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1.
Robert Šajn Josip Halamić Zoran Peh Lidija Galović Jasminka Alijagić 《Journal of Geochemical Exploration》2011
The objectives of this study are as follows: (a) an assessment of the geochemical background signature of the Drava Valley before the industrial revolution; (b) an evaluation of anthropogenic geochemical influences on the alluvial plains and river terraces in the valley; and (c) a determination of the spatial distribution of trace elements in the alluvial soils of the Drava River downstream of the Austrian–Slovenian border to the confluence of Mura and Drava Rivers. 相似文献
2.
安徽江淮地区土壤微量元素分布特征及成因分析 总被引：2，自引：0，他引：2
多目标区域地球化学调查作为生态地球化学调查的基础工作,以快速查明表层土壤及其背景地球化学元素分布为目的.本文以安徽江淮地区多目标区域地球化学调查结果为基础,对安徽江淮地区耕地土壤及其母质中主要元素分布特征及其成因进行了分析研究,结果得出:(1)大多数地区表层土壤微量元素含量与深层具有一致性和继承性;(2)各地土壤微量元素分布特征主要受成土母质类型控制,说明其成因与成土母质和成土过程等因素有关;(3)耕地土壤微量元素含量的变异受施肥、灌溉和耕作方式等人为因素影响较大,且存在较大的地区差异性. 相似文献
3.
Isabel Ribeiro da Costa Rita Fonseca Catarina Pinho Alexandre Araújo Luísa Catarina Martins Nuno Dias Ana Isabel Janeiro Guilherme Freitas 《Environmental Earth Sciences》2018,77(5):202
Draining through industrial areas of the Minas Gerais mining state (Brazil), some tributaries of the São Francisco River constitute a potential environmental hazard for this great river and threaten the quality of the regional soils for agriculture and other activities. Extensive geochemistry and mineralogy of sediments, soils and alluvial plains from six selected areas within the Consciência drainage basin close to an important Zn-extraction plant, have been carried out. In this report, detailed mineralogy of those samples and supporting geochemical data are discussed, taking into account their specific climactic and environmental context. Petrographic and electron microprobe characterization of the sand-grained fraction of these materials was complemented by XRD on their finer fraction: the main contaminant minerals are willemite (one of the Zn ores used in the industrial plant) and jarosite, though their contents are quite variable in the studied areas and also with depth; minor amounts of Zn-, Pb-, Cd-, and Mn-bearing mineral phases are also frequent, usually as inclusions in willemite or in polycrystalline clasts, or adsorbed on the finer materials, such as clay minerals and associated Fe-hydroxides. Mineralogical contamination is responsible for high metal contents in the soils and sediments of the areas closer to the plant (e.g. Zn ? 2000 mg kg?1 and Cd ? 20 mg kg?1, which are the Intervention Values for Industrial Areas) and the greatest contamination risks are related to the more labile phases that circulate throughout the alluvial plains, the shallow sediments and the stream bed. Monitoring the mineral/chemical contamination and its extent also constitutes a useful basis for future proposals to remediate and recover this industrial area in order to decrease medium- and long-term negative impacts of metal contamination on the local and downstream environments. 相似文献
4.
Dr.-Ing. Mehdi Nadji 《International Journal of Earth Sciences》1974,63(3):897-904
Noteworthy facts about terrestrial deposits which fill the Internal Basins in Iran have been studied mainly in the last decade. Hydrogeological investigations in more than 100 alluvial basins have been most informative for essential knowledge about the structure of and sedimentation in the extensive plains. The thickness of the alluvial deposits ranges in different amount. Its known maximum, above 500 m, is located in the area between Teheran and Karaj. By the example of Varamin Plain it is shown that the sedimentation has an unequivocal dependence on the recent drainage pattern. The trace of“Water veins” is very important for exploration of ground water. The“Veins” are ancient washes filled up with outwashed gravels which are covered later with younger fine grained materials. The occurrence of these highly permeable deposits can be found by means of sedimentological investigations. 相似文献
5.
