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1.
Precise in situ zircon U-Pb dating and Lu–Hf isotopic measurement using an LA-ICP-MS system, whole-rock major and trace element geochemistry and Sr–Nd isotope geochemistry were conducted on the volcanic host rocks of the Tongyu copper deposit on the basis of further understanding of its geological characteristics. Three zircon samples from the volcanic host rocks yielded 206Pb/238 U weighted average ages ranging from 436±4 Ma to 440±5 Ma, which are statistically indistinguishable and coeval with the ca. 440 Ma northward subduction event of the Paleo-Qinling oceanic slab. The volcanic host rocks were products of magmatic differentiation that evolved from basalt to andesite to dacite to rhyolite, forming an integrated tholeiitic island arc volcanic rock suite. The primitive mantle-normalized trace element patterns for most samples show characteristics of island arc volcanic rocks, such as relative enrichment of LILE(e.g. Th, U, Pb and La) and depletion of HFSE(e.g. Nb, Ta, Ti, Zr and Hf). Discrimination diagrams of Ta/Yb vs Th/Yb, Ta vs Th, Yb vs Th/Ta, Ta/Hf vs Th/Hf, Hf/3 vs Th vs Nb/16, La vs La/Nb and Nb vs Nb/Th all suggest that both the volcanic host rocks from the Tongyu copper deposit and the volcanic rocks from the regional Xieyuguan Group were formed in an island arc environment related to subduction of an oceanic slab. Values of ISr(0.703457 to 0.708218) and εNd(t)(-2 to 5.8) indicate that the source materials of volcanic rocks from the Tongyu copper deposit and the Xieyuguan Group originated from the metasomatised mantle wedge with possible crustal material assimilation. Most of the volcanic rock samples show good agreement with the values of typical island arc volcanic rocks in the ISr-εNd(t) diagram. The involvement of crustal-derived material in the magma of the volcanic rocks from the Tongyu copper deposit was also reflected in the zircon εHf(t) values, which range from-3.08 to 10.7, and the existence of inherited ancient xenocrystic zircon cores(2616±39 Ma and 1297±22 Ma). The mineralization of the Tongyu copper deposit shows syn-volcanic characteristics such as layered orebodies interbedded with the volcanic rock strata, thus, the zircon U-Pb age of the volcanic host rocks can approximately represent the mineralization age of the Tongyu copper deposit. Both the Meigou pluton and the volcanic host rocks were formed during the ca. 440 Ma northward subduction of the Paleo-Qinling Ocean when high oxygen fugacity aqueous hydrothermal fluid released by dehydration of the slab and the overlying sediments fluxed into the mantle wedge, triggered partial melting of the mantle wedge, and activated and extracted Cu and other ore-forming elements. The magma and ore-bearing fluid upwelled and erupted, and consequently formed the island arc volcanic rock suite and the Tongyu VHMS-type copper deposit.  相似文献   

2.
The Zhou’an PGE-Cu-Ni deposit was recently discovered in the Qinling orogenic belt bound by the Yangtze and the North China Cratons. It is a blind deposit thoroughly covered by the Cenozoic alluvial sediments in the Nanyang Basin. As the first large PGE-Cu-Ni deposit discovered in the Qinling-Dabie-Sulu orogenic belt, its geological and geochemical characteristic, isotope age, genesis and tectonic setting are of wide concern in both scientific studies and ore exploration. In this contribution, we report the results obtained from a pioneering study. The Zhou’an ultramafic complex is ferruginous, with m/f?=?4.79–5.08, and shows the nature of tholeiite series. It is rich in light rare earth elements, Rb, Th, U, La, Sm, Zr and Hf, and poor in heavy rare earth elements, Nd and Ta, suggesting an intraplate setting. It has high 87Sr/86Sr and low 143Nd/144Nd ratios. The ratios of Zr/Nb, La/Nb, Ba/Nb, Rb/Nb, Th/Nb, Th/La and Ba/La, suggest the magma originated from lithosphere mantle. The Fo values of olivine and Pd/Ir-Ni/Cu diagram suggest primary magma was High Mg basalt. The laser ablation inductively coupled plasma atomic emission spectroscopy zircon U-Pb age is 641.5?±?3.7 Ma.  相似文献   

