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1.
王河锦 《地质学报》2022,96(5):1711-1723
本文集中讨论了甚低级变质作用研究中涉及到的几个问题,包括:① 近变质带的创立及其在解决划分成岩作用与变质作用界线这一国际难题中所取得的进步;② 伊利石结晶度对碎屑岩甚低级变质作用研究起到的作用与贡献;③ 仪器校正、粒度大小及其与Kübler指数的经验关系式;④ 泥质碎屑岩中的成岩指示矿物与变质指示矿物;⑤ 松潘 甘孜、巴颜喀拉造山带的甚低级变质作用的模式与新的成因解释;⑥ 讨论了涉及到的科学研究的相关规则。提出了运用指示矿物结合伊利石结晶度划分成岩作用/变质作用界线的方案和建立喜马拉雅伊利石结晶度标样的重要性与必要性;提出碎屑岩甚低级变质作用的新成因模式。  相似文献   

2.
由伊利石结晶度研究桂西右江地区区域极低级变质作用   总被引:10,自引:0,他引:10  
运用伊利石结晶度Kübler指数将桂西右江地区下三叠统罗楼群和中三叠统百逢组下段划归为浅层变质带(K.I△2θ°为0.22~0.25);将中三叠统百逢组上段和河口组划归为近变质带,中三叠统百逢组上段为高级近变质带(K.I△2θ°为0.26~0.33);中三叠统上部河口组为低级近变质带(K.I△2θ°为0.38~0.40),不排除局部为成岩带的可能.地层柱自下向上,伊利石结晶度Kübler指数由小变大,变质程度由高变低,而且,变质作用级别与岩层在地层柱中位置协调以及变质带边界与地层界线趋于一致,证明为区域埋藏极低级变质作用.凌云明山金矿区剖面矿体和百逢组各层段伊利石结晶度Kübler指数为0.42~0.50,属成岩带,且没有明显时空变化规律.  相似文献   

3.
极低级变质作用及其研究方法   总被引:9,自引:2,他引:9  
近年来国际上极低级变质作用的研究进展包括综合运用了伊利石结晶度等各项指标 ,将极低级变质带划分为成岩带、近变质带和浅变质带 ,成岩带和近变质带又可进一步划分为低级成岩带、高级成岩带、低级近变质带和高级近变质带 ;研究了伸展背景、阿尔卑斯碰撞背景和增生背景下的极低级变质作用 ;进一步理解了矿物的转变过程 ,建立了变质泥质岩石的矿物反应系列。即变质泥质岩石的二八面体矿物反应系列 ,为蒙皂石—伊 /蒙混层 (I/S)—伊利石—白云母 ;对应变质镁铁质岩石的三八面体矿物反应系列 ,为蒙皂石—绿泥石 /蒙皂石混层 (C/S)—绿泥石。岩石微构造也发生同步变化 ;明确了广泛应用的伊利石结晶度的本质是雏晶大小的一种量度 ,也与晶格应变有关 ,主要受反应动力的控制 ;建立了系统的研究技术方法 ,包括野外采样方法、室内X光衍射法 (XRD)、透射电镜法 (TEM )、地质温度计、地质压力计、岩石学方法、同位素地质学方法等  相似文献   

4.
就像用"砝码"标定"称"来测量物质质量一样,伊利石结晶度的测量也需要这样的"砝码"标定它的测量工具——衍射仪,从而能够进行伊利石结晶度的测量和对比。这个砝码就是伊利石结晶度标样或称伊利石结晶度国际标样。第2届Kübler-Frey国际研讨会伊利石结晶度圆桌会议就伊利石结晶度标样和近变质带的确定的问题进行了深入的讨论。会议一致认为,用伊利石结晶度标样校正X射线衍射仪是极为重要和必要的,没有进行标样校正的伊利石结晶度数据将被拒绝发表,经过伊利石结晶度国际标样校正后的伊利石结晶度数据才可用于近变质带的划分和国际对比。本文就伊利石结晶度测量的有关衍射仪类型与差别,衍射仪系统,测量条件,样品的影响和国际标样对仪器的校正等问题进行了分析研究。结果表明不同型号仪器,同型号仪器不同测量条件与状态,样品的不同制备方法都将影响伊利石结晶度Kübler指数的测量。指出只有使用国际标样才可校正测量的伊利石结晶度Kübler指数,从而达到消除偏差准确划分近变质带的标准和进行国际对比的目的。  相似文献   

