共查询到17条相似文献，搜索用时 171 毫秒
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湘南黄沙坪多金属矿床位于南岭构造带中段北缘,属于矽卡岩型矿床。根据矽卡岩产出状态、矿物共生组合及岩相学特征,从早期到晚期可划分为矽卡岩阶段、退化蚀变阶段、早期硫化物阶段和晚期硫化物阶段。矽卡岩矿物主要为石榴石、辉石、符山石等;金属矿物主要为白钨矿、辉钼矿、磁铁矿、方铅矿、闪锌矿等。电子探针分析结果表明,石榴石为钙铝-钙铁榴石系列,从早期到晚期,石榴石具有由钙铝榴石逐渐向钙铁榴石演化的规律。且钙铁榴石普遍发育震荡环带,而环带结构可持续记录钙铁榴石物理化学条件演化的过程。同时两种石榴石中均含Sn的成分,但钙铁榴石中Sn的含量明显高于钙铝榴石。辉石为透辉石-钙铁辉石系列,而且由内接触带向外接触带,辉石中Fe和Mn的含量有逐渐升高的趋势。矽卡岩矿物学特征及矿物成分的变化表明,成矿流体至少经历了两次氧化还原性质的转变。矽卡岩矿物学特征,对W(Sn) Mo Bi等多金属的矿化具有重要的地质指示意义。 相似文献
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研究区为矽卡岩铜矿床,岩体与围岩接触带石榴石矽卡岩十分发育。通过类质同像端员分子百分比计算,石榴石划分为钙铁榴石、钙铝榴石及钙铝—钙铁榴石三种类型,其中钙铝—钙铁榴石是本区常见的石榴石类型。发育于矽卡岩晶洞或空隙中的半自形—自形石榴石具明显的非均质性及发育良好的环带。环带状石榴石CaFe及CaAl端员组分具有三种变异方式。研究表明,石榴石环带及其非均质性不仅与石榴石类质同像端员分子百分比组成有关,而且与石榴石的生成条件有关。 相似文献
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西藏甲玛铜多金属矿石榴子石矿物学特征及成因意义 总被引：2，自引：0，他引：2
甲玛铜多金属矿主要的工业矿体赋存于矽卡岩中,石榴石矽卡岩是主要的矽卡岩类型,因此,研究石榴子石的矿物学特征及其成因具有重要的意义。本文综合前人研究成果,重点对采于甲玛矿区不同钻孔的、不同空间位置的石榴子石进行了矿石学及电子探针分析研究,并系统对比其矿物学特征。对18个石榴子石测点和项目组其它电子探针分析成果表明,甲玛铜多金属矿的石榴子石均为钙质系列,由贫Ti的钙铁榴石和富Ti、Mg、Mn的钙铝榴石组成。受流体氧逸度的制约,矿区中心以钙铁榴石为主,边缘以钙铝榴石为主,从深部至浅部钙铁榴石含量减少,钙铝榴石含量增加。此外,石榴子石"锯齿状"环带成分暗示了其流体过程的多期多阶段性。 相似文献
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喇嘛苏铜锌矿位于中亚成矿域西段,为新疆西天山地区相对较早发现的斑岩-矽卡岩铜锌矿床。本文对喇嘛苏铜锌矿矽卡岩和矽卡岩化大理岩中的矽卡岩矿物进行了岩相学及主微量成分分析,首次发现了喇嘛苏铜锌矿床发育的黑榴石和富钛钙铝榴石。对矽卡岩中发育震荡环带的钙铁榴石进行主量元素和电子探针mapping分析,发现钙铁榴石发育不均一的核部,环带部分表现为Al-Fe元素此消彼长的耦合震荡关系;对钙铁榴石从核部中央向边缘环带进行定向原位微量元素LA-ICPMS分析,发现∑REE表现为连续略有降低的趋势、δEu表现出震荡变化。黑榴石和富钛钙铝榴石表现为核幔结构,显示流体氧逸度的降低,流体从超常富集Ti转变为富集Ti。对富钛钙铝榴石进行原位微量元素LA-ICPMS测试,发现富钛钙铝榴石∑REE高于钙铁榴石(钙铝榴石：58.4×10-6～408.4×10-6;钙铁榴石28.2×10-6～108.7×10-6),富钛钙铝榴石具有强烈正Eu异常(δEu=11.3～15.0),钙铁榴石和富钛钙铝榴石均表现为富集轻稀土而亏损重稀土。喇... 相似文献
