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1.
Eclogite facies metamorphic rocks have been discovered from the Bizan area of eastern Shikoku, Sambagawa metamorphic belt. The eclogitic jadeite–garnet glaucophane schists occur as lenticular or sheet‐like bodies in the pelitic schist matrix, with the peak mineral assemblage of garnet + glaucophane + jadeite + phengite + quartz. The jadeitic clinopyroxene (XJd 0.46–0.75) is found exclusively as inclusions in porphyroblastic garnet. The eclogite metamorphism is characterized by prograde development from epidote–blueschist to eclogite facies. Metamorphic P–T conditions estimated using pseudosection modelling are 580–600 °C and 18–20 kbar for eclogite facies. Compared with common mafic eclogites, the jadeite–garnet glaucophane schists have low CaO (4.4–4.5 wt%) and MgO (2.1–2.3 wt%) bulk‐rock compositions. The P–T– pseudosections show that low XCa bulk‐rock compositions favour the appearance of jadeite instead of omphacite under eclogite facies conditions. This is a unique example of low XCa bulk‐rock composition triggered to form jadeite at eclogite facies conditions. Two significant types of eclogitic metamorphism have been distinguished in the Sambagawa metamorphic belt, that is, a low‐T type and subsequent high‐T type eclogitic metamorphic events. The jadeite–garnet glaucophane schists experienced low‐T type eclogite facies metamorphism, and the P–T path is similar to lawsonite‐bearing eclogites recently reported from the Kotsu area in eastern Shikoku. During subduction of the oceanic plate (Izanagi plate), the hangingwall cooled gradually, and the geothermal gradient along the subduction zone progressively decreased and formed low‐T type eclogitic metamorphic rocks. A subsequent warm subduction event associated with an approaching spreading ridge caused the high‐T type eclogitic metamorphism within a single subduction zone.  相似文献   

2.
Pseudosections calculated with thermocalc predict that lawsonite‐bearing assemblages, including lawsonite eclogite, will be common for subducted oceanic crust that experiences cool, fluid‐saturated conditions. For glaucophane–lawsonite eclogite facies conditions (500–600 °C and 18–28 kbar), MORB compositions are predicted in the NCKMnFMASHO system to contain glaucophane, garnet, omphacite, lawsonite, phengite and quartz, with chlorite at lower temperature and talc at higher temperature. In these assemblages, the pyrope content in garnet is mostly controlled by variations in temperature, and grossular content is strongly controlled by pressure. The silica content in phengite increases linearly with pressure. As the P–T conditions for these given isopleths are only subtly affected by common variations in bulk‐rock compositions, the P–T pseudosections potentially present a robust geothermobarometric method for natural glaucophane‐bearing eclogites. Thermobarometric results recovered both by isopleth and conventional approaches indicate that most natural glaucophane–lawsonite eclogites (Type‐L) and glaucophane–epidote eclogites (Type‐E) record similar peak P–T conditions within the lawsonite stability field. Decompression from conditions appropriate for lawsonite stability should result in epidote‐bearing assemblages through dehydration reactions controlled by lawsonite + omphacite = glaucophane + epidote + H2O. Lawsonite and omphacite breakdown will be accompanied by the release of a large amount of bound fluid, such that eclogite assemblages are variably recrystallized to glaucophane‐rich blueschist. Calculated pseudosections indicate that eclogite assemblages form most readily in Ca‐rich rocks and blueschist assemblages most readily in Ca‐poor rocks. This distinction in bulk‐rock composition can account for the co‐existence of low‐T eclogite and blueschist in high‐pressure terranes.  相似文献   

3.
An undated high-pressure low-temperature tectonic mélange in the Elekda area (central Pontides, N Turkey) comprises blocks of MORB-derived lawsonite eclogite within a sheared serpentinite matrix. In their outer shells, some of the eclogite blocks contain large (up to 6 cm) tourmaline crystals. Prograde inclusions in poikiloblastic garnet from a well-preserved eclogite block are lawsonite, epidote/clinozoisite, omphacite, rutile, glaucophane, chlorite, Ba-bearing phengite, minor actinolite, winchite and quartz. In addition, glaucophane, lawsonite and rutile occur as inclusions in omphacite. These inclusion assemblages document the transition from a garnet-lawsonite-epidote-bearing blueschist to a lawsonite eclogite with the peak assemblage garnet + omphacite I + lawsonite + rutile. Peak metamorphic conditions are not well-constrained but are estimated approximately 400–430°C and >1.35 GPa, based on Fe–Mg exchange between garnet and omphacite and the coexistence of lawsonite + omphacite + rutile. During exhumation of the eclogite–serpentinite mélange in the hanging wall of a subduction system, infiltration of B-rich aqueous fluids into the rims of eclogite blocks caused retrogressive formation of abundant chlorite, titanite and albite, followed by growth of tourmaline at the expense of chlorite. At the same time, omphacite I (XJd=0.24–0.44) became unstable and partially replaced by omphacite II characterized by higher XJd (0.35–0.48), suggesting a relatively low silica activity in the infiltrating fluid. Apart from Fe-rich rims developed at the contact to chlorite, tourmaline crystals are nearly homogeneous. Their compositions correspond to Na-rich dravite, perhaps with a small amount of excess (tetrahedral) boron (~5.90 Si and 3.10 B cations per 31 anions). 11 B values range from –2.2 to +1.7. The infiltrating fluids were most probably derived from subducting altered oceanic crust and sediments.  相似文献   

