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1.
New data on the mineral composition and the first data on the geochemical composition of ores of the Rogovik gold-silver deposit (Omsukchan ore district, northeastern Russia) have been obtained. Study of the regularities of the spatial distribution of ore mineralization shows that the deposit ores formed in two stages. Epithermal Au-Ag ores of typical poor mineral and elemental compositions were generated at the early volcanic stage. The major minerals are low-fineness native gold, electrum, acanthite, silver sulfosalts, kustelite, and pyrite. The typomorphic elemental composition of ores is as follows: Au, Ag, Sb, As, Se, and Hg. The content of S is low, mostly < 1%. Silver ores of more complex mineral and elemental compositions were produced under the impact of granitoid intrusion at the late volcanoplutonic stage. The major minerals are high-Hg kustelite and native silver, silver sulfosalts and selenides, fahlore, pyrite, chalcopyrite, galena, and sphalerite. The typomorphic elemental composition of ores is as follows: Ag, As, Sb, Se, Hg, Pb, Zn, Cu, and B. The content of S is much higher than 1%. The ores also have elevated contents of Mo, Ge, F, and LREE (La, Ce, and Nd). At the volcanoplutonic stage, polychronous Au-Ag ores formed at the sites of the coexistence of silver and epithermal gold-silver mineralization. Their specific feature is a multicomponent composition and a strong variability in chemical composition (both qualitative and quantitative). Along with the above minerals, the ores contain high-Hg gold, hessite, argyrodite, canfieldite, orthite, fluorapatite, and arsenopyrite. At the sites with strongly rejuvenated rocks, the ores are strongly enriched in Au, Ag, Hg, Cu, Pb, Zn, Ge, Se, La, Ce, Nd, S, and F and also contain Te and Bi. The hypothesis is put forward that the late silver ores belong to the Ag-complex-metal association widespread in the Omsukchan ore district. A close relationship between the ores of different types and their zonal spatial distribution have been established. In the central part of the Rogovik deposit, epithermal Au-Ag ores are widespread in the upper horizons, Ag ores are localized in the middle horizons, and rejuvenated polyassociation Au-Ag ores occur at the sites (mostly deep-seated) with ore-bearing structures of different ages.  相似文献   

2.
The first data on native silver from the Rogovik Au–Ag deposit in northeastern Russia are presented. The deposit is situated in central part of the Okhotsk–Chukchi Volcanic Belt (OCVB) in the territory of the Omsukchan Trough, unique in its silver resources. Native silver in the studied ore makes up finely dispersed inclusions no larger than 50 μm in size, which are hosted in quartz; fills microfractures and interstices in association with küstelite, electrum, acanthite, silver sulfosalts and selenides, argyrodite, and pyrite. It has been shown that the chemical composition of native silver, along with its typomorphic features, is a stable indication of the various stages of deposit formation and types of mineralization: gold–silver (Au–Ag), silver–base metal (Ag–Pb), and gold–silver–base metal (Au–Ag–Pb). The specificity of native silver is expressed in the amount of trace elements and their concentrations. In Au–Ag ore, the following trace elements have been established in native silver (wt %): up to 2.72 S, up to 1.86 Au, up to 1.70 Hg, up to 1.75 Sb, and up to 1.01 Se. Native silver in Ag–Pb ore is characterized by the absence of Au, high Hg concentrations (up to 12.62 wt %), and an increase in Sb, Se, and S contents; the appearance of Te, Cu, Zn, and Fe is notable. All previously established trace elements—Hg, Au, Sb, Se, Te, Cu, Zn, Fe, and S—are contained in native silver of Au–Ag–Pb ore. In addition, Pb appears, and silver and gold amalgams are widespread, as well as up to 24.61 wt % Hg and 11.02 wt % Au. Comparison of trace element concentrations in native silver at the Rogovik deposit with the literature data, based on their solubility in solid silver, shows that the content of chalcogenides (S, Se, Te) exceeds saturated concentrations. Possible mechanisms by which elevated concentrations of these elements are achieved in native silver are discussed. It is suggested that the appearance of silver amalgams, which is unusual for Au–Ag mineralization not only in the Omsukchan Trough, but also in OCVB as a whole, is caused by superposition of the younger Dogda–Erikit Hg-bearing belt on the older Ag-bearing Omsukchan Trough. In practice, the results can be used to determine the general line of prospecting and geological exploration at objects of this type.  相似文献   