5.
伊利石结晶度及其在低温变质研究中若干问题的讨论   总被引:4,自引:0,他引:4  
王河锦  陶晓风  M.Rahn 《地学前缘》2007,14(1):151-156
文中介绍与伊利石结晶度相关的伊利石矿物新的定名方案;讨论了伊利石结晶度的结晶学基础与Scherrer方程式的关系;讨论了三个重要的伊利石结晶度指数Weaver、K櫣bler和Weber指数的关系,并介绍推导的Weaver、K櫣bler和Weber指数的理论关系式;评价了衍射仪测量条件对结晶度数值的影响和三套伊利石结晶度标样的作用以及成岩带、变质带与葡萄石-绿纤石相、沸石相、绿纤石-阳起石亚相对比的依据。建议(1)停用绢云母一词;(2)建立可供各实验室使用的具有晶体结构和晶体化学参数和多型参数的伊利石结晶度标样;(3)建议多开展规范的可进行国际对比的低温变质研究,划分出与国际上一致的成岩带和近变质带,不仅利于低温变质作用理论的研究,而且由于成岩带到近变质转变带是重要的煤气油的生成带,也利于中国煤气油资源的勘探与开发,利于国民经济的长远持续发展。  相似文献   

6.
应用国际标样对伊利石结晶度测定值的校正及其意义   总被引:1,自引:0,他引:1  
伊利石的结晶度(IC),又称Kbler指数(K.I.),是指粘土矿物伊利石10×10-8cmXRD峰的半高宽。作为一个变质程度的指标,结晶度广泛用于研究高级成岩—极低级变质—低级变质作用的演变过程,随着变质程度的提高,伊利石结晶度逐渐增大。根据Kbler的建议,近变质带(极低级变质带)上、下边界的伊利石结晶度分别为0.42(°Δ2θ)和0.25(°Δ2θ)。然而,测定伊利石结晶度时,由于缺少国际标样,且各实验室间的样品制备、仪器条件、测试方法也不相同,因而导致获得的数据有较大差别,缺少可比性;因此,使用国际标样对数据进行校正,使各实验室获得的数据都能直接地进行对比,是非常必要的。利用X射线衍射方法测定了由L.N.Warr提供的5个伊利石结晶度的国际标样(其中,4个为岩石碎屑样品,采自英格兰西南部的极低级变质带;1个为单矿物样品,采自印度的花岗岩),获得了校正方程,ICCIS=0.977IC测定值+0.0336(°Δ2θ),R2=0.9835。在实验室内对213件采自国内的样品进行测定,测试条件与国际标样的测试条件相同,利用此方程对测得的伊利石结晶度数值进行校正,证实本实验室对伊利石结晶度的测定具有较高的可信度和国际可比性。  相似文献   

7.
川北阿坝地区三叠系粘土矿物特征及地质意义   总被引:6,自引:1,他引:6  
分析了川北阿坝地区三叠系泥质岩的岩石矿物组合、粘土矿物类型、伊利石结晶度和镜质体反射率特征,并以此划分成岩演化阶段及变质程度。以成岩作用—极低级变质作用的研究方法,明确了阿坝地区成岩作用及极低级变质作用的上、下界限及区域分布规律:以唐克为中心的地区处于成岩作用晚期阶段,成岩作用温度200~212℃,伊利石结晶度IC≥0.42;周围地区处于极低级变质作用阶段,成岩作用温度212~222℃,伊利石结晶度IC<0.42。镜质体反射率(Ro)也具有同样的演化规律。对该地区域上成岩演化的差异及原因作如下解释:由于构造活动的远近程效应存在差异,该地区的周缘明显受到构造作用的影响,因叠加动力变质而达到极低级变质作用阶段;唐克位于阿坝地块中心,受构造作用的影响相对较小,因而处于成岩作用晚期阶段。  相似文献   

