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1.
Major and trace element, and Sr, Nd and Pb isotopic compositionswere determined for whole-rock samples from the ‘isotopicallyanomalous’ Akagi volcano in the volcanic front of theNE Japan arc. Sr and Nd isotopic compositions of phenocrystswere also analyzed together with their major and trace elementcompositions. Compared with the other volcanoes from the volcanicfront, the whole-rock isotope compositions of Akagi show highlyenriched characteristics; 87Sr/86Sr = 0·7060–0·7088,  相似文献   

2.
Shock metamorphosed rocks and shock-produced melt glasses from the Wanapitei Lake impact structure have been examined petrographically and by electron microprobe. Eleven clasts exhibiting varying degrees of shock metamorphism and eight impact-produced glasses have been analyzed for Rb, Sr and Sr isotopic composition. Five clasts and one glass have also been analyzed for large ion lithophile (LIL) trace element abundances including Li, Rb, Sr, and Ba and the REE's.The impact event forming the Wanapitei Lake structure occurred 37 m.y. ago based on K/Ar dating of glass and glassy whole-rock samples. Rb/Sr isotopic dating failed to provide a meaningful whole-rock or internal isochron. The isotopic composition of the glasses can be explained by impact-produced mixing and melting of metasediments. Large ion lithophile trace element abundance patterns confirm the origin of the glasses by total shock melting of metasediments.  相似文献   

3.
Major, trace element and Sr isotopic compositions have been determined on 21 lava samples from Vico volcano, Roman Province, Central Italy. The rocks investigated range from leucite tephritic phonolites to leucite phonolites and trachytes. Trace element compositions are characterized by high enrichments of incompatible elements which display strong variations in rocks with a similar degree of evolution. Well-defined linear trends are observed between pairs of incompatible trace elements such as Th-Ta, Th-La, Th-Hf. A decrease of Large Ion Lithophile (LIL) elements abundance contemporaneously with the formation of a large central caldera is one of the most prominent characteristics of trace element distribution. Sr isotope ratios range from 0.71147 to 0.71037 in the pre-caldera lavas and decreases to values of 0.70974–0.70910 in the lavas erupted after the caldera collapse. Theoretical modelling of geochemical and Sr isotopic variations indicates that, while fractional crystallization was an important evolutionary process, AFC and mixing also played key roles during the evolution of Vico volcano. AFC appears to have dominated during the early stages of the volcanic history when evolved trachytes with the highest Sr isotope ratios were erupted. Mixing processes are particularly evident in volcanites emplaced during the late stages of Vico evolution. According to the model proposed, the evolution of potassic magmas emplaced in a shallow-level reservoir was dominated by crystal fractionation plus wall rock assimilation and mixing with ascending fresh mafic magma. This process generated a range of geochemical and isotopic compositions in the mafic magmas which evolved by both AFC and simple crystal liquid fractionation, producing evolved trachytes and phonolites with variable trace element and Sr isotopic compositions.  相似文献   

4.
Four volcanoes in the Pantar Strait, the westernmost part of the extinct sector of the east Sunda arc, show remarkable across-arc variation in elemental abundances (K2O: 1.2 to 4.3%), trace element ratios (Pb/Ce: 0.4 to 0.18; Ce/Yb: 20 to 55) and isotope ratios (143Nd/144Nd: 0.51263 to 0.51245; 87Sr/86Sr: 0.7053 to 0.7068; 206Pb/204Pb: 19.29 to 19.15). Pb isotopes are decoupled from Sr and Nd isotopes, with the frontal volcanoes showing the higher Nd and Pb and lower Sr isotopic ratios. The isotopic and trace element ratios of the volcanic samples are best explained by modification of a MORB-type source (with Indian Ocean island basalt-type Pb isotopic characteristics) by a fluid and a partial melt of subducted continental material (SCM). The frontal volcano contains the highest proportion of the fluid component, with a small contribution of partial melt. The source of the rear-arc volcano is strongly influenced by a partial melt of SCM that had undergone a previous dehydration event, by which it lost most of its fluid-mobile elements such as Pb. The SCM partial melt was in equilibrium with both rutile and garnet, whereas mantle melting took place in the presence of residual mica. The relatively large across-arc increase in incompatible elements can be explained by a combination of increasing addition of SCM partial melt, changing mantle wedge fertility and smaller degrees of partial melting toward the rear of the arc. Comparison with a more westerly across-arc transect shows that the relatively low 143Nd/144Nd ratios of the frontal volcano, and the decoupling of Pb from Sr and Nd isotopes are unique to the Pantar Strait volcanoes. This is likely to reflect magma generation in a collisional environment, where the leading edge of the Australian continent, rather than subducted sediment, contributes to the magma source.  相似文献   