3.
广东英德东山楼金银矿区处于东西向佛冈构造岩浆岩带和北北东向吴川-四会深大断裂带交汇部位旁侧、大镇铜多金属矿田北部,成矿条件十分有利。1∶5万水系沉积物测量显示了较好Pb、Zn、Au、Ag、As等异常。对1∶5万异常进一步解析,在异常浓集中心开展1∶1万土壤测量,共圈定两个综合异常,主要异常元素为Au、Ag、As、Pb,其次为Zn、Sb。通过对1∶1万土壤测量资料进行剖析,结合矿区地质特征,初步认为该区土壤综合异常AP1、AP2具有较大的金银矿找矿潜力。  相似文献   

4.
The geology and genesis of a large high-grade silica deposit is considered. It occurs in the form of a quartzite layer, 20–50 m thick, extending for 8 km in conformity with the host Upper Proterozoic silicate-carbonate metasedimentary rocks. The average content of SiO2 is 99.2%. It has been established that quartzite was formed by metasomatic silicification of sandstone during metamorphism of the carbonate-silicate sequence. The rocks were silicified by infiltration acid leaching, whereas long-term refinement of quartzite was provided by diffusion in finely dispersed capillary-porous systems, where the energy of the solution-solid phase interface was important. In the course of metasomatic migration of components, Au, Ag, Pb, Zn, Fe, and other elements were removed from quartzite and formed gold-sulfide mineralization in contact zones of the quartzite body. This opens up opportunities for discovering economic Au-Ag and Pb-Zn ores in the ore field.  相似文献   

5.
闽东北地区位于政和—大埔断裂带东侧。在晚侏罗世—早白垩世,该地区经历了十分强烈的火山活动,形成了分布广泛、厚度巨大的陆相火山沉积岩系,其下伏基底地层中的迪口组与福建省金矿或矿化关系极为密切,是福建省重要的含金矿源层,有较好的成矿条件。水系沉积物异常重现性试验及元素的表生迁移研究表明,不同采样批次、不同季节、不同年份在相同采样介质和采样点获得的主要成矿元素异常重现性较好。与全国水系沉积物元素平均含量相比,Au、Ag、Pb、Zn异常较明显。水系沉积物元素异常统计揭示,Au、Ag、As、Sb的成矿能力评价最高。这种元素异常组合表明,与火山岩有关的金矿是本区最有利的成矿矿种,并在闽东北地区经钻探验证,取得了良好的找矿效果。  相似文献   

6.
西南大面积低温成矿域:研究意义、历史及新进展   总被引:8,自引:0,他引:8  
我国西南大面积低温成矿域是目前世界上公认的2个大面积低温成矿域之一,其面积之大(约100万km^2)、包含的矿种之多(Au、Hg、sb、As、P、Pb—Zn、Ag以及萤石、冰洲石、水晶、分散元素等)、矿床组成和组合之复杂全球罕见,是我国重要的Au、Hg、sb、As、Pb—zn、Ag以及多种分散元素生产基地。国内外学者对该成矿域进行了近30年的研究工作,取得了大量高水平研究成果,同时也存在许多有待深人研究的科学问题。本文回顾了我国西南大面积低温成矿域的研究历史,总结了各研究阶段的主要研究内容、主要研究成果和存在的主要科学问题,同时介绍了近年来我国西南大面积低温成矿域研究新进展。  相似文献   

