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1.
The alluvial aquifer of the Guadalquivir River comprises shallow Quaternary deposits located in the central-eastern part of the Province of Jaén in southern Spain, where groundwater resources are used mainly for crop irrigation in an important agricultural area. In order to establish the baseline hydrochemical conditions and processes determining the groundwater quality, groundwater and river water samples were collected as part of an integrated investigation that coupled multivariate statistical analysis with hydrochemical methods to identify and interpret the groundwater chemistry of the aquifer system. Three main hydrochemical types (Mg–Ca–HCO3, Ca–Mg–SO4–HCO3–Cl and Na–Ca–Mg–Cl–SO4) were identified. Further interpretation, using R-mode principal components analysis (PCA) conducted with 13 hydrochemical variables, identified two principal components which explain ⅔ of the variance in the original data. In combination with the hydrochemical interpretation, mineralogical analyses of the aquifer sediment together with inverse geochemical modelling using NETPATH showed that dedolomitization (calcite precipitation and dolomite dissolution driven by gypsum dissolution) is the principal hydrochemical process controlling the regional groundwater chemistry. Other processes such as silicate weathering, ion exchange, mixing between river water and groundwater, and agricultural practices also affect the groundwater chemistry.  相似文献   

2.
The Kali-Hindon is a watershed in the most productive central Ganga plain of India. The whole area is a fertile track with sugarcane being the principal crop. Systematic sampling was carried out to assess the source of dissolved ions, impact of sugar factories and the quality of groundwater. Thirty-six samples were collected covering an area of 395 km2. The quality of groundwater is suitable for irrigational purposes but is rich in SO4 which is not best for human consumption. Graphical treatment of major ion chemistry helps identify six chemical types of groundwater. All possible species such as Na–Cl, K–Cl, Na–HCO3, Na–SO4, Ca–HCO3, Mg–HCO3, Ca–SO4 and Mg–SO4 are likely to occur in the groundwater system. The most conspicuous change in chemistry of groundwater is relative enrichment of SO4. The interpretation of data reveals that SO4 has not been acquired through water–rock interaction. The source of SO4 is anthropogenic. Sugar factories alone are responsible for this potential environmental hazard.  相似文献   

3.
The sea level rise has its own-bearing on the coastal recession and hydro-environmental degradation of the River Nile Delta. Attempts are made here to use remote sensing to detect the coastal recession in some selected parts and delineating the chemistry of groundwater aquifers and surface water, which lie along south-mid-northern and coastal zone of the Nile Delta. Eight water samples from groundwater monitoring wells and 13 water samples from surface water were collected and analyzed for various hydrochemical parameters. The groundwater samples are classified into five hydrochemical facies on Hill-Piper trilinear diagram based on the dominance of different cations and anions: facies 1: Ca–Mg–Na–HCO3–Cl–SO4 type I; facies 2: Na–Cl–HCO3 type II; facies 3: Na–Ca–Mg–Cl type III, facies 4: Ca–Na–Mg–Cl–HCO3 type IV and facies 5: Na–Mg–Cl type V. The hydrochemical facies showed that the majority of samples were enriched in sodium, bicarbonate and chloride types and, which reflected that the sea water and tidal channel play a major role in controlling the groundwater chemical composition in the Quaternary shallow aquifers, with a severe degradation going north of Nile Delta. Also, the relationship between the dissolved chloride (Cl, mmol/l), as a variable, and other major ion combinations (in mmol/l) were considered as another criterion for chemical classification system. The low and medium chloride groundwater occurs in southern and mid Nile Delta (Classes A and B), whereas the high and very high chloride (classes D and C) almost covers the northern parts of the Nile Delta indicating the severe effect of sea water intrusion. Other facets of hydro-environmental degradation are reflected through monitoring the soil degradation process within the last two decades in the northern part of Nile Delta. Land degradation was assessed by adopting new approach through the integration of GLASOD/FAO approach and Remote Sensing/GIS techniques. The main types of human induced soil degradation observed in the studied area are salinity, alkalinity (sodicity), compaction and water logging. On the other hand, water erosion because of sea rise is assessed. Multi-dates satellite data from Landsat TM and ETM+ images dated 1983 and 2003 were used to detect the changes of shoreline during the last two decades. The obtained results showed that, the eroded areas were determined as 568.20 acre; meanwhile the accreted areas were detected as 494.61 acre during the 20-year period.  相似文献   

