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1.
To discriminate the mineral potentiality of the trachybasalt around the Miocene Sarcheshmeh porphyry copper deposit, petrogeochemical characteristics of more than 45 samples of the volcanic rocks were studied. Sarcheshmeh is one of the world's largest Miocene porphyry copper deposits in a continental arc setting and contains about 1200 million tonnes of ores with an average grade of 1.2 percent copper, 0.03 percent molybdenum, 3.9 g/t Ag and 0.11 g/t Au. The biotized and sericitized trachybasalts around the Sarcheshmeh deposit are associated with chalcopyrite, pyrite and molybdenite and and are enriched in Cu (>3108 ppm), K2O (>4.2%), Rb (>155 ppm) and MgO (>2.9%), but depleted in yttrium (<11 ppm), MnO (<0.06%), CaO (<0.6%), Na2O (<0.33%), Sr (<107 ppm), and Ba (<181 ppm). The propylitized trachybasalts are enriched in CaO (>9.1%), Na2O (>3.2%), MnO (>0.24%), Y (>18.2 ppm), and Ba (>323 ppm). The results demonstrate that the diagrams of loss on ignition ? Cu, Cu ? Y, K2O/K2O + Na2O + CaO ? Cu and Y ? MnO may be used as an exploration guide for undiscovered porphyry copper mineralization in the Central Iranian volcano—plutonic copper belt.  相似文献   

2.
This note reports new occurrences of syenite bodies around Marunthurkota area from the Kerala khondalite belt (KKB). Petrological and geochemical studies suggest that the syenites have a pronounced A-type affinity, metaluminous characteristics with high concentrations of alkalies, Rb, Sr, Zr, and high K2O/Na2O ratio. Miaskitic nature (agpaitic index<1) of syenite suggest involvement of CO2 related phase in their genesis. The petrological characteristics signify crystallization of the rock at shallow levels within the crust. Geochemistry favours mantle origin of the magma and enrichment of Ba and Sr are indicative of involvement of carbonatite melt in the source region. The study envisages the presence of a juvenile CO2 enriched upper mantle below the southern Indian continental crust during the Pan-African time.  相似文献   

3.
A medium tonnage unconformity proximal uranium deposit has been established at Chitrial by the Atomic Minerals Directorate in the Srisailam sub-basin. In this type of deposits, the association of uranium with potassic alteration (illitization) is well-documented. The present study is directed towards understanding such an association in the Chitrial area for which the uranium mineralized borehole core samples were collected and analyzed. It is observed that the average concentrations of K2O, Na2O, Rb, Ba and Sr in the granite of the Chitrial area are 5.35%, 1.78%, 252 ppm, 564 ppm and 52 ppm, respectively, and they show average critical elemental ratios of K/Rb, Ba/Rb and Rb/Sr as 191, 2.37 and 7.13, respectively. The granites show low K/Rb, low Rb/Ba and high Rb/Sr ratios compared to that of the average crust indicating its derivation from crustal source. The samples have higher values of uranium (av. 53 ppm), thorium (av. 66 ppm) and lead (av. 41 ppm). The U/Th ratio in the granite varies from 0.07 to 20.86 with an average of 1.68. They also exhibit high K2O/Na2O ratio typical of post-Archaean granite and very high values suggest the possibility of later potassium enrichment.  相似文献   

4.
The distribution of Ba, Rb and Sr during crystallization of a granitic melt is examined in a number of theoretical models. The modes of crystallization considered are perfect fractional crystallization, perfect equilibrium crystallization, and an intermediate mode, incremental equilibrium crystallization. The effect of the degree of separation of cumulus minerals from melt during crystallization is also considered. Perfect fractional and incremental equilibrium crystallization (with small increments) are broadly similar, but differ in the final stages of crystallization in that the latter mode defines a finite trace element composition for the last solid. The effect of intercumulus melt in both modes of crystallization imparts a ‘liquid’ character to the solids, and suppresses the degree of enrichment of Rb and depletion of Ba and Sr in late solids and melts.Examination of trace element data for the Acid Phase of the Bushveld Igneous Complex in the light of these models suggests that these granites represent a suite of cumulate rocks, containing relatively large amounts of intercumulus melt.  相似文献   

