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1.
山东滕州西公桥遗址人骨的稳定同位素分析   总被引:8,自引:3,他引:8       下载免费PDF全文
文章应用稳定同位素C和N分析的方法,研究了山东滕州大汶口文化时期西公桥遗址先民的食谱,试图揭示该遗址先民生活方式、社会经济结构的变化。总体而言,该遗址样品保存较差,骨中骨胶原的含量较低,以C/N摩尔比作为标准,仅有8个样品属于未污染样品,可用作食谱分析。对样品进行稳定同位素C和N分析,结果表明:该遗址先民均为稻、粟混食,但在肉食资源获取上有所不同。以C3为主的先民,具有较低的δ15N;而以C4类为主的先民,δ15N值较高。在该遗址的发展过程中,人们的食物结构发生了一定的变化。  相似文献   

2.
X射线荧光光谱法测定土壤样品中碳氮硫氯等31种组分   总被引:3,自引:3,他引:3  
利用新型的ZSX Primus Ⅱ型X射线荧光光谱仪采用粉末压片法直接测定土壤样品中的C、N、S、Cl等31种元素。各元素分析晶体为N采用RX45,C采用RX61,Na、Mg采用RX25,C1、S、P采用Ge,Si、Al采用PET,其余元素均采用LiF200。结果表明,方法的检出限、精密度和准确度对绝大多数元素而言,均可满足多目标地球化学调查样品分析的质量要求:  相似文献   

3.
海洋沉积物有机碳和稳定氮同位素分析的前处理影响   总被引:2,自引:0,他引:2  
海洋沉积物中的有机碳和稳定氮同位素为海洋古环境和碳氮循环提供了大量信息,然而不同的前处理方法对有机碳和稳定氮同位素测定结果的准确性产生不同程度的影响.笔者通过大量条件实验,分析了前处理过程中影响结果准确性的可能因素.①器皿材质:使用聚丙烯和玻璃离心管进行酸处理所得样品的δ13C和δ15N基本无差别.②干燥方式:样品经热烘干燥会导致样品中轻碳组分和易挥发组分的逸散,引起样品中δ13C的分馏.鲜样和酸处理后样均采用热烘干燥会引起样品中δ15N发生明显分馏.③驱酸方式和洗酸程度:水洗造成溶解性有机碳和氮的损失,致使δ13C和δ15N值较真实值偏正,但酸蒸法不能保证氯离子的有效驱除.洗至中性后的洗酸次数对δ13C影响甚小,但会导致δ15N继续偏正.全程采用冷冻干燥,选用PP离心管作为主要酸处理水洗和干燥的器皿,具有很好的重复性,可获得较理想、准确的δ13C和δ15N测试数值.  相似文献   

4.
对山西芮城新石器时代的清凉寺墓地出土的仰韶文化和龙山文化两个阶段人骨中C和N同位素进行了分析,研究了先民的食谱特征和生活经济形式,探讨了不同性别之间食物结构的差异以及不同阶段食谱的变化趋势。所有人骨样品的C和N含量以及C/N 摩尔比,均表明人骨样品保存较好,可用于食谱分析。骨胶原的C和N稳定同位素分析结果显示,清凉寺地区史前先民的食物结构中包括C4类植物和少量以C4类植物为食的动物,反映了先民以种植粟、黍等作物的农业形式,并辅以饲养家畜为生的经济模式;  发现男性比女性获取肉类食物相对较多,可能是由于当时男女社会分工不同的缘故;  此外,从仰韶文化到龙山文化时期,山西芮城清凉寺先民获取植物性食物资源没有明显变化,但肉类资源有所增加,反映了此时的农业生产逐渐趋向更为稳定,家畜饲养有了进一步的发展。  相似文献   

