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新疆延东斑岩铜矿床火山机构、容矿岩石及热液蚀变 总被引：5，自引：1，他引：4
延东斑岩铜矿床位于新疆东天山晚古生代大南湖岛弧中。延东矿区出露地层是石炭纪企鹅山组火山-沉积岩,我们研究提出延东矿区出露的火山-沉积岩以及浅成侵入岩为石炭纪火山喷发-岩浆侵入产物,并将其划分成两个旋回五个岩相:第一旋回包括溢流相(玄武岩和安山岩)、爆发相(集块角砾熔岩)和爆发-沉积相(凝灰岩);第二旋回包括次火山相(闪长玢岩和闪长岩)和浅成侵入相(斜长花岗斑岩)。容矿岩石是次火山相的闪长玢岩和闪长岩以及浅成侵入相的斜长花岗斑岩。闪长玢岩发育中性斑岩蚀变系统,包括内部的绢云母-绿泥石蚀变带和绿泥石-绢云母蚀变带和外围的青磐岩化带,其中绢云母-绿泥石蚀变带控制本区部分富矿体的形成和分布;斜长花岗斑岩发育酸性斑岩蚀变系统,从中心向外依次为黄铁绢英岩化带、强绢云母化带和弱绢云母化带,黄铁绢英岩化带控制本区部分富矿体的形成和分布。这两个蚀变系统以钾硅酸盐化蚀变不发育和绢云母化广泛发育为特点。 相似文献
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普朗斑岩铜矿床是近年来发现的一个重要印支期铜矿床.含矿岩体为普朗复式斑岩体,由全岩铜矿化的石英二长斑岩、石英闪长玢岩及花岗闪长斑岩组成,其中矿化较好者主要与石英二长斑岩关系密切.矿区蚀变矿物有伊利石、镁绿泥石、多水高岭石、硬石膏、蒙脱石、黑云母、铁镁绿泥石、白云母、阳起石、金云母、方解石等,蚀变类型主要有钾长石化、黑云母化、钠长石化、硅化、绢云母化、钠黝帘石化、泥化.并且由中心向外依次为硅化核—硅化钾化带—绢英岩化带—青磐岩化带—角岩化带的面型蚀变特征.其中硅化钾化、绢英岩化蚀变带与铜矿关系密切. 相似文献
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春都斑岩铜矿床地处著名的印支期中甸-义敦岛弧成矿带南端。矿区出露闪长玢岩-花岗闪长斑岩复式岩体,成矿岩体为印支晚期的花岗闪长斑岩。围绕成矿岩体,围岩蚀变强烈,蚀变分带明显,由中心向外,依次出现硅化钾化带→绢英岩化带→硅化带→硅化黑云母化带→青磐岩化带→绢云母化及泥化带。区内蚀变与矿化关系密切,蚀变类型决定矿化程度,蚀变... 相似文献
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短波红外光谱技术在斑岩-高硫化型浅成低温热液矿床中的应用——以西藏铁格隆南超大型铜(金)矿床为例 总被引：1，自引：0，他引：1
铁格隆南铜(金)矿是西藏首例超大型斑岩-高硫化型浅成低温热液矿床.准确划分该矿床的蚀变分带对于后续的找矿勘探具有重要意义.本文主要运用短波红外光谱分析技术对西藏铁格隆南矿床进行蚀变矿物信息提取,同时利用X射线衍射辅助矿物识别;并结合岩相学和电子探针分析,对主要蚀变矿物绢云母的光谱特征进行系统梳理,构建铁格隆南矿区蚀变分带模型,探讨其勘查指示意义.结果表明:短波红外光谱清晰识别出高岭石、明矾石、地开石、叶腊石、绢云母、石膏、水铝石、蒙脱石8种蚀变矿物.根据蚀变矿物组合空间分布特征,从斑岩中心向外,可划分出钾硅酸盐化、绢英岩化、青磐岩化蚀变,在中浅部被高级泥化蚀变广泛叠加.矿区广泛产出绢云母,其主吸收谷波长介于2196～2215 nm(平均值为2206.6 nm)之间,且深部钾硅酸盐化带与绢英岩化带中的绢云母主吸收谷波长差异明显,钾硅酸盐化带中波长可大于2210 nm,可能是绢英岩化蚀变对钾硅酸盐化蚀变叠加改造的结果,绢英岩化带则集中于2206～2208 nm区间.绢云母1400 nm吸收峰波长(Pos1400值)和绢云母Al-OH的吸收深度(Dep2200值)与铜矿化强度呈现良好的耦合关系,可作为后续斑岩-浅成低温热液矿床勘查评价的重要指示标志.绢云母族矿物Al-OH吸收峰(Pos2200值)较小(＜2203 nm)且结晶度指数值越大(＞5.5)的区域揭示铁格隆南矿床的热液成矿中心主要位于ZK2404的深部. 相似文献
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玉峰金矿位于中亚造山带东天山东缘,是近年来新发现的含银高品位金矿床。该矿床目前已探明6个金矿体,均赋存在石英斑岩中。矿区热液蚀变作用发育,与成矿关系最密切的为黄铁绢英岩化和硅化,显示明显的蚀变分带:以石英硫化物脉为中心,黄铁绢英岩化带在其两侧大致对称分布。本文选取矿体上盘和下盘的石英斑岩、黄铁绢英岩进行了全岩的主、微量元素及成矿元素测试,并对其中的长石和绢云母进行电子探针成分分析。测试结果表明,黄铁绢英岩中的Au含量较蚀变前呈指数级增长,Ag、Cu、As等成矿元素大量增加,CaO、Na_2O、P_2O_5、P_2O_5、Sr、Pb、Th、U、Sb等元素显著迁出,而SiO_2、Al_2O_3、TiO_2含量和稀土元素含量变化较小,表现稳定。热液蚀变过程中,石英斑岩中71%～76%的正长石发生绢云母化,导致K_2O大量迁出;而钠长石几乎全部蚀变为绢云母,造成Na_2O大量迁出。热液流体的贡献使得蚀变岩中MgO、Fe_2O_3~T含量成倍增加,并主要富集在绢云母和/或黄铁矿晶格中。综合分析认为,绢英岩化蚀变带,Au、Cu、As和Bi等元素的综合化探异常,低电阻率、高激化率的地球物理特征可以作为玉峰矿区深部和外围找矿的标志。研究区内的石炭纪石英斑岩带,尤其是在构造叠加部位,热液活动使其更有利于矿化富集,是找矿勘探的有利部位。 相似文献
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安徽铜陵桂花冲斑岩铜矿围岩蚀变与矿化作用 总被引：1，自引：0，他引：1
