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1.
The deposit under study is a hydrothermal filling-metasomatic vein type lead-zinc-silver deposit, in whichgold and silver can be recovered as by-products. These metals mainly occur as microgranular native gold,electrum, stephanite, acanthite, pyraragyrite, freibergite, and native silver. Gold minerals tend to be associatedwith galenobismutite, native bismuth and unnamed Bi_2Te. They are either enclosed in pyrite, marmatite,iron-bearing sphalerite and galens or fill the microfissures of these minerals. Silver minerals usually occur incleavages or fissures of galena, marmatite and pyrite, but are not associated with gold and bismuth minerals.Gold and silver mineralizations occurred later than lead and zinc, while the silver mineralization was precededby that of gold.  相似文献   

2.
The paper presents original authors' data on the O, H, C, S, and Sr isotopic composition of water and sediments from the basins into which the Aral Sea split after its catastrophic shoaling: Chernyshev Bay (CB), the basin of the Great Aral in the north, Lake Tshchebas (LT), and Minor Sea (MS). The data indicate that the δ18О, δD, δ13C, and δ34S of the water correlate with the mineralization (S) of the basins (as of 2014): for CB, S = 135.6‰, δ18О = 4.8 ± 0.1‰, δD = 5 ± 2‰, δ13C (dissolved inorganic carbon, DIC) = 3.5 ± 0.1‰, δ34S = 14.5‰; for LT, S = 83.8‰, δ18О = 2.0 ± 0.1‰, δD =–13.5 ± 1.5‰, δ13C = 2.0 ± 0.1‰, δ34S = 14.2‰; and for MS, S = 9.2‰, δ18О =–2.0 ± 0.1‰, δD =–29 ± 1‰, δ13C =–0.5 ± 0.5‰, δ34S = 13.1‰. The oxygen and hydrogen isotopic composition of the groundwaters are similar to those in MS and principally different from the artesian waters fed by atmospheric precipitation. The mineralization, δ13С, and δ34S of the groundwaters broadly vary, reflecting interaction with the host rocks. The average δ13С values of the shell and detrital carbonates sampled at the modern dried off zones of the basins are similar: 0.8 ± 0.8‰ for CB, 0.8 ± 1.4‰ for LT, and –0.4 ± 0.3‰ for MS. The oxygen isotopic composition of the carbonates varies much more broadly, and the average values are as follows: 34.2 ± 0.2‰ for CB, 32.0 ± 2.2‰ for LT, and 28.2 ± 0.9‰ for MS. These values correlate with the δ18O of the water of the corresponding basins. The carbonate cement of the Late Eocene sandstone of the Chengan Formation, which makes up the wave-cut terrace at CB, has anomalously low δ13С up to –38.5‰, suggesting origin near a submarine methane seep. The δ34S of the mirabilite and gypsum (11.0 to 16.6‰) from the bottom sediments and young dried off zone also decrease from CB to MS in response to increasing content of sulfates brought by the Syr-Darya River (δ34S = 9.1 to 9.9‰) and weakening sulfate reduction. The 87Sr/86Sr ratio in the water and carbonates of the Aral basins do not differ, within the analytical error, and is 0.70914 ± 0.00003 on average. This value indicate that the dominant Sr source of the Aral Sea is Mesozoic–Cenozoic carbonate rocks. The Rb–Sr systems of the silicate component of the bottom silt (which is likely dominated by eolian sediments) of MS and LT plot on the Т = 160 ± 5 Ma, I0 = 0.7091 ± 0.0001, pseudochron. The Rb–Sr systems of CB are less ordered, and the silt is likely a mixture of eolian and alluvial sediments.  相似文献   

