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湖北狮子立山锶(铅锌)矿区石英闪长玢岩锆石SHRIMP U-Pb定年及其意义 总被引：4，自引：3，他引：1
湖北狮子立山锶(铅锌)矿床是我国重要的超大型锶矿床之一,产出于鄂东矿集区北部铁山岩体东缘的狮子立山岩体(主要为石英闪长玢岩)与三叠纪蒸发岩地层(嘉陵江组)的接触带或附近。本文对矿区内的石英闪长玢岩与成矿作用之间的关系和该岩体的年代学开展了详细的研究工作。结果表明,狮子立山岩体与锶矿成矿作用可能存在密切的联系,矿床中的部分Sr可能来自于石英闪长玢岩的强烈蚀变。锆石SHRIMP U-Pb的定年工作得到2个石英闪长玢岩样品的形成时代分别为138.6±0.8Ma和138.9±1.2Ma,二者在误差范围内基本一致,这些数据与前人获得的铁山岩体的成岩时代基本一致,暗示本次测得的石英闪长玢岩的样品年龄可靠性较高,且很可能与铁山岩体是同一地质背景下的产物,即形成于区域晚侏罗-早白垩世岩石圈由挤压到伸展的转换环境。狮子立山岩体的侵位地层及矿床中硫同位素组成的特征与程潮和金山店矽卡岩型铁矿具有明显的相似性,暗示在狮子立山矿床附近具有寻找矽卡岩型铁矿床的潜力。 相似文献
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安徽宣城茶亭矿床位于长江中下游成矿带东南缘的南陵-宣城盆地内,是近年来该盆地内新发现的大型斑岩型Cu-Au矿床。石英闪长玢岩是茶亭矿床主要的赋矿岩石,文章从石英闪长玢岩的造岩矿物黑云母入手,利用EMPA及LA-ICP-MS等原位微区分析方法,对黑云母进行了详细的矿物化学分析,旨在查明赋矿石英闪长玢岩形成的物理化学条件,并探讨其成岩成矿意义。分析结果表明:茶亭赋矿石英闪长玢岩中黑云母具有高w(TiO_2)、低w(Al_2O_3)的特征,整体富Mg、贫Fe。黑云母温压计算结果表明,在不同深度上,石英闪长玢岩具有相似的结晶温度及压力,其结晶温度为746～773℃,压力为44～85 MPa,对应深度为1.7～3.3 km,平均为2.47 km,显示石英闪长玢岩侵位深度相对较浅。黑云母中高的氧化系数(0.613～0.864)、高Mg#(0.557～0.864),以及w(MgO)介于14.73%～15.86%,均显示石英闪长玢岩为壳幔混源,并且以幔源为主。黑云母成分显示石英闪长玢岩形成于较高氧逸度条件下。浅部岩体具有较高的X_(Mg)值,表明浅部岩体氧逸度较高,可能指示随着岩浆的不断演化,残余岩浆的氧逸度不断降低。同时,石英闪长玢岩黑云母相对一般斑岩型铜矿具有较高的w(Cu),并且高Cl、低F。这些特征均有利于茶亭Cu-Au矿床的形成。 相似文献
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为查明普朗超大型斑岩铜矿床外围岩体的岩石类型及其地球化学特征,对其外围东部斑岩体的岩石学、岩石地球化学及成岩年代进行了研究。结果表明,外围东部斑岩类型为石英闪长玢岩,缺少二长斑岩;岩石属钙碱性系列;富集轻稀土及Cs、Rb、K等大离子亲石元素,相对亏损Y、Hf、Zr等高场强元素。石英闪长玢岩的侵位年龄为(221.3±0.3)Ma,与I号复式岩体中的闪长玢岩年龄一致。通过与首采区I号复式岩体进行对比,认为外围东部石英闪长玢岩体相当于首采区闪长玢岩体的边缘部位,二者属于同一个侵入体,但在岩石学及岩石化学特征上有一定区别。由于普朗矿区外围东部缺乏主成矿阶段的二长斑岩体,因此不利于斑岩型矿体的形成。 相似文献