4.
Sodic metapelites with jadeite, chloritoid, glaucophane and lawsonite form a coherent regional metamorphic sequence, several tens of square kilometres in size, and over a kilometre thick, in the Orhaneli region of northwest Turkey. The low‐variance mineral assemblage in the sodic metapelites is quartz + phengite + jadeite + glaucophane + chloritoid + lawsonite. The associated metabasites are characterized by sodic amphibole + lawsonite ± garnet paragenesis. The stable coexistence of jadeite + chloritoid + glaucophane + lawsonite, not reported before, indicates metamorphic pressures of 24 ± 3 kbar and temperatures of 430 ± 30 °C for the peak blueschist facies conditions. These P–T conditions correspond to a geotherm of 5 °C km?1, one of the lowest recorded in continental crustal rocks. The low geotherm, and the known rate of convergence during the Cretaceous subduction suggest low shear stresses at the top of the downgoing continental slab.  相似文献   

5.
The Sivrihisar Massif, Turkey, is comprised of blueschist and eclogite facies metasedimentary and metabasaltic rocks. Abundant metre‐ to centimetre‐scale eclogite pods occur in blueschist facies metabasalt, marble and quartz‐rich rocks. Sivrihisar eclogite contains omphacite + garnet + phengite + rutile ± glaucophane ± quartz + lawsonite and/or epidote. Blueschists contain sodic amphibole + garnet + phengite + lawsonite and/or epidote ± omphacite ± quartz. Sivrihisar eclogite and blueschist have similar bulk composition, equivalent to NMORB, but record different P–T conditions: ～26 kbar, 500 °C (lawsonite eclogite); 18 kbar, 600 °C (epidote eclogite); 12 kbar, 380 °C (lawsonite blueschist); and 15–16 kbar, 480–500 °C (lawsonite‐epidote blueschist). Pressures for the Sivrihisar lawsonite eclogite are among the highest reported for this rock type, which is rarely exposed at the Earth's surface. The distribution and textures of lawsonite ± epidote define P–T conditions and paths. For example, in some lawsonite‐bearing rocks, epidote inclusions in garnet and partial replacement of matrix epidote by lawsonite suggest an anticlockwise P–T path. Other rocks contain no epidote as inclusions or as a matrix phase, and were metamorphosed entirely within the lawsonite stability field. Results of the P–T study and mapping of the distribution of blueschists and eclogites in the massif suggest that rocks recording different maximum P–T conditions were tectonically juxtaposed as kilometre‐scale slices and associated high‐P pods, although all shared the same exhumation path from ～9–11 kbar, 300–400 °C. Within the tectonic slices, alternating millimetre–centimetre‐scale layers of eclogite and blueschist formed together at the same P–T conditions but represent different extents of prograde reaction controlled by strain partitioning or local variations in fO2 or other chemical factors.  相似文献   

6.
In the Chinese southwestern Tianshan (U)HP belt, former lawsonite presence has been predicted for many (U)HP metamorphic eclogites, but only a very few lawsonite grains have been found so far. We discovered armoured lawsonite relicts included in quartz, which, on its part, is enclosed in porphyroblastic garnet in an epidote eclogite H711‐14 and a paragonite eclogite H711‐29. H711‐14 is mainly composed of garnet, omphacite, epidote and titanite, with minor quartz, paragonite and secondary barroisite and glaucophane. Coarse‐grained titanite occasionally occurs in millimetre‐wide veins in equilibrium with epidote and omphacite, and relict rutile is only preserved as inclusions in matrix titanite and garnet. H711‐29 shows the mineral assemblage of garnet, omphacite, glaucophane, paragonite, quartz, dolomite, rutile and minor epidote. Dolomite and rutile are commonly rimed by secondary calcite and titanite respectively. Porphyroblastic garnet in both eclogites is compositionally zoned and exhibits an inclusion‐rich core overgrown by an inclusion‐poor rim. Phase equilibria modelling predicts that garnet cores formed at the P‐peak (490–505 °C and 23–25.5 kbar) and coexisted with the lawsonite eclogite facies assemblage of omphacite + glaucophane + lawsonite + quartz. Garnet rims (550–570 °C and ~20 kbar) grew subsequently during a post‐peak epidote eclogite facies metamorphism and coexisted with omphacite + quartz ± glaucophane ± epidote ± paragonite. The results confirm the former presence of a cold subduction zone environment in the Chinese southwestern Tianshan. The P–T evolution of the eclogites is characterized by a clockwise P–T path with a heating stage during early exhumation (thermal relaxation). The preservation of lawsonite in these eclogites is attributed to isolation from the matrix by quartz and rigid garnet, which should be considered as a new type of lawsonite preservation in eclogites. The complete rutile–titanite transition in H711‐14 took place in the epidote eclogite facies stage in the presence of an extremely CO2‐poor fluid with X(CO2) [CO2/(CO2 + H2O) in the fluid] <<0.008. In contrast, the incomplete rutile–titanite transition in H711‐29 may have occurred after the epidote eclogite facies stage and the presence of dolomite reflects a higher X(CO2) (>0.01) in the coexisting fluid at the epidote eclogite facies stage.  相似文献   