5.
陕北靖边五庄果墚动物骨的C和N稳定同位素分析   总被引:3,自引:2,他引:1  
对陕北靖边五庄果墚遗址出土的4种动物(家猪、狗、鼠、草兔)骨骼进行了C和N稳定同位素分析,研究了这4种动物的食谱特征、营养级结构,分析了人类活动对生活在其周围动物食物结构的影响。所有骨骼样品的C,N含量以及C/N摩尔比表明,所选取的样品均保存较好,可用于食谱分析。骨胶原的C和N稳定同位素分析结果显示,所研究的4种动物呈现出不同的营养级结构,草兔和鼠类为植食性动物,而家猪和狗为杂食性动物,狗部分表现出肉食性。草兔主要以野草或树叶等C3类植物为食;而家猪、狗和鼠类则主要以C4类植物为食,这与先民从事的粟作农业密切相关。褐家鼠、家猪和狗的骨胶原中具有较高的δ15N值,表明其食物结构明显受到人类活动的影响,其中家猪和狗更为明显,其食物结构已与野生动物产生明显差异。  相似文献   

6.
渤海湾北岸Bg10孔磁性地层研究及其构造意义   总被引:2,自引:0,他引:2       下载免费PDF全文
对渤海湾北岸孔深600m的Bg10孔进行了详细的沉积学和古地磁研究,划分了39个沉积单元;基于516个样品(60个交变样品,456个热退样品)分离出的特征剩磁,建立了钻孔的磁性地层,并与标准极性年表相对比,确定正极性N1、N2、N3、N4、N5、N6和N7分别对应C1n、C1r.1n、C2n、C2r.1n、C2An.1n、C2An.2n和C2An.3n,R1、R2、R3、R4、R5和R6分别对应C1r.1r、C1r.2r+C1r.3r、C2r.1r、C2r.2r、C2An.1r和C2An.2r。钻孔B/M界限埋深162.3m,M/G界限埋深为475.8m,钻孔底部位于C2An.3n内,其年龄应小于3.596Ma。Bg10孔包括3个沉积阶段:Ⅰ阶段为3.3~3.6Ma,沉积速率略大于130m/Ma,为构造活动期,唐县期夷平面结束后,盆地沉降和山体隆升的差异增大,并与西部地区的青藏运动A幕相对应;Ⅱ阶段为1.9~3.3Ma,沉积速率为112m/Ma,为盆地的填充过程,气候变化控制沉积过程,但沧县隆起和黄骅坳陷之间沉降仍有差异。Ⅲ阶段为0~1.9Ma,沉积速率为202m/Ma,约在1.0~1.2Ma发生一期构造活动,与西部地区的昆黄运动时代大体相当。1.0Ma以来,沉积过程受构造和气候变化双重影响,沧县隆起和黄骅坳陷之间仍有差异沉降。唐山-邢台断裂带可能在1.9Ma之后活动性增强,并和张家口-蓬莱断裂带在沧县隆起上的交汇区域形成一个次级凹陷。  相似文献   

7.
宗日遗址人骨的稳定同位素分析   总被引:5,自引:0,他引:5  
利用C和N稳定同位素分析方法研究了青海宗日遗址先民的食谱,探讨了先民的经济模式以及食谱变化趋势。所有人骨骨胶原中的C,N含量以及C/N摩尔比,均表明样品保存较好,可用作食谱分析。骨胶原的δ13 C值和δ15 N值分析显示,先民主要以C4类植物为食,也摄取一定量的肉食,反映了以粟、黍等为主食而渔猎为辅的生活方式。性质未明墓葬与宗日墓葬之间存在的较大食谱差异,可能与其来自不同文化密切相关。宗日遗址在发展过程中,先民食谱中C4植物增加而肉食类减少,反映了农业加狩猎采集的混和经济模式向稳定农业模式转变的趋势。  相似文献   