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普朗斑岩铜矿床是云南中甸地区最大的斑岩型铜矿床,其成矿作用与普朗复式岩体存在密切的成因联系。对普朗复式岩体成矿的第1期石英闪长玢岩和第2期石英二长斑岩,以及不成矿的第3期闪长玢岩开展了锆石原位微量元素和磷灰石原位主量元素成分的研究。结果表明,锆石Ce/Ce~*值、Ce~(4+)/Ce~(3+)比值和Ce/Nd比值指示,不成矿的第3期闪长玢岩与成矿的第1期石英闪长玢岩的岩浆相对氧化状态大致相当,且明显高于成矿的第2期石英二长斑岩。磷灰石Cl、OH和SO3成分指示,普朗复式岩体3期斑岩具有相似的岩浆含水量,但成矿的第1期石英闪长玢岩和第2期石英二长斑岩较不成矿的第3期闪长玢岩具有更高的岩浆挥发分Cl含量和硫逸度。岩浆的高氧逸度和硫逸度、富水和富挥发分Cl均是形成斑岩铜矿床的关键因素,普朗不成矿的第3期闪长玢岩与成矿的第1期石英闪长玢岩和第2期石英二长斑岩均具有富水和高氧逸度特征,但第3期闪长玢岩较成矿的第1期石英闪长玢岩和第2期石英二长斑岩具有明显更低的岩浆挥发分Cl含量和硫逸度,这很可能是导致第1期石英闪长玢岩和第2期石英二长斑岩成矿,而第3期闪长玢岩不成矿的重要原因之一。 相似文献
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玢岩铁矿是我国重要的铁矿床类型之一,主要产出在富钠质的安山玢岩和闪长玢岩内或接触带中,由于其围岩多为火成岩,给常规的地球物理探测造成诸多影响,很难确定矿体位置及产状,找矿难度较大。电磁法具有勘探深度大、分辨率高等特点,是探测玢岩铁矿可能的重要手段,为评估电磁法在玢岩铁矿探测中的应用效果,作者在物性统计的基础上,结合已知地质资料,构建了玢岩铁矿理论电性模型,通过模型正演及反演,探讨了音频大地电磁、可控源音频大地电磁、瞬变电磁和复电阻率法刻画玢岩铁矿的分辨率和效果。在此基础上,以安徽省泥河铁矿为例,开展了4种电磁法探测试验,获得了泥河铁矿区三维电性结构模型,该模型反映了地层、岩体、构造的基本信息,虽然不能直接指明矿体位置,但是通过圈定闪长玢岩岩体隆起范围,为找矿工作提供了重要线索。试验结果表明,高质量的数据采集、精细的数据处理和有效的反演方式,是电磁法寻找玢岩铁矿重要保障,泥河铁矿的电磁法探测实例可以为长江中下游玢岩铁矿找矿工作提供指导。 相似文献
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新疆东天山玉海铜钼矿区志留纪侵入体岩石成因及构造意义 总被引：1，自引：0，他引：1
文章对东天山玉海铜钼矿区含矿岩体石英闪长(玢)岩及围岩二长花岗岩的成岩年龄进行研究。LAMC-ICP-MS锆石U-Pb定年结果显示石英闪长(玢)岩形成于(427.80±0.98)Ma,即中志留世;二长花岗岩形成于(318.40±0.66)Ma,即晚石炭世。石英闪长(玢)岩w(SiO_2)为58.30%~64.28%,w(Al2O3)为15.24%~17.36%,w(MgO)为1.73%~4.80%,w(Y)为10.20×10~(-6)~17.40×10~(-6),w(Yb)为1.33×10~(-6)~1.98×10~(-6),石英闪长(玢)岩Sr/Y比值为41.58~79.22,(La/Yb)N为4.19~10.04,为类埃达克岩(adakite-like)。石英闪长(玢)岩具轻稀土元素富集、重稀土元素亏损的配分型式,Eu无异常或正异常,富集大离子亲石元素,亏损高场强元素,具有典型岛弧岩浆岩的特征。Sr-Nd同位素(εNd(t)=+5.4~+7.1,(87Sr/86Sr)i=0.703 59~0.703 83)表明其源区是亏损地幔。通过与土屋-延东斑岩矿床含矿岩体的对比研究,认为玉海石英闪长(玢)岩也形成于岛弧环境,但源区可能是俯冲流体改造过的地幔楔。综合区域早古生代岩浆岩的资料,认为大南湖-头苏泉岛弧带早古生代为不成熟弧环境,与准噶尔洋向南俯冲有关。 相似文献