3.
徐文涛  刘福来  冀磊  许王 《岩石学报》2020,36(12):3607-3630
哀牢山-大象山变质杂岩带位于青藏高原东南缘,是西南三江地区重要的北西向造山带。杂岩带主要由各种类型的副片麻岩、片岩、石英岩、大理岩和斜长角闪岩构成,岩石发生强烈的糜棱岩化。本文在哀牢山变质杂岩带东南段元江和金平地区以及大象变质杂岩带北段老街和Pho Rang地区发现了中二叠-早三叠世的斜长角闪岩。岩石地球化学和锆石U-Pb年龄研究表明,这些斜长角闪岩可分为4组:第1组为元江斜长角闪岩,具有类似于E-MORB的稀土和微量元素配分曲线特征,锆石U-Pb定年显示其原岩形成年龄为272.5±1.7Ma;第2组为勐桥-马鞍底斜长角闪岩,相比于元江斜长角闪岩(第1组)具有更高的轻/重稀土分馏程度,其稀土和微量元素配分曲线类似于E-MORB,微量元素比值(Nb/Yb、Th/Yb等)显示具有沿MORB-OIB序列演化的趋势,勐桥和马鞍底斜长角闪岩中的Ti含量和Ti/Y比值等特征分别类似于峨眉山低Ti玄武岩和高Ti玄武岩。锆石U-Pb定年结果表明,勐桥-马鞍底斜长角闪岩形成于265.2±1.0Ma~266.2±1.0Ma和250.4±1.5Ma~248.7±1.6Ma,其中晚期岩石中含有261.2±1.5Ma~257.9±1.6Ma的继承锆石,该年龄与峨眉山玄武岩(约260Ma)近于同期。上述证据表明勐桥-马鞍底斜长角闪岩岩浆演化过程中可能混染了部分具有OIB属性的峨眉山地幔柱物质成分;第3组为大象山老街-Pho Rang斜长角闪岩,具有类似于OIB的稀土和微量元素配分曲线特征,微量元素含量和比值(TiO2=3.28%~4.31%,Nb/La=0.84~1.01,Ti/Y>500等)特征显示与峨眉山高Ti玄武岩相似的地球化学属性,表明峨眉山玄武岩在哀牢山-大象山变质杂岩带内广泛分布,该岩石成分可能为勐桥-马鞍底斜长角闪岩(第2组)的端元组分之一;第4组为大象山Pho Rang斜长角闪岩,该组岩石具有与元江斜长角闪岩(第1组)相似的E-MORB属性特征。进一步的研究表明,哀牢山-大象山变质杂岩带中具有类似于E-MORB属性的斜长角闪岩均表现出不同程度的Nb、Ta元素亏损和Rb、Ba等大离子元素富集,微量元素比值(Nb/Yb(0.72~5.29),Th/Yb(0.11~0.87),La/Nb(0.91~8.83))等特征类似于岛弧玄武岩,这些特征指示其原岩岩浆可能是俯冲环境下地幔楔岩石部分熔融的产物。结合哀牢山-大象山变质杂岩带、哀牢山-马江缝合带以及扬子地块之间的时-空关系,本文推测哀牢山-大象山变质杂岩带内的E-MORB类型岩浆岩形成于东古特提斯支洋(即哀牢山-马江洋)向东的俯冲过程,其俯冲持续时间为中二叠-早三叠世(272~248Ma)。  相似文献   

4.
《International Geology Review》2012,54(13):1668-1690
The western Junggar Basin is located on the southeastern margin of the West Junggar terrane, Northwest China. Its sedimentary fill, magma petrogenesis, tectonic setting, and formation ages are important for understanding the Carboniferous tectonic evolution and continental growth of the Junggar terrane and the Central Asian Orogenic Belt. This paper documents a set of new zircon secondary ion mass spectrometry U–Pb geochronological and Hf isotopic data and whole-rock elemental and Sr–Nd isotopic analytical results for the Carboniferous strata and associated intrusions obtained from boreholes in the western Junggar Basin. The Carboniferous strata comprise basaltic andesite, andesite, and dacite with minor pyroclastic rocks, intruded by granitic intrusions with zircon secondary ion mass spectrometry U–Pb ages of 327–324 Ma. The volcanic rocks are calc-alkaline and show low high εNd(t) values (5.3–5.6) and initial 87Sr/86Sr (0.703561–0.703931), strong enrichment in LREEs, and some LILEs and depletion in Nb, Ta, and Ti. Furthermore, they also display high (La/Sm)N (1.36–1.63), Zr/Nb, and La/Yb, variable Ba/La and Ba/Th and constant Th/Yb ratios. These geochemical data, together with low Sm/Yb (1.18–1.38) and La/Sm (2.11–2.53) ratios, suggest that these volcanic rocks were derived from a 5–8% partial melting of a mainly spinel Iherzolite-depleted mantle metasomatized by slab-derived fluids and melts of some sediments in an island-arc setting. In contrast, the granitic intrusions represent typical adakite geochemical features of high Sr and low Y and Yb contents, with no significant Eu anomalies, high Mg#, and depleted εNd(t) (5.6–6.4) and εHf(t) (13.7–16.2) isotopic compositions, suggesting their derivation from partial melting of hot subducted oceanic crust. In combination with the previous work, the West Junggar terrane and adjacent western Junggar Basin are interpreted as a Mariana-type arc system driven by northwestward subduction of the Junggar Ocean, possibly with a tectonic transition from normal to ridge subduction commencing ca. at 331–327 Ma.  相似文献   

