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1.
Trophic resources are an important control governing carbonate production. Though this importance has long been recognized, no calibration exists to quantitatively compare biogenic assemblages within trophic resource fields. This study presents a field calibration of carbonate producers in a range of settings against high‐resolution in situ measurements of nutrients, temperature and salinity. With its latitudinal extent from 30° to 23° N, the Gulf of California, Mexico, spans the warm‐temperate realm and encompasses nutrient regimes from oligo‐mesotrophic in the south to eutrophic in the north. Accordingly, from south to north carbonates are characterized by: (i) coral‐dominated shallow carbonate factories (5–20 m water depth) with average sea‐surface temperatures of 25 °C (min. 18 °C, max. 31 °C), average salinities of 35·06‰ and average chlorophyll a levels, which are a proxy for nutrients, of 0·25 mg Chl a m?3 (max. 0·48, min. 0·1). (ii) Red algal‐dominated subtidal to inner‐shelf carbonate formation (10–25 m) in the central Gulf of California exhibiting average temperatures of 23 °C (min. 18 °C, max. 30 °C), average salinities of 35·25‰, and average Chl a levels of 0·71 Chl a m?3 (max. 5·62, min. 0). (iii) Molluskan bryozoan‐rich inner to outer shelf factories in the northern Gulf of California (20–50 m) with average sea surface temperatures of only 20 °C (min. 13 °C, max 29 °C), average salinities of 35·01‰, and average contents of 2·2 mg Chl a m?3 (max. 8·38, min. 0). By calibrating sedimentological data with in situ measured oceanographic information in different environments, the response of carbonate producers to environmental parameters was established and extrapolated to carbonates on a global scale. The results demonstrate the importance of recognizing and quantifying trophic resources as a dominant control determining the biogenic composition and facies character of both modern and fossil carbonates.  相似文献   

2.
The Gulf of Tonkin coastline migrated at an average rate of ca 60 m year?1 landward during Holocene sea‐level rise (20 to 8 ka). Due to a combination of rapid coastline migration and undersupply of sand, neither coastal barriers nor tidal sand bars developed at the mouth of the Red River incised valley. Only a 30 to 80 cm thick sandy interval formed at the base of full‐marine deposits. Thus, the river mouth represented a mud‐dominated open funnel‐shaped estuary during transgression. At the base of the valley fill, a thin fluvial lag deposit marks a period of lowered sea‐level when the river did not reach geomorphic equilibrium and was thus prone to erosion. The onset of base‐level rise is documented by non‐bioturbated to sparsely bioturbated mud that occasionally contains pyrite indicating short‐term seawater incursions. Siderite in overlying deposits points to low‐salinity estuarine conditions. The open funnel‐shaped river mouth favoured upstream incursion of seawater that varied inversely to the seasonal strongly fluctuating discharge: several centimetres to a few tens of centimetres thick intervals showing marine or freshwater dominance alternate, as indicated by bioturbational and physical sedimentary structures, and by the presence of Fe sulphides or siderite, respectively. Recurrent short‐term seawater incursions stressed the burrowing fauna. The degree of bioturbation increases upward corresponding to increasing marine influence. The uppermost estuarine sediments are completely bioturbated. The estuarine deposits aggraded on average rapidly, up to several metres kyr?1. Siphonichnidal burrows produced by bivalves, however, document recurrent episodes of enhanced deposition (>0·5 m) and pronounced erosion (<1 m) that are otherwise not recorded. The slope of the incised valley affected the sedimentary facies. In steep valley segments, the marine transgressive surface (equivalent to the onset of full‐marine conditions) is accentuated by the Glossifungites ichnofacies, whereas in gently sloped valley segments the marine transgressive surface is gradational and bioturbated. Marine deposits are completely bioturbated.  相似文献   