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西藏知不拉铜多金属床是冈底斯成矿带东段典型的矽卡岩矿床,石榴子石是矿区最主要的矽卡岩矿物,其颗粒间的空隙是金属矿物的主要赋存部位。本文通过详细的钻孔编录,结合岩矿鉴定及电子探针分析,划分出两种不同类型的石榴子环带,并在垂向上具有明显的分带:产于顶板凝灰岩中的石榴子石以钙铁榴石为主,环带中心颜色深,向外逐渐变浅,由纯钙铁榴石过渡到钙铝榴石;而位于底板大理岩附近石榴子石多以钙铝榴石为主,从环带核部向外颜色变深,化学组成由钙铝榴石向钙铁榴石变化,其它化学成分变化不大。反映该区上下两套不同性质围岩在石榴子石形成过程中所起的作用不同,其中上部凝灰岩主要提供了Fe,底部大理岩则是Ca的来源,热液流体贡献Si、Al及部分Fe,并随着环境和物质成分改变导致环带外侧具有不同于核部的变化趋势。这很好地解释了石榴子石矽卡岩在空间上具有上部为钙铁榴石、向下逐渐过渡到钙铝榴石的空间分带。石榴子石特征及分带显示了其属热液接触交代成因,这为矿床类型的确定提供了依据,也为在该区域内寻找类似矿床指明了方向。 相似文献
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鄂东南矿集区程潮大型矽卡岩铁矿的矿物学特征及其地质意义 总被引：14，自引：5，他引：9
程潮铁矿是鄂东南地区典型的矽卡岩铁矿,迄今为止对其矽卡岩矿物学特征研究较少。本文以程潮铁矿主要矽卡岩矿物为研究对象,利用电子探针技术对该矿矽卡岩矿物学特征进行了研究。电子探针分析结果表明:程潮铁矿石榴石和辉石分别以钙铁榴石和透辉石为主;角闪石主要是韭闪石,其次为铁韭闪石、透闪石、阳起石。其中,早期矽卡岩阶段的石榴石和辉石分别以钙铁榴石和透辉石为主;晚期脉状矽卡岩阶段的石榴石端员组分介于钙铁榴石和钙铝榴石之间,而辉石则相对于早期矽卡岩阶段的辉石更趋近于钙铁辉石端员。通过矽卡岩矿物学特征研究表明,花岗岩对矽卡岩和矿体的形成起到了重要作用。 相似文献
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西藏冈底斯知不拉矽卡岩型铜矿床位于驱龙超大型斑岩型铜钼矿床以南约2 km,矽卡岩及矿体主要呈层状-似层状赋存于下侏罗统叶巴组凝灰岩和大理岩中,具有凝灰岩-石榴子石化凝灰岩-石榴子石矽卡岩-辉石矽卡岩-(硅灰石化)大理岩的空间分带特征.石榴子石从早期到晚期以及从凝灰岩到大理岩方向均具有暗棕红色-棕红色-绿色(褐色)-淡黄褐色的变化特征,以钙铁榴石和钙铝榴石为主,辉石主要为透辉石,少量为锰钙辉石.靠近凝灰岩的石榴子石Al、Ti含量较高,靠近大理岩的石榴子石Fe、Mn含量较高.石榴子石环带特征明显,浅色环带富钙铁,暗色环带富钙铝,由核部向边缘整体显示钙铁组分逐渐增加、钙铝组分相对减少的趋势.知不拉层状-似层状矽卡岩型矿体是由深部隐伏岩浆结晶分异的含矿热液在温度与压力的驱动下沿凝灰岩和大理岩的岩性分界面选择性交代形成,属于岩浆热液接触交代型矿床而非层控或喷流成因层矽卡岩型矿床,应与驱龙斑岩铜钼矿床属于同一套斑岩成矿系统. 相似文献
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通过野外与显微镜观察和电子探针分析, 对柿竹园多金属矿床矽卡岩中石榴石的特征进行了研究.根据石榴石的产出状态、矿物的共生组合, 矽卡岩可分为4个带: 磁铁矿-辉石-石榴石带、辉石-石榴石带、符山石-石榴石带、矽卡岩化大理岩带.从成分上的变化, 探讨了石榴石在各矽卡岩带中的特征.柿竹园矿床矽卡岩中的石榴石可分为早、晚两期, 早期形成的石榴石颜色为暗棕色, 并且在垂直和水平方向上有明显的变化规律.从磁铁矿-辉石-石榴石带到矽卡岩化大理石带, 随着石榴石中Fe2O3含量的减少, Al2O3含量的增加, 由钙铁榴石向钙铝榴石变化; 石榴石晶体具有从核部向边缘由均质性向非均质性变化的规律.早期石榴石形成于较氧化的条件下, 温度为520~620℃, 压力为1000×105Pa, 由富含Si, Al, Fe, Cl, F组分的热液和泥盆纪佘田桥组灰岩反应交代形成.当温度降至450~ 540℃, pH, Eh值降低时, 晚期石榴石形成的同时使白钨矿沉淀.晚期石榴石颜色比早期形成的石榴石浅, 为红色.结晶颗粒较大, 并且, 普遍可以观察到石榴石环带结构. 相似文献
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滇西红牛矽卡岩型铜矿床石榴子石特征 总被引：13，自引：7，他引：6