4.
Eighty-seven groundwater samples have been collected from a mountainous region (Alvand, Iran) for hydrochemical investigations to understand the sources of dissolved ions and assess the chemical quality of the groundwater. Most water quality parameters are within World Health Organization acceptable limits set for drinking water. The least mineralized water is found closest to the main recharge zones and the salinity of water increased towards the north of the basin. The most prevalent water type is Ca–HCO3 followed by water types Ca–NO3, Ca–Cl, Ca–SO4 and Mg–HCO3. The Ca–NO3 water type is associated with high nitrate pollution. Agricultural and industrial activities were associated with elevated level of NO3−. Mineral dissolution/weathering of evaporites dominates the major element hydrochemistry of the area. Chemical properties of groundwater in Alvand region are controlled both by natural geochemical processes and anthropogenic activities.  相似文献   

5.
Geochemical processes that take place in the aquifer have played a major role in spatial and temporal variations of groundwater quality. This study was carried out with an objective of identifying the hydrogeochemical processes that controls the groundwater quality in a weathered hard rock aquifer in a part of Nalgonda district, Andhra Pradesh, India. Groundwater samples were collected from 45 wells once every 2 months from March 2008 to September 2009. Chemical parameters of groundwater such as groundwater level, EC and pH were measured insitu. The major ion concentrations such as Ca2+, Mg2+, Na+, K+, Cl−, and SO4 2− were analyzed using ion chromatograph. CO3 − and HCO3 − concentration was determined by acid–base titration. The abundance of major cation concentration in groundwater is as Na+ > Ca2+ > Mg2+ > K+ while that of anions is HCO3 − > SO4 2− > Cl− > CO3 −. Ca–HCO3, Na–Cl, Ca–Na–HCO3 and Ca–Mg–Cl are the dominant groundwater types in this area. Relation between temporal variation in groundwater level and saturation index of minerals reveals the evaporation process. The ion-exchange process controls the concentration of ions such as calcium, magnesium and sodium. The ionic ratio of Ca/Mg explains the contribution of calcite and dolomite to groundwater. In general, the geochemical processes and temporal variation of groundwater in this area are influenced by evaporation processes, ion exchange and dissolution of minerals.  相似文献   

6.
The chemical analysis of 59 water wells in Meshkinshar area, Ardabil province NW of IRAN has been evaluated to determine the hydrogeochemical processes and ion concentration background in the region. The dominated hydrochemical types are Na–SO4, Ca–HCO3, Na–HCO3 and Na–Cl in the whole area. Based on the total hardness, the groundwater is soft. According to electrical conductivity and sodium adsorption ratio, the most dominant classes are C1–S1, C2–S1 and C3–S1. The major ion concentrations are below the acceptable level for drinking water. The groundwater salinity hazard is medium to high but the Na hazard is low to medium and in regard of irrigation water the quality is low to medium. So the drainage system is necessary to avoid the increase of toxic salt concentrations.  相似文献   

7.
Groundwater is a significant water resource in India for domestic, irrigation, and industrial needs. By far the most serious natural groundwater-quality problem in India, in terms of public health, derives from high fluoride, arsenic, and iron concentrations. Hydrogeochemical investigation of fluoride contaminated groundwater samples from Kolar and Tumkur Districts in Karnataka are undertaken to understand the quality and potability of groundwater from the study area, the level of fluoride contamination, the origin and geochemical mechanisms driving the fluoride enrichment. Majority of the groundwater samples did not meet the potable water criteria as they contained excess (>1.5 mg/L) fluoride, dissolved salts (>500 mg/L) and total hardness (75–924 mg/L). Hydrogeochemical facies of the groundwater samples suggest that rock weathering and evaporation–crystallization control the groundwater composition in the study area with 50–67% of samples belonging to the Ca–HCO3 type and the remaining falling into the mixed Ca–Na–HCO3 or Ca–Mg–Cl type. The saturation index values indicated that the groundwater in the study area is oversaturated with respect to calcite and under-saturated with respect to fluorite. The deficiency of calcium ion concentration in the groundwater from calcite precipitation favors fluorite dissolution leading to excess fluoride concentration.  相似文献   