3.
Aeolian sand and dust in polar regions are transported offshore over sea ice and released to the ocean during summer melt. This process has long been considered an important contributor to polar sea floor sedimentation and as a source of bioavailable iron that triggers vast phytoplankton blooms. Reported here are aeolian sediment dispersal patterns and accumulation rates varying between 0·2 g m?2 yr?1 and 55 g m?2 yr?1 over 3000 km2 of sea ice in McMurdo Sound, south‐west Ross Sea, adjacent to the largest ice free area in Antarctica. Sediment distribution and the abundance of southern McMurdo Volcanic Group‐derived glass, show that most sediment originates from the McMurdo Ice Shelf and nearby coastal outcrops. Almost no sediment is derived from the extensive ice free areas of the McMurdo Dry Valleys due to winnowed surficial layers shielding sand‐sized and silt‐sized material from wind erosion and because of the imposing topographic barrier of the north‐south aligned piedmont glaciers. Southerly winds of intermediate strength (ca 20 m sec?1) are primarily responsible for transporting sediment northwards and offshore. The results presented here indicate that sand‐sized sediment does not travel more than ca 5 km offshore, but very‐fine sand and silt grains can travel >100 km from source. For sites >10 km from the coast, the mass accumulation rate is relatively uniform (1·14 ± 0·57 g m?2 yr?1), three orders of magnitude above estimated global atmospheric dust values for the region. This uniformity represents a sea floor sedimentation rate of only 0·2 cm kyr?1, well below the rates of >9 cm kyr?1 reported for biogenic‐dominated sedimentation measured over much of the Ross Sea. These results show that, even for this region of high‐windblown sediment flux, aeolian processes are only a minor contributor to sea floor sedimentation, excepting areas proximal to coastal sources.  相似文献   

4.
Seagrasses are marine angiosperms that form extensive submarine meadows in the photic zone where carbonate producing biota dwell as epiphytes on the leaves or as infaunal forms, and act as prolific carbonate sediment factories. Because seagrasses have a low preservation potential and records of exceptionally well‐preserved and plant material from marine settings are rare, these palaeoenvironments are difficult to identify in the rock record. Consequently, sedimentological and palaeontological proxies are the main indicators of the presence of seagrass‐dominated ecosystems. This work investigates the skeletal assemblage of Modern (Maldivian and western Mediterranean) and fossil (Eocene; Apula and Oman carbonate platforms and Oligocene; Malta platform) seagrass examples to characterize the skeletal assemblage of modern and fossil seagrasses. Two main types of grains, calcareous algae and foraminifera, constitute around 50% of the bioclastic sediment in both tropical Maldivian and temperate Mediterranean scenarios. However, in the tropical setting they are represented by green algae (Halimeda), while in the Mediterranean they are represented by corallinacean red algae. In contrast, in the Eocene examples, the foraminifera are the most conspicuous group and the green algae are also abundant. The opposite occurs in the Maltese Chattian, which is dominated by coralline algae (mean 42%), although the foraminifera are still abundant. It is suggested to use the term foralgal to identify the seagrass skeletal assemblage. To discriminate between red algae and green algae dominance, the introduction of the prefixes ‘GA’ (green algae) and ‘RA’ (red algae) is proposed. The investigated examples provide evidence that the green algae–foralgal assemblage is typical of tropical, not excessively dense seagrass meadows, characterized by a well‐illuminated substrate to support the development and calcification of the Halimeda thallus. Contrarily, the red algae‐foralgal assemblage is typical of high density tropical to subtropical seagrass meadows which create very dense oligophotic conditions on the sea floor or in temperate settings where Halimeda cannot calcify.  相似文献   

5.

Holocene sediments from southern Spencer Gulf are cool‐water carbonate‐rich gravels and sands, dominated by molluscs and Bryozoa. Five sedimentary fades are recognized: (i) molluscan gravel; (ii) branching coralline‐algal gravel, associated with shallow partially protected environments; (iii) molluscan‐biyozoan sand; (iv) mixed bioclastic sand, representative of the deeper central region of the lower gulf; and (v) bryozoan gravel, an isolated fades developed in a semi‐protected micro‐environment. The southern gulf is characterized by complex oceanographic conditions together with variations in water depth and substrate. The sediments share the characteristics of both the southern shelf and upper Spencer Gulf. Grain‐size distribution and sedimentary facies are controlled by a combination of all the above processes. Past sea level fluctuations are recognized from sea floor strand‐line deposits. The relic component of the palimpsest sediments has eroded from the Pleistocene aeolianite dunes. The sediments, therefore, reflect both the modern marine and past environments.  相似文献   