5.
Hydrothermal convection initiated by emplacement of the gabbro-syenite complex of Abu Khruq into the Egyptian basement 89 Ma ago systematically altered the trace element and isotopic compositions of the syenites. The scale of Sr transport in migrating solutions was far larger than the scale of Sr isotopic equilibration within rocks. As a result, Sr exchange was heterogeneous in the syenites, an effect which can be observed on three different scales. Within grains of a single mineral species, heterogeneities are related to grain boundaries and microfractures through which fluids migrated. Among minerals within rock samples, heterogeneities are related to differences in susceptibility to Sr alteration. Among samples within a single unit, heterogeneous alteration is apparently related to differences in permeability close to fracture zones.During the early stages of alteration radiogenic Sr derived from the country rocks was added to the syenites, causing small net changes in concentration (5 ppm ave.). Some Rb-Sr mineral isochrons from single rock samples yield the emplacement age because isotopic equilibration of this added Sr sometimes occurred within rock specimens. However, regressions of the whole-rock Rb-Sr data yield apparent ages that are about 10 Ma too old. Later stage alteration involved larger changes in whole-rock Sr concentration (45 ppm ave.) but had little further effect on the isotopic relationships because the Sr was derived from cogenetic gabbros rather than the country rocks.Alterations of Rb, Sr, and Sr isotopic compositions are not well correlated with changes in 18O/16O ratio because mineralogy played an important role in decoupling trace element and oxygen isotopic alteration. In general, the absence of such correlations for whole-rock data is not diagnostic of rocks with unaltered trace element and isotopic compositions. Mineral-scale Sr isotopic heterogeneities associated with grain boundaries and microfractures may be the most unambiguous evidence of trace element mobility.Deceased on 9/81  相似文献   

6.
The postshield and posterosional stages of Haleakala Volcano contain intercalated alkalic basalt and evolved alkalic lavas. Isotopic and incompatible element abundance ratios in the Haleakala postshield basalts changed systematically with time, providing evidence for significant temporal changes in the mantle components contributing to the magmatic sources. Specifically, a depleted, i.e. low87Sr/86Sr and high143Nd/144Nd, mantle component is more abundant in younger lavas. However, as magma-production rates decreased during the postshield and posterosional stages, basaltic melts in magma reservoirs cooled and fractionated, leading to evolved residual melts such as hawaiite. Because primary basalt compositions changed with time, the evolved Haleakala lavas formed from a range of parental compositions. However, basalts and evolved lavas of similar age and isotopic ratios (Sr and Nd) have major and trace element contents that are consistent with a crystal-fractionation model. Although alkalic basalt and hawaiite are the dominant lavas of the postshield stages of both Haleakala and Mauna Kea volcanoes, there are important differences between their lavas. For example, compositional differences between the hawaiite suites at Haleakala and Mauna Kea indicate that, on average, the evolved lavas at Haleakala formed at lower pressures. Also, at Haleakala basalts are intercalated with hawaiites, whereas at Mauna Kea basalts and hawaiites are separated by a sharp boundary. These differences probably reflect a higher magma supply rate to the Haleakala volcano.  相似文献   

