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1.
The Brixen Quartzphyllite, basement of the Southern Alps (Italy), consists of metasediments which had suffered progressive deformation and low grade metamorphism (p
max4 kbar, T
max375±25° C) during the Palaeozoic. It has been excavated by pre-Permian erosion, buried again beneath a pile of Permo-mesozoic to Cainozoic sediments (estimated T
max150° C), and is now exposed anew due to late Alpine uplift and erosion. The behavior of the K-Ar system of white micas is investigated, taking advantage of the narrow constraints on their thermal history imposed by the geological/stratigraphic reference systems.The six structurally and petrographically differing samples come from a single outcrop, whose position is roughly two kilometers beneath the Permian land-surface. White mica concentrates from five grain size fractions (<2 , 2–6 , 6–20 , 20–60 , 60–75 ) of each sample have been analyzed by the conventional K-Ar method, four selected concentrates additionally by the 40Ar/39Ar stepwise heating technique; furthermore, Ar content and isotopic composition of vein quartz were determined.The conventional ages of the natural grain size fractions (20–60 , 60–75) are in the range 316±8 Ma, which corresponds to the 40Ar/39Ar plateau age of 319.0±5.5 Ma within the error limits. The finer grain size fractions yield significantly lower ages, down to 233 Ma for fractions <2 . Likewise low apparent ages (down to 83 Ma) are obtained for the low temperature 40Ar/39Ar degassing steps.There is no correlation between microstructural generation of white mica prevailing in the sample and apparent age. This favours an interpretation of the 316±8 Ma values as cooling age; progressive deformation and metamorphism must be respectively older and their timing cannot be resolved by these methods. The data preclude any significant influence of a detrital mica component as well as of excess argon.The lower ages found for the fine grain-size fractions (respectively the low-T degassing steps) correspond to a near-surface period (p-T-minimum); the values are geologically meaningless. The effect is interpreted to result from partial Ar loss due to reheating during Mesozoic-Cainozoic reburial. A model based on diffusion parameters derived from the outgassing experiments and Dodson's (1979) equation yields a closure temperature of 284±40 °C for a cooling rate of 18° C/Ma. Furthermore, this model suggests that the observed argon loss of up to 5% may in fact have been induced by reheating to 150 °C for 50 Ma. 相似文献
2.
The effects of sub-blocking temperature metamorphism on the K/Ar system in hornblende, as revealed by 40Ar/39Ar release spectra, have been studied in a polymetamorphic knocker from the Franciscan Complex (FC), California. A primary amphibolite assemblage of horn-blende +rutile+epidote+apatite±garnet±sphene is variably overprinted by a blueschist facies assemblage of blue amphibole +lawsonite+chlorite+white mica+pumpellyite±sphene. The secondary assemblage formed at a temperature of 370° C, below that at which rapid Ar diffusion is expected in hornblende. Hornblendes from three, variably-altered samples of garnet amphibolite yield total gas ages of 147 to 161 Ma, but the corresponding plateau ages of 163.0±2.8, 160.6±2.2, and 161.8±2.2 Ma are identical within error. Hornblende separates with lower total gas ages come from more highly overprinted rocks, have excess K compared to that expected on the basis of electron probe analyses, and exhibit anomalously high K/Ca ratios in the low-temperature fractions of their incremental heating spectra. The reduced total gas ages result from the presence of thin (2 m) sheets of younger white mica in hornblendes from the moderately and highly altered amphibolites. The secondary micas are difficult to detect because of their small size and low abundance (2%), but because their K content is 50 to 100 times that of the host hornblende, they contribute significantly to the K and Ar budgets of the sample. The mica intergrowths are not removed by normal sample preparation, but because the mica inclusions degas at lower temperatures than hornblende during vacuum extraction, incremental heating analyses can provide precise cooling ages for the hornblendes as well as useful estimates of the age of the mica inclusions. The hornblende separate from the most altered sample contained 20±10% younger blue amphibole replacing hornblende, but its plateau age was not significantly affected. This is consistent with a replacement process in which K and Ar loss from the hornblende are coupled, leaving the K/Ar system undisturbed in relict primary grains. The K and Ar budgets of the sample are not strongly affected by the blue amphibole because of its very low K content. Because partial replacement of primary amphibole by high-K phyllosilicates occurs in many geological environments, effects like those described here could be widespread. 相似文献
3.
Twenty-eight samples of groundwater from bedrock boreholes in three distinct Norwegian geological provinces have been taken and analyzed for content of Rn, U, and Th, together with a wide variety of minor and major species. Median values of 290 Bq/1, 7.6 g/1, and 0.02 g/1 were obtained for Rn, U, and Th respectively, while maximum values were 8500 Bq/1, 170 g/1, and 2.2 g/1. Commonly suggested drinking water limits range from 8 to 1000 Bq/1 for radon and 14 to 160 g/1 for uranium. Radioelement content was closely related to lithology, the lowest concentrations being derived from the largely Caledonian rocks of the Trøndelag area, and the highest from the Precambrian Iddefjord Granite of southeast Norway (11 boreholes) where median values of 2500 Bq/1, 15 g/1 and 0.38 g/1, respectively, were obtained. The Iddefjord Granite is not believed to be unique in Norway in yielding high dissolved radionuclide contents in groundwaters, and several other granitic aquifers warrant further investigation in this respect. 相似文献
4.
