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贵州务川-沿河地区分布大量萤石矿床(点),这些矿床(点)多与重晶石矿共生,萤石矿赋存在奥陶系桐梓组和红花园组碳酸盐岩内,矿体分布严格受地层与北西向张性断裂控制。本文选择务川涪洋地区双河、鹿坪、一碗水和通木水等萤石矿床开展稀土元素地球化学研究,结果显示,各矿床萤石稀土元素配分模式均为右倾的轻稀土富集型,且具有一定的相似性。∑REE含量分别为28.96×10-6～115.12×10-6、123.10×10-6～124.11×10-6、14.77×10-6～22.35×10-6和20.73×10-6～123.69×10-6,总体具有较强的Eu正异常、Ce负异常,表明这类萤石矿形成于较为氧化环境中。区内萤石属于北西向张性断裂和下奥陶统地层碳酸盐岩控制的中-低温热液充填交代型矿床。结合La/Ho-Y/Ho图解及矿床地质特征,本研究认为区内萤石为同一来源的成矿流体在同一成矿期次不同阶段成矿,其中双河矿床经历了多个阶段成矿叠加... 相似文献
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雷公嶂钼矿床是赣南地区新发现的一座具中型钼矿找矿前景的独立钼矿床,成矿特征明显区别于赣南已发现的与钨多金属共(伴)生的钼矿床。为确定矿床成矿时代,文章利用高精度ICP-MS辉钼矿Re-Os同位素测年技术,首次获得了雷公嶂钼矿床的辉钼矿Re-Os同位素加权平均模式年龄,为(156.3±1.0)Ma,等时线年龄为(156.9±3.6)Ma,证实了矿床成岩与成矿作用同时发生,形成于南岭地区燕山早期中晚侏罗世(165～150 Ma)。矿床中辉钼矿的w(Re)为6.104×10-6～13.974×10-6,平均为8.507×10-6,结合矿床地质特征和成矿岩体主量元素及Hf同位素等证据,文章认为成矿物质来自地壳,没有地幔物质加入。结合赣南地区成岩与成矿年代学资料,文章认为区内钨钼多金属矿床形成于华南中生代岩石圈大规模伸展-减薄的地球动力学背景。 相似文献
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锗(Ge)属于战略性关键矿产资源,是众多高新技术领域的重要原材料。Ge主要以共/伴生形式产出于Zn、Pb和Cu等热液贱金属矿床和煤矿床中,目前全球Ge资源主要来源于铅锌矿的副产品。近期取得较大找矿突破的半边街锌矿床(7.70Mt矿石,Zn平均品位5.1%)伴生有超大型规模的金属Ge(>900t@110×10-6),然而Ge超常富集的机制不清。本次研究利用LA-ICPMS对闪锌矿进行了微区原位微量元素组成和Mapping分析,以揭示Ge等元素的富集特征、赋存状态和替代方式,探讨Ge的富集机制。分析结果表明,半边街矿床闪锌矿中高含量(平均值>100×10-6)微量元素有Fe、Pb、Ge和Cd等,较高含量(平均值100×10-6～10×10-6)的有Mn、Ga、Sn和Tl,以及较低含量(平均值<10×10-6)的有Ag、Cu、In和Sb。相比于各类型铅锌矿床,半边街闪锌矿Ge超常富集(274×10-6～1938×10-6,... 相似文献
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通过1∶5万区域地质调查及典型剖面研究,在滇中禄劝地区二叠系峨眉山组顶部识别出一套厚约20～50 m不等的Nb、Co、Ga、Zr及REE超常富集层。富集层主要岩性为灰紫色泥岩、凝灰质泥岩、凝灰岩,局部夹杏仁状玄武岩。通过对禄劝万鲁布、撒角海一带的富集层刻槽分析显示,Nb2O5含量在82.4×10-6～120.1×10-6,平均值为100.3×10-6,大于风化壳型矿床一般工业指标80×10-6;Ga含量28.8×10-6～35.6×10-6,平均值为32.1×10-6,高于现行的Ga矿资源工业指标要求30×10-6;REE含量在360×10-6～510×10-6,平均值为440.6×10-6,接近风化壳型矿床一般工业指标500×10-6;并呈现出泥岩→凝灰质泥岩→凝灰岩关键金属含量依... 相似文献
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空布岗位于特提斯喜马拉雅带东部、桑日-错那裂谷系内，发育二云母花岗岩、白云母淡色花岗岩、含石榴子石淡色花岗岩以及混合岩淡色体。LA-MC-ICP-MS锆石U-Pb定年显示，空布岗白云母淡色花岗岩结晶年龄为16.9±0.1Ma。全岩元素地球化学分析表明：二云母花岗岩为过铝质富钠花岗岩，具有较高的Sr (107×10-6～141×10-6)和Ba (230×10-6～311×10-6),较低的Rb(108×10-6～221×10-6)和Rb/Sr比值(0.78～2.07),Ba与Rb/Sr比值没有相关性，指示其为白云母含水部分熔融作用的产物。白云母淡色花岗岩为过铝质富钾花岗岩，具有较高的Rb(>270×10-6)和Rb/Sr比值(5.2～9.5),但是其Sr(<58.5×10-6)和Ba(<167×10-6)含量较低，Ba与Rb/Sr比值呈现明显的负相关关系，表明它是白云母脱水... 相似文献
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辽宁铁岭地区为一新的含矿金伯利岩区。本文利用地球化学方法对其成因做了些初步探讨。研究表明本区金伯利岩是由强富集型地幔即碳酸盐化的磷灰石-金云母-石榴石二辉橄榄岩经1％～2％的部分熔融形成的。富集型地幔的稀土元素丰度估算值为:La≈65×10-6,Ce≈105×10-6, Nd≈55×10-6,Sm≈8.20×10-6, Eu≈1.75×10-6。 相似文献
