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1.
邱检生  李真  刘亮  赵姣龙 《地质学报》2012,86(4):561-576
漳浦复式花岗岩体位于福建东南沿海,为一由多期岩浆作用形成的大岩基,出露面积大于1500km2。按岩性特征,该复式岩体可肢解为长桥黑云母花岗岩、程溪碱长花岗岩和湖西花岗闪长岩3个单元。锆石LA-ICP-MS U-Pb定年结果表明,3个单元岩石的成岩年龄分别为119Ma、101Ma和96Ma。化学组成上,各单元岩石均具有亚碱、准铝或弱过铝、贫磷特征,它们的A/NKC值均在1.10以下,P2O5含量均低于0.20%,均可归为钙碱性的I型花岗岩。各单元岩石均富Cs、Rb、Th、U、Pb和轻稀土,贫Ba、Sr、P、Ti,但长桥和程溪单元较之湖西单元岩石Rb/Sr、Rb/Ba比值高,K/Rb比值低,并表现出更显著的铕负异常,指示各单元岩石的分异演化程度各不相同。3单元岩石具有较均一的Nd同位素组成,εNd(t)=-2.43～-3.24,tDM2=1.11～1.16Ga,但锆石Hf同位素组成普遍具有较大的变化范围,长桥、程溪和湖西3单元岩石的εHf(t)值分别为-8.3～+3.0、+1.7～+10.2和-2.5～+3.5,变化幅度均在6个εHf单位以上,反映岩体的形成存在不同来源物质的贡献。综合分析表明,各单元岩石的形成均经历了幔源岩浆与其诱发地壳物质熔融产生的长英质岩浆在地壳深部混合,随后又经不同程度结晶分异的二阶段成岩过程。各单元岩石之间显著的成岩时差及成分变异趋势指示复式岩体不可能为同一原始岩浆分异演化的产物,而最可能为演化程度各异的壳幔混源岩浆叠次侵位复合的结果。  相似文献   

2.
Shock metamorphosed rocks and shock-produced melt glasses from the Wanapitei Lake impact structure have been examined petrographically and by electron microprobe. Eleven clasts exhibiting varying degrees of shock metamorphism and eight impact-produced glasses have been analyzed for Rb, Sr and Sr isotopic composition. Five clasts and one glass have also been analyzed for large ion lithophile (LIL) trace element abundances including Li, Rb, Sr, and Ba and the REE's.The impact event forming the Wanapitei Lake structure occurred 37 m.y. ago based on K/Ar dating of glass and glassy whole-rock samples. Rb/Sr isotopic dating failed to provide a meaningful whole-rock or internal isochron. The isotopic composition of the glasses can be explained by impact-produced mixing and melting of metasediments. Large ion lithophile trace element abundance patterns confirm the origin of the glasses by total shock melting of metasediments.  相似文献   

3.
The Attic‐Cycladic crystalline belt in the central Aegean region records a complex structural and metamorphic evolution that documents Cenozoic subduction zone processes and exhumation. A prerequisite to develop an improved tectono‐metamorphic understanding of this area is dating of distinct P–T–D stages. To evaluate the geological significance of phengite ages of variably overprinted rocks, 40Ar/39Ar and Rb–Sr analyses were undertaken on transitional blueschist–greenschist and greenschist facies samples from the islands of Syros and Sifnos. White mica geochronology indicates a large age variability (40Ar/39Ar: 41–27 Ma; Rb–Sr: 34–20 Ma). Petrologically similar samples have either experienced greenschist facies overprinting at different times or variations in ages record variable degrees of greenschist facies retrogression and incomplete resetting of isotopic systematics. The 40Ar/39Ar and Rb–Sr data for metamorphic rocks from both islands record only minor, localized evidence for Miocene ages (c. 21 Ma) that are well documented elsewhere in the Cyclades and interpreted to result from retrogression of high‐pressure mineral assemblages during lower pressure metamorphism. Field and textural evidence suggests that heterogeneous overprinting may be due to a lack of permeability and/or limited availability of fluids in some bulk compositions and that retrogression was more or less parallel to lithological layering and/or foliation as a result of, possibly deformation‐enhanced, channelized fluid ingress. Published and new 40Ar/39Ar and Rb–Sr data for both islands indicate apparent age variations that can be broadly linked to mineral assemblages documenting transitional blueschist‐to‐greenschist‐ and/or greenschist facies metamorphism. The data do not record the timing of peak HP metamorphism, but may accurately record continuous (partial) resetting of isotopic systematics and/or (re)crystallization of white mica during exhumation and greenschist facies retrogression. The form of 40Ar/39Ar phengite age spectra are complex with the lowest temperature steps yielding Middle to Late Miocene ages. The youngest Rb–Sr ages suggest maximum ages of 20.6 ± 0.8 Ma (Syros) and 22.5 ± 0.6 Ma (Sifnos) for the timing of greenschist facies overprinting. The results of this study further accentuate the challenges of interpreting isotopic data for white mica from polymetamorphic terranes, particularly when mixing of populations and/or incomplete resetting of isotopic systematics occurs during exhumation. These data capture the full range of isotopic age variations in retrogressed HP rocks documented in previous isotopic studies, and can be interpreted in terms of the geodynamic evolution of the Aegean.  相似文献   