W. Linke 《Mineralogy and Petrology》1970,14(1):61-63
Zusammenfassung Der Pleochroismus der OH-Streckfrequenz (=3,16 ±0,02 ) zeigt sowohl für -Zoisit als auch für -Zoisit, daß die OH-Dipole paralel [001] orientiert sind.
Mit 1 Abbildung 相似文献
Measurement of the infrared-pleochroism in minerals. X. The pleochroism of the OH-stretching frequency in zoisite
Summary The pleochroism of the OH-stretching frequency (=3.16 ±0.02 ) proves for - and -zoisite that the OH-dipoles are oriented parallel [001].
Mit 1 Abbildung 相似文献
5.
Lake Suwa, located in the center of the largest Japanese island of Honshu was a typical hypertrophic lake with a dense scum Microcystis species in summer during the 1970's. However, due to the introduction of a sewage treatment plant and the awareness of environmental pollution by local residents, a decrease in the concentration of nutrients in lake water since 1981 has been observed (from 1600 g l–1 and 160 g l–1 in 1977 to 990 g l–1 and 110 g l–1 in 1984 for total nitrogen and phosphorus respectively). 相似文献
6.
Metamictization and U-PB isotopic discordance in single zircons: a combined Raman microprobe and SHRIMP ion probe study 总被引：7，自引：0，他引：7
Summary We report results of a combined SHRIMP ion microprobe and Raman microprobe study of the correlation between metamictization and U-Pb isotopic discordance of zircon. The spatial resolution of the SHRIMP and Raman probe used are about 200 m3 and 80 m3, respectively. This allows a direct comparison of U-Pb isotopic discordance and metamictization of small areas within zircon crystals. We show that the impact of the oxygen ion beam on the zircon during the SHRIMP analysis does not cause significant amorphization or recrystallization in the remaining zircon on a scale of 1 m. Consequently, it is possible to determine the initial degree of metamictization of zircon within and adjacent to a SHRIMP analytical spot by Raman microprobe measurements after performing SHRIMP analyses. A combination of the two microprobe techniques gives information on the concentration and distribution of radionuclides as well as the degree of metamictization and its heterogeneity and the lateral age distribution within the grain. We found that the degree of U-Pb isotopic discordance correlates closely with the degree of metamictization within single zircon grains, on a scale of 15 m, which is consistent with previous results on the scale of single and multiple zircon grains showing that metamictization enhances the relative potential for secondary loss of radiogenic lead in zircon.
Metamiktisierung und U-Pb-Isotopendiskordanz in Einzelzirkonen: eine komplexe Untersuchung mittels Ramanmikrosonde und SHRIMP Ionensonde
Zusammenfassung Wir präsentieren die Ergebnisse einer Untersuchung des Zussammenhangs von Metamiktisierung und U-Pb Isotopendiskordanz in Zirkonen mittles kombinierter SHRIMP-Ionenmikrosonden- und Ramanmikrosondenanalysen. Die räumliche Auflösung der verwendeten Analysensysteme, experimentell mit 200 m3 (SHRIMP) und 80 m3 (Ramansonde) bestimmt, gestattet den direkten Vergleich der in Mikrobereichen innerhalb von Zirkon-Einkristallen gemessenen Isotopendiskordanzen und Metamiktisierungsgrade. Wir zeigen, daß der während der SHRIMP-Analyse auf den Zirkon einwirkende Sauerstoffionenstrahl weder signifikante Amorphisierung noch Rekristallisation des benachbarten Zirkonmaterials im 1 m-Bereich hervorruft. Es ist deshalb möglich, den Grad der Metamiktisierung eines Zirkon-Mikrobereiches auch in den SHRIMP-Analysengrübchen, d.h. erst nach dem Analysieren dieses Bereiches mit der Ionensonde, mittels hochauflösender Ramanmessungen unverfälscht zu bestimmen. Der Einsatz beider Mikromethoden liefert kombinierte Informationen zu den Gehalten und Verteilungen radioaktiver Elemente, zum Grad der Metamiktisierung und seiner Heterogenität und zur lateralen Altersverteilung innerhalb von Einzelkörnern. Wir weisen eine deutliche Korrelation des Grades der U-Pb-Isotopendiskordanz mit dem Grad der Metamiktisierung im Mikrobereich (15 m Auflösung) nach. Dies stimmt mit früheren, an Einzelzirkonen und Populationen getätigten Beobachtungen überein, daß die Metamiktisierung von Zirkon dessen Potential zu sekundären Bleiverlusten erhöht.相似文献
7.
