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1.
藏南马扎拉金锑矿床成矿流体地球化学和成矿机制   总被引:4,自引:2,他引:2  
莫儒伟  孙晓明  翟伟  周峰  梁业恒 《岩石学报》2013,29(4):1427-1438
马扎拉是藏南金锑成矿带内最具有代表性的金-锑矿床.为了更直接地了解该矿床的流体物理化学特征,探讨成矿流体来源、成矿机制及其矿床类型,本文对该矿床中主要载金矿物辉锑矿及石英中的流体包裹体进行了显微测温研究.流体包裹体岩相学观察表明,辉锑矿及石英具有近乎相同的4类流体包裹体类型:富液两相水溶液包裹体、三相CO2-H2O包裹体、纯CO2包裹体和纯H2O包裹体.红外显微测温结果显示,辉锑矿中流体包裹体均一温度(Th)峰值为180 ~ 210℃,盐度峰值介于2.5%~3.4% NaCleqv,密度峰值在0.895~0.915g/cm3之间.石英中流体包裹体Th、盐度及密度均具有三个明显峰值,Th为270~300℃、225~255℃和180~ 210℃,盐度为4.3%~4.9% NaCleqv,3.4% ~4.0%NaCleqv和2.8% ~ 3.4%NaCleqv,密度为0.895 ~0.915g/cm3、0.835~0.855g/cm3和0.775~0.795g/cm3.对比辉锑矿和石英中流体包裹体测温结果可见,辉锑矿中流体包裹体Th和盐度比石英偏低,而密度较石英偏高,表明含金石英可能先于辉锑矿从成矿流体中沉淀,且辉锑矿大量沉淀成矿时可能不断有较低温、低盐度和较高密度流体混入.辉锑矿及石英中流体包裹体水的δDH2o为-68.1‰~-108‰,δ18OH2o为-2.2‰ ~ 12.2‰,在δD-δ18O投影图上主要位于变质水附近,个别样品靠近大气降水,表明成矿流体为变质水与大气降水的混合.石英中流体包裹体的δ13C为-2.9‰~-3.5‰,平均值为-3.1‰,落入幔源碳同位素组成范围(δ13C=-5‰~-2‰)之内,说明CO2可能主要为幔源,而辉锑矿中流体包裹体的δ13C为-12.6‰,明显小于幔源碳同位素组成,说明在辉锑矿成矿过程中可能有少量地层有机碳加入.马扎拉金锑矿床成矿流体具有富含CO2、低盐度、低密度和中低温度的特征,与造山型金矿成矿流体相似.地质和地球化学特征显示马扎拉金锑矿床为喜马拉雅期陆陆碰撞造山型金锑矿.  相似文献   

2.
湘中锑矿带中的渣滓溪锑钨矿床,是我国典型的大型脉状充填型锑矿床,前人对其成矿流体研究较少,该矿的矿石沉淀机制和成矿过程,目前尚不清楚。本次采用红外显微测温和传统显微测温相结合的方法,对渣滓溪矿区的白钨矿、辉锑矿及与其共生的石英中的流体包裹体,进行了系统的岩相学和显微测温研究。研究表明,该区矿物中发育的流体包裹体有四种类型,纯液相包裹体、富液相的气液包裹体、富气相的气液包裹体和纯气相包裹体。该区白钨矿中流体包裹体的均一温度为147~285℃,盐度为2.4%~6.0%NaCleqv,与其共生的石英中流体包裹体的均一温度为147~314℃,盐度为3.1%~6.2%NaCleqv;辉锑矿中流体包裹体的均一温度为124~269℃,盐度为0.4%~4.5%NaCleqv,与其共生的石英中流体包裹体的均一温度为114~298℃,盐度为0.2%~5.9%NaCleqv,成矿流体为一种中温、低盐度,以H2O为主的热水溶液。该区钨矿石中的白钨矿和石英、锑矿石中的辉锑矿和石英分别具有相似的均一温度和盐度。钨矿石和锑矿石具有不同的沉淀机制,前者是由于流体混合作用导致的,而后者则是由于流体沸腾引起的。湘西浅变质岩中的锑矿床和湘中碳酸盐岩中的锑矿床,两者锑矿石的形成过程与沉淀机制明显不同:前者的矿石矿物与脉石矿物的均一温度和盐度基本一致,是从同一溶液中沉淀的,流体沸腾作用导致锑矿石发生沉淀;而后者的矿石矿物与脉石矿物的均一温度和盐度明显有别,是不同流体作用的产物,锑矿石的形成是流体混合作用所致。  相似文献   