3.
Among several lithostratigraphic subdivisions of the Gaj Formation of Miocene age, the Jhill limestone is entirely different with respect to its colour, texture and structures. This limestone unit has been evaluated to elaborate its geochemical and sedimentological characteristics. The distribution of various elements in the acid-soluble fraction has been studied in order to determine their mineralogy, sedimentary environment, facies and diagenesis. Mineralogy, recrystallization and other diagenetic changes are the main factors affecting the distribution of trace elements and their mutual relationships in the limestones. Samples of the Jhill limestone show depletion in large-sized ions (Sr, Pb & K) and also in the ions that are not compatible with calcite space group. Elements (Fe, Mn, Zn, Cu & Co) having distribution coefficient (D) above unity for natural calcites, are more enriched. Microscopic and X-ray studies revealed nearly complete conversion of aragonite into stable low-Mg calcite. An attempt has also been made to verify the reefal conditions for these limestones on the basis of geochemical studies. The plots of Sr and other facies-indicator elements show that the majority of the beds belong to forereef flank facies with some algal banks. Low Mg/Ca and Sr/Ca ratios suggest that a phreatic diagenetic environment prevailed after the deposition. High concentrations of Cr, Ni, and Co in the Jhill limestone show a positive correlation with a higher amount of insoluble residue, which reflects a relatively high rate of influx of terrigenous material.  相似文献   

4.
The characteristic structures of the Precambrian cherts from the Gusui section, Guangdong ,Chi-na, include bedded structure ,laminated structure ,massive structure and pseudobrecciated structure.The chert is characterized by consistently low abundance of TiO2,Al2O3 and most trace elements.Howevver ,it is enriched in Ba,As,Sb,Hg and Se.In Al-Fe-Mn ternary diagrams,it falls into the “hydrothermal field“ .Correspondence analysis and factor analysis show that many elements show up in the factor that represents the leaching of country rocks by hydrothermal solutions,and are the very characteristic element association fo the geochemically anomalous South China basement.Petrologic and geochemical evidence suggests a hydrothermal origin for the chert.The chert may have been formed in a Precambrian fift or an extension zone developed within the Yunkai marginal geosyncline, with a fault system linking it to an unknown heat source at depth.  相似文献   

5.
Variations in the abundances of Zn, Cu, and Pb are found to be useful in identifying tectonic regimes and separating oceanisland basalts into enriched- and depleted-source categories. The average Zn, Cu, and Pb contents of normal mid-ocean ridge basalts (N-MORB) are 84, 70, and 0.35 ppm, respectively. Differences in average Zn contents for various ridges reflect more the varying degrees of differentiation than variations of Zn content in the source rocks. At a Mg# of 70, or Mg#70, which is taken to represent primitive MORB, many MORB sequences converge at a Zn content of 58 ± 6 ppm, which is close to the value for primitive mantle (50 ppm) and ordinary chondrites (～55 ppm). Values of 0.1 to 0.15 ppm Pb in MORB at Mg#70, best defined at the superfast-spreading Southern East Pacific Rise, are similar to estimates of Pb in the primitive mantle (0.12 to 0.18 ppm). They also are near the lower end of the range for ordinary chondrites. The very slow spreading Southwest Indian Ocean Ridge has a sequence with higher Pb contents, in addition to a more normal sequence, which has a visual best value of 0.4 ppm Pb at Mg#70. With the exception of the Walvis Ridge, Zn and Cu appear to be little affected by proximity to hotspots (i.e., E-MORB); however, Pb contents are higher and average about 0.6 ppm.

Both Zn and Pb in MORB are incompatible elements (i.e., favor the melt), but Cu is a compatible element. At Mg#70, there is the suggestion of a value of 100 ppm for Cu, with lower values possibly representing partial removal of sulfides and their associated Cu from the source. Nonetheless, Cu contents of primitive MORB tend to be much higher than even high estimates for the primitive mantle (28 ppm), and are closer to ordinary chondrites (～90 ppm). Therefore, Zn, Cu, and Pb all approximate chondritic values in the primitive MORB melt.