桂花冲铜矿为安徽铜陵地区新发现的斑岩型铜矿,斑岩体为准铝质高钾钙碱性的花岗闪长斑岩。围岩蚀变与矿化作用是斑岩型矿床成矿过程研究的一项重要内容,对蚀变带岩石开展元素地球化学成分的迁移研究,是分析热液交代蚀变过程的基础。桂花冲铜矿区内围岩蚀变作用比较强烈,蚀变类型主要有钾化、绢云母化、硅化、绿泥石化和碳酸盐化等。蚀变分带比较明显,由内向外依次为钾化带、绢英岩化带和青磐岩化带,矿体主要产于绢英岩化带内。矿化蚀变自早至晚划分为钾长石、石英-绢云母、石英多金属硫化物和碳酸盐4个阶段。蚀变带物质组分迁移结果表明,在蚀变过程中,岩石的主量元素除TiO2、MnO、MgO外,其他元素迁移量发生了明显改变;微量元素除Sr和Cu外,迁移量变化较小,稀土元素在矿化强的部位亏损,在矿化弱的地带富集。岩体及蚀变带岩石稀土元素球粒陨石标准化配分模式一致,说明岩体与蚀变岩石经历了相同来源流体的交代蚀变,是岩浆流体连续作用的结果。 相似文献
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玉海铜矿位于东天山大南湖-头苏泉岛弧带的东段,是新疆有色地勘局704队近年来发现的一中型铜矿床,但人们对其蚀变和矿化分布特点、矿床成因类型依然知之甚少.基于详细的矿床地质、黑云母和绢云母Ar-Ar同位素定年及短波红外光谱（SWIR）研究,结果表明矿区蚀变主要有黑云母-磁铁矿化、绢英岩化及绿泥石化.其中,黑云母-磁铁矿化在矿区石英闪长岩中均有分布;绢英岩化出现在石英闪长岩中,呈带状分布;绿泥石化在石英闪长岩中均有分布,但在黑云母-磁铁矿化与绢英岩化接触部位,绿泥石化最强.黄铜矿化主要以黄铜矿-黄铁矿-磁铁矿、绿帘石-黄铜矿组合的形式出现,前者与黑云母-磁铁矿化关系密切,后者与绢英岩化关系密切.黑云母及绢云母40Ar/39Ar定年得到的年龄为324~314 Ma,与矿区出露的花岗岩年龄（325.4±2.5 Ma）在误差范围内相似,但地质条件表明矿区黑云母及绢云母Ar-Ar体系均可能被后期岩浆作用重置,结合前人研究成果,玉海铜矿化可能形成于360~350 Ma.此外,矿区绿泥石Fe-OH特征峰位值（Pos2250）的高值（>2 253 nm）主要分布在绢英岩化带及其附近,且与矿体位置相近,可作为玉海矿区找矿勘查的标志. 相似文献
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新疆土屋斑岩铜矿床火山-侵入杂岩体、 成矿岩石及其蚀变 总被引：3，自引：1，他引：2
土屋斑岩铜矿床位于新疆东天山晚古生代大南湖-头苏泉岛弧中.矿区出露地层为石炭系企鹅山群火山-沉积岩.文章提出矿区出露的火山-沉积岩以及浅成侵入岩为一火山-侵入杂岩体,发育2个旋回4个岩相:第一旋回包括溢流相玄武岩和安山岩、爆发相集块角砾熔岩和爆发-沉积相凝灰岩;第二旋回包括次火山相闪长玢岩和玄武玢岩.斜长花岗斑岩侵入到火山机构断裂系中.矿体赋存于斜长花岗斑岩和闪长玢岩中.斜长花岗斑岩为成矿斑岩,次火山岩相闪长玢岩为容矿岩石,火山岩为围岩.土屋斑岩铜矿床可分为前成矿期和主成矿期.前成矿期形成于火山活动的晚期,发育青磐岩化;主成矿期形成于斜长花岗斑岩侵位时期,发育钾硅酸盐蚀变、绿泥石-绢云母蚀变和黄铁绢英岩化蚀变及与之有关的矿化,形成了土屋斑岩型矿化的主体.矿化阶段包括钾硅酸盐阶段、绿泥石-绢云母阶段和黄铁绢英岩化阶段等. 相似文献
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伴随深部地质过程的地幔流体作用是引发地壳中成矿作用的重要物质源和动力源。由于地幔流体的超深源性及由此决定其性质和演化的复杂性,使人们很难具体捕捉其实际存在,或者多数情况下很难准确界定。通过岩相学、岩石化学、电子探针和扫描电镜及能谱分析的综合研究发现,地幔流体活动的现实微观踪迹和存在方式可以表现为富铁熔浆包体和富铁微晶玻璃,二者在透射偏光显微镜下无光性,呈黑色不透明状;反射偏光显微镜下不反光,但在电子显微镜下呈显微晶质结构,显示微晶金属和非金属矿物之间呈熔离交生,超微晶矿物组成以硅酸盐和石英为主,尤其是经过成分配比换算,得到碳硅石,含铬自然铁、钛铁矿、磷灰石和含钛镜铁矿等地幔标型矿物,反映了地幔流体的熔浆性质。捕捉和揭示深部地质过程中地幔流体作用的现实微观踪迹,对于深入分析和认识地壳地质作用的机制和成矿效应具有重要理论和现实意义。 相似文献
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B.L. Sidwell L.E. McKinney M.F. Bozeman P.C. Egbujor G.R. Eaton S.S. Eaton D.A. Netzel 《Geochimica et cosmochimica acta》1979,43(8):1337-1342
Electron paramagnetic resonance (EPR) reveals the presence of free radicals in raw shale, shale oil, and spent shale. Thirty-four samples of raw shale, and the spent shale and shale oil produced in the Fischer assay of these raw shale samples were studied. There is a significant correlation between the gallons per ton oil yield as estimated by Fischer assay and the spin density in the raw oil shale. However, the scatter in the data (due to uncertainties in sample preparation, Fischer assay results, and estimation of spins per gram of sample) limits the analytical utility of this finding. Sample preparation techniques affect the EPR signal. 相似文献