8.
李科  张琳  刘福亮  贾艳琨 《岩矿测试》2020,39(5):753-761
实验室和研究人员所使用的碳、氮同位素标准物质一般由国际原子能机构(IAEA)获得,然而近年来,随着碳氮同位素在实验室质量监控、方法评价、仪器校准等方面的广泛应用,市场需求量不断增加, IAEA研制的碳、氮同位素标准物质的种类与数量逐渐不能满足科学研究快速发展的需求。我国急需研制适应当今分析技术水平的有机质碳氮同位素国家标准物质用以进行质量监控、方法评价、仪器校准。为保证量值传递精度,本文研制了4个有机化学物质的碳氮稳定同位素标准物质,其中3个为尿素样品,1个为L-谷氨酸。经检验4种标准物质的均匀性通过F值检验,标准物质的δ~(13)C和δ~(15)N值经过一年的稳定性检验,特征量值变化在测量方法允许的不确定度范围内,由此判定δ~(13)C和δ~(15)N值稳定性良好。由包括研制单位实验室在内的12家实验室协同定值,采用高温燃烧-气体同位素质谱法测定了δ~(13)C和δ~(15)N值,系列标准物质δ~(13)C和δ~(15)N认定值区间呈梯度分布,δ~(13)C值为-40‰~0‰,δ~(15)N值为-10‰~30‰,涵盖了我国天然样品中有机质碳氮稳定同位素组成范围;研制的系列标准物质δ~(13)C的定值扩展不确定度不大于0.08‰,δ~(15)N的定值扩展不确定度不大于0.09‰,定值水平与国际标准物质相当。该系列标准物质已被国家质检总局批准为国家一级标准物质,批准号为GBW04494~GBW04497。可被用于地质、生态、环境等多种样品δ~(13)C和δ~(15)N比值测定时的分析监控、仪器校准、方法评价、质量保证和质量监控。  相似文献   

9.
根据形成机制,黑碳可以分为烟炱(soot)和木炭(charcoal)。以稻秆、玉米秆、马尾松和煤为原料分别制备了soot和charcoal两类黑碳,并利用元素分析和热解-气相色谱/质谱联用技术(Py-GC/MS)研究了不同类型黑碳(soot和charcoal)的元素组成和热解特征。结果表明,不同类型黑碳的元素组成具有类似性,均表现为C含量最高,其次为O、H和N。但不同类型黑碳也具有一定的差异,soot黑碳的H/C、O/C、N/C和(O+N)/C原子比均高于charcoal黑碳,表明soot颗粒中含有较多的极性组分。Py-GC/MS分析结果显示,不同类型黑碳裂解产物组成具有一定的类似性,均以芳香化合物为主,还包括含氮化合物、呋喃类化合物、酚类化合物和含硫化合物等,表明黑碳都是以高度芳香性的结构为核心,连接有含氧、氮等杂原子基团等组成。研究还表明,不同类型的黑碳具有各自不同的特征,3种生物质soot样品包含更多的来自燃料本身如蛋白质类、木质素类和多糖类结构信息,而charcoal样品则具有更强的芳香性结构。本研究结果对于理解不同类型黑碳的分子结构和组成具有重要的意义。  相似文献   

10.
《岩矿测试》2006,25(2):199-199
通常需要进行总有机碳(TOC)分析的样品种类很多。除废水和地表水外,很多时候也要测量海水中TOC的含量。与其他样品不同的是,海水的基体中含盐量非常高。另外,在化学工业、垃圾处理、电镀行业等样品分析中,样品的含盐量也很高。过高的盐含量易使TOC分析仪中的催化剂(一般是Pt催化剂)受到污染。德国耶拿分析仪器股份公司研制的Multi N/C系列TOC分析仪采用氧化铈(CeO)催化剂,有效地解决了这一问题,测试结果的重现性极佳。  相似文献   

11.
采用低压聚乙烯镶边垫底的粉末样品压片制样,用ARL ADVANT’XP+型X射线荧光光谱仪对土壤和水系沉积物样品中C、N、Na2O、MgO、Al2O3、SiO2、P、S、Cl、K2O、CaO、Sc、Ti、V、Cr、Mn、Fe、Co、Ni、Cu、Zn、Ga、Nb、Zr、Y、Sr、Rb、Pb、Th、Ba、As、Br、Hf、La、Ce和Nd等36个组分进行测定。重点研究了C、N等元素的测定务件和痕量元素的背景选择和谱线重叠校正问题。使用经验系数法和康普敦散射作内标校正基体效应。经标准物质校验,结果与标准值吻合。方法的检出限、精密度和准确度能满足多目标地球化学调查样品的分析要求。用GBW 07404土壤国家标准物质进行测试,12次重复测定的精密度(RSD),除N和Cl〈11.0%,其余各组分均〈6.0%。  相似文献   