红牛矽卡岩型铜矿床是义敦岛弧南段格咱火山-岩浆弧新探明的铜矿床之一,目前探明铜金属资源量已达大型规模。与由侵入岩和大理岩直接接触形成的典型矽卡岩矿床不同,红牛铜矿床是隐伏岩体远程矽卡岩化的产物,其矽卡岩矿体与地层产状基本一致,通常相间排列,且距离岩体较远,大理岩中可见粗粒石榴子石和硅灰石,矽卡岩中常见大理岩捕掳体。根据矽卡岩矿物组合可将该矿床矽卡岩类型划分为石榴子石矽卡岩、石榴子石透辉石(或透辉石石榴子石)矽卡岩、透辉石矽卡岩、符山石-石榴子石矽卡岩、硅灰石-石榴子石矽卡岩、绿帘石-石榴子石矽卡岩、阳起石-绿帘石矽卡岩、硅灰石矽卡岩和绿帘石矽卡岩,其中以石榴子石矽卡岩、透辉石矽卡岩和硅灰石矽卡岩为主。石榴子石是最重要的矽卡岩矿物,分布广泛、颜色变化大,且石榴子石矽卡岩中黄铜矿、黄铁矿、磁黄铁矿化最好。本文通过对0ZK10、3ZK11和7ZK16钻孔岩芯的地质编录,查明石榴子石在红牛铜矿床的空间分布和矿化特征,采集该矿区新鲜的石榴子石矽卡岩、矽卡岩化大理岩和角岩磨制成光薄片,开展详细的显微镜下鉴定工作,观察石榴子石的颜色、粒度、结构、光性等岩相学特征,并通过电子探针分析其化学成分。红牛铜矿床石榴子石集中产出于矽卡岩中,少量产出于矽卡岩化大理岩和角岩中,具有明显的两期。早期石榴子石分布广泛,多呈褐色-红褐色,非均质性,异常干涉色,粒径一般在0.2~4mm之间,半自形-自形中细粒结构,韵律环带发育。SiO2含量变化范围为35.18%~37.69%、CaO为33.34%~36.35%、Al2O3为3.64%~13.69%、FeO为11.90%~24.18%、MgO为0.00%~0.08%,FeO和Al2O3含量变化呈负相关,SiO2和CaO含量变化整体呈正相关。石榴子石端员组分总体以钙铁榴石(36.88%~82.36%)为主,其次为钙铝榴石(16.59%~60.75%),还有少量的镁铝榴石、铁铝榴石和锰铝榴石,属于钙铁榴石-钙铝榴石系列(And37-82Gro17-61Spe+Pyr+Alm0.33-3.71)。晚期石榴子石呈浅褐色-浅红色,多发育于矽卡岩化角岩和大理岩中,少量发育于矽卡岩中,半自形-他形粒状结构,均质性,全消光,常具有溶蚀结构。SiO2含量变化范围为35.06%~36.27%、CaO为33.07%~33.77%、Al2O3为0.04%~1.05%、FeO为27.38%~28.18%、MgO为0.00%~0.04%,属于钙铁榴石(94.42%~98.46%)。早期石榴子石韵律环带发育,其主量元素含量变化显示出一定的规律性,由核部向边缘,SiO2和CaO基本保持不变,FeO含量增加,Al2O3含量减少,钙铁榴石含量增加,钙铝榴石含量减少,反映在石榴子石形成早期,成岩环境为低氧逸度、酸性还原环境;形成过程中氧逸度增加,成矿溶液由酸性向弱碱性演化。黄铜矿、磁黄铁矿、辉钼矿等金属硫化物多呈他形充填于石榴子石颗粒之间,或在石榴子石的裂隙中形成细脉,或沿石榴子石生长环带面交代,表明石榴子石形成于矽卡岩早期、早于铜矿化,并为金属硫化物的沉淀富集提供了空间。 相似文献
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Petr Gadas Milan Novák Dominik Talla Michaela Vašinová Galiová 《Mineralogy and Petrology》2013,107(2):311-326
Five distinct paragenetic, morphological and compositional types of grossular garnet (G1, G2, G3, G4, G5) were distinguished within the individual (sub)units of the zoned leucotonalitic pegmatite cutting serpentinized lherzolite with rodingite dikes at ??