5.
本文对北秦岭马河钼矿区桃官坪中-细粒二长花岗岩和西沟斑状二长花岗岩进行了LA-ICP-MS锆石U-Pb年龄测定,分别获得了157±1Ma(NSWD=13)和153±1Ma(NSWD=14)的谐和年龄,表明其为晚侏罗世侵入体。马河钼矿的形成与这两个侵入体密切相关,据此限定该钼矿床成矿时代略晚于157~153Ma,为侏罗世晚期成矿。桃官坪和西沟花岗岩具有高硅(68.12%~76.33%),富碱(Na2O+K2O=6.35%~10.38%)的特征,K2O/Na2O变化较大(0.91~1.89),A/CNK在0.85~1.14之间,为准铝质-弱过铝质高钾钙碱性系列。微量元素上富集U、Pb、Hf等高场强元素,亏损Rb、Ba、K、Sr、P等大离子亲石元素。稀土元素配分曲线为轻稀土相对富集的右倾型,多数具有弱的负铕异常(δEu=0.5~0.9),少数样品具有弱正铕异常(δEu=1.05~1.08)。与华北地块南缘与钼矿有关的花岗岩相比,二者均具有高硅、高钾、富碱的特征。但马河钼矿区成矿花岗岩比华北地块南缘的稍基性,这可能是导致马河钼矿的矿床规模比华北地块南缘较小的原因之一。  相似文献   

6.
Mildly deformed granitoids exposed around Bilgi in the northernmost part of the eastern Dharwar craton are divided into two groups viz. granodiorites and monzogranites. The granodiorites contain microgranular enclaves and amphibolite xenoliths, and show low-Al TTG affinity with high SiO2 (71–74 %), Na2O, Y and Sr/Y, moderate to moderately high Mg#, Cr and Ni, low to moderate LILE, and low Nb and Ta. However, compared to similar TTGs from different cratons the Bilgi granodiorites have distinctly higher K2O, K2O/Na2O, Rb and lower REE and Th. The amphibolite xenoliths are characterized by variable enrichment of K2O, Rb, Ba and Th and depletion of Ti, Zr and P compared to MORB. The microgranular enclaves are quartz diorite to granodiorite in composition with high Mg, Ni and Cr, and compared to MORB, are enriched in LILE and depleted in Ti and Y. The monzogranites, compared to the granodiorites, display higher SiO2, K2O and Rb with lower Mg#, although still maintaining the high Na2O, Ni and Cr and low REE character. The Bilgi granodiorites are explained as transitional TTGs late synkinematic with respect to regional deformation. Geochemical signatures and regional geological set up suggest that they are probably derived from partial melting of a highly depleted slab material (metabasalt) followed by variable contamination or assimilation of intermediate crustal rocks in a subduction zone set up. Late stage fluid activity on the granodioritic magma is probably responsible for the generation of monzogranites. The amphibolite xenoliths predate the granodiorites and possibly represent fragments of a schist belt carried away by the granitic magma. They are probably island arc basalt derived from mantle source that has been metasomatized by slab-derived fluids. The microgranular enclaves are coeval with the Bilgi granodiorites and also likely to be island arc magmas derived from mantle variably enriched in slab-derived and within-plate components.  相似文献   

7.
刘杰勋  郭巍  朱凯 《岩石学报》2016,32(9):2889-2900
本文对辽东岫岩地区帽盔山二长花岗岩、荒地花岗闪长岩和朝阳苏长辉长岩进行了岩相学、地球化学、LA-ICP-MS U-Pb定年。帽盔山二长花岗岩主量元素具有富Si、Al、K,贫Fe、Mg、Ca的特征;微量元素亏损Sr、P、Eu、Ti,富集K、Rb、Th等不相容元素,元素地球化学特征表明岩体为铝质A型花岗岩(A/CNK=1.03~1.06,A/NK=1.11~1.12)。荒地花岗闪长岩的SiO_2含量为64.1%~70.8%,K_2O/Na_2O的比值为0.87~1.08,含铝指数A/CNK和A/NK分别为0.98~1.02和1.31~1.55,微量元素富集K、Rb、Sr、Ba等大离子亲石元素,亏损Nb、P、Ti等高场强元素,轻重稀土分馏强烈,(La/Yb)N值为13.41~68.2,属于准铝质到过铝质I型花岗岩。朝阳苏长辉长岩的SiO_2含量为54.8%~58.3%,K_2O/Na_2O的比值为0.57~0.78,微量元素富集K、Ba、Sr等大离子亲石元素,亏损Nb、U、P、Ti等高场强元素,富集La、Ce、Pr、Nd等轻稀土元素。测年结果显示帽盔山二长花岗岩的锆石年龄为137Ma,荒地花岗闪长岩的锆石年龄为139Ma,朝阳苏长辉长岩的锆石年龄为139Ma,均形成于早白垩世。结合构造背景图解,帽盔山二长花岗岩、荒地花岗闪长岩和朝阳苏长辉长岩均为伸展构造环境下的岩浆活动产物。结合三个岩体的时空特点,表明在早白垩世时期,辽东岫岩地区处于非造山的伸展环境,且岩石圈减薄及伸展活动的发展有自深部至浅部的特点,是华北板块东部伸展地球动力学背景的具体体现。  相似文献   