5.
在华北克拉通中部的山西云中山地区,新太古代花岗闪长质片麻岩中存在一些超镁铁质岩-镁铁质岩块及由斜长角闪岩、角闪变粒岩、石英岩和石榴夕线黑云片岩等岩石类型构成的变质表壳岩残片,其中的超镁铁质-镁铁质岩、斜长角闪岩和角闪变粒岩构成一套高镁火成岩组合。超镁铁质岩已变质为橄榄绿泥阳起片岩等岩石类型,呈变余斑状结构,橄榄石斑晶仍有保存;岩石SiO_2含量为39.22%~44.99%,Al_2O_3为8.82%~13.47%,Mg O为19.24%~22.13%,Na_2O+K_2O=0.71%~1.11%,CaO为5.75%~8.42%;Al_2O_3/TiO_2=14.8~17.4,CaO/Al_2O_3=0.60~0.84;化学成分上与科马提岩有一定的相似性。与之紧密伴生的斜长角闪岩也具有高镁特征,Mg O含量为11.28%~15.09%,铝、硅和碱质均偏低,具正铕异常,显示堆晶辉长岩的特征。非高镁斜长角闪岩有相对高的铝、硅和碱质,其原岩应为钙碱性玄武岩。角闪变粒岩样品的SiO_2含量为54.21%~55.71%,Al_2O_3为14.24%~15.49%,Mg O为6.26%~8.28%,Fe OT/Mg O=1.11~1.58,高钠低钾,Na_2O+K_2O=3.7%~4.78%,Na_2O/K_2O=5.15%~13.13,Mg#=53.0~61.5,属于高镁安山岩。由超镁铁质质岩-斜长角闪岩-角闪变粒岩构成的变质高镁火山岩组合具有钙碱性系列趋势。超镁铁质岩稀土元素含量总量较低,具有轻稀土富集和重稀土亏损的稀土型式;斜长角闪岩与超镁铁质岩比较,除富集大离子亲石元素和Cr、Ni明显较低外,具有相似的微量元素图谱形态。三种岩石类型在微量元素蛛网图上均显示出Ta、Nb、Ti负异常和Pb正异常。野外产状和岩石地球化学特征表明超镁铁质岩和高镁斜长角闪岩属于阿拉斯加型杂岩体,角闪变粒岩属于赞岐岩质高镁安山岩。在Zr/Nb-Nb/Th和Nb/Y-Zr/Y构造环境判别图解上显示出与俯冲相关的演化趋势,在Hf-Th-Ta、Nb/La-(La/Sm)N和Th/Yb-Nb/Yb图解上也落在岛弧钙碱性岩石区域。以上特征表明高镁火成岩组合形成于与板块俯冲相关的岛弧构造背景。野外地质关系和锆石U-Pb年龄限定高镁火成岩组合形成时代在~2.5Ga。云中山地区阿拉斯加型镁铁质-超镁铁质杂岩与赞岐岩质高镁安山岩共生,表明该地区存在新太古代的板块俯冲作用,为太古宙存在板块构造机制提供了新证据。  相似文献   

6.
<正>The Hadamiao granodiorite,located on the northern margin of the North China platform and acting as the country rock of gold deposits in the Hadamiao region,was formed in the same age and similar tectonic settings with the Hadamiao gold deposit and the large-scale Bilihe gold deposit in the same area.By using the LA-ICP-MS method,the U-Pb age obtained is 267±1.3 Ma,which represents the crystallized age of the granodiorite,and that of the xenolithic zircon is 442.8±5 Ma. Base on the main elements,it exhibits the features of calc-alkaline to high-potassium calc-alkaline series,low silicon,and quasi-aluminous I-type granites,and with high magnesium(Mg~#=0.45-0.57) and high sodium contents(Na_2O/K_2O=0.98-2.29).The SREE values(81.6-110.15 ppm) are relatively low,the fractionations between LREE and HREE are obvious,showing a right-inclined dispersion in the REE distribution diagram.Compared with the primitive mantle,the rock is relatively rich in LREE(La and Ce),LILE(K,Sr,and Th),and intensively depleted in HFSE(Ti,P,Nb and Ta).The ratios of Sr/Y and(La/Yb)_N and the contents of Rb,Nb and Y are relatively low,the Sr values are high (436.35-567.26 ppm),and the Yb contents of most samples are low(1.25-1.8),which indicate the features of typical continental margin arc and adakitic rocks.According to the values ofε_(Nd)(t)(-2.4 to +0.2) and I_(Sr)(0.7028-0.7083),and variations of the La/Sm ratios,the Hadamiao granodiorite was formed from mixing of the thickened molten lower crust and the mantle wedge substances.The rock was related to the southward subduction and accretion of the Paleo-Asia Ocean in the Late Paleozoic, being Late Paleozoic magma of the continental margin arc formed on the basement of the Early Paleozoic accretion complexes,and showing a trend of turning into adakitic rocks,which indicates their great metallogenic(Au) potential.  相似文献   