ár near Ruda nad Moravou, Staré Město Unit, Northern Moravia. Detailed study using Electron Microprobe Analysis, Laser Ablation Inductively Coupled Plasma Mass Spectrometry, Cathodoluminiscence and Infrared Spectroscopy revealed distinct compositional trends in major, minor and trace elements. The contents of Fe3+, Mn, Mg and Ti increase from early garnet (G1) in the outermost grossular subunit through the interstitial garnet (G2) in the leucocratic subunit to graphic intergrowths of quartz+garnet (G3) in the coarse-grained unit. Then these constituents decrease in inclusions of garnet (G4) from the blocky unit and large crystals of garnet (G5) from the quartz core. Some trace elements (V, Ni, Y) exhibit the same trends, only Be evidently increases in garnet from border zone to the centre. Fluorine has negative correlation with Fe3+ as well as some trace elements (Ta, Pb). Concentrations of H2O in garnets, up to 0.22 wt.% H2O, are comparable with spessartine-almandine garnets from the Rutherford No. 2 pegmatite, Virginia, and grossular garnets from high-temperature calc-silicate rocks (skarns). Water contents correlate positively with Fe3+, but inversely with F. The use of water contents in garnet to elucidate the fluctuations of activity of H2O during the pegmatite formation is only limited; the incorporation of hydrous defects seems to be controlled instead by crystal-structural constraints. However, the sum of all volatile components (H2O + F) increases about twice from the outermost subunit to the centre of the pegmatite body. 相似文献
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台湾花莲碧玉因其浓厚的颜色以及较细腻的结构和特殊光学效应受到广大消费者的喜爱.本文运用常规仪器、电子探针等测试手段研究台湾花莲碧玉宝石矿物学特征.通过科学全面系统的研究与前人资料对比可得,碧玉样品的颜色主要为淡绿-深绿色,颜色较为纯净,分布不均匀.内部可见黑色金属矿物杂质.具油脂-丝绢光泽,微透明-不透明,折射率为1.61,相对密度2.96～3.02 g/cm3,硬度为6～7.碧玉的主要组成矿物为透闪石或者阳起石,次要矿物包括铬铁矿、铬钙铝榴石、透绿泥石.电子探针结果显示,碧玉样品的主要元素成分为MgO、SiO2、CaO,以及少量的FeO和微量的Cr2O3、MnO、K2O、Na2O、Al2O3、TiO2.根据样品数据的对比可以推测,碧玉颜色的深度与FeO的含量呈正比,当碧玉含有铬钙铝榴石包体时,碧玉颜色更鲜艳. 相似文献
13.