7.
The geochemical zoning of the Rogovik epithermal deposit in northeast Russia has been established on the basis of endogenic anomalous geochemical fields (AGCF) of Au–Ag zones, their qualitative and quantitative compositions, and spatial distribution of chemical element indicators of Au–Ag mineralization. The obtained geochemical data (monoelemental AGCF, associations of elements, their composition, contrast, and correlation) allowed us to estimate the erosion level of Au–Ag ore zones. It has been shown that AGCF related to Au–Ag mineralization are distinguished by simple component composition (Au, Ag, Hg, Sb, As, Cu, Pb, Zn) and regular spatial distribution of the elements. It has been established that the least eroded central part of the object is characterized by widespread and the most contrasting Au, Ag, Hg, Sb, and As AGCF closely related to the ore-bearing units of the deposit. The contrast of these fields gradually decreases with depth. Low-contrast Cu, Pb, and Zn AGCF typical of the footwall depth intervals and flanks of Au–Ag zones intervals appear at depth. The northern part of the area is eroded to the deepest level. The contrast of Ag, Hg, Sb, and As geochemical fields abruptly decreases here, and Cu, Pb, and Zn AGCF become widespread with depth. The relatively contrasting fields of anomalous Au concentrations develop here extremely locally and near the surface. It has been concluded that the as yet poorly explored southern part of the Rogovik deposit most likely is promising for further geological exploration and the discovery of new mineralized areas.  相似文献   

8.
罗开欢 《矿产与地质》1993,7(4):307-310
青海拉脊山东段水系沉积物地球化学测量,发现金源、喇嘛庙、七里寺峡Au、As、Ag、Bi、Sb、Hg等元素的水系沉积物组合异常.Au、Ag、As相对高浓度带发育形态、分布范围、异常浓集中心吻合,与区内已知尼旦沟金矿床地球化学异常特征可以类比,发现有金、铜矿体和金矿化,显示铜金成矿的有望远景地段.  相似文献   

9.
该文以山东招远大尹格庄金矿床中微量元素为研究对象,通过对矿床围岩、矿石等微量元素的研究,表明大尹格庄金矿围岩中微量元素以富含 Bi,Au,Pb,W,Ag,Sn 为特点,矿体和矿化体中元素组合为 Au,Ag,As,Sb,Hg,B, Cu,Zn,Bi,Mo,Mn,Co,Ni,W。在5个成矿阶段中,第二阶段与第三阶段微量元素的富集程度较明显,表现为 Au, Ag,As,Co,Bi,Cu,Pb,Zn 等的富集,成矿元素可分为2个分带序列,主成矿元素为 Au Ag Cu Pb Zn Bi 组合、头晕元素 As Sb Hg 组合和尾晕元素 Co Ni 组合。  相似文献   

10.
The Pt-Pd and Au-Ag mineralization hosted in both wehrlite without visible links to sulfide mineralization (dispersed assemblage of the Tartai massif) and disseminated Cu-Ni sulfide ore (ore assemblage of the Ognit massif) was found in dunite-wehrlite massifs localized in the fold framework of the Siberian Craton. The Pt minerals in both assemblages comprise sperrylite (PtAs2) and secondary Pt-Fe-Ni alloys in the Ognit massif and Pt-Fe-Cu and Pt-Cu alloys in the Tartai massif. The Pd minerals are widespread in the ore assemblages as compounds with Te, Sb, and Bi, whereas in the dispersed assemblage Pd is concentrated primarily in Pd-Cu-Sb compounds. Both assemblages are characterized by similar substitution of sperrylite with orcelite (Ni5 ? xAs2) and then with secondary Pt-Fe-Ni or Pt-Fe-Cu and Pt-Cu alloys; the occurrence of Au-Ag alloys with prevalence of Ag over Au; and replacement of them with auricupride (Cu3Au) at the late stage. Sperrylite in both assemblages contains Ir impurities, while the Pd minerals contain Cu and Ni admixtures, which are typical of mineral assemblages related to the ultramafic intrusions with nickel specialization. PGM were formed under a low sulfur fugacity and high As, Bi, and Sb activities. The postmagmatic fluids affected the primary mineral assemblages under reductive conditions, and this effect resulted in replacement of sperrylite with Ni arsenide (orcelite) and Pt-Fe-Ni and Pt-Fe-Cu alloys; Ni and Cu sulfides were replaced with awaruite and native copper.  相似文献   