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Crystallographically orientated samples of synthetic optical-grade colourless quartz with high chemical purity and low dislocation density together with synthetic gem-grade amethyst with high Fe-concentration and ca. 250 H/106 Si (“dry”) or 600 H/106 Si (“wet”) and with very high dislocation densities were irradiated using TEM. Samples of cuts perpendicular (<c>-cuts) and parallel (<X>-cuts) to the c-axis, that were as-grown or pretreated for 5 days at 820 K on air or under p(H2O)=108 Pa were prepared. Characterization methods used include AAS, FTIR, Raman-spectroscopy, X-ray-topography, REM, TEM in SAED and bright-field mode and polarized light microscopy. Radiolysis was carried out in TEM from 10 to 300 K with 100 kV and from 70–850 K (low-high-transition temperature of quartz) with 200 kV. Irradiation damage was investigated by decay of Kikuchi-lines or of Bragg reflections in SAED and in bright-field mode by development of strain contrast centres and of noncrystalline volume areas. Special preparates where the irradiation damage was of microscopic dimensions were investigated using Raman-spectroscopy. Radiolysis of quartz is able to proceed at 10 K with measurable velocity. The required electron dose for a standardized irradiation damage decreases with increasing temperature. At ca. 500 K it goes through a minimum and then increases steadily up to ca. 700 K. From there the increase is steep until ca. 820 K where it culminates sharply, showing strong fluctuations until 850 K. The <X>-cuts in the as-grown state show significantly higher irradiation damage sensitivity than <E1>-cuts. Dry or hydrothermal preheating increases the overall sensitivity of irradiation damage and levels out the orientation differences. The high Fe-concentrations in amethyst in comparison with very pure quartz have no detectable influence on the damage sensitivity. This is also true for different water concentrations independently from the ratio of silanole-group to molecular water. Sample thinning by ion etching with different gun currents produces differences in irradiation sensitivity. Thinning by crushing produces samples with sensitivities comparable with ion-etching at low gun current. 相似文献