Average contents of Zn, Cu, and Pb in oceanic island basalts (OIB) are 115, 62, and 3.2 ppm, respectively. At Mg#70, values of Zn and Cu are similar to the respective averages for OIB, with Zn higher and Cu lower than MORB. At a Mg# of ～40, however, OIB and MORB tend to have similar Zn contents. With further differentiation, OIB trachytes can contain >200 ppm Zn. Unlike MORB, OIB can differentiate to high Cu contents of 200 ppm at Mg#s of 40 to 60. In contrast to Zn and Cu, Pb regresses to a value of 0.83 ppm at Mg#70 for Hawaiian and Reunion volcanics, which is much less than the average value for Pb in OIB volcanics, but higher than for MORB.

Average Zn, Cu, and Pb contents of magmatic-arc basalts are 77, 108, and 1.9 ppm, respectively. In basalts, Zn tends to be incompatible, but a dual incompatible and compatible behavior can occur at high SiO2 contents. Dacites may average near 55 ppm Zn, but peralkalic rhyolite can contain >300 ppm Zn. A dual compatible and incompatible nature occurs for Cu. Most common, particularly in submarine volcanics, is a compatible trend, with a Cu content of around 80 ppm at a Mg# of 60, which decreases to less than 40 ppm at a Mg# of 30. The incompatible trend of increasing Cu can achieve >200 ppm at a Mg# of 30, leaving a gap approaching 100 ppm at that Mg#. The gap is less obvious on a plot of Cu vs. SiO2, but is still there. The compatible trend is proposed to result from sulfur-saturated magmas, whereas the incompatible trend is believed to result from sulfur-deficient magmas. Support for this hypothesis is found in sparse sulfur-isotope data. Zn and Cu both can be incompatible over an extended range of Mg#s or silica content. When Zn and Cu are both compatible, Cu decreases more than twice as rapidly as Zn.

Primitive magmas at Mg#70 average about 50 ppm Zn for submarine Mariana arc basalts and 58 ppm for forearc boninites, contents close to MORB values. Mariana arc basalts have a Zn content of ～45 ppm estimated at Mg#70. Cu varies more widely than Zn in primitive magmas, being about 50 ppm Cu for Mariana Islands volcanics and 120 ppm for Kermadec Islands volcanics, a range broadly around MORB values. Average Pb contents are 1.9 ppm for island-arc tholeiites, 5.6 ppm for high-Al basalt, and 3.2 ppm for alkali basalt with average boninite of approximately 1.8 ppm. Back-arc-basin basalts in the deepest parts of the Mariana trough have Pb contents of 0.45 ppm, but more shallow parts may exceed 1.0 ppm Pb. Although the lower contents are similar to MORB values, the 208Pb/204Pb values are greater than Pacific Ocean MORB. At Mg#70 for rocks from the Tonga and Kermadec island arcs, the Pb content is about 0.1 ppm, similar to MORB.  相似文献   

6.
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7.
This study is aimed at determining the diffusion coefficient of net-work modifiers (mainly Na, K, and Ca) in a two-phase melt-NaCl system, in which the melts are granitic and the system is NaCl-rich in composition. The diffusion coefficients of Na, K, and Ca were measured at the temperatures of 750 – 1400°C, pressures of 0.001 × 108 – 2 × 108 Pa, and initial H2O contents of 0 wt% –6.9 wt% in the granitic melts. The diffusion coefficients of Fe and Mg were difficult to resolve. In all experiments a NaCl melt was present as well. In the absence of H2O, the diffusion of net-work modifiers follows an Arrhanious equation at 1 × 105 Pa: lgDca=−3. 88−5140/T, lgDk =−3. 79−4040/T, and lgDNa, =−4.99−3350/T, where D is in cm2 /s andT is in K. The diffusion coefficients of Ca, Na, K, and Fe increase non-linearly with increasing H2O content in the melt. The presence of about 2 wt% H2O m the melt will lead to a dramatical increase in diffusivity, but higher H2O content has only a minor effect. This change is probably the result of a change in the melt structure when H2O is present. The diffusion coefficients measured in this study are significantly different from those in previous works. This may be understood in terms of the “transient two-liquid equilibrium” theory. Element interdiffusion depends not only on its concentration, but also on its activity co-efficient gradient, which is reflected by the distribution coefficient, of the two contacting melts.  相似文献   