11.
The mineral composition and geochemical characteristics of the ores of the Malinovskoe gold-ore deposit are studied by the data from mining works (ditches, cleanings, and boreholes). It is found that the ore–magma system of the deposit was formed in several stages of mineralization characterized by two phases of magmatism differing in age. In terms of the set of features (the geological–structural position of the deposit, as well as the material composition and geochemical characteristics of the ores), the deposit is attributed to the gold–tourmaline type of mineralization associated spatially and genetically with the “raremetal” granitoid magmatism. This type has not previously been found in Primorskii Krai. The studies of the material composition and geochemical characteristics of the ores allow us to ascertain the correlations between the elements along with the reasons of their origination. By analogy with other gold-ore formations of the Russian Far East, the mineralogical and geochemical model of the deposit is developed (Be–Sn–Cr–Ba–Au–Cu–Mo–Pb–V–Ti–Co–W–Ag–Bi–Ni–Mn–Sr–Zn–Sb–As modeling element series of vertical zoning), which enables us to estimate the levels of the erosion section of the ore bodies and to evaluate their prospects. It is found that the most productive associations in the deposit are the gold–bismuth geochemical association (Au–Ag–Bi–Cu–As–Co) and, to a lesser degree, the gold–tungsten association (W–Au–Ag–Cu–Bi–As).  相似文献   

12.
The dispersed mineralization in the Late Cretaceous leucogranite of the Dukat ore field comprises melanocratic high-sulfide epidote-feldspar, pyroxene-feldspar and low-sulfide allanite-fluorite-feldspar inclusions in greisenized intrusions. The silver-base-metal mineralization is composed of pyrite, pyrrhotite, small particles of Pb, Zn, Sn, Ag, and Sb sulfides and oxides, their native species, and intermetallic compounds; the rare-metal mineralization consists of REE, Th, U, Ti, Zr, Nb, Ta, and W oxides, silicates, and aluminosilicates. The isotopic Nd, Sr, and Pb isotopic compositions and geochemical characteristics of the mineralized inclusions, rock-forming minerals of granitoids, hydrothermal minerals of preore metasomatic propylites and orebodies at the Dukat deposit show that their components have been taken from heterogeneous domains of the Paleozoic juvenile continental crust of the Siberian Platform.  相似文献   

13.
Geochemical exploration by stream sediment sampling using bulk leach extractable gold (BLEG) technique and applying concentration-number (C-N) fractal model, factor analysis (FA), and geochemical mineralization probability index (GMPI) resulted in the recognition of new Au occurrences around the Sukari gold mine in the central Eastern Desert of Egypt. The geochemical data of 128 stream sediment samples collected from the study area was used for delineating the geochemical anomalies and characterizing the dispersion trains of ore and associated elements (Au, Ag, As, Sb, Cu, Pb, Zn, Mo). Statistical analysis of the geochemical data applying the C-N fractal modeling enabled us to identify significant anomaly and background populations of the investigated elements and to construct reliable geochemical anomaly maps. Factor analysis using centered log-ratios (CLR), to address the problem of closed compositional data, revealed significant element associations for mineralization (Au, As, Mo, Zn, Ba), country rock compositions (Rb, Li, Be, Sn, Bi for granite, and Co, Cr, Ni for mafic rocks), and element mobility (e.g. Sb, Zr, and Ag). Weak and moderate Au anomalies that cannot be detected by factor score maps can be delineated clearly by using the C-N fractal method and GMPI distribution map. Our study revealed that Ag, As, and Sb are the main pathfinder elements for gold mineralization in arid to semiarid regions exemplified by the Sukari gold district. Silver can be used as a “direct” pathfinder, whereas As and Sb are “indirect” pathfinders for Au in such regions. The spatial distribution of Au and Ag anomalies indicate that gold mineralization in the Sukari district is structurally controlled. However, the spatial distribution of Cu, Pb, Zn, and Mo is controlled by mineralogical and lithological factors and is not related to any significant base metal deposits.  相似文献   