8.
Groundwater samples were collected from 25 sampling sites of the Oropos–Kalamos basin aiming to describe the groundwater quality in relation to geology, lithology and anthropogenic activities of the study area. Chromium speciation analysis, factor analysis, GIS database and geochemical data proved successful tools for the identification of natural and anthropogenic factors controlling the geochemical data variability and for the identification of the redox couple controlling Cr speciation. A Durov diagram is used to classify groundwater quality into five types: Ca–HCO3, Mg–HCO3, Na–Cl, Mg–Cl and Ca–Cl. The groundwater quality of Oropos–Kalamos is influenced by various natural and anthropogenic factors. Evaluation of water quality for drinking and irrigation purposes is discussed.  相似文献   

9.
The degradation of groundwater quality, which has been noted in the recent years, is closely connected to the intensification of agriculture, the unreasonable use of chemical fertilizers and the excess consumption of large volumes of irrigation water. In the hilly region of central Thessaly in Greece, which suffers the consequences of intense agricultural use, a hydrogeological study is carried out, taking groundwater samples from springs and boreholes in the Neogene aquifers. The aim of this study is the investigation of irrigation management, water quality and suitability for various uses (water supply, irrigation), the degradation degree and the spatial distribution of pollutants using GIS. The following hydrochemical types prevail in the groundwater of the study area: Ca–Mg–HCO3, Mg–Ca–Na–HCO3 and Na–HCO3. In the above shallow aquifers, especially high values of NO3 − (31.7–299.0), NH4 + (0.12–1.11), NO2 − (0.018–0.109), PO4 3− (0.07–0.55), SO4 2− (47.5–146.5) and Cl− (24.8–146.5) are found, particularly near inhabited areas (values are in mg L−1). The water of shallow aquifers is considered unsuitable for human use due to their high polluting load, while the water of the deeper aquifers is suitable for human consumption. Regarding water suitability for irrigation, the evaluation of SAR (0.153–7.397) and EC (481–1,680 μS cm−1) resulted in classification category ‘C3S1’, indicating high salinity and low sodium water which can be used for irrigation in most soils and crops with little to medium danger of development of exchangeable sodium and salinity. The statistical data analysis, the factor analysis and the GIS application have brought out the vulnerable-problematic zones in chemical compounds of nitrogen and phosphates. The groundwater quality degradation is localized and related exclusively to human activities. Based on 2005 and 2008 estimates, the annual safe yield of the region’s aquifers were nearly 41.95 MCM. However, the existing situation is that 6.37 MCM of water is over extracted from these aquifers.  相似文献   

10.
High arsenic (As) groundwater is widely distributed in northwestern Hetao Plain, an arid region with sluggish groundwater flow. Observed As concentration in groundwater from wells ranges from 76 to 1,093 μg/l. Most water samples have high total dissolved solids, with Cl and HCO3 as the dominant anions and Na as the dominant cation. The major hydrochemical types of most saline groundwaters are Na–Mg–Cl–HCO3 and Na–Mg–Cl. By contrast, fresh groundwaters generally belong to the Na–Mg–HCO3 type. High concentrations of arsenic in shallow aquifers are associated with strongly reducing conditions, as evidenced by high concentrations of dissolved organic carbon, ammonium, as well as dissolved sulfide and Fe, dominance of arsenite, relatively low concentrations of nitrate and sulfate, and occasionally high content of dissolved methane (CH4). High As groundwaters from different places at Hetao Plain experienced different redox processes. Fluoride is also present in high As groundwater, ranging between 0.40 and 3.36 mg/l. Although fluorosis poses an additional health problem in the region, it does not correlate well with As in spatial distribution. Geochemical analysis indicates that evapotranspiration is an important process controlling the enrichment of Na and Cl, as well as trace elements such as As, B, and Br in groundwater. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

11.
Seawater intrusion is a problem in the coastal areas of Korea. Most productive agricultural fields are in the western and southern coastal areas of the country where irrigation predominantly relies on groundwater. Seawater intrusion has affected agricultural productivity. To evaluate progressive encroachment of saline water, the Korean government established a seawater intrusion monitoring well network, especially in the western and southern part of the peninsula. Automatic water levels and EC monitoring and periodic chemical analysis of groundwater help track salinization. Salinization of fresh groundwater is highly associated with groundwater withdrawal. A large proportion of the groundwaters are classified as Na–Cl and Ca–Cl types. The Na–Cl types represent effects of seawater intrusion. The highest EC level was over 1.6 km inland and high Cl values were observed up to 1.2 km inland. Lower ratios of Na/Cl and SO4/Cl than seawater values indicate the seawater encroachment. A linear relation between Na and Cl represents simple mixing of the fresh groundwater with the seawater. The saline Na–Cl typed groundwaters showed Br/Cl ratios similar to or less than seawater values. The Ca–HCO3 type groundwaters had the highest Br/Cl ratios. Substantial proportions of the groundwaters showed potential for salinity and should be better managed for sustainable agriculture.  相似文献   