8.
The mineralogy and geochemistry data are presented for thirty-seven shales,four concretions,two carbonate sediments and seven lignites from the Marathousa coal field of the Megalopolis Basin in Greece.The argillaceous rocks consist of chlorite,illite,kaolinte,albite,quartz.opal-A,calcite and dolomite;the concretions of aragonite,gypsum and pyrite;and the carbonate rocks of calcite,quartz and illite.The mineral matter in the lignites consists of gypsum,quartz,albite,chlorite,illite,opal-A,dolomite,pyrite,and rarely calcite and kaolinite Athree-factor model explains the total variaition of major and trace elements in the argillaceous sediments.The first factor is an aluminosilicate factor and involves the following elements:Al,Si,Mg,Na,K,Ti,Mn,Nb,Y,Rb,Zn,Cu,Ni,Cr,Nband V,associated with chlorite,albite and illite.The second factor involves the elements Ca,Sr,Ba,Znand Sc and is related to carbonate lithology and mainly the carbonate concretions with gypsum.The third factor involves Fe and Ce with a weak association with Mn.The diagenesis of the Marathousa sediments and lignites was not very advanced as indicated by (a) the total thickness of the sequence (500m),(b) the presence of biogenic silica(opal-A) and (c) the age of the deposit(Pleistocene).FOr these reasons the rpresence of chlorite,illite and kaolinite in the sediments and lignite is due not to diagenetic reactions but to weathering of the flysch and metamorphic rocks at the edges of the Megalopolis Basin and transport of the weathering products(illite,chlorite,kaolinite)into the basin of deposition.The diagenetic minerals of the Marathousa sequence include pyrite,gypsum,dolomite and aragonite.  相似文献   

9.
Three dumping sites have been formed at the northern region of Fushun City, Liaoning Province, for a large number of gangues including much oil shale that had been piled onto ground as gangue during long-term coal exploitation at West Fushun Open-pit Mine. Under appropriate conditions, self-combustion occurs after long-term exposure of oil shale and consequently such phenomena could be found almost everywhere at the three dumping sites. Much polycyclic aromatic hydrocarbons （PAHs） must be generated through oil shale self-combustion, a kind of incomplete combustion. In this paper, in order to make clear the PAHs distribution in oil shale and its self-combustion and their potential effects on surrounding environment, coal, low-grade oil shale, high-grade oil shale, burning oil shale, burnt oil shale and shaly soil collected from West Fushun Open-Pit Mine and West Dumping Site were analyzed quantitatively in 16 US EPA priority PAHs for the first time. Results showed that 16 PAHs in all samples were less than those in some bitumites and carbonaceous coals and were as much as those in lignites and anthracites from some Chinese mining areas. Coal and low-grade oil shale were abundant in lower molecular-weighted PAHs in contrast to high-grade oil shale with rich higher molecular-weighted PAHs. They had more benzo[a] pyrene than the highest background value in soils in Liaoning Province. So PAHs in these crude oil shales could cause potential effects on environment. There were at least 5121.40 p.g/kg PAils generated and at least 3976.70 μg/kg PAHs released into environment in the period from combustion beginning to sampling on the basis of calculation. Furthermore, the concentrations of 3-4 ring PAHs among them were very high. Therefore it could be said that oil shale self-combustion aggravated the environmental impacts of PAHs in oil shale. The low concentrations of PAHs in shaly soil showed that much PAHs had been released through recultivation and biodegradation.  相似文献   