The pre-Mesozoic basement in the eastern and central part of the Tauern Window (Eastern Alps) consists mainly of anatectic plagioclase gneisses and amphibolites intruded and migmatized by Carboniferous granitoids. The gneisses are geochemically similar to calcalkaline dacites of modern primitive island arcs. Cathodoluminescence investigations and U/Pb-data on zircons indicate an uppermost Proterozoic or Cambrian extrusion age of the dacitic protoliths and a Carboniferous syngranitoid anatexis around 320 Ma. High-K calcalkaline meta-rhyolites in the north central Tauern Window form a separate part of the basement not affected by Carboniferous anatexis and plutonism. Their protoliths extruded in the Lower Carboniferous. In the Permian, high-K granitoids intruded the anatectic basement.Results are consistent with an island-arc system evolving from a Late Proterozoic and Early Paleozoic primitive stage to a Lower Carboniferous mature stage represented by K-rich rhyolite volcanism. An Upper Carboniferous collisional event caused anatexis, affecting mainly the K-rich calcalkaline rocks. The last calcalkaline magmas intruded in a Permian post-collisional setting.
Zusammenfassung Das prä-mesozoische Grundgebirge des östlichen und zentralen Tauernfensters (Ostalpen) besteht größtenteils aus anatektischen Plagioklasgneisen und Amphiboliten, welche von karbonischen Granitoiden intrudiert und migmatisiert werden. Die Plagioklasgneise entsprechen geochemisch kalkalkalischen Daziten primitiver Inselbögen. Die anhand von Kathodolumineszenzaufnahmen ausgewerteten U/Pb-Daten der Zirkone weisen auf ein jüngst-proterozoisches oder kambrisches Extrusionsalter der dazitischen Protolithe und auf eine karbonische syn-granitoide Anatexis um 320 Ma. High-K kalkalkalische Metarhyolithe im nördlichen Teil des zentralen Tauernfensters bilden einen separaten Teil des Grundgebirges, der von karbonischer Anatexis und Plutonismus nicht berührt wurde. Ihre Protolithe extrudierten im unteren Karbon. Das anatektisch überprägte Grundgebirge aus Plagioklasgneisen und Amphiboliten wurde im Perm von high-K Granitoiden intrudiert.Die Ergebnisse sind konsistent mit der Entwicklung von einem jung-proterozoischen und alt-paläozoischen primitiven Inselbogen zu einem unter-karbonischen reifen Inselbogen mit K-reichen Rhyolith-Vulkanismus. Ein ober-karbonisches Kollisions-Ereignis führte zur Anatexis insbesondere der K-reichen kalkalkalischen Gesteine. Die letzten kalkalkalischen Magmen intrudierten postkollisional im Perm.
Résumé Le socle pré-Mésozoïque du centre et de l'est de la Fenêtre des Tauern (Alpes orientales), est principalement composé de gneiss plagioclasiques anatectiques et d'amphibolites. Des granitoïdes carbonifères sont intrusifs dans ce socle et le migmatitisent. Les gneiss sont géochimiquement comparables à des dacites calco-alcalines d'arc insulaire immature. Des études sur zircons par cathodoluminescence et datation U-Pb indiquent, pour les dacites, un âge d'extrusion protérozoïque supérieur ou cambrien. L'anatexie contemporaine de la mise en place des granitoïdes est datée aux alentours de 320 Ma. Dans le nord de la partie centrale de la fenêtre, des méta-rhyolites calco-alcalines riches en potassium forment une zone distincte du socle et ne sont pas affectées par l'anatexie et le plutonisme carbonifère. Leur extrusion date du Carbonifère inférieur. Au Permien, des granitoïdes riches en potassium ont recoupé le socle anatectique.Les résultats sont en accord avec une évolution d'arc insulaire depuis un stade primitif d'âge protérozoïque supérieur ou paléozoïque inférieur jusqu'à un stade de maturité d'âge carbonifère inférieur représenté par les rhyolites riches en potassium. Au Carbonifère supérieur, un événement de collision a provoqué l'anatexie qui affecte principalement les roches calco-alcalines riches en potassium. Les derniers magmas calco-alcalins se sont intrudés dans le contexte post-collisionnel Permien.
( ) , . - . , - , , , - 320 . - , , , . , . - , . - . , , - .相似文献
8.