7.
The isotopic compositions of Nd and Sr and concentrations of major and trace elements were measured in flows and tuffs of the Woods Mountains volcanic center of eastern California to assess the relative roles of mantle versus crustal magma sources and of fractional crystallization in the evolution of silicic magmatic systems. This site was chosen because the contrast in isotopic composition between Precambrian-to-Mesozoic country rocks and the underlying mantle make the isotope ratios sensitive indicators of the proportions of crustal- and mantle-derived magma. The major eruptive unit is the Wild Horse Mesa tuff (15.8 m.y. old), a compositionally zoned rhyolite ignimbrite. Trachyte pumice fragments in the ash-flow deposits provide information on intermediate composition magma types. Crustal xenoliths and younger flows of basalt and andesite (10 m.y. old) provide opportunities to confirm the isotopic compositions of potential mantle and crustal magma sources inferred from regional patterns. The trachyte and rhyolite have Nd values of -6.2 to -7.5 and initial 87Sr/86Sr ratios mostly between 0.7086 and 0.7113. These magmas cannot have been melted directly from the continental basement because the Nd values are too high. They also cannot have formed by closed system fractional crystallization of basalt because the 87Sr/86Sr ratios are higher than likely values for parental basalt. Both major and trace element variations indicate that crystal fractionation was an important process. These results require that the silicic magmas are end products of the evolution of mantle-derived basalt that underwent extensive fractional crystallization accompanied by assimilation of crustal rock. The mass fraction of crustal components in the trachyte and rhyolite is estimated to be between 10% and 40%, with the lower end of the range considered more likely. The generation of magmas with SiO2 contents greater than 60% appears to be dominated by crystal fractionation with minimal assimilation of upper crustal rocks.  相似文献   

8.
The processes operating in the development of chemical zonationin silicic magma chambers have been addressed with a Sr–Nd–Pb–Hf–Thisotope study of the chemically zoned trachyte pumice depositof the Fogo A eruption, Fogo volcano, Azores. Sr isotopic variationis observed in whole rocks, glass separates and sanidine phenocrysts(whole-rock 87Sr/86Sr: 0·7049–0·7061; glass87Sr/86Sr: 0·7048–0·7052; sanidine 87Sr/86Sr:0·7048–0·7062). Thorium isotopic variationis observed in glass separates, with (230Th/232Th)o rangingfrom 0·8737 to 0·8841, and exhibiting a negativecorrelation with Sr isotopes. The Nd, Pb and Hf isotopic compositionsof the whole-rock trachytic pumices are invariant and indistinguishablefrom basalts flanking the volcano. The Sr isotope variationsin the whole rocks are proposed to be the result of three distinctprocesses: contamination of the Fogo A magma by assimilationof radiogenic seawater-altered syenite wall rock, to explainthe Sr and Th isotopic compositions of the glass separates;incorporation of xenocrysts into the trachytic magma, requiredto explain the range in feldspar Sr isotopic compositions; andpost-eruptive surface alteration. This study emphasizes theimportance of determining the isotopic composition of glassand mineral separates rather than whole rocks when pre-eruptivemagmatic processes are being investigated. KEY WORDS: Azores; open-system processes; Sr isotopes; trachytic pumices; zoned magma chambers  相似文献   

9.
阿拉善右旗库和乌拉石英闪长岩体位于塔里木—华北古陆块与西伯利亚古陆块之间的古生代褶皱带,为探讨其独特的地质意义,本文通过对库和乌拉石英闪长岩体的常量、微量和稀土元素成分分析和综合研究,系统讨论了岩体的岩石地球化学特征、岩体的形成时代及大地构造环境等地质问题。研究表明库和乌拉石英闪长岩属于钙碱性岩,岩体40 Ar-39 Ar同位素测年结果为278.0±2.0Ma,形成时代为早二叠世。稀土元素球粒陨石标准化配分曲线为轻稀土略富集型,LREE/HREE为6.83~6.92,(La/Yb)N为7.23~7.29,δEu=0.93~0.98,δCe=0.90~0.91;大离子亲石元素(Ba、Sr)和不相容元素(Zr、Hf)明显的富集,与碰撞造山环境有关的钙碱性岩石相似。研究认为库和乌拉石英闪长岩体是在板块碰撞条件下形成于造山带的深源岩浆演化产物,具备形成浆控型铜金矿的地质地球化学条件。  相似文献   