7.
The spinel–quartz-bearing Al–Fe granulites from Ihouhaouene (In Ouzzal, West Hoggar) have a migmatitic appearance with quartzo-feldspathic layers intercalated with restitic layers. These granulites are characterized by a hercynitic spinel–quartz assemblage typical of high grade terranes. The stability of the spinel–quartz assemblage is attributed to an elevation of temperature (from 800 to >1100 °C) at high pressures (10–11 kbar), followed by an isothermal decompression from 9 to 5 kbar, an evolution typical of the In Ouzzal clockwise P–T path. The Al–Fe granulites’ history can be subdivided into different successive crystallisation stages. During the first stage, the spinel–quartz assemblage formed, probably following a prograde event that also produced partial melting. During a second stage, the primary spinel–garnet–sillimanite–quartz paragenesis broke-down to give rise to the secondary assemblage. The metamorphic evolution and phase relations during this stage are shown in P–T–X pseudosections calculated for the simple FMASH system. These pseudosections show that the orthopyroxene–cordierite–spinel symplectite appeared during a high temperature decompression, as a product of destabilisation of garnet in sillimanite-free microdomains with high XMg values. At the same time, the spinel–quartz association broke-down into cordierite in Fe-rich microdomains. Average pressure and temperature estimates for the orthopyroxene–spinel–garnet–cordierite–quartz association are close to the thermal peak of metamorphism (1000 ± 116 °C at 6.3 ± 0.5 kbar). With decreasing temperatures garnet–sillimanite corona developed from the breakdown of the primary spinel–quartz assemblage in the Fe-rich microdomains, whereas cordierite–spinel formed at the expense of primary sillimanite and garnet in the Mg-rich microdomains.  相似文献   

8.
The compositions of sodic pyroxenes from blueschist metabasites in Northwest Turkey were investigated by electronprobe microanalysis. These are compared with sodic pyroxenes from high-grade blueschist terrains and eclogites with special reference to the island of Syros in Greece. Pyroxenes from lawsonite zone metabasites in Northwest Turkey are chloromelanites, aegerine augites and aegerine jadeites with the acmite contents ranging from 65% down to 30%. Epidote-garnet bearing high-grade blueschist metabasites of Syros on the other hand contain omphacite with the acmite content less than 30%. All the analyzed sodic pyroxenes from eclogites and high-grade blueschists in the literature are also omphacites with low acmite contents. It is argued that the acmite content of the sodic pyroxene decreases with rising temperature of metamorphism. This is almost entirely related to the appearance of epidote as an additional ferric ion bearing phase with an increase in temperature.  相似文献   

9.
A low‐grade metamorphic “Coloured Mélange” in North Makran (SE Iran) contains lenses and a large klippe of low temperature, lawsonite‐bearing blueschists formed during the Cretaceous closure of the Tethys Ocean. The largest blueschist outcrop is a >1,000 m thick coherent unit with metagabbros overlain by interlayered metabasalts and metavolcanoclastic rocks. Blueschist metamorphism is only incipient in coarse‐grained rocks, whereas finer grained, foliated samples show thorough metamorphic recrystallization. The low‐variance blueschist peak assemblage is glaucophane, lawsonite, titanite, jadeite±phengitic mica. Investigated phase diagram sections of three blueschists with different protoliths yield peak conditions of ~300–380°C at 9–14 kbar. Magnesio‐hornblende and rutile cores indicate early amphibolite facies metamorphism at >460°C and 2–4 kbar. Later conditions at slightly higher pressures of 6–9 kbar at 350–450°C are recorded by barroisite, omphacite and rutile assemblages before entering into the blueschist facies and finally following a retrograde path through the pumpellyite–actinolite facies across the lawsonite stability field. Assuming that metamorphic pressure is lithostatic pressure, the corresponding counterclockwise P–T path is explained by burial along a warm geothermal gradient (~15°C/km) in a young subduction system, followed by exhumation along a cold gradient (~8°C/km); a specific setting that allows preservation of fresh undecomposed lawsonite in glaucophane‐bearing rocks.  相似文献   