12.
X射线荧光光谱法测定生物样品中氯硫氮磷钾铜锌溴   总被引:4,自引:2,他引:2       下载免费PDF全文
研究了用微晶纤维素垫底镶边粉末压片制样-X射线荧光光谱测定生物样品中的Cl、S、N、P、K、Cu、Zn和Br的分析方法。重点研究了N的分析条件和校正方式,K、Cu和Zn的内标选定,测量次数对测定结果的影响。方法的检出限、精密度和准确度基本满足生物样品的分析要求。方法用于实际生物样品的测定,结果与化学法相符。  相似文献   

13.
A method to determine F and Cl in silicate materials by employing pyrohydrolysis and ion chromatography (IC) is described. Pyrohydrolysis involved mixing a pulverised sample (∼ 40 mg) with V2O5 (∼ 160 mg) and heating to 1100 °C under a wet oxygen flow in a quartz tube. Recovery yields of F and Cl were ∼ 97% using a NaF + NaCl standard solution. Detection limits of the pyrohydrolysis-IC method for silicate samples were 0.36 and 0.69 μg g-1 for F and Cl, respectively. Fluorine and Cl concentrations were determined in the reference materials JB-2, JB-3 and JA-1 from the GSJ; BCR-2, BHVO-1, BHVO-2, AGV-1 and AGV-2 from the USGS; and NIST SRM 610, 612 and 614 glasses. Precisions (RSD) for determinations of F were 1–13% (except NIST SRM 614) and 2–19% for Cl, and were dependent on the concentration and blank correction. Most results obtained in this study were in good agreement with those of previous studies. In comparison, the Na2CO3 + ZnO fusion method at 900 °C showed that the yields of F and Cl by alkaline fusion systematically decreased with fusion duration time. The yields were 84% and 83% for JB-3, inferring that F and Cl were lost in this alkaline fusion.  相似文献   

14.
一种新的、快速的碳、氮、硫同位素测定手段──EA-IRMS连线分析技术储雪蕾(中国科学院地质研究所,北京100029)关键词元素分析仪-同位素比值质谱仪,连线分析碳,氮,硫同位素碳、氮、硫三种元素的稳定同位素在地学、生态学、环境科学等领域受到了重视,...  相似文献   

15.
Concentrations of halogens (fluorine, chlorine, bromine and iodine) were determined in six geochemical reference materials (BHVO‐2, GS‐N, JG‐1, JR‐1, JB‐1b, JB‐2). Halogens were first extracted from powdered samples using a pyrohydrolysis technique, then hydrolysis solutions were analysed by ion chromatography for F and Cl and inductively coupled plasma‐mass spectrometry for Br and I. The detection limits in solutions were 100 μg l?1 for both F and Cl and 10 ng l?1 for Br and I. Considering the extraction procedure, performed on a maximum of 500 mg of sample and producing 100 ml of pyrohydrolysis solution, detection limits in rock samples were 20 mg kg?1 for F and Cl and 2 μg kg?1 for Br and I. The mean analytical errors on the studied composition ranges were estimated at 10 mg kg?1 for F and Cl, 100 μg kg?1 for Br and 25 μg kg?1 for I. The concentration values, based on repeated (generally > 10) sample analysis, were in good agreement generally with published values and narrowed the mean dispersion around mean values. Large dispersions are discussed in terms of samples heterogeneity and contaminations during sample preparation. Basaltic RMs were found to be more suitable for studies of halogen compositions than differentiated rock material, especially granites – the powders of which were heterogeneous in halogens at the 500 mg level.  相似文献   