Cheng-Long Tu Teng-Bing He Xiao-Hui Lu Yun-Chao Lang Long-Bo Li 《Environmental Earth Sciences》2013,70(1):131-137
The properties of soils derived from carbonate rock, red residua, and sand-shale in Guizhou province, China are essentially different. However, the effects of parent material and anthropogenic activities on the concentration of trace elements when the soils are converted into paddy soils are unknown. A total of 319 paddy topsoil samples (0–20 cm) were collected in a typical region to determine their relative contribution to the concentrations of trace elements in the soil. The results indicated that the contents of trace elements were far beyond the uncultivated soil background and the input of organic fertilizers was presumably responsible for accumulation of trace elements. In addition, principal component analysis showed that the first component included Cd, Cr, and As, which strongly associated with anthropogenic activities. Pb and Hg formed the second component, which related to both parent materials and anthropogenic input. Furthermore, the Cr and Hg contents in paddy soil derived from carbonate rock have higher values than other types of soils partly because of the high background values as well as slightly alkaline condition. In the paddy soil derived from red residua, high physical clay content accounted for enrichment of Pb. 相似文献
6.
7.
The paper presents the first data on the zoning of modern volcanic soils on the Kamchatka Peninsula according to the age and composition of volcanic ashes in which the surface organogenic horizons of the soils were formed. The following soil provinces are recognized: Northern, Central, Western, and Southeastern. Parameters of their regional geochemical background (concentrations of trace elements) are determined. The main factor controlling the background concentrations of trace elements in these soils is the composition of the ashes underlying the soils. The geochemical specifics of the surface organogenic horizons of volcanic soils on Kamchatka may be variably affected only by the concentrations of trace elements whose average contents in magmatic rocks are the highest: Cr, Cu, Mn, Sc, Zn, Co, V, and Ag. The maximum concentrations of excess elements were determined in the soils underlain by ashes of basic composition, and the minimum concentrations of these elements occur in the soils formed in silicic ashes. All soil provinces recognized on Kamchatka are characterized by pervasively elevated Cu concentrations. It is proposed to identify volcanic soils formed in the peninsula in ashes of various composition with the application of a multiplicative geochemical coefficient. 相似文献
8.
Groundwater contamination with arsenic and other trace elements in an area of the pampa,province of Córdoba,Argentina 总被引：1，自引：0，他引：1
Hugo B. Nicolli Jose M. Suriano Miguel A. Gomez Peral Luis H. Ferpozzi Omar A. Baleani 《Environmental Geology》1989,14(1):3-16
A geochemical study of groundwater of the pampa in the province of Córdoba, Argentina, was performed; the area covered approximately 10,000 km2.Physical-chemical parameters, dissolved solids, and seven trace elements were determined in 60 selected water samples. Systematic and accurate measurements of arsenic, flourine, and vanadium were performed for the first time. Three trace element contaminants not reported earlier were found: an important one, selenium, and two others of less known effects, uranium and molybdenum.Eighty-four percent of the water analyzed showed arsenic contents over 0.05 mg/L, maximum contaminant level established by the U.S. Environmental Protection Agency (1982). The frequency distribution of trace elements was analyzed, and its fit to the lognormal distribution was proved by means of the Pearson and Kolmogorov-Smirnov test; the geographic distribution of the seven trace elements was mapped and its correlation with the anion-cation composition of the water was studied.The maximum arsenic, fluorine, vanadium, and uranium contents were found in the western part of the area under study, in waters containing dominant alkali metals in the cation composition. Maximum selenium and antimony contents were found in the eastern part of the area, while molybdenum distribution does not show any relationship with the other two groups. In addition, the geographic distribution of the trace elements seems to be related to the subsurface structure, which has been inferred using interactive digital analysis of Landsat imagery. The movements of the subsoil have disturbed surface and subsurface drainage influencing the water salinity and trace element contents.In order to investigate the origin of the contamination, 54 loess samples were collected in wells at depths ranging from the surface down to the water table. This loess, which has a high proportion of volcanic components, mainly rhyolitic glass, exhibits a chemical composition corresponding to that of a dacite.The loess and the volcanic glass show anomalous contents of all contaminant trace elements, mainly arsenic and selenium. For this reason loess is considered the most important contamination source in the groundwater under study. 相似文献
9.