10.
The north Qilian high‐pressure (HP)/low‐temperature (LT) metamorphic belt is composed mainly of blueschists, eclogites and greenschist facies rocks. It formed within an Early Palaeozoic accretionary wedge associated with the subduction of the oceanic crust and is considered to be one of the best preserved HP/LT metamorphic belts in China. Here we report new lawsonite‐bearing eclogites and eclogitic rocks enclosed within epidote blueschists in the North Qilian Mountains. Five samples contain unaltered lawsonite coexisting with omphacite and phengite as inclusions in garnet, indicating eclogite facies garnet growth and lawsonite pseudomorphs were observed in garnet from an additional 11 eclogites and eclogitic rocks. Peak pressure conditions estimated from lawsonite omphacite‐phengite‐garnet assemblages were 2.1–2.4 GPa at temperatures of 420–510 °C, in or near the stability field of lawsonite eclogite, and implying formation under an apparent geothermal gradient of 6–8 °C km?1, consistent with metamorphism in a cold subduction zone. SHRIMP U‐Pb dating of zircon from two lawsonite‐bearing eclogitic metabasites yields ages of 489 ± 7 Ma and 477 ± 16 Ma, respectively. CL images and mineral inclusions in zircon grains indicate that these ages reflect an eclogite facies metamorphism. An age of 502 ± 16 Ma is recorded in igneous cores of zircon grains from one lawsonite pseudomorph‐bearing eclogite, which is in agreement with the formation age of Early Ordovician for some ophiolite sequences in the North Qilian Mountains, and may be associated with a period of oceanic crust formation. The petrological and chronological data demonstrate the existence of a cold Early Palaeozoic subduction zone in the North Qilian Mountains.  相似文献   

11.
L. Millonig  A. Zeh  A. Gerdes  R. Klemd 《Lithos》2008,103(3-4):333-351
The Bulai pluton represents a calc-alkaline magmatic complex of variable deformed charnockites, enderbites and granites, and contains xenoliths of highly deformed metamorphic country rocks. Petrological investigations show that these xenoliths underwent a high-grade metamorphic overprint at peak P–T conditions of 830–860 °C/8–9 kbar followed by a pressure–temperature decrease to 750 °C/5–6 kbar. This P–T path is inferred from the application of P–T pseudosections to six rock samples of distinct bulk composition: three metapelitic garnet–biotite–sillimanite–cordierite–plagioclase–(K-feldspar)–quartz gneisses, two charnoenderbitic garnet–orthopyroxene–biotite–K-feldspar–plagioclase–quartz gneisses and an enderbitic orthopyroxene–biotite–plagioclase–quartz gneiss. The petrological data show that the metapelitic and charnoenderbitic gneisses underwent uplift, cooling and deformation before they were intruded by the Bulai Granite. This relationship is supported by geochronological results obtained by in situ LA-ICP-MS age dating. U–Pb analyses of monazite enclosed in garnet of a charnoenderbite gneiss provide evidence for a high-grade structural-metamorphic–magmatic event at 2644 ± 8 Ma. This age is significantly older than an U–Pb zircon crystallisation age of 2612 ± 7 Ma previously obtained from the surrounding, late-tectonic Bulai Granite. The new dataset indicates that parts of the Limpopo's Central Zone were affected by a Neoarchaean high-grade metamorphic overprint, which was caused by magmatic heat transfer into the lower crust in a ‘dynamic regional contact metamorphic milieu’, which perhaps took place in a magmatic arc setting.  相似文献   