8.
The Chalukou porphyry Mo deposit, located in the northern Great Xing'an Range, is the largest Mo deposit in the Xing'an–Mongolia orogenic belt. Its ore bodies are mainly hosted in the intermediate-felsic complex and Jurassic volcanic sedimentary rocks, of which Late Jurassic granite porphyry, quartz porphyry and fine-grained granite are closely associated with Mo mineralization. The Middle Jurassic monzogranite belongs to shoshonite series, with SiO2 and Al2O3 contents of 69.48 to 74.98% and 12.35 to 14.48%, respectively. The total alkali (K2O + Na2O) content ranges from 7.67 to 10.42%, with K2O/Na2O ratios between 1.07 and 2.81. These rocks are strongly enriched in Rb and K but are depleted in Ta, Nb, P and Ti, with negative Eu anomalies and positive εHf(t). The Late Jurassic granite porphyry, quartz porphyry and fine-grained granite are shoshonite or high-K calc-alkaline series. Their SiO2 and Al2O3 contents range from 73.87 to 78.95% and 10.35 to 13.47%, respectively. The total alkali (K2O + Na2O) contents range from 8.06 to 10.02%, with K2O/Na2O ratios from 1.03 to 8.20. These rocks are strongly enriched in Rb, K and Th, but are depleted in P, Ti, Ba and Sr, indicating clear negative Eu anomalies and positive εHf(t). The Middle–Late Jurassic granitoids in the Chalukou deposit are highly fractionated I-type granitoids, and derived from juvenile lower crust materials that originated from the Neoproterozoic depleted mantle. These granitoids formed in the extension tectonic setting of the post-collision stage of the Mongol–Okhotsk orogenic belt, probably superposed by the back-arc extension related to the subduction of the Paleo-Pacific Plate.  相似文献   

9.
Loss of metals from pelites during regional metamorphism   总被引：3，自引：0，他引：3  
In aluminous metapelites the ratio H2O+/K2O decreases with increasing metamorphic grade and degree of reaction. This ratio is a very practical indicator for the progress of the mineral reconstitution during progressive metamorphism. With decreasing values of the ratio H2O+/ K2O the Cu concentration and the following element ratios also decrease either continuously or in stepwise fashion: Tl/K2O, Ba/K2O, Pb/K2O, Bi/K2O, Hg/K2O, Sr/Na2O, Zn/(Fe2++Mg), Cd/(Fe2++Mg); Rb/K2O remains approximately constant. In the aluminous metapelites of the Damara Orogen in Namibia the following losses occur between the biotite isograd and anatexis: 61% Cu, 20% Tl, 34% Ba, 59% Pb, 86% Bi, 46% Hg, 30% Sr, 25% Zn, 31% Cd. Thus the potential of regional metamorphism to form hydrothermal deposits in the low grade environment should not be neglected.  相似文献   

10.
A dike–vein complex of potassic type of alkalinity recently discovered in the Baikal ledge, western Baikal area, southern Siberian craton, includes calcite and dolomite–ankerite carbonatites, silicate-bearing carbonatite, phlogopite metapicrite, and phoscorite. The most reliable 40Ar–39Ar dating of the rocks on magnesioriebeckite from alkaline metasomatite at contact with carbonatite yields a statistically significant plateau age of 1017.4 ± 3.2 Ma. The carbonatite is characterized by elevated SiO2 concentrations and is rich in K2O (K2O/Na2O ratio is 21 on average for the calcite carbonatite and 2.5 for the dolomite–ankerite carbonatite), TiO2, P2O5 (up to 9 wt %), REE (up to 3300 ppm), Nb (up to 400 ppm), Zr (up to 800 ppm), Fe, Cr, V, Ni, and Co at relatively low Sr concentrations. Both the metapicrite and the carbonatite are hundreds of times or even more enriched in Ta, Nb, K, and LREE relative to the mantle and are tens of times richer in Rb, Ba, Zr, Hf, and Ti. The high (Gd/Yb)CN ratios of the metapicrite (4.5–11) and carbonatite (4.5–17) testify that their source contained residual garnet, and the high K2O/Na2O ratios of the metapicrite (9–15) and carbonatite suggest that the source also contained phlogopite. The Nd isotopic ratios of the carbonatite suggest that the mantle source of the carbonatite was mildly depleted and similar to an average OIB source. The carbonatites of various mineral composition are believed to be formed via the crystallization differentiation of ferrocarbonatite melt, which segregated from ultramafic alkaline melt.  相似文献   