8.
王河锦  周钊  王玲  苑蕾 《岩石学报》2014,30(10):3013-3020
运用伊利石结晶度、K云母晶格常数b0、应变值τ、颗粒大小分布与矿物组合分析等低温变质指示数据对湘北杨家坪剖面中晚元古宇和下古生界的近变质作用和成岩作用进行了研究。Kisch国际标样用于校正伊利石结晶度的测定。中晚元古宇伊利石结晶度Kübler指数范围为:0.21~0.24°Δ2θ,而下古生界为0.28~0.67°Δ2θ。表明近变质作用影响了中晚元古宇和部分下古生界。按照Kisch国际标样的成岩/变质界限(0.21~0.38°Δ2θ,CuKα),将剖面划分为北部近变质带和中南部成岩带。由绿泥石化学成分地质温度计估计近变质峰期温度约为260℃。K云母晶格常数b0值变化范围0.9000~0.9045nm,平均为0.9017nm,表明近变质作用处于中压-中低压力范围。近变质带伊利石(主要是中晚元古宇)的多型为2M1型,而成岩带伊利石(主要是下古生界)的多型为2M1+1M混合类型。平均对数粒度与对数方差之积(GLR)称为对数总成熟效应具有不同的两组分布特征即近变质作用区(GLR1.88)与成岩作用区(GLR1.88),这是一个新的发现。后变质作用的构造应力不仅可产生断层,而且可引起矿物的应变,从而导致衍射峰的宽化,使得近变质带伊利石结晶度值次生变大到成岩值范畴。与剖面南部地区(长沙-澧陵-浏阳,黄土店-仙溪,沅古坪)比较,杨家坪剖面中晚元古宇和下古生界经历了中压-中低压近变质作用和成岩作用的影响。这一结果与多数前人认为的"元古宇板溪群处于绿片岩相或亚绿片岩相或低绿片岩相而震旦到下古生界为沉积盖层"的观点不同。  相似文献   

9.
针对青藏高原可可西里的三叠系巴彦喀拉山群低级-极低级变质岩,利用X射线粉晶衍射分析确定了其矿物的共生组合、伊利石的结晶度Kubler指数(K)和b0值,并根据伊利石结晶度K和b0值对其区域变质作用的温压条件、分带、变质相进行了详细研究,得出了工作区5个不同岩性组合带的变质作用特征:昆仑山脉带属中压浅变质-近变质带,具葡萄石-绿纤石相和绿片岩相;不冻泉-库赛湖带属中压浅变质带,具绿片岩相;楚玛尔河带属中压近变质带,具葡萄石-绿纤石相;直达日旧带属中压浅变质带,具绿片岩相;五道梁带属中压近变质带,具葡萄石-绿纤石相.  相似文献   

10.
根据衍射峰具有的不同分布特点推导出了14个伊利石结晶度Kübler指数,Weaver指数和Weber指数关系式中常数项C1-C14的数值,提出了PearsonⅦ分布中形态参数μ与C5,C6,C11,C12的4个定量方程。由此,14个伊利石结晶度指数关系式可直接用于实际计算。根据阿尔卑斯复理石伊利石形态特征Sc=0.731,由这些关系式进行近变质带上下界线的转换得出与Kübler指数0.42~0.25。△2θ界线对应的Weaver指数和Weber指数的界线值分别为5.8~17.6和300~179。讨论了在自然干燥状态下直接进行伊蒙混层鉴定的基本原理。  相似文献   

11.
A multiple inter-laboratory calibration with illite Kübler?CFrey?CKisch ??crystallinity?? index and related standards is presented and compared with CIS standards used in the last two decades in very low-grade metamorphic studies. Comparing CIS values with KI standards the CIS values show a higher full width at half-high maximum peak intensity. In all cases due to broadening effects on the Kübler-index, zone-limits, specifically the diagenetic zone/anchizone boundary, a shift is produced in geographical dimensions in a metamorphic map-view. Combining standardised Kübler-index and vitrinite?Cbituminite reflectance measurements a coherent data set for compilation studies can be generated from the data of different research groups. This attempt to establish a unified database of independent measures to determine diagenetic/metamorphic zones with different analytical instrumental methods are indispensable to present metamorphic maps at very low-grade conditions. Given that the Kübler?CFrey?CKisch standards are difficult to preserve for the future and presumably they will be replaced with ongoing time by the CIS standards, a rescue of the laboratory settings from Frey, Kübler and others is done. After having compiled the Kübler-index??vitrinite reflectance zones in the Alps for the ??New Metamorphic Map of the Alps??, the presented calibration and inter-laboratory correlation gives a chance to save the KI values obtained by very different preparation procedures applied. This is an important step for further studies in an area like the Central Alps with a very high data grid. This correlation study will also make it possible that nearly 90?% of Kübler-index data from Switzerland can be compared in future work. Using the same calibration and preparation technique no fundamental problem in data comparison is achieved for the vitrinite/bituminite reflectance data operation. The main problem arises when rock maturity is compared with CIS calibrated Kübler-index values. Kübler-index values obtained by the so-called CIS calibration are not compatible with Kübler?CFrey?CKisch (árkai, Aprahamian, Brime, Ferreiro M?hlmann, H. Krumm, Leoni, Petschick) calibrated Kübler-Indices. Applying both standardisation approaches for field studies, partially different results are obtained.  相似文献   