12.
Medium‐temperature ultrahigh pressure (MT‐UHP) eclogites from the south Dabie orogen, as represented by samples from the Jinheqiao, Shuanghe and Bixiling areas, consist of garnet, omphacite, phengite, epidote, hornblendic amphibole, quartz/coesite and rutile with or without kyanite and talc. Garnet is mostly anhedral and unzoned, but a few porphyroblasts are weakly zoned with core–mantle increasing grossular (Xgr) and decreasing pyrope (Xpy) contents. Garnet compositions are closely correlated with the bulk compositions. For instance, the Xpy and Xgr contents are positively correlated with the bulk MgO and CaO contents. Phengite is occasionally zoned with core–rim deceasing Si content, and phengite grains as inclusions in garnet show higher Si than in the matrix, suggesting differently resetting during post‐peak stages. The maximum Si contents are mostly 3.60–3.63 p.f.u. for the three areas. Pseudosections calculated using THERMOCALC suggest that the MT‐UHP eclogites should have a peak assemblage of garnet + omphacite + lawsonite + phengite + coesite in most rocks of higher MgO content. In this assemblage, the Xpy in garnet mostly depends on bulk compositions, whereas the Xgr in garnet and the Si contents in phengite regularly increase, respectively, as temperature and as pressure rise, and thus, can provide robust thermobarometric constraints. Using the Xgr and Si isopleths in pseudosections, the peak P–T conditions were estimated to be 40 kbar/730 °C for the Jinheqiao, 41 kbar/726 °C for the Shuanghe, and 37–52 kbar and 700–830 °C for the Bixiling eclogites. Some eclogites with higher FeO are predicted to have a peak assemblage of garnet + omphacite + coesite ± phengite without lawsonite, where the garnet and phengite compositions highly depend on bulk compositions and generally cannot give available thermobarometric constraints. Decompression of the eclogites with lawsonite in the peak stage is inferred to be accompanied with cooling and involves two stages: an early‐stage decompression is dominated by lawsonite dehydration, resulting in increase in the mode of anhydrous minerals, or further eclogitization, and formation of epidote porphyroblasts and kyanite‐bearing quartz veins in eclogite. As lawsonite dehydration can facilitate evolution of assemblages under fluid‐present conditions, it is difficult to recover real peak P–T conditions for UHP eclogites with lawsonite. This may be a reason why the P–T conditions estimated for eclogites using thermobarometers are mostly lower than those estimated for the coherent ultramafic rocks, and lower than those suggested from the inclusion assemblages in zircon from marble. A late‐stage decompression is dominated by formation of hornblendic amphibole and plagioclase with fluid infiltration. The lawsonite‐absent MT‐UHP eclogites have only experienced a decompression metamorphism corresponding to the later stage and generally lack the epidote overprinting.  相似文献   

13.
Coexisting garnet blueschist and eclogite from the Chinese South Tianshan high‐pressure (HP)–ultrahigh‐pressure (UHP) belt consist of similar mineral assemblages involving garnet, omphacite, glaucophane, epidote, phengite, rutile/sphene, quartz and hornblendic amphibole with or without paragonite. Eclogite assemblages generally contain omphacite >50 vol.% and a small amount of glaucophane (<5 vol.%), whereas blueschist assemblages have glaucophane over 30 vol.% with a small amount of omphacite which is even absent in the matrix. The coexisting blueschist and eclogite show dramatic differences in the bulk‐rock compositions with higher X(CaO) [=CaO/(CaO + MgO + FeOtotal + MnO + Na2O)] (0.33–0.48) and lower A/CNK [=Al2O3/(CaO + Na2O + K2O)] (0.35–0.56) in eclogite, but with lower X(CaO) (0.09–0.30) and higher A/CNK (0.65–1.28) in garnet blueschist. Garnet in both types of rocks has similar compositions and exhibits core–rim zoning with increasing grossular and pyrope contents. Petrographic observations and phase equilibria modelling with pseudosections calculated using thermocalc in the NCKMnFMASHO system for the coexisting garnet blueschist and eclogite samples suggest that the two rock types share similar P–T evolutional histories involving a decompression with heating from the Pmax to the Tmax stage and a post‐Tmax decompression with slightly cooling stage, and similar P–T conditions at the Tmax stage. The post‐Tmax decompression is responsible for lawsonite decomposition, which results in epidote growth, glaucophane increase and omphacite decrease in the blueschist, or in an overprinting of the eclogitic assemblage by a blueschist assemblage. Calculated P–X(CaO), P–A/CNK and P–X(CO2) pseudosections indicate that blueschist assemblages are favoured in rocks with lower X(CaO) (<0.28) and higher A/CNK (>0.75) or fluid composition with higher X(CO2) (>0.15), but eclogite assemblages preferentially occur in rocks with higher X(CaO) and lower A/CNK or fluid composition with lower X(CO2). Moreover, phase modelling suggests that the coexistence of blueschist and eclogite depends substantially on P–T conditions, which would commonly occur in medium temperatures of 500–590 °C under pressures of ~17–22 kbar. The modelling results are in good accordance with the measured bulk‐rock compositions and modelled temperature results of the coexisting garnet blueschist and eclogite from the South Tianshan HP–UHP belt.  相似文献   