14.
The mineral and geochemical compositions of noble-metal (first of all, gold) deposits of the Fennoscandian, Siberian, and Northeast Asian orogenic belts are considered. These deposits are of several types: Au (disseminated Au–sulfide and Au–quartz), Au–Bi, Au–Ag, Au–Sb, Ag–Sb, Au–Sb–Hg, and Ag–Hg. They formed in different geodynamic settings as a result of the active motion of crustal tectonic blocks of different nature. Subduction processes (both at the front and at the rear of continent-marginal and island-arc magmatic arcs) resulted in Au–Ag, Ag–Sb, Ag–Hg, Au–Sb–Hg, and Au–Bi deposits. Collision events gave rise to Au and Au–Bi deposits. Intraplate continental rifting and formation of orogenic belts along the boundaries of block (plate) sliding led to the origin of Au and Au–Bi ores in association with Au–Ag, Au–Sb–Hg, and complex ores. In all cases, the formation of noble-metal mineralization was accompanied by magmatism of different types and metamorphism. Because of this diversity of ores, there is no single concept of the genesis of noble-metal mineralization. Several competing models of genesis exist: hydrothermal-metamorphic, pluton-metamorphic, plutonic, activity of mantle fluid flows, and multistage concentration during the crust–mantle interaction with the leading role of sedimentary complexes.  相似文献   

15.
The Bell Springs deposit is a bulk-tonnage, low-grade gold deposit, formed in a hot-spring environment, that is hosted by middle Miocene weakly peralkaline, high-silica rhyolite ash flows and rheomorphic tuffs. Ore grade mineralization over about 460 × 460 m was controlled by northeast- and northwest-trending structures. Sixty-nine soil samples collected along a traverse across the Bell Springs deposit, screened into six mesh size fractions, +10, −10+35, −35+80, −80+120, −120+200, and −200, were treated by low-detection-limit acid digestion/organic extraction procedures, and analyzed by ICP or graphite furnace techniques for Au, Ag, As, Bi, Cd, Cu, Ga, Hg, Mo, Pb, Sb, Se, Te, Tl, and Zn. Twenty-five stream-sediment samples were collected from a drainage crossing mineralization and from a nearby tributary. Sediment size fractions of −200 mesh and −10+200 mesh were analyzed by the same procedures used for soils. In addition, analyses of bulk leachable gold via cyanide leach method (BLEG) was done on bulk −10 mesh sediments.Anomalous Au, Ag, As, Sb, and Mo in all soil size fractions revealed the underlying ore. Areas with anomalous Sb and As were about three times larger than areas with anomalous Au and Ag. Analyses of fine-fractions of stream sediments provided the best-defined Au anomalies in drainages. A multi-element factor calculated by multiplying Au, As, Sb, and Mo reinforced anomalous Au in drainages and correlated well with Bell Springs mineralization.  相似文献   