3.
黑龙江乌拉嘎金矿是我国陆相火山岩区的重要金矿之一。构造位置处于古亚洲构造域与滨太平洋构造域交接复合部位的东北缘,矿体主要分布于团结沟斜长花岗斑岩接触带部位的隐爆角砾岩带和黑龙江群变质岩的层间裂隙中。斜长花岗斑岩的石英斑晶中发育3类包裹体:熔体包裹体、原生的L-V包裹体(及少量的L-V-S包裹体)和次生的L-V包裹体。玻璃质熔体包裹体相当于酸性殘浆的成分(SiO2达69.5%~73.8%),其捕获温度大于800℃。石英斑晶中次生L-V包裹体均一温度集中在210~350℃、盐度5%~7%NaCleqv,代表了次火山岩浆热液的特征,与黄铁矿-早期白色玉髓状石英阶段中Q1的包裹体均一温度范围很接近,而盐度略高于白色玉髓状石英Q1的。乌拉嘎金矿的金成矿可划分3个成矿阶段,发育盐水溶液包裹体:(1)黄铁矿-早期白色玉髓状石英阶段,包裹体均一温度为154~355℃,集中在190~330℃,盐度为1.3%~8.2%NaCleqv,密度为0.53~0.88g/cm3。(2)烟灰色玉髓状石英-多金属硫化物阶段,石英中包裹体均一温度为159~196℃,集中在170~190℃,盐度为2.2%~3.2%NaCleqv,密度0.79~0.92g/cm3。(3)碳酸盐-石英阶段,方解石中包裹体均一温度集中在170~270℃;盐度0.5%~2.9%NaCleqv。成矿流体以中低温、低盐度、贫CO2的盐水体系为特征,与国内外陆相火山-次火山热液矿床十分相似。石英斑晶中熔体、流体包裹体及其共存反映了次火山岩浆活动晚期,由硅酸盐熔体通过不混溶产生含矿的盐水溶液的可能,说明了金成矿与斑岩的成因联系,乌拉嘎金矿应该属于陆相火山-次火山活动有关的中低温浅成热液金矿床。  相似文献   

4.
周超  孙骥  郭爱民  贾朋远  陆文  隗含涛  郭鼎  蔡毅 《中国地质》2020,47(4):1241-1259
古台山矿床和龙王江矿床是雪峰弧形构造带中段颇具代表性的石英脉型金锑矿床。古台山金锑矿床位于白马山复式岩体的外接触带,而龙王江金锑矿床则距离白马山岩体较远。本文从流体包裹体和氢氧同位素研究入手,讨论了成矿流体的特征、来源及其与成矿的关系。流体包裹体岩相学观察和显微测温表明,古台山矿床成矿期石英中包裹体以气液水两相包裹体和CO2-H2O三相包裹体为主,均一温度集中在199~298°C,盐度集中在2.07%~11.46%NaCleqv;龙王江矿床成矿期石英中包裹体以气液水两相包裹体为主,均一温度集中在164~238°C,盐度集中在1.40%~8.41%NaCleqv。氢氧同位素研究表明,古台山矿床成矿流体来源主要为岩浆水和变质水的混合流体;龙王江矿床成矿流体主要来源于变质水。根据流体包裹体岩相学观察,结合显微测温,认为流体不混溶是导致古台山矿区矿质沉淀的主要机制;而龙王江矿区矿质沉淀很可能是温度和(或)压力的变化,或大气降水的加入(混合)所导致。  相似文献   