覆盖区地球化学异常是由自然和人为因素引起的，在土壤垂直剖面上元素有多种分布类型，它反映了元素在土壤中迁移、演化及人为干扰的分布特征；通过对自然和人为污染的地球化学异常源追踪和评价，为环境污染治理和地区经济可持续发展提供决策依据。 相似文献
10.
元素表生活动性规律研究是制定地球化学勘查方法技术、开展地球化学找矿工作的前提和基础。以北山地区辉铜山铜矿为例,系统研究了元素的表生活动特性。结果表明：在不同母岩形成的土壤中,Cu、Mo、Pb、Zn、Au、Ag、As、Bi、Ba、Sr等微量元素富集作用存在差异;与粗粒级相比较,细粒级中元素的富集作用更加明显;随着样点到矿体之间距离的增加,粗粒级土壤样品的Cu、Mo元素含量降低,而Ba、Sr元素含量略有升高。土壤中常量元素含量特征表明：粗粒级与细粒级的物质组成、化学成分存在明显差异,粗粒级更接近于母岩。微量元素的富集作用与黏土矿物含量呈正比,与主要造岩矿物含量呈反比。以上述试验结果为基础,采用－4～＋40目粗粒级为采样介质,有效圈出了辉铜山铜矿元素正异常和负异常,为该地区的找矿靶区优选提供了依据。 相似文献
11.
青藏高原东部广泛分布着典型黄土沉积,对气候变化有着敏感的响应。对青藏高原东部地区典型表土、黄土、古土壤以及砂样,进行系统的常量、微量元素组成分析,结果显示,高原东部黄土常量元素氧化物主要为SiO2、Al2O3、Fe2O3和CaO,黄土中SiO2和CaO含量差别较大;Rb、Sr、Ba、Zr、V含量占了微量元素含量的大部分,表土、黄土、古土壤微量元素含量差别不一。与高原东部的风沙沉积、黄土高原黄土、河西走廊黄土的对比结果表明,青藏高原东部黄土组分的常量元素之间的比值（SiO2/Al2O3、TiO2/Al2O3）、常量与微量元素之间的比值（Zr/Al、Zr/Ti）、常量元素三角图（Ca-Mg-K、Ca-Mg-Na）等与其他地区黄土有明显差异,而青藏高原东部黄土与高原表土沉积物及河流砂、风成砂样品比较接近。这些异同点指示青藏高原东部黄土与黄土高原黄土的物源不同;其物源可能主要来自于青藏高原内部,高原内部的河流沉积物、冰碛物等粉尘物质可能为青藏高原东部黄土的主要物源。 相似文献
12.
冲积平原区生态地球化学调查方法技术研究中矿物鉴定和化学分析结果对比研究表明，土壤中化学元素的含量及其分布特征主要取决于土壤对成壤母质中各种矿物成分的继承，元素的区域地球化学背景差异和在不同深度的含量变化均可通过矿物和矿物组合特征较为直接地示踪显现，土壤中矿物组成对其化学元素含量的影响是直接的、决定性的。因此，利用土壤的矿物组成确定其常量和微量元素的初始值具有重要意义。据此可进一步解析土壤中元素地球化学异常成因，判别土壤的元素地球化学异常类型。 相似文献
13.
Barbara Mueller 《Environmental Earth Sciences》2018,77(2):35
Arsenic contamination of groundwater used as drinking water in South Asia poses a serious health threat to the inhabitants living on alluvial plains of the Himalayan foreland of countries like Bangladesh, India, Nepal and Myanmar. Although the geological and geochemical conditions favoring the release of the highly poisonous contaminant from the sediments hosting the groundwater are meanwhile quite well understood, there is still a significant debate about the origin of arsenic. The sediments forming a huge proportion of the Terai (lowlands of Nepal) aquifers are derived from two main sources, (i) sediments deposited by large rivers that erode the upper Himalayan crystalline rocks and (ii) weathered meta-sediments carried by smaller rivers originating in the Siwalik foothills adjacent to the Terai. In this article a so far underestimated source of As is discussed: the peraluminous leucogranites found ubiquitously in the Nepal Himalaya. The relationship between the trace elements analyzed in the groundwater in the Terai and trace elements found in such felsic rocks reflect the origin of the arsenic in the high Himalayas of Nepal. In addition to the high concentration of As, a striking feature is the presence of the lithophile trace elements like Li, B, P, Mn, Br, Sr and U in the groundwater. The mentioned elements point to a felsic initial source like metapelites or leucogranites—all rocks showing a high abundance of especially B, P and As as well as Cd and Pb. 相似文献
14.