10.
A combined compositional and Hf, Nd and Sr isotopic study was performed on a suite of samples of progressively deformed granite from a mylonite zone in the Harquahala Mountains, western Arizona, to evaluate the effects of deformation and metamorphism on the isotopic systematics of typical continental crustal rocks. The 1.4 Ga Harquahala Granite was deformed during Mesozoic thrusting along the Harquahala thrust. Granite in the resulting 60 m wide shear zone ranges from protomylonite to ultramylonite. In most of these mylonites, the protolith is not megascopically recognizable, and can be discerned only by the progressive transition to undeformed granite. Isotopic analyses of Hf, Nd and Sr from the shear zone document the immobility of the Hf and Nd isotopic systems relative to that of the Sr isotopic system during deformation. The Rb–Sr isotopic data show considerable scatter on an isochron plot, exhibiting both gains and losses of Rb and Sr from the whole-rock systems. In contrast, the Sm–Nd and Lu–Hf isotopic systematics are mostly well behaved on isochron diagrams, plotting mostly in tight clusters or along 1.4 Ga isochrons. These results show that while the Sr isotopic system in crustal rocks is quite susceptible to later tectonic disturbance, both Hf and Nd isotopic systems can provide reliable model age information in continental crustal terranes even when the rocks have been subjected to low to medium grades of deformation and metamorphism.  相似文献   

11.
刘洁  袁玲玲  杨智荔 《地球科学》2022,47(4):1271-1294
镁铁质岩石作为幔源岩浆产物,其成因研究有助于探讨华北克拉通深部地幔性质及其演化过程.对中条山地区镁铁质侵入岩开展了系统的锆石U-Pb年代学、全岩主、微量元素、全岩Sr-Nd同位素和锆石Hf同位素研究,揭示了晚三叠世(217±2 Ma)和早白垩世(121±2 Ma)两期镁铁质岩浆活动.晚三叠世镁铁质侵入岩SiO2含量低至...  相似文献   

12.
M.E.P. Gomes  A.M.R. Neiva 《Lithos》2005,81(1-4):235-254
Deformed Hercynian peraluminous granitoids ranging from tonalite to granite crop out in the Rebordelo–Agrochão area, northern Portugal and some of them contain tonalitic and granodioritic enclaves. Variation diagrams of major and trace elements of the rocks, biotites and sphenes show fractionation trends. The most- and the least-deformed samples of granite and their biotites also define fractionation trends. There is decrease in all rare earth element (REE) contents and increase in the Eu anomaly in REE patterns from the most- to the least-deformed samples of granite. All the granitoids define a whole-rock Rb–Sr errorchron. A whole-rock Rb–Sr isochron for the least-deformed samples of granite yields an age of 357±9 Ma and an initial 87Sr/86Sr ratio of 0.7087±0.0007. Geochemical modelling suggests that the tonalitic magma evolved by AFC (fractional crystallization of magnesiohornblende, plagioclase, quartz, biotite and ilmenite, and assimilation of metasediments) to originate tonalitic and granodioritic enclaves, granodiorite and granite. δ18O values support this mechanism. The tonalite is hybrid and derived by interaction of a mantle-derived magma and crustal materials.  相似文献   

13.
Daisen volcano, southwest Japan, has been thought to be an exclusivelydacitic volcano, lavas having trace element patterns with agarnet signature. We studied the basalts at the western footof the volcano and made two unexpected findings. (1) The homogeneityof 87Sr/86Sr in Daisen basalts (Sr isotopic variability  相似文献   

14.
The Myggbukta caldera complex and a swarm of basic dykes constitute the latest Tertiary magmatism in the Hold with Hope region, East Greenland. The Sr and Nd isotope ratios of these rocks show coherent variations which extend to high 87Sr/86Sr and low 143Nd/144Nd values and require a contribution from continental lithosphere. Broad correlations with major element differentiation indices suggest that the continental component was incorporated during magmatic differentiation thereby favouring a crustal contamination process. Trace element concentrations are strongly correlated with isotopic compositions but display ranges for many incompatible elements which extend beyond likely crustal contaminant compositions. This is readily modelled by AFC processes in which the dominant cause of trace element enrichment is the concentration effect of fractional crystallisation rather than the composition of the contaminant. The simplest such models still require unrealistically high degrees of fractional crystallisation to explain the ten-fold enrichment of some trace elements. This can be overcome if the primary magmas entering the crust already had highly variable trace element compositions. Such variability is readily achieved if melts from different parts of the melting column escape without thorough homogenization. An AFC model which incorporates variability in parental magma composition is then able to simulate the range of compositions observed at Hold with Hope. This carries the implication that the variations observed are more readily attributed to changes in uncontaminated parental magma than to variations in the composition or amount of contaminant. Received: 5 March 1998 / Accepted: 16 June 1998  相似文献   