14.
Robust quantification of pressure (P)–temperature (T) paths for subduction-related HP/UHP metamorphic rocks is fundamental in recognizing spatial changes in both the depth of detachment from the down-going plate and the thermal evolution of convergent margin sutures in orogenic belts. Although the Chinese southwestern (SW) Tianshan is a well-known example of an accretionary metamorphic belt in which HP/UHP metabasites occur in voluminous host metasedimentary schists, information about the P–T evolution of these rocks in the eastern segment is limited, precluding a full understanding of the development of the belt as a whole. In this study at Kekesu in the eastern segment of the SW Tianshan, we use microstructural evidence and phase equilibrium modelling to quantify the peak and retrograde P–T conditions from two lawsonite-bearing micaschists and an enclosed garnet–epidote blueschist; for two of the samples we also constrain the late prograde P–T path. In the two micaschist samples, relics of prograde lawsonite are preserved in quartz inclusions in garnet, whereas in the metabasite, polymineralic aggregates included in garnet are interpreted as pseudomorphs after lawsonite. For garnet micaschist TK21, which is mainly composed of garnet, phengite/paragonite, albite, chlorite, quartz and relict lawsonite, with accessary rutile, titanite and ilmenite, the maximum P–T conditions for the peak stage are 18.0–19.0 kbar at 480–485°C. During initial exhumation, the retrograde P–T path passed through metamorphic conditions of 15.0–17.0 kbar at 460–500°C. For garnet–glaucophane micaschist TK33, which is mainly composed of garnet, glaucophane, phengite/paragonite, albite, chlorite, quartz, relict lawsonite and minor epidote, with accessary titanite, apatite, ilmenite and zircon, the maximum P conditions for the peak stage are >24.0 kbar at 400–500°C. During exhumation, the P–T path passed through metamorphic conditions of 17.5–18.5 kbar at 485–495°C and 14.0–17.5 kbar at 460–500°C. For garnet–epidote blueschist TK37, which is mainly composed of garnet, glaucophane, epidote, phengite, chlorite, albite and quartz, with accessary titanite, apatite, ilmenite, zircon and calcite, the prograde evolution passed through metamorphic conditions of ~20.0 kbar at ~445°C to Pmax conditions of ~21.5 kbar at 450–460°C and Tmax conditions of 19.5–21.0 kbar at 490–520°C. During exhumation, the rock passed through metamorphic conditions of 17.5–19.0 kbar at 475–500°C, before recording P–T conditions of <17.5 kbar at <500°C. These results demonstrate that maximum recorded pressures for individual samples vary by as much as 6 kbar in the eastern segment of the SW Tianshan, which may suggest exhumation from different depths in the subduction channel. Furthermore, the three samples record similar P–T paths from ~17.0 to 15.0 kbar, which suggests they were juxtaposed at a similar depth along the subduction interface. We compare our new results with published information from eclogites in the same area before considering the wider implications of these data for the orogenic development of the belt as a whole.  相似文献   

15.
The Ballantrae ophiolite in southern Scotland includes a NEE–SWW-trending serpentinite mélange that contains blocks of mafic blueschist and high-pressure, granulite facies, metapyroxenite (Sm–Nd metamorphic age: 576 ± 32 and 505 ± 11 Ma). Tectonic blocks of mafic schist are less than 3 × 3 m in size, and have greenschist, blueschist or epidote amphibolite facies assemblages corresponding to the high-pressure intermediate-type metamorphic facies series.Adjacent rocks of the serpentinite mélange are hydrothermally-altered MORB-like ophiolitic basalt (prehnite–pumpellyite facies), dolerite (actinolite–oligoclase sub-facies) and gabbro (amphibolite facies), all with assemblages that are diagnostic of the low-pressure metamorphic facies series.The difference in metamorphic facies series and parageneses of minerals between the high-pressure mafic blocks and the adjacent, low-pressure ophiolitic meta-basic rocks suggests that the former were exhumed from > 25 km depth within a cold subducted slab, and were juxtaposed with the latter, the bottom of a MORB-like ophiolite in the hanging wall of a trench. An ENE–WSW-trending, 501 ± 12 Ma volcanic arc belt extends for 3 km south of the serpentinite mélange. We suggest that ridge subduction associated with a slab window created arc-related gabbro (483 ± 4 Ma) at Byne Hill and within-plate gabbro (487 ± 8 Ma) at Millenderdale. Final continental collision created the duplex structure of the Ballantrae complex that includes the HP blocks and serpentinite mélange. These relations define diapiric exhumation in the Caledonian orogen of SW Scotland.  相似文献   