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杏枫山Au-W矿床位于湘中Au-Sb-W成矿带西部,以发育矽卡岩型钨矿化和席状石英脉型金矿化两套成矿系统为典型特征,明显有别于区域其它Au-W矿床,为进一步研究区域金、钨成矿机制提供了理想对象。文章根据野外穿切关系、矿物共生组合以及结构特征,将杏枫山白钨矿按次序划分为早期矽卡岩型钨矿化中具振荡环带的Sch-1、内部结构均一的Sch-2、多孔状的Sch-3和晚期席状石英脉型金矿化中结构均一的Sch-4。Sch-1和Sch-2的Mo含量和Eu异常(δEu)分别呈现逐渐降低(47.5×10-6→0.044×10-6)和升高(1.74→3.18)的趋势,暗示其成矿热液氧逸度的逐步降低,这可能与其富Sr特征(251×10-6～4916×10-6)和与矽卡岩矿物共生所指示的强烈水岩反应相关。同时,Sch-1至Sch-3整体上与白马山印支期岩体具有相似的Y/Ho比值,结合前人的年代学研究指示其成矿热液可能来自白马山印支期岩体。Sch-4的低Mo含量(0.014×10-6～0.068×10 相似文献
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关键金属矿产是国际上最近提出的资源概念,对战略性新兴产业的发展至关重要,但认知程度较低。洛扎岩浆-变质杂岩体位于喜马拉雅带东部,侵位于藏南拆离系内。在岩体东北侧,云母片岩被含电气石淡色花岗岩捕虏。云母片岩主要由金云母、绿泥石和少量黑云母组成。从全岩地球化学成分来看,云母片岩具有含量较高的Al2O3(13.38%～14.32%)、K2O(6.09%～9.66%)、FeO*(27.11%～30.09%)、MgO(15.25%～17.21%)、TiO2(0.09%～0.26%),富集关键金属Li(650×10-6～1 031×10-6)、Rb(1 649×10-6～2 773×10-6)、Cs(98×10-6～229×10-6)、Tl(5.7×10-6～12.1×10-6)、Ga(121×10-6 相似文献
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云南省小水井铜金多金属矿床产于东川铜多金属矿集区。矿区土壤地球化学特征表明,在小水井铜金多金属矿床所处的因民组和黑山组中,w(Cu)平均值分别为133×10-6和168×10-6,变异系数分别为0.63和0.59;w(Au)平均值分别为8.7×10-9和4.0×10-9,变异系数分别为0.71和0.61;Cu的富集系数分别为2.20和3.68,Au的富集系数分别为1.31和1.01;Cu和Au的矿化叠加强度分别5.9和8.7,Cu和Au元素的峰值分别为2 017×10-6和570×10-9。在元素异常等值线图上,Cu,Au呈多个富集中心,且二者的富集中心基本吻合;地球化学特征与矿床实际情况也非常吻合。研究表明,区内构造不仅控制地层和岩体的分布,同时控制铜金多金属矿床的展布,岩浆活动和区域脆-韧性剪切作用直接为成矿元素的活化和运移成矿提供了便利。 相似文献
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四川省日乃金矿位于甘孜—理塘蛇绿混杂岩带的南段,区内中生代构造-岩浆活动强烈,发育上、下两套蛇绿岩,日乃金矿即赋存于上部的瓦能蛇绿岩组中,矿化带主要发育在区域性断裂次级的F6和F7之间的断裂破碎带中,矿化范围具有中-低温热液蚀变,形成3条金矿化带,矿体为脉状,长520~1120 m,宽5.18~6.97 m;矿体倾向NW,倾角40°~75°;矿石品位w（Au）=1.89×10-6~3.77×10-6;矿石的主要含金矿物为黄铁矿和毒砂。根据金矿地质特征和主要控矿因素提出矿床的成因类型为与燕山晚期构造-岩浆活动有关的热液交代充填型金矿床,同时归纳了日乃金矿床的控矿因素。 相似文献
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通过对坦桑尼亚恩泽加绿岩带玛汀杰金成矿区的4个金矿（化）体的成矿背景和地质特征进行分析,初步了解该区金矿体地质特征及矿床成因。玛汀杰金矿为产自韧性剪切带的石英脉型金矿,赋矿层位为太古代尼安兹超群绿片岩,矿体由NW向和EW向两组构造控制,矿石类型包括石英脉型、蚀变岩型和构造角砾岩型。普遍发育黄铁绢英云化。矿石w（Au）=0.62×10-6~3.04×10-6,部分矿石w（Au）值大于100×10-6。玛汀杰地区金矿为典型的产自绿岩带韧性剪切带的石英脉型金矿,矿床成因为热液成因。 相似文献
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冀北隆化县小罗卜沟中型金银矿床的发现是该地区找矿的重大突破。勘查区位于1∶20万和1∶5万Au、Ag等多元素综合异常内,通过以钻探、硐探为主的探矿工程,基本查明了矿体赋存于早白垩世九佛堂组复成分角砾岩和义县组安山岩及安山质火山角砾岩的构造裂隙内。矿体受断裂带控制,与围岩界线明显,对围岩没有选择性,矿床属燕山期与岩体有关的浅成中低温热液矿床。矿区内共圈定17个矿体,矿体长28～788 m,斜深8～489 m,平均厚度0.80～3.96 m,Ag平均品位68.44×10~(-6)～447.50×10~(-6),共生Au平均品位1.16×10~(-6)～6.25×10~(-6);伴生Au平均品位0.20×10~(-6)～1.00×10~(-6),伴生S平均品位2.34%～11.10%。主要矿体Ⅳ-1银资源储量达中型。矿区内及外围仍存在寻找多金属矿床的潜力。该矿床的发现对寻找同类矿床具有重要指示意义。 相似文献