12.
Low-temperature metamorphic petrology occupies the P?CT field between sedimentary and metamorphic petrology. Two important pillars of low-temperature metamorphism are coal petrology and clay mineralogy. When low temperature petrology was established bridging a hiatus between the two classical geological disciplines of sedimentary geology and metamorphic petrology, geologists faced a need for the usage of different terminology tenets. Martin Frey and Bernard Kübler were two pioneers in low-grade metamorphic petrology. They focused their research on clarifying the relationships of clay mineralogy and organic petrology to metamorphic pressure (P) and temperature (T) conditions. The ultimate aim of M. Frey and B. Kübler was to establish a correlation between clay indices and organic parameters for different geodynamic setting and therefore for various pressure?Ctemperature (P?CT) conditions occurring in low grade metamorphic terranes. For this purpose, a special attention was addressed to the correlation between the Kübler-Index (KI) and vitrinite reflectance (VR). All these efforts are dedicated to estimate the P?CT conditions and thus to gain insight into the geodynamic evolution of low-grade metamorphic terranes. B. Kübler and M. Frey honored here concentrated their studies to the Helvetic Central Alps area. The very low-grade Helvetic domain is therefore of basic interest of this paper. Ensuing the extensive compilation of data from the Helvetic domain, a reinterpretation of Kübler and Frey??s research is presented in the light of last decade??s scientific progress. A comprehensive dataset available enables to discriminate many factors influencing the Kübler-Index and organic-matter reflectance alongside to time, temperature and pressure. The correlation is restricted to the KI and organic matter reflectance (mostly VR) because most of the studies used both methods. Organic matter reflectance (OMR) includes data from vitrinite reflectance and bituminite reflectance measurements. Geodynamics has important control on the KI/VR (OMR) correlation. Tectonic units having a similar geodynamic evolution are featured by the comparable KI/OMR trends, related to the particular paleo-geothermal conditions. Obviously the KI/OMR correlations provide a mean to characterise geothermal gradients and metamorphic very-low-grade pressure?Ctemperature conditions. In terranes where high deformations rates are reported, exceeding the high anchizone conditions, strain promotes the kinetic effects of temperature and pressure on the KI versus OMR ratio.  相似文献   

13.
In order to verify the Triassic stratum metamorphism in this area, the crystallinity of illite in mudstone (shale) of Triassic stratum was analyzed and tested during the 1:50 000 regional mineral geological survey (I47E007023, I47E008023, I47E009023,1I47E009024)in Tuoyema area of Henan Mongolian Autonomous County in Qinghai Province. According to the experimental results of 30 samples, the crystallinity index of Triassic mudstone (shale) illite Kübler in Zongwulong-Zeku stratigraphic division in the north is 0.312-0.537, and the cell parameter b0 is 0.898-0.903 2 nm. The metamorphic temperature is less than 350 ℃, with the grape-chlorite and zeolite facies. The crystallinity index of Triassic mudstone (shale) illite Kübler in the western inclined mountain stratigraphic division in the south is 0.21-0.318, and the b0 value is 0.898 1-0.901 4 nm. The metamorphic temperature is mainly between 200 and 350 ℃, with the local temperature above 350 ℃ and grape-chlorite and greenschist facies. It is considered that the regional metamorphism grade in this area is very low or has no regional metamorphism. The metamorphism degree of the western dipping mountain stratum in the south is slightly higher than that of Zongwulong-Zeku stratum in the north. The measured metamorphic facies belts are not consistent with the previous thought, that is "regional low temperature dynamic metamorphism and low greenschist facies metamorphic belts", and the degree of metamorphism is relatively lower. It is confirmed that there is no large area regional metamorphism in the Triassic strata of Henan County in Qinghai Province, but only very low-level regional metamorphism.  相似文献   

14.
在开展“青海省河南县托叶玛地区I47E007023、I47E008023、I47E009023、1I47E009024四幅1:5万区域地质矿产调查”时,为验证该地区三叠系变质情况,针对三叠系中泥岩(页岩)的伊利石结晶度做了分析测试。30件样品的实验结果表明: 北部宗务隆—泽库地层分区三叠系泥岩(页岩)伊利石Kübler结晶度指数为0.312~0.537,晶胞参数b0为0.898 0~0.903 2 nm,判断其变质温度小于350 ℃,具葡萄石-绿纤石和沸石相; 南部西倾山地层分区三叠系泥岩(页岩)的伊利石Kübler结晶度指数为0.21~0.318,b0为0.898 1~0.901 4 nm,变质温度主要分布在200~350 ℃,局部>350 ℃,具葡萄石-绿纤石和绿片岩相。研究认为青海省河南县地区区域变质程度较低,为极低级变质作用或者未发生区域变质作用,且南部西倾山地层分区的变质程度略高于北部宗务隆—泽库地层分区变质程度。这一变质相带研究结论与前人认为的“区域低温动力变质作用及低绿片岩相变质带”不一致,变质程度相对更低。该研究证实了在青海省河南县地区三叠系地层中不存在大面积区域变质作用,仅存在极低级区域变质作用。  相似文献   