7.
广西那龙地区中三叠世火山岩地球化学特征及构造意义   总被引:6,自引:0,他引:6  
右江盆地西南缘广泛出露早—中三叠世火山岩,目前对这些火山岩没有精确的年代学和地球化学研究。本文选择广西那坡县那龙地区下三叠统罗楼组与中三叠统百逢组之间的一套厚层状分布的火山岩作为研究对象,对其进行了LA-ICP-MS锆石U-Pb同位素定年、锆石主微量元素及全岩的地球化学研究。锆石206Pb/238U同位素年龄为241.2±1.9Ma(MSWD=0.69),代表火山岩的结晶年龄。锆石稀土元素总量较高,富集重稀土元素,具有明显Eu负异常及Ce正异常,含有较低的Th、Th/U、Ce/Sm和δEu值及相对较高的Hf、Yb/Gd和U/Ce值,指示原岩岩浆源区有地壳熔体的组分。火山岩全岩SiO2含量为51.28%~56.17%,并显示低TiO2含量(0.79%~1.28%)和高Al2O3含量(13.52%~15.51%)的特征。稀土元素地球化学特征表现为Eu负异常(δEu=0.60~0.71),富集大离子亲石元素(Rb、Cs、Ba、U、Sr、Pb、Th、K)和轻稀土元素而亏损高场强元素(Nb、Ta、Zr、Hf、P、Ti)及重稀土元素,与岛弧火山岩的特征一致。Ce/Pb及Nb/U值接近大陆地壳,Zr/Y值和Zr含量偏高,表明原始岩浆源区可能为地壳熔体和俯冲洋壳熔体组成的混合物,岩浆在形成上升过程中有深海沉积物或地壳物质的加入,岩石成因与俯冲作用有关。但Ba/Th值(2.92~69.75)小于300,表明原始岩浆在上升过程中受到流体混染的程度比较小。结合前人研究成果可得出,广西那龙中三叠世岛弧火山岩的发现,代表早中生代古特提斯洋东延部分存在一个俯冲消减带。  相似文献   

8.
内蒙古西乌旗地区出露一些石英闪长岩,其LA-ICP-MS锆石U-Pb年龄为(304.64±0.82)Ma和(309.84±0.86)Ma,表明这套岩石形成于晚石炭世。地球化学分析表明,西乌旗地区石英闪长岩属于低Ti O2和高Al2O3钙碱性玄武岩系列;富集Rb、Ba、K大离子亲石元素(LILE),亏损Nb、Ta、Ti、P等高场强元素(HFSE),具有典型弧岩浆岩的特征,显示岩浆源区曾经历过俯冲带流体的交代作用;稀土元素丰度偏低,呈LREE富集HREE亏损的右倾模式;强不相容元素比值(La/Nb、La/Ta等)及判别图解表明晚石炭世石英闪长岩类似大陆边缘弧玄武岩,岩浆来源于浅部岩石圈地幔,系石榴石+尖晶石二辉橄榄岩源区中等程度(10%~20%)部分熔融的结果。综合研究区样品的地球化学特征,结合区域地质资料及对比分析前人成果,认为早石炭世末期西乌旗地区在强烈拉张的裂谷环境下形成了有限洋盆,由于洋盆发育不成熟或边伸展边向两侧俯冲—消减,形成了西乌旗地区类似大陆边缘弧玄武岩特征的晚石炭世石英闪长岩。  相似文献   

9.
ABSTRACT

We present the major and trace elements and Sr, Nd, and Pb isotopes in mid-ocean ridge basalts (MORB) from the East Pacific Rise (EPR) at 2.6–3.1°S. These samples are low-K tholeiites and show significant variation in their major element compositions (e.g. 4.60–8.18 wt% MgO, 8.34–12.12 wt% CaO, 9.78–14.25 wt% Fe2O3, and 0.06–0.34 K2O wt%). Trace element abundances of the 2.6–3.1°S MORB are variably depleted (e.g. (La/Sm), N = 0.51–0.78, Zr/Y = 2.35–3.42, Th/La = 0.035–0.056, and Ce/Yb = 2.38–3.96) but closely resemble the average N-MORB. In the compatible elements (Ni and Cr) against incompatible element Zr plots, the 2.6–3.1°S MORB show well-defined negative correlations, together with a liquid line of descent (LLD) modelling and petrographic observations, implying a significant role of olivine, plagioclase and clinopyroxene fractionation during magma evolution. When compared to global MORB and peridotites, the 2.6–3.1°S MORB and most of the other axial lavas from the South EPR show similar Zn/Fe, Zn/Mn, and Fe/Mn ratios, attesting to a peridotite-dominated mantle lithology. However, the relationships between incompatible trace element ratios, such as Zr/Rb and Nb/Sm, and the negative correlation between Zr/Nb and 87Sr/86Sr indicate a geochemically heterogeneous mantle source. The mantle beneath the South EPR likely consists of two components, with the enriched component residing as physically distinct domains (e.g. veins or dikes) in the depleted peridotite matrix. In the Sr–Nd–Pb isotope space, the South EPR MORB lie along the mixing lines between the depleted MORB mantle (DMM) and the ‘C’-like Pukapuka endmember. We infer that low-F melts derived from these enriched materials may cause localized mantle heterogeneity (veins or dikes) via an infiltration process. Subsequent melting of the refertilized mantle may impart an isotopically distinct characteristic to South EPR MORB.  相似文献   