11.
Summary Archaean granodioritic rocks from the Ventersdorp Dome have been hydrothermally altered in two stages: epidotization and K-feldspatization. The alteration locally is both pervasive or occurs along veins. Mass balance calculations reveal CaO, Fe2O3, Sr and Y addition and loss of Na2O,K2O, MgO, Pb and Ba during epidotization. The combined epidotization and K-feldspatization involved a gain in SiO2, Fe2O3, CaO, K2O, Ba, Sr and Rb. A12O3 and Nb were immobile during both alteration stages. The alteration is accompanied by a change in the An-content of the plagioclase (An11 to An1).
Mineralogie und Geochemie der hydrothermal veränderten, archaischen Granodiorite des Ventersdorp Domes (westliches Transvaal, Südafrika)
Zusammenfassung Archaische Granodiorite des Ventersdorp Domes sind durch zwei Typen hydrothermaler Verdnderung, Epidotisierung und Kalifeldspatisierung überprägt worden. Die Veránderung tritt sowohl durchdringend als auch auf Adern auf. Massenvergleichsberechnungen ergaben, daß während der Epidotisierung CaO, Fe2O3, Sr und Y angereichert und Na2O, K2O, MgO, Pb und Ba abgeführt worden sind. Während der kombinierten Epidotisierung und Kalifeldspatisierung treten eine Zufuhr von SiO2, Fe2O3, CaO, K2O, Ba, Sr und Rb auf. A12O3 und Nb verhielten sich während beider Verdnderungen immobil. Die hydrothermale Veränderung wurde von einer Verminderung des Ca-Gehaltes der Plagioklase begleitet (An11 zu An1).
  相似文献   

12.
We provide data on the geochemical and isotopic consequences of nonmodal partial melting of a thick Jurassic pelite unit at mid-crustal levels that produced a migmatite complex in conjunction with the intrusion of part of the southern Sierra Nevada batholith at ca. 100 Ma. Field relations suggest that this pelitic migmatite formed and then abruptly solidified prior to substantial mobilization and escape of its melt products. Hence, this area yields insights into potential mid-crustal level contributions of crustal components into Cordilleran-type batholiths. Major and trace-element analyses in addition to field and petrographic data demonstrate that leucosomes are products of partial melting of the pelitic protolith host. Compared with the metapelites, leucosomes have higher Sr and lower Sm concentrations and lower Rb/Sr ratios. The initial 87Sr/86Sr ratios of leucosomes range from 0.7124 to 0.7247, similar to those of the metapelite protoliths (0.7125–0.7221). However, the leucosomes have a much wider range of initial εNd values, which range from −6.0 to −11.0, as compared to −8.7 to −11.3 for the metapelites. Sr and Nd isotopic compositions of the leucosomes, migmatites, and metapelites suggest disequilibrium partial melting of the metapelite protolith. Based on their Sr, Nd, and other trace-element characteristics, two groups of leucosomes have been identified. Group A leucosomes have relatively high Rb, Pb, Ba, and K2O contents, Rb/Sr ratios (0.15<Rb/Sr<1.0), and initial εNd values. Group B leucosomes have relatively low Rb, Pb, Ba, and K2O contents, Rb/Sr ratios (<0.15), and initial εNd values. The low Rb concentrations and Rb/Sr ratios of the group B leucosomes together suggest that partial melting was dominated by water-saturated or H2O-fluxed melting of quartz + feldspar assemblage with minor involvement of muscovite. Breakdown of quartz and plagioclase with minor contributions from muscovite resulted in low Rb/Sr ratios characterizing both group A and group B leucosomes. In contrast, group A leucosomes have greater contributions from K-feldspar, which is suggested by: (1) their relatively high K concentrations, (2) positive or slightly negative Eu anomalies, and (3) correlation of their Pb and Ba concentrations with K2O contents. It is also shown that accessory minerals have played a critical role in regulating the partitioning of key trace elements such as Sm, Nd, Nb, and V between melt products and residues during migmatization. The various degrees of parent/daughter fractionations in the Rb–Sr and Sm–Nd isotopic systems as a consequence of nonmodal crustal anatexis would render melt products with distinct isotopic signatures, which could profoundly influence the products of subsequent mixing events. This is not only important for geochemical patterns of intracrustal differentiation, but also a potentially important process in generating crustal-scale as well as individual pluton-scale isotopic heterogeneities.  相似文献   

