg-bearing minerals. They are not enriched andnot related to organic matter. 相似文献
4.
The Peoples' Republic of China produces and consumes the largest quantity of coal in the world; about 2.19 billion tons of coal were produced in 2005. It is estimated that coal consumption will reach 7 billion tons by 2020. Although the nationwide percent… 相似文献
5.
The Tabaco anticline is a 15 km long, south plunging, east-vergent anticline in northern Colombia, close to the transpressional collisional margin between the Caribbean and South American plates. In the Cerrejón open-cast coal mine, systematic mapping of coal seams in the middle to upper Paleocene Cerrejón Formation has yielded an exceptional dataset consisting of 10 horizontal slices (sea level to 90 m elevation, regularly spaced at 10 m intervals) through the anticline. Coal seams and fault traces in these slices are used to construct a 3D model of the anticline. This 3D model shows tighter folds within lower coal seams, NW-vergent thrusts and related folds on the gentler western limb, and strike-slip faults on the steeper eastern limb. Fault slip-tendency analysis is used to infer that these two faulting styles resulted from two different stress fields: an earlier one consistent with thrusting and uplift of the Perijá range, and a later one consistent with strike-slip faulting (Oca, Ranchería and Samán faults). Our preferred interpretation is that the anticline developed its eastern vergence during the early stages (late Paleocene-early Eocene) of tilting of the Santa Marta massif. Later NW-vergent thrusting on the western limb (early to middle Eocene) was related to western propagation of the Perijá thrust system. These results contribute to the understanding of the structural evolution of the area. They are also a good example of the complex interplay between detachment folding, thrusting, and strike-slip faulting during the growth of a km-size fold in a transpressive setting. 相似文献
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Harvey E. Belkin Susan J. Tewalt Robert B. Finkelman Baoshan ZHENG Daishe WU Shehong LI Jianming ZHU Binbin WANG 《中国地球化学学报》2006,25(B08):52-52
The Peoples＇ Republic of China produces and consumes the largest quantity of coal in the world; about 2.19 billion tons of coal were produced in 2005. It is estimated that coal consumption will reach 7 billion tons by 2020. Although the nationwide percentage of electrical production from coal is falling due to increased coal-fired power generation efficiency and alternative sources, China will bum more coal than any other country for the foreseeable future. China also is estimated to be the largest producer of Hg emissions （Dastoor and Larocque, 2004, Atmos. Envirn. 38：147-161）. A recent comprehensive study of anthropogenic Hg emissions in China （Streets et al., 2005, Atmos. Envirn. 39：7789-7806） produced a figure of 536 tons of Hg for the year 1999 with coal combustion （all types） accounting for 38% of the total. Atmospheric Hg emission is an international problem as the upper atmosphere provides effective global transport of mercury. Although the estimates vary, China produces about three times more Hg/t of coal burnt than the USA because of the lack of modem technology for pollution control and limited use of cleaned coal. Knowledge of the mercury content, mode of occurrence, and regional distribution in Chinese coal is vital in order to assess the global atmospheric contribution from Chinese coal combustion. 相似文献
8.
This paper examines the influence of sorbed gas type and pressure on the strength of coal. Particular attention is focused on the influence of gas type and pressures on drillability characteristics of coal and particle size distribution of drill cuttings. Drillability of coal has a strong bearing on the strength properties of coal. Based on fracture mechanics and mechanical rock cutting, weaker rocks are easier to drill and the drill cuttings produced are generally coarse in size. Accordingly a specially designed precision drill was used to drill coal samples under both normal atmospheric and confined gas pressure conditions. Indications of changes to coal strength as a result of increased sorbed gas pressure were examined by analysing the particle size distribution of the drill flushing. A laser controlled Malvern Mastersizer S particle size analyser with measuring range between 0.05 m and 900 m was used to study the particle size distribution. This paper demonstrates that there is a definite variation in the range of particle size distribution with particles obtained from drilling coal samples not subjected to gas pressures in comparison with those obtained from samples drilled under confined gas pressure. Gas types also have an influence. Higher proportions of coarse particles were produced when the confined gas was changed from CH4 to CO2. A change in the rate of drilling under varying confining pressure and gas type was also evident. The rate of drilling in air (at normal atmospheric conditions) was slower than at higher confining pressures. The highest drill rates were obtained with CO2 confinement. 相似文献
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《中国地球化学学报》2006,(Z1)
With increasing use of coal, the growing impact on the environment from potentially hazardous trace elements becomes a great concern. Southwestern Guizhou, China, is a typical area of endemic arsenosis related to coal combustion. The use of locally mined,… 相似文献
11.