10.
Volcán Ceboruco, Mexico, erupted ~1,000 years ago, producing the Jala pumice and forming a ~4-km-wide caldera. During that eruption, 2.8 to 3.5 km3 of rhyodacite (~70 wt% SiO2) magma and 0.2 to 0.5 km3 of mixed dacite (~67 wt% SiO2) magma were tapped and deposited as the Jala pumice. Subsequently, the caldera was partially filled by extrusion of the Dos Equis dome, a low-silica (~64 wt% SiO2) dacite dome with a volume of ~1.3 km3. Petrographic evidence indicates that the Jala dacite and Dos Equis dacite originated largely through the mixing of three end-member magmas: (1) rhyodacite magma, (2) dacite magma, and (3) mafic magma. Linear least-squares modeling and detailed modal analysis indicate that the Jala dacite is predominantly a bimodal mixture of rhyodacite and dacite with a small additional mafic component, whereas the Dos Equis dacite is composed of mostly dacite mixed with subordinate amounts of rhyodacite and mafic magma. According to Fe–Ti oxide geothermometry, before the caldera-forming eruption the rhyodacite last equilibrated at ~865 °C, whereas the dacite was originally at ~890 °C but was heated to ~960 °C by intrusion of mafic magma as hot as ~1,030 °C. Zoning profiles in plagioclase and/or magnetite phenocrysts indicate that mixing between mafic and dacite magma occurred ~34–47 days prior to eruption, whereas subsequent mixing between rhyodacite and dacite magmas occurred only 1–4 days prior to eruption. Following the caldera-forming eruption, continued inputs of mafic magma led to effusion of the Dos Equis dome dacite. In this case, timing between mixing and eruption is estimated at ~93–185 days based on the thickness of plagioclase overgrowth rims.Editorial responsibility: T.L. Grove  相似文献   

11.
The Chahe copper deposit occurs in the Early Proterozoic metamorphic series in the area of Chahe and its chalcopyrite yielded a Pb−Pb isochron age of 951±36 Ma, providing evidence for copper mineralization at the early stage of the Jinning movement. The ore-forming material came from terrestrial clastic sediments and marine volcanic eruption and the ores were deposited in a relatively open beach environment. The Jinning movement led to folding and metamorphism of country strata, as well as to the rebomilization and transport of copper, resulting in ore deposition in structurally weak locations. This deposit is a volcano-sedimentary metamorphic deposit.  相似文献   

12.
Geochronology of the Dahongshan Group   总被引：10，自引：0，他引：10  
The Dahongshan Group is divided into five formations from the bottom to the top: the Laochanghe Formation; the Manganghe Formation; the Hongshan Formation, the Feiweihe Formation and the Potou Formation. As can be seen from the U-Pb concordia plot for zircon fractions collected from the metamorphic sodic lava of the Hongshan Formation, the upper intersect age with the concordia is 1665.55 -10.86 +13.56 Ma. Sm-Nd dating of four whole-rock samples and one hornblende from the Manganghe and Hongshan formations yielded an isochron age of 1657 ± 82 Ma. This result is in good agreement with the zircon U-Pb age and thus can represent the formation age of the Dahongshan Group. The initial143Nd/144Nd ratio is estimated at 0.510646. with ENd (T) = + 3.1 ± 1.8. In addition the Dahongshan Group rocks are characterized by low REE contents, with δEu>1. All this goes to show that the original rocks of the Dahongshan Group were derived from a depleted mantle. The calculated Sm-Nd model ages range from ∼ 1900 to ∼ 2000 Ma. representing the time of crust/ mantle differentiation in the area studied. From the above results, in conjunction with the time-scale scheme for China, the Dahongshan Group should be assigned to the Middle Proterozoic.  相似文献   