10.
李平  王洪亮  徐学义  陈隽璐  过磊  奚仁刚 《岩石学报》2014,30(12):3553-3568
新疆西准噶尔北部地区的早泥盆世马拉苏组出露有少量富钠低钾的拉斑质中基性熔岩,这些分布于谢米斯台断裂北侧的玄武安山岩和玄武岩多呈夹层状断续产出于火山碎屑岩之中。马拉苏中基性熔岩的Mg#与主、微量元素协变关系及Th-Th/Nd图反映了其并非同源岩浆演化的结果。马拉苏火山岩中的玄武安山岩富集LILE、亏损HFSE,具有较高的Th含量及较低的Hf/Th和(Nb/Th)PM比值,显示出弧火山岩的地球化学特征。其中的玄武岩则具有略为平坦的稀土元素分配样式,较低的Th含量及较高的Hf/Th和(Nb/Th)PM比值,此同MORB地球化学特征极为相似;虽然其也显示有轻微的LILE富集、HFSE亏损,但是较高的La/Nb比值则暗示这同地壳或俯冲物质组分的卷入有关,且一系列构造环境判别图解也进一步印证了马拉苏组内的玄武岩应属似MORB基性熔岩。此外,两类岩石的高场强元素比值Zr/Nb、Hf/Ta同全球平均大洋中脊玄武岩的相应比值极为接近,反映了马拉苏组中基性火山岩的物质源区主体均为MORB地幔物质源区。La/Yb-Gd/Yb原始地幔标准化比值的模拟计算进一步显示了马拉苏组玄武安山岩与受改造(俯冲沉积物或地壳物质的混染)的石榴子石或尖晶石-石榴子石地幔橄榄岩物质源区的部分熔融作用有关,而似MORB型玄武岩则源自尖晶石地幔橄榄岩源区的部分熔融。结合区内同期的蛇绿岩、火山岩和碱性花岗岩的地球化学研究,我们可以进一步推断此类兼具有似MORB和弧火山岩地球化学特征的早泥盆世马拉苏火山岩应当是西准噶尔地块北部在早古生代受后期俯冲作用影响下经历弧后扩张形成的火山-岩浆地质记录。  相似文献   

11.
温德娟 《地质通报》2019,38(10):1711-1717
太古宙TTG岩石的成因及年代学研究是理解前板块构造和板块构造开始及其演化过程的关键,是陆壳增生的重要标志,为太古宙地质体研究的热点和难点之一。对鞍山地区的白家坟岩体进行了地球化学研究和锆石U-Pb测年。数据结果显示,该岩体具有正片麻岩特征,Si、Na含量高,TFeO、MgO、CaO含量低,轻、重稀土元素分异程度低,且具有一定变化。稀土元素总量偏低(12.6×10~(-6)~119.34×10~(-6)),LREE/HREE值为8.98~13.11。微量元素富集K、Rb、Ba,亏损Nb、Ce、Zr、Sm、Ti、Y、Yb;K/Rb平均值为229.37,Rb/Sr平均值为0.58,Ba/Sr平均值为3.28,Y/Nb平均值为3.36。表明该岩体为岩浆作用的产物,也有部分为壳内再循环的产物或受到陆壳物质影响。测得~(207)Pb/~(206)Pb年龄加权平均值为3816±14Ma,锆石具有清晰的振荡环带结构,所有核部锆石分析点的Th/U值在0.05~0.54之间,具有岩浆锆石的特点,代表了白家坟奥长花岗质岩石的结晶时代。3613~3651Ma和3331Ma两组年龄数据代表早太古代的一次岩浆事件及重要的陆壳增生时期的热事件。  相似文献   

12.
永新金矿是近年发现的大型蚀变岩型脉状金矿床,闪长玢岩脉等与金矿脉相互穿切并侵入于上盘龙江组火山岩中。锆石LA ICP MS U-Pb测年显示,龙江组安山岩结晶年龄为(1137 ± 18)Ma,闪长玢岩结晶年龄为(1148 ± 19)Ma,均形成于早白垩世晚期。二者钠钾含量变化相对较大,相对富铝富铁、钙镁含量中等,从火山岩到脉岩表现为钙碱性向碱性系列过渡特征。火山岩、脉岩与矿石的稀土元素配分曲线有很好的一致性,矿石稀土含量低于岩石。岩石微量元素总体显示Zr、Hf、Nd、U等明显富集,而Nb、Ta、Th、P、Ti等明显亏损。在Sr/Y-Y和(La/Yb)N-(Yb)N图解中,所有样品均落入经典岛弧岩石范围;在Nb-Y、Ta-Yb的构造环境判别图中均处于火山弧岩浆岩区,在(La/Yb)N-δEu变异图上落在壳-幔型岩浆范围。结合矿床稳定同位素及区域金矿时空分布规律等综合特征,认为永新金矿的形成与早白垩世古太平洋板块俯冲所引发的(火山)岩浆活动有关。  相似文献   