蒙库铁矿床是一个以下泥盆统斜长角闪变粒岩(原岩为火山岩)为围岩的大型矽卡岩型矿床,矽卡岩矿物组合为辉石、石榴子石和方柱石,退化蚀变岩的组成矿物为角闪石、绿帘石、绿泥石、磷灰石等。电子探针分析结果表明,矽卡岩矿物中单斜辉石以透辉石为主,仅存在少量普通辉石;石榴子石端员组分以钙铁榴石为主,伴以少量钙铝榴石和锰铝榴石;角闪石属于单斜角闪石中的阳起石。蒙库铁矿床的矽卡岩与正常的矽卡岩矿床形成方式不同,不是中酸性岩浆与碳酸盐地层接触交代的产物,而是由热流体沿裂隙交代火山变质岩形成的。 相似文献
14.
湘中曹家坝大型钨矿床的主要矽卡岩矿物学特征及其地质意义 总被引：5，自引：1，他引：4
矽卡岩矿物特征是确定矽卡岩矿床成因的关键证据之一。曹家坝钨矿床是湘中盆地新探明的大型钨矿床,矿体呈似层状产于中泥盆统棋梓桥组灰岩与跳马涧组碎屑岩之间硅钙界面附近。矿区内发育大量矽卡岩矿物,但是未见到岩浆岩。文章通过钻孔编录、矿物的显微特征和电子探针分析,确定了曹家坝钨矿床的成因类型。研究表明曹家坝钨成矿作用与矽卡岩关系密切;石榴子石存在早、晚2个阶段,早阶段石榴子石以钙铝榴石和钙铁榴石为主,晚阶段以钙铝榴石和铁铝榴石-锰铝榴石为主;辉石以钙铁辉石为主;绿泥石主要是铁镁绿泥石。根据矽卡岩的矿物特征,结合发育磁黄铁矿和伴生金矿化等特征,提出曹家坝钨矿床可能是还原性远端矽卡岩型钨矿床。 相似文献
15.
The chemistry of garnet can provide clues to the formation of skarn deposits. The chemical analyses of garnets from the Astamal Fe-LREE distal skarn deposit were completed using an electron probe micro-analyzer. The three types of garnet were identified in the Astamal skarn are: (I) euhedral coarse-grained isotropic garnets (10–30 mm across), which are strongly altered to epidote, calcite and quartz in their rim and core, with intense pervasive retrograde alteration and little variation in the overall composition (Adr94.3–84.4 Grs8.5–2.7 Alm1.9–0.2) (garnet I); (II) anhedral to subhedral brecciated isotropic garnets (5–10 mm across) with minor alteration, a narrow compositional range along the growth lines (Adr82–65.4 Grs21.9–11.7 Alm11.1–2.4) and relatively high Cu (up to 1997 ppm) and Ni (up to 1283 ppm) (garnet II); and (III) subhedral coarser grained garnets (> 30 mm across) with moderate alteration, weak diffusion and irregular zoning of discrete grossular-almandine-rich domains (Adr84.2–48.8 Grs32.4–7.6 Alm19.9–3.5) (garnet III). In the third type, the almandine content increases with increasing grossular/andradite ratio and increasing substitutions of Al for Fe3 +.Almost all three garnet types have been replaced by fine-grained, dark-brown allanite that is typically disseminated and has the same relief as andradite. The Cu content increases while Ni content decreases slightly towards the rim of garnet II and garnet III. Copper in garnet II is positively correlated with increasing almandine content and decreasing andradite content, indicating that the almandine structure, containing relatively more Fe2 +, is more suitable than andradite and grossular to host divalent cations such as Cu2 +. Nickel in garnet II is positively correlated with increasing andradite content, total Fe, and decreasing almandine content. This is because Ni2 + substitutes for Fe3 + in the Y (octahedral) position. There are unusual discrete grossular-almandine rich domains within andraditic garnet III, indicating the low diffusivity of Ca compared to Fe at high temperatures. 相似文献
16.