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Kevin E. Burdette William J. Rink David J. Mallinson Guy H. Means Peter R. Parham 《Quaternary Research》2013,79(1):66-74
For the first time, electron spin resonance optical dating (ESROD) has been conducted on littorally transported and aeolian siliciclastic sediments in Florida. ESROD utilizes light-sensitive radiation-sensitive defects at silicon sites that have been replaced by aluminum and titanium atoms to give rise to a time-dependant signal. These defects saturate at higher levels of radiation dose, compared to optically stimulated luminescence, and therefore extend the optical dating range back into the millions of years. Our results show that the Trail Ridge Sequence is a multi-depositional unit that began deposition around 2.2 Ma and continued until 6 ka. The Osceola Cape, of the Effingham Sequence, was deposited around 1.5 Ma, and the Chatham Sequence was a multi-depositional terrace with at least three events preserved. 相似文献
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Electron spin resonance of auriferous and barren quartz at beaconsfield, Northern Tasmania 总被引：1，自引：0，他引：1
The intensity of ESR spectra of powdered quartz from auriferous veins at Beaconfield is greater that the intensity of the spectra from barren vein quartz at the same locality. Lattice impurities are presumed to be the cause of the electron paramagnetism of the mineralised quartz species. The method can be used for the characterisation of different types of quartz and may provide a tool useful in exploration geochemistry. 相似文献
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独居石电子探针定年及其在新疆东天山变质作用研究中的应用 总被引：11，自引：1，他引：10
以化学法独居石电子探针定年的原理以及前人改良过的年龄计算公式为基础,利用全微分和最大误差原理,确定了年龄误差计算新方法。并用Visual C语言在Windows平台下编制出了计算年龄和年龄误差的计算机程序。运用此程序对前人公开发表的分析资料和计算的年龄以及年龄误差数据进行了重新计算,验证了给出的误差公式的可靠性。同时,利用JXA—8100电子探针仪对新疆东天山变质沉积岩的两个样品(KM2127—5,DK2107—2)中的独居石进行了电子探针微区U—Th—Pb成分分析。结果表明,样品DK2107—2记录了两期变质作用,峰期年龄分别是341．0±3．9Ma和255．2±3．3Ma,其中最主要的变质峰期年龄为341．0±3．9Ma,该期的矿物组合为Ky+St+Bt+Pl+Q+／-Or;而255．2±3．3Ma和样品KM2127-5记录的变质峰期年龄262．3±4．4Ma为次要变质峰期年龄,该期矿物组合是Cord+Bt+Pl+Or+Q。分析结果与前人用^40Ar—^39Ar法得到的结果相吻合,表明独居石电子探针定年技术是一种可靠有效的测年方法。 相似文献