6.
Widespread use of septic tanks in the Florida Keys increase the nutrient concentrations of limestone groundwaters that discharge into shallow nearshore waters, resulting in coastal eutrophication. This study characterizes watershed nutrient inputs, transformations, and effects along a land-sea gradient stratified into four ecosystems that occur with increasing distance from land: manmade canal systems (receiving waters of nutrient inputs), seagrass meadows, patch reefs, and offshore bank reefs. Soluble reactive phosphorus (SRP), the primary limiting nutrient, was significantly elevated in canal systems compared to the other ecosystems, while dissolved inorganic nitrogen (DIN; NH4 + and NO3 ?) a secondary limiting nutrient, was elevated both in canal systems and seagrass meadows. SRP and NH4 + concentrations decreased to low concentrations within approximately 1 km and 3 km from land, respectively. DIN and SRP accounted for their greatest contribution (up to 30%) of total N and P pools in canals, compared to dissolved organic nitrogen (DON) and dissolved organic phosphorus (DOP) that dominated (up to 68%) the total N and P pools at the offshore bank reefs. Particulate N and P fractions were also elevated (up to 48%) in canals and nearshore seagrass meadows, indicating rapid biological uptake of DIN and SRP into organic particles. Chlorophylla and turbidity were also elevated in canal systems and seagrass meadows; chlorophylla was maximal during summer when maximum watershed nutrient input occurs, whereas turbidity was maximal during winter due to seasonally maximum wind conditions and sediment resuspension. DO was negatively correlated with NH4 + and SRP; hypoxia (DO<2.5 mg l?1) frequently occurred in nutrient-enriched canal systems and seagrass meadows, especially during the warm summer months. These findings correlate with recent (<5 years) observations of increasing algal blooms, seagrass epiphytization and die-off, and loss of coral cover on patch and bank reef ecosystems, suggesting that nearshore waters of the Florida Keys have entered a stage of critical eutrophication.  相似文献   

7.
Spatial and temporal patterns of distribution and abundance were examined for postsettlement sciaenids collected from seagrass meadows in the Aransas Estuary, Texas. Overall, 5443 sciaenid larvae and early juveniles were identified from biweekly epibenthic sled collections taken from August 1994 to August 1995. Eight species were present in seagrass meadows, with five accounting for over 99.9% of sciaenids collected: silver perch (Bairdiella chrysoura), spotted seatrout (Cynoscion nebulosus), spot (Leiostomus xanthurus), Atlantic croaker (Micropogonias undulatus), and red drum (Sciaenops ocellatus). Settlement to seagrass meadows was partitioned temporally with little overlap among the five species. Postsettlers from inshore spawners (B. chrysoura, C. nebulosus, S. ocellatus) inhabited seagrass meadows during the spring and summer, while individuals from offshore spawners (L. xanthurus, M. undulatus) were present in the late fall and winter. Densities ofB. chrysoura, C. nebulosus, S. ocellatus were highest for small individuals (4–8 mm SL) and these taxa remained in seagrass sites through the early juvenile stage. Conversely,L. xanthurus andM. undulatus maintained longer pelagic periods and generally entered seagrass meadows at larger sizes (10–14 mm SL). Moreover, these taxa were only temporary residents of selected seagrass meadows, apparently migrating to alternative habitats shortly after arrival. During peak settlement, mean and maximum densities among species ranged from 0.1 m?2 to 0.8 m?2 and 0.7 m?2 to 23.8 m?2, respectively. Density and mean size of possettlement sciaenids differed significantly between seagrass species (Halodule wrightii, Thalassia testudinum) and among sites within the estuary.  相似文献   

8.

Surficial deposits of the tidally influenced Australian shelf seas exhibit a variation in fades related to energy gradient. These deposits comprise a high energy gravelly facies, a mobile sand sheet facies and a low energy muddy sand facies. Such a facies distribution conforms generally with the existing model of continental shelf tidal sedimentation, derived for the west European tidal seas. However, the carbonate rich and mainly warm water deposits of the Australian shelf differ from the mainly quartzose and temperate cold‐water deposits of the European type case in terms of: (i) the role of seagrasses in trapping fine‐grained sediment; and (ii) the relative importance of the production of carbonate mud by mechanical erosion of carbonate grains. Seagrasses in Spencer Gulf, Gulf of St Vincent and Torres Strait are located in regions of strong tidal currents, associated with bedforms and gravel lag deposits. Thus, in the case of tropical carbonate shelves, seagrass deposits containing fine‐grained and poorly sorted sediments are located in close proximity to high energy gravel and mobile sand facies. In contrast, the European model (for temperate, siliciclastic shelves) places facies in a regional gradient with a wide separation (in the order of 50–100 km).