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为讨论石湖金矿的形成与麻棚花岗岩体、石英闪长玢岩脉之间的联系,对花岗闪长岩、石英闪长玢岩进行了U--Pb年代学研究,并分别对花岗闪长岩、石英闪长玢岩、矿化蚀变岩和围岩的地球化学进行了系统测定。麻棚花岗岩体U--Pb年龄为(124.8±1.4)Ma(MSWD=0.74),石英闪长玢岩脉年龄为(127.3±1.1)Ma(MSWD=1.15),但二者地球化学特征表现不同,应有不同起源。地球化学特征表明,麻棚花岗岩与矿化蚀变岩具有较一致的稀土、微量元素配分型式,而与围岩差别大,说明金矿的成矿流体来源与麻棚花岗岩关系密切。此外,花岗闪长岩具高钾钙碱性,且重稀土亏损、轻稀土富集、弱Eu异常、高Sr--Ba和高Sr/Y、La/Yb比值,表明麻棚岩体的形成有幔源岩浆的混入。笔者认为成矿流体和成矿物质来源为幔源岩浆底侵和混合,并以花岗岩浆为载体而迁移上升。结合矿床地质特征,初次提出闪长玢岩脉与矿体时空关系密切,这应是闪长玢岩脉作为隔流体层对来自麻棚花岗岩体的成矿流体具有一定的封闭作用,使得矿化、蚀变富集产出,即岩脉封闭作用。石湖金矿的成岩成矿机制与中生代期间岩石圈减薄的地球动力学背景密切相关,应是一种非造山型金矿。 相似文献
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宁芜盆地卧儿岗铁矿成矿地质特征及找矿方向探讨 总被引：1，自引：0，他引：1
[摘 要] 本文在分析研究卧儿岗铁矿成矿地质背景和矿床地质特征的基础上,探讨了宁芜盆地卧
儿岗铁矿的控矿因素和找矿方向。卧儿岗铁矿位于宁芜断陷盆地NW 向和NNE 向断裂的交汇部位,矿
体主要赋存在浅成、超浅成侵入的辉石闪长玢岩体顶部,严格受岩体制约,认为该矿床属于玢岩型铁矿。
指出在卧儿岗铁矿深部仍有较大找矿空间,在宁芜断陷盆地NW 向和NNE 向断裂构造交汇处,并且发
育有辉石闪长玢岩的部位是寻找玢岩铁矿的有利部位。 相似文献
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新疆蒙库铁矿床稀土元素地球化学及对铁成矿作用的指示 总被引：16，自引：4，他引：16
新疆富蕴县蒙库大型铁矿呈层状、似层状、透镜状赋存于下泥盆统康布铁堡组变质火山-沉积岩系中.矿体中发育矽卡岩,但矽卡岩并不产在侵入岩接触带上.绿帘石、石榴石和矿石的稀土配分模式具有相似性,均为轻稀土富集,正铕异常,基本上无铈异常,暗示它们之间存在成因联系.石榴石稀土配分模式呈折线型,具有明显的正铕异常,石榴石流体包裹体中熔融包裹体、熔流包裹体和气液包裹体共存,表明石榴石矽卡岩具有岩浆成因和热液成因的特征,形成于晶体 熔体 流体三相共存的岩浆-热液过渡阶段.矿床地质特征、矽卡岩矿物和矿石稀土特征表明蒙库铁矿为矽卡岩型矿床. 相似文献
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Exploitation of low-grade iron ore would be quite unique in a South African context as South Africa is well endowed with
high-grade iron ore resources. Low-grade iron ore, defined as containing between 20 and 47% iron, is thought to be the primary
iron-bearing lithology from which most high-grade ore deposits formed, through different processes of enrichment. The low-grade
iron ores in the Northern Province represent meta-banded iron formations (BIFs), with an average iron content of about 36%.