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西天山东塔尔别克金矿区安山岩LA-ICP-MS锆石U-Pb年代学、元素地球化学与岩石成因 总被引：10，自引：7，他引：3
东塔尔别克金矿区位于西天山吐拉苏盆地内阿希金矿区南侧,构造上属于伊犁-中天山微板块与准噶尔板块之间的博罗科努早古生代岛弧带西段。东塔尔别克矿区出露有一些安山岩,这些岩石具有典型高镁安山岩特征,如高硅（SiO2=58.94%~63.85%),具有较高的MgO含量(3.75%~6.59%)和Mg#(58~69)、高的Cr（94.2×10-6~241×10-6）、和Ni（54.5×10-6~126 ×10-6）含量,以及低的FeOT/MgO比值。除了Sr含量略微偏低（235×10-6~696×10-6）之外,这些岩石基本显示了埃达克岩的地球化学特征：高的Al2O3（15.39%~16.65%）,低Y（9.86×10-6~14.9×10-6）含量,以及高的Sr/Y比值(23.8~48.1),无Eu异常,Nb、Ta、Ti亏损等。LA-ICP-MS锆石U-Pb测年结果显示安山岩的年龄为347.2±1.6Ma,为早石炭世。安山岩富集Rb、Th、U 等大离子亲石元素,相对亏损Nb、Ta、Ti等高场强元素,轻重稀土元素分馏明显,具有俯冲带岛弧岩浆的特征。东塔尔别克安山岩可能形成于岛弧环境中,并可能由俯冲的晚古生代北天山洋洋壳以及少量上覆沉积物熔融形成,产生的熔体在上升过程中与地幔橄榄岩发生了相互作用. 熔体-地幔相互作用对区内金矿的形成具有重要意义。 相似文献
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经研究确认鄂东南铜绿山矿床为隐爆角砾岩型金(铜)矿。这一新类型的金(铜)矿体受NWW向断裂、隐爆角砾岩带、接触带复合构造的控制,产于矽卡岩型矿体上盘大理岩残留体的边部,走向上大致与NNE向矽卡岩型主矿带垂直。矿石呈角砾状构造,角砾成分为大理岩、斜长石岩,含少量块状磁铁矿矿石角砾和高岭石化花岗岩角砾。胶结物主要为细碎屑物及微细粒状石英、玉髓、高岭石、黄铜矿和黄铁矿等中低温热液矿物。矿石平均wCu2.54%,wAu3.44×10-6。隐爆角砾岩型矿化是在岩浆侵入作用下成矿热液演化晚期阶段形成的,时间上晚于矽卡岩型,但可叠加其上,常形成富铜金矿体,也可形成独立金矿体。隐爆角砾岩型金(铜)矿体的发现为大幅度增加铜绿山矿床的储量指明了方向,对认识铜绿山矿田的成矿系列具有重要意义。 相似文献
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《China Geology》2020,3(3):369-384
Although some porphyry-skarn deposits occur in post-collisional extensional settings, the post-collisional deposits remain poorly understood. Here the authors describe the igneous geology, and mineralization history of Tuolangla, a newly-discovered porphyry-skarn Cu-W-Mo deposit in southern Tibet that belongs to the post-collisional class. The deposit is associated with Lower Cretaceous Bima Formation. It was intruded by granodiorite porphyry intrusions at about 23.1 Ma. Field investigation indicated that mineralization is spatially and temporally associated with granodiorite porphyry. Molybdenite yielded a Re-Os weighted mean age of 23.5 ± 0.3 Ma and is considered to represent the age of skarn mineralization at the deposit. The δ34S values of sulfides, concentrated in a range between 0.6‰ to 3.4‰, show that the sulfur has a homogeneous source with characteristics of magmatic sulfur. The Pb isotopic compositions of sulfides indicate that ore-forming metal materials were derived from the mantle and ancient crust. The granodiorite porphyry displays high SiO2 (68.78%–69.75%) and K2O (3.40%–3.56%) contents, and relatively lower Cr (2.4×10-6–4.09×10-6), Ni (2.79×10-6–3.58×10-6) contents, and positive εHf(t) values (7.7–12.9) indicating that the mineralization porphyry was derived from the partial melting of juvenile lower crust. The Tuolangla deposit is located in the central part of Zedang terrane. This terrane was once considered an ancient terrane. This terrane is in tectonic contact with Cretaceous ophiolitic rocks to its south and Mesozoic continental margin arc volcanics and intrusions of the Gangdese batholith of the Lhasa terrane to its north. Thus, the authors proposed that the Oligocene porphyry skarn Cu-W-Mo mineralization is probably associated with the Zedang terrane. This finding may clarify why the Oligocene (about 23 Ma) deposits are found only in the Zedang area and why mineralization types of the Oligocene mineralization are considerably different from those of the Miocene (17–14 Ma) mineralization. 相似文献
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《Resource Geology》2018,68(4):395-424
Petrochemical characteristics of Permo‐Triassic granitoids from five regions (i) Mung Loei, (ii) Phu Thap Fah – Phu Thep, (iii) Phetchabun, (iv) Nakon Sawan – Lobburi, and (v) Rayong – Chantaburi along the Loei Fold Belt (LFB), northeastern Thailand were studied. The LFB is a north–south trending 800 km fold belt that hosts several gold and base‐metal deposits. The granitoids consist of monzogranite, granodiorite, monzodiorite, tonalite, quartz‐syenite, and quartz‐rich granitoids. These are composed of quartz, plagioclase, and K‐feldspar with mafic minerals such as hornblende and biotite. Accessory minerals, such as titanite, zircon, magnetite, ilmenite, apatite, garnet, rutile, and allanite are also present. Magnetic susceptibilities in the SI unit of granitoids vary from 6.5 × 10−3 to 15.2 × 10−3 in Muang Loei, from 0.1 × 10−3 to 29.4 × 10−3 in Phu Thap Fah – Phu Thep, from 2.7 × 10−3 to 34.6 × 10−3 in Petchabun, from 2.4 × 10−3 to 14.1 × 10−3 in Nakon Sawan – Lobburi, and from 0.03 × 10−3 to 2.8 × 10−3 in Rayong – Chantaburi. Concentration of major elements suggests that these intermediate to felsic plutonic rocks have calc‐alkaline affinities. Concentration of REE of the granitoids normalized to chondrite displays moderately elevated light REE (LREE) and relatively flat heavy (HREE) patterns, with distinct depletion of Eu. Rb versus Y/Nb