Of the locations reviewed, the Gulf of St Vincent, Bass Strait, southern Great Barrier Reef, Torres Strait and Gulf of Carpentaria exhibit zones of carbonate mud accumulation. The production and winnowing of carbonate mud from the mobile sand facies is a factor that must be taken into account in the assessment of a sediment budget for this facies, and which is of relatively greater importance for carbonate shelves. Insufficient data are presently available from the macrotidal North West Shelf to test the applicability of the model to this region.  相似文献   

9.
Seaward of the Bosphorus Strait, the south‐west Black Sea shelf is dominated by the world's largest channel network maintained by a quasi‐continuous saline (ca 35 → 31 psu) underflow. Calculations indicate that >85% of the initial discharge of ca 104 m3s?1 spills overbank before the shelf edge. This paper documents interaction of the overspill with sea bed topography using multibeam bathymetry, echo‐sounder images of the water column, conductivity–temperature–depth profiles and sediment cores. Overbank spill is widespread, particularly through crevasse channels and on the middle shelf where confinement by channel banks is negligible. Towards the outer shelf, the wind‐driven Rim Current advects mud along the shelf, contributing to levée successions and deposition on stoss sides of elongate transverse ridges. Echo‐sounder profiles reveal metre‐scale eddies over megaflutes, and breaking lee waves and internal hydraulic jumps over ridges. Megaflutes reach 600 m long and 7 m deep, yet form where the underflow, outside the flute, is no thicker than ca 2 to 5 m. Two types of elongate seaward‐facing ridges are recognized. Type 1 ridges, 2 to 5 m high, consist of bivalve‐rich muddy sand in low‐angle (3·5° to 6°) cross‐sets created by the underflow. Type 2 ridges, ca 5 m high, have crests up to 2 km long and a buried wedge‐shaped foundation (the ‘ridge‐core’) comprised of facies similar to Type 1 ridges. These ridge‐cores are blanketed on the landward side by stratified muds, and are capped by obliquely oriented ribs supporting a diverse benthic community. This facies distribution is interpreted to result from stoss‐side and lee‐side velocity and turbulence fluctuations induced by internal hydraulic jumps and breaking lee waves in overspilling portions of the underflow. Experimental results published by W.H. Snyder and co‐workers effectively explain ridge evolution and flow across the ridges, and therefore can be applied with confidence to less easily studied deep‐marine settings swept by turbidity currents.  相似文献   

10.
Creep and saltation are the primary modes of surface transport involved in the fluid‐like movement of aeolian sands. Although numerous studies have focused on saltation, few studies have focused on creep, primarily because of the experimental difficulty and the limited amount of theoretical information available on this process. Grain size and its distribution characteristics are key controls on the modes of sand movement and their transport masses. Based on a series of wind tunnel experiments, this paper presents new data regarding the saltation flux, obtained using a flat sampler, and on the creeping mass, obtained using a specifically designed bed trap, associated with four friction velocities (0·41, 0·47, 0·55 and 0·61 m sec?1). These data yielded information regarding creeping and saltating sand grains and their particle size characteristics at various heights, which led to the following conclusions: (i) the creeping masses increased as a power function (q = ?1·02 + 14·19u*3) of friction wind velocities, with a correlation (R2) of 0·95; (ii) the flux of aeolian sand flow decreases exponentially with increasing height (q = a exp(–z/b)) and increases as a power function (q = ?26·30 + 428·40 u*3) of the friction wind velocity; (iii) the particle size of creeping sand grains is ca 1·15 times of the mean diameter of salting sand grains at a height of 0 to 2 cm, which is 1·14 times of the mean diameter of sand grains in a bed; and (iv) the mean diameter of saltating sand grains decreases rapidly with increasing height whereas, while at a given height, the mean diameter of saltating sand grains is positively correlated with the friction wind velocity. Although these results require additional experimental validation, they provide new information for modelling of aeolian sand transport processes.  相似文献   

11.
In November 2004, we evaluated the effect of Hurricane Ivan on seagrass meadows in Alabama by surveying all coastal locations known to support seagrass prior to Hurricane Ivan's Iandfall in September 2004. We found that 82% of the sites containing seagrass in 2002 still supported seagrass, and that, as in 2002, the most abundant species wasHalodule wrightii (shoalgrass). We also found more sites containingRuppia maritima (widgeongrass) than previously recorded. We confirmed the existence ofThalassia testudinum (turtlegrass) in Little Lagoon, Alabama, whose first record in the state had been noted in 2002. A resurvey of the western half of Alabama's coastal waters in October 2005 after Hurricane Katrina found no loss of seagrass, with all sites that supported seagrass in 2004 still containing seagrass in 2005. There was no major loss of Alabama's seagrass resources due to Hurricanes Ivan or Katrina, even though both category 3 hurricanes severely affected the northern Gulf Coast.  相似文献   