《中国地球化学学报》2006,(Z1)
The spatial distribution of major, minor and trace elements in a coal basin is important for exploitation strategy and for the understanding of processes of coal formation and diagenesis. The 35400 km2 intermontane Powder River Basin, NW USA, is a major s… 相似文献
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《中国地球化学学报》2006,(Z1)
The geochemistry theory can provide information about the distribution, contents and migration in nature of the chemical elements in minerals, rocks. soils, waters, atmospheres, etc. Therefore, it has been applied extensively. Nowadays the petroleum suppl… 相似文献
14.
Characterization of coal reservoirs and determination of in-situ physical coal properties related to transport mechanism are complicated due to having lack of standard procedures in the literature. By considering these difficulties, a new approach has been developed proposing the usage of relationships between coal rank and physical coal properties. In this study, effects of shrinkage and swelling (SS) on total methane recovery at CO2 breakthrough (TMRB), which includes ten-year primary methane recovery and succeeding enhanced coalbed methane (ECBM) recovery up to CO2 breakthrough, and CO2 sequestration have been investigated by using rank-dependent coal properties. In addition to coal rank, different coal reservoir types, molar compositions of injected fluid, and parameters within the extended Palmer & Mansoori (P&M) permeability model were considered. As a result of this study, shrinkage and swelling lead to an increase in TMRB. Moreover, swelling increased CO2 breakthrough time and decreased displacement ratio and CO2 storage for all ranks of coal. Low-rank coals are affected more negatively than high-rank coals by swelling. Furthermore, it was realized that dry coal reservoirs are more influenced by swelling than others and saturated wet coals are more suitable for eliminating the negative effects of CO2 injection. In addition, it was understood that it is possible to reduce swelling effect of CO2 on cleat permeability by mixing it with N2 before injection. However, an economical optimization is required for the selection of proper gas mixture. Finally, it is concluded from sensitivity analysis that elastic modulus is the most important parameter, except the initial cleat porosity, controlling SS in the extended P&M model by highly affecting TMRB. 相似文献
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DING Xiaozhong GUO Xianpu PENG Yang JI Yunlong WANG Yineng Institute of Geology Chinese Academy of Geological Sciences Beijing China University of Geosciences Beijing Northwestern Bureau of Petroleum Geology SINOPEC Urumqi 《Continental Dynamics》2001,(2)
1. IntroductionThe Tarim basin, one of the most developed and important areas of marine Cretaceous-Tertiary in China except for south Tibet, is very rich in oil and gas, such as Kekeya oilfield in southwestern Tarim and Kela2 gas field in northeastern Tarim. Because of the expansion, subduction of the oceanic crust of the Tethys and the collision between the India plate and the Eurasia plate during the Cretaceous-Tertiary, the Tethys transgressed into the Tarim basin from west to east fr… 相似文献
17.
The research area that is in the north of Istanbul (Turkey) and it is a land of open pit coal mining residuals reclaimed and turned to forest in 1988–1989. The materials that are open pit mine spoils are formed by sandy loam, sandy clay loam, heavy loam and clay (noncalcareous Pliocene I sediments). Pseudoacacia (Robinia pseudoacacia), Maritima Pine (Pinus pinaster) and Stone Pine (Pinus pinea) are planted on these materials. The aims of this research were to determine the strength of the material provided by tree roots and evaluate the performance of the forestation practices at lands especially where open pit coal mining spoil (residual) materials piled up. The research has been performed at two stages. The first one was hydro-mechanical effect concerned about material moisture depletion as a result of transpiration and the second one was bio-mechanical effects due to strength parameters of the roots and their growth pattern within the material. All results were evaluated in relation to tensile strength and displacement curves due to pre and post failure behaviors of materials and root systems. The results showed the increase of the displacement of the material was the significant indicator of the bio-mechanics tensile strength of the material provided by the tree roots. The fast growing type of tree roots have stabilized the material up to a depth for 80–100 cm by covering the coal residual materials within 12 years. 相似文献
18.