16.
湖泊沉积物中的总有机碳含量(TOC)、总有机氮含量(TN)和碳氮比值(C/N)已被广泛应用于第四纪湖泊古环境研究中。对湖泊沉积物样品进行TOC和TN测定前,首先要有效去除沉积物中的无机碳酸盐,同时较好地保留有机质组分,才能使实验结果较准确地反映古气候环境的变化。选取鹤庆钻孔不同深度的不同岩性样品,分别进行粒度、盐酸浓度、洗除残留酸方法等对去除碳酸盐和总有机碳测定结果影响的前处理条件实验,根据测得的TOC、TN和C/N,结合总无机碳酸盐含量(TIC),确定了鹤庆钻孔沉积物有机碳含量测定的前处理方法:室温条件下,将磨得足够细(无需过筛处理)的样品与足量浓度为2mol/L盐酸充分反应24小时,期间超声震荡3次,采用离心加速沉淀的方法清洗酸处理样品至中性,烘干,研磨均匀上机测定。结果显示,该流程可有效去除沉积物中的无机碳酸盐,测得的TOC、TN数值具有很好的稳定性和可重复性。在此基础上测定了鹤庆钻孔沉积物样品的TOC、C/N和TIC,它们间存在很好的正相关关系,指示了西南季风强度的变化。  相似文献   

17.
A study has been undertaken to determine sulfur in geological samples by coupled analytical techniques. Two measurement methods have been developed: one using an electric furnace coupled to an ion chromatograph (electric furnace-IC) and another using infrared (IR) and quadrupole mass spectrometry (QMS) for evolved gas analysis (EGA) coupled with a thermogravimetric analyser (TGA). In the electric furnace-IC method, measurement was performed without any sample pre-treatment. The measurement conditions were optimised by varying sample quantity, type of catalyst (WO3, Cu, W and V2O5) and sample/catalyst ratio, and the detection limit was 10 μg g−1. Sulfur ores decompose at different temperatures. However, TGA-EGA allowed identification of the different forms of sulfur in the sample, even when they were found in very low concentrations, because the sulfur was continuously analysed. The developed chromatographic method allowed simultaneous analysis of several sample components, such as S, Cl and F, with a low detection limit. The method was much faster and more specific than the methods described in the literature. The results of the sulfur determination had low scatter, possibly because the samples underwent little handling during analysis: the operator only weighed and placed the sample in the furnace, the rest of the measurement process was fully automated. The results obtained by both the developed methods have been validated by using reference materials and comparison with combustion-IR spectroscopy, a standard method for determining total sulfur in a sample.  相似文献   

18.
杜淑兰 《吉林地质》2010,29(4):106-107,119
使用粉末压片法制样,X射线荧光光谱法测定地质样品中氯,探讨了样片背衬、样片接受X光照射时间对测量结果的影响。Cl的精密度(RSD,n=12)小于10%。Cl的方法检出限为12μg/g,采用国家一级标准物质分析验证方法,其结果与标准值相符。  相似文献   

19.
The elemental composition of the individual macerals in a suite of Australian coals has been determined in polished sections using light-element electron microprobe techniques. The analyses of the individual macerals in each coal were combined with data on maceral abundance to produce an inferred chemical composition for the organic matter of the respective whole-coal samples, and this was compared, for each sample, to the respective whole-coal ultimate analysis data, corrected to a dry, ash-free (daf) basis. Except for slightly lower values in some lower-rank coals, the inferred percentages of whole-coal C estimated from the microprobe data were found to be very close to the respective whole-coal C percentages as determined by conventional ultimate analysis. The proportion of O in the coals indicated by the microprobe study, however, appears to be as much as 2% higher than that derived from the ultimate analysis data, especially in the lower-rank coal samples. The difference it may represent errors in calculating the O percentages in ultimate analysis, errors in the microprobe analysis due to difficulties in calibration or measurement, or increased proportions of O in the coals due to factors such as take-up with storage of the polished sections. The percentages of whole-coal N calculated from the microprobe data are up to 0.5% (absolute) below the proportion of N determined directly by whole-coal ultimate analysis. This may reflect the inherent difficulty of dealing with a light element at low concentrations by the microprobe technique, or it may indicate that some of the N occurs in the coals in mineral form. The percentages of whole-coal (organic) S calculated from the microprobe study are close to the percentages of organic S determined for each sample by more conventional techniques. With the exception of (organic) O, which may be affected by other factors, and also possibly of N, the electron microprobe technique appears from the study to provide results that are consistent with ultimate analysis over a wide rank range.  相似文献   

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