12.
The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.  相似文献   

13.
Thick bay‐fill sequences that often culminate in strandplain development serve as important sedimentary archives of land–ocean interaction, although distinguishing between internal and external forcings is an ongoing challenge. This study employs sediment cores, ground‐penetrating radar surveys, radiocarbon dates, palaeogeographic reconstructions and hydrodynamic modelling to explore the role of autogenic processes – notably a reduction in wave energy in response to coastal embayment infilling – in coastal evolution and shoreline morphodynamics. Following a regional 2 to 4 m highstand at ca 5·8 ka, the 75 km2 Tijucas Strandplain in southern Brazil built from fluvial sediments deposited into a semi‐enclosed bay. Holocene regressive deposits are underlain by fluvial sands and a Pleistocene transgressive–regressive sequence, and backed by a highstand barrier‐island. The strandplain is immediately underlain by 5 to 16 m of seaward‐thickening, fluvially derived, Holocene‐age, basin‐fill mud. Several trends are observed from the landward (oldest) to the seaward (youngest) sections of the strandplain: (i) the upper shoreface and foreshore become finer and thinner and shift from sand‐dominated to mud‐dominated; (ii) beachface slopes decrease from >11° to ca 7°; and (iii) progradation rates increase from 0·4 to 1·8 m yr?1. Hydrodynamic modelling demonstrates a correlation between progressive shoaling of Tijucas Bay driven by sea‐level fall and sediment infilling and a decrease in onshore wave‐energy transport from 18 to 4 kW m?1. The combination of allogenic (sediment supply, falling relative sea‐level and geology) and autogenic (decrease in wave energy due to bay shoaling) processes drove the development of a regressive system with characteristics that are rare, if not unique, in the Holocene and rock records. These findings demonstrate the complexities in architecture styles of highstand and regressive systems tracts. Furthermore, this article highlights the diverse internal and external processes and feedbacks responsible for the development of these intricate marginal marine sedimentary systems.  相似文献   

14.
Oligo–Miocene carbonates associated with the Padthaway Ridge form the southern margin of the Murray Basin, South Australia. The carbonates are a thin, somewhat condensed succession of echinoid and bryozoan‐rich limestones that record accumulation in the complex of islands and seaways and progressive burial of the Ridge through time. The rocks are grainy to muddy bioclastic packstones, grainstones and floatstones, composed of infaunal echinoderms, bryozoans, coralline algae and benthic foraminifera, with lesser contributions from molluscs and serpulid worms. Locally as much as half of these skeletal components are Fe‐stained, relict grains that imbue the lithologies with a conspicuous yellow to orange hue. This variably lithified succession is partitioned into metre‐scale, firmground‐bounded and hardground‐bounded beds textured by extensive Thalassinoides burrows. Dominant lithologies are interpreted as temperate seagrass facies. Limestones contain attributes indicative of both seagrass‐dominated palaeoenvironments and carbonate production and accumulation on unconsolidated, barren sandflat palaeoenvironments. Together these two depositional systems are thought to have generated a single multigenerational, amalgamated facies recording sedimentation within a complex temperate seagrass environment. Limestones overlying the Padthaway Ridge reflect a gradually warming climate, increasing water temperature and decreasing nutrient content, within the framework of a ridge gradually being buried in sediment. This succession from cool–temperate to warm–temperate to subtropical through time permits recognition of the relative influence of changing oceanography on a seagrass‐dominated shallow inter‐island sea floor. Criteria are proposed herein to enable future recognition of similar temperate seagrass facies in Cenozoic limestones elsewhere.  相似文献   