13.
Petrochemical studies on acid plutonic (granite, microgranite) and volcanic (rhyolite, trachyte) rocks occurring in the Siner area of the Siwana Ring Complex, Malani Igneous Suite have been carried out. These rocks are characterized by high concentrations of SiO2, Na2O, K2O, Zr, Nb, Y and REE (except Eu) but low in MgO, Fe2O3(t), CaO, Cr, Ni, Sr; indicating their A-type affinity. Field studies in conjunction with the geochemical characteristic indicate that the magmatism in the Siner area is generally represented by peralkaline suite of rocks which are formed due to rift tectonics. It is also suggested that these acidic rocks could have been derived by low degree partial melting of crustal material. Characteristics of certain pathfinder elements such as Rb, Ba, Sr, K, Zr, Nb, REE and the ratios of K/Rb, Zr/Rb, Ba/Rb along with the multi elemental primitive mantle normalized spidergrams suggest that the Siner peralkaline granites and microgranites have the potential for rare metal and rare earth mineralizations.  相似文献   

14.
By the example of the Orlovka massif of Li-F granites in Eastern Transbaikalia, the major- and trace-element (Li, Be, B, Ta, Nb, W, REE, Y, Zr, and Hf) compositions of the parental melt and the character of its variations during the formation of the differentiated rock series were quantitatively estimated for the first time on the basis of electron and ion microprobe analysis and Raman spectroscopy of rehomogenized glasses of melt inclusions in quartz. It was shown that the composition of the Orlovka melt corresponded to a strongly evolved alumina-saturated granitoid magma (A/CNK = 1.12–1.55) rich in normative albite, poor in normative quartz, and similar to ongonite melts. This magma was strongly enriched in water (up to 9.9 ± 1.1 wt %) and fluorine (up to 2.8 wt %). Most importantly, this massif provided the first evidence for high B2O3 contents in melts (up to 2.09 wt %). The highest contents of trace elements were observed in the melt from pegmatoid bodies in the amazonite granites of the border zone: up to 5077 ppm Li, 6397 ppm Rb, 313 ppm Cs, 62 ppm Ta, 116 ppm Nb, and 62 ppm W. Compared with the daughter rock, the Orlovka melt was depleted at all stages of formation in SiO2 (by up to 6 wt %), Na2O (by up to 2.5 wt %), and, to a smaller extent, in Ti, Fe, Mg, Sr, and Ba, but was enriched in Mn, Rb, F, B, and H2O.  相似文献   

15.
The Kejie pluton is located in the north of the Changning-Menglian suture zone. The rock types are mainly biotite-granite. Zircon LA-ICP-MS U-Pb dating indicates that the Kejie pluton emplaced at about 80–77 Ma, Late Cretaceous. The Kejie pluton samples are characterized by high SiO2(71.68%–72.47%), K2O(4.73%–5.54%), total alkali(K2O + Na2O = 8.21%–8.53%), K2O/Na2O ratios(1.36–1.94) and low P2O5(0.13%–0.17%), with A/CNK of 1.025–1.055; enriched in U, Th, and K, depleted in Ba, Nb, Sr, Ti, P and Eu. They are highly fractionated, slightly peraluminous I-type granite. The two samples of the Kejie pluton give a large variation of εHf(t) values(-5.04 to 1.96) and Hf isotope crustal model ages of 1.16–1.5 Ga. Zircon Hf isotopes and zircon saturation temperatures of whole-rock(801°C–823°C) show that the mantle-derived materials maybe have played a vital role in the generation of the Kejie pluton. The Kejie pluton was most likely generated in a setting associated with the eastward subduction of the neo-Tethys ocean, where intrusion of mantle wedge basaltic magmas in the crust caused the anatexis of the latter, forming hybrid melts, which subsequently experienced high-degree fractional crystallization.  相似文献   