5.
在总结狮子山铜矿床地质特征基础上,开展了流体包裹体岩相学、显微测温、成分分析等研究,结果表明狮子山铜矿成矿流体为H2O-NaCl体系,包裹体分三大类:含子矿物包裹体(S型)、液体包裹体(W型)和气体包裹体(V型)。S型包裹体为气液固三相包裹体,子矿物多为石盐,加热时常晚于气相均一为液相。均一温度范围广,在192~570℃之间,盐度在31.2%~69.63%NaCleqv之间,高温高盐度流体包裹体的存在说明有深源流体叠加;W型包裹体均一温度范围在98~583℃之间,盐度低至中等,在3.55%~22.98%NaCleqv之间;V型包裹体为高温(平均454℃)低盐度(平均9.54%NaCleqv)包裹体;矿区高温阶段不同相比的S型、V型、W型包裹体共生,且均一温度相同,说明成矿流体经过沸腾作用。  相似文献   

6.
应用红外显微镜和流体包裹体显微测温分析技术,对晴隆大厂锑矿床辉锑矿和萤石中的流体包裹体进行了对比研究。研究表明,该矿床辉锑矿与萤石中的流体包裹体类型、均一温度和盐度存在明显差异。辉锑矿中的流体包裹体以含子晶-气-液三相包裹体和气-液两相包裹体为主,具有较高的盐度(0.18%~19.45%Na Cleqv)和均一温度(153~285℃),并具有明显的正相关关系,而萤石则主要发育气-液两相流体包裹体,具有较低的盐度(0.18%~1.91%Na Cleqv)和均一温度(144~176℃),认为形成辉锑矿和萤石的成矿流体来自不同的源区,流体混合导致的温度和盐度降低可能是锑成矿的重要控制因素之一。辉锑矿硫同位素研究进一步揭示其成矿物质主要来自地幔,可能与晴隆地区及其外围的基性-超基性岩浆活动的地质背景有一定的成因联系。  相似文献   

7.
马扎拉Au-Sb矿床和沙拉岗Sb矿床是藏南金锑成矿带中典型的造山型矿床。马扎拉Au-Sb矿床中矿体以含金辉锑矿石英脉的形式产于下中侏罗统陆热组地层中,主要组成矿物有自然金、辉锑矿、石英和碳酸盐矿物;沙拉岗Sb矿床中矿体主要以辉锑矿石英脉的形式产于下白垩统多久组地层和辉长岩体中,主要组成矿物为辉锑矿、辰砂、锑华、石英和少量碳酸盐矿物。在两个矿床的矿脉石英和辉锑矿中均发现有三类原生和假次生包裹体:水溶液包裹体、CO2-水溶液包裹体和有机包裹体。流体包裹体显微测温结果显示:马扎拉Au-Sb矿床的成矿温度为160~280℃,沙拉岗Sb矿床的成矿温度为140~240℃。He-Ar同位素分析显示马扎拉Au-Sb矿辉锑矿石英脉矿石中辉锑矿和石英以及赋矿地层中沉积层状硫化物中黄铁矿的流体包裹体均具有低的3He/4He比值,分别为0. 01382~0. 05642Ra和0. 03353~0. 08744Ra,40Ar/36Ar比值具有比较大的变化范围,分别为346. 8~4770. 1和349. 4~2689. 1;沙拉岗Sb矿床中辉锑矿样品的3He/4He比值为0. 02385~0. 11488Ra,40Ar/36Ar比值变化小,为300. 6~537. 5。与藏南Au-Sb成矿带中造山型Au矿床成矿流体中含一定量的幔源挥发份相对比,马扎拉AuSb矿床和沙拉岗Sb矿床成矿流体中均无幔源流体的参与,马扎拉Au-Sb矿床成矿流体为壳源变质流体与改造型饱和大气水形成的混合流体;沙拉岗Sb矿床成矿流体以改造型饱和大气水为主,并有壳源变质流体的加入。  相似文献   