4.
The Newer Volcanics Province of Victoria and South Australia consists of a major region of mainly alkaline basalts within which are two restricted areas containing strongly differentiated flow‐rocks. Typical alkalic basalts from this widespread province have K‐Ar ages from 4.5 to 0.5 m.y. and initial 87Sr/86Sr ratios from 0.7038 to 0.7045. Contrastingly, in the Macedon area of differentiated lavas, flow compositions range from limburgite to soda trachyte, with K‐Ar ages from 6.8 to 4.6 m.y. and initial 87Sr/86Sr ratios from 0.7052 to 0.7127. These differentiated rocks therefore are older, and some of them may have been contaminated by reaction with more radiogenic basement rocks during differentiation. Alternatively, the variation in initial Sr‐isotope composition may have resulted from varying isotopic composition of partial melts from the immediate source rocks. The most felsic of the differentiated rocks, soda trachyte, is extremely enriched with Rb relative to Sr; one of the three restricted outcrops of this rock (Camel's Hump) yields a total‐rock Rb‐Sr isochron age of 6.3 ± 0.6 m.y. with an initial 87Sr/86Sr ratio of 0.7127. K‐Ar sanidine ages reported for the three outcrops of trachyte are identical to each other and to the Rb‐Sr isochron result.  相似文献   

5.
Diffusion rates of Sr and O in minerals are often comparable while Nd has a lower diffusion rate during thermal overprint(s); thus, the O isotope systems between metamorphic minerals can serve as an indicator to evaluate whether equilibrium of Rb–Sr and Sm–Nd systems has been preserved in the metamorphic minerals that experienced retrograde metamorphism. This study presents a combination of investigation on Sm–Nd, Rb–Sr, and O isotopic compositions of minerals separated from ultrahigh-pressure eclogite and gneiss that were collected from the main hole of the Chinese Continental Scientific Drilling project located in the Sulu orogen, eastern China. Oxygen isotopic compositions of minerals from gneiss and eclogite yield two temperature groups of 620–740 and 460–590°C, representing diffusion cessation of isotopic exchange during the eclogite-facies recrystallization and later amphibolite-facies retrograde overprint. Rb–Sr mineral regressions of two eclogite samples give consistent Triassic ages of 244 Ma, corresponding to eclogite-facies metamorphism, while the same minerals do not yield meaningful Sm–Nd isochron ages. This phenomenon likely suggests that Rb–Sr isotopic equilibrium was achieved during eclogite-facies metamorphism and preserved during late amphibolite-facies retrogression. In contrast, Sm–Nd isotopic equilibrium between the minerals of eclogite was not achieved under UHP metamorphic conditions. Regressions of epidote and biotite of one gneiss sample give a Triassic Sm–Nd age of 243 ± 34 Ma, corresponding to the time of the eclogite-facies metamorphism, and a Jurassic mineral Rb–Sr age of 187.5 ± 1.8 Ma. These results imply that fluids have played an important role to achievement of the Sm–Nd isotopic equilibrium during eclogite-facies metamorphism and re-equilibration of the Rb–Sr isotopic system during later retrograde overprint.  相似文献   