13.
The regular variations in magmatic activities along the Northwest Pacific plate have been little studied in spite of their importance. In this contribution, systematic analyses were conducted on tholeiitic basalts from three Ocean Drilling Program sites (Sites 304, 1149, and 801), including the petrographic features, major and trace elements, Nd isotopic compositions, and mineral structure and compositions of whole rocks. Volcanic rocks from Sites 304, 1149, and 801 belong to tholeiites and exhibit depleted light rare earth elements (LREE), large ion lithophile elemental contents (LILE), and relatively depleted Nd isotopic ratios (143Nd/144Nd=0.513139–0.513211), similar to those of normal mid-ocean ridge basalts (N-MORB). Comprehensive data on mineral compositions, whole-rock geochemistry, and geochronology demonstrate that a regular variation trend exists in the north-south direction along the Northwest Pacific plate. The 143Nd/144Nd values (0.513139–0.513211) and trace-element ratios for whole rocks (Sm/Th=15.35–30.00; Zr/Hf=28.53–35.76; Zr/Y=2.58–3.67; Th/La=0.04–0.06; Th/Y=0.33–0.70), as well as the trace-element ratios (Zr/Hf, La/Yb, Ti/Zr) of clinopyroxenes from Sites 1149 and 801 tholeiites show larger variations compared to those from Site 304 tholeiites (143Nd/144Nd=0.513185–0.513195; Sm/Th=18.19–20.58; Zr/Hf=31.07–33.26; Zr/Y=2.62–3.03; Th/La=0.05–0.06; Th/Y=0.48–0.57). Mineral zoning textures were obvious in tholeiites from Sites 1149 and 801 but were rarely observed in Site 304. These regular features were likely attributed to the differences in the heterogeneity of the magma source, the process of magmatic evolution, the plate-spreading rate, and the effective and ineffective mixing.  相似文献   

14.
The Roshtkhar area is located in the Khaf-Kashmar-Bardaskan volcano-plutonic belt to the northeastern Iran along the regional E–W trending Dorouneh Fault, northeastern of the Lut Block. There are several outcrops of subvolcanic rocks occurring mainly as dikes in the area, which intruded into Cenozoic intrusive rocks. We present U–Pb dating of zircons from a diabase dike and syenite rock using LA-ICP-MS that yielded an age of 1778 ± 10 Ma for the dike, indicating this Cenozoic dike has zircon xenocrysts inherited from deeper sources; and 38.0 ± 0.5 Ma, indicating an Late Eocene crystallization age for the syenite. Geochemically, the dikes typical of high-K calc-alkaline to shoshonitic magmas. Petrographic observations and major and trace element variations suggest that diabase melts underwent variable fractionation of clinopyroxene, olivine, and Fe-Ti oxides and minor crustal contamination during the differentiation process. Primitive mantle-normalized multi-element diagrams display enrichment in LILE, such as Rb, Ba, Th, U, and Sr compared to HFSE, as well as negative anomalies of Nb, Ta, P, and Ti, suggesting derivation from subduction-modified mantle. Chondrite-normalized REE plots show moderately LREE enriched patterns (<3.83 LaN/YbN <8.27), and no significant Eu anomalies. Geochemical modelling using Sm/Yb versus La/Yb and La/Sm ratios suggests a low-degree of batch melting (~1–3%) of a phlogopite-spinel peridotite source to generate the mafic dikes. The geochemical signatures suggest that the Roshtkhar mafic dikes cannot be related directly to subduction and likely resulted from melting of upper mantle in an extensional setting where the heat flow was provided from deeper levels. These dikes presumably derived the zircon xenocrysts from the assimilation of upper crust of Gondwanian basement. Processes responsible for partial melting of metasomatized lithospheric mantle and post-collision magmatism in NE Iran was triggered by heating due to asthenospheric upwelling in an extensional setting.  相似文献   

15.
鄂西黄陵背斜南部元古宙庙湾蛇绿岩的发现及其构造意义   总被引:2,自引:1,他引:1  
对鄂西黄陵背斜南部宜昌太平溪、邓村一带崆岭岩群中的元古宙庙湾岩组强烈变形变质超镁铁—镁铁质岩的研究表明,镁铁质岩主要为似层状细粒斜长角闪岩,变辉长岩岩体、岩脉及辉绿岩岩脉,超镁铁质岩则主要为蛇纹石化纯橄榄岩、方辉橄榄岩,呈构造岩片、岩块分布于斜长角闪岩之中。细粒斜长角闪岩TiO2=1.14%~1.48%,稀土元素配分型式为略亏损—平坦型,无明显的Eu异常,(La/Yb)N=0.87~1.12,La/Nb、Ce/Zr、Zr/Nb、Zr/Y、Ti/Y平均值分别为1.04、0.15、18.78、2.53、290.51,Nb/Th平均为9.88,显示为大洋中脊构造环境形成的N-MORB型拉斑玄武岩;变辉长岩具典型的堆晶结构特征,稀土元素配分型式为平坦型,具明显的Eu正异常;蛇纹石化纯橄榄岩的稀土元素配分型式具中稀土元素略亏损的U形特征,显示为LREE略富集的地幔岩。上述特征表明,黄陵背斜南部崆岭岩群中的元古宙庙湾岩组实际上是一套混杂堆积的古大洋蛇绿岩残片。元古宙庙湾蛇绿岩的发现为华南扬子克拉通存在中元古代洋盆和哥伦比亚超大陆聚合、裂解构造事件提供了重要的证据。  相似文献   