15.
Bermuda is a reef atoll along the northern edge of Caribbean coral province. Although investigated by seismic and some shallow drilling, the Pleistocene marine depositional geohistory is poorly constrained. Islands along the southern rim are built by tropical calcareous aeolianites that range in age from Holocene to early Pleistocene (ca 880 kyr). These dunes are composed of particles that were derived from adjacent Pleistocene marine environments at the time of formation. Thus, the aeolianites should contain a record of marine deposition through the Early to Late Pleistocene. Carbonate grains from all aeolian deposits can, via Ward cluster analysis, be separated into two distinct groups: (i) a Halimeda‐rich group; and (ii) a crustose coralline‐rich group. Distribution of these two groups is interpreted to broadly reflect low‐energy (lagoonal) and high‐energy marginal reef (coralline algae and cup‐reef) environments, respectively. Unlike the beach sources, coral particles are perplexingly absent in the aeolianites. This conundrum is interpreted to partly reflect the domal nature of Bermudan corals, which are not incorporated into aeolian deposits due to their relatively large size. Aeolianites from Marine Isotope Stages 7, 9 and 11 record sediments produced in adjacent shallow marine settings that were similar to those present today. The spatially consistent sediment trends are not, however, present in aeolianites from Marine Isotope Stage 5E, where the aeolian bioclastic components are uniformly rich in Halimeda along both southern and northern shores. Such a distribution, where coralline‐rich sediments would be expected, suggests an extrinsic oceanographic control, interpreted herein to be elevated seawater temperature brought in by the Gulf Stream. This interpretation is consistent with palaeozoological studies of Bermuda, as well as North America, the Mediterranean, Japan and Western Australia.  相似文献   

16.
We present in this article a rapid method for B extraction, purification and accurate B concentration and δ11B measurements by ID‐ICP‐MS and MC‐ICP‐MS, respectively, in different vegetation samples (bark, wood and tree leaves). We developed a rapid three‐step procedure including (1) microwave digestion, (2) cation exchange chromatography and (3) microsublimation. The entire procedure can be performed in a single working day and has shown to allow full B recovery yield and a measurement repeatability as low as 0.36‰ (± 2s) for isotope ratios. Uncertainties mostly originate from the cation exchange step but are independent of the nature of the vegetation sample. For δ11B determination by MC‐ICP‐MS, the effect of chemical impurities in the loading sample solution has shown to be critical if the dissolved load exceeds 5 μg g?1 of total salts or 25 μg g?1 of DOC. Our results also demonstrate that the acid concentration in the sample loading solution can also induce critical isotopic bias by MC‐ICP‐MS if chemistry of the rinsing‐, bracketing calibrator‐ and sample solutions is not thoroughly adjusted. We applied this method to provide a series of δ11B values of vegetal reference materials (NIST SRM 1570a = 25.74 ± 0.21‰; NIST 1547 = 40.12 ± 0.21‰; B2273 = 4.56 ± 0.15‰; BCR 060 = ?8.72 ± 0.16‰; NCS DC73349 = 16.43 ± 0.12‰).  相似文献   

17.
This study presents two matrix‐matched reference materials developed for petroleum Re‐Os measurements. We present the Re and Os mass fractions and 187Re/188Os and 187Os/188Os values (ratio of the number of atoms of the isotopes) for repeatedly measured aliquots (ca. 120–150 mg test portions) of the NIST Research Material 8505 (RM 8505) crude oil, and its asphaltene and maltene fractions, and ~ 90 g of homogeneous asphaltene powder isolated from this oil. Measurements were performed using the Carius tube‐isotope dilution negative‐thermal ionisation mass spectrometry methodology. The RM 8505 crude oil contains 1.98 ± 0.07 ng g?1 Re and 25.0 ± 1.1 pg g?1 Os, with Re‐Os isotope amount ratios of 452 ± 6 for 187Re/188Os and 1.51 ± 0.01 for 187Os/188Os (n = 20, 95% conf.). The homogeneous asphaltene sample contains 16.52 ± 0.10 ng g?1 Re and 166.0 ± 0.9 pg g?1 total Os, and possesses isotope amount ratios of 574 ± 3 for 187Re/188Os and 1.64 ± 0.01 for 187Os/188Os (n = 24, 95% conf.). The intermediate precision of these data makes the RM 8505 whole oil and the (~ 90 g) homogenised asphaltene appropriate petroleum matrix‐matched reference materials for Re‐Os measurements. The asphaltene fraction of the oil is the main carrier of Re and Os of the RM 8505 whole oil, and caution is suggested in using asphaltene and maltene fractions of a single oil for Re‐Os geochronology.  相似文献   