13.
In this paper the Pb-Pb isochron method was used to determine the isotopic ages of the Luoxue Formation dolomites (1716 ±56 Ma), the Heishan Formation carbonaceous slates ( 1607 ±128 Ma) of the middle sub-group of the Kunyang Group and the Dayingpan Formation carbonaceous slates (1258 ±70Ma) of the upper sub-group of the Kunyang Group. The age of the middle sub-group of the Kunyang Group is about 1800 – 1600 Ma, belonging to the Late Paleo-Proterozoic, and that of the Dayingpan Formation in the upper sub-group of the Kunyang Group is about 1200 – 1300 Ma, belonging to the Middle Proterozoic. In addition, the Pb isotope chemical exploration techniques were used to study systematically the Pb isotopic compositions of rocks and ores across the No. 14 vein in the middle segment of the No. 1 pit of the Tangdan copper deposit and the result showed that the Pb isotope V1 values are negatively correlated with the copper contents. It is the first trial to use the systematic section method to conduct Pb isotope chemical exploration. This research project was financially supported jointly by the National Natural Science Foundation of China (Grant Nos. 49702022, 40073001) and the State 973 Program (No.G1999043215).  相似文献   

14.
杨红  刘福来  刘平华  王舫 《岩石学报》2013,29(6):2161-2170
大红山群是扬子地块西南缘出露的古元古代结晶基底,主要经历了绿片岩相-低角闪岩相变质作用.本研究对大红山群老厂河组变质中酸性岩和变质沉积岩——石榴白云母-长石石英片岩中的白云母进行了40Ar-39Ar测年,得到三个样品的坪年龄和40Ar/39Ar等时线年龄结果较统一,坪年龄代表的变质年龄分别为837.7±4.2Ma、839.6±4.2Ma和844.2±4.2Ma.变质沉积岩和变质中酸性岩的变质时代类似,均介于837～845Ma.大红山群变质基性岩中变质锆石的U-Pb定年年龄为849±12Ma(杨红等,2012),40Ar-39Ar测年数据与锆石定年数据相结合,说明大红山群古元古代结晶基底中的火山岩和沉积岩均在新元古代经历了同期变质作用,其主期低角闪岩相变质作用发生于新元古代837～850Ma.结合前人发表的扬子西缘～750Ma的变质年龄,扬子西缘从北向南的区域变质作用时限可扩展到750 ～850Ma.此外,扬子西缘存在750～850Ma的岩浆事件,本文研究结果说明,扬子地块西缘在新元古代不仅发生了大规模岩浆作用,也发生了750～850Ma的区域变质作用,扬子西缘存在新元古代的岩浆-变质事件.岩浆事件与变质事件之间可能存在相关性,即新元古代岩浆作用引起了扬子西缘的区域动力热流变质作用.  相似文献   

15.
杨红  刘福来  杜利林  刘平华  王舫 《岩石学报》2012,28(9):2994-3014
大红山群是扬子地台西缘相对较老的地层单元,普遍经历了绿片岩相-低角闪岩相变质作用。其中部的曼岗河组、红山组已获得古元古代晚期～1.68Ga的成岩年龄,其底部的老厂河组却未有相关年龄的报道。大红山群的变质时代目前也无精确的年龄结果。本文以老厂河组厚层变质沉积岩中的薄层变质火山岩样品为研究对象,在岩相学研究的基础上,运用LA-ICP-MS方法对变质火山岩锆石进行原位U-Pb同位素定年及相关的微量、稀土元素测试,获得变质火山岩的原岩年龄和变质年龄:(1)老厂河组变质中酸性岩和变质基性岩中岩浆锆石微区的207Pb/206Pb加权平均年龄分别为1711±4Ma和1686±4Ma,限定老厂河组的形成年龄范围为1711～1686Ma;(2)变质基性岩(石榴斜长角闪岩)中变质锆石的206Pb/238U年龄为849±12Ma。本文结果表明,大红山群的形成时代可提早至1711±4Ma,又一次证明了扬子地台西缘古老结晶基底的存在;大红山群在～850Ma经历了一期新元古代变质事件,这期变质可能是与扬子地台西缘新元古代岩浆事件有关的区域变质事件。  相似文献   