The main iron-bearing mineral is magnetite. The Northern Province ores have to be milled to sizes smaller than 150 μm in order
to liberate the iron minerals from the host rock, and beneficiation is accomplished through a series of magnetic separation
processes. Irrespective of the in situ quality of the ore, final concentrates of exceptionally good quality with more than
69% iron and very low contaminant levels can be produced. This, combined with mass yields of between 40 and 50% and iron recoveries
greater than 80%, are excellent for this type of iron ore deposit. The beneficiation products are suitable for use in iron-
and steel-making processes.
Received: 4 July 1996 / Accepted: 7 January 1997 相似文献
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The Nedagolla meteorite was recognized by Axon to be a rare example of an iron which has been preterrestrially reheated to the point of melting. The dendrite secondary arms are spaced 200 μm apart, implying that Nedagolla solidified and cooled at ~0·02°C/sec. The presence of (Fe, Cr)1-xS inclusions precipitated during cooling in the interdendritic regions and evidence of solute redistribution of Ni, Cr, Co, Si and P are consistent with this cooling rate. Such a rate indicates that Nedagolla cooled very near the surface of its parent ‘body’. Secondary microstructural features including the presence of isothermal taenite and minute phosphide precipitates, which have formed from the dissolution of primary phosphide material, indicate a later reheating to about 750°C for a period of several hours. 相似文献
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Meteoritic iron, iron ore and nickel-iron alloy (either alone or in some cases mixed with alumina, carbonaceous chondrite, potassium carbonate or sodium carbonate) were used to catalyze the reaction of deuterium and carbon monoxide in a closed reaction vessel. The mole ratio of deuterium to carbon monoxide ranged from 1/2:1 to 10:1, the reaction temperature from 195 to 370°C, and the reaction time from 6 to 480 hr. Analysis of the reaction products showed that normal alkanes and alkenes (C11-C25), their monomethyl substituted isomers and aromatic hydrocarbons (e.g. naphthalene, acenaphthene, fluorene, phenanthrene and the methyl derivatives of these hydrocarbons) were synthesized. In addition to the aforementioned hydrocarbons, one reaction product was shown to contain perdeutero normal fatty acids (10:0–16:0). 相似文献
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Transformations of mercury, iron, and sulfur during the reductive dissolution of iron oxyhydroxide by sulfide 总被引：1，自引：0，他引：1
Methylmercury can accumulate in fish to concentrations unhealthy for humans and other predatory mammals. Most sources of mercury (Hg) emit inorganic species to the environment. Therefore, ecological harm occurs when inorganic Hg is converted to methylmercury. Sulfate- and iron-reducing bacteria (SRB and FeRB) methylate Hg, but the effects of processes involving oxidized and reduced forms of sulfur and iron on the reactivity of Hg, including the propensity of inorganic Hg to be methylated, are poorly understood. Under abiotic conditions, using a laboratory flow reactor, bisulfide (HS−) was added at 40 to 250 μM h−1 to 5 g L−1 goethite (α-FeOOH) suspensions to which Hg(II) was adsorbed (30-100 nmol m−2) at pH 7.5. Dissolved Hg initially decreased from 103 or 104 nM (depending on initial conditions) to 10−1 nM, during which the concentration of Hg(II) adsorbed to goethite decreased by 80% and metacinnabar (β-HgS(s)) formed, based on identification using Hg LIII-edge extended X-ray absorption fine structure (EXAFS) spectroscopic analysis. The apparent coordination of oxygens surrounding Hg(II), measured with EXAFS spectroscopy, increased during one flow experiment, suggesting desorption of monodentate-bound Hg(II) while bidentate-bound Hg(II) persisted on the goethite surface. Further sulfidation increased dissolved Hg concentrations by one to two orders of magnitude (0.5 to 10 nM or 30 nM), suggesting that byproducts of bisulfide oxidation and Fe(III) reduction, primarily polysulfide and potentially Fe(II), enhanced the dissolution of β-HgS(s) and/or desorption of Hg(II). Rapid accumulation of Fe(II) in the solid phase (up to 40 μmol g−1) coincided with faster elevation of dissolved Hg concentrations. Fe(II) served as a proxy for elemental sulfur [S(0)], as S(0) was the dominant bisulfide oxidation product coupled to Fe(III) reduction, based on sulfur K-edge X-ray absorption near edge structure (XANES) spectroscopy. In one experiment, dissolved Hg concentrations tracked those of all sulfide species [S(-II)]. These results suggest that S(-II) reacted with S(0) to form polysulfide, which then caused the dissolution of β-HgS(s). A secondary Fe-bearing phase resembling poorly formed green rust was observed in sulfidized solids with scanning electron microscopy, although there was no clear evidence that either surface-bound or mineralized Fe(II) strongly affected Hg speciation. Examination of interrelated processes involving S(-II) and Fe(III) revealed new modes of Hg solubilization previously not considered in Hg reactivity models. 相似文献