15.
九龙嶂和相山火山-侵入杂岩是中国华南地区与铀矿有关的中生代流纹英安质火山-侵入杂岩。相山火山-侵入杂岩是华南地区最大的火山岩型铀矿赋矿围岩,其主体岩石为流纹质碎斑熔岩,浅成-超浅成侵入岩有英安斑岩、花岗斑岩等;九龙嶂火山-侵入杂岩的铀资源潜力尚待评价,主体岩石为流纹质熔结凝灰岩,浅成-超浅成侵入岩有英安斑岩、石英二长斑岩等。两地区的火山-侵入杂岩的岩石化学成分及其变化特点极为相近,微量元素蛛网图和稀土配分型式也基本一致,它们具有相似的岩浆过程和统一的活动陆缘构造背景;同时,从早期火山岩浆活动到晚期浅成-超浅成岩浆侵入活动,其w(SiO2)和w(Rb)/w(Sr)的值降低,而w(MgO)以及w(K)/w(Rb)、w(Ba)/w(Rb)和w(LREE)/w(HREE)的值增高,晚期浅成-超浅成侵入岩与早期火山岩没有直接的分异演化关系。  相似文献   

16.
为解释冈底斯南缘新发现的中基性岩体构造环境及物质来源等信息,以西藏自治区贡嘎县昌果乡辉长闪长岩为研究对象,通过开展锆石U-Pb定年、Hf同位素组成、全岩地球化学分析,得到岩体锆石年龄为(165±1. 1) Ma。样品富集大离子亲石元素,亏损高场强元素,具有富铝(Al2O3=18. 84%~20. 70%)、富钾的特征,在构造判别图解中样品多落在挤压岛弧区域,表明其形成构造环境应为俯冲岛弧环境。样品具较为平缓的稀土配分曲线,岩浆分异程度较低,无明显Eu异常,(La/Yb)N平均值为2. 30(<4. 3),与幔源岩浆的稀土配分型式相似。锆石Hf同位素显示εHf(t)值为很高的正值(12. 97~18. 74),二阶段模式年龄集中在150~218 Ma,略大于其侵位年龄,表明幔源岩浆在侵位过程中受到地壳物质的混染。结合区域构造演化史认为该岩体形成于新特提斯洋向冈底斯俯冲过程中的成熟岛弧期,从而也进一步证实了南冈底斯在中侏罗世处于俯冲岛弧构造环境。  相似文献   

17.
关于冀东-辽西中-晚三叠世具有埃达克质岩石特征的花岗质岩石的源区性质,存在较大争议,且以往对位于其北东向隆起区内的柏杖子岩体的成因研究程度低.对柏杖子花岗质侵入岩进行了系统的年代学、地球化学、Sr-Nd-Hf同位素研究,结果显示:柏杖子岩体结晶年龄为233±3 Ma,岩石具有低MgO、Mg#和Co、Ni、Cr含量;富集大离子亲石元素,亏损高场强元素,显示明显的Pb、Th正异常和Nb、Ta、Ti、P负异常;轻、重稀土元素分馏明显;87Sr/86Sr (t) 为0.704 45~0.705 24,εNd(t) 值为-7.3~-1.7;锆石εHf(t) 为-13.4~-5.9.综合分析认为,高Sr/Y比值和低Y含量的柏杖子岩体属于华北克拉通正常厚度镁铁质下地壳熔融的产物,岩石高Sr/Y比值、低Y含量和Nb-Ta负异常特征为继承的华北克拉通下地壳内在性质,并具有与太古宙-古元古代TTG岩石系列相一致的Nb-Ta解耦特征,表明柏杖子岩体源区物质有TTG岩石的贡献;岩石Sr-Nd-Hf同位素组成和低相容元素含量特征同样表明岩浆来源于受改造的下地壳熔融.早中生代玄武岩底侵过程中幔源组分的加入对华北克拉通下地壳形成改造,同时提供热源诱发下地壳物质熔融,形成的熔体向浅表侵位,经历一定程度的斜长石分离结晶,并最终形成柏杖子岩体.   相似文献   