16.
《International Geology Review》2012,54(11):1296-1308
Geochronological, geochemical, and whole-rock Sr–Nd isotopic analyses were performed on a suite of Palaeozoic nepheline syenites from Zijinshan to characterize their ages and petrogenesis. Laser ablation inductively coupled plasma-mass spectrometry U–Pb zircon analyses yield consistent ages of 525.7 ± 2.8 million years for a sample (HYK01). These intrusive rocks belong to the foid syenite magma series in terms of K2O?+?Na2O contents (14.3–15.2 wt.%) and to the shoshonitic series based on their high K2O contents (5.42–5.61 wt.%). The nepheline syenites are further characterized by high light rare earth element contents [(La/Yb) N ?=?29.1–36.1]; show modest negative Eu anomalies (δEu?=?0.5–0.6) and positive anomalies in Rb, Th, U, Pb, Zr, and Hf; are depleted in Ba and high field strength elements (P and Ti). In addition, all the nepheline syenites in this study display relatively low radiogenic Sr (87Sr/86Sr) i (0.7042–0.7043) and positive ?Nd (t) (0.7–0.8). These results suggest that the nepheline syenites were derived from depleted continental crust. The parent magmas likely experienced fractional crystallization of plagioclase, Ti-bearing oxides (e.g. rutile, ilmenite, and titanite), apatite, and zircon during ascent, with negligible crustal contamination before final emplacement at a high crustal level.  相似文献   

17.
Mineralogy,geochemistry and petrogenesis of Kurile island-arc basalts   总被引：1，自引：0，他引：1  
Whole-rock (major- and trace-element) and mineral chemical data are presented for basaltic rocks from the main evolutionary stages of the Kurile island arc, NW Pacific. An outer, inactive arc contains a Cretaceous-Lower Tertiary sequence of tholeiitic, calcalkaline and shoshonitic basalts. The main arc (Miocene-Quaternary) is dominated by weakly tholeiitic, with lesser, alkalic basalts. The mineralogy of Kuriles basalts is characterised by An-rich plagioclases, a continuous transition from chromites to titanomagnetites, pyroxenes with low Fe3+ contents and without strong Fe-enrichment, abundance of groundmass pigeonites and the absence of amphiboles. There is an increase in K2O contents both along-arc (northwards) and towards the reararc side. The basalts show an exceptionally wide but continuous range of K2O contents (0.1–4.7%) which correlate with other LIL element contents. Tholeiitic basalts with low LIL element contents, La/Yb and Th/U, but high K/ Rb, P2O5/La and Zr/Nb were derived from depleted, lherzolitic mantle which had suffered fluid metasomatism by K, Rb, Cs, Sr, Ba, Pb and H2O only. Alkali basalts are also thought to be derived from depleted mantle but melt metasomatism involved addition of all LIL elements to a garnet lherzolite mantle. The Kuriles basalts and their mantle sources range continuously between these two end-member compositions. The metasomatic fluids/melts were probably released by early dehydration and later melting within subducted oceanic lithosphere though the process is not adequately constrained.  相似文献   

18.
The Ancient Gneiss Complex (AGC) of Swaziland, an Archean gray gneiss complex, lies southeast and south of the Barberton greenstone belt and includes the most structurally complex and highly metamorphosed portions of the eastern Kaapvaal craton. The AGC is not precisely dated but apparently is older than 3.4 Ga.The AGC consists of three major units: (a) a bimodal suite of closely interlayered siliceous, low-K gneisses and metabasalt; (b) homogeneous tonalite gneiss; and (c) interlayered siliceous microcline gneiss, metabasalt, and minor metasedimentary rocks — termed the metamorphite suite. A geologically younger gabbro-diorite-tonalite-trondhjemite suite, the Granodiorite Suite, is spatially associated with the AGC and intrusive into it.The bimodal suite consists largely of two types of low-K siliceous gneiss: one has SiO2 < 75%, Al2O3 > 14%, low Rb/Sr ratios, and depleted heavy rare earth elements (REE's); the other has SiO2 > 75%, Al2O3 < 13%, high Rb/Sr ratios, and relatively abundant REE's except for negative Eu anomalies. The interlayered metabasalt ranges from komatiitic to tholeiitic compositions. Lenses of quartz monzonitic gneiss of K2O/Na2O close to 1 form a minor part of the bimodal suite. Tonalitic to trondhjemitic migmatite locally is abundant and has major-element abundances similar to those of non-migmatitic varieties.The siliceous gneisses of the metamorphic suite show low Al2O, K2O/Na2O ratios of about 1, high Rb/Sr ratios, moderate REE abundances and negative Eu anomalies.K/Rb ratios of siliceous gneisses of the bimodal suite are very low (～130); of the tonalitic gneiss, low (～225); of the siliceous gneiss of the metamorphite suite, moderate (～300); and of the Granodiorite Suite, high (～400).Rocks of the AGC differ geochemically in several ways from the siliceous volcanic and hypabyssal rocks of the Upper Onverwacht Group and from the diapirs of tonalite and trondhjemite that intrude the Swaziland Group.  相似文献   