Concentration levels of the trace elements Al, As, B, Ba, Be, Cd, Co, Cr, Cu, Li, Mo, Ni, Pb, Sr, V, Y, and Zn in the shallow Dutch ground water were studied. Data were extracted from the data base of the Dutch National Ground Water Quality Monitoring Network, a network set up to monitor the diffuse contamination. The network contains over 350 sites at a low density of about 1 per 100 km2. The sites are sampled once a year at two depths (approx. 10 and 25 m below surface). A two-step multivariate statistical approach was used, in which the major element chemistry was used to define water types. Within each water type, trace element behavior could be coupled to distinct geochemical processes: dilution, acidification and weathering, carbonate dissolution, oxidation/reduction, and ion exchange. In recently infiltrated acid rain water in low buffering capacity sands, the anthropogenic influence indirectly caused mobilization of Al (median 430 g/l), Cd (0.6 g/l), Co (14 g/l), Cu (2.7 g/l), Ni (16 g/l), Y (11 g/l), and Zn (50 mg/l). In carbonate bearing sediments the acidification is neutralized, and the mentioned trace elements remain immobile. Arsenic and Cr have higher concentrations levels in ground waters with a slightly reducing character and are possibly governed by the dissolution of iron-manganese hydroxides. Boron, Li, and Sr have high concentrations (respectively 875, 80, 2700 g/l) in the water type related to a seawater source. Strontium is related to carbonate dissolution in all other water types (medians ranging from 100 to 1000 g/l). Barium shows a complex behaviour. It is concluded that the high Al, Cd, Co, Cr, Ni, and Zn concentrations are anthropogenically induced. High Ba and Cr concentrations are inferred to be due to natural processes. 相似文献
9.
Soil samples collected from various places in and around Mysore were analyzed for the total trace elements such as Fe, Mn, Cu, Zn, Pb, and Cd. The results of the analysis indicate that the concentration of lead and cadmium in soils is below 2.5 g ml–1 and 0.2 g ml–1, respectively, which are the minimum detection levels, whereas the concentration of iron, manganese, copper, and zinc in most of the samples is within the global average ranges of 3%, 500–1000 g g–1, 15–40 g g–1, and 50–100 g g–1, respectively. The investigated area has the presence of gneisses and schists, in which partly there are igneous intrusions and pegmatitic intrusions. There are amphibolite enclaves in gneisses that account for the higher concentration of trace elements. The lower concentration may be attributed to the presence of silicic type of rock. 相似文献
10.
Kevin H. Johannesson W. Berry Lyons Suey Huey Georgia a. Doyle Eric E. Swanson Ed Hackett 《Aquatic Geochemistry》1997,3(1):61-97
Water samples were collected from the Truckee River-Pyramid Lake system, the Walker River-Walker Lake system, and the Carson River, all located in eastern California and western Nevada, U.S.A., at three different times (i.e., summer 1991, spring 1992, and autumn 1992) over a two year period. The concentrations of As, Na, Cl, PO4, and pH were measured in these river samples and the associated terminal lakes. Arsenic values ranged from below 13 nmol/kg near Truckee, California to 160 nmol/kg at Nixon, Nevada in the Truckee River, from 40 nmol/kg in the headwaters of both West and East Walker Rivers to 270 nmol/kg below Weber Reservoir on the main branch of the Walker River, and from <27 nmol/kg to 234 nmol/kg for the lower Carson River system. Arsenic concentrations in Steamboat Creek (0.91 mol/kg–1.80 mol/kg) in the Truckee River catchment are above the U.S. EPA drinking water maximum contaminant level of 0.67 mol/kg, as are the As concentrations in both Pyramid Lake (1.33 mol/kg–1.57 mol/kg ) and Walker Lake (13.7 mol/kg–18.7 mol/kg). Sources of As for all three rivers include weathering of As-rich rocks and/or regolith and input of high-As geothermal spring waters, both processes primarily, although not exclusively, adding As to the headwater regions of these rivers. Steamboat Hot Springs (29 mol/kg As 54.5 mol/kg), for example, is identified as a source of As to the Truckee River via Steamboat Creek. The high As concentrations in Pyramid and Walker Lakes are likely due to (1) desorption of arsenate from aquatic particulate matter in these high pH waters (9.0 pH 9.5), (2) limited biologic uptake of arsenate, and (3) evaporative concentration of the lake waters. Evaluation of molar PO4}/As ratios of river waters and geothermal spring waters (e.g., Steamboat Hot Springs), indicates that phosphate is substantially enriched in Steamboat Creek as well as the mid to lower reaches of the Walker and Carson Rivers. These regions of each river are dominated by agricultural interests and, additionally, in the case of Steamboat Creek, residential areas and golf courses. Our data strongly imply that phosphate-rich agricultural return flow has likely added P to these streams and, consequently, increased their respective P:As ratios. 相似文献
11.