16.
槐树坪金矿床位于河南省洛阳市嵩县境内,是豫西熊耳山地区近年来新发现的大型金矿床。本次研究对槐树坪金矿区地表及井下不同类型的较新鲜围岩、蚀变岩和矿石以及地表1∶20000面积性土壤采样,分析29项微量元素,从岩石和土壤两种采样介质来确定槐树坪金矿床的地球化学找矿指示元素。一方面基于较新鲜围岩的元素含量特征确定每个微量元素在该区岩石中的异常下限,进而分别计算了蚀变岩和矿石中微量元素平均含量与异常下限的比值,即异常衬度。按照异常衬度大于1.4的标尺确定了蚀变岩与矿石中明显富集的微量元素组合。另一方面,基于Au与28项微量元素在较新鲜围岩、蚀变岩、矿石三种介质中含量关系散点图直观确定了指示金成矿的微量元素组合。综合二者确定出槐树坪金矿区岩石地球化学找矿的指示元素组合为Au、Ag、As、Sb、Hg、Sn、Mo、Bi、Cu、Pb、Zn、Cd、Nb计13项。针对地表1∶20000面积性土壤调查,采用上述岩石中异常衬度为1.4作为土壤异常下限绘制了槐树坪金矿区微量元素的地球化学异常剖析图,以槐树坪金矿区已探明鸡公山一带的主成矿段为模型确定了土壤地球化学找矿的指示元素组合为Au、Ag、As、Sb、Hg、Bi、Cu、Pb、Zn、Cd、B计11项。综合上述结果认为在找矿指示元素组合方面土壤对岩石具有明显的继承性。基于岩石与土壤介质中共同的10项找矿指示元素,构建了归一化的综合异常指标,以鸡公山矿段为标准对整个槐树坪矿区进行了综合评价,发现槐树坪矿区内马蹄沟、秦佛爷沟、姜疙瘩和天坪西4处具有类似鸡公山矿段的找矿潜力。  相似文献   

17.
岩石化学元素丰度在地球化学块体研究中的意义   总被引:5,自引:0,他引:5  
迟清华 《物探与化探》2003,27(6):428-430,444
以Au、Ag、Cu、Pb、Zn、Sb、Hg、W、Sn、Mo、U、Cr、Ni、Co等14种成矿元素为例,利用中国东部不同构造单元的出露地壳和不同类型岩石的元素丰度阐明其在水系沉积物地球化学块体划分与研究中的意义.利用岩石元素丰度对地球化学块体进行研究,既可查明不同地球化学景观区水系沉积物地球化学块体的成因,又可为地球化学块体的研究对比提供条件.因此,应建立不同大地构造单元或不同地球化学景观区的岩石元素丰度并加强其与水系沉积物元素含量的对应关系的研究,这将会对地球化学块体的划分与推断解释提供重要的更加合理的依据.  相似文献   

18.
通过对原生晕的统计分析可研究出地球化学元素在成矿中的演化特征,从而为预测、找矿提供有力的依据。文章通过对有关元素的聚类分析、因子分析及轴向分带序列的研究,揭示了养马甸钼矿区内Mo与Au,As的相关性较好,Au和As可以作为找钼的近程指示元素,而Ag对钼的寻找也有一定的指示意义。Ag和Sb的关系表明,Sb对钼的寻找具有一定的远程指示意义。通过轴向分带的研究,结合ZK5地球化学变化曲线可知,ZK5的地球化学参数值于250m左右由升到降,表明了下部隐伏矿体存在的可能。  相似文献   

19.
冲绳海槽Jade热液活动区热液沉积物主要以块状硫化物和硫酸盐矿物为主。与其它热液活动区相比,本区的热液沉积物以富含Pb和Ag等元素为特征。电子探针和中子活化的分析结果表明,在块状硫化物矿石中,Ag主要以分散态富集在粗粒硫化物和细粒硫化物集合体中,在热液活动的早期和晚期均有Ag的富集。在以硬石膏为主的块状矿石中,Ag主要在细粒硫化物集合体中富集,其富集成矿的时间为热液活动的中后期,富集成矿温度在150℃以上。在重晶石为主的块状矿石中,Ag主要以颗粒状自然银的形式在热液活动后期富集成矿,其成矿温度低于160℃。  相似文献   

20.
姚家岭锌金多金属矿床是铜陵矿集区近年来新发现的一处大型矿床.该矿床可分为2个成矿期,早期为铜(金、锌)矿化,晚期为锌(金银)多金属矿化,以后者为主.多金属硫化物期以大量发育多种不规则脉状和角砾状矿石为特征,发育硅化、绿泥石化和高岭土化,矿化受张性构造控制,矿物组合为富铁闪锌矿、黄铁矿、黄铜矿、方铅矿、石英(包括玉髓和蛋...  相似文献   

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