16.
东南沿海分布大面积的白垩纪晚期侵入岩。这些岩石可分为两期:其中115~100Ma以钙碱性系列岩石为主,岩石组合为辉长岩-闪长岩-花岗闪长岩-二长花岗岩-碱性长石花岗岩;而100~86Ma的岩石为碱性系列,岩石组合为石英二长斑岩-正长斑岩-碱性长石花岗岩。115~100Ma的辉长岩以角闪辉长岩为主,具有极高的CaO、MgO和Al_(2)O_(3)含量,具有极低的SiO_(2)(42.9%~53.8%)、全碱(K_(2)O+Na_(2)O:0.86%~5.28%)、Ba、Nb、Th、Rb和Zr含量,也具有极低的FeO^(T)/MgO、La/Yb和Zr/Hf比值,较高的Eu/Eu^(*)、Sr/Y比值和Sr含量,为基性-超基性堆晶岩。与辉长岩同期的闪长岩和细粒暗色包体具有较高的SiO_(2)(50.34%~63.68%),较低的CaO、P_(2)O_(5)、MgO、Al_(2)O_(3)含量,相对低的Eu/Eu^(*)和Sr/Y比值,变化较大的La/Yb和Zr/Hf比值,代表了从基性岩浆储库中抽取的富硅熔体。115~100Ma的花岗闪长岩和二长花岗岩类岩石为准铝质岩石,SiO_(2)含量变化较大(61.7%~75.3%),具有较低的FeO^(T)/MgO、Ga/Al比值和Nb、Zr及Nb+Zr+Ce+Y元素含量,显示出典型I型花岗岩的特征。这些花岗岩具有相对高的La/Yb、Eu/Eu^(*)和Zr/Hf比值和高的Sr、Ba和Zr含量。结合岩相学特征,这些花岗岩为堆晶花岗岩。而115~100Ma的碱性长石花岗岩具有极高的SiO_(2)含量(大于75%),低的Eu/Eu^(*)、La/Yb、Zr/Hf和Sr/Y比值,具有低的Ba、Sr和Zr含量和高的Rb、Nb、Y和Th含量和Rb/Sr比值,表明这些花岗岩是由富硅岩浆储库中抽离的高硅熔体侵入地壳形成。100~86Ma期间形成的二长斑岩和正长斑岩具有极高的全碱含量,可以达到8%~12%,其SiO_(2)主要集中在60%~70%,具有极高的Zr、Sr和Ba含量和Eu/Eu^(*)、La/Yb和Sr/Y比值,显示出堆晶花岗岩的特征。而100~86Ma期间形成的大部分碱性长石花岗岩具有极高的SiO_(2)含量(大于75%),并显示出A型花岗岩的特征,具有高的Rb/Sr比值和高的Rb、Y和Th和低的Ba、Sr含量和低的Zr/Hf、La/Yb、Eu/Eu^(*)和Sr/Y比值,表明它们是由富硅岩浆储库抽离的高硅熔体侵入浅部地壳形成。东南沿海高硅花岗岩的形成和穿地壳岩浆系统密切相关,高硅花岗岩是由浅部地壳内晶体-熔体分异产生的熔体侵入地壳所形成,而高硅花岗岩的地球化学特征与岩浆储库的水及挥发份含量密切相关。115~100Ma期间,从富水的岩浆储库抽离的熔体形成具有低高场强元素含量和低Rb/Sr比值的高硅花岗岩,这一过程与古太平洋板块俯冲有关;100~86Ma期间,从富挥发份的岩浆储库抽离的熔体形成碱性特征、富含高场强元素和具有高的Rb/Sr比值的高硅花岗岩,这一过程和古太平洋板块回撤软流圈上涌有关。  相似文献   

17.
新疆东天山中北部的卡拉塔格地区广泛出露一套二叠纪陆相火山熔岩,本次对其采集的玄武岩和英安岩进行岩相学、锆石U-Pb定年、Lu-Hf同位素和岩石地球化学分析。年代学研究获得2个英安岩样品LA-ICP-MS锆石U-Pb加权平均年龄为(267.5±1.5)Ma和(296.7±1.7)Ma,代表了英安岩的结晶年龄为早二叠世。岩石地球化学数据显示:玄武岩为碱性系列,具有高Al2O3质量分数和Na2O/K2O值,低TFeO、Cr质量分数和Mg#值的特征;微量元素Yb标准化的Ta、La和Nb值指示该区玄武质岩浆起源于富集型地幔;低La/Ba值,(Th/Nb)N>1,Nb/La<1,表明岩浆在上升过程中受到了地壳岩石圈物质的混染;样品w(Zr)>100×10-6,Zr/Y>5,显示大陆板内玄武岩特征。英安岩为钙碱性系列,富硅铝,Rb、Ba、Th、U、Zr等元素质量分数较高,Ti、Nb、Ta、Sr、P等元素质量分数较低,明显不同于玄武岩元素分布特征,却与地壳元素分布相似;εHft) 值(5.4~14.7)为正,表明英安岩源区为新生地壳;w(Rb)-w(Y+Nb)构造环境判别图解表明其形成于大陆伸展环境。结合前人的研究成果,认为卡拉塔格早二叠世火山岩形成于板内伸展环境,为天山石炭纪—二叠纪大火成岩省裂谷火山作用的组成部分,限定了该区古亚洲洋闭合于早二叠世之前。  相似文献   