12.
 An unconfined aquifer system suggests an open system in the study area. Hydrochemical evolution is related to the flow path of groundwater. The groundwaters are divided into two hydrochemical facies in the study area, 1) Ca–Mg–HCO3 and 2) Ca–Mg–SO4HCO3. Facies 1 has shallow (young) waters which dominate in recharge areas during rapid flow conditions, whereas facies 2 may show shallow and mixed waters which dominate intermediate or discharge areas during low flow conditions. Ionic concentrations, TDS, EC and water quality are related to groundwater residence time and groundwater types. The groundwaters in the plain are chemically potable and suitable for both domestic and agricultural purposes. Received: 20 May 1996 · Accepted: 30 July 1996  相似文献   

13.
Pollution of groundwater by seawater intrusion poses a threat to sustainable agriculture in the coastal areas of Korea. Therefore, seawater intrusion monitoring stations were installed in eastern, western, and southern coastal areas and have been operated since 1998. In this study, groundwater chemistry data obtained from the seawater intrusion monitoring stations during the period from 2007 to 2009 were analyzed and evaluated. Groundwater was classified into fresh (<1,500 μS/cm), brackish (1,500–3,000 μS/cm), and saline (>3,000 μS/cm) according to EC levels. Among groundwater samples (n = 233), 56, 7, and 37% were classified as the fresh, brackish, and saline, respectively. The major dissolved components of the brackish and saline groundwaters were enriched compared with those of the fresh groundwater. The enrichment of Na+ and Cl− was especially noticeable due to seawater intrusion. Thus, the brackish and saline groundwaters were classified as Ca–Cl and Na–Cl types, while the fresh groundwater was classified as Na–HCO3 and Ca–HCO3 types. The groundwater included in the Na–Cl types indicated the effects of seawater mixing. Ca2+, Mg2+, Na+, K+, SO4 2−, and Br− showed good correlations with Cl− of over r = 0.624. Of these components, the strong correlations of Mg2+, SO4 2−, and Br− with Cl− (r ≥ 0.823) indicated a distinct mixing between fresh groundwater and seawater. The Ca/Cl and HCO3/Cl ratios of the groundwaters gradually decreased and approached those of seawater. The Mg/Cl, Na/Cl, K/Cl, SO4/Cl, and Br/Cl ratios of the groundwaters gradually decreased, and were similar to or lower than those of seawater, indicating that Mg2+, Na+, K+, SO4 2−, and Br−, as well as Cl− in the saline groundwater can be enriched by seawater mixing, while Ca2+ and HCO3 − are mainly released by weathering processes. The influence of seawater intrusion was evaluated using threshold values of Cl− and Br−, which were estimated as 80.5 and 0.54 mg/L, respectively. According to these criteria, 41–50% of the groundwaters were affected by seawater mixing.  相似文献   

14.
This paper is an attempt to study the geochemistry of Akra Kaur Dam (AKD) water, north of Gwadar city, southern Balochistan. Representative water samples were collected from AKD reservoir to assess the suitability of water for drinking and agriculture purposes. The major ionic composition is suggestive for freshwater. The average ionic composition demonstrate SO4 > Ca > Na > Cl > HCO3 > Mg > K. The plots on Piper diagram reflected Ca–Mg–SO4 type of water facies. High Ca/SO4 and Ca/Mg ratios revealed that the water has influence of gypsum dissolution. The negative ratio of chloro-alkaline indices indicated reverse exchange between Ca and Mg in water occurred with Na and K in rocks. The pH, electrical conductivity, total dissolved salts, Ca, Mg, Na, K, HCO3, Cl and SO4 concentrations in the dam water were below the permissible limit, however, Na and SO4 were above the desirable limit, set by the World Health Organization. Important parameters such as residue sodium carbonate, sodium percent, sodium adsorption ratio, permeability index, magnesium content and Kelley’s ratio were calculated to evaluate the suitability of water for irrigation purpose. The result were compared with standard permissible limits and found satisfactory. The health and agriculture hazards of sulphate-bearing water were also discussed.  相似文献   