Hodges K. V. Hames W. E. Olszewski W. Burchfiel B. C. Royden L. H. Chen Z. 《Contributions to Mineralogy and Petrology》1994,117(2):151-163
Mineral assemblages in the Dinggyê area of southern Tibet (28°N; 88°E) provide new insights regarding the poorly understood Eohimalayan metamorphic event in the eastern Himalayan orogen. Major element partitioning thermobarometry of pelitic rocks indicates temperatures of 750–830 K at depths of 14±3 km, consistent with the presence of kyanite, sillimanite, and andalusite schists in the area. Laser and resistance furnace40Ar/39Ar analyses of hornblendes from intercalated amphibolites yield closure ages of 25 Ma. Overlap between the probable range of Ar closure temperatures for these hornblendes and the metamorphic temperatures estimated through thermobarometry suggests that Eohimalayan metamorphism in the Dinggyê area occurred in Late Oligocene time, no more than about 10 million years before the main or Neohimalayan phase of metamorphism in Early to Middle Miocene time. Muscovite, biotite, and K-feldspar40Ar/39Ar ages indicate an important episode of rapid cooling between 16 and 13 Ma, which is interpreted as a signature of tectonic denudation related to movement on N-dipping extensional structures of the South Tibetan detachment system. 相似文献
12.
Gerald L. Crow Marlin J. Atkinson Benny Ron Shannon Atkinson Arleene D. K. Skillman George T. F. Wong 《Aquatic Geochemistry》1998,4(3-4):469-480
Captive whitetip reef sharks, Triaenodon obesus,at Sea Life Park (SLP) Hawaii, Waimanalo, Hawaii develop goitre, whereas, T. obesus at the Waikiki Aquarium (WAQ), Honolulu,Hawaii do not develop goitre. To determine theeffects of natural concentrations of iodine on thereduction of goitre, two sharks from SLP with goitrewere placed in an enclosed coastal lagoon with naturalseawater. Using ultrasound measurements the twogoitres were initially 11.4 cm and 14.6 cm in depthand after 3 months decreased to 4.7 cm and 5.7 cm. Radioimmunoassay analysis of the thyroid hormoneT3 sera concentrations were initially 0.22 ng/mland 0.33 ng/ml and increased to 1.84 ng/ml after beingplaced in the lagoon. Sera T4 were initially0.93 ng/ml and 0.99 ng/ml and increased dramaticallyto 17 ng/ml and 56 ng/ml. Over the six month samplingperiod, two resident sharks in the lagoon with normalthyroids had sera T3 concentrations from 0.89ng/ml to 1.1 ng/ml, and sera T4 concentrationsfrom 3.1 ng/ml to 7.9 ng/ml. The hypothyroidcondition in the SLP goitred-sharks is likely linkedto the low environmental iodide (<0.005 M), andhigh nitrate (111 M) of SLP water. The WAQwell-water facility was characterized by anoxic waterwith high iodide (0.60 M), total iodine (1.90M), and typical nitrate (24.6 M)concentrations of interstitial groundwater. Thedifference of iodide concentration of SLP and WAQ tankwater (<0.005 M versus 0.60 M) wasdirectly related to the hydrogeology of the well-watersources. To avoid goitre in marine aquarium systems,we recommend maintaining iodide concentrations of atleast 0.15 M. 相似文献
13.
Samples of MH-10, a K-feldspar thought to contain discrete diffusion domains for argon, have been examined by light and TEM microsopy to search for domain boudaries. We examined both unheated K-feldspar separates and samples heated in vacuum between 750 and 1150°C in order to characterize the initial microstructure as well as any changes resulting from laboratory heating. The MH-10 rock shows almost no evidence of plastic deformation, and the K-feldspar does not possess networks of dislocations which might define a subgrain structure derived from external stresses. Three classes of substructure are present in the K-feldspar, but only the third appears to have been affected by laboratory heating: (1) Cross-hatched extinction in light microscope is common but variably developed. TEM reveals almost no albite/pericline twinning but tweed microstructure is ubiquitous. (2) Turbid zones occur with about 5 volume % abundance. Micropores, <1 to 2m in diameter, characterize these regions, which often also contain bleds of albite, up to 40 m indiameter, TEM shows these turbid zones to be very complex with intricate twin and tweed structures at the sub-micron scale and numerous dislocation and strain features. (3) Albitic exsolution lamellae (<1 m thick, 20 m long and separated by 1 m) are rarely seen in the light microscope but TEM shows that 0.01 m thick by 0.2–1 m long lamellae, separated by 0.1 to 0.5 m, occur in about 20% of the sample. These lamellae are disk-shaped, have a semi-coherent or coherent relationship to the host K-feldspar, and seem to disappear upon heating to 750°C. Extensive diffusion studies have been conducted on HM-10, and the results analyzed in terms of distribution of sizes of diffusion domains. The preferred result of the analyses was a distribution consisting of three distinct sizes. The largest domain size identified in this way is approximately 50 to 100 m, and this corresponds to blocks of K-feldspar defined by the network of fractured/turbid zones. The smallest domain size inferred from diffusion analysis is 0.1 m which corresponds to the spacing between albite exsolution lamellae that may represent fast diffusion pathways. Alternatively, the modulated argon distribution accompanying the lamellar variation in feldspar composition may result in an overestimation of the initial diffusion coefficients. Even though a promising agreement exists between domain analyses based upon diffusional and microstructural analyses, at least two questions remain unanswered. Firstly, no clear candidate has been identified for a domain of intermediate size. Secondly, the diffusion analysis has been formulated with independent gas release from all domains, whereas the observed structures are likely to be nested (i.e., small domains exist inside bigger domains) with the network of semi-coherent lamellar boundaries having connectivity and permeability which can provide only a modest increase in argon diffusivity over bulk values. 相似文献
14.