Geochemical features of rocks,stream sediments,and soils of the Fiume Grande Valley (Calabria,Italy)
Carmine Apollaro Luigi Marini Rosanna De Rosa Paolo Settembrino Fabio Scarciglia Giuseppe Vecchio 《Environmental Geology》2007,52(4):719-729
The role of both natural weathering and anthropogenic pollution in controlling the distribution of major oxides and several
trace elements in soils, stream sediments, and rocks of the Fiume Grande catchment was evaluated. The contents of major oxides
and trace elements in soils appear to be governed by weathering and pedogenetic processes, although the use of fertilizers
in agriculture could also partly affect K2O and P2O5 contents. Stream sediments have concentrations of major oxides (except CaO) very similar to soils, as relevant amounts of
soil materials are supplied to the stream channels by erosive phenomena. In contrast, stream sediments have concentrations
of Cr, Co, Ni, Zn, As, and Pb significantly higher than those of soils, probably due to different conditions and rates of
mobility of these elements within the three considered matrices and/or disposal of wastes in the drainage network. Comparison
of the concentrations of PHEs in soils with the maximum admissible contents established by the Italian law shows that these
limits are too restrictive in some cases and too permissive in other ones. The approach of setting these limits with no consideration
for the local geological–geochemical framework may lead to improper management of the territory and its resources.
Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users. 相似文献
15.
《Applied Geochemistry》2002,17(8):961-973
Legal regulation of heavy metal contents is an important issue in many European countries, where laws still do not exist establishing the heavy metal levels permitted in soils. As a first step to determine the reference levels of heavy metals, it is necessary to know their contents in soils under natural conditions. To achieve this goal in the Autonomous Community of Aragón, a total of 133 sites have been sampled. A balanced allotment of the sampling sites, according to soil spatial distribution in the region, has been carried out by selecting 9 soil types that represent 97.5% of its surface area. Fifteen elements (Cr, Cu, Ba, As, Sb, Hg, Sn, Mn, Fe, Al, Zn, Ni, Co, Cd and Pb) have been analysed by (ICP–AES) after a partial acid extraction. The content of analysed elements has been correlated to some soil parameters such as organic matter, pH, and granulometric fractions. Results of the statistical analyses have shown a large variety and complexity in some of these relationships. The main factors for variation in the heavy metal contents are both the soil type and the lithology. Gypsisols and Calcisols developed on sedimentary rocks have the lowest contents while Leptosols overlying metamorphic and igneous rocks have the highest contents. The spatial distribution of heavy metal contents shows a large variability with the highest contents in the mountain ranges (Iberian and Pyrenees) and the lowest in the plains of the central Ebro valley. 相似文献
16.
M. A. Rasheed P. L. Srinivasa Rao Annapurna Boruah Syed Zaheer Hasan Bougi Mohamoud Mohamed Seddik Disha Pandey T. Harinarayana 《Journal of the Geological Society of India》2016,88(4):433-439
The aim of the present work is to define the geo-microbial signatures along with trace metals, and to investigate whether the geo-microbial anomalies have correlation with trace metal anomalies in Ahmedabad block of Cambay basin. The surface geochemical techniques are based on seepage of light hydrocarbon gases from the oil and gas pools to the shallow surface and can bring up near-surface oxidation reduction zones that favor the development of a diverse array of chemical and mineralogical changes. The paper reports the role of hydrocarbon microseepage in surface alterations of trace metal concentrations and hydrocarbon oxidizing bacteria and its interrelationship. For the purpose a total of 90 soil samples are collected in grid pattern of 2 x 2 km interval. The paper reports the chemical alterations associated with trace metals in soils that are related to hydrocarbon microseepages above some of the major oil and gas fields of this petroliferous region. The concentrations of V (0 to149 ppm), Cr (2 to 192 ppm), Cu (4 to 171 ppm), Se (98 to 440 ppm), Zn (56 to 1215 ppm) are obtained. It is observed that the concentrations of trace elements are tremendously increased when they are compared with their normal concentrations in soils. In this study the hydrocarbon oxidizing bacterial counts ranged between 1.0 x 103 and 1.59 x 106 cfu/g of soil sample respectively. The attempt has made for the first time, which revealed good correlation as both these anomalies are found as apical in relation. Integrated studies between trace elements and hydrocarbon oxidizing bacterial anomalies showed positive correlation with existing oil and gas wells in the study area. 相似文献
17.