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Ca-rich and Ca-poor pyroxenes present in the Bushveld rocksof the Bethal area display well developed exsolution texturestypical of slowly cooled mafic intrusions. This gave rise topoor reproducibility in electron microprobe analyses of thesame pyroxene grain, as well as results which departed fromthe bulk composition of the original homogeneous mineral. EMMA-4was used together with the electron microprobe to establishthe composition of the constituent phases in exsolved pyroxenes.The data showed that microprobe analyses carried out with adefocused beam were equivalent to the bulk composition of thepyroxenes. Microprobe analyses obtained using a focused beamwere found to approach closely the bulk composition of pyroxenesonly when the exsolution density reached 90 lamellae per millimetre. Transmission electron microscope examination of microstructuresin ion-thinned samples of pyroxenes at 100 kV and 1000 kV showedthat the exsolution mechanism in Ca-rich and Ca-poor pyroxeneswas one of heterogeneous nucleation. Subsequent growth tookplace by means of the migration of ledges along the (100) plane.Pigeonite inversion was also shown to occur in iron-rich Ca-poorpyroxene exsolution lamellae in augite. Fractionation trends established for the Bethal pyroxenes frommicroprobe analyses indicated an overall range from Fs14En84Wo2to Fs60En31Wo9 in the Ca-poor pyroxene and Fs7En50Wo43 to Fs36En27Wo37in the Ca-rich pyroxene. Comparison of pyroxene fractionationtrends from the western, eastern and Bethal areas of the Bushveldsuggests that crystallization took place under different conditionsof pressure and temperature. 相似文献
19.
Electron spin resonance and infrared spectroscopic studies of lignite and ball clay from South Devon, and of extracts obtained from them by solvent fractionation, revealed similarities between corresponding organic components associated with both materials. All fractions exhibited a free radical resonance at g = 2.0037, which occurred with greatest intensity in the humic acids. Additional ESR features due to Fe3+, Mn2+ and VO2+ complexes were observed. Ferric ions give rise to resonances at g = 4.2 which have not been previously reported in the case of natural carbonaceous materials. It is shown that the paramagnetic species associated with the ball clay and lignite extracts do not significantly contribute to the observed ESR spectra of kaolinites, the latter being attributable to substituted Fe3+ ions and defect centres within the kaolinite lattice. 相似文献
20.
在吉林陨石熔壳的形态和组构特征的研究过程中,偶尔在吉林江密蜂地区采集到的一块陨石中发现了一种黑色的细脉。这种黑色细脉很象陨石体内经常可以见到的那种冲击玻璃。但通过双目镜下的观察、扫描电子显微镜和电子探针的形态和组构 相似文献