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W.T. Parry 《Sedimentary Geology》2011,233(1-4):53-68
Iron oxide concretions are formed from post depositional, paleogroundwater chemical interaction with iron minerals in porous sedimentary rocks. The concretions record a history of iron mobilization and precipitation caused by changes in pH, oxidation conditions, and activity of bacteria. Transport limited growth rates may be used to estimate the duration of fluid flow events. The Jurassic Navajo Sandstone, an important hydrocarbon reservoir and aquifer on the Colorado Plateau, USA, is an ideal stratum to study concretions because it is widely distributed, well exposed and is the host for a variety of iron oxide concretions.Many of the concretions are nearly spherical and some consist of a rind of goethite that nearly completely fills the sandstone porosity and surrounds a central sandstone core. The interior and exterior host-rock sandstones are similar in detrital minerals, but kaolinite and interstratified illite–smectite are less abundant in the interior. Lepidocrocite is present as sand-grain rims in the exterior sandstone, but not present in the interior of the concretions.Widespread sandstone bleaching resulted from dissolution of early diagenetic hematite grain coatings by chemically reducing water that gained access to the sandstone through fault conduits. The iron was transported in solution and precipitated as iron oxide concretions by oxidation and increasing pH. Iron diffusion and advection growth time models place limits on minimum duration of the diagenetic, fluid flow events that formed the concretions. Concretion rinds 2 mm thick and 25 mm in radius would take place in 2000 years from transport by diffusion and advection and in 3600 years if transport was by diffusion only. Solid concretions 10 mm in radius would grow in 3800 years by diffusion or 2800 years with diffusion and advection.Goethite (α-FeO (OH)) and lepidocrocite (γ-FeO (OH)) nucleated on K-feldspar grains, on illite coatings on sand grains, and on pore-filling illite, but not on clean quartz grains. Model results show that regions of detrital K-feldspar in the sandstone that consume H+ more rapidly than diffusion to the reaction site determine concretion size, and spacing is related to diffusion and advection rates of supply of reactants Fe2+, O2, and H+. 相似文献
18.
The origin of bedded iron-ore deposits developed in greenstone belt-hosted (Algoma-type) banded iron formations of the Archean Pilbara Craton has largely been overlooked during the last three decades. Two of the key problems in studying these deposits are a lack of information about the structural and stratigraphic setting of the ore bodies and an absence of geochronological data from the ores. In this paper, we present geological maps for nearly a dozen former mines in the Shay Gap and Goldsworthy belts on the northeastern margin of the craton, and the first U-Pb geochronology for xenotime intergrown with hematite ore. Iron-ore mineralisation in the studied deposits is controlled by a combination of steeply dipping NE- and SE-trending faults and associated dolerite dykes. Simultaneous dextral oblique-slip movement on SE-trending faults and sinistral normal oblique-slip movement on NE-trending faults during initial ore formation are probably related to E–W extension. Uranium–lead dating of xenotime from the ores using the sensitive high-resolution ion microprobe (SHRIMP) suggests that iron mineralisation was the cumulative result of several Proterozoic hydrothermal events: the first at c. 2250 Ma, followed by others at c. 2180 Ma, c. 1670 Ma and c. 1000 Ma. The cause of the first growth event is not clear but the other age peaks coincide with well-documented episodes of orogenic activity at 2210–2145 Ma, 1680–1620 Ma and 1030–950 Ma along the southern margin of the Pilbara Craton and the Capricorn Orogen farther south. These results suggest that high-grade hematite deposits are a product of protracted episodic reactivation of a structural architecture that developed during the Mesoarchean. The development of hematite mineralisation along major structures in Mesoarchean BIFs after 2250 Ma implies that fluid infiltration and oxidative alteration commenced within 100 myr of the start of the Great Oxidation Event at c. 2350 Ma. 相似文献
19.