8.
新疆萨热阔布金矿床流体包裹体研究及矿床成因   总被引:2,自引:0,他引:2  
新疆萨热阔布金矿床位于阿尔泰造山带南缘克兰火山-沉积盆地内,矿体呈脉状产于康布铁堡组上亚组地层中(D1k2)。不同成矿阶段石英脉中广泛发育流体包裹体,可划分为H2O-CO2包裹体(C型)、纯CO2包裹体(PC型)、水溶液包裹体(W型)及含子矿物多相包裹体(S型)四类。测温结果显示,成矿早阶段主要发育C型和PC型包裹体,均一温度范围为271~446℃,流体盐度介于5.9%~8.4%NaCleqv之间;中阶段主要发育C、PC、W和S型包裹体,均一温度低于早阶段,为236~374℃,流体盐度介于4.8%~15.0%NaCleqv之间;晚阶段主要发育W型包裹体,均一温度范围为139~264℃,流体盐度介于1.1%~6.9%NaCleqv之间。对成矿压力和深度的估算表明,成矿压力为90~330MPa,成矿深度为9~12km。综上所述,萨热阔布金矿成矿流体具有富CO2、中低盐度的变质流体特征,流体沸腾导致了成矿物质的沉淀。结合矿床地质特征,萨热阔布金矿床属于造山型金矿床。  相似文献   

9.
利用红外显微镜对湖南瑶岗仙石英脉型黑钨矿矿床中共生的黑钨矿与石英原生流体包裹体均一温度和冰点的测定结果表明,石英中流体包裹体均一温度范围为149~352℃,主要集中在160~300℃之间,盐度w(NaCleq)为0.9%~9.5%;黑钨矿中流体包裹体均一温度范围为212~386℃,主要集中在280~360℃之间,盐度w(NaCleq)为4.5%~15.2%.可见,黑钨矿中流体包裹体具有更高的均一温度和盐度,与石英中原生流体包裹体均一温度相差可达60℃,盐度w(NaCleq)相差可达6%.结合该矿床的矿石显微结构特征、包裹体岩相学特征及前人所做的氢、氧同位素测试分析结果,推断黑钨矿主要形成于早期阶段,为均一流体冷却成因,石英形成较晚,主要为流体混合成因.  相似文献   

10.
江西香炉山矽卡岩型钨矿床流体包裹体研究   总被引:13,自引:5,他引:8  
从江西西北部至安徽南部发育一条显著的斑岩-矽卡岩型钨成矿带,香炉山是其中一典型的矽卡岩钨矿床。矿床具有明显的矿化分带特征,由近接触带矽卡岩和云英岩矿体和远接触带脉状石英-硫化物-白钨矿和透镜状矿体组成。通过对不同蚀变带上矿石矿物和脉石矿物的流体包裹体显微测温分析表明:矽卡岩中的流体包裹体的均一温度范围在209~383℃,脉状石英-白钨矿和石英-硫化物-白钨矿中流体包裹体的均一温度范围分别为163~278℃和204~284℃,晚期方解石脉的温度最低为143~235℃;矽卡岩中的流体包裹体的盐度范围在0.35%~5.26%NaCleqv,脉状石英-白钨矿和石英-硫化物-白钨矿中流体包裹体的盐度范围分别为0.35%~5.86%NaCleqv和0.70%~9.21%NaCleqv,晚期方解石脉的盐度为0.35%~2.07%NaCleqv。激光拉曼探针测试表明,矽卡岩、石英-白钨矿脉和石英-硫化物-白钨矿脉中流体包裹体组分主要为H2O,还含有一定量CH4和少量的N2。从早期到晚期成矿阶段表现为一个降温的过程,指明了钨成矿温度较宽泛;钨在流体中可能以钨酸的形式运移,与围岩反应时,温度降低和碱性升高,促使白钨矿沉淀成矿。早期到晚期成矿流体温度和物质组成发生变化是成矿发生分带的重要原因。  相似文献   

11.
红外成像无损检测技术基本原理及其应用范围   总被引:5,自引:0,他引:5  
红外检测技术是一门应用范围极广的技术,它不仅在军事上应用广泛,近年来在民用工程技术也得到了进一步发展,文章着重介绍红外成像无损检测的基本原理、应用范围及检测技术。  相似文献   