15.
The study region covers 1,650 km2 of the Mid-Ganga Basin in Bihar, experiencing intensive groundwater draft. The area forms a part of the Gangetic alluvial plain where high incidence of arsenic groundwater contamination (>50 μg/l) has recently been detected. Seventy-seven groundwater samples have been collected and analysed for major ions, iron and arsenic. Arsenic contamination (max 620 μg/l) is confined in hand pump zones (15–35 m) within the newer alluvium deposited during Middle Holocene to Recent age. The older alluvial aquifers are arsenic-safe and recorded maximum concentration as 9 μg/l. Out of 12 hydrochemical facies identified, four have been found arsenic-affected: Ca–HCO3, Mg–HCO3, Ca–Mg–HCO3 and Mg–Ca–HCO3. The geochemical evolution of groundwater, as investigated by graphical interpretation and statistical techniques (correlation, principal component analysis) revealed that dissolution of detrital calcite, dolomite and infiltration of rainwater are the major processes shaping the groundwater chemistry in the newer alluvium. Arsenic and iron showed strong positive correlation. Rainfall infiltration, carrying organic matter from recently accumulated biomass from this flood-prone belt, plays a critical role in releasing arsenic and iron present in the sediments. Geochemical evolution of groundwater in older alluvium follows a different path, where cation-exchange has been identified as a significant process.  相似文献   

16.
 A strong geochemical gradient was observed in the thick overburden aquifer of the Asa drainage basin. Different types of groundwater occur at different (downslope) locations and groundwater table depths. The following sequence was noticed with increasing distance downslope or with increasing groundwater table depth: 1. Ca–Mg–HCO3 water at about 390-m groundwater table elevations or upslope locations. 2. Ca–Mg–HCO3–Cl water at middle-slope locations or groundwater table elevations of about 350 m above sea level; 3. Ca–Mg–SO4–Cl water at downslope locations or groundwater table elevations of about 300 m above sea level. In this basin, changes in the type of water are expected at about every 40–50 m depth from the surface. Statistical analysis via the determination of the correlation coefficient (r) and regression analysis shows that about 80–99% of the variation in groundwater chemistry is accounted for by the topography, using the model presented in this paper. The rate of change in the sequence will depend on the permeability of the aquifer, which determines the rate of groundwater flow and the residence time, and the nature of recharge. Received: 4 February 1997 · Accepted: 22 July 1997  相似文献   

17.
A long mining history and unscientific exploitation of Jharia coalfield caused many environmental problems including water resource depletion and contamination. A geochemical study of mine water in the Jharia coalfield has been undertaken to assess its quality and suitability for domestic, industrial and irrigation uses. For this purpose, 92 mine water samples collected from different mining areas of Jharia coalfield were analysed for pH, electrical conductivity (EC), major cations (Ca2+, Mg2+, Na+, K+), anions (F−, Cl−, HCO3 −, SO4 2−, NO3 −), dissolved silica (H4SiO4) and trace metals. The pH of the analysed mine water samples varied from 6.2 to 8.6, indicating mildly acidic to alkaline nature. Concentration of TDS varied from 437 to 1,593 mg L−1 and spatial differences in TDS values reflect the variation in lithology, surface activities and hydrological regime prevailing in the region. SO4 2− and HCO3 − are dominant in the anion and Mg2+ and Ca2+ in the cation chemistry of mine water. High concentrations of SO4 2− in the mine water of the area are attributed to the oxidative weathering of pyrites. Ca–Mg–SO4 and Ca–Mg–HCO3 are the dominant hydrochemical facies. The drinking water quality assessment indicates that number of mine water samples have high TDS, total hardness and SO4 2− concentrations and needs treatment before its utilization. Concentrations of some trace metals (Fe, Mn, Ni, Pb) were also found to be above the desirable levels recommended for drinking water. The mine water is good to permissible quality and suitable for irrigation in most cases. However, higher salinity, residual sodium carbonate and Mg-ratio restrict its suitability for irrigation at some sites.  相似文献   

