共查询到20条相似文献，搜索用时 586 毫秒
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一、对我国石油天然气工业发展历史、现状、前景的评估 1、世界天然气工业,从50年代以来迅速发展。1950年世界剩余探明储量为8.5万亿m~3,1988年初已达111.9万亿m~3。其探明储量大约每十年翻一番。据十二届世界石油大会(1987年,美国休斯敦)资料介绍,尚可寻找的储量为119万亿m~3。以目前年产约1.5～1.8万亿m~3(有人预测2020年年产可达2.0万亿m~3)计算,世界天然气储量可维持开采100年以上。从全球来看,在可望的未来,天然气仍是不可替代的重要能源和化工原料。天然气工业仍处于蓬勃发展的趋势。 相似文献
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This paper reports in situ observations on barite (0 0 1) surface dissolution behavior in 0.1–0.001 M NaCl solutions at 30 °C using atomic force microscopy (AFM). The step retreating on barite (0 0 1) surfaces changed with increasing NaCl solution concentrations. In solutions with a higher NaCl concentration (⩾0.01 M), many steps showed curved or irregular fronts during the later experimental stage, while almost all steps in solutions with a lower NaCl concentration exhibited straight or angular fronts, even during the late stage. The splitting phenomenon of the initial 〈h k 0〉 one-layer steps (7.2 Å) into two half-layer steps (3.6 Å) occurred in all NaCl solutions, while that of the initial [0 1 0] one-layer steps observed only in the 0.1 M NaCl solution. The step retreat rates increased with an increasing NaCl solution concentration. We observed triangular etch pit and deep etch pit formation in all NaCl solutions, which tended to form late in solutions with lower NaCl concentrations. The deep etch pit morphology changed with increasing NaCl solution concentrations. A hexagonal form elongated in the [0 1 0] direction was bounded by the {1 0 0}, {3 1 0}, and (0 0 1) faces in a 0.001 M NaCl solution, and a rhombic form was bounded by the {5 1 0} and (0 0 1) faces in 0.01 M and 0.1 M NaCl solutions. An intermediate form was observed in a 0.005 M NaCl solution, which was defined by {1 0 0}, a curved face tangent to the [0 1 0] direction, {3 1 0}, and (0 0 1) faces: the intermediate form appeared between the hexagonal and rhombic forms in solutions with lower and higher NaCl concentrations, respectively. The triangular etch pit and deep etch pit growth rates also increased with the NaCl solution concentration. Combining the step and face retreat rates in NaCl solutions estimated in this AFM study as well as the data on the effect of water temperature on the retreat rates reported in our earlier study, we produced two new findings. One finding is that the retreat rates increase by approximately two-fold when the NaCl solution concentration increases by one order of magnitude, and the other finding is that the retreat rate increase due to a one order of magnitude increase in the NaCl concentration corresponds to an increase of approximately 8 °C in water temperature. This correlation may help to understand and evaluate increasing dissolution kinetics induced by the different mechanisms where barite dissolution is promoted by the catalytic effect of Na+ and Cl− ions (through an increase in the NaCl solution concentration) or by an increase in the hydration of Ba2+ and SO42− (through an increase in water temperature). 相似文献
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《地学前缘(英文版)》2022,13(6):101431
Melt inclusions in kimberlitic minerals and diamonds indicate that chlorides are important constituents of mantle carbonatite melts. Besides, alkaline chlorides are important constituents of saline high-density fluids (HDFs) found in diamonds from kimberlites and placers around the world. Continuous compositional variations suggest that saline and carbonatitic HDFs could be genetically linked. However, the essence of this link remains unclear owing to the lack of data on phase relations in the chloride-carbonate systems under pressure. Here we studied subsolidus and melting phase relations in the system NaCl–CaCO3–MgCO3 at 6 GPa and 1000–1600 °C using a Kawai-type multianvil press. We found that at 1000 °C, subsolidus assemblage consists of halite, magnesite, and aragonite. At higher temperatures, the stabilization of dolomite splits the subsolidus area into two partial ternary fields: halite + magnesite + dolomite and halite + dolomite + aragonite. The minimum on the liquidus surface corresponds to the halite-dolomite-aragonite ternary eutectic, situated at 1100 °C. The eutectic melt has Ca# 89 and contains 30 wt.% NaCl (26 mol% 2NaCl). The system has two ternary peritectics: halite + dolomite = magnesite + liquid located near the ternary eutectic and magnesite + dolomite = Mg-dolomite + liquid situated between 1300 and 1400 °C. Although under dry conditions incipient melting yields carbonate-dominated melt, the addition of water facilitates the fusion of NaCl and expands the liquid field to NaCl-rich compositions with up to 70 wt.% NaCl. The obtained results favor the idea that hydrous saline melts/fluids (brines) found as inclusions in diamonds could be a lower temperature derivative of mantle carbonatite melts and disagree with the hypothesis on chloride melt generation owing to the chloride-carbonate liquid immiscibility since no such immiscibility was established. We also studied the interaction of the NaCl–CaCO3–MgCO3 system with iron metal and found that carbonate reduction produces C-bearing species (Fe0, Fe-C melt, Fe3C, Fe7C3, C0) and wüstite containing Na2O, CaO, and MgO. Besides, a carbonate chloride compound, Ca2Cl2CO3, was established among the reaction products. The interaction between NaCl-bearing carbonate melt shifts its composition toward Mg-poor and NaCl-rich. Given the above, an alternative hypothesis can be proposed, according to which the interaction of alkaline chloride-bearing carbonate melts formed in the subduction zones with the reduced mantle should be accompanied by diamond crystallization and shift the composition of the melt from carbonatitic to alkali-rich saline. 相似文献