18.
Palaeotemperature estimates from the oxygen‐isotope compositions of belemnites have been hampered by not knowing ancient seawater isotope compositions well enough. We have tackled this problem using Mg/Ca as a proxy for temperature and here, we present a ~2 Ma record of paired Mg/Ca and δ18O measurements of Jurassic (Early Pliensbachian) belemnites from the Asturian basin as a palaeo‐proxy of seawater oxygen‐isotope composition. From the combined use of the two approaches, we suggest a δ18Ow composition of about ?0.1‰ for the Jamesoni–Ibex zones. This value may have been increased by about 0.6‰ during the Davoei Zone due to the effect of waters with a different δ18Ow composition. These findings illustrate the inaccuracy of using a globally homogeneous ice‐free value of δ18Ow = ?1‰ for δ18Ocarb‐based palaeotemperature reconstructions. Our data suggest that previous palaeotemperatures calculated in the region from δ18O values of belemnites may have been underestimated as the seawater oxygen isotopic composition could have been higher.  相似文献   

19.
This study reports a robust procedure that permits precise measurement of all fourteen naturally occurring rare earth element (REE) concentrations, present at ng kg?1 to sub ng kg?1 levels, in ~ 100 ml seawater. This procedure is simple and can be routinely applied to measure seawater REEs with relatively high sample throughput. The procedure involves addition of a 142Ce‐145Nd‐171Yb‐enriched spike mixture, iron co‐precipitation, REE purification with chromatographic separation and the use of a magnetic‐sector‐field ICP‐MS (Element 2) coupled with a desolvating sample introduction system (Aridus 1). Critical steps of the procedure, including co‐precipitation pH and matrix removal, have been optimised through a set of experiments described here. The accuracy of the new procedure was assessed against a gravimetric mixture of REEs, and the precision was demonstrated by repeated measurement of two well‐mixed natural seawaters. Repeated analyses of these seawater reference materials (RMs), using ~ 100 ml seawater for each aliquot, indicate precision of 3% (1s) for the REEs. Measured REE concentrations of two uncertified seawater RMs (CASS‐4 and NASS‐5) are consistent with published values, and REE concentrations of the GEOTRACES intercalibration samples show good agreement with those reported by other participant laboratories. REE concentrations for other intercalibration samples (SAFe and Arctic PS70) are also reported.  相似文献   

20.
The Miocene to Modern Baram Delta Province is a highly efficient source to sink system that has accumulated 9 to 12 km of coastal–deltaic to shelf sediments over the past 15 Myr. Facies analysis based on ca 1 km of total vertical outcrop stratigraphy, combined with subsurface geology and sedimentary processes in the present‐day Baram Delta Province, suggests a ‘storm‐flood’ depositional model comprising two distinct periods: (i) fair‐weather periods are dominated by alongshore sediment reworking and coastal sand accumulation; and (ii) monsoon‐driven storm periods are characterized by increased wave‐energy and offshore‐directed downwelling storm flow that occur simultaneously with peak fluvial discharge caused by storm precipitation (‘storm‐floods’). The modern equivalent environment has the following characteristics: (i) humid‐tropical monsoonal climate; (ii) narrow (ca <100 km) and steep (ca 1°), densely vegetated, coastal plain; (iii) deep tropical weathering of a mudstone‐dominated hinterland; (iv) multiple independent, small to moderate‐sized (102 to 105 km2) drainage basins; (v) predominance of river‐mouth bypassing; and (vi) supply‐dominated shelf. The ancient, proximal part of this system (the onshore Belait Formation) is dominated by strongly cyclical sandier‐upward successions (metre to decametre‐scale) comprising (from bottom to top): (i) finely laminated mudstone with millimetre‐scale silty laminae; (ii) heterolithic sandstone–mudstone alternations (centimetre to metre‐scale); and (iii) sharp‐based, swaley cross‐stratified sandstone beds and bedsets (metre to decimetre‐scale). Gutter casts (decimetre to metre‐scale) are widespread, they are filled with swaley cross‐stratified sandstone and their long axes are oriented perpendicular to the palaeo‐shoreline. The gutter casts and other associated waning‐flow event beds suggest that erosion and deposition was controlled by high‐energy, offshore‐directed, oscillatory‐dominated, sediment‐laden combined flows within a shoreface to delta front setting. The presence of multiple river mouths and exceptionally high rates of accommodation creation (characteristic of the Neogene to Recent Baram Delta Province; up to 3000 m Ma−1), in a ‘storm‐flood’‐dominated environment, resulted in a highly efficient and effective offshore‐directed sediment transport system.  相似文献   

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