16.
The North Qaidam Orogenic Belt (NQOB), lying at the northern margin of the Tibet Plateau, records two orogenic cycles: A Proterozoic cycle related to the amalgamation and breakup of the supercontinent Rodinia, and an Early Palaeozoic cycle including oceanic subduction and continental deep subduction. At present, the only information about the Proterozoic cycle is the concurrent c. 1,000–900 Ma magmatic and metamorphic events, which limited the understanding of the Proterozoic evolution of NQOB and the relationship between the Qaidam Block and other Rodinia fragments. In this study, a kyanite‐bearing eclogite was identified in Yuka terrane. It has positive‐slope chondrite‐normalized rare earth element distribution patterns, similar to present‐day N‐MORB. LA–ICP–MS zircon U–Pb dating obtained a protolith age of 1,273 Ma and an eclogite facies metamorphic age of 437 Ma, which is similar to the continental deep subduction age of the Yuka terrane. Zircon Lu–Hf analysis show that the magmatic zircon cores have high εHf(t) of 8.36–15.98 and TDM1 of 1,450–1,131 Ma (M = 1,303 ± 55 Ma, consistent with its protolith age within error), indicating a juvenile crust protolith of the eclogite. The MORB‐like whole‐rock composition and zircon U–Pb and Lu–Hf analysis indicate that the protolith of the kyanite‐bearing eclogite was a Mesoproterozoic oceanic slice. P–T pseudosection analysis shows that the kyanite‐bearing eclogite experienced four metamorphic stages: (1) a prograde stage with the assemblage garnet+omphacite+talc+lawsonite+phengite+quartz at 22.4–23.2 kbar and 585°C; (2) a peak stage with the assemblage garnet+omphacite+lawsonite+phengite+coesite at 32.5 kbar and 670°C; (3) an early retrograde stage with the assemblage garnet+omphacite+kyanite+phengite+coesite/quartz±lawsonite at 27.1–30.0 kbar and 670–690°C; and (4) a late retrograde stage with the assemblage garnet+omphacite+epidote+hornblende+phengite+quartz at <18.0 kbar. The established clockwise P–T path is similar with other continental‐type eclogites in this area. On the basis of the geochemical and geochronological data, as well as the P–T path, we suggest that the protolith of the kyanite‐bearing eclogite was emplaced in the active margin of the Qaidam Block during the assembly of Rodinia and underwent continental deep subduction in the Early Palaeozoic. We conclude that (1) the Qaidam Block participated in the assembly of the Rodinia supercontinent. It was situated at or proximal to the margin of the supercontinent and probably close to India, east Antarctica and Tarim; and (2) both Mesoproterozoic and Early Palaeozoic oceanic crust slices occur in the NQOB. Thus, special caution is needed when using the metamorphic ages of oceanic affinity eclogites without protolith ages to constrain the evolution history of the North Qaidam UHPM belt.  相似文献   

17.
The Changning–Menglian orogenic belt (CMOB) in the southeastern Tibetan Plateau, is considered as the main suture zone marking the closure of the Palaeo‐Tethys Ocean between the Indochina and Sibumasu blocks. Here, we investigate the recently discovered retrograded eclogites from this suture zone in terms of their petrological, geochemical and geochronological features, with the aim of constraining the metamorphic evolution and protolith signature. Two types of metabasites are identified: retrograded eclogites and mafic schists. The igneous precursors of the retrograded eclogites exhibit rare earth element distribution patterns and trace element abundance similar to those of ocean island basalts, and are inferred to have been derived from a basaltic seamount in an intra‐oceanic tectonic setting. In contrast, the mafic schists show geochemical affinity to arc‐related volcanics with the enrichment of Rb, Th and U, and depletion of Nb, Ta, Zr, Hf and Ti, and their protoliths possibly formed at an active continental margin tectonic setting. Retrograded eclogites are characterized by peak metamorphic mineral assemblages of garnet, omphacite, white mica, lawsonite and rutile, and underwent five‐stage metamorphic evolution, including pre‐peak prograde stage (M1) at 18–19 kbar and 400–420°C, peak lawsonite‐eclogite facies (M2) at 24–26 kbar and 520–530°C, post‐peak epidote–eclogite facies decompression stage (M3) at 13–18 kbar and 530–560°C, subsequent amphibolite facies retrogressive stage (M4) at 8–10 kbar and 530–600°C, and late greenschist facies cooling stage (M5) at 5–8 kbar and 480–490°C. Laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) U–Pb spot analyses of zircon show two distinct age groups. The magmatic zircon from both the retrograded eclogite and mafic schist yielded protolith ages of 451 ± 3 Ma, which is consistent with the ages of Early Palaeozoic ophiolitic complexes and ocean island sequences in the CMOB reported in previous studies. In contrast, metamorphic zircon from the retrograded eclogite samples yielded consistent Triassic metamorphic ages of 246 ± 2 and 245 ± 2 Ma, which can be interpreted as the timing of closure of the Palaeo‐Tethys Ocean. The compatible peak metamorphic mineral assemblages, P–T–t paths and metamorphic ages, as well as the similar protolith signatures for the eclogites in the CMOB and Longmu Co–Shuanghu suture (LCSS) suggest that the two belts formed part of a cold oceanic subduction system in the Triassic. The main suture zone of the Palaeo‐Tethyan domain extends at least 1,500 km in length from the CMOB to the LCSS in the Tibetan Plateau. The identification of lawsonite‐bearing retrograded eclogites in the CMOB provides important insights into the tectonic framework and complex geological evolution of the Palaeo‐Tethys.  相似文献   