A. Reuter 《Contributions to Mineralogy and Petrology》1987,97(1):105-115
White mica bearing fractions ranging in grain size from 0.4 m to 6.3–20 m were separated from metapelites and intercalated metatuffs of the eastern Rheinisches Schiefergebirge (FRG). The stratigraphic age of these rocks is Middle Devonian (Eifelian), and they contain detrital material of northwestern provenance (Old Red Continent, probably mainly derived from the Caledonian Orogen). Folding in the Carboniferous was associated with cleavage formation and an apparently synkinematic anchizonal metamorphism. Apparent K-Ar ages of metapelite fractions display a marked positive correlation with grain size illustrating the detrital influence which is diminished with decreasing grain size and increasing metamorphism (determined by illite crystallinity). Contrasting grain morphologies observed by SEM enable the interpretation of apparent age/ grain size relationship for coarse fractions. The anticipated lack of detrital mica in metatuffs is confirmed by the fairly consistent apparent K-Ar ages determined for the coarser than 0.63 m size fractions which date the anchizonal metamorphism at ca. 330 Ma. Comparison of metatuff and metapelite apparent ages suggests that the extent of rejuvenation in the latter was largely dependent on grain size. Rejuvenation was also somewhat controlled by the degree of anchizonal metamorphism as suggested by differences in K-Ar results of metapelites which were metamorphosed at variable anchizonal conditions. Fractions <0.63 m from upper anchizonal metapelites record ca. 330 Ma ages similar to those of the 0.63–20 m sizes in metatuffs. Together those results confirm the limited applicability of conventional K-Ar dating on bulk clay fractions (<2 m) of very-low grade (anchizonal) metamorphic rocks in dating metamorphic events and concomitant cleavage formation. 相似文献
15.
The distribution of some trace metals (Cu, Zn, Ni, Co,Fe, Mn) and of DOC over a particulate (> 1 m),a colloidal (size < 0.45 m and molecular weight > 10 kD) and an ultrafiltered fraction (< 10 kD)was determined at several sites on the Thur River,Switzerland, at various times of the year. Thecomplexation of Cu by strong ligands in theultrafiltrate and in the conventional filtrate (<0.45 m) was compared using a ligand-exchange/CSV method.The <0.45 m concentrations of Cu (from anaverage of 7 nM to 24 nM), Zn (<5–23 nM), Ni (5–13 nM),Co (1.5–3 nM) and Mn (7–92 nM)increased downstream. The major part of Cu, Zn, Niand Co usually occurred in the ultrafiltratefraction at all sites, whereas Fe and Mn were mostlyin the particulate fraction, under conditions of lowsuspended matter content (< 10 mg L-1) in theriver. The percentage of metal in the colloidalfraction, with respect to the 0.45-m filtrate,decreased in the order: Cu (median 11%) > Zn Ni(median 5–6%) > Mn Co (median < 5%). DOCalso consisted mostly of molecules in the < 10 kDrange.Cu was strongly complexed by natural organic ligandsin all filtrate and ultrafiltrate samples. A largepart of the strong Cu binding ligands consisted ofcompounds in the < 10 kD range, but colloidalligands with similar properties also occurred. Cu wasdistributed among the dissolved and the colloidalligands, roughly in proportion to organic carbon.The colloidal fraction (as defined here) did notincrease in its proportional amount downstream and wasonly of limited significance in transporting traceelements in the Thur River under low discharge conditions. 相似文献
16.
Divariant oxide plus metal assemblages potentially make useful redox sensors for use in hydrothermal and other high pressure experiments. Here we report the calibration of the (Ni, Mn)O/Ni redox sensor in which the Ni/NiO (NNO) oxygen buffer is displaced to lower oxygen chemical potentials (O2), by the solid solution of MnO in the oxide phase. This assemblage was chosen because: (1) it covers a useful range of O2; (2) the system can be calibrated very accurately. Values of O2 defined by the (Ni, Mn)O/Ni assemblage were determined electrochemically, from 900 to 1300 K, using calcia-stabilized zirconia solid electrolytes. The oxide compositions (8 in total, ranging from 0.1X
NiO0.8) were analysed afterwards by electron microprobe, and were checked for internal consistency by measuring the lattice parameters (a0), using powder XRD. The accuracies of the measurements, both assessed theoretically and established empirically, are (1): ±80J/mol in O2, ±0.0002 Å in a0 and ±0.002 to 0.005 in X
NiO. Activity-composition relations were fitted to the Redlich-Kister formalism. There is a slight asymmetry (corresponding to a subregular model) across the solution with A
0
G
=9577(±45) J/mol, and A
1
G
=–477(±80) J/mol. The experimental data were also used to derive the parameters Vex, Hex and Sex. There is no obvious relationship between excess volumes and enthalpies of mixing, nor between excess volumes and excess entropies. The experimental data from this study have been used to formulate the (Ni, Mn)O/Ni redox sensor expression: O2 = 2(NNO) + 2RTlnX
NiO + 2(1 – X
NiO)2[11483 – 1.697T] – 477(4X
NiO – 1)(900 < T(K) < 1300) where O2(NNO)=–478967+248.514T–9.7961 T In T, from O'Neill and Pownceby(1993a). 相似文献
17.