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Kent C.Condie 《地学前缘(英文版)》2018,9(1):51-60
Many geological and geochemical changes are recorded on Earth between 3 and 2 Ga.Among the more important of these are the following:(1)increasing proportion of basalts with"arc-like"mantle sources;(2)an increasing abundance of basalts derived from enriched(EM)and depleted(DM)mantle sources;(3)onset of a Great Thermal Divergence in the mantle;(4)a decrease in degree of melting of the mantle;(5)beginning of large lateral plate motions;(6)appearance of eclogite inclusions in diamonds;(7)appearance and rapid increase in frequency of collisional orogens;(8)rapid increase in the production rate of continental crust as recorded by zircon age peaks;(9)appearance of ophiolites in the geologic record,and(10)appearance of global LIP(large igneous province)events some of which correlate with global zircon age peaks.All of these changes may be tied directly or indirectly to cooling of Earth's mantle and corresponding changes in convective style and the strength of the lithosphere,and they may record the gradual onset and propagation of plate tectonics around the planet.To further understand the changes that occurred between 3 and 2 Ga,it is necessary to compare rocks,rock associations,tectonics and geochemistry during and between zircon age peaks.Geochemistry of peak and inter-peak basalts and TTGs needs to be evaluated in terms of geodynamic models that predict the existence of an episodic thermal regime between stagnant-lid and plate tectonic regimes in early planetary evolution. 相似文献
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由国家科学基金委地球科学部主办的“秦岭造山带学术讨论会”于1989年11月在西安召开。其目的在于交流秦岭造山带地质研究的最新成果和新观点、新认识、新方法;并根据当前学科发展和国民经济建设的需要,围绕秦岭造山带岩石圈的组成、结构及其演化的中心议题,集中讨论需进一步深入研究的关键科学问题,研究内容和主攻方向,为国家自然科学基金重大项目的设立提供科学依据。 会议得到国内地学界广泛响应和热情支持,来自教学、科研和生产部门的论文摘要达298篇(选编成册268篇)。经学术讨论会的学术委员会评审,确定会议代表85人,宣讲论文52篇、展示论文33篇;而实际到会代表达121名,来自全国的68个单位,且绝大部分是多年 相似文献
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M.I. Epov V.L. Mironov P.P. Bobrov I.V. Savin A.V. Repin 《Russian Geology and Geophysics》2009,50(5):470-474
We have measured the dielectric spectra of sand and bentonite mixtures with oil and saline water (NaCl solution) in the frequency range from 50 MHz to 16 GHz at 22 °C. The measured spectra were compared with predictions in terms of the generalized refractive mixing dielectric model (GRMDM), and the respective error was estimated as a check of the model applicability to describe oil-bearing formations. The results may be useful in developing new methods of electromagnetic logging. 相似文献
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Natalie Bonneton Philippe BonnetonJean-Paul Parisot Aldo SottolichioGuillaume Detandt 《Comptes Rendus Geoscience》2012,344(10):508-515
In this article, we present a study on the tidal bore dynamics based on the analysis of the database acquired in 2011 during two simultaneous field campaigns in the Seine and Garonne Rivers. We have shown that in the Garonne River, contrary to the common view, undular tidal bore can form for a large majority of tides, even sometimes at neap tide when the river discharge is low. We have identified, from surface elevation measurements, low-steepness, low-frequency undular tidal bores which are not visually observable. Such low-frequency tidal bores have been also identified and characterised for the first time in the Seine River. In this river, the first undulation wave height can be higher than 1 m. We have shown that the secondary wave steepness strongly increases when the Froude number exceeds the critical value Fc. The large-steepness tidal bore regime corresponds to what is commonly termed in French mascaret. 相似文献
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MANAGING PLANET EARTH TO MAKE FUTURE DEVELOPMENT MORE SUSTAINABLE： CLIMATE CHANGE AND HONG KONG 
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下载免费PDF全文 Selected recent findings related to climate change in Hong Kong include： (1)The Hong Kong seafloor has yielded a ca0.5-million year record of climate and sealevel changes.(2)Greenhouse gases produced naturally from subaerially exposed continental shelves and oceanic islands were a probable forcing mechanism in triggering the abrupt termination of past ice ages. (3)An analysis of annual mean temperature records has revealed that the urban heat island effect has contributed ca75％ of the warming. (4)Past volcanic eruptions are found to lower Hong Kongs temperature and to cause extremely dry and wet years. (5)No evidence can be found for an increase in frequency and intensity of typhoons based on the instrumental record since the end of the Second World War. (6)The observed rate of sealevel rise in the South China Sea is much slower than the predictions of the IPCC Fourth Assessment.