6.
Whole-rock Rb-Sr isochron dating of Sn-bearing granites and alkaline rocks from Gejiu, Yunnan Province has been conducted for their emplacement ages and initial87Sr/86Sr ratios. The Sr isotopic compositions of apatites from some basic rocks in Jiasha, and granite bodies also have been studied in detail. The genesis and evolution of Gejiu Sn-bearing granites as well as ore-search indicators are discussed on the basis of the available data in conjunction with the geochemical data on trace elements (such as Rb and Sr), Sr isotopic characteristics of the volcanic rocks, meta-diabase and host rocks and the isotopic features of ore leads.  相似文献   

7.
K-A ages from a variety of alkaline rocks, carbonatites (sövites) and alnöites from the Alnö complex range between 370 and 605 m.y. but the most meaningful ages concentrate between 546 and 578 m.y. Most nephelinites, phonolites and alkali trachytes that occur in a dike complex surrounding the main intrusion give a middle Cambrian RbSr whole-rock isochron age of 553±6 m.y. (2σ). Some samples (deleted from the age regression) were contaminated by radiogenic strontium. Plutonic pyroxenites, ijolites and nepheline syenites that form most of the core of the intrusion formed at about the same time and from the same parental magma as the dike rocks. Sövites and alnöites that crosscut the dike and core rocks did not intrude significantly later and may have formed from the same parent magma or mantle source. Many samples show evidence of either mixing or isotopic exchange of the magma with the country rocks during intrusion (fenitisation?) or open system behavior after crystallization. These processes resulted in some scatter of the data points about the best-fit RbSr isochron lines and in some anomalous K-A ages. Fenites have higher Rb/Sr and 87Sr/86Sr ratios than the alkaline rocks, making it unlikely that the latter were the remobilized products of extreme fenitization, as suggested by von Eckermann (1948). The Alnö intrusion is about the same age as the Fen complex of southern Norway, but is significantly older or younger than many other apparently similar intrusions in Scandinavia.  相似文献   

8.
Major, trace element, and Sr isotopic data are reported forvolcanic rocks from the island of Alicudi, Aeolian Arc, SouthernTyrrhenian Sea. The island is constructed of basalt, basalticandesite to high-K andesite lavas, and pyroclastites, whichshow a continuum in the variation of many major and trace elements.Total iron, MgO, CaO, Ni, Co, Sc, and Cr decrease with increasingsilica, whereas incompatible elements Rb, Ba, Th, and LREE displaythe opposite tendency. Very significant positive correlationsare defined by incompatible elements on interelemental variationdiagrams. Sr isotopic ratios vary from 0–70352 to 0–70410.Overall, basalts (0–70352–O-70410) and basalticandesltes (0–70356–0–70409) are enriched in87Sr compared with high-K andesites (O–70352–O–70367),which display the lowest Sr isotopic ratios within the entireAeolian archipelago. Overall negative relationships exist between87Sr/86Sr and several incompatible trace element abundancesand ratios, such as Th, U, LREE, Zr, La/Yb, and Th/Hf. Otherelemental ratios such as La/Rb, Ba/Rb, and Sr/Rb show more complexbehaviour, even though negative correlations with Sr isotopicratios are observed in the basalts. The observed compositional variations are best explained interms of a model in which primitive calc-alkaline magmas evolvedby crystal-liquid fractionation to give a series of variouslydifferentiated liquids, which underwent different degrees ofinteraction with crustal material. The more mafic and hotterbasaltic liquids appear to have assimilated higher amounts ofmetamorphic wall rocks than did the cooler late erupted andesiticmagmas. This process produced significant variations of Sr isotopicratios, Rb, Cs, Rb/Sr ratios, and LILE/Rb ratios in mafic magmas,but had only minor effects on the abundances and ratios of otherincompatible elements such as Th, LREE, La/Yb, and Th/Hf. When compared with mafic rocks from other Aeolian islands, theAlicudi basalts are more primitive geochemically and isotopically.Going eastward, there is a decrease in Ni and Cr abundances,mg-number and Nd isotopic ratios which parallels an increaseof Sr isotopic ratios in basaltic rocks along the arc. Thesecompositional variations are typical of volcanic series whichhave undergone interaction with upper-crustal material, andsuggest that this process may have contributed significantlyto the regional geochemical and isotopic trends observed inthe Aeolian arc.  相似文献   