Alessandro Pavese 《Physics and Chemistry of Minerals》2005,32(4):269-276
The notion of scalar strain in minerals is crucial for the formulation of P-V equations of state (EoS). A scalar strain, , holding for any crystal symmetry has been derived by a rigorous and general approach, and then used to develop the related phenomenological P-V EoS. , which depends on V and the trace of the G* G0 matrix, can be split into two components, M and , where the former takes values close to those of the scalar strain according to Birch. M, providing the main contribution (often larger than 80%) to , is appropriate for the formulation of an EoS as M/V behaves regularly in the limit of an unstrained configuration. The phenomenological EoS based on M shows the same dependence on the elastic parameters (bulk modulus and derivatives versus pressure) of the usual Birch-Murnaghan EoS, and yields comparable results. Slight deviations occur for low symmetry minerals. This work is meant to contribute (1) to shed light on the relationships between scalar strain and related P-V EoSs, and (2) to provide a most general EoS which includes, as a particular case, the Birch-Murnaghan model and explains why this latter is reliable for crystal symmetry other than the cubic one, for which it was originally derived. 相似文献
18.
Zusammenfassung Mikroskopisch Einschluß-freie Andalusite aus Brasilien zeigen im UR-Absorptionsspektrum ein Doppelmaximum bei zirka 2,9 und ein deutlich schwächeres einfaches Maximum bei 3,04 , die OH-Valenzschwingungen zugeordnet werden. Diese Maxima verschwinden nach mehrtägigem Glühen bei 1000° C. In Platten parallel (110) zeigt das Doppelmaximum bei zirka 2,9 einen extrem starken Pleochroismus, wobei die Bande praktisch völlig verschwindet, wenn der elektrische Vektor parallel [001] schwingt. Damit müssen zumindest die OH-Gruppen, die für diese Bande verantwortlich sind, in die Struktur eingebaut sein. Für beide Arten von OH-Gruppen werden die plausiblen Anordnungen diskutiert.
Mit 3 Abbildungen 相似文献
Measurement of the infrared-pleochroism in minerals. VIII. The pleochroism of the OH-stretching frequency in andalusite
Summary Inclusion-free andalusites from Brazil show in the IR absorption spectrum a double maximum at ca. 2.9 and a much weaker single maximum at 3.04 which are interpreted as belonging to OH-stretching frequencies. The maxima disappear after annealing the specimen at 1000°C for several days. Plates parallel to (110) show a very strong pleochroism for the 2.9 -band, the peak being practically of zero height if the electric vector vibrates parallel [001]. This proves that at least the OH-groups which are responsible for this absorption band are constituents of the crystal structure. For both kinds of OH-groups the probable distributions are discussed.
Mit 3 Abbildungen 相似文献
19.
Dr. Heimo Nielsen 《International Journal of Earth Sciences》1966,55(1):160-172
Zusammenfassung Durch Isotopenfraktionierung bei der bakteriellen Reduktion marinen Sulfats enthalten die Sedimente im Mittel einen Überschuß an32S (34S s – 5), während32S im marinen Sulfat angereichert ist. Der 34S-Wert im heutigen Meerwasser beträgt etwa + 20 . Evaporit-34S-Messungen zeigen, daß dieser Wert im Cambrium, Silur und Devon höher war, bis zum Perm dann auf etwa + 11 abnahm und anschließend wieder zum heutigen Wert anstieg.Der hohe 43S-Wert in der geologischen Frühzeit wird mit extremer Anreicherung biogener Sulfide in den Schwarzschiefern erklärt, der Abfall zum Perm mit Rückführung großer Mengen von Sediment-Schwefel im Laufe der caledonischen und varistischen Orogenesen und der Wiederanstieg im Erdmittelalter mit erneuter Anhäufung toniger Sedimente.Aufgrund modellmäßiger Abschätzungen und der Gesamtheit aller verfügbaren Meßwerte (etwa 800) wird versucht, die Entwicklungslinie des Meerwasser-34S-Wertes zeichnerisch darzustellen.Hinweis auf praktische Bedeutung: Informationen über Stoffbilanz geologischer Vorgänge, Interpretation von 34S-Meßwerten an normalen Gesteinen und Erzen, Zuordnung von Proben unbekannten Alters.