18.
In Alpine Corsica (France), deeply subducted metabasalts are well preserved as lawsonite‐bearing eclogite (Law‐Ecl), occurrence of which is restricted to ～10 localities worldwide. The Corsican Law‐Ecl, consisting of omphacite + lawsonite + garnet + phengite + titanite, occurs as both single undeformed metabasaltic pillows surrounded by lawsonite blueschist (Law‐Bs), and carbonate‐bearing eclogitic veins. Law‐Bs are found as variably deformed metabasaltic pillows locally cross‐cut by eclogitic veins and consist of glaucophane + actinolite + lawsonite + garnet + phengite + titanite. Field evidence and microstructures reveal that both Law‐Ecl and Law‐Bs are stable at the metamorphic peak in the lawsonite‐eclogite stability field. Isochemical phase diagrams (pseudosections) calculated for representative Law‐Ecl and Law‐Bs samples indicate that both lithologies equilibrated at the same conditions of ～520 ± 20 °C and 2.3 ± 0.1 GPa. Therefore, the coexistence at the same peak metamorphic conditions of Law‐Ecl and Law‐Bs implies that different portions of deeply subducted oceanic crust may store significantly different H2O contents, depending on bulk‐rock chemical composition. In addition, thermodynamic modelling of phase equilibria indicates that the occurring progressive dehydration reactions, which are significantly depending on bulk‐rock chemical composition, strongly influence rock densification and eclogite formation in subducting slabs.  相似文献   

19.
Abstract Two blueschist belts in the North Qilian Mountains occur in Middle Cambrian and Lower Ordovician strata and strike N30–35°W for about 500 km along the Caledonian fold belt on the south-west margin of the Sino-Korean plate. The styles of metamorphism and deformation are quite different in the two belts. The Middle Cambrian to Ordovician rocks in the high-grade belt are mainly blueschists and C-type eclogites in which six phases of lower and upper crustal deformation have been recognized. The rocks contain glaucophane, phengite, epidote, clinozoisite, chlorite, garnet, stilpnomelane, piedmontite, albite, titanite and quartz. The estimated P–T conditions of eclogites are 340 ± 10°C, 8 ± 1 kbar and, of blueschist, >380°C, 6–7 kbar. The Ordovician rocks in the low-grade belt are characterized by ductile to brittle deformation in the middle to upper crust. The low-grade blueschists contain glaucophane, lawsonite, pumpellyite, aragonite, albite and chlorite. The estimated P–T conditions are 150–250°C and 4–7 kbar.
K–Ar and 39Ar/40Ar geochronology on glaucophane and phengite from the high-grade blueschist belt suggest two stages of metamorphism at 460–440 and 400–380 Ma, which may represent the times of subduction and orogeny. The subduction metamorphism of the northern low-grade blueschist belt took place approximately at the end of the Ordovician.  相似文献   

20.
Lawsonite eclogite pods ranging in size from 3 cm to 6 m occur in lawsonite blueschist and eclogite facies metasedimentary and metabasaltic rocks in the Sivrihisar Massif, Turkey. Some pods have a core of lawsonite eclogite surrounded by alternating, centimeter-scale layers of lawsonite blueschist, eclogite, and transitional eclogite–blueschist, all with similar basaltic bulk composition. These pods also contain texturally late lawsonite-rich veins and layers. Most eclogites and blueschists within the pods lack reaction textures, but some blueschists near pod margins contain texturally complex garnet as well as glaucophane rims on omphacite, suggesting retrogression of eclogite to blueschist. Phase diagrams (pseudosections) calculated for the lawsonite eclogite core of a meter-scale pod indicate that the eclogite equilibrated at ∼22–24 kbar, ∼520°C. Lawsonite eclogite and blueschist at the tectonized margin of the same pod equilibrated at similar temperatures and slightly lower pressures. The composite eclogite–blueschist pod is foliated, lineated, and folded. An earlier generation of lineated omphacite in the pod core has a different spatial orientation than the lineation at the pod margin, although electron backscattered diffraction data show that core and rim omphacite have similar lattice preferred orientation patterns. Petrologic and structural data are consistent with mechanical formation of pods by folding and dissection of eclogite layers at high-P, and localized retrogression at pod margins during initial stages of exhumation at P–T conditions >425°C, 16 kbar.  相似文献   

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