9.
A combined study of mineral O and Rb–Sr isotopes was carried out for a number of Mesozoic granitoids in China in order to compare the degree of O isotope equilibrium between coexisting minerals, with the validity of mineral Rb–Sr isochrons for granitoids. A scrutiny of both O isotope geothermometry and Rb–Sr internal isochron dating for corresponding minerals indicates that equilibrium O isotope fractionation between Rb–Sr isochron minerals corresponds to geologically meaningful isochron ages if the variation in 87Rb/86Sr ratio is big enough to provide reasonably small uncertainties in age. Significant deviation of the Rb–Sr isochron age from the actual age appears to depend on the difference in Sr isotopic composition between an external fluid and the igneous minerals. As a result, O isotope disequilibrium is often caused by interaction between the rock and the external fluid that results in mineral alteration. Post-magmatic alteration can cause isotope exchange between the minerals and an internally buffered fluid that is isotopically identical to the host rock. The O isotope composition of coexisting minerals in studied samples changed principally due to a decrease in temperature. Both Rb and Sr concentrations and the Sr isotope ratios of isochron minerals also changed due to the mixing of different Sr reservoirs. Nevertheless, the isochron age can remain unchanged if the mixing took place along the isochron chord between the internal fluid and the minerals from that newly altered minerals formed. This provides an insight into the effect of internal and external fluids on the validity of mineral Rb–Sr chronometry. In addition, an alternative approach is proposed to construct the cooling curve by a combined use of O isotope temperature and mineral isotope age for the granitoids of interest. Comparing with the traditional method using the empirical closure temperature for Rb–Sr chronometry, the proposed approach utilizes fewer variables with smaller uncertainties than the traditional way.  相似文献   

10.
Rb/Sr internal mineral isochrons in the eclogite facies Marun-Keu metamorphic complex, Polar Urals, Russia, date periods of fluid-rock interaction and record the metamorphic reaction history. The Marun-Keu complex consists of Late Proterozoic to Early Ordovician, mostly igneous rocks that experienced a subduction-related, non-pervasive eclogite facies metamorphism, followed by a local decompression-related amphibolite facies overprint, during the Uralian orogeny. Field observations show that metamorphic reactions as well as ductile deformation are controlled by local availability of a free fluid phase. Isotopic data reveals that availability of fluids similarly exerts control on isotope distribution. From a relic gabbro which has never been infiltrated by free fluids, a premetamorphic Rb/Sr age of 467 ± 39 Ma was obtained. Rb/Sr isochron ages for 14 samples of eclogite and amphibolite facies assemblages, sampled from within or close to metamorphic fluid veins, range from 352 ± 5 Ma to 360 ± 3 Ma. A Sm/Nd isochron for a metagranite yields an age of 354 ± 4 Ma. Taken together, the ages for both prograde and retrograde metamorphic assemblages overlap within analytical uncertainty and yield an average value of 355.5 ± 1.4 Ma, indicating that the metamorphic evolution and incipient exhumation of the Marun-Keu complex proceeded rapidly. The results demonstrate that assemblages preserve their Rb/Sr isotopic signatures as long as they remain devoid of free fluids, and that only fluid-rock interaction may cause Sr isotope redistribution. In addition, the data suggest local fluid-rock equilibrium, low fluid-rock ratios with overall fluid deficiency, and limited fluid mobility at depth. However, some fluids must have been mobile on the km-scale since they can be traced into the suprasubduction zone mantle wedge. Metasomatic veins in the Rai-Iz ophiolite yield a Rb/Sr mineral isochron age of 373.1 ± 5.4 Ma. They are interpreted as evidence for suprasubduction zone metasomatism in an oceanic setting, prior to subduction of the East European margin and associated formation of eclogites in the Marun-Keu complex.We propose that Rb/Sr mineral-isochron ages provide hygrochronological rather than thermochronological constraints. They define the cooling history only in combination with zircon and apatite fission track data. The straightforward interpretation of Rb/Sr mineral ages as cooling ages is obsolete.  相似文献   

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