12.
石英是原生银矿床银的主要载体矿物。通过对山门银矿床石英的红外光谱、热释发光,X射线衍射、原子吸收光谱及电镜能谱能谱等分析测定,研究了石英的含银性与包裹体CO2和H2O的相对吸光度漳,含银性与石英热光曲线、晶胞参数及杂持含量间关系,给出了石英含矿性的谱学找矿标志。  相似文献   

13.
流体包裹体是古地质流体的唯一直接记录,为反演地质过程涉及的物理化学条件等提供了最为重要的证据。流体包裹体是研究热液矿床成矿流体最有利手段,常规的测试对象为透明的脉石矿物,而矿石矿物中的流体包裹体更为直接、准确地记录了成矿流体信息。大多数矿石矿物在显微镜透射光下不透明,其捕获的流体包裹体研究需要使用配备有红外成像系统的显微镜进行。近20 年来,不透明矿物流体包裹体红外显微测温研究获得了长足的进展,但其中仍有一些问题尚未解决,制约了该方法的应用;同时,国内该研究领域正处在起步阶段,多个实验室已安装了红外测试仪器,但尚未开展系统的研究工作。因此,需要对该研究领域进行综述,探讨存在的问题,以促进该研究方法的发展。本文首先介绍了红外显微镜仪器工作原理及样品制备注意事项,阐述了影响不透明矿物红外透明度的因素,讨论了红外显微测温研究中的主要问题和难点,并针对测温过程中相变观察困难、红外光可能影响测温结果等问题提出可行的解决方案,最后论述了红外显微测温系统在矿床学领域的应用前景。  相似文献   

14.
应用富时叶变换红外谱仪研究了三个启三绿柱石样(包括原样与热处理)。将3435cm^-1宽吸收带归属于与铁离子成键的水。谱图表明隧道水的大量脱去是在800℃以上的温度开始的,对于富碱样品,更可能是在1000℃以后开始。隧道中碱金属离子的阻塞作用是造成绿柱石隧道水难以失去的重要原因.  相似文献   

15.
Powder infrared spectroscopy and X-ray diffraction techniques on single crystals were used to study the thermal behaviour of malayaite, CaSnSiO5. Infrared spectra show a discontinuity in the temperature evolution of phonon frequencies and absorbance near 500 K. However, crystal structure data collected at 300, 450, 550, 670, and 750 K show no evidence of a symmetry-breaking phase transition and no split positions. The most obvious change with heating is a tumbling motion of the SnO6 octahedra and an increase of the anisotropic displacement factors of Ca. The thermal evolution of the mean-square vibrational amplitude of the Ca atom shows a pronounced change in slope near 500 K. The evidence suggests that the 500 K anomaly in malayaite is more similar in character to the 825 K (β-γ) transition as opposed to the 496 K (α-β) transition in synthetic titanite. Received: 26 March 1998 / Revised, accepted: 23 December 1998  相似文献   

16.
Short-wave infrared (SWIR) reflectance spectroscopy was used to characterize hydrothermal minerals and map alteration zones in the Tuwu Cu–Au deposit, Xinjiang, China. The Palaeozoic hydrothermal system at Tuwu is structurally controlled, developed in andesitic volcanic rocks and minor porphyries. Hydrothermal alteration is characterized by horizontally zoned development of quartz, sericite, chlorite, epidote, montmorillonite and kaolin about individual porphyry dykes and breccia zones, as is shown by changes outward from a core of quartz veining and silicification, through an inner zone of sericite + chlorite to a marginal zone of chlorite + epidote. The alteration system comprises several such zoning patterns. Silicification and sericitization are spatially associated with Cu–Au mineralization. Zoning is also shown by compositional variations such that Fe-rich chlorite and Al-rich sericite occur preferentially toward the core and the most intensely altered parts, whereas Mg-rich chlorite and relatively Al-poor sericite are present on the margin and the relatively weakly altered parts of the hydrothermal alteration system. The compositions of chlorite and sericite, therefore, can be potentially used as vectors to Cu–Au mineralization. Montmorillonite and kaolinite, of probable weathering origin, are located near the surface, forming an argillic blanket overlying Cu–Au mineralization. Sporadic montmorillonite is also present at depth in the hydrothermal alteration system, formed by descending groundwater. Presence of a well-developed kaolinite-bearing zone on the surface is an indication of possible underlying Cu–Au mineralization in this region. Epidote occurs widely in regional volcanic rocks, as well as in variably altered rocks on the margin of the hydrothermal mineralization system at Tuwu. The widespread occurrence of epidote in volcanic country rocks probably reflects a regional hydrothermal alteration event prior to the localized, porphyry intrusion-related hydrothermal process that led to the Cu–Au mineralization at Tuwu.  相似文献   