16.
辽宁省本溪连山关地区出露大面积的古元古代辽河群地层,在朱家沟典型剖面浪子山组中识别出2层斜长角闪岩,镜下观察其原岩为玄武岩;在连山关及河栏镇里尔峪组中识别出一套酸性火山岩。对浪子山组2件斜长角闪岩样品、里尔峪组2件流纹岩样品测定LA-ICP-MS锆石U-Pb年龄。阴极发光图像显示,样品D020锆石内部结构整体发黑、条痕状吸收程度不等,Th/U值较低,为变质锆石,其1934±45Ma代表了浪子山组的变质年龄。其余3个样品阴极发光图像显示典型的岩浆振荡环带结构和较高的Th/U值,为岩浆锆石。1952±38Ma代表了浪子山组的形成时代,2177±34Ma和2208±12Ma代表了里尔峪组的形成时代。结合前人资料,将辽河群形成时代限制在2.20~1.95Ga,其形成时代持续了250Ma左右。野外接触关系及火山岩年代学特征从另一个方面揭露了辽河群总体为一套无序、局部有序的构造地层,各岩组间不存在上下关系,浪子山组已经不适合置于里尔峪组之下。  相似文献   

17.
The strata-bound Cu−Pb−Zn polymetallic sulfide deposits occur in metamorphic rocks of greenschist phase of the middle-upper Proterozoic Langshan Group in central Inner Mongolia. δ34S values for sulfides range from −3.1‰ to +37.3‰, and an apparent difference is noticed between vein sulfides and those in bedded rocks. For example, δ34S values for bedded pyrite range from +10.6‰ to +20.0‰, while those for vein pyrite vary from −3.1‰ to +14.1‰. δ34S of bedded pyrrhotite is in the range +7.9‰–+23.5‰ in comparison with +6.5‰–+17.1‰ for vein pyrrhotite. The wide scatter of δ34S and the enrichment of heavier sulfur indicate that sulfur may have been derived from H2S as a result of bacterial reduction of sulfates in the sea water. Sulfur isotopic composition also differs from deposit to deposit in this area because of the difference in environment in which they were formed. The mobilization of bedded sulfides in response to regional metamorphism and magmatic intrusion led to the formation of vein sulfides. δ18O and δ13C of ore-bearing rocks and wall rocks are within the range typical of ordinary marine facies, with the exception of lower values for ore-bearing marble at Huogeqi probably due to diopsidization and tremalitization of carbonate rocks. Pb isotopic composition is relatively stable and characterized by lower radio-genetic lead. The age of basement rocks was calculated to be about 23.9 Ma and ore-forming age 7.8 Ma.207Pb/204Pb−206Pb/204Pb and208Pb/204Pb−206Pb/204Pb plots indicate that Pb may probably be derived from the lower crust or upper mantle. It is believed that the deposits in this region are related to submarine volcanic exhalation superimposed by later regional metamorphism and magmatic intrusion.  相似文献   

18.
邹平火山岩盆地是山东省重要的铜多金属矿区之一,区内含有1套多旋回多期次的中生代火山-侵入杂岩,已发现的铜矿床、矿化点均与晚期侵入杂岩体及次火山岩有关。为了查明矿区的成岩成矿作用时代,采用SHRIMP同位素测定技术,对区内与铜多金属矿化有关的侵入岩中的锆石进行了U-Th-Pb同位素测定,获得王家庄铜矿床的赋矿围岩——石英二长闪长岩的侵位年龄为（128.8±0.8）Ma,盆地中部裂隙充填交代型铜金矿床的赋矿围岩环状二长岩岩墙的侵位年龄为（122.9±0.5）Ma;对王家庄铜矿中的5件辉钼矿样品进行了Re-Os同位素分析,获得的等时线年龄为（126.7±4）Ma及模式年龄加权平均值（128.2±0.8）Ma,代表了辉钼矿在流体中沉淀的时间。所获年龄数据准确地厘定了区内晚期岩浆活动及其矿化时限,表明王家庄杂岩体的侵位时间早于环状二长岩岩墙,其多金属矿化时间与成岩时间接近,岩体与矿化关系密切;而裂隙充填交代型铜矿的形成时间晚于环状二长岩岩墙,具有明显的构造控矿特征。所获得的年龄数据对于进一步研究区域成矿规律和指导找矿具有重要的意义。  相似文献   