Summary Due to an isotope fractionation involved in the bacterial reduction of marine sulfate the sediments as a whole contain an excess of32S (34S – 5), while marine sulfate is enriched in34S. Recent seawater has 34S + 20. Evaporite measurements indicate a still higher value in Cambrian, Silurian and Devonian time. Then the 34S decreased to about + 11 in the Upper Permian and later on increased once more to the modern value.The accumulation of abnormally large quantities of biogenic sulfides in the slates of that era accounts for the high 34S value in the early Palaeozoic. A considerable fraction of light sulfur has been brought back to the oceans by weathering solutions of the Caledonian and Variscan orogenies, and in Mesozoic times another accumulation of slates has taken place.From a synopsis of the data available (some 800) and from model estimations an attempt has been made to construct the marine sulfur gd34S evolution curve. Some practical consequences are lined out: informations on material balance of geological processes, interpretation of 34S-data of normal rocks and ores, sample dating in the case of doubtful age.
Résumé Un fractionnement isotopique pendant la réduction bactérienne du sulfate marin a pour conséquence un excédent de32S dans la masse totale des sédiments (34S – 5) et un enrichissement de34S dans le sulfate marin. Dans les océans actuels le 34S est + 20 ; nous pouvons conclure des 34S des échantillons de sulfates d'évaporites, qu'aux temps cambrien, silurien et dévonien cette valeur fut plus élevée. Puis elle a diminué jusqu'à + 11 au Permien supérieur pour remonter ensuite à la valeur actuelle.La valeur élevée de 34S au Paléozoïque inférieur doit être expliquée par une accumulation extraordinaire de sulfures biogènes dans les ardoises noires de cette époque. La décomposition d'une fraction considérable de ces roches pendant les orogenèses calédonienne et varisque entraînait à l'océan du soufre léger. Au Mésozoïque une autre accumulation d'ardoises commençait. Par l'examen de toutes valeurs disponibles (environ 800) et par certaines estimations on a tenté de tracer la courbe de l'évolution de la valeur du 34S marin.Quelques conséquences pratiques sont indiquées: informations sur le bilan matériel des procès sus-géologiques, interprétation des 34S de roches et minerais normaux, datation d'échantillons d'âge problématique.
. S34 , , ( 2%); 1,1%. .相似文献
20.
Ion microprobe analysis of magnetites from the Adirondack Mountains, NY, yields oxygen isotope ratios with spatial resolution of 2–8 m and precision in the range of 1 (1 sigma). These analyses represent 11 orders of magnitude reduction in sample size compared to conventional analyses on this material and they are the first report of routinely reproducible precision in the 1 per mil range for analysis of 18O at this scale. High precision micro-analyses of this sort will permit wide-ranging new applications in stable isotope geochemistry. The analyzed magnetites form nearly spherical grains in a calcite matrix with diopside and monticellite. Textures are characteristic of granulite facies marbles and show no evidence for retrograde recrystallization of magnetite. Magnetites are near to Fe3O4 in composition, and optically and chemically homogeneous. A combination of ion probe plus conventional BrF5 analysis shows that individual grains are homogeneous with 18O=8.9±1 SMOW from the core to near the rim of 0.1–1.2 mm diameter grains. Depth profiling into crystal growth faces of magnetites shows that rims are 9 depleted in 18O. These low 18O values increase in smooth gradients across the outer 10 m of magnetite rims in contact with calcite. These are the sharpest intracrystalline gradients measured to date in geological materials. This discovery is confirmed by bulk analysis of 150–350 m diameter magnetites which average 1.2 lower in 18O than coarse magnetites due to low 18O rims. Conventional analysis of coexisting calcite yields °18O=18.19, suggesting that bulk 18O (Cc-Mt)=9.3 and yielding an apparent equilibration temperature of 525° C, over 200° C below the temperature of regional metamorphism. Consideration of experimental diffusion data and grain size distribution for magnetite and calcite suggests two contrasting cooling histories. The data for oxygen in calcite under hydrothermal conditions at high P(H2O) indicates that diffusion is faster in magnetite and modelling of the low 18O rims on magnetite would suggest that the Adirondacks experienced slow cooling after Grenville metamorphism, followed by a brief period of rapid cooling, possibly related to uplift. Conversely, the data for calcite at low P(H2O) show slower oxygen diffusion than in magnetite. Modelling based on these data is consistent with geochronology that shows slow cooling through the blocking temperature of both minerals, suggesting that the low 18O rims form by exchange with late, low temperature fluids similar to those that infiltrated the rock to serpentinize monticellite and which infiltrated adjacent anorthosite to form late calcite veinlets. In either case, the ion microprobe results indicate that two distinct events are recorded in the post-metamorphic exchange history of these magnetites. Recognition of these events is only possible through microanalysis and has important implications for geothermometry. 相似文献