Martin Okrusch 《Contributions to Mineralogy and Petrology》1971,32(1):1-23
Three garnet-biotite pairs and eleven garnet-cordierite-biotite triplets from the Steinach aureole (Oberpfalz, North-East Bavaria) were analyzed using an electron probe microanalyzer.The regional metamorphic muscovite-biotite schists contain garnets strongly zoned with Mn-Ca-rich centers and Fe-rich edges, the average composition being almandine 67 — spessartine 4 — pyrope 4 — grossular (+andradite) 25.The first contact garnet that is formed in mica schists of the outermost part of the aureole is small, virtually unzoned, and has an average composition of almandine 52 — spessartine 37 — pyrope 8 — grossular (+andradite) 3. With increasing metamorphic grade, there is a consistent trend to form garnets richer in Fe ending up with a composition almandine 84.5 — spessartine 5.5 — pyrope 7.5 — grossular (+andradite) 2.5. This trend is accompanied by a general increase in grain size and modal amount of garnet. Associated cordierites and biotites also become richer in Fe with increasing grade. While the garnets in the highest grade sillimanite hornfelses are poorly zoned, the transitional andalusite-sillimanite hornfelses contain garnets with distinct but variable zonation profiles.These facts can possibly be explained by the time-temperature relationships in the thermal aureole. In a phase diagram such as the Al-Fe-Mg-Mn tetrahedron, the limiting mineral compositions of a four-phase volume or a three-phase triangle are fixed by T and P (the latter remaining effectively constant within a thermal aureole). Thus, in garnet-cordierite-biotite assemblages, garnet zonation should be controlled by temperature variation rather than by a non-equilibrium depletion process. Taking into account the experimental data of Dahl (1968), a zoned garnet from a transitional andalusite-sillimanite hornfels would reflect a temperature increase of about 40° C during its growth. A hypothetical P-X diagram is proposed to show semi-quantitatively the compositional variation of garnet-cordierite pairs with varying pressures (T constant). 相似文献
17.
D. Naimo G. Balassone A. Beran C. Amalfitano M. Imperato D. Stanzione 《Mineralogy and Petrology》2003,77(3-4):259-270
Summary ?Post-magmatic garnets occur in volcanic breccias at the base of the Neapolitan Yellow Tuff (NYT) formation in the north-western
area of the Phlegraean Fields. We report the results of a comprehensive study of these grandites. Garnet is found on the surfaces of tuffaceous blocks or inside their micropores, and is associated with sodalite, sanidine,
marialite and amorphous silica. Garnet samples were examined by scanning electron microscopy (SEM), electron probe microanalysis
(EPMA), powder and single-crystal X-ray diffraction (XRD) and infrared spectroscopy (IR). SEM observations on morphology showed
typical dodecahedral and icositetrahedral habits. EPM analysis showed that they are close to grossular or andradite end members,
with only moderate solid solution between them. X-ray study of single crystals showed cubic cell dimensions ao of 11.86 ? (grossular) and 12.04 ? (andradite). IR spectroscopy confirmed the presence of hydroxyls in coexisting garnet
and sanidine, 0.06 wt% H2O (garnet) and 0.05–0.07 wt% H2O (sanidine), respectively. Well-crystallized sanidine of an earlier generation showed significantly higher water contents,
in the range 0.13–0.23 wt% H2O. Type of occurrence and mineralogical features suggest a post-magmatic (pneumatolitic) genesis for these garnets. This is
consistent with the physico-chemical processes linked to the eruptive dynamics of the breccias. Experimental studies of garnet
synthesis at 550 °C and 2 kbar provide further support for this concept.
Received January 16, 2002; accepted March 18, 2002 相似文献