For the Earths management, population growth and the depletion of nonrenewable resources must be recognized as unsustainable. The human impact on the natural hydrological cycle is an important forcing mechanism in climate change. In order to delay the demise of the human race, management must include curbing population growth and much more waste recycling than at present. 相似文献
For the Earths management, population growth and the depletion of nonrenewable resources must be recognized as unsustainable. The human impact on the natural hydrological cycle is an important forcing mechanism in climate change. In order to delay the demise of the human race, management must include curbing population growth and much more waste recycling than at present. 相似文献
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Joseph G. Meert Anatoly S. Gibsher Natalia M. Levashova Warren C. Grice George D. Kamenov Alexander B. Ryabinin 《Gondwana Research》2011,19(4):867-880
The Cambrian explosion, c. 530–515 Ma heralded the arrival of a diverse assembly of multicellular life including the first hard-shelled organisms. Fossils found in Cambrian strata represent the ancestors of most modern animal phyla. In contrast to the apparent explosiveness seen in the Cambrian fossil record, studies of molecular biology hint that the diversification observed in Cambrian strata was rooted in ancestry extending back into the Ediacaran (635–542 Ma). Fossil evidence for this mostly cryptic phase of evolution is derived from the soft-bodied fossils of the Ediacaran biota found throughout the world and bilaterian embryos found in the Doushantuo lagerstätte in South China. The first appearance of Ediacara fauna is thought to have followed the last of the ~ 750–635 Ma Neoproterozoic glacial episodes by 20–30 million years. In this paper, we present evidence for the oldest discovery of the ‘Ediacara’ discoidal fossils Nimbia occlusa and Aspidella terranovica (?) that predate the early Cryogenian glaciations by more than fifty million years. There is considerable disagreement over the significance of discoidal Ediacaran fossils, but our findings may support earlier suggestions that metazoan life has roots extending deeper into the Proterozoic Eon. We also confirm the presence of a Late Cryogenian (e.g. “Marinoan”) glaciation on the Lesser Karatau microcontinent including dropstones and striated clasts within the glacial strata. 相似文献
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利用国际科技论文和中国科学院年报等统计资科，介绍了我国在国际上科技水平的地位，以及我国一些地质科研单位的研究水平状况，最后阐述了加强地质科研工作的一些措施。 相似文献
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《Comptes Rendus Geoscience》2018,350(5):195-201
To protect their steel structures from corrosion by cathodic protection, many harbours use aluminium sacrificial anodes, which induces aluminium release and potential contamination of the surrounding waters and sediments. To study the impact on Al mobility, a natural marine sediment was artificially contaminated with aluminium from different sources: sulphate or chloride salts, or sacrificial anodes. To estimate Al mobility in sediments, single (HCl) and sequential (F6) extractions were performed; they highlighted that aluminium is poorly mobile in natural sediment (HCl-leachable: 2% and F6-leachable: 9%). Contamination by aluminium salts inhibits HCl-leachability (≤ 2%), whereas the Al F6-leachability is intensified up to 18%, suggesting that the additional aluminium is scavenged in a mobile fraction that HCl is not able to solubilise. In case of aluminium anode contamination, sediments present surging Al HCl-leachable (15%) and F6-leachable (32%) fractions, which are related to aluminium mineralogical speciation. Indeed, contrary to the Al naturally present or introduced by salts, Al released by anodes is partly bound to the acid-soluble fraction, probably because of the integration of the released Al into the calcareous deposit produced at the anodes surfaces that finally comes away and gets mixed up with the sediment. The presence of aluminium in the acid-soluble fraction of sediments could have an important environmental impact as this fraction is easily available. Indeed, Al scavenged in the acid-soluble fraction of sediments participates in enhancing Al lability near the sacrificial anodes and may affect the surrounding ecosystems. 相似文献
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《地学前缘(英文版)》2018,9(6):1945-1955
CO2 mineral sequestration (in ultrabasic or basaltic rocks) has been considered as a promising long-term and stable approach to reduce CO2 in the atmosphere and would counteract the effect of global warming. Meanwhile, clays are widely found in ultrabasic reservoirs. In our study, clays were observed in natural olivine samples, which were used for laboratory experiments in a supercritical CO2 system at 140 °C and 15 MPa. Initial olivine samples were crushed into two sizes which were large grains of ∼850–1000 μm and powder particles of ∼75–150 μm, with the durations of 400 and 1000 h for the powder and grains, respectively. The results showed amorphous silica was newly formed and this passivating layer could mitigate the water-rock interaction to some extent, but it would not play a long-term prohibited effect on secondary mineral carbonate formation as it is a Fe(III) free silica coating. More interestingly, the secondary carbonates were observed to form near the surface sites where locates more clays. Our findings provide insights into the reaction mechanisms of olivine-scCO2-water interaction process in natural ultrabasic rocks. 相似文献