浙江省北部地区调查研究表明,受成土母质来源、土壤类型及其理化性质等因素的影响,土壤元素全量、有效量及其有效度表现为:1)低山丘陵岗地土壤中As,Cd,Mo,Pb和Se全量较高,As,Cd,Fe,Pb,Se和Zn有效量较高;而山前平原区土壤中Hg,Pb和Zn元素全量较高,由地表向深部的下降递度较小,显示为原始沉积成因特点。2)中酸性、富含有机质的红壤和水稻土中As,Cd,Cu,Fe,Mn,Pb,Se,Zn等元素有效度较高,水稻土Hg有效度最低;弱碱性或碱性、贫有机质的潮土和滨海盐砂土中As,Cd,Cu,Fe,Mn,Pb,Se,Zn等元素有效量较低,但B有效量及有效度均较高。3)统计分析表明,土壤中Mn,Cu,Zn,Mo,Cd,Pb,Se等元素全量与有效量间具显著正相关性,表明全量是有效量的重要影响控制因素;有机质含量与Fe,Cu,Zn,Cd,As和Pb有效度间为显著正相关,说明有机质较高有利于土壤元素活化;Fe,Cu,Zn,Cd,As,Pb和Se有效度与pH值为显著负相关,表明土壤酸性增强(酸化)会增加这类元素的生物有效性。 相似文献
18.
Large areas of acid sulfate (AS) soils are located along the coastal plains of Finland, and previous studies have shown that
after reclamation they release extreme quantities of metals to watercourses in mid-western and northern Finland. In this study
on streams of south-western Finland, where little information about AS soils is available, these soils were found to exhibit
the same pattern of elevated metal- and sulfate concentrations as in the notorious AS soil landscapes of mid-western Finland.
Meteorologically/hydrologically driven temporal variations of these elements were great in the most affected streams. There
were also significant positive implications regarding future environmental work; AS soils in the highlighted region were found
to cause sudden temporal influxes of acidic water only in the most affected streams, indicating that the overburden and soils
of the area discharge well buffered water. Moreover, it was indicated that the high (less toxic) metal concentrations are
largely caused by erosion of suspended phyllosilicates (<0.45 μm) from farmland rather than by AS soils. 相似文献
19.
Tian Yang Zhaoyu Zhu Quanzhou Gao Zhiguo Rao Jiangwei Han Yi Wu 《Environmental Earth Sciences》2010,60(3):623-631
The concentrations of 23 trace elements in 50 topsoil samples collected from sites ranging between 18°19′N and 49°13′N in
East China were analyzed. Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, and Ta have mean contents more than two times higher than
in the continental upper crust. Three elements, Rb, Sr, and Ba, are present at lower concentrations than in the continental
upper crust. Finally, a group of elements consisting of Ge, Y, Zr, Nb, Sc, Hf, Pb, Th, and U are present at concentrations
1–2 times higher than in the continental upper crust. However, concentrations of trace elements are mainly affected by parent
rock. The contents of Sc, Ti, V, Cr, Mn, Co, and Cu for 29 soils from basalt were found to increase from north to south, whereas
Rb, Sr, and Ba contents were found to decrease. In addition, element concentration shows a close relationship with annual
average temperature (AAT) as well as annual average precipitation (AAP). Since the 29 soils are all from basalt, the trends
of the elemental contents should reflect the influence of climate, which determines the intensity of weathering. These elemental
trends suggest that the content of certain elements may indicate the intensity of basalt weathering. Ba/Nb and Sr/Nb ratios
were both found to have good correlations with AAT and AAP in this study, which means that these ratios can also indicate
the intensity of chemical weathering of basalt. 相似文献