and Nb/Y tectonic discrimination diagrams illustrate that the granitoids from Muang Loei, Phu Thap Fah – Phu Thep, Phetchabun, Nakon Sawan – Lobburi, and Rayong – Chantaburi formed in continental volcanic‐arc setting. New age data from radiometric K‐Ar dating on K‐feldspar from granodiorite in Loei and Nakhon Sawan areas yielded 171 ± 3 and 221 ± 5 Ma, respectively. K‐Ar dating on hornblende separated from diorite in Lobburi yielded 219 ± 8 Ma. These ages suggest that magmatism of Muang Loei occurred in the Middle Jurassic, and Nakon Sawan – Lobburi occurred in Late Triassic. Both Nb versus Y and Rb versus (Y + Nb) diagrams and age data indicate that Nakon Sawan – Lobburi granitoids intruded in Late Triassic at Nong Bua, Nakon Sawan province and Khao Wong Phra Jun, Lobburi province in volcanic arc setting. Muang Loei granitoids at the Loei province formed later in Middle Jurassic also in volcanic arc setting. The negative δ34SCDT values of ore minerals from the skarn deposit suggest that the I‐type magma has been influenced by light biogenic sulfur from local country rocks. The Au‐Cu‐Fe‐Sb deposits correlate with the magnetite‐series granitoids in Phetchabun, Nakon Sawan – Lobburi and Rayong – Chantaburi areas. Metallogeny of the Au and Cu‐Au skarn deposits and the epithermal Au deposit is related to adakitic rocks of magnetite‐series granitoids from Phetchabun and Nakon Sawan areas. All mineralizations along the LFB are generated in the volcanic arc related to the subduction of Paleo‐Tethys. The total Al (TAl) content of biotite of granitoids increases in the following order: granitoids associated with Fe and Au deposit < with Cu deposit < barren granitoids. XMg of biotite in granitoids in Muang Loei indicates the crystallization of biotite in magnetite‐series granitoids under high oxygen fugacity conditions. On the other hand, low XMg (<0.4) of biotite in magnetite‐series granitoids in Phu Thap Fah – Phu Thep and Rayong – Chantaburi indicates a reduced environment and low oxygen fugacity, associated with Au skarn deposit (Phu Thap Fah) and Sb‐Au deposit (Bo Thong), respectively. The magnetite‐series granitoids at Phu Thap Fah having low magnetic susceptibilities and low XMg of biotite were formed by reduction of initially oxidizing magnetite‐series granitic magma by interaction with reducing sedimentary country rocks as suggested by negative δ34SCDT values. 相似文献