18.
Study of the groundwater samples from Tajarak area, western Iran, was carried out in order to assess their chemical compositions and suitability for agricultural purposes. All of the groundwaters are grouped into two categories: relatively low mineralized of Ca–HCO3 and Na–HCO3 types and high mineralized waters of Na–SO4 and Na–Cl types. The chemical evolution of groundwater is primarily controlled by water–rock interactions mainly weathering of aluminosilicates, dissolution of carbonate minerals and cation exchange reactions. Calculated values of pCO2 for the groundwater samples range from 2.34 × 10−4 to 1.07 × 10−1 with a mean value of 1.41 × 10−2 (atm), which is above the pCO2 of the earth’s atmosphere (10−3.5). The groundwater is oversaturated with respect to calcite, aragonite and dolomite and undersaturated with respect to gypsum, anhydrite and halite. According to the EC and SAR the most dominant classes (C3-S1, C4-S1 and C4-S2) were found. With respect to adjusted SAR (adj SAR), the sodium (Na+) content in 90% of water samples in group A is regarded as low and can be used for irrigation in almost all soils with little danger of the development of harmful levels of exchangeable Na+, while in 40 and 37% of water samples in group B the intensity of problem is moderate and high, respectively. Such water, when used for irrigation will lead to cation exchange and Na+ is adsorbed on clay minerals while calcium (Ca2+) and magnesium (Mg2+) are released to the liquid phase. The salinity hazard is regarded as medium to high and special management for salinity control is required. Thus, the water quality for irrigation is low, providing the necessary drainage to avoid the build-up of toxic salt concentrations.  相似文献   

19.
 An integrated geological, geoelectrical and hydrochemical investigation of shallow groundwater occurrence in the Ibadan area, southwestern Nigeria, is presented. The primary objective was to characterise the groundwater in a typical low-latitude environment underlain by Precambrian crystalline basement complex rocks. The dominant rocks comprise suites of gneisses and quartzites. Chemical analyses of the groundwater show that the mean concentration of the cations is in the order Na>Ca>Mg>K while that for the anions is Cl>HCO3>NO3>SO4. Statistical analyses, using the product-moment coefficient of correlation, indicate positive correlations between the following pairs of parameters: TDS and conductivity (r=0.96); Na++Mg2+ and Cl– (r=0.95); Na++K+ and Ca2+ (r=0.43); Na++K+ and HCO3 – (r=0.17); Ca2+ and Mg2+ (r=0.74); Ca2+ and HCO3 – (r=0.33); Ca2++Mg2+ and HCO3 – (r=0.31) and pH and HCO3 – (r=0.54). A very weak negative correlation was recorded between pH and Cl–, with r=–0.003. Five groundwater groups have been identified, namely, (1) the Na-Cl, Na-Ca-Cl, Na-Ca-(Mg)-Cl; (2) the Ca-(Mg)-Na-HCO3-Cl, Na-Ca-HCO3-Cl, and Ca-HCO3-Cl; (3) the Ca-(Mg)-Na-HCO3, Ca-Na-HCO3; (4) Ca-Na-Cl-(SO4)-HCO3 and (5) the Ca-(Mg)-Na-SO4-HCO3. The different groups reflect the diversity of bedrock types and consequently also of the products of weathering. Most of the water sampled is unfit for drinking on account of the high NO3 – content. It can, however, be used for irrigation purposes as the sodium hazard is low while the salinity hazard ranges from low to medium. Resistivity soundings indicate the presence of a thick weathering profile, which could be up to 60 m. Such sites should be the target for any long-term and sustainable groundwater development in the area. Received: 15 April 1998 · Accepted: 4 July 1998  相似文献   

20.
The groundwater flow pattern in the northern portion of GAS (Guarani Aquifer System) is characterized by the existence of four regional recharge areas located in São Paulo, Mato Grosso do Sul and Goiás states. From these areas of recharge the regional flow is radial and directed toward the center of the Paraná Sedimentary Basin. Local discharge occurs in portions of outcrop regions. The groundwater has low mineralization and can be classified as Ca or Ca–Mg–HCO3 type, Na–HCO3 type and Na–HCO3/Cl/SO4 type, this sequence represents the hydrochemical evolution. The mechanisms responsible for this evolution are dissolution of feldspars and removal of the carbonate cement from the sandstone mineral framework, followed by ion exchange, responsible for the increase in the Na concentration and decrease of Ca, and, finally, enrichment in Cl and SO4 derived from underlying aquifer units. The hydrochemical evolution is consistent with diagenetic features that are observed in the sandstones, with the presence of siliceous cement in the outcrop areas, and carbonate cement toward the center of Paraná Basin.  相似文献   

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