18.
北秦岭新元古代前属于扬子板块的地球化学证据   总被引:18,自引:1,他引:17  
秦岭是扬子板块和华北陆块间的复合造山带,其中存在两个古缝合带,北面的新元古代到早古生代商-丹缝合带介于北秦岭和南秦岭之间,南面的晚古生代勉-略缝合带形成于南秦岭与扬子陆块北缘之间,属于确知的扬子陆块内部打开形成的类型。北秦岭在地壳增生历史,元古宙上地慢性质,以及元古宙以来地幔相对富Nb、Ta、Cu,高Rb/Sr、Ba/Sr、Ba/La、Th/La、Nb/Ta比值和相对贫Fe、Mo方面均与南秦岭和扬子陆块北段一致。而与华北板块南段明显不同。变玄武岩类的Pb同位素三维空间拓扑图和铀εNd(t)-206Pb/204Pb图显示,区域一级地球化学界面位于北秦岭与华北陆块的分界处,二级界面才是商丹-缝合带。构造侵位于该带中的松树沟蛇绿岩<1000 Ma士)中已发现并存着N—MORB和E—MORB型变拉斑玄武岩。表明它们的岩浆分别来自亏损地幔和深部地幔热柱源区。松树沟蛇绿岩与勉,略蛇绿岩中的N—MORB型岩石具有与此相似的同位素组成和特征元素对比值,暗示松树沟蛇绿岩所代表的古洋壳也应属于扬子板块内部型。加之,新元古代之前秦岭只存在裂谷系而无板块结合带,故可确定北秦岭原来应属于扬子板块的组成部分。对秦岭群和宽坪群变拉斑玄武岩及松树沟E—MORB和N—MIORB进行地球化学对比的结果,既能够支持北秦岭是在扬子板块的洋壳洋岛基础上发展形成的微陆块的推断,又可解释北秦岭幔源岩石具有特高Th/La、Yb/Hf、Sc/Th比值和壳幔更富于放射成因钳的原因。此外。对本研究结果在秦岭造山带发展动力学方面的意义也进行了初步讨论。  相似文献   

19.
New major and trace element data on the Proterozoic Chimalpahad layered anorthositic Complex and associated basaltic amphibolites of the Nellore Schist Belt of South India provide new constraints on their petrogenesis and geodynamic setting. The Complex consists of layered anorthosites, leucogabbros, gabbros, ultramafic rocks and is spatially associated with basaltic amphibolites. Despite deformation and metamorphism, primary cumulate textures and igneous layering are locally well preserved throughout the Complex. Whereas the amphibolites display diverse REE systematics, the Chimalpahad anorthositic–gabbroic rocks are characterized by moderately depleted to strongly enriched LREE patterns and by flat to depleted HREE patterns. The field relations, major and trace element compositions of the basaltic amphibolites suggest that they are petrogenetically related to the anorthositic–gabbroic rocks by fractional crystallization. The anorthositic rocks and the basaltic amphibolites share the depletion of Nb relative to Th and La on primitive mantle-normalized diagrams. They exhibit signatures of arc magmatic rocks, such as high LILE and LREE relative to the HFSE and HREE, as well as high Ba/Nb, Ba/Zr, Sr/Y, La/Yb ratios that mimic chondrite-normalized REE and primitive mantle-normalized trace element patterns of arc magmas. Similarly, on log-transformed tectonic discrimination diagrams, the Chimalpahad rocks plot within the field of Phanerozoic magmatic arcs, consistent with a subduction zone origin. On the basis of field relations and geochemical characteristics, the Chimalpahad Complex is interpreted as a fragment of a magma chamber of an island arc, which is tectonically juxtaposed against its original volcanic cover. A new preliminary Sm–Nd date of anorthosite from the Chimalpahad Complex indicates a model age of 1170 Ma.  相似文献   

20.
Zircon populations of Neoproterozoic and early Paleozoic age occur in metabasites of a high-pressure amphibolite-facies unit of the Austroalpine basement south of the Tauern Window. The host rocks for these zircons are eclogitic amphibolites of N-MORB-type character, hornblende gneisses with volcanic-arc basalt signature, and alkaline within-plate-basalt amphibolites. Bulk rock magmatic trace element patterns were preserved during amphibolite-facies high-pressure and subsequent high-temperature events, as well as a greenschist-facies overprint. Positive Ce and negative Eu anomalies and enrichment of HREE in normalized zircon REE patterns, as analysed by LA-ICP-MS, are typical for an igneous origin of these zircon suites. Zircon Y is well correlated to HREE, Ce, Th, U, Nb, and Ta and allows discrimination of compositional fields for each host rock type. Low Th/U ratios are correlated to low Y and HREE abundances in zircon from low bulk Th/U host rocks. This is likely a primary igneous characteristic that cannot be attributed to metamorphic recrystallization. Variations of zircon/host rock element ratios confirm that ionic radii and charges control abundances of many trace elements in zircon. The trace element ratios—presented as mineral/melt distribution coefficients—indicate a selectively inhibited substitution of Zr and Si by HREE and Y in zircon which crystallized from a N-MORB melt. Correlated host rock and zircon trace element concentrations indicate that the metabasite zircons are not xenocrysts but crystallized from mafic melts, represented by the actual host rocks.  相似文献   

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