18.
苏北盆地隐伏早第三纪玄武岩地球化学及源区特征   总被引:4,自引:0,他引:4  
杨祝良  沈渭洲 《岩石学报》1998,14(3):332-342
早第三纪玄武岩在苏北盆地以橄榄拉斑玄武岩为主,在地表基本无出露,均为钻井揭示,呈夹层产出。对它们详细的岩相岩石学、微量元素地球化学及锶钕同位素研究表明,玄武岩原始岩浆源于受俯冲洋壳影响的陆下岩石圈地幔较高程度部分熔融并在源区经历了一定程度的单斜辉石和橄榄石的结晶分异,岩浆上升至喷出地表过程中没有发生明显地壳物质的混染,其所表现出的过渡特征暗示区域在古新世时处在一个由活动大陆边缘向大陆板内裂谷转换的关键时期。  相似文献   

19.
对甜水海地块东北部阿克萨依矽卡岩型铁矿区内与矿化有关的二长花岗岩开展LA-ICP-MS锆石U-Pb年代学、全岩主微量元素、Sr-Nd-Pb同位素及锆石Lu-Hf同位素研究,旨在厘定花岗岩的形成时代、岩石成因及成矿动力学背景。LA-ICP-MS锆石U-Pb定年结果表明,二长花岗岩侵位年龄为12.37±0.18 Ma(中新世高拉瓦尔期)。地球化学特征表明二长花岗岩属准铝质?弱过铝质高钾钙碱性?钾玄岩系列,具有高Sr(432~1174μg/g),低Y(3.08~18.11μg/g)和Yb(0.35~1.39μg/g)以及高Sr/Y值(64.8~203)的埃达克岩特征。在Harker图解上SiO2与其他主量元素呈负相关关系,La/Sm-La以及La/Yb-La图解显示具有分离结晶趋势,表明岩浆演化以分离结晶为主。二长花岗岩SiO2与Y、Yb呈负相关关系而与Sr/Y值呈正相关关系,并且矿区内存在同源同期闪长玢岩,因此认为阿克萨依二长花岗岩的埃达克岩性质是玄武质岩浆的分离结晶作用引起的。全岩Sr-Nd-Pb同位素分析表明,阿克萨依二长花岗岩与青藏高原北部地球化学省具有相似的同位素组成特征,岩浆起源于受俯冲板片交代的富集地幔,而变化范围较大的εHf(t)值以及较低的Mg#暗示岩石侵位过程中受到地壳混染。结合前人研究,我们认为阿克萨依二长花岗岩及相关的矽卡岩铁矿形成于中新世西昆仑受巨型地幔低速体上涌影响的伸展构造背景下。  相似文献   

20.
The ∼133 Ma volcanic rocks of Sangxiu Formation are distributed in the eastern part of the central Tethyan Himalaya and belong paleogeographically to the northeastern margin of Greater India. These volcanic rocks include alkaline basalts and felsic volcanic rocks. Major and trace element abundances and whole-rock isotopic data for selected samples of these volcanic rocks are used to infer their petrogenesis. Geochemically, the Sangxiu basalts are closely similar to the Emeishan high-Ti basalts. Major and trace element data and Sr–Nd isotopic compositions suggest that the Sangxiu basalts may have been derived from an OIB-type mantle source, with discernable contributions from subcontinental lithospheric mantle (SCLM). The basaltic magmas may have formed as a result of the infiltration of plume-derived melts into the base of the lithosphere in a continental rift setting. The Sangxiu felsic volcanic rocks share most of the geochemical features of A-type granite, and have Sr–Nd isotopic compositions which differ considerably from the Sangxiu basalts, suggesting that they originated from the anatexis of ensialic continental crust. The Sangxiu volcanic rocks may be considered as the consequence of an interaction between the Kerguelen hotspot and the lithosphere of the northeastern margin of Greater India at ∼133 Ma, and may represent the initial stage of the separation of Greater India from southwestern Australia.  相似文献   

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