15.
The Neoproterozoic and Lower Paleozoic along the profile of Yuanguping in western Hunan Province, China underwent anchimetamorphism. The illite crystallinity (IC) of the <2 μm fractions ranges from 0.23-0.34°△2θfor the Neoproterozoic to 0.23-0.35°△A2θ for the Lower Paleozoic (calibrated with the Kisch IC set, Kisch, 1991). This indicates that the metamorphic grade of the Neoproterozoic and Lower Paleozoic is the anchizone. The peak metamorphic temperature is estimated to be 290-210℃. This result does not agree with the greenschist or subgreenschist facies of the Banxi Group, nor with the lower-greenschist facies or sedimentary cover of the Sinian to Lower Paleozoic, as most previous researchers thought. The illite (K-mica) b0 values range from 0.9074 to 0.8963 (nm) for the Neoproterozoic and the Lower Paleozoic. Based on cumulative frequency curves of the illite (K-mica) b0, the peak metamorphic pressure of the Banxi Group was derived to be of a type that is slightly higher than that of the N. Ne  相似文献   

16.
This study uses clay mineral assemblages, illite ??crystallinity?? (IC), chlorite ??crystallinity?? (CC), illite polytypes, the b cell-dimension of K-white mica, mineral geothermo-geobarometers and homogenization temperatures of fluid inclusions to investigate the transition from diagenesis to metamorphism in a 7?km thick Triassic flysch sequence in the well Hongcan 1, eastern Tibetan plateau. The 7,012.8?m deep borehole penetrated flysch of Upper to the Middle Triassic age and represents a unique chance to characterize low temperature metamorphic processes in an unusually thick sedimentary sequence developed on thickened continental crust. Mineral assemblage analysis reveals a burial metamorphic pattern with kaolinite and chlorite/smectite mix-layer phases present in the upper 1,500?m, and illite/smectite mixed-layer phases extending to a depth of 3,000?m. The metamorphic index mineral, graphite, was detected in sedimentary rock below 5,000?m using Raman spectroscopy. There exists a good correlation between IC and CC within the prograde burial sequence; with CC anchizonal boundaries of 0.242 and 0.314°2?? (upper and lower boundaries, respectively) corresponding to Kübler??s IC limits at 0.25 and 0.42°2??. Illite polytypism also shows an increase in the 2M 1 polytype with increasing depth, with ca. 60?% 2M 1 abundance compared to the 1M type at the surface, to 100?% 2M 1 at the bottom of the borehole. Fluid inclusion analysis show HHC-rich bearing fluids correspond to the diagenetic zone, CH4-rich bearing fluids appear at transitional zone from diagenetic to low anchizone and H2O-rich bearing fluids mark the high anchizone to epizone. Based on chlorite chemical geothermometer, calcite?Cdolomite geothermo-barometers as well as homogenization temperature of fluid inclusions, a paleotemperature range of 118?C348?°C is estimated for the well with a pressure facies of low to intermediate type.  相似文献   

17.
利用X射线衍射、扫描电子分析方法,对临夏地区塔湾黄土沉积物的粘土矿物学特征及其古气候指示作用进行了深入研究。结果表明:晚更新世的黄土沉积物风成黄土或经过表生风化改造形成的古土壤,其粘土矿物组成主要为伊利石、绿泥石、伊/蒙混层粘土矿物、高岭石和少量的坡缕石,沉积物中高岭石、伊利石/蒙脱石、伊利石和绿泥石矿物组合,指示物源区经历了气候从湿润变为冷干的转变。沉积物中伊利石结晶度的测量结果显示,其(001)衍射峰的半高宽在0.23°~0.86°之间,不同岩性层中伊利石结晶度存在明显的差别,伊利石结晶度存在着两个明显的峰值区,这表明临夏地区晚更新世的气候变化经历了从湿润→冷干→湿润→冷干的两个周期性的演化,而且晚期与早期相比更加湿润同时又更为冷干。沉积物中既有自生成因的坡缕石,又有碎屑成因的坡缕石。沉积物中自生成因坡缕石和碎屑成因坡缕石均稳定存在的现象表明,本区晚更新世的古气候是以干旱为特征,年均降雨量在300 mm左右。  相似文献   

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