Nurudeen Kolawole Olasunkanmi Olufemi S. Bamigboye Adebayo Aina 《Arabian Journal of Geosciences》2017,10(24):541
This report details the result of geophysical exploration for iron ore; which involved vertical magnetic intensity (?Z) and gravity measurements, to delineate the geometry and depth extent of the deposit and acquiring quantitative and qualitative information for pre-drilling purposes in Agbado-Okudu. It is located about 3 km from Jakura along Lokoja-Jakura marble quarry and within low latitude precambrian basement complex district of Kogi State, Nigeria. A total of 517 magnetic measurement points along 16 traverses and 330 gravity reading along 11 profiles on the deposit in northeast–southwest azimuth were undertaken. The magnetic and gravity data enhancement involved linear regression curve fitting and fast Fourier transform, which were used to construct residual magnetic (RM) and gravity (RG) anomalies, analytic signal amplitude, Euler deconvolution at varying spectral indices (SI), power spectrum, and source parameter image (SPI), using the submenu of Geosoft Oasis Montaj software. Interpretation of the RM and RG anomalies revealed a primary causative body which perfectly correlates the positive anomalies and iron ore deposit, in form of a horizontal or gently dipping dyke with strike length of 600 m and average width of 110–130 m, within the gneiss complex in the north and trending south of the area. A secondary causative body associated with the negative anomalies and inferred as a vertical/near vertical thin sheet striking northeast–southwest coincided with the granitic and quartzitic intrusion. The NW–SE and E–W lineament trend conformed Kibarian and Liberian orogeny cycles of generally known structural trends in Nigeria, which shows that the iron ore deposit is structurally controlled. Depths to sources were estimated within range ≤ 2–24 m and 37.5–60 m, regarded as shallow and relatively deep depths, respectively. Ten vertical boreholes ranging in depth between 50 and 100 m are recommended, five of which require a priority attention to ascertain the thickness of the primary causative body. 相似文献
20.
河南省安林矽卡岩型铁矿的成岩时代和成矿物质来源探讨 总被引：4，自引：1，他引：3
位于华北克拉通中部的河南省安林铁矿是典型的邯邢式矽卡岩型铁矿,矿体产于闪长质岩石和中奥陶统灰岩的接触带。LA-ICPMS锆石U-Pb定年结果表明安林闪长岩体的侵位年龄为123.38±0.81Ma,略晚于华北克拉通东部地区的含矿岩体,形成于岩石圈大规模减薄伸展时期。但其中含有古老的锆石说明岩浆经历了地壳的混染。闪长质岩石具有相对低SiO2、高Mg#、高碱,富集Ba、Sr和LREE大离子亲石元素,亏损Nb、Ti、Ta等高场强元素的特点,暗示了其形成于岩石圈地幔。岩相学特征以及Harker图解指示了岩浆经历了较强的分离结晶作用,因此推断安林闪长岩可能是软流圈地幔上涌导致富集的岩石圈地幔发生部分熔融形成原始的辉长质岩浆在上升过程中或岩浆房中发生了以铁镁矿物为主的分离结晶作用,同时受到地壳物质的混染的结果。安林地区矿石具有和闪长岩体相似的稀土元素地球化学特征,反映铁的成矿作用与岩浆作用密切相关。矿床中闪长岩体、矽卡岩、矿石和碳酸盐围岩的主量元素对比研究表明钠交代作用引起Na、K、Fe、Si等元素在各岩类间的迁移,其中迁移出的铁为成矿提供了物质基础。安林地区初始岩浆富含水,分离结晶作用使残留岩浆水饱和而发生出溶;且岩浆在演化过程中受到区内膏盐层和碳酸盐地层的混染,促进了岩浆中流体的出溶并使出溶的流体富含Cl-,为有利于铁质活化的富Cl-岩浆流体的形成创造了条件。 相似文献