19.
为进一步查明钦(州湾)-杭(州湾)结合带中段龙头寨群的地质时代及龙头寨群黄竹洞组与上覆南迳组的接触关系,在野外考察、代表性剖面测制的基础上,对粤北始兴司前龙头寨群黄竹洞组变质岩系顶部首次发现的火山岩夹层的2个弱变质流纹岩样品进行了SHRIMP锆石U-Pb年龄测定,获得~(206)Pb/~(238)U加权平均年龄分别为436.2±2.1Ma (n=15,MSWD=1.60)和438.7±2.1Ma(n=16,MSWD=1.17),指示黄竹洞组的地质时代属晚奥陶世-早志留世,为黄竹洞组的地质时代归属提供了证据。结合上覆南迳组碎斑熔岩SHRIMP锆石U-Pb年龄为443.6±5.4Ma,说明黄竹洞组火山岩夹层与南迳组火山岩的锆石U-Pb年龄在误差范围内一致,属同期火山活动的产物,为黄竹洞组与南迳组的接触关系属整合接触提供了时代约束。粤北龙头寨群黄竹洞组顶部火山岩及南迳组火山岩系的发现和地质时代的厘定,为钦-杭结合带中段晚奥陶世-早志留世龙头寨群属活动大陆边缘沉积提供了依据,暗示钦-杭结合带中段加里东造山带属俯冲-碰撞造山带。  相似文献   

20.
In the Archaean Murchison Province of Western Australia, granitoid batholiths and plutons that intruded into the ca. 2.7–2.8 Ga and ca. 3.0 Ga greenstone belts can be divided into three major suites. Suite I is a ca. 2.69 Ga monzogranite-granodiorite suite, which was derived from anatexis of old continental crust and occurs as syn-tectonic composite batholiths over the entire province. Suite II is a trondhjemite-tonalite suite (termed I-type) derived from partial melting of subducted basaltic crust, which intruded as syn- to late-tectonic plutons into the greenstone belts in the northeastern part of the province where most of the major gold deposits are situated. One of the Suite II trondhjemite plutons has a Pb−Pb isochron age of 2641±36 Ma, and one of the structurally youngest tonalite plutons has a minimum Pb−Pb isochron age of 2630.1±4.3 Ma. Suite III is a ca. 2.65–2.62 Ga A-type monzogranite-syenogranite suite which is most abundant in the largely unmineralised southwestern part of the province. Gold deposits in the province are mostly hosted in brittle-ductile shear zones, and were formed at a late stage in the history of metamorphism, deformation and granitoid emplacement. At one locality, mineralisation has been dated at 2636.8±4.2 Ma through a pyritetitanite Pb−Pb isochron. Lead and Sr isotope studies of granitoids and gold deposits indicate that, although most gold deposits have initial Pb isotope compositions most closely similar to those of Suite II intrusions, both Suite I and Suite II intrusions or their source regions could have contributed solutes to the ore fluids. These preliminary data suggest that gold mineralisation in the Murchison Province was temporally and spatially associated with Suite II I-type granitoids in the northeastern part of the province. This association is consistent with the concept that Archaean gold mineralisation was related to convergent-style tectonic settings, as generation of both Suite II I-type granitoids and hydrothermal ore fluids could have been linked to the dehydration and partial fusion of subducted oceanic crust, and old sialic crust or its anatectic products may also contribute solutes to the ore fluids. Integration of data from this study with other geological and radiogenic isotope constraints in the Yilgarn Block argue against direct derivation of gold ore fluids from specific I-type granitoid plutons, but favour a broad association with convergent tectonics and granitoid magmatism in the late Archaean.  相似文献   

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