17.
The theoretical infrared (IR) and Raman spectra of bayerite (β-Al(OH)3) are computed in the density functional theory framework, using the linear response theory. The results are consistent with the occurrence of six non-equivalent OH groups in a bayerite structure with space group P21/n. Similar to gibbsite, the transmission powder IR spectrum of bayerite in the region of the OH stretching bands is found to depend on the shape of particles. In particular, the broadening of the strong band observed at about 3,460 cm−1 in the spectrum of Al hydroxides is related to the electrostatic charges occurring at the surface of the polarized dielectric particles. The experimental correlation observed between the shape of this band and morphological parameters has therefore a physical, instead of chemical, origin.  相似文献   

18.
The kinetics of hydrogen diffusion in enstatite was studied by hydrogen–deuterium exchange experiments in the range of 1–5,000 bar and 700–850°C using synthetic single crystals of pure and Cr-doped enstatites. The OH- and OD-content in the samples was quantified after each thermal treatment with Fourier transformed infrared spectroscopy. H–D-exchange rates were measured parallel to the three crystallographic axes. In addition, in order to visualize diffusion profiles, OH and OD were mapped for some samples, utilizing synchrotron IR micro-spectroscopy. Hydrogen self-diffusivities derived from D/H exchange experiments at one atmosphere are very similar to the chemical diffusivity of hydrogen in natural Fe-bearing orthopyroxene, which was reported previously (Stalder and Skogby 2003) to exhibit a small, but significant anisotropy (D[001] > D[100] > D[010]). Activation energies are estimated to be 211 (±31) kJ/mol for diffusion parallel [100] and 185 (±28) kJ/mol for diffusion parallel [010]. Lattice diffusion of hydrogen is decelerated by more than one order of magnitude when Cr is dissolved in enstatite. In comparison to the chemical composition, pressure seems to have only a minor influence on hydrogen diffusion. Compared to other minerals in the Earth’s upper mantle, enstatite exhibits the highest activation energy for hydrogen diffusion, suggesting faster diffusion than in other mafic minerals at mantle temperatures, but slower diffusion at crustal conditions. Thus under upper mantle conditions, physical properties that are expected to be influenced by hydrogen mobility, such as electrical conductivity, may in enstatite be more intensely affected by the presence of hydrogen than in other upper mantle minerals.  相似文献   

19.
Infrared microthermometry of opaque minerals has revealed that temperatures of phase changes vary with the infrared light source intensity, resulting in an overestimate of fluid salinities and an underestimate of homogenization temperatures. Failing to recognize this analytical artifact during infrared microthermometry may result in meaningless geological models. A fluid inclusion investigation on enargite from a high-sulfidation epithermal deposit is used as an example to document this. Fluid salinities obtained during an early investigation ranged between 6.3 and 20.4 wt.% NaCl, which were interpreted as intense boiling or as evidence for the involvement of a magmatic brine during ore formation. Fluid inclusion salinities obtained with improved analytical settings, i.e. low light intensities, fall between 1.1 and 1.7 wt.% NaCl and are in better agreement with fluid salinities obtained in quartz from similar deposits, and recent modeling suggesting vapor transport of Au and Cu from deep porphyry-Cu environments to shallower high-sulfidation epithermal deposits.  相似文献   

20.
莫来石在电子,光学和高温结构中的应用已广泛以受到关注。本文介绍了以电子基板材料和红外辐射材料为应用背景下,有关莫来石基陶瓷的组成与性能间的关联研究,显示了新型莫来石材料在这些应用领域的潜在优良和良好的应用前景。  相似文献   

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