19.
Partitioning of Rb, Sr and Ba between alkali feldspar and a synthetic granitic melt has been determined at 8 kb and 720 to 780°C for a single quaternary granite composition. The results suggest that Henry's law is obeyed by Rb up to ~0.8 wt.% Rb2O in both the liquid and in the alkali feldspar. The measured D values for Rb range from 0.77 to 1.1. For Ba, Henry's Law is obeyed up to ~0.6 wt.% BaO in the liquid and ~5 wt.% BaO in the alkali feldspar. D values for Ba range from 6.4 to 14. For Sr there is only a crude relationship between concentration in the liquid and concentration in the alkali feldspar at concentrations greater than ~0.6 wt.% SrO in the liquid and ~0.4 wt.% SrO in the alkali feldspar. D values for Sr range from 1.2 to 5.0. Partitioning of Sr is apparently sensitive to the concentration of Ba in the system and this partly explains the failure of Sr to obey Henry's Law.Linear least-squares fits to the partitioning data as a function of temperature suggest inverse correlation between temperature and D values. Rb shows only a slight temperature effect whereas Ba and Sr appear to be rather strongly affected by temperature, but the temperature range examined here is small compared to the scatter in the data making these trends relatively uncertain. Other factors that appear to affect partitioning, especially of Sr, are growth rate, development of sector zoning and Or content of the alkali feldspar. These factors severely limit the use of partitioning of these elements in alkali feldspar as geothermometers.The technique for measuring growth rates utilized here combined with measurement of trace element depletion in diffusion boundary layers adjacent to the alkali feldspar crystals makes it possible to estimate diffusivities for Ba and Sr. These estimates suggest a difference of 2 orders of magnitude between diffusivities for Ba and Sr in a vapor-saturated melt and those measured by HOFMANN and MAGARITZ (1976) for a dry obsidian glass.  相似文献   

20.
余海军  李文昌 《岩石学报》2016,32(8):2265-2280
本文首次在格咱岛弧休瓦促Mo-W矿区识别出印支晚期似斑状黑云母花岗岩,并确定其结晶年龄为200.93±0.65Ma,同时获得燕山晚期二长花岗岩结晶年龄83.57±0.32Ma;即首次在休瓦促Mo-W矿区内厘定出印支晚期和燕山晚期两期花岗岩浆叠加活动,而Mo-W成矿作用与燕山晚期二长花岗岩具有成因关系。岩石地球化学显示燕山晚期二长花岗岩具有较高的SiO_2和全碱含量及较低的Fe、Mg、Ca和P含量,呈准铝质-弱过铝质;富集Rb、Th、U、Nb、Zr和轻稀土元素,亏损Ba、Sr、P、Eu,具有高分异I型花岗岩特征;其形成于与拉萨-羌塘板块碰撞相关的陆内伸展环境,主要来自中-基性下地壳物质的部分熔融,为Mo-W成矿作用提供了重要的物质基础。相对于二长花岗岩,印支晚期似斑状黑云母花岗岩具有较低的SiO_2、Na_2O+K_2O含量和A/CNK比值,较高的Mg、Ca和P含量;富集Th、U、Rb和轻稀土元素,强烈亏损Nb、Ta、Zr、Hf等高场强元素,为准铝质高钾钙碱性具有岛弧岩浆性质的花岗岩,可能形成于甘孜-理塘洋壳俯冲作用结束后,松潘-甘孜地块和义敦岛弧碰撞后伸展环境,为俯冲期改造后形成的下地壳部分熔融的产物。  相似文献   

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