Hongfu SUN Fenghua ZHAO 《中国地球化学学报》2006,25(B08):26-27
In this study, geochemical characteristics of acid mine drainage （AMD） and its sediments from the Malan and Sitai coalmines, Shanxi Province, China, were investigated. Many analytical approaches such as IC, ICP-MS, XRD, XRF, and modeling calculation of hydrogeochemistry using PHREEQCI software were employed. The AMD is characterized by higher concentrations of iron and sulfate, a low pH, and elevated concentrations of a wide variety of heavy metals. The results of modeling calculation by PHREEQCI software demonstrate the metals in AMD are present mainly as Me^n＋ and MeSO4^n-2 species. The sediments of AMD are composed mainly of iron-beating minerals such as goethite and schwertmannite, which are controlled by pH, Fe and SO4^2- concentrations. The schwertmannite mineral has been found for the first time in China. 相似文献
19.
L. J. Phillips J. L. Crowley D. J. Mantle J. S. Esterle R. S. Nicoll J. L. McKellar 《Australian Journal of Earth Sciences》2018,65(2):153-173
This study presents the first chemical abrasion-isotope dilution thermal ionisation mass spectrometry (CA-IDTIMS) U–Pb zircon ages from tuffs in Lopingian (upper Permian) strata of the Galilee Basin, Queensland and reassigns the B coal-seam to the ‘Burngrove Formation equivalent.’ Five Lopingian tuffs were dated: four from the CRD Montani-1 drill hole including three from the ‘Fair Hill Formation equivalent’ (255.13 ± 0.09, 254.41 ± 0.07 and 254.32 ± 0.10 Ma) and one from the ‘Burngrove Formation equivalent’ (252.81 ± 0.07 Ma, approximately the age of the Yarrabee Tuff in the adjacent Bowen Basin); and a single tuff from the Black Alley Shale in the GSQ Tambo-1-1A drill hole (254.09 ± 0.06 Ma). In the Galilee Basin, all three units are constituents of the Betts Creek Group, here formally elevated in nomenclatural status from the Betts Creek beds. On the western margin of the basin, the group thins, and the ‘J and K’ seams (formerly known as the Crossmore and Glenaras sequences, respectively) in the GSQ Muttaburra-1 drill hole have been interpreted through palynology as Cisuralian–early Guadalupian (spore-pollen assemblage APP3.2). This corroborates the exclusion of the ‘J and K’ seams from the overlying Lopingian Betts Creek Group (spore-pollen assemblage APP5), and the underlying lower to mid-Cisuralian Aramac Coal Measures (spore-pollen assemblage APP2.2), which represent the uppermost unit of the Joe Joe Group. It is proposed that the ‘J and K’ seams are restricted to a depocentre in the Hulton–Rand structure. The recognition of these strata containing APP3.2 spore-pollen assemblages suggests that the mid-Permian hiatus is locally reduced to 12–13 My from 30 Ma (where the ‘J and K’ seams are absent). The results of the radiometric dating and palynological analysis in the Galilee Basin support the proposed, albeit informal stratigraphy, that is given in terms of equivalents of formational units in the Bowen Basin and on the intervening Springsure Shelf. 相似文献
20.
Wei Cao Yu Sheng Jichun Wu Jing Li Yaling Chou Jinping Li 《Environmental Earth Sciences》2017,76(20):711
Based on two-dimensional heat-conduction equations with a phase-change component, this study investigates the impact of underground mining on the permafrost environment in an opencast coal mining pit. The dynamics of the maximum thawed and freezing depths at different depths around a borehole wall are determined. The spatial distributions of these dynamics are also determined at different locations of the wall profile. The results show that (1) the maximum freezing depth tends to increase over 100 years; (2) the maximum thawed depth increases along a borehole wall over 100 years. In particular, the maximum thawed depth increases faster near the junctions of permafrost and seasonally frozen soil; (3) due to the small cross section of mining laneways, coal mining does not cause rapid increases in permafrost temperature around borehole walls. Once disturbance to permafrost around a borehole wall decreases, the once-insignificant effect of temperature will become more obvious. Underground mining does have some impacts on permafrost surrounding borehole walls, but it does not cause large